Specified Blending Process Patents (Class 525/197)
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Patent number: 12198834Abstract: The present invention aims to provide a resin composition capable of providing a molded article that has high slidability and high impact resistance, as well as excellent tensile strength. The present invention relates to a resin composition containing an aromatic polyether ketone resin (I) and a fluororesin (II). The composition preferably has a sodium content of 120 ppm or less relative to the composition or a calcium content of 15 ppm or less relative to the composition.Type: GrantFiled: September 29, 2015Date of Patent: January 14, 2025Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Junya Iida, Koji Nakanishi, Ayane Nakaue, Hideki Kono
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Patent number: 12173107Abstract: To provide a solid catalyst component for olefin polymerization having a small amount of fine powder. A solid catalyst component for olefin polymerization containing a titanium atom, a magnesium atom, a halogen atom, and an internal electron donor. The solid catalyst component has an absolute difference in binding energy of 73.50 to 75.35 eV between a peak (1) with the binding energy of 457.00 to 459.00 eV and a peak (2) with the binding energy of 532.50 to 534.50 eV. The peak (1) and the peak (2) are within peak components measured by X-ray photoelectron spectroscopy, the peak (1) is obtained by waveform separation of peaks assigned to the 2p orbitals of the titanium atom, and the peak (2) is obtained by waveform separation of peaks assigned to the is orbital of an oxygen atom.Type: GrantFiled: May 10, 2023Date of Patent: December 24, 2024Assignee: Sumitomo Chemical Company, LimitedInventors: Tetsuo Suzuki, Masaki Ito
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Patent number: 12122073Abstract: A method for curing a composite including a thermoset resin, a reinforcement material and a thermoplastic additive, the thermoplastic additive having a melt onset temperature, the method including heating the composite to increase a resin temperature of the thermoset resin and, during the heating, controlling the resin temperature such that the resin temperature exceeds the melt onset temperature prior to the thermoset resin achieving a degree of cure of 98 percent.Type: GrantFiled: April 30, 2021Date of Patent: October 22, 2024Assignee: The Boeing CompanyInventors: George Holden, Benjamin P. Adamson, Christopher A. Howe
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Patent number: 11512193Abstract: A polymeric substrate is disclosed. The polymeric substrate comprises a barrier layer including a polymeric material comprising about 50 wt. % or more of at least one polyolefin polymer and 50 wt. % or less of a hydrocarbon resin. The polymeric material exhibits a DTUL of 30° C. or more and a tensile modulus of 500 MPa or more and/or a flexural secant modulus of 500 MPa or more. The barrier layer has a thickness of greater than 200 ?m to 6,500 ?m. A shaped polymeric article comprising the polymeric substrate is also disclosed.Type: GrantFiled: December 11, 2020Date of Patent: November 29, 2022Inventors: Ross Michael Mahan, Billy R. Bodiford
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Patent number: 11059965Abstract: The invention relates to a process for producing thermoplastic molding materials based on acrylonitrile-styrene-acrylate copolymers (ASA) having improved surface properties, in particular an improved stability of surface quality during storage in a hot and humid environment and a reduced content of residual monomers. The invention further relates to the use of a fluidized bed dryer and/or a flow dryer in the production of thermoplastic ASA molding materials for improving surface quality and the use of a fluidized bed dryer and/or a flow dryer in the production of thermoplastic ASA molding materials for reducing the content of residual monomers. The invention further provides ASA molding materials producible by means of the process according to the invention and also moldings.Type: GrantFiled: September 25, 2017Date of Patent: July 13, 2021Assignee: INEOS STYROLUTION GROUP GMBHInventors: Wolfgang Fischer, Ulrich Jansen, Tobias Schulz
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Patent number: 11024441Abstract: The present invention aims to provide and insulated wire having an insulation layer which is excellent in insulation properties and has a low dielectric constant. The insulated wire of the present invention includes a conductor (A) and an insulation layer (B) formed around the periphery of the conductor (A). The insulation layer (B) is formed from a resin composition containing an aromatic polyether ketone resin (I) and a fluororesin (II). The fluororesin (II) is a copolymer of tetrafluoroethylene and a perfluoroethylenic unsaturated compound represented by the following formula (1): CF2?CF—Rf1??(1) wherein Rf1 represents —CF3 or —ORf2, and Rf2 is a C1-C5 perfluoroalkyl group. The aromatic polyether ketone resin (I) and the fluororesin (II) satisfy a melt viscosity ratio (I)/(II) of 0.3 to 5.0.Type: GrantFiled: November 29, 2012Date of Patent: June 1, 2021Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Haruhisa Masuda, Yuki Adachi
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Patent number: 10941220Abstract: A high pressure polymerization process to form an ethylene-based polymer, the process comprising at least the following step: polymerizing a reaction mixture comprising ethylene and at least one comonomer, using a reactor system comprising a reactor configuration, and the following: (A) at least two reaction zones, a zone (reaction zone 1) and an ith zone (reaction zone i where i?2), (B) at least two ethylene-based feed streams, each comprising a percentage of the total make-up ethylene fed to the polymerization process, and wherein a first stream is sent to reaction zone 1 and a second stream is sent to reaction zone i; (C) a control system to control the percentage of the total make-up ethylene in the stream sent to reaction zone 1, and the percentage of the total make-up ethylene in the stream sent to reaction zone i, and wherein the ratio (Q) of the molar concentration of the at least one comonomer fed to the first reaction zone, to the molar concentration of comonomer in the sum of all ethylene-based feeType: GrantFiled: June 23, 2017Date of Patent: March 9, 2021Assignee: Dow Global Technologies LLCInventors: Otto J. Berbee, Stefan Hinrichs, Hayley A. Brown, Bharat I. Chaudhary, John O. Osby, Teresa P. Karjala
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Patent number: 10919283Abstract: A sealing membrane including: a) a thermoplastic polyolefin membrane and b) a barrier film including b1) a barrier layer including at least one polymer selected from ethylene-vinyl alcohol copolymer, polyamide or polyester and b2) an outer layer, wherein the barrier film is laminated over the full surface area or over part of the surface area onto the polyolefin membrane, and so the outer layer is connected directly to the polyolefin membrane, and the outer layer and the polyolefin membrane are both ethylene-based or the outer layer and the polyolefin membrane are both propylene-based. The sealing membrane can be produced at low cost and has a stable interconnecting bond. It is suitable in particular for sealing in building construction or civil engineering work.Type: GrantFiled: September 24, 2015Date of Patent: February 16, 2021Assignee: SIKA TECHNOLOGY AGInventors: Stefan Keiser, Yannic Pironato
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Patent number: 10839980Abstract: A covered electric wire has a core wire and a covering material made of a composition applied around the core wire. The covering material is a melt-moldable resin composition. The resin composition may be a fluororesin composition that includes a fluorinated elastomer and a melt-moldable fluororesin. The fluorinated elastomer can be dispersed in the fluororesin. The resin composition has a volume change after being immersed in an automatic transmission fluid at 165° C. for 70 hours of at most 10%, flexural modulus of at most 200 MPa, a rate of the change in tensile elongation after 2,000 hours of a thermal exposure test in the air at 200° C. of at most 30%, and a melting point of at least 215° C.Type: GrantFiled: October 18, 2018Date of Patent: November 17, 2020Assignee: AGC Inc.Inventor: Satoko Yasuda
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Patent number: 10377889Abstract: A thermoplastic elastomer composition obtained by dynamically crosslinking an ethylene/?-olefin/non-conjugated polymer copolymer (A), a polyolefin resin (B), a softener (C) in an amount of 1 to 200 parts by mass per 100 parts by mass of the total of the copolymer (A) and the resin (B), and a crosslinking agent (D) by the use of a batch mixer under the conditions satisfying the requirements (1) to (4).Type: GrantFiled: March 23, 2016Date of Patent: August 13, 2019Assignee: MITSUI CHEMICALS, INC.Inventors: Hayato Kurita, Kazuyoshi Kaneko, Masahiro Enna, Tatsuya Enomoto, Hideki Mochizuki
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Patent number: 10294362Abstract: The present invention aims to provide a resin composition capable of providing a molded article which is excellent in flexibility, acid resistance, and electrical properties. The resin composition of the present invention includes: an aromatic polyether ketone resin (I); and a fluororesin (II), the fluororesin (II) being a copolymer of tetrafluoroethylene and a perfluoroethylenic unsaturated compound represented by the following formula (1): CF2?CF—Rf1 (1) wherein Rf1 represents —CF3 or —ORf2, and Rf2 represents a C1-C5 perfluoroalkyl group, the fluororesin (II) being dispersed as particles in the aromatic polyether ketone resin (I), the resin composition satisfying a ratio (I):(II) by mass between the aromatic polyether ketone resin (I) and the fluororesin (II) of 50:50 to 10:90.Type: GrantFiled: July 23, 2013Date of Patent: May 21, 2019Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Yuki Ueda, Masami Nishiumi, Haruhisa Masuda
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Patent number: 9862815Abstract: The present invention provides a rubber composition that comprises a rubber component containing a polybutadiene and a dienic rubber or an olefinic rubber immiscible with the polybutadiene, and a filler, in which the Mooney viscosity (ML1+4/100° C.) of the polybutadiene referred to as ML(I), and the Mooney viscosity (ML1+4/100° C.) of the dienic rubber or the olefinic rubber immiscible with the polybutadiene referred to as ML(II) are in a relation of ML(I)?ML(II), a method for producing the rubber composition and a tire using the rubber composition. The rubber composition is excellent in fracture resistance and capable of attaining good workability not lowering the durability such as abrasion resistance and the like of tires, and can reduce the rolling resistance of tires.Type: GrantFiled: September 30, 2011Date of Patent: January 9, 2018Assignee: BRIDGESTONE CORPORATIONInventor: Junko Matsushita
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Patent number: 9663638Abstract: An object of the present invention is to provide an acrylonitrile-butadiene rubber composition that can provide an acrylonitrile-butadiene rubber molded article having excellent properties of non-stickiness, oil resistance, heat resistance, and low-friction properties. The acrylonitrile-butadiene rubber composition of the present invention includes: an acrylonitrile-butadiene rubber (A); and a fluororesin (B), the fluororesin (B) being a perhalopolymer, the composition formed from a co-coagulated composition obtainable by co-coagulating the acrylonitrile-butadiene rubber (A) and the fluororesin (B).Type: GrantFiled: February 28, 2014Date of Patent: May 30, 2017Assignee: DAIKIN INDUSTRIES, LTD.Inventors: Tomihiko Yanagiguchi, Haruhisa Masuda
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Patent number: 9290624Abstract: Disclosed herein is a process for the manufacture of a fluoroelastomer composition containing fluoropolymer fibrils. The process comprises applying shear to a fluoroelastomer gum in a mixer while adding a liquid dispersion of fibrillatable fluoropolymer.Type: GrantFiled: August 27, 2014Date of Patent: March 22, 2016Assignee: E I DU PONT DE NEMOURS AND COMPANYInventors: Christopher J Bish, Kostantinos Kourtakis
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Patent number: 8981006Abstract: The present invention is a method for manufacturing a rubber composition containing a rubber component, a resin, a reinforcing filler and a crosslinking agent, and the method contains: a first step of adding the resin to the rubber component to produce a master batch; a second step of kneading the master batch with the reinforcing filler to produce a filled master batch; and a third step of kneading the filled master batch with the crosslinking agent, thereby providing a rubber composition having higher elasticity and large breaking elongation.Type: GrantFiled: August 19, 2011Date of Patent: March 17, 2015Assignee: Bridgestone CorporationInventors: Reiko Yagi, Kumi Fujiki
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Publication number: 20150045496Abstract: The present disclosure relates to a thermo-reversible and self-healing blend comprising polybutadiene compounded with at least one ring opening agent and at least one ring compound containing at least one hetero-cyclic compound and at least one grafting enabling moiety, wherein the ring opening agent is capable of opening the ring compound to provide at least one open functional group to which the ring opening agent is capable of bonding, and wherein the ring compound is capable of grafting on the backbone of a polymer through the grafting enabling moiety. The present disclosure also relates to a process for preparing a thermo-reversible and self-healing blend and its use in preparing molded articles.Type: ApplicationFiled: March 14, 2013Publication date: February 12, 2015Inventors: Rakshvir Jasra, Madhuchhanda Maiti, Vivek Srivastava
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Patent number: 8920891Abstract: A polymer composition comprises a low-molecular-weight (LMW) ethylene polymer component and a high-molecular-weight (HMW) ethylene polymer component coupled with a polysulfonyl azide. Preferably, the LMW polyethylene component and the HMW polyethylene component co-crystallize in the composition such that it exhibits a single or substantially single peak in a lamella thickness distribution (LTD) curve. The ethylene polymer for the LMW and the HMW polyethylene components can be either homopolymer or ethylene copolymer. Preferably, both components are an ethylene copolymer of the same, or different, composition (that is, with the same or different comonomers). A method of making a pipe that includes selecting a polymer composition having a substantially single peak in the LTD curve is described. Compositions comprising a chromium-catalyzed ethylene polymer, coupled with a polysulfonyl azide are also described herein.Type: GrantFiled: December 9, 2005Date of Patent: December 30, 2014Assignee: Dow Global Technologies LLCInventors: William J. Michie, Jr., Dane Chang, Anthony C. Neubauer, Mridula Kapur, Todd A. Hogan, Felipe B. Martinez, Stephane Costeux
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Patent number: 8889792Abstract: Propylene copolymer composition (P) comprising (a) a propylene copolymer (A) having a comonomer content of at least 1.0 wt.-%, the comomers are C5 to C12 a-olefins, and (b) a propylene copolymer (B) having a comonomer content of 4.0 to 20.0 wt.-%, the comomers are C5 to C12 a-olefins, wherein further (i) the comonomer content in the propylene copolymer (A) is lower compared to the comonomer content in the propylene copolymer (B), (ii) the propylene copolymer composition (P) has a comonomer content of 2.0 to 10.0 wt.-%, the comomers are C5 to C12 a-olefins, (iii) the weight ratio of the propylene copolymer (A) to the propylene copolymer (B) is the range of 30/70 to 80/20.Type: GrantFiled: April 18, 2011Date of Patent: November 18, 2014Assignee: Borealis AGInventors: Juha Paavilainen, Petar Doshev, Kristin Reichelt
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Patent number: 8871868Abstract: Propylene impact copolymers (ICPs) are provided which comprise: (a) a matrix phase which comprises from 60 to 95 weight % of a polypropylene polymer containing from 0 to 6 mole % of units derived from one or more alpha-olefins other than propylene, and (b) a dispersed phase which comprises from 5 to 40 weight % of a copolymer derived from a first comonomer which can be either propylene or ethylene together with a second alpha-olefin comonomer. The ICP is further characterized by having a beta/alpha ratio less than or equal to 1.1. The ICPs of the present invention are particularly well suited for applications requiring clear, tough polymers such as thin walled injection molded articles for frozen food packaging applications.Type: GrantFiled: January 9, 2013Date of Patent: October 28, 2014Assignee: Braskem America, Inc.Inventors: Peter S. Dias, Jonathan D. Kersey, Peter S. Martin, Thomas R. Cuthbert
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Patent number: 8865838Abstract: Provided are methods for producing a thermoplastic vulcanizate. One method includes charging vulcanizable rubber to a reactor; charging a masterbatch of thermoplastic resin and a catalyst for a phenolic resin curative to the reactor; charging a phenolic resin curative to the reactor; and dynamically vulcanizing the rubber with the phenolic resin curative in the presence of the catalyst. Also provided are thermoplastic vulcanizates made by the methods of the invention.Type: GrantFiled: November 24, 2010Date of Patent: October 21, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Stephen F. Roche, Randal H. Kerstetter
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Patent number: 8853327Abstract: A process for preparing a blend of thermoplastic polymer and resin modifier within a single-screw extruder, wherein the resin modifier is a hydrocarbon resin.Type: GrantFiled: August 19, 2011Date of Patent: October 7, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Jay K. Keung, Yann Devorest, Chia Y. Cheng
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Patent number: 8846812Abstract: Disclosed herein is a process for the manufacture of a fluoroelastomer composition containing fluoropolymer fibrils. The process comprises applying shear to a fluoroelastomer gum in a mixer while adding a liquid dispersion of fibrillatable fluoropolymer.Type: GrantFiled: November 14, 2012Date of Patent: September 30, 2014Assignee: E I du Pont de Nemours and CompanyInventors: Christopher J Bish, Kostantinos Kourtakis
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Patent number: 8816009Abstract: The present invention is directed to a method of making a functionalized elastomer, comprising the steps of polymerizing at least one diene monomer and optionally a vinyl aromatic monomer in the presence of an initiator of formula (II) to produce a protected hydroxyl end-terminated polymer where R1, R2, R3 can all be the same or different and are selected from the group consisting of alkyls having from 1 to 8 carbon atoms, cycloalkyls having from 3 to 11 carbon atoms, or aryls having from 6 to 14 carbon atoms, R4 is an alkylene having from 1 to 8 carbon atoms, a cycloalkylene having from 3 to 11 carbon atoms, or an arylene having from 6 to 14 carbon atoms, X is S, O or NH, and Li is lithium; de-protecting the protected hydroxyl end-terminated elastomer to produce a hydroxyl end-functionalized polymer; reacting the hydroxyl end-funtionalized polymer with a maleimido acid chloride to produce a maleimido end-functionalized polymer; and reacting the maleimido end-functionalized polymer with a thiol-terminatedType: GrantFiled: May 15, 2013Date of Patent: August 26, 2014Assignee: The Goodyear Tire & Rubber CompanyInventors: Arindam Mazumdar, Frank James Feher
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Patent number: 8742020Abstract: The instant invention is an impact modifier composition and method of producing the same. The impact modifier composition comprises (a) less than 30 percent by weight of high-density polyethylene, based on the weight of the impact modifier composition; and (b) at least 70 percent by weight of chlorinated polyethylene, based on the weight of the impact modifier composition.Type: GrantFiled: September 5, 2012Date of Patent: June 3, 2014Assignee: Dow Global Technologies LLCInventors: Charles M. Vanek, Mark T. Berard, Edward M. Bridge
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Patent number: 8742019Abstract: Crosslinked polyolefin blends, methods for their production, and articles made of the same are provided. In at least one specific embodiment, the polyolefin blends comprise a first polymer formed in a first reactor and a second polymer formed in a second reactor. The first and second polymers, as well as the resulting blend, may comprise units derived from propylene, ethylene, and a diene. The blended composition can then be compounded with one or more coagents, antioxidants, and/or other additives and crosslinked, preferably by exposure to energetic photons. The crosslinked polymers are particularly useful for making fibers, films, and nonwovens.Type: GrantFiled: September 24, 2010Date of Patent: June 3, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Sunny Jacob, Alistair D. Westwood, Justin R. Huber
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Patent number: 8729186Abstract: A high pressure polymerization process to form an ethylene-based polymer comprises the steps of: A. Injecting a first feed comprising ethylene and optionally a chain transfer agent system (CTA system) into a first autoclave reactor zone operating at polymerization conditions to produce a first zone reaction product, the CTA system of the first reactor zone having a transfer activity Z1; and B. (1) Transferring at least part of the first zone reaction product to a second reactor zone selected from a second autoclave reactor zone or a tubular reactor zone and operating at polymerization conditions, and, optionally, (2) freshly injecting a second feed into the second reactor zone to produce a second zone reaction product, with the proviso that the second reactor zone contains a CTA system having a transfer activity Z2; and with the proviso that the ratio of Z1/Z2 is less than 1.Type: GrantFiled: December 14, 2010Date of Patent: May 20, 2014Assignee: Dow Global Technologies LLCInventors: Otto J. Berbee, Cornelis Den Doelder, Egbert Nijhof, Mehmet Demirors, Sjoerd A. De Vries
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Patent number: 8697808Abstract: A high-temperature solution process for making an ethylene polymer blend having a controlled degree of long-chain branching is disclosed. Ethylene is polymerized in the presence of a first Ziegler-Natta catalyst comprising titanium, magnesium, and aluminum in the absence of hydrogen to produce a first ethylene polymer component having substantial long-chain branching. A second ethylene polymer component having little or no long-chain branching is also prepared. Both polymerizations are performed at a temperature from 140° C. to 250° C. The first and second ethylene polymer components are combined to give a polymer blend. The degree of long-chain branching in the blend is controlled by adjusting the relative amounts of the first and second ethylene polymer components. The invention enables the preparation of valuable products having a pre-determined degree of long-chain branching using readily available Zeigler-Natta catalysts, commercially practiced techniques, and conventional equipment.Type: GrantFiled: November 8, 2010Date of Patent: April 15, 2014Assignee: Equistar Chemicals, LPInventors: Michael W. Lynch, Kenneth J. Klug
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Patent number: 8691354Abstract: This invention is related to the preparation of polyethylene pipe resins suitable for transporting hot and cold water containing chlorine dioxide.Type: GrantFiled: April 26, 2013Date of Patent: April 8, 2014Assignee: Total Research & Technology FeluyInventors: Pierre Belloir, Christine Bertrand
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Patent number: 8664336Abstract: A method for forming a fiber, the method comprising charging to a reactive extruder a first polymer and a second polymer to form an initial blend, where the first polymer is a propylene-based elastomer including up to 35% by weight ethylene-derived units and a heat of fusion, as determined according to DSC procedures according to ASTM E-793, of less than 80 J/g and a melt temperature of less than 110° C., where the second polymer is a propylene-based polymer having a melt temperature in excess of 110° C. and a heat of fusion in excess of 80 J/g, and introducing the reactive blend to a spinneret to form a fiber or extruding the reacted blend through a plurality of die capillaries to form molten threads or filaments which are attenuated in a gas stream to form meltblown fibers.Type: GrantFiled: October 22, 2012Date of Patent: March 4, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Vetkav R. Eswaran, Bruce A. Harrington, Robert F. Bahm, Smita Kacker, Paul E. Rollin, Jr.
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Patent number: 8653194Abstract: Processes and compounds are described herein for single polymer composites based on a process for making the single polymer composites that includes the steps of heating a matrix material to create polymer melt, cooling the polymer melt to below its Tm to create an undercooled polymer melt, or quasi-melt, and combining the melt with an enhancing or reinforcing material to produce a single polymer composite. The process can produce materials that do not have any degradation of the polymer characteristic of the enhancing material due to melting of the polymer in the enhancing material.Type: GrantFiled: May 3, 2012Date of Patent: February 18, 2014Assignee: Georgia Tech Research CorporationInventors: Donggang Yao, Youjiang Wang, Pan Dai, Jinnan Chen
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Patent number: 8575272Abstract: A polymer composition comprising (percent by weight): a) 57%-74%, of a crystalline propylene polymer having an amount of isotactic pentads (mmmm), measured by 13C-MNR on the fraction insoluble in xylene at 25° C., higher than 97.5 molar % and a polydispersity index ranging from 5 to 10; b) 8 to 15%, of an elastomeric copolymer of ethylene and propylene, the copolymer having an amount of recurring units deriving from ethylene ranging from 30 to 50%, and being partially soluble in xylene at ambient temperature; the polymer fraction soluble in xylene at ambient temperature having an intrinsic viscosity value ranging from 2.5 to 3.5 dl/g; and c) 18-28%, of ethylene homopolymer having an intrinsic viscosity value ranging from 1.5 to 4 dl/g; said composition having a value of melt flow rate ranging from 35 to 60 g/10 min, and the amount of hexane extractables lower than 4.0 wt %.Type: GrantFiled: July 20, 2010Date of Patent: November 5, 2013Assignee: Basell Poliolefine Italia S.r.l.Inventors: Marco Ciarafoni, Paola Massari, Gisella Biondini, Roberto Pantaleoni
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Patent number: 8552113Abstract: A rubber material of a wiper blade for windshield wipers is described, which comprises a first rubber component of a first polarity and a second rubber component of a second greater polarity. To equalize the first and second polarities, the first rubber component is at least partially replaced by a chemically functionalized derivative.Type: GrantFiled: September 29, 2008Date of Patent: October 8, 2013Assignee: Robert Bosch GmbHInventors: Eric Pieters, Reiner Lay, Hilde Parton
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Patent number: 8546491Abstract: The present invention provides a polyolefin-based composite resin spherical particle that gives a coating film having a matte appearance, a soft feeling, and excellent scratch resistance by being used for a coating material. The present invention also provides a coating composition containing the polyolefin-based composite resin spherical particle and a coating resin, and a coated article obtained by applying the coating composition to a substrate. The invention relates to a polyolefin-based composite resin spherical particle, which is a spherical particle obtained by mixing 100 parts by mass of a polyolefin-based resin, 40 to 1,500 parts by mass of water, and 3 to 30 parts by mass of an ethylene oxide/propylene oxide copolymer having a weight average molecular weight of 4,000 to 30,000 to prepare a mixture, emulsifying the mixture at a temperature of the highest melting point of the polyolefin-based resin or higher, and cooling the mixture from a temperature at least 25° C.Type: GrantFiled: September 2, 2010Date of Patent: October 1, 2013Assignee: Sumitomo Seika Chemicals Co., Ltd.Inventors: Yuhei Funabiki, Toshiaki Fujiwara, Hirofumi Fujita
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Patent number: 8513360Abstract: Modular plastic structural composites having a web section disposed along a horizontal axis and at least one flange section disposed along a horizontal axis parallel thereto and integrally molded to engage the top or bottom surface of the web section, wherein said composite is formed from a mixture of (A) high density polyolefin and (B) a thermoplastic-coated fiber material, poly-styrene, or a combination thereof. Composites molded in the form of I-Beams and bridges constructed therefrom are also disclosed.Type: GrantFiled: July 8, 2011Date of Patent: August 20, 2013Assignee: Rutgers, The State University of New JerseyInventors: Thomas Nosker, James Kerstein, Louis Simon, Maryann Renfree
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Patent number: 8507599Abstract: Golf balls containing a core having at least one layer and cover having at least one layer are provided. A thermoplastic ionomeric composition is used to form at least one layer of the ball. The composition is prepared by providing a masterbatch comprising cycloalkene (polyalkenamer) rubber and neutralizing agent and mixing the masterbatch with ethylene acid copolymer. The acid groups are neutralized to 30 weight percent or greater, preferably 50% or greater, and more preferably 70% or greater. The resulting ball has high resiliency and rebounding properties along with a soft feel.Type: GrantFiled: December 20, 2010Date of Patent: August 13, 2013Assignee: Acushnet CompanyInventors: Mark L. Binette, Brian Comeau, Douglas S. Goguen, Robert Blink, Michael J. Sullivan, David A. Bulpett
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Patent number: 8455588Abstract: Modular plastic structural composites formed from a mixture of (A) high density polyolefin and one or both of: (B) a thermoplastic-coated fiber material, or (C) polystyrene, poly(methyl methacrylate), or a combination thereof. Composites molded in the form of I-Beams and bridges constructed therefrom are also disclosed.Type: GrantFiled: July 28, 2011Date of Patent: June 4, 2013Assignee: Rutgers, The State University of New JerseyInventors: Jennifer Lynch, Thomas Nosker, Richard Lehman, James D. Idol, Kenneth Van Ness, Richard W. Renfree, Maryann Renfree
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Publication number: 20130137794Abstract: The present invention relates to a process for manufacturing an adhesive by extrusion, wherein the adhesive comprises at least one degraded polypropylene(co)polymer and at least one additional additive.Type: ApplicationFiled: January 25, 2013Publication date: May 30, 2013Applicant: HENKEL AG & CO. KGAAInventor: HENKEL AG & CO. KGAA
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Patent number: 8450421Abstract: Cable layer comprising a propylene polymer composition comprising (a) a polypropylene (A) (b) an elastomeric copolymer (E) comprising units derived from propylene and ethylene and/or C4 to C20 ?-olefin and (c) a polar ethylene polymer (C) wherein the cable layer and/or the propylene polymer composition has a gel content of equal or more than 0.20 wt.-%.Type: GrantFiled: December 17, 2009Date of Patent: May 28, 2013Assignee: Borealis AGInventors: Tung Pham, Doris Machl, Sybille Simon, Katja Klimke, Christer Svanberg, Thomas Steffl, David Friel
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Publication number: 20130099424Abstract: The present techniques provide an extruder screw comprising a high shear melting and mixing zone starting a distance away from an entry point of the screw corresponding to 35%-50% of the overall screw L/D. The extruder screw may also include elements capable of increasing a degree of fill of the high shear melting and mixing zone. In accordance with present techniques, the extruder screw is configured to blend two or more polyolefin polymers having greater than about a 200,000 difference in weight-average molecular weight in a single extrusion step. The extruder screw of the present techniques may be used in a single screw or twin screw extruder, and may be incorporated into a polyolefin production plant for producing multi-modal resins.Type: ApplicationFiled: October 25, 2011Publication date: April 25, 2013Applicant: CHEVRON PHILLIPS CHEMICAL COMPANY LPInventors: Vivek Rohatgi, Ashish M. Sukhadia
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Patent number: 8404755Abstract: Polyester compositions described herein have properties which are particularly suitable for extrusion blow molding (EBM). These properties relate primarily to the rate of crystallization and melt strength or melt viscosity. Articles prepared from the polyester compositions exhibit good clarity, aesthetics, and other physical properties. The polyester compositions also exhibit broad molecular weight distribution (MWD), resulting in improved processability and melt strength. The crystallization rate allows for good drying characteristics while also enabling the use of regrind. In addition, the compositions exhibit improved recyclability, such as in existing PET recycling streams. In one aspect, articles are prepared in an extrusion blow molding method by combining a dry first polyester copolymer component, a dry second polyester component, and a chain extender to form a feed material suitable for extrusion blow molding.Type: GrantFiled: April 17, 2009Date of Patent: March 26, 2013Assignee: PepsiCo, Inc.Inventor: Clarence Sequeira
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Patent number: 8389654Abstract: The present invention relates to a polymer composition, comprising (i) a polypropylene homopolymer, (ii) a polypropylene random copolymer, prepared by copolymerization of propylene with an olefin comonomer and having an amount of olefin comonomer units of 0.2 to 5 wt %, and (iii) an elastomeric copolymer of propylene and at least one olefin comonomer, the polymer composition having a tensile modulus, determined according to ISO 527-2/1B at 1 mm/min. and 23° C., of at least 1200 MPa.Type: GrantFiled: July 1, 2010Date of Patent: March 5, 2013Assignee: Borealis Technology OyInventors: Kauno Alastalo, Carl-Gustaf Ek, Bo Malm, Ulf Torgersen, Olli Tuominen
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Publication number: 20130041109Abstract: To provide a process for producing an ethylene/tetrafluoroethylene copolymer composition which is excellent in mechanical properties of the molded product and which has good moldability. A process for producing a fluorinated copolymer composition, which comprises heating a mixture comprising ethylene/tetrafluoroethylene copolymers having extremely different viscosities and a solvent capable of dissolving the ethylene/tetrafluoroethylene copolymers at a temperature not higher than the melting points of the ethylene/tetrafluoroethylene copolymers, to at least a temperature where the ethylene/tetrafluoroethylene copolymers are dissolved in the solvent to obtain a solution state; and removing the solvent.Type: ApplicationFiled: October 16, 2012Publication date: February 14, 2013Applicant: Asahi Glass Company, LimitedInventor: Asahi Glass Company, Limited
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Publication number: 20130005908Abstract: This invention relates to in-reactor polymer blends comprising at least 60 mole % of propylene and from 0.01 to 10 mole % of at least one diene selected from the group of C6 to C12 ?,?-diene, norbornadiene, vinyl norbornene and mixtures thereof with the balance being ethylene. The blend comprises first and second polymers having different crystallinities and or different Tg's.Type: ApplicationFiled: September 11, 2012Publication date: January 3, 2013Inventors: Kevin R. Squire, Charles J. Ruff, Cesar A. Garcia-Franco, Peijun Jiang
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Patent number: 8338539Abstract: The present invention is a film obtained from a blend of chemically distinguishable copolymers, wherein the film has a light transmission of at least 85%, and/or a haze of less than 6%, and wherein the blend comprises a component copolymer has a secant modulus of less than 15,000 when cast independently into a film.Type: GrantFiled: April 21, 2008Date of Patent: December 25, 2012Assignee: E I du Pont de Nemours and CompanyInventors: Richard J. Arhart, Geraldine M. Lenges
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Patent number: 8283418Abstract: Polypropylene composition comprising a) an isotactic polypropylene (iPP) produced in the presence of a single-site catalyst and said isotactic polypropylene (iPP) has a mean isotactic block length between two structural chain defects, as a statistical average, greater than 70, and b) an atactic polypropylene (aPP) with an absorbance ratio of the absorption band at 998 cm?1 to the absorption band at 973 cm?1 [A998/A973] below 0.80 wherein the weight ratio of said atactic polypropylene to the sum of said atactic polypropylene and said isotactic polypropylene (aPP/(aPP+iPP)) is at least 0.50 wt.-%.Type: GrantFiled: January 18, 2008Date of Patent: October 9, 2012Assignee: Borealis Technology OyInventors: Werner Posch, Manfred Stadlbauer, Stefan Schiesser
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Publication number: 20120248002Abstract: A polymer composition of polypropylene copolymer and 1 to 50% by weight of hard resin. The polypropylene copolymer is either an impact copolymer or a random copolymer. The polymer composition can be used to make injection stretch blow molded articles having improved top load strength.Type: ApplicationFiled: March 30, 2011Publication date: October 4, 2012Applicant: Fina Technology, Inc.Inventors: Luyi Sun, Tim Coffy, Leland Daniels
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Patent number: 8231974Abstract: A fluoropolymer molding method and the resulting molded article are disclosed where the fluoropolymer is composed of fluoropolymer particles each having a multi-layer structure that consists of at least two types of fluoropolymers having different melting points, with at least one inner layer made of a fluoropolymer with a melting point higher than that of the outermost fluoropolymer. The fluoropolymer of the at least one inner layer is molded at a temperature higher than the melting point of the lowest melting point of the fluoropolymers that form the outermost layers of the multi-layer-structure fluoropolymer particles, and lower than the melting point of the fluoropolymer having the highest melting point. The resulting articles have excellent chemical liquid resistance and gas impermeability and low linear expansion coefficient.Type: GrantFiled: March 15, 2012Date of Patent: July 31, 2012Assignee: Dupont Mitsui Fluorochemicals Co LtdInventor: Takao Nishio
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Patent number: 8188188Abstract: A thermoplastic resin composition production method wherein melt-kneading is performed in a stretched flow when producing a thermoplastic resin composition as specified in the paragraph (I) or (II) below: (I) a thermoplastic resin composition comprising a Thermoplastic resin (A) and a Resin (B) with a reactive functional group; (II) a thermoplastic resin composition comprising a Thermoplastic resin (A), a Thermoplastic resin (C) that is different from the Thermoplastic resin (A), and a Compound (D) with a reactive functional group.Type: GrantFiled: March 25, 2009Date of Patent: May 29, 2012Assignee: Toray Industries, Inc.Inventors: Sadayuki Kobayashi, Hideo Matsuoka, Makiko Saito, Masaru Akita
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Patent number: 8173746Abstract: A method for producing an olefinic thermoplastic elastomer comprising mixing 100 parts by weight of an olefin copolymer rubber (A) obtained by polymerizing ethylene, an ?-olefin having 3 to 20 carbon atoms and a non-conjugated polyene, and based on 100 parts by weight of the olefin copolymer rubber (A), 11 to 50 parts by weight of a volatile organic solvent (B) and 5 to 150 parts by weight of an olefin resin (C), and removing from the mixture the volatile organic solvent (B) while kneading in an extruder.Type: GrantFiled: December 19, 2007Date of Patent: May 8, 2012Assignee: Sumitomo Chemical Company, LimitedInventors: Kazuyoshi Fuse, Hironobu Shigematsu, Takeshi Tominaga
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Patent number: 8158260Abstract: A fluoropolymer molding method and the resulting molded article are disclosed where the fluoropolymer is composed of fluoropolymer particles each having a multi-layer structure that consists of at least two types of fluoropolymers having different melting points, with at least one inner layer made of a fluoropolymer with a melting point higher than that of the outermost fluoropolymer. The fluoropolymer of the at least one inner layer is molded at a temperature higher than the melting point of the lowest melting point of the fluoropolymers that form the outermost layers of the multi-layer-structure fluoropolymer particles, and lower than the melting point of the fluoropolymer having the highest melting point. The resulting articles have excellent chemical liquid resistance and gas impermeability and low linear expansion coefficient.Type: GrantFiled: May 29, 2007Date of Patent: April 17, 2012Assignee: Dupont Mitsui Fluorochemicals Co LtdInventor: Takao Nishio