With Subsequent Physical Treatment Patents (Class 525/198)
  • Patent number: 5346727
    Abstract: A process of coating a substrate such as aluminum by the steps of (a) applying thereon a powder coating composition prepared by (i) blending a mix containing a poly(vinylidene fluoride) resin, a thermoplastic resin, a pigment, and a vinylidene fluoride/tetrafluoroethylene/hexafluoropropylene terpolymer, (ii) pelletizing the blend from (i), and (iii) cryogenically grinding the pellets from (ii); (b) heating the powder coating composition above its melt temperature; and (c) cooling the coated substrate.
    Type: Grant
    Filed: July 13, 1993
    Date of Patent: September 13, 1994
    Assignee: Elf Atochem North America, Inc.
    Inventor: Benjamin Simkin
  • Patent number: 5342897
    Abstract: Aqueous polymer dispersions containing,I as the disperse phase, a film-forming dispersion polymer andII in the aqueous phase, from 5 to 40% by weight, based on the total dry mass of I and II, of a completely or partially neutralized water-soluble copolymer ofa) from 50 to 80 mol % of an olefinically unsaturated mono- or dicarboxylic acid, of an anhydride of these acids or of a mixture of these monomers,b) from 20 to 50 mol % of a C.sub.3 -C.sub.12 -alkene, of styrene or of a mixture of these monomers andc) from 0 to 10 mol % of further monomers which can be subjected to free radical polymerization,and the powders obtained by spray-drying these polymer dispersions are suitable as binders for water-resistant plastics renders and coatings and as adhesives or adhesive components.
    Type: Grant
    Filed: March 19, 1993
    Date of Patent: August 30, 1994
    Assignee: BASF Aktiengesellschaft
    Inventors: Gernot Franzman, Folf Petri, Walter Pitteroff
  • Patent number: 5342885
    Abstract: A coating composition is provided from about 0.5 to about 80 parts by weight of a modified selectively hydrogenated block copolymer comprising at least one block of predominantly vinyl arene monomer units and at least one block which is, before hydrogenation, predominantly conjugated diolefin monomer units, the modified block copolymers having been modified by grafting predominantly to the conjugated diolefin block a carboxylic acid or acid derivative and 100 parts by weight of an epoxy resin. The blend of the modified block copolymer and epoxy resin is heated to above 150.degree. C. for a time sufficient for the carboxylic acid or acid derivative to form an adduct with the epoxy resin. The modified block copolymer forms a stable suspension in the epoxy after the adduct is formed which greatly enhances storage stability.
    Type: Grant
    Filed: December 8, 1989
    Date of Patent: August 30, 1994
    Assignee: Shell Oil Company
    Inventor: David J. St. Clair
  • Patent number: 5334663
    Abstract: The compositions contain a) less than 90% and at least 2% by weight of at least one ethylene polymer (A), and optionally, at least one .alpha.-olefin having from 3 to 12 carbon atoms, said polymer containing at least 70% in moles of patterns derived from ethylene, and b) more than 10% and up to 98% by weight of at least one polymer (B) containing at least 85% in moles of patterns derived from at least one .alpha.-olefin having from 3 to 12 carbon atoms and at the most 15% in moles of patterns derived from ethylene, and are characterized in that the polymer (A) is a modified polymer of which the measured limit viscosity is comprised between 1.3 and 100 times its limit viscosity calculated from the distribution of molecular masses. The compositions are obtained by a process consisting in providing a polymer of ethylene and, optionally, of at least one .alpha.-olefin having from 3 to 12 carbon atoms in the presence, on the one hand, of at least one initiator of free radicals in a quantity comprised between 0.
    Type: Grant
    Filed: March 1, 1993
    Date of Patent: August 2, 1994
    Assignee: ECP-Enichem Polymeres France S.A.
    Inventors: Joel Audureau, Vincent Crenna
  • Patent number: 5310801
    Abstract: Disclosed herein is a process for the production of cycloolefin random copolymers comprising flash drying a solution of a cylcoolefin random copolymer in a hydrocarbon, said solution being obtained by copolymerization of ethylene and a specific cycloolefin in said hydrocarbon in the presence of a catalyst. Further proposed herein is a process for the production of cycloolefin random copolymers by copolymerization of ethylene with a specific cycloolefin of the in a hydrocarbon in the presence of a catalyst wherein said copolymerization is carried out in a polymerization reactor where a gas phase is not substantially present.
    Type: Grant
    Filed: April 27, 1993
    Date of Patent: May 10, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Takashi Hayashi, Shunyo Uesugi, Hiroo Wamura
  • Patent number: 5310804
    Abstract: The morphology of a polymer alloy displaying miscibility over some region of composition and temperature may be varied by thermodynamically altering the miscibility, such as raising the temperature for an LCST system, to phase separate the components then quenching the alloy below the glass transition temperature of the matrix phase. Such phase separated alloys have improved toughness.
    Type: Grant
    Filed: June 5, 1992
    Date of Patent: May 10, 1994
    Assignee: Novacor Chemicals (International) S.A.
    Inventors: Gregory Beaucage, Richard S. Stein
  • Patent number: 5296552
    Abstract: An adhesive resin composition is obtained by mixing at least one member (C) selected from the group consisting of unsaturated carboxylic acids and the derivatives thereof, a free-radical initiator (D), and a mixture consisting of a crystalline polyolefin resin (A) and an amorphous or low crystalline olefin copolymer of ethylene and an .alpha.-olefin (B), to obtain a precursor mixture, melt-kneading the precursor mixture in the first half of an extruder having at least one side feeder, to obtain a modified precursor mixture, and feeding a crystalline polyolefin resin (E) from the side feeder of the extruder and mixing the resin (E) with the modified precursor mixture.The adhesive resin composition has good extrudability and exhibits high adhesive property to polar materials such as polar polymeric materials and the like.
    Type: Grant
    Filed: February 25, 1992
    Date of Patent: March 22, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tadayuki Ohmae, Yoshiki Toyoshima, Hisao Tanaka, Mitsuyuki Okada, Harunori Fujita
  • Patent number: 5290483
    Abstract: A process for preparing a conductive polymer article comprises the steps of preparing a dispersible neutral intrinsically conductive polymer; dispersing the intrinsically conductive polymer in a thermoplastic polymer to form a blend; processing the blend into the shape of the desired article; and, contacting the processed article with a dopant solution capable of both swelling the thermoplastic polymer and doping the intrinsically conductive polymer. A process for preparing neutral polyaniline comprises the steps of neutralizing doped polyaniline with a sodium carbonate solution and washing the polyaniline with a polyethyleneglycol solution. A conductive polymer article comprises a blend of an intrinsically conductive polymer and a thermoplastic polymer which is subsequently doped. A conductive polymer blend according to the invention, includes polyaniline, or insulating thermoplastic material and carbon black.
    Type: Grant
    Filed: June 22, 1993
    Date of Patent: March 1, 1994
    Assignee: Americhem, Inc.
    Inventors: Vaman G. Kulkarni, Bernhard Wessling
  • Patent number: 5284892
    Abstract: The present invention relates generally to compositions of polyalkylene imine ("PAI"), particularly polyethylene imine ("PEI") and polyolefin polymer (including copolymers and derivatives thereof); such compositions can be used in producing packaging films for oil containing foods, whereby the film is capable of scavenging unwanted aldehydes from the food product. The preferred compositions comprise a PAI substantially discontinuous phase and a olefinic polymer (including copolymers or derivatives thereof) substantially continuous phase in a weight ratio of PAI to olefinic polymer of about 0.001-30:100 which optionally also includes a binding agent.
    Type: Grant
    Filed: November 10, 1992
    Date of Patent: February 8, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Vincent Brodie, III, Donna L. Visioli
  • Patent number: 5274042
    Abstract: A graft polymer wherein an iodine-containing fluororubber has been grafted on an ethylene-.alpha.-olefin copolymer can be obtained by mixing 30 parts by weight of an iodine-containing fluororubber (a vinylidene fluoride-hexafluoropropylene copolymer containing iodine) and 70 parts by weight of an ethylene-propylene copolymer rubber at 180.degree. C. for 30 minutes while applying shear deformation using a Brabender mixer.
    Type: Grant
    Filed: February 12, 1992
    Date of Patent: December 28, 1993
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Keisaku Yamamoto, Yoshio Tanimoto, Kiyosi Ikeda, Nobuhiro Natsuyama
  • Patent number: 5264493
    Abstract: Isotactic polypropylene and/or ethylene-propylene copolymers are blended with 5-65 wt % of atactic polypropylene and up to 20 wt % of the total blend of a thermosensitive agent. The process is particularly adapted for the incorporation of prodegradents used for reducing the molecular weight and its distribution, thereby producing polyethylene particularly suitable for fiber or film formation.
    Type: Grant
    Filed: March 4, 1993
    Date of Patent: November 23, 1993
    Assignee: Fina Research, S.A.
    Inventors: Claude Palate, Alain M. F. Prevot, Rene Venneman
  • Patent number: 5258419
    Abstract: Polymer blends of non-crystalline mesomorphous polypropylene and a polymer compatible with such polypropylene and the method of making such polymer blends are provided. Such compatible polymer blends exhibit substantial maintenance of structural integrity after exposure to gamma irradiation and provide heat sealing properties, puncture resistance, and tear strength. Films, fibers, and other articles made from such blends may be used in various applications, including medical articles such as medical packaging films, ostomy pouches, and transdermal delivery patches, which may require sterilized storage prior to usage.
    Type: Grant
    Filed: June 26, 1992
    Date of Patent: November 2, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Richard J. Rolando, Dennis L. Krueger
  • Patent number: 5244942
    Abstract: The invention concerns a homogenous, in particular multicolored plastic sheet or panel, based on ethylene vinyl acetate copolymer (EVA) as binder with a filler content of 30 to 80 wt. % and a process for producing it. In other embodiments the binder contains, in addition to the 70 to 85 wt. % of EVA, polypropylenes to improve the processability (tendency to adhere), EPDM to improve the flexibility, and polyethylenes to reduce the tendency to soiling. In the process described, several additives, each consisting of a binder containing at least some ethylene vinyl acetate copolymer, up to 80 wt. % of fillers and up to 5 wt. % of pigments, are mixed, plasticized and granulated or comminuted to form granules or chips of assorted colours which are mixed and, possibly after other processing operations, pressed to form the plastic web or plates.
    Type: Grant
    Filed: August 31, 1992
    Date of Patent: September 14, 1993
    Assignee: Huels Troisdorf AG
    Inventors: Alexander Hover, Manfred Simon, Herbert Schulte, Josef Becker, Richard Weiss, Hans-Joachim Kaseler
  • Patent number: 5239000
    Abstract: Thermoplastic elastomers in which low molecular weight ethylene/propylene/nonconjugated diene rubber ("liquid" EPDM rubber) replaces part of the high molecular weight EPDM rubber used in conventional blends exhibit better tension set properties than conventional blends in which liquid EPDM rubber is not used. A masterbatch containing liquid EPDM rubber and phenolic curing resin which is added to a mixture of polyolefin, high molecular weight EPDM rubber, and other ingredients during mixing results in a thermoplastic elastomer having better mechanical properties as well as better tension set properties than blends of conventional materials.
    Type: Grant
    Filed: June 21, 1991
    Date of Patent: August 24, 1993
    Assignee: Yukong Limited
    Inventors: Myung H. Kim, Byung H. Lee
  • Patent number: 5229460
    Abstract: A solventless process for preparing a fluoropolymer based coating which involves mixing and heating a fluoropolymer with a thermoplastic acrylic resin to obtain a molten mixture, slowly cooling the molten mixture to obtain a solid mass having a degree of crystallinity of at least 85% and grinding the solid mass at a temperature higher than -50.degree. C.
    Type: Grant
    Filed: December 6, 1991
    Date of Patent: July 20, 1993
    Assignee: Evodex Powder Coatings
    Inventors: Mohammed K. Yousuf, Peter J. Stephenson, Nicholas J. Welton, Adrian J. Shortland
  • Patent number: 5210141
    Abstract: Disclosed in a delustered, thermally shrinkable polyvinyl chloride film which is obtained by extruding and orienting a polyvinyl chloride resin composition in which the polyvinyl chloride is a mixture of (A) a partially crosslinked polyvinyl chloride resin and (B) a non-crosslinked polyvinyl chloride resin in an (A)/(B) weight ratio of from 15/85 to 80/20; and in which the average polymerization degree of tetrahydrofuran-soluble portion of the polyvinyl chloride resin (B) is greater than that of tetrahydrofuran-soluble portion of the polyvinyl chloride resin (A).
    Type: Grant
    Filed: February 18, 1992
    Date of Patent: May 11, 1993
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Takeji Yanagisawa, Yasutoshi Soda
  • Patent number: 5206293
    Abstract: A rubber composition obtained by subjecting a mixture of (I) 35-95 parts by weight of a fluoroelastomer, (II) 65-5 parts by weight of at least one member selected from the group consisting of polyethylene, ethylene-vinyl acetate copolymer and ethylene-unsaturated carboxylic acid ester copolymer, and an organic peroxide to reaction while imparting shearing deformation to the mixture. A crosslinkable rubber composition can be obtained by compounding the above rubber composition with a crosslinking agent for the fluoroelastomer (I). The above rubber composition is superior in processability, particularly extrusion-processability, sealing property, heat resistance, steam resistance and weather resistance.
    Type: Grant
    Filed: October 5, 1990
    Date of Patent: April 27, 1993
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Masato Sakai, Isao Sugita, Itsuki Umeda, Yoji Mori
  • Patent number: 5198502
    Abstract: A thermoplastic elastomer composition comprising a thermoplastic elastomeric block or graft polymer comprising at least one hard segment and at least one soft segment and a vulcanizing agent, which can be molded under high shearing stress at a temperature lower than a melting or softening point of the hard sements under shear force to give a molded article having a substantially smooth surface.
    Type: Grant
    Filed: April 9, 1992
    Date of Patent: March 30, 1993
    Assignee: Daikin Industries Ltd.
    Inventor: Masayoshi Tatemoto
  • Patent number: 5187231
    Abstract: Plastics suitable for use as thermoplastic moulding compositions obtained fromA) a thermoplastic vinyl polymer andB) a mixture ofB1) a copolymer of 35 to 49% by weight of maleic acid anhydride and 65 to 51% by weight of styrene andB2) a copolymer of styrene, .alpha.-methylstyrene or mixtures thereof on the one hand and acrylonitrile on the other having an acrylonitrile content of 35 to 60% by weight [based on B2)]and a process for their preparation.
    Type: Grant
    Filed: August 30, 1991
    Date of Patent: February 16, 1993
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Lindner, Herbert Eichenauer, Holger Lutjens, Hans-Eberhard Braese
  • Patent number: 5180769
    Abstract: An olefinic thermoplastic elastomer composition which is excellent in mechanical properties and is substitutable for vulcanized rubbers is provided, which comprises a mixture comprising (A) 40-95% by weight of an oil-extended olefinic copolymer rubber comprising 100 parts by weight of an olefinic copolymer rubber having a Mooney viscosity (ML.sub.1+4 100.degree. C.) of 150-350 and 20-150 parts byw eight of a mineral oil and (B) 5-60% by weight of an olefinic plastic, said mixture being partially crosslinked by dynamic heat treatment in the presence of an organic peroxide. This composition gives superior molded articles free from bleeding of oil on the surface.
    Type: Grant
    Filed: March 19, 1992
    Date of Patent: January 19, 1993
    Assignee: Sumitomo Chemical Company Limited
    Inventors: Tadashi Hikasa, Koichiro Ibuki, Tatsuo Hamanaka, Motoo Mizumori
  • Patent number: 5180783
    Abstract: Compositions containing at least 60% by weight of at least one copolymer (A) of ethylene and at least one alpha-olefin with 3 to 10 carbon atoms, and no more than 40% by weight of at least one copolymer (B) based on ethylene and at least one anhydride of an unsaturated dicarboxylic acid, characterized in that:(i) copolymer (A) has a density between 0.850 and 0.890,(ii) copolymer (B) contains at least 80 mol-% of units derived from ethylene and at least 0.1 mol-% of units derived from the anhydride of an unsaturated dicarboxylic acid, and(iii) at least one of copolymers (A) and (B) is modified by means of an effective amount either of a free-radical initiator if the modification involves copolymer (A), or of at least one compound capable of reacting with the anhydride functions of copolymer (B).
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: January 19, 1993
    Assignee: Atochem
    Inventors: Brigitte Seguela, Patrick Kaifasz
  • Patent number: 5166268
    Abstract: A process for the solid phase forming of an impact polypropylene copolymer comprising (a) providing an impact polypropylene copolymer comprising (i) a matrix, which is either a homopolymer of propylene or a copolymer of propylene and up to about 5 percent by weight of at least one other alpha-olefin based on the weight of the copolymer, and, incorporated into said matrix, (ii) a copolymer of ethylene and at least one other alpha-olefin, said copolymer having a crystallinity of at least about 20 percent and being present in the impact copolymer in an amount of at least about 10 percent by weight based on the total weight of the impact copolymer; and (b) forming the impact polypropylene copolymer at a temperature above the melting point of component (ii) but below the melting point of component (i).
    Type: Grant
    Filed: April 12, 1990
    Date of Patent: November 24, 1992
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: Harold K. Ficker
  • Patent number: 5157081
    Abstract: A dynamically vulcanized alloy composition having improved tensile strength including a first butyl or halogenated butyl rubber-based elastomer and a second EPM and/or EPDM elastomer in a matrix of a crystalline polyolefinic resin, and processes for producing the improved composition.
    Type: Grant
    Filed: June 10, 1991
    Date of Patent: October 20, 1992
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Robert C. Puydak, Donald R. Hazelton, Trazollah Ouhadi
  • Patent number: 5140073
    Abstract: Polymer blends of non-crystalline mesomorphous polypropylene and a polymer compatible with such polypropylene and the method of making such polymer blends are provided. Such compatible polymer blends exhibit substantial maintenance of structural integrity after exposure to gamma irradiation and provide heat sealing properties, puncture resistance, and tear strength. Films, fibers, and other articles made from such blends may be used in various applications, including medical articles such as medical packaging films, ostomy pouches, and transdermal delivery patches, which may require sterilized storage prior to usage.
    Type: Grant
    Filed: June 26, 1989
    Date of Patent: August 18, 1992
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Richard J. Rolando, Dennis L. Krueger
  • Patent number: 5128446
    Abstract: Disclosed herein is a process for the production of cycloolefin random copolymers comprising flash drying a solution of a cylcoolefin random copolymer in a hydrocarbon, said solution being obtained by copolymerization of ethylene and a specific cycloolefin in said hydrocarbon in the prsence of a catalyst. Further proposed herein is a process for the production of cycloolefin random copolymers by copolymerization of ethylene with a specific cycloolefin of the in a hydrocarbon in the presence of a catalyst wherein said copolymerization is carried out in a polymerization reactor where a gas phase is not substantially present.
    Type: Grant
    Filed: September 6, 1989
    Date of Patent: July 7, 1992
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Takashi Hayashi, Shunyo Uesugi, Hiroo Wamura
  • Patent number: 5118753
    Abstract: An olefinic thermoplastic elastomer composition which is excellent in mechanical properties and is substitutable for vulcanized rubbers is provided, which comprises a mixture comprising (A) 40-95 % by weight of an oil-extended olefinic copolymer rubber comprising 100 parts by weight of an olefinic copolymer rubber having a Mooney viscosity (ML.sub.1+4 100.degree. C.) of 150-350 and 20-150 parts by weight of a mineral oil and (B) 5-60% by weight of an olefinic plastic, said mixture being partially crosslinked by dynamic heat treatment in the presence of an organic peroxide. This composition gives superior molded articles free from bleeding of oil on the surface.
    Type: Grant
    Filed: July 5, 1990
    Date of Patent: June 2, 1992
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tadashi Hikasa, Koichiro Ibuki, Tatsuo Hamanaka, Motoo Mizumori
  • Patent number: 5112910
    Abstract: Process for the preparation of mixtures of thermoplastic polymers in powder form from aqueous emulsions ofa) particulate, partly crosslinked rubber-like copolymers of a C.sub.2 -C.sub.8 -alkyl acrylate and/or butadiene with (based on the copolymer) up to 40 wt. % acrylonitrile, styrene or C.sub.1 -C.sub.4 -alkyl methacrylate,b) a thermoplastic resin, and if appropriatec) a rubber-rich graft polymer of styrene, .alpha.-methylstyrene, acrylonitrile, methyl methacrylate and/or alkyl acrylate on a diene or alkyl acrylate rubber having a rubber content of 50 to 95 wt. %,wherein aqueous emulsions of a) and b) and if appropriate c) having polymer contents of 15 to 50 wt. % are mixed with a coagulate solution simultaneously, but in separate streams, continuously or semi-continuously at 20.degree. to 100.degree. C., the polymers a) and b) and if appropriate c) being coagulated, the streams are combined and the polymer mixture is then separated off.
    Type: Grant
    Filed: August 12, 1991
    Date of Patent: May 12, 1992
    Assignee: Bayer AG
    Inventors: Karl-Erwin Piejko, Christian Lindner, Ralph Ostarek, Hans-Eberhard Braese, Karl-Heinz Ott
  • Patent number: 5106906
    Abstract: 37 Highly dispersed mixtures of at least two polymers which are not completely miscible in the melt under customary conditions are produced by melting the polymers used in the presence of supercritical gases or mixtures of gases, intensively thoroughly mixing the molten polymers for long enough until the viscosity of the melt has diminished by at least 10%, subsequently cooling the polymer melt with further thorough mixing, until the viscosity of the melt has at least reached the original value again and then depressurizing the polymer melt. The highly dispersed mixtures produced in this way can be processed in the customary manner into mouldings.
    Type: Grant
    Filed: September 22, 1989
    Date of Patent: April 21, 1992
    Assignee: Bayer Aktiengesellschaft
    Inventors: Erich Meier, Hanns-Ingolf Paul, Rudiger Plaetschke, Gunther Weymanns
  • Patent number: 5086121
    Abstract: Thermoplastic compositions of matter useful as gasketing materials as well as flexible boots and seals which are soft, have low compression set and high tensile. The compositions comprise a polyolefin resin and at least two different rubbers, one of which is vulcanized to a fully cured state by a cure systems which leaves the other rubber(s) unvulcanized. The preferred embodiment comprises a blend of polypropylene and ethylene vinylacetate as the polyolefin resin component, EPDM as the uncured rubber component and a ZnO cured halogenated butyl rubber. In another embodiment of the invention, the resin is excluded and the uncured rubber is a high crystallinity EPDM.
    Type: Grant
    Filed: July 20, 1990
    Date of Patent: February 4, 1992
    Assignee: Advanced Elastomer Systems, L. P.
    Inventors: Donald R. Hazelton, Robert C. Puydak, D. A. Booth
  • Patent number: 5073597
    Abstract: A dynamically vulcanized alloy composition having improved tensile strength including a first butyl or halogenated butyl rubber-base elastomer and a second EPM and/or EPDM elastomer in a matrix of a crystalline polyolefinic resin, and processes for producing the improved composition.
    Type: Grant
    Filed: May 26, 1989
    Date of Patent: December 17, 1991
    Assignee: Advanced Elastomer Systems, L. P.
    Inventors: Robert C. Puydak, Donald R. Hazelton, Trazollah Ouhadi
  • Patent number: 5051478
    Abstract: A dynamically vulcanized composition is provided which comprises a polyolefin resin, an elastomer, and an ethylene copolymer resin such as a copolymer of ethylene and vinyl acetate or an alkyl acrylate. A process for producing the dynamically vulcanized composition is also provided, which process includes the addition of the ethylene copolymer resin after the dynamic vulcanization step. The resulting composition comprises the ethylene copolymer resin predominantly in the polyolefin resin phase. The compositions have improved surface appearance and softness.
    Type: Grant
    Filed: July 26, 1990
    Date of Patent: September 24, 1991
    Assignee: Advanced Elastomer Systems, L. P.
    Inventors: Robert C. Puydak, Donald R. Hazelton
  • Patent number: 5051477
    Abstract: A dynamically vulcanized thermoplastic composition is provided which comprises a polymer blend of a polyolefin resin, a halogenated elastomeric copolymer, such as a halogenated butyl rubber, or a halogenated copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene, and a halogenated polyethylene. The composition has improved flame retarding properties. Additional flame retarding additives may be incorporated in the composition. The dynamically vulcanized thermoplastic composition is suitable for use in roofing sheets.
    Type: Grant
    Filed: May 4, 1990
    Date of Patent: September 24, 1991
    Assignee: Advanced Elastomer Systems, L. P.
    Inventors: Thomas C. Yu, Robert C. Puydak, Charles W. Degener
  • Patent number: 5028663
    Abstract: This invention involves polyethylene blends prepared by a particular method to achieve a unique solid state processability. More specifically, the polyethylene blends of this invention are high density polyethylenes (HDPE) blended in solution with a minor fraction of branched low density polyethylene, linear low density polyethylene or other polyethylene copolymers with a melting point significantly lower than that of HDPE. The HDPE blends described herein possess a unique large scale deformation characteristics below the melting pointing of the major HDPE component, such that the HDPE blends are suitable for solid state processing such as stamping or forging, etc.
    Type: Grant
    Filed: February 22, 1990
    Date of Patent: July 2, 1991
    Inventor: Chan I. Chung
  • Patent number: 5017659
    Abstract: This invention relates to a polymer composition comprising per 100 parts by weight of the composition(a) 30-60 parts by weight of copolymer of ethylene and 1-olefin having at least 6 C atoms,(b) 35-65 parts by weight of copolymer of ethylene and vinyl acetate,(c) 1-10 parts by weight of ethylene-propylene-diene rubber,said polymer composition being obtained by reaction at elevated temperature of the components.
    Type: Grant
    Filed: November 3, 1988
    Date of Patent: May 21, 1991
    Inventor: L. A. van der Groep
  • Patent number: 4997881
    Abstract: A blend of a polyolefin and a poly(alkyl vinyl ether) can be blended at elevated temperature to form a copolymer of the polyolefin and poly(alkyl vinyl ether). The resulting composition is useful as a compatibilizer, as a more water permeable substrate than the polyolefin, and as a photo-degradable material.
    Type: Grant
    Filed: October 6, 1989
    Date of Patent: March 5, 1991
    Assignee: Virginia Tech Intellectual Properties, Inc.
    Inventors: Niranjan Patel, Judy S. Riffle, James E. McGrath
  • Patent number: 4945127
    Abstract: A heat-resistant formed product produced from a polymer composition comprising 40-70 weight % of a thermoplastic elastomer containing a repeating unit derived from ethylene and a repeating unit derived from propylene and 60-30 weight % of an ethylene-vinyl acetate copolymer containing 7.5 weight % or more of a vinyl acetate repeating unit, by blending the polymer composition at a temperature of 160.degree. C. or less, molding it at a temperature of 180.degree. C. or less, and then cross-linking the resulting molded product by irradiating electron beam or heating. The formed product also has good shape memory characteristics.
    Type: Grant
    Filed: December 23, 1988
    Date of Patent: July 31, 1990
    Assignee: Tonen Sekiyukagaku Kabushiki Kaisha
    Inventors: Seiji Kagawa, Hideaki Toda, Shinichiro Nomura
  • Patent number: 4904421
    Abstract: A method for preparing a soft ocular lens, which comprises machining a machinably hard polymer blend body composed essentially of a soft lens material and a hard polymer into an ocular lens shape, and removing the hard polymer from the shaped product.
    Type: Grant
    Filed: November 12, 1987
    Date of Patent: February 27, 1990
    Assignee: Tomei Sangyo Kabushiki Kaisha
    Inventors: Ichiro Ando, Toru Kawaguchi
  • Patent number: 4892910
    Abstract: Polymer powders comprising aggregated polymer particles, said powders having a low content of fines and being suitable as processing aids in the manufacture of polyvinyl chloride, are made by spray drying an aqueous dispersion (latex) of two emulsion polymers, one of which has a dynamic glass transition temperature above 90.degree. C. and the other of which has a dynamic glass transition below 105.degree. C., the latter being at least 10 K. degrees below the former.
    Type: Grant
    Filed: July 13, 1988
    Date of Patent: January 9, 1990
    Assignee: GmbH Rohm
    Inventors: Wolfgang Klesse, Hubert Rauch, Peter J. Arndt, Norbert Suetterlin
  • Patent number: 4892911
    Abstract: This invention teaches using blends of polyisobutylene and polypropylene copolymer in the formation of single layer films and multiple layer sheet materials. The films and sheet materials are useful as flexible packaging materials. The multiple layer sheet materials may be entirely polymeric or may include layers having non-polymeric components, such as metal. The blends of polyisobutylene and polypropylene copolymer unexpectedly have the capability of being extruded through a slot die to form a film having a functionally useful mixture of its components. Thus the invention further includes methods of forming film-like layers of the blends of polyisobutylene and polypropylene copolymer.
    Type: Grant
    Filed: January 11, 1988
    Date of Patent: January 9, 1990
    Assignee: American National Can Company
    Inventor: Roger P. Genske
  • Patent number: 4877827
    Abstract: This invention relates to a polymer composition comprising(a) 30-70 parts by weight of one or more ethylene-propylene-diene rubbers,(b) 30-70 parts by weight of one or more ethylene-vinyl acetate copolymers with a vinyl acetate content of 18-40% by weight, and(c) 1-25 parts by weight of one or more other polymers.The composition can be used with advantage, among other purposes for improving the miscibility of synthetic resins.
    Type: Grant
    Filed: March 14, 1988
    Date of Patent: October 31, 1989
    Inventor: Lambertus A. Van Der Groep
  • Patent number: 4874820
    Abstract: The present invention relates to polymeric composition of a first copolymer which includes at least one copolymer having at least one of Mw/Mn less than 2 and Mz/Mw less than 1.8; and a second copolymer having Mw/Mn greater than or equal to 2. The composition can be produced by preparing the first and second copolymers in different reactors and blending them. The blend can also be produced in a single reactor by initiating the reaction to prepare one copolymer, and adding additional reactants, or recycling the reaction mixture, during the reaction to produce the other copolymer.
    Type: Grant
    Filed: December 27, 1985
    Date of Patent: October 17, 1989
    Assignee: Exxon Research and Engineering Company
    Inventors: Charles Cozewith, Shiaw Ju, Gary W. Verstrate
  • Patent number: 4873288
    Abstract: A two-step process for production of thermoplastic elastomer, which comprises dynamically vulcanizing polypropylene and olefinic rubber in the presence of peroxide (1st step), and dynamically vulcanizing the vulcanized mixture, polypropylene and halogenated butyl rubber in the presence of zinc oxide (2nd step). In another method (a) polyolefin and olefin rubber are dynamically cross-linked in the presence of an organic peroxide and (b) in a separate second operation a dynamically vulcanized blend comprising polyolefin and halogenated butyl rubber is prepared and mixed with (a) to disperse (a) and (b) in one another. The thermoplastic elastomer composition is useful in materials for parts of automobiles.In an example, pp 9 wt. % parts, EPDM 21 wt. % parts, peroxide 0.3 wt. % part and divinylbenzene 0.5 wt. % part were blended and supplied to the first hopper (1) of biaxial extruder as shown in a figure. In the first blending zone (2), temperature and residence time are 200.degree. C.
    Type: Grant
    Filed: October 4, 1988
    Date of Patent: October 10, 1989
    Assignee: Toa Nenryo Kogyo K.K.
    Inventors: Masato Komatsu, Isao Baba, Takashi Mikami, Kiyotada Narukawa, Tsuyoshi Kanai
  • Patent number: 4851500
    Abstract: A process and apparatus is provided for making a rubber-like product from rubber scrap, such as recycled tire scrap. The process includes mixing the rubber scrap with from 1 percent to 15 percent, with respect to the weight of the rubber scrap, of added sulphur, and applying a pressure thereto of about 1000 to 3000 pounds per square inch for 1 to 10 minutes at a temperature of from about 250 degrees F. to about 450 degrees F. In addition, 1 to 8 percent, with respect to the weight of the rubber scrap, of antioxidants and antiozonants are added to the mixture of rubber scrap and sulphur. The sulphur is free sulphur. Derivative sulphur compounds, or like vulcanizing agents, can be added in place of the free sulphur of about 1 to 45 percent of the weight of the rubber scrap. The rubber scrap is buffing of recycled tire rubber, or powder made from recycled tire rubber. An apparatus for carrying out the process is also provided.
    Type: Grant
    Filed: May 16, 1988
    Date of Patent: July 25, 1989
    Assignee: GAF Corporation
    Inventors: Steven S. Lalwani, William G. Pursell, Sr., Charles J. Horner, Jr.
  • Patent number: 4801650
    Abstract: A process for producing a 4-methylpentene-1 copolymer comprising copolymerizing 4-methylpentene-1 with other .alpha.-olefin in a hydrocarbon solvent in the presence of a Ziegler-Natta catalyst and a resin composition containing the 4-methylpentene-1 copolymer are disclosed. The copolymerization comprises a first stage in which (A) a homopolymer or random copolymer of 4-methylpentene-1 having an .alpha.-olefin content of not more than 3 mol % and an intrinsic viscosity of at least 2.5 dl/g is prepared and a second stage in which (B) a random copolymer having an .alpha.-olefin content higher than that of the polymer (A) and no higher than 9 mol % and an intrinsic viscosity of at least 2.5 dl/g is prepared, and the produced copolymer insoluble in the solvent is separated to recover a 4-methylpentene-1 copolymer containing from 5 to 80% by weight of the polymer (A). The process produces a solvent-insoluble copolymer in an increased yield without impairing transparency of the copolymer.
    Type: Grant
    Filed: September 4, 1987
    Date of Patent: January 31, 1989
    Assignee: Sumimoto Chemical Co., Ltd.
    Inventors: Kizuku Wakatsuki, Kazuki Wakamatsu
  • Patent number: 4778833
    Abstract: Composition for the preservation of wood containing a wood preservative, such as a boron compound or a fluorine compound, in a polymer or polymer composition, which upon contact with water releases the wood preservative. Said composition is introduced into a hole in the wood or in a wood construction, whereafter the hole is sealed.
    Type: Grant
    Filed: December 11, 1986
    Date of Patent: October 18, 1988
    Assignee: Nederlandse Centrale Organisatie voor Toegepast- Natuurweten- Schappelijk Onderzoek
    Inventors: Jan W. P. T. Van der Drift, Jan La Brijn
  • Patent number: 4725505
    Abstract: A polymer blend with good hot tack and a low and broad heat seal initiation temperature range for vertical and horizontal form and fill film packaging which contains a copolymer of butene-1 and propylene and a copolymer of propylene and ethylene.
    Type: Grant
    Filed: September 12, 1986
    Date of Patent: February 16, 1988
    Assignee: Shell Oil Company
    Inventors: Charles C. Hwo, Masaki Kohyama
  • Patent number: 4692295
    Abstract: Thermoplastic resin compositions comprising a thermoplastic resin capable of biaxial orientation and an additive resin, having a molecular weight above 10.sup.6, compatible with said thermoplastic resin and selected from a homopolymer of a vinyl monomer or a copolymer of at least two vinyl monomers.
    Type: Grant
    Filed: September 9, 1985
    Date of Patent: September 8, 1987
    Assignee: Produits Chimiques Ugine Kuhlmann
    Inventor: Bernard Vinatier
  • Patent number: 4668738
    Abstract: A process, and the well-dispersed product thereof, for recovering solids from a latex of a grafted rubber concentrate having a rubber substrate and a glassy superstrate by: (a) adding a latex of said superstrate to said grafted rubber concentrate latex; (b) coagulating said latex with high shear to form a paste; (c) heating said paste to cause syneresis of said paste into polymeric particles; and (d) dewatering said particles.
    Type: Grant
    Filed: December 24, 1985
    Date of Patent: May 26, 1987
    Assignee: The Dow Chemical Company
    Inventors: John W. Lee, Eugene R. Moore
  • Patent number: 4650830
    Abstract: Disclosed is a thermoplastic elastomer composition excellent in the injection fusion bondability and the surface gloss, which comprises (1) an amorphous ethylene/.alpha.-olefin copolymer (a) and (2) (i) a lowly crystalline copolymer (b) of propylene with an .alpha.-olefin having at least 4 carbon atoms, (ii) a polymer (d) composed mainly of 1-butene or (iii) a combination of the copolymer (b) or the polymer (d) with a crystalline polymer (c) composed mainly of propylene, wherein the component (1) is present in an amount of 10 to 95% by weight based on the total amount of the components (1) and (2), the component (2) is present in an amount of 5 to 90% by weight based on the total amount of the components (1) and (2), and the component (1) or the components (1) and (2) are partially crosslinked.The partial crosslinking is effected by grafting of a radical-polymerizable monomer having at least two polymerizable groups.
    Type: Grant
    Filed: May 30, 1984
    Date of Patent: March 17, 1987
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Katsuyoshi Yonekura, Akira Uchiyama, Akira Matsuda
  • Patent number: 4615848
    Abstract: A pyroelectric and isotropic piezoelectric polymeric film, the film being formed from a blend of polyvinylidene fluoride and at least one polymer miscible therewith at a temperature above the melting point of the polyvinylidene fluoride, and a process for preparing the film comprising forming the film, heating it to a temperature sufficient to render the film substantially amorphous, cooling at a rate and to a temperature sufficient to prevent crystallization, and polarizing the film to render same pyroelectric and isotropically piezoelectric.
    Type: Grant
    Filed: February 15, 1985
    Date of Patent: October 7, 1986
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Dennis L. Krueger, Neil W. Loeding, Claudia I. Poser