With Subsequent Physical Treatment Patents (Class 525/198)
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Patent number: 5346727Abstract: A process of coating a substrate such as aluminum by the steps of (a) applying thereon a powder coating composition prepared by (i) blending a mix containing a poly(vinylidene fluoride) resin, a thermoplastic resin, a pigment, and a vinylidene fluoride/tetrafluoroethylene/hexafluoropropylene terpolymer, (ii) pelletizing the blend from (i), and (iii) cryogenically grinding the pellets from (ii); (b) heating the powder coating composition above its melt temperature; and (c) cooling the coated substrate.Type: GrantFiled: July 13, 1993Date of Patent: September 13, 1994Assignee: Elf Atochem North America, Inc.Inventor: Benjamin Simkin
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Patent number: 5342897Abstract: Aqueous polymer dispersions containing,I as the disperse phase, a film-forming dispersion polymer andII in the aqueous phase, from 5 to 40% by weight, based on the total dry mass of I and II, of a completely or partially neutralized water-soluble copolymer ofa) from 50 to 80 mol % of an olefinically unsaturated mono- or dicarboxylic acid, of an anhydride of these acids or of a mixture of these monomers,b) from 20 to 50 mol % of a C.sub.3 -C.sub.12 -alkene, of styrene or of a mixture of these monomers andc) from 0 to 10 mol % of further monomers which can be subjected to free radical polymerization,and the powders obtained by spray-drying these polymer dispersions are suitable as binders for water-resistant plastics renders and coatings and as adhesives or adhesive components.Type: GrantFiled: March 19, 1993Date of Patent: August 30, 1994Assignee: BASF AktiengesellschaftInventors: Gernot Franzman, Folf Petri, Walter Pitteroff
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Patent number: 5342885Abstract: A coating composition is provided from about 0.5 to about 80 parts by weight of a modified selectively hydrogenated block copolymer comprising at least one block of predominantly vinyl arene monomer units and at least one block which is, before hydrogenation, predominantly conjugated diolefin monomer units, the modified block copolymers having been modified by grafting predominantly to the conjugated diolefin block a carboxylic acid or acid derivative and 100 parts by weight of an epoxy resin. The blend of the modified block copolymer and epoxy resin is heated to above 150.degree. C. for a time sufficient for the carboxylic acid or acid derivative to form an adduct with the epoxy resin. The modified block copolymer forms a stable suspension in the epoxy after the adduct is formed which greatly enhances storage stability.Type: GrantFiled: December 8, 1989Date of Patent: August 30, 1994Assignee: Shell Oil CompanyInventor: David J. St. Clair
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Patent number: 5334663Abstract: The compositions contain a) less than 90% and at least 2% by weight of at least one ethylene polymer (A), and optionally, at least one .alpha.-olefin having from 3 to 12 carbon atoms, said polymer containing at least 70% in moles of patterns derived from ethylene, and b) more than 10% and up to 98% by weight of at least one polymer (B) containing at least 85% in moles of patterns derived from at least one .alpha.-olefin having from 3 to 12 carbon atoms and at the most 15% in moles of patterns derived from ethylene, and are characterized in that the polymer (A) is a modified polymer of which the measured limit viscosity is comprised between 1.3 and 100 times its limit viscosity calculated from the distribution of molecular masses. The compositions are obtained by a process consisting in providing a polymer of ethylene and, optionally, of at least one .alpha.-olefin having from 3 to 12 carbon atoms in the presence, on the one hand, of at least one initiator of free radicals in a quantity comprised between 0.Type: GrantFiled: March 1, 1993Date of Patent: August 2, 1994Assignee: ECP-Enichem Polymeres France S.A.Inventors: Joel Audureau, Vincent Crenna
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Patent number: 5310801Abstract: Disclosed herein is a process for the production of cycloolefin random copolymers comprising flash drying a solution of a cylcoolefin random copolymer in a hydrocarbon, said solution being obtained by copolymerization of ethylene and a specific cycloolefin in said hydrocarbon in the presence of a catalyst. Further proposed herein is a process for the production of cycloolefin random copolymers by copolymerization of ethylene with a specific cycloolefin of the in a hydrocarbon in the presence of a catalyst wherein said copolymerization is carried out in a polymerization reactor where a gas phase is not substantially present.Type: GrantFiled: April 27, 1993Date of Patent: May 10, 1994Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takashi Hayashi, Shunyo Uesugi, Hiroo Wamura
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Patent number: 5310804Abstract: The morphology of a polymer alloy displaying miscibility over some region of composition and temperature may be varied by thermodynamically altering the miscibility, such as raising the temperature for an LCST system, to phase separate the components then quenching the alloy below the glass transition temperature of the matrix phase. Such phase separated alloys have improved toughness.Type: GrantFiled: June 5, 1992Date of Patent: May 10, 1994Assignee: Novacor Chemicals (International) S.A.Inventors: Gregory Beaucage, Richard S. Stein
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Patent number: 5296552Abstract: An adhesive resin composition is obtained by mixing at least one member (C) selected from the group consisting of unsaturated carboxylic acids and the derivatives thereof, a free-radical initiator (D), and a mixture consisting of a crystalline polyolefin resin (A) and an amorphous or low crystalline olefin copolymer of ethylene and an .alpha.-olefin (B), to obtain a precursor mixture, melt-kneading the precursor mixture in the first half of an extruder having at least one side feeder, to obtain a modified precursor mixture, and feeding a crystalline polyolefin resin (E) from the side feeder of the extruder and mixing the resin (E) with the modified precursor mixture.The adhesive resin composition has good extrudability and exhibits high adhesive property to polar materials such as polar polymeric materials and the like.Type: GrantFiled: February 25, 1992Date of Patent: March 22, 1994Assignee: Sumitomo Chemical Company, LimitedInventors: Tadayuki Ohmae, Yoshiki Toyoshima, Hisao Tanaka, Mitsuyuki Okada, Harunori Fujita
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Patent number: 5290483Abstract: A process for preparing a conductive polymer article comprises the steps of preparing a dispersible neutral intrinsically conductive polymer; dispersing the intrinsically conductive polymer in a thermoplastic polymer to form a blend; processing the blend into the shape of the desired article; and, contacting the processed article with a dopant solution capable of both swelling the thermoplastic polymer and doping the intrinsically conductive polymer. A process for preparing neutral polyaniline comprises the steps of neutralizing doped polyaniline with a sodium carbonate solution and washing the polyaniline with a polyethyleneglycol solution. A conductive polymer article comprises a blend of an intrinsically conductive polymer and a thermoplastic polymer which is subsequently doped. A conductive polymer blend according to the invention, includes polyaniline, or insulating thermoplastic material and carbon black.Type: GrantFiled: June 22, 1993Date of Patent: March 1, 1994Assignee: Americhem, Inc.Inventors: Vaman G. Kulkarni, Bernhard Wessling
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Patent number: 5284892Abstract: The present invention relates generally to compositions of polyalkylene imine ("PAI"), particularly polyethylene imine ("PEI") and polyolefin polymer (including copolymers and derivatives thereof); such compositions can be used in producing packaging films for oil containing foods, whereby the film is capable of scavenging unwanted aldehydes from the food product. The preferred compositions comprise a PAI substantially discontinuous phase and a olefinic polymer (including copolymers or derivatives thereof) substantially continuous phase in a weight ratio of PAI to olefinic polymer of about 0.001-30:100 which optionally also includes a binding agent.Type: GrantFiled: November 10, 1992Date of Patent: February 8, 1994Assignee: E. I. Du Pont de Nemours and CompanyInventors: Vincent Brodie, III, Donna L. Visioli
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Patent number: 5274042Abstract: A graft polymer wherein an iodine-containing fluororubber has been grafted on an ethylene-.alpha.-olefin copolymer can be obtained by mixing 30 parts by weight of an iodine-containing fluororubber (a vinylidene fluoride-hexafluoropropylene copolymer containing iodine) and 70 parts by weight of an ethylene-propylene copolymer rubber at 180.degree. C. for 30 minutes while applying shear deformation using a Brabender mixer.Type: GrantFiled: February 12, 1992Date of Patent: December 28, 1993Assignee: Sumitomo Chemical Company, LimitedInventors: Keisaku Yamamoto, Yoshio Tanimoto, Kiyosi Ikeda, Nobuhiro Natsuyama
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Patent number: 5264493Abstract: Isotactic polypropylene and/or ethylene-propylene copolymers are blended with 5-65 wt % of atactic polypropylene and up to 20 wt % of the total blend of a thermosensitive agent. The process is particularly adapted for the incorporation of prodegradents used for reducing the molecular weight and its distribution, thereby producing polyethylene particularly suitable for fiber or film formation.Type: GrantFiled: March 4, 1993Date of Patent: November 23, 1993Assignee: Fina Research, S.A.Inventors: Claude Palate, Alain M. F. Prevot, Rene Venneman
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Patent number: 5258419Abstract: Polymer blends of non-crystalline mesomorphous polypropylene and a polymer compatible with such polypropylene and the method of making such polymer blends are provided. Such compatible polymer blends exhibit substantial maintenance of structural integrity after exposure to gamma irradiation and provide heat sealing properties, puncture resistance, and tear strength. Films, fibers, and other articles made from such blends may be used in various applications, including medical articles such as medical packaging films, ostomy pouches, and transdermal delivery patches, which may require sterilized storage prior to usage.Type: GrantFiled: June 26, 1992Date of Patent: November 2, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Richard J. Rolando, Dennis L. Krueger
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Patent number: 5244942Abstract: The invention concerns a homogenous, in particular multicolored plastic sheet or panel, based on ethylene vinyl acetate copolymer (EVA) as binder with a filler content of 30 to 80 wt. % and a process for producing it. In other embodiments the binder contains, in addition to the 70 to 85 wt. % of EVA, polypropylenes to improve the processability (tendency to adhere), EPDM to improve the flexibility, and polyethylenes to reduce the tendency to soiling. In the process described, several additives, each consisting of a binder containing at least some ethylene vinyl acetate copolymer, up to 80 wt. % of fillers and up to 5 wt. % of pigments, are mixed, plasticized and granulated or comminuted to form granules or chips of assorted colours which are mixed and, possibly after other processing operations, pressed to form the plastic web or plates.Type: GrantFiled: August 31, 1992Date of Patent: September 14, 1993Assignee: Huels Troisdorf AGInventors: Alexander Hover, Manfred Simon, Herbert Schulte, Josef Becker, Richard Weiss, Hans-Joachim Kaseler
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Patent number: 5239000Abstract: Thermoplastic elastomers in which low molecular weight ethylene/propylene/nonconjugated diene rubber ("liquid" EPDM rubber) replaces part of the high molecular weight EPDM rubber used in conventional blends exhibit better tension set properties than conventional blends in which liquid EPDM rubber is not used. A masterbatch containing liquid EPDM rubber and phenolic curing resin which is added to a mixture of polyolefin, high molecular weight EPDM rubber, and other ingredients during mixing results in a thermoplastic elastomer having better mechanical properties as well as better tension set properties than blends of conventional materials.Type: GrantFiled: June 21, 1991Date of Patent: August 24, 1993Assignee: Yukong LimitedInventors: Myung H. Kim, Byung H. Lee
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Patent number: 5229460Abstract: A solventless process for preparing a fluoropolymer based coating which involves mixing and heating a fluoropolymer with a thermoplastic acrylic resin to obtain a molten mixture, slowly cooling the molten mixture to obtain a solid mass having a degree of crystallinity of at least 85% and grinding the solid mass at a temperature higher than -50.degree. C.Type: GrantFiled: December 6, 1991Date of Patent: July 20, 1993Assignee: Evodex Powder CoatingsInventors: Mohammed K. Yousuf, Peter J. Stephenson, Nicholas J. Welton, Adrian J. Shortland
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Patent number: 5210141Abstract: Disclosed in a delustered, thermally shrinkable polyvinyl chloride film which is obtained by extruding and orienting a polyvinyl chloride resin composition in which the polyvinyl chloride is a mixture of (A) a partially crosslinked polyvinyl chloride resin and (B) a non-crosslinked polyvinyl chloride resin in an (A)/(B) weight ratio of from 15/85 to 80/20; and in which the average polymerization degree of tetrahydrofuran-soluble portion of the polyvinyl chloride resin (B) is greater than that of tetrahydrofuran-soluble portion of the polyvinyl chloride resin (A).Type: GrantFiled: February 18, 1992Date of Patent: May 11, 1993Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Takeji Yanagisawa, Yasutoshi Soda
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Patent number: 5206293Abstract: A rubber composition obtained by subjecting a mixture of (I) 35-95 parts by weight of a fluoroelastomer, (II) 65-5 parts by weight of at least one member selected from the group consisting of polyethylene, ethylene-vinyl acetate copolymer and ethylene-unsaturated carboxylic acid ester copolymer, and an organic peroxide to reaction while imparting shearing deformation to the mixture. A crosslinkable rubber composition can be obtained by compounding the above rubber composition with a crosslinking agent for the fluoroelastomer (I). The above rubber composition is superior in processability, particularly extrusion-processability, sealing property, heat resistance, steam resistance and weather resistance.Type: GrantFiled: October 5, 1990Date of Patent: April 27, 1993Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Masato Sakai, Isao Sugita, Itsuki Umeda, Yoji Mori
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Patent number: 5198502Abstract: A thermoplastic elastomer composition comprising a thermoplastic elastomeric block or graft polymer comprising at least one hard segment and at least one soft segment and a vulcanizing agent, which can be molded under high shearing stress at a temperature lower than a melting or softening point of the hard sements under shear force to give a molded article having a substantially smooth surface.Type: GrantFiled: April 9, 1992Date of Patent: March 30, 1993Assignee: Daikin Industries Ltd.Inventor: Masayoshi Tatemoto
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Patent number: 5187231Abstract: Plastics suitable for use as thermoplastic moulding compositions obtained fromA) a thermoplastic vinyl polymer andB) a mixture ofB1) a copolymer of 35 to 49% by weight of maleic acid anhydride and 65 to 51% by weight of styrene andB2) a copolymer of styrene, .alpha.-methylstyrene or mixtures thereof on the one hand and acrylonitrile on the other having an acrylonitrile content of 35 to 60% by weight [based on B2)]and a process for their preparation.Type: GrantFiled: August 30, 1991Date of Patent: February 16, 1993Assignee: Bayer AktiengesellschaftInventors: Christian Lindner, Herbert Eichenauer, Holger Lutjens, Hans-Eberhard Braese
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Patent number: 5180769Abstract: An olefinic thermoplastic elastomer composition which is excellent in mechanical properties and is substitutable for vulcanized rubbers is provided, which comprises a mixture comprising (A) 40-95% by weight of an oil-extended olefinic copolymer rubber comprising 100 parts by weight of an olefinic copolymer rubber having a Mooney viscosity (ML.sub.1+4 100.degree. C.) of 150-350 and 20-150 parts byw eight of a mineral oil and (B) 5-60% by weight of an olefinic plastic, said mixture being partially crosslinked by dynamic heat treatment in the presence of an organic peroxide. This composition gives superior molded articles free from bleeding of oil on the surface.Type: GrantFiled: March 19, 1992Date of Patent: January 19, 1993Assignee: Sumitomo Chemical Company LimitedInventors: Tadashi Hikasa, Koichiro Ibuki, Tatsuo Hamanaka, Motoo Mizumori
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Patent number: 5180783Abstract: Compositions containing at least 60% by weight of at least one copolymer (A) of ethylene and at least one alpha-olefin with 3 to 10 carbon atoms, and no more than 40% by weight of at least one copolymer (B) based on ethylene and at least one anhydride of an unsaturated dicarboxylic acid, characterized in that:(i) copolymer (A) has a density between 0.850 and 0.890,(ii) copolymer (B) contains at least 80 mol-% of units derived from ethylene and at least 0.1 mol-% of units derived from the anhydride of an unsaturated dicarboxylic acid, and(iii) at least one of copolymers (A) and (B) is modified by means of an effective amount either of a free-radical initiator if the modification involves copolymer (A), or of at least one compound capable of reacting with the anhydride functions of copolymer (B).Type: GrantFiled: December 21, 1990Date of Patent: January 19, 1993Assignee: AtochemInventors: Brigitte Seguela, Patrick Kaifasz
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Patent number: 5166268Abstract: A process for the solid phase forming of an impact polypropylene copolymer comprising (a) providing an impact polypropylene copolymer comprising (i) a matrix, which is either a homopolymer of propylene or a copolymer of propylene and up to about 5 percent by weight of at least one other alpha-olefin based on the weight of the copolymer, and, incorporated into said matrix, (ii) a copolymer of ethylene and at least one other alpha-olefin, said copolymer having a crystallinity of at least about 20 percent and being present in the impact copolymer in an amount of at least about 10 percent by weight based on the total weight of the impact copolymer; and (b) forming the impact polypropylene copolymer at a temperature above the melting point of component (ii) but below the melting point of component (i).Type: GrantFiled: April 12, 1990Date of Patent: November 24, 1992Assignee: Union Carbide Chemicals & Plastics Technology CorporationInventor: Harold K. Ficker
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Patent number: 5157081Abstract: A dynamically vulcanized alloy composition having improved tensile strength including a first butyl or halogenated butyl rubber-based elastomer and a second EPM and/or EPDM elastomer in a matrix of a crystalline polyolefinic resin, and processes for producing the improved composition.Type: GrantFiled: June 10, 1991Date of Patent: October 20, 1992Assignee: Advanced Elastomer Systems, L.P.Inventors: Robert C. Puydak, Donald R. Hazelton, Trazollah Ouhadi
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Patent number: 5140073Abstract: Polymer blends of non-crystalline mesomorphous polypropylene and a polymer compatible with such polypropylene and the method of making such polymer blends are provided. Such compatible polymer blends exhibit substantial maintenance of structural integrity after exposure to gamma irradiation and provide heat sealing properties, puncture resistance, and tear strength. Films, fibers, and other articles made from such blends may be used in various applications, including medical articles such as medical packaging films, ostomy pouches, and transdermal delivery patches, which may require sterilized storage prior to usage.Type: GrantFiled: June 26, 1989Date of Patent: August 18, 1992Assignee: Minnesota Mining and Manufacturing CompanyInventors: Richard J. Rolando, Dennis L. Krueger
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Patent number: 5128446Abstract: Disclosed herein is a process for the production of cycloolefin random copolymers comprising flash drying a solution of a cylcoolefin random copolymer in a hydrocarbon, said solution being obtained by copolymerization of ethylene and a specific cycloolefin in said hydrocarbon in the prsence of a catalyst. Further proposed herein is a process for the production of cycloolefin random copolymers by copolymerization of ethylene with a specific cycloolefin of the in a hydrocarbon in the presence of a catalyst wherein said copolymerization is carried out in a polymerization reactor where a gas phase is not substantially present.Type: GrantFiled: September 6, 1989Date of Patent: July 7, 1992Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Takashi Hayashi, Shunyo Uesugi, Hiroo Wamura
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Patent number: 5118753Abstract: An olefinic thermoplastic elastomer composition which is excellent in mechanical properties and is substitutable for vulcanized rubbers is provided, which comprises a mixture comprising (A) 40-95 % by weight of an oil-extended olefinic copolymer rubber comprising 100 parts by weight of an olefinic copolymer rubber having a Mooney viscosity (ML.sub.1+4 100.degree. C.) of 150-350 and 20-150 parts by weight of a mineral oil and (B) 5-60% by weight of an olefinic plastic, said mixture being partially crosslinked by dynamic heat treatment in the presence of an organic peroxide. This composition gives superior molded articles free from bleeding of oil on the surface.Type: GrantFiled: July 5, 1990Date of Patent: June 2, 1992Assignee: Sumitomo Chemical Company, LimitedInventors: Tadashi Hikasa, Koichiro Ibuki, Tatsuo Hamanaka, Motoo Mizumori
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Patent number: 5112910Abstract: Process for the preparation of mixtures of thermoplastic polymers in powder form from aqueous emulsions ofa) particulate, partly crosslinked rubber-like copolymers of a C.sub.2 -C.sub.8 -alkyl acrylate and/or butadiene with (based on the copolymer) up to 40 wt. % acrylonitrile, styrene or C.sub.1 -C.sub.4 -alkyl methacrylate,b) a thermoplastic resin, and if appropriatec) a rubber-rich graft polymer of styrene, .alpha.-methylstyrene, acrylonitrile, methyl methacrylate and/or alkyl acrylate on a diene or alkyl acrylate rubber having a rubber content of 50 to 95 wt. %,wherein aqueous emulsions of a) and b) and if appropriate c) having polymer contents of 15 to 50 wt. % are mixed with a coagulate solution simultaneously, but in separate streams, continuously or semi-continuously at 20.degree. to 100.degree. C., the polymers a) and b) and if appropriate c) being coagulated, the streams are combined and the polymer mixture is then separated off.Type: GrantFiled: August 12, 1991Date of Patent: May 12, 1992Assignee: Bayer AGInventors: Karl-Erwin Piejko, Christian Lindner, Ralph Ostarek, Hans-Eberhard Braese, Karl-Heinz Ott
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Patent number: 5106906Abstract: 37 Highly dispersed mixtures of at least two polymers which are not completely miscible in the melt under customary conditions are produced by melting the polymers used in the presence of supercritical gases or mixtures of gases, intensively thoroughly mixing the molten polymers for long enough until the viscosity of the melt has diminished by at least 10%, subsequently cooling the polymer melt with further thorough mixing, until the viscosity of the melt has at least reached the original value again and then depressurizing the polymer melt. The highly dispersed mixtures produced in this way can be processed in the customary manner into mouldings.Type: GrantFiled: September 22, 1989Date of Patent: April 21, 1992Assignee: Bayer AktiengesellschaftInventors: Erich Meier, Hanns-Ingolf Paul, Rudiger Plaetschke, Gunther Weymanns
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Patent number: 5086121Abstract: Thermoplastic compositions of matter useful as gasketing materials as well as flexible boots and seals which are soft, have low compression set and high tensile. The compositions comprise a polyolefin resin and at least two different rubbers, one of which is vulcanized to a fully cured state by a cure systems which leaves the other rubber(s) unvulcanized. The preferred embodiment comprises a blend of polypropylene and ethylene vinylacetate as the polyolefin resin component, EPDM as the uncured rubber component and a ZnO cured halogenated butyl rubber. In another embodiment of the invention, the resin is excluded and the uncured rubber is a high crystallinity EPDM.Type: GrantFiled: July 20, 1990Date of Patent: February 4, 1992Assignee: Advanced Elastomer Systems, L. P.Inventors: Donald R. Hazelton, Robert C. Puydak, D. A. Booth
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Patent number: 5073597Abstract: A dynamically vulcanized alloy composition having improved tensile strength including a first butyl or halogenated butyl rubber-base elastomer and a second EPM and/or EPDM elastomer in a matrix of a crystalline polyolefinic resin, and processes for producing the improved composition.Type: GrantFiled: May 26, 1989Date of Patent: December 17, 1991Assignee: Advanced Elastomer Systems, L. P.Inventors: Robert C. Puydak, Donald R. Hazelton, Trazollah Ouhadi
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Patent number: 5051478Abstract: A dynamically vulcanized composition is provided which comprises a polyolefin resin, an elastomer, and an ethylene copolymer resin such as a copolymer of ethylene and vinyl acetate or an alkyl acrylate. A process for producing the dynamically vulcanized composition is also provided, which process includes the addition of the ethylene copolymer resin after the dynamic vulcanization step. The resulting composition comprises the ethylene copolymer resin predominantly in the polyolefin resin phase. The compositions have improved surface appearance and softness.Type: GrantFiled: July 26, 1990Date of Patent: September 24, 1991Assignee: Advanced Elastomer Systems, L. P.Inventors: Robert C. Puydak, Donald R. Hazelton
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Patent number: 5051477Abstract: A dynamically vulcanized thermoplastic composition is provided which comprises a polymer blend of a polyolefin resin, a halogenated elastomeric copolymer, such as a halogenated butyl rubber, or a halogenated copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene, and a halogenated polyethylene. The composition has improved flame retarding properties. Additional flame retarding additives may be incorporated in the composition. The dynamically vulcanized thermoplastic composition is suitable for use in roofing sheets.Type: GrantFiled: May 4, 1990Date of Patent: September 24, 1991Assignee: Advanced Elastomer Systems, L. P.Inventors: Thomas C. Yu, Robert C. Puydak, Charles W. Degener
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Patent number: 5028663Abstract: This invention involves polyethylene blends prepared by a particular method to achieve a unique solid state processability. More specifically, the polyethylene blends of this invention are high density polyethylenes (HDPE) blended in solution with a minor fraction of branched low density polyethylene, linear low density polyethylene or other polyethylene copolymers with a melting point significantly lower than that of HDPE. The HDPE blends described herein possess a unique large scale deformation characteristics below the melting pointing of the major HDPE component, such that the HDPE blends are suitable for solid state processing such as stamping or forging, etc.Type: GrantFiled: February 22, 1990Date of Patent: July 2, 1991Inventor: Chan I. Chung
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Patent number: 5017659Abstract: This invention relates to a polymer composition comprising per 100 parts by weight of the composition(a) 30-60 parts by weight of copolymer of ethylene and 1-olefin having at least 6 C atoms,(b) 35-65 parts by weight of copolymer of ethylene and vinyl acetate,(c) 1-10 parts by weight of ethylene-propylene-diene rubber,said polymer composition being obtained by reaction at elevated temperature of the components.Type: GrantFiled: November 3, 1988Date of Patent: May 21, 1991Inventor: L. A. van der Groep
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Patent number: 4997881Abstract: A blend of a polyolefin and a poly(alkyl vinyl ether) can be blended at elevated temperature to form a copolymer of the polyolefin and poly(alkyl vinyl ether). The resulting composition is useful as a compatibilizer, as a more water permeable substrate than the polyolefin, and as a photo-degradable material.Type: GrantFiled: October 6, 1989Date of Patent: March 5, 1991Assignee: Virginia Tech Intellectual Properties, Inc.Inventors: Niranjan Patel, Judy S. Riffle, James E. McGrath
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Patent number: 4945127Abstract: A heat-resistant formed product produced from a polymer composition comprising 40-70 weight % of a thermoplastic elastomer containing a repeating unit derived from ethylene and a repeating unit derived from propylene and 60-30 weight % of an ethylene-vinyl acetate copolymer containing 7.5 weight % or more of a vinyl acetate repeating unit, by blending the polymer composition at a temperature of 160.degree. C. or less, molding it at a temperature of 180.degree. C. or less, and then cross-linking the resulting molded product by irradiating electron beam or heating. The formed product also has good shape memory characteristics.Type: GrantFiled: December 23, 1988Date of Patent: July 31, 1990Assignee: Tonen Sekiyukagaku Kabushiki KaishaInventors: Seiji Kagawa, Hideaki Toda, Shinichiro Nomura
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Patent number: 4904421Abstract: A method for preparing a soft ocular lens, which comprises machining a machinably hard polymer blend body composed essentially of a soft lens material and a hard polymer into an ocular lens shape, and removing the hard polymer from the shaped product.Type: GrantFiled: November 12, 1987Date of Patent: February 27, 1990Assignee: Tomei Sangyo Kabushiki KaishaInventors: Ichiro Ando, Toru Kawaguchi
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Patent number: 4892910Abstract: Polymer powders comprising aggregated polymer particles, said powders having a low content of fines and being suitable as processing aids in the manufacture of polyvinyl chloride, are made by spray drying an aqueous dispersion (latex) of two emulsion polymers, one of which has a dynamic glass transition temperature above 90.degree. C. and the other of which has a dynamic glass transition below 105.degree. C., the latter being at least 10 K. degrees below the former.Type: GrantFiled: July 13, 1988Date of Patent: January 9, 1990Assignee: GmbH RohmInventors: Wolfgang Klesse, Hubert Rauch, Peter J. Arndt, Norbert Suetterlin
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Patent number: 4892911Abstract: This invention teaches using blends of polyisobutylene and polypropylene copolymer in the formation of single layer films and multiple layer sheet materials. The films and sheet materials are useful as flexible packaging materials. The multiple layer sheet materials may be entirely polymeric or may include layers having non-polymeric components, such as metal. The blends of polyisobutylene and polypropylene copolymer unexpectedly have the capability of being extruded through a slot die to form a film having a functionally useful mixture of its components. Thus the invention further includes methods of forming film-like layers of the blends of polyisobutylene and polypropylene copolymer.Type: GrantFiled: January 11, 1988Date of Patent: January 9, 1990Assignee: American National Can CompanyInventor: Roger P. Genske
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Patent number: 4877827Abstract: This invention relates to a polymer composition comprising(a) 30-70 parts by weight of one or more ethylene-propylene-diene rubbers,(b) 30-70 parts by weight of one or more ethylene-vinyl acetate copolymers with a vinyl acetate content of 18-40% by weight, and(c) 1-25 parts by weight of one or more other polymers.The composition can be used with advantage, among other purposes for improving the miscibility of synthetic resins.Type: GrantFiled: March 14, 1988Date of Patent: October 31, 1989Inventor: Lambertus A. Van Der Groep
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Patent number: 4874820Abstract: The present invention relates to polymeric composition of a first copolymer which includes at least one copolymer having at least one of Mw/Mn less than 2 and Mz/Mw less than 1.8; and a second copolymer having Mw/Mn greater than or equal to 2. The composition can be produced by preparing the first and second copolymers in different reactors and blending them. The blend can also be produced in a single reactor by initiating the reaction to prepare one copolymer, and adding additional reactants, or recycling the reaction mixture, during the reaction to produce the other copolymer.Type: GrantFiled: December 27, 1985Date of Patent: October 17, 1989Assignee: Exxon Research and Engineering CompanyInventors: Charles Cozewith, Shiaw Ju, Gary W. Verstrate
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Patent number: 4873288Abstract: A two-step process for production of thermoplastic elastomer, which comprises dynamically vulcanizing polypropylene and olefinic rubber in the presence of peroxide (1st step), and dynamically vulcanizing the vulcanized mixture, polypropylene and halogenated butyl rubber in the presence of zinc oxide (2nd step). In another method (a) polyolefin and olefin rubber are dynamically cross-linked in the presence of an organic peroxide and (b) in a separate second operation a dynamically vulcanized blend comprising polyolefin and halogenated butyl rubber is prepared and mixed with (a) to disperse (a) and (b) in one another. The thermoplastic elastomer composition is useful in materials for parts of automobiles.In an example, pp 9 wt. % parts, EPDM 21 wt. % parts, peroxide 0.3 wt. % part and divinylbenzene 0.5 wt. % part were blended and supplied to the first hopper (1) of biaxial extruder as shown in a figure. In the first blending zone (2), temperature and residence time are 200.degree. C.Type: GrantFiled: October 4, 1988Date of Patent: October 10, 1989Assignee: Toa Nenryo Kogyo K.K.Inventors: Masato Komatsu, Isao Baba, Takashi Mikami, Kiyotada Narukawa, Tsuyoshi Kanai
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Patent number: 4851500Abstract: A process and apparatus is provided for making a rubber-like product from rubber scrap, such as recycled tire scrap. The process includes mixing the rubber scrap with from 1 percent to 15 percent, with respect to the weight of the rubber scrap, of added sulphur, and applying a pressure thereto of about 1000 to 3000 pounds per square inch for 1 to 10 minutes at a temperature of from about 250 degrees F. to about 450 degrees F. In addition, 1 to 8 percent, with respect to the weight of the rubber scrap, of antioxidants and antiozonants are added to the mixture of rubber scrap and sulphur. The sulphur is free sulphur. Derivative sulphur compounds, or like vulcanizing agents, can be added in place of the free sulphur of about 1 to 45 percent of the weight of the rubber scrap. The rubber scrap is buffing of recycled tire rubber, or powder made from recycled tire rubber. An apparatus for carrying out the process is also provided.Type: GrantFiled: May 16, 1988Date of Patent: July 25, 1989Assignee: GAF CorporationInventors: Steven S. Lalwani, William G. Pursell, Sr., Charles J. Horner, Jr.
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Patent number: 4801650Abstract: A process for producing a 4-methylpentene-1 copolymer comprising copolymerizing 4-methylpentene-1 with other .alpha.-olefin in a hydrocarbon solvent in the presence of a Ziegler-Natta catalyst and a resin composition containing the 4-methylpentene-1 copolymer are disclosed. The copolymerization comprises a first stage in which (A) a homopolymer or random copolymer of 4-methylpentene-1 having an .alpha.-olefin content of not more than 3 mol % and an intrinsic viscosity of at least 2.5 dl/g is prepared and a second stage in which (B) a random copolymer having an .alpha.-olefin content higher than that of the polymer (A) and no higher than 9 mol % and an intrinsic viscosity of at least 2.5 dl/g is prepared, and the produced copolymer insoluble in the solvent is separated to recover a 4-methylpentene-1 copolymer containing from 5 to 80% by weight of the polymer (A). The process produces a solvent-insoluble copolymer in an increased yield without impairing transparency of the copolymer.Type: GrantFiled: September 4, 1987Date of Patent: January 31, 1989Assignee: Sumimoto Chemical Co., Ltd.Inventors: Kizuku Wakatsuki, Kazuki Wakamatsu
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Patent number: 4778833Abstract: Composition for the preservation of wood containing a wood preservative, such as a boron compound or a fluorine compound, in a polymer or polymer composition, which upon contact with water releases the wood preservative. Said composition is introduced into a hole in the wood or in a wood construction, whereafter the hole is sealed.Type: GrantFiled: December 11, 1986Date of Patent: October 18, 1988Assignee: Nederlandse Centrale Organisatie voor Toegepast- Natuurweten- Schappelijk OnderzoekInventors: Jan W. P. T. Van der Drift, Jan La Brijn
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Patent number: 4725505Abstract: A polymer blend with good hot tack and a low and broad heat seal initiation temperature range for vertical and horizontal form and fill film packaging which contains a copolymer of butene-1 and propylene and a copolymer of propylene and ethylene.Type: GrantFiled: September 12, 1986Date of Patent: February 16, 1988Assignee: Shell Oil CompanyInventors: Charles C. Hwo, Masaki Kohyama
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Patent number: 4692295Abstract: Thermoplastic resin compositions comprising a thermoplastic resin capable of biaxial orientation and an additive resin, having a molecular weight above 10.sup.6, compatible with said thermoplastic resin and selected from a homopolymer of a vinyl monomer or a copolymer of at least two vinyl monomers.Type: GrantFiled: September 9, 1985Date of Patent: September 8, 1987Assignee: Produits Chimiques Ugine KuhlmannInventor: Bernard Vinatier
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Patent number: 4668738Abstract: A process, and the well-dispersed product thereof, for recovering solids from a latex of a grafted rubber concentrate having a rubber substrate and a glassy superstrate by: (a) adding a latex of said superstrate to said grafted rubber concentrate latex; (b) coagulating said latex with high shear to form a paste; (c) heating said paste to cause syneresis of said paste into polymeric particles; and (d) dewatering said particles.Type: GrantFiled: December 24, 1985Date of Patent: May 26, 1987Assignee: The Dow Chemical CompanyInventors: John W. Lee, Eugene R. Moore
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Patent number: 4650830Abstract: Disclosed is a thermoplastic elastomer composition excellent in the injection fusion bondability and the surface gloss, which comprises (1) an amorphous ethylene/.alpha.-olefin copolymer (a) and (2) (i) a lowly crystalline copolymer (b) of propylene with an .alpha.-olefin having at least 4 carbon atoms, (ii) a polymer (d) composed mainly of 1-butene or (iii) a combination of the copolymer (b) or the polymer (d) with a crystalline polymer (c) composed mainly of propylene, wherein the component (1) is present in an amount of 10 to 95% by weight based on the total amount of the components (1) and (2), the component (2) is present in an amount of 5 to 90% by weight based on the total amount of the components (1) and (2), and the component (1) or the components (1) and (2) are partially crosslinked.The partial crosslinking is effected by grafting of a radical-polymerizable monomer having at least two polymerizable groups.Type: GrantFiled: May 30, 1984Date of Patent: March 17, 1987Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Katsuyoshi Yonekura, Akira Uchiyama, Akira Matsuda
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Patent number: 4615848Abstract: A pyroelectric and isotropic piezoelectric polymeric film, the film being formed from a blend of polyvinylidene fluoride and at least one polymer miscible therewith at a temperature above the melting point of the polyvinylidene fluoride, and a process for preparing the film comprising forming the film, heating it to a temperature sufficient to render the film substantially amorphous, cooling at a rate and to a temperature sufficient to prevent crystallization, and polarizing the film to render same pyroelectric and isotropically piezoelectric.Type: GrantFiled: February 15, 1985Date of Patent: October 7, 1986Assignee: Minnesota Mining and Manufacturing CompanyInventors: Dennis L. Krueger, Neil W. Loeding, Claudia I. Poser