Solid Polymer Derived From Reactant Containing A Fused- Or Bridged- Ring System Patents (Class 525/210)
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Patent number: 11987692Abstract: Provided is a thermoplastic resin composition or an adhesive coating material capable of adhering a cyclic polyolefin-based polymer with a metal or metal compound such as aluminum foil or an ethylene-vinyl alcohol copolymer with sufficient strength. The thermoplastic resin composition contains (A) 100 parts by mass of thermoplastic resin; (B) 0.05 to 5 parts by mass of one or more kinds selected from the group consisting of an unsaturated carboxylic acid and an unsaturated carboxylic acid derivative; and (C) 0.01 to 3 parts by mass of organic peroxide; which component (A) contains (a1) 10 to 90% by mass cyclic polyolefin-based polymer; and (a2) 90 to 10% by mass a hydrogenated product of a block copolymer comprising a polymer block composed mainly of an aromatic vinyl compound and a random copolymer block of a conjugated diene compound and an aromatic vinyl compound (with the proviso that the total of the component (a1) and the component (a2) is 100% by mass).Type: GrantFiled: February 29, 2016Date of Patent: May 21, 2024Assignee: RIKEN TECHNOS CORPORATIONInventors: Ryota Nakanishi, Kosuke Sugiya
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Patent number: 11193030Abstract: Cyclic olefin copolymer (COC) is useful as a build material for 3D printing, especially desktop 3D printing.Type: GrantFiled: June 22, 2017Date of Patent: December 7, 2021Assignees: Avient Corporation, Spyder3D LLCInventors: Joseph Bloomfield, Roger W. Avakian, Yannan Duan
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Patent number: 11169312Abstract: A pressure-sensitive-adhesive-layer-attached polarizing film is disclosed having an odd shape, and capable of reducing occurrence of a crack in a polarizer and preventing peeling and foaming of a pressure-sensitive adhesive layer and warpage of a polarizing film. This pressure-sensitive-adhesive-layer-attached polarizing film comprises a polarizing film, and a pressure-sensitive adhesive layer on one surface of the polarizing film. The pressure-sensitive-adhesive-layer-attached polarizing film has an odd shape other than a rectangular shape, and when a strain gauge is attached to a surface not having the pressure-sensitive adhesive layer of the polarizing film such that a measurement axis and an absorption axis of the polarizing film intersect at right angles and strain amounts are measured, a difference between a strain amount at ?40° C. and a strain amount at 85° C. is 3000?? or less, and the creep value of the pressure-sensitive adhesive layer at 85° C. is 15-600 ?m inclusive.Type: GrantFiled: March 25, 2019Date of Patent: November 9, 2021Assignee: NITTO DENKO CORPORATIONInventors: Tomoyuki Kimura, Yusuke Toyama, Eiko Suefusa
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Patent number: 10703138Abstract: The rubber composition for a tread comprises: 5 to 30 parts by mass of a carbon black, 95 parts by mass or more of silica, 25 parts by mass or more of a powder of an inorganic compound represented by a given formula (A) and having an average primary particle size of 10 ?m or less, and 70 parts by mass or more of a softening agent comprising 2 to 15 parts by mass of a coumarone-based resin, based on 100 parts by mass of a rubber component comprising 70% by mass or more of a styrene-butadiene rubber having a styrene content of from 20 to 50% by mass and a vinyl content of from 15 to 65%, and the tire has a tread composed of the rubber composition for a tread.Type: GrantFiled: February 14, 2018Date of Patent: July 7, 2020Assignee: SUMITOMO RUBBER INDUSTRIES, LTD.Inventors: Yumi Suzuki, Takeo Nakazono
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Patent number: 10240031Abstract: The present invention relates to surface modifying agents for polymeric and/or textile materials, methods of making and/or using a surface modifying agent to modify and functionalize polymeric and/or textile materials, and/or methods of using surface modified or functionalized polymeric and textile materials, and/or products using or incorporating surface modified or functionalized polymeric and textile materials. For example, the surface modifying agent in precursor form can be styrene sulfonyl azide monomer, polymer or copolymer capable of undergoing a chemical reaction in the presence of heat or light to form one or more styrene sulfonated nitrene monomers, polymers or copolymers, which are capable of chemically reacting with the surface of a polymeric or textile material to endow a specific or desired chemical surface functionality to the surface of a polymeric or textile material.Type: GrantFiled: January 17, 2014Date of Patent: March 26, 2019Assignee: Celgard, LLCInventor: Kristoffer K. Stokes
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Patent number: 9938362Abstract: An isoprene polymerization catalyst composition includes: Component (a): a rare earth element compound having a rare earth element-oxygen bond or a rare earth element-sulfur bond; Component (b): an ionic compound; and Component (c): at least one compound selected from the group consisting of a compound of formula (X): YR1aR2bR3c and a compound having a repeating unit of formula (Y): (—Y(R1)O—) (where Y is a metal selected from groups 1, 2, 12 and 13 in a periodic table, R1 and R2 are C1-10 hydrocarbon groups or hydrogen atoms and R3is a C1-10 hydrocarbon group).Type: GrantFiled: February 14, 2014Date of Patent: April 10, 2018Assignee: BRIDGESTONE CORPORATIONInventors: Shojiro Kaita, Satoru Tamaki
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Patent number: 9926469Abstract: Described herein is an adhesive composition comprising: (a) a (meth)acryloyl polymer; and (b) greater than 1 parts of a tackifier per 100 parts of the (meth)acryloyl polymer, wherein the tackifier comprises a substituted oligomeric quinoline.Type: GrantFiled: September 17, 2015Date of Patent: March 27, 2018Assignee: 3M Innovative Properties CompanyInventors: Kimberly C. M. Schultz, Nathan E. Schultz
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Patent number: 9243137Abstract: Propylene copolymer composition comprising a propylene copolymer (A) having a comonomer content in the range of equal or more than 0.5 to equal or below 2.0 wt.-%, the comonomers are C5 to C12 ?-olefins, and a propylene copolymer (B) having a comonomer content in the range of equal or more than 4.0 to equal or below 10.0 wt.-%, the comonomers are C5 to C12 ?-olefins, wherein further the propylene copolymer composition has a comonomer content in the range of equal or more than 3.5 to equal or below 7.0 wt.-%, the comonomers are C5 to C12 ?-olefins, and the weight ratio of the propylene copolymer (A) to the propylene copolymer (B) is in the range of 20/80 to below 55/45.Type: GrantFiled: February 7, 2012Date of Patent: January 26, 2016Assignee: Borealis AGInventors: Kristin Reichelt, Luigi Resconi, Juha Paavilainen
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Publication number: 20150125098Abstract: A resin composition for a sealant which has heat-sealing properties and non-absorbing properties to an inorganic component contained in the content, a laminated film, and a packaging bag, and a resin composition for a sealant including a cycloolefin polymer and a cycloolefin copolymer, wherein the resin composition includes 10 to 95% by weight of the cycloolefin polymer and 5 to 90% by weight of the cycloolefin copolymer.Type: ApplicationFiled: January 7, 2013Publication date: May 7, 2015Applicant: FUJIMORI KOGYO CO., LTD.Inventors: Hajime Okamoto, Kousuke Kashima, Masakazu Inada, Mihoko Yoshida
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Patent number: 8993111Abstract: The present invention provides surface treated articles comprising a recoatable surface treatment of an acrylic or vinyl polymer that does not change the appearance of the treated surface, and which imparts blocking resistance and/or stain and dirt pickup resistance to the treated surface. The one or more acrylic or vinyl polymer has a number average molecular weight of from 1,000 to 100,000, a glass transition temperature of ?10° C. or higher, preferably, 30° C. or higher, and comprises the polymerization product of one or more non-ionic monomer, such as methyl methacrylate, with up to 47 wt. % of an ethylenically unsaturated acid monomer and, preferably, is non-migrating under use conditions. When dry, the surface treatments may form a layer of domains of polymer distributed all over the treated surface, rather than a film. Treated articles include coating or painted articles and elastomer films.Type: GrantFiled: October 26, 2009Date of Patent: March 31, 2015Assignee: Rohm and Haas CompanyInventors: Bonnie E. Baker, Arnold S. Brownell, Nancy P. Buford, Willie Lau, Joseph J. Spanier
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Patent number: 8969467Abstract: The present invention relates to innovative materials which can be crosslinked by means of two different crosslinking mechanisms, the first crosslinking mechanism being an irreversible crosslinking. The second crosslinking mechanism is a thermoreversible mechanism. As a result of this thermoreversible change in the arc length, properties of the crosslinked material can be decisively changed and controlled, including flexibility, elasticity and other mechanical properties, but also chemical properties, the gas permeability and vapor permeability and storage capacity of the network. In this way it would be possible, for example, to store energy sources such as fuels.Type: GrantFiled: October 12, 2011Date of Patent: March 3, 2015Assignee: Evonik Roehm GmbHInventors: Stefan Hilf, Friedrich Georg Schmidt, Christopher Barner-Kowollik, Jiawen Zhou
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Patent number: 8969481Abstract: Thermoplastic elastomer compositions and methods for making same. The elastomer composition can include at least one partially cured rubber component that is an ethylene-alpha-olefin-vinyl norbornene elastomeric polymer, and at least one thermoplastic component. The rubber component is at least partially cured using a peroxide curative in an amount effective to yield a cure level of the rubber component of at least 85%. The rubber component has a molecular weight distribution (MWD) less than 6, and a branching index greater than 0.60.Type: GrantFiled: November 5, 2009Date of Patent: March 3, 2015Assignee: ExxonMobil Chemical Patent Inc.Inventors: Maria D. Ellul, Periagaram S. Ravishankar
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Publication number: 20150018788Abstract: Various polymeric barrier compositions are described which when formed into films, are useful in reducing transmission of odors. The films can be incorporated into a wide range of products such as multilayer barrier films used in medical applications and particularly in ostomy appliances. In certain versions, the films include blends of amorphous cyclic olefin copolymers and semi-crystalline cyclic olefin copolymers.Type: ApplicationFiled: December 13, 2012Publication date: January 15, 2015Inventors: Hoang T. Pham, Farid F. Ghiam, Thomas Laney
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Publication number: 20150004344Abstract: The present invention relates to a polar group-containing olefin copolymer (A?) which is produced through polymerization using a transition metal catalyst, which has a weight-average molecular weight falling within a specific range and which contains a polar group-containing monomer within a specific range; a multinary polar olefin copolymer (A?) indispensably containing a polar monomer component that has a norbornene skeleton and a carboxyl group or an acid anhydride group and having three or more types of monomer units; and a resin composition (C) containing a specific amount of a polar group-containing olefin copolymer (A) and a specific amount of an olefin resin (B).Type: ApplicationFiled: December 21, 2012Publication date: January 1, 2015Applicants: JAPAN POLYPROPYLENE CORPORATION, JAPAN POLYETHYLENE CORPORATIONInventors: Kazunari Abe, Minoru Kobayashi, Hideshi Uchino, Hiroyuki Shimizu, Tetsuya Morioka, Naoshi Iwama
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Publication number: 20140371379Abstract: The present invention relates to an adhesive, comprising at least one polymer system obtained by a process for reducing the melt viscosity of at least one polymer blend starting material, wherein the process comprises the step of treating at least one polymer blend with at least one radical donor under shear stress at a temperature above the softening point of said polymer blend.Type: ApplicationFiled: September 2, 2014Publication date: December 18, 2014Inventors: Dirk Kasper, Thomas Mueller, Gunter Hoffmann, Knut Hoffmann, Andy Swain, Claudia Yaacoub, Maria Cristina Barbosa DeJesus
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Publication number: 20140350187Abstract: Provided is a curable resin composition comprising a thermoplastic resin (A) that includes a cyclic structure in its main chain, and has a glass transition temperature (Tg) of 140° C. or more, and a monofunctional curable monomer (B). The present invention provides: a cured resin formed article that has heat resistance and low birefringence, a method for producing the same, a curable resin composition and a curable resin formed article that are useful as a raw material for producing the cured resin formed article, and a laminate that includes a layer formed of a cured resin.Type: ApplicationFiled: December 11, 2012Publication date: November 27, 2014Applicant: LINTEC CORPORATIONInventors: Masaharu Ito, Wataru Iwaya, Hironobu Fujimoto, Naoki Taya
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Patent number: 8883925Abstract: A cyclic olefin polymer composition comprising: [A] a specific cyclic olefin polymer having a softening temperature (TMA) of 120 to 300° C.; and [B] a specific cyclic olefin polymer having a glass transition temperature (Tg) of 50° C. or lower, wherein the absolute value of the difference between nD[A] and nD[B] is 0.014 or less in which nD[B] represents a refractive index of the cyclic olefin polymer [B] and nD[A] represent that of the cyclic olefin polymer [A], and the component [A] is contained in an amount of 50 to 95 parts by weight and the component [B] is contained in an amount of 5 to 50 parts by weight (provided that the total amount of the components [A] and [B] is defined as 100 parts by weight).Type: GrantFiled: December 3, 2007Date of Patent: November 11, 2014Assignee: Mitsui Chemicals, Inc.Inventors: Kouichi Kizu, Masako Takamatsu, Michio Tsugawa, Ryouichi Seki
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Publication number: 20140322528Abstract: A base film for a dicing sheet is provided which can suppress dicing debris from generating during the dicing of a cut object without imparting physical energy, such as electron beam or ? ray. The base film for a dicing sheet comprises a resin layer. The resin layer comprises: a ring-containing resin that is a thermoplastic resin having a monomer, as a constitutional unit, having at least one type of an aromatic ring and an aliphatic ring; and an acyclic olefin-based resin that is an olefin-based thermoplastic resin other than the ring-containing resin. The ring-containing resin in the resin layer has a content of more than 3.0 mass %. A dicing sheet is also provided which comprises: the base film for a dicing sheet; and a pressure-sensitive adhesive layer placed on the base film.Type: ApplicationFiled: September 5, 2012Publication date: October 30, 2014Applicant: LINTEC CORPORATIONInventors: Naoki Taya, Masashi Ueda, Yosuke Sato, Masaharu Ito
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Patent number: 8822603Abstract: The present disclosure provides a resinous material for covering electric wire having all required properties meeting or exceeding a certain standard, produced using a cyclic olefin-derived resin, and electric wires manufactured using the resinous material for covering electric wire, and flame-retardant cables. The resinous material including (A) an olefin-derived resin, (B) an elastomer resin, (C) a cyclic olefin-derived resin having a glass transition point of from 120° C. to 170° C., and (D) a flame retardant, the resinous material having: a content of the component (D) of from 60 parts by mass to 150 parts by mass relative to 100 parts by mass of the total contents of the components (A), (B) and (C); a tensile elongation of no less than 250%; and a heat deformation of no greater than 40%.Type: GrantFiled: February 16, 2009Date of Patent: September 2, 2014Assignee: Polyplastics Co., Ltd.Inventors: Hajime Serizawa, Masumi Tanikita
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Publication number: 20140205835Abstract: A base film for a dicing sheet is provided which can suppress dicing debris from generating during the dicing of a cut object without imparting physical energy, such as electron beam or ? ray. The base film for a dicing sheet comprises a resin layer. The resin layer comprises: a norbornene-based resin that is a thermoplastic resin having a norbornene-based compound as at least one type of monomer; and an olefin-based thermoplastic resin other than the norbornene-based resin. The norbornene-based resin in the resin layer has a content of more than 3.0 mass %. A dicing sheet is also provided which comprises: the base film for a dicing sheet; and a pressure-sensitive adhesive layer placed on a surface of the film at the resin layer side.Type: ApplicationFiled: September 5, 2012Publication date: July 24, 2014Applicant: LINTEC CORPORATIONInventors: Naoki Taya, Masashi Ueda, Yosuke Sato, Masaharu Ito
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Publication number: 20140194576Abstract: A rubber composition containing a rubber component having an olefinic double bond, and an isobutylene polymer having a structural unit represented by the following formula (1) and a structural unit represented by the following formula (2), wherein the content of a low molecular weight substance whose molecular weight is 1000 or less in the isobutylene polymer is 5% by mass or less based on the total amount of the isobutylene polymer. [wherein X represents a divalent group, Y represents a substituted or unsubstituted alicyclic group having an unsaturated bond, and n represents 0 or 1.Type: ApplicationFiled: June 29, 2012Publication date: July 10, 2014Applicant: JX NIPPON OIL & ENERGY CORPORATIONInventors: Zhengzhe Jin, Tsutomu Takashima, Tsuyoshi Yamaguchi, Tatsuya Chiba
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Patent number: 8722806Abstract: An object of the present invention is to provide a rubber composition for a tire, which is, when it is used as a rubber composition for a tire, capable of exhibiting good dry grip properties and excellent grip properties in both a relatively low temperature range and a relatively high temperature range, as well as a tire produced by using the rubber composition. The rubber composition of the present invention contains: a rubber component made of at least one type of diene-based polymer; and a copolymer resin obtained by copolymerizing ?-methylstyrene based monomer and aromatic vinyl monomer.Type: GrantFiled: February 16, 2009Date of Patent: May 13, 2014Assignee: Bridgestone CorporationInventors: Toshihiro Uchiyama, Seiichi Kato, Rika Fukushima
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Patent number: 8703283Abstract: The invention relates to selected polymer blends which can be used for production of films or sheets having reduced defects, and also to a process for preparation of the polymer blends.Type: GrantFiled: October 13, 2005Date of Patent: April 22, 2014Assignee: Topas Advanced Polymers GmbHInventors: Wolfram Goerlitz, Anne-Meike Schauwienold
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Patent number: 8691925Abstract: The present invention relates to novel neutral layer compositions and methods for using the compositions. The neutral layer composition comprises at least one random copolymer having at least one unit of structure (1), at least one unit of structure (2) and at least one unit of structure (3) where R1 is selected from the group consisting of a C1-C8 alkyl, C1-C8 fluoroalkyl moiety, C1-C8 partially fluorinated alkyl, C4-C8 cycloalkyl, C4-C8 cyclofluoroalkyl, C4-C8 partially fluorinated cycloalkyl, and a C2-C8 hydroxyalkyl; R2, R3 and R5 are independently selected from a group consisting of H, C1-C4 alkyl, CF3 and F; R4 is selected from the group consisting of H, C1-C8 alkyl, C1-C8 partially fluorinated alkyl and C1-C8 fluoroalkyl, n ranges from 1 to 5, R6 is selected from the group consisting of H, F, C1-C8 alkyl and a C1-C8 fluoroalkyl and m ranges from 1 to 3.Type: GrantFiled: September 23, 2011Date of Patent: April 8, 2014Assignee: AZ Electronic Materials (Luxembourg) S.A.R.L.Inventors: Hengpeng Wu, Yi Cao, SungEun Hong, Jian Yin, Margareta Paunescu, Mark O. Neisser, Guanyang Lin
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Patent number: 8669328Abstract: The invention describes a composition comprising, in the form of aqueous dispersion, A) for every 100 parts by weight of a, or of a plurality of, (meth)acrylate polymer(s); B) from 1-400 parts by weight of a, or of a plurality of, (meth)acrylate polymer(s), which contain(s) a compound of the formula (I) copolymerized, where the (meth)acrylate polymer(s) B) differ from the (meth)acrylate polymers specified in A), where these are obtainable by emulsion polymerization of a mixture comprising a) from 0.1 to 99.9 percent by weight of at least one compound of the formula (I), preferably of a benzophenone (meth)acrylate, in which the definitions of the moieties are those given in the description; and b) from 99.9 to 0.Type: GrantFiled: March 2, 2010Date of Patent: March 11, 2014Assignee: Evonik Roehm GmbHInventors: Christine Maria Breiner, Mario Gomez Andreu, Gerold Schmitt, Wolfgang Klesse
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Patent number: 8609763Abstract: A resin composition for vibration damping material for a vibration damping material exhibiting high vibration damping performance in a wider temperature range and a vibration damping material using the same are provided. The resin composition contains 100 parts by weight of a resin component A as a matrix and 5 to 300 parts by weight of a resin component B dispersed in the matrix. The resin component B has two or more cyclic structures selected from the group consisting of an aromatic hydrocarbon group, an aliphatic cyclic hydrocarbon group, and a heteroaromatic group, and is in a glassy state at use temperature.Type: GrantFiled: August 29, 2007Date of Patent: December 17, 2013Assignee: Koatsu Gas Kogyo Co., Ltd.Inventors: Toshio Sugimae, Kiyohiro Inoue, Yasushi Taguchi
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Publication number: 20130303678Abstract: The present invention relates to innovative materials which can be crosslinked by means of two different crosslinking mechanisms, the first crosslinking mechanism being an irreversible crosslinking. The second crosslinking mechanism is a thermoreversible mechanism. As a result of this thermoreversible change in the arc length, properties of the crosslinked material can be decisively changed and controlled, including flexibility, elasticity and other mechanical properties, but also chemical properties, the gas permeability and vapour permeability and storage capacity of the network. In this way it would be possible, for example, to store energy sources such as fuels.Type: ApplicationFiled: October 12, 2011Publication date: November 14, 2013Applicant: Evonik Roehm GmbHInventors: Stefan Hilf, Friedrich Georg Schmidt, Christopher Barner-Kowollik, Jiawen Zhou
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Publication number: 20130274419Abstract: An acrylic pressure-sensitive adhesive composition contains: an acrylic polymer (A); and a (meth)acrylic polymer (B) that includes, as a monomer unit, a (meth)acrylic monomer having a tricyclic or higher alicyclic structure and that has a weight average molecular weight of 1000 or more and less than 30000.Type: ApplicationFiled: June 6, 2013Publication date: October 17, 2013Inventors: Masayuki OKAMOTO, Masahito NIWA, Jun AKIYAMA, Kiyoe SHIGETOMI
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Patent number: 8552113Abstract: A rubber material of a wiper blade for windshield wipers is described, which comprises a first rubber component of a first polarity and a second rubber component of a second greater polarity. To equalize the first and second polarities, the first rubber component is at least partially replaced by a chemically functionalized derivative.Type: GrantFiled: September 29, 2008Date of Patent: October 8, 2013Assignee: Robert Bosch GmbHInventors: Eric Pieters, Reiner Lay, Hilde Parton
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Publication number: 20130258622Abstract: The disclosure provides a cross-linkable polymer composition, a core layer for an information carrying card comprising such cross-linked composition, resulting information carrying card, and methods of making the same. A crosslinkable polymer composition comprises a curable base polymer resin in a liquid or paste form, and a particulate thermoplastic filler. The base polymer resin is selected from the group consisting of urethane acrylate, silicone acrylate, epoxy acrylate, urethane, acrylate, silicone and epoxy. The particulate thermoplastic filler may be polyolefin, polyvinyl chloride (PVC), a copolymer of vinyl chloride and at least another monomer, or a polyester such as polyethylene terephthalate (PET), a compound or blend thereof.Type: ApplicationFiled: October 9, 2012Publication date: October 3, 2013Applicant: X-CARD HOLDINGS, LLCInventor: Mark A. Cox
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Patent number: 8519056Abstract: Disclosed is the preparation of compositions which are blends of certain types of hydrogenated ethylene-dicyclopentadiene (E/DCPD) copolymers in combination with elastomeric polymers. An E/DCPD copolymer and an elastomeric polymer are co-dissolved in a common liquid reaction medium which is then subjected to hydrogenation conditions. These hydrogenation conditions serve to hydrogenate in-situ at least a portion of the residual double bonds of the E/DCPD copolymer component and possibly also eliminate any residual unsaturation which might be present in the elastomeric polymers. This combination of materials which has been hydrogenated in-situ can then be co-precipitated to form a polymer composition which can be molded into polyolefin materials of improved structural, thermal and mechanical properties with desirable impact resistance.Type: GrantFiled: June 1, 2007Date of Patent: August 27, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Lisa Saunders Baugh, Enock Berluche
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Patent number: 8519057Abstract: Disclosed is the preparation of compositions which are mixtures of certain types of epoxidized rigid copolymers of ?-olefins and diene-derived co-monomers in combination with elastomeric diene-based polymers or copolymers. These two types of rigid and elastomeric polymeric materials are placed in a common liquid reaction medium and contacted therein with an oxidizing agent. The oxidizing agent, which can be a peroxide or peracid, epoxidizes in-situ at least a portion of the residual double bonds of the rigid copolymer and preferably also introduces hydroxyl groups, e.g., diol moieties, (or derivatives thereof such as ester groups) onto the unsaturated moieties of the elastomeric diene-based polymers or copolymers. This combination of materials which has been oxidized in-situ can then be co-precipitated to form a polymeric mixture which can be melt-molded into polyolefin materials of improved structural, thermal and mechanical properties with desirable impact resistance.Type: GrantFiled: June 1, 2007Date of Patent: August 27, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Abhimanyu Onkar Patil, Stephen Zushma
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Patent number: 8487046Abstract: The present invention relates to a polycycloolefin (PCO) thermoset network assembly and a process for its preparation obtainable by polymerising a first reactive composition comprising a norbornene-type cycloolefin monomer in the presence of a Mo- or W-catalyst to obtain a PCO-Mo/W-network and polymerising a second reactive composition comprising a nor-bornene-type cycloolefin monomer in the presence of a Ru-catalyst on said PCO-Mo/W-network to obtain a PCO thermoset network assembly.Type: GrantFiled: September 26, 2008Date of Patent: July 16, 2013Assignee: RIMTEC CorporationInventors: Gilles Recher, Nicolas Lessart, Naoki Nishioka
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Patent number: 8426529Abstract: Disclosed is a selected type of copolymer composition comprising copolymers having units derived from ethylene and dicyclopentadiene (DCPD) co-monomers. Such copolymer compositions: a) have a DCPD-derived comonomer unit content of from about 25 mole % to about 45 mole %; b) have a Weight Average Molecular Weight, Mw, of greater than about 170,000; c) comprise amorphous material and have glass transition temperatures, Tg, of from about 8° C. to about 129° C., which also fit the equation Tg (in ° C.)?[(mole % DCPD×3.142)?4.67]; and d) comprise no significant amount of crystalline polyethylene homopolymer or crystallizable polyethylene segments within the ethylene-dicyclopentadiene copolymers. Such copolymers can be readily derivatized by hydrogenation and/or epoxidation to provide polymeric materials suitable for use as engineering thermoplastics.Type: GrantFiled: May 10, 2007Date of Patent: April 23, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Lisa Saunders Baugh, Abhimanyu Onkar Patil, Christian Peter Mehnert, Kevin R. Squire, Kenneth A. Cook, Caiguo Gong, Enock Berluche, Karla Schall Colle, Alan J. Oshinski, Stephen Zushma, Beverly J. Poole
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Publication number: 20130078576Abstract: The present invention relates to novel neutral layer compositions and methods for using the compositions. The neutral layer composition comprises at least one random copolymer having at least one unit of structure (1), at least one unit of structure (2) and at least one unit of structure (3) where R1 is selected from the group consisting of a C1-C8 alkyl, C1-C8 fluoroalkyl moiety, C1-C8 partially fluorinated alkyl, C4-C8 cycloalkyl, C4-C8 cyclofluoroalkyl, C4-C8 partially fluorinated cycloalkyl, and a C2-C8 hydroxyalkyl; R2, R3 and R5 are independently selected from a group consisting of H, C1-C4 alkyl, CF3 and F; R4 is selected from the group consisting of H, C1-C8 alkyl, C1-C8 partially fluorinated alkyl and C1-C8 fluoroalkyl, n ranges from 1 to 5, R6 is selected from the group consisting of H, F, C1-C8 alkyl and a C1-C8 fluoroalkyl and m ranges from 1 to 3.Type: ApplicationFiled: September 23, 2011Publication date: March 28, 2013Applicant: AZ ELECTRONIC MATERIALS USA CORP.Inventors: Hengpeng WU, Yi CAO, SungEun HONG, Jian YIN, Margareta PAUNESCU, Mark O. NEISSER, Guanyang LIN
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Publication number: 20130071656Abstract: A peelable pressure-sensitive adhesive composition includes: 100 parts by mass of a polymer (A) having a glass transition temperature lower than 0° C.; and 0.05 parts by mass to 3 parts by mass of a (meth)acrylic polymer (B) that has a weight average molecular weight of 1000 or more and less than 30000 and that contains, as a monomer unit, a (meth)acrylic monomer having an alicyclic structure represented by the following general formula (1): CH2?C(R1)COOR2??(1) [wherein, R1 is a hydrogen atom or methyl group and R2 is an alicyclic hydrocarbon group having an alicyclic structure].Type: ApplicationFiled: September 14, 2012Publication date: March 21, 2013Applicant: NITTO DENKO CORPORATIONInventors: Masato YAMAGATA, Masayuki OKAMOTO, Kiyoe SHIGETOMI
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Publication number: 20130005911Abstract: An acrylic pressure-sensitive adhesive composition contains: an acrylic polymer (A); and a (meth)acrylic polymer (B) that includes, as a monomer unit, a (meth)acrylic monomer having a tricyclic or higher alicyclic structure and that has a weight average molecular weight of 1000 or more and less than 30000.Type: ApplicationFiled: September 12, 2012Publication date: January 3, 2013Applicant: NITTO DENKO CORPORATIONInventors: Masayuki OKAMOTO, Masahito NIWA, Jun AKIYAMA, Kiyoe SHIGETOMI
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Patent number: 8344070Abstract: A polymer composition comprises (a) least 40 wt % (based upon the weight of the composition) of a cyclic olefin polymer comprising at least one acyclic olefin and at least 20 wt % of one or more cyclic olefins (based upon the weight of the cyclic olefin polymer), wherein at least a portion of the cyclic olefin polymer has a glass transition temperature of greater than 100° C.; (b) an acyclic olefin polymer modifier in an amount up to 40 wt % (based upon the weight of the composition); and (c) at least 10 wt % (based upon the weight of the composition) of one of more fillers. The polymer composition has a notched Izod impact resistance measured at 23° C. of greater than 100 J/m and a flexural modulus (1% secant method) of greater than 1400 MPa.Type: GrantFiled: June 20, 2007Date of Patent: January 1, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Kevin R. Squire, Alan J. Oshinski, Kevin D. Robinson, Christian Peter Mehnert, Marsha M. Arvedson, Beverly J. Poole, Abhimanyu Onkar Patil, Lisa Saunders Baugh, Karla Schall Colle
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Patent number: 8292256Abstract: This invention describes molds made from alicyclic co-polymers that are useful in the production of contact lenses and methods for their use.Type: GrantFiled: September 22, 2010Date of Patent: October 23, 2012Assignee: Johnson & Johnson Vision Care, Inc.Inventors: Changhong Yin, Scott F. Ansell
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Patent number: 8277914Abstract: A polymer composition includes (1) a crystalline norbornene-based polymer and (2) an amorphous alicyclic structure-containing polymer in a weight ratio of 90:10 to 50:50, the crystalline norbornene-based polymer (1) having a melting point of 110 to 145° C., an Mw measured by gel permeation chromatography of 50,000 to 200,000, and a ratio Mw/Mn of 1.5 to 10.0, and obtained by ring-opening polymerization of a polymerizable monomer mixture (1) containing 90 to 100 wt % of 2-norbornene and 0 to 10 wt % of a substituent-containing norbornene monomer, and hydrogenating the resulting polymer, and the amorphous alicyclic structure-containing polymer (2) having a Tg of 50° C. or more and not having a melting point, and obtained by polymerization of a polymerizable monomer mixture (2) containing a 2-norbornene compound and a dicyclopentadiene compound in an amount of 50 wt % or more and less than 90 wt % in total. A film obtained by molding the polymer composition has a steam permeability of 0.Type: GrantFiled: September 30, 2009Date of Patent: October 2, 2012Assignee: Zeon CorporationInventors: Tokudai Ogawa, Hiroaki Matsuda
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Patent number: 8247494Abstract: A rubber composition comprising: a cured rubber; and thermoplastic resin, where the thermoplastic resin is in the form of discrete domains dispersed within a continuous phase of the cured rubber, and where the cured rubber includes silicon-containing crosslinks.Type: GrantFiled: November 8, 2010Date of Patent: August 21, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: Edward J. Blok, Maria D. Ellul, Sunny Jacob, Alfred V. Pickett
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Patent number: 8207269Abstract: A terpolymer containing: a) from 90% to 50% by weight; preferably from 90% to 70% by weight of ethylene derived units; b) from 5% to 40% by weight; preferably from 5% to 20% by weight of derived units of alpha olefin of formula CH2?CHA wherein A is a C1-C20 alkyl radical; c) from 2% to 30% by weight, preferably from 5% to 20% by weight of cycloolefins derived units. Said terpolymer being characterized by the following features i) distribution of molecular weight Mw/Mn lower than 3.5; preferably lower than 3; more preferably lower than 2.7 ii) solubility in xylene at 25° C. higher than 99%.Type: GrantFiled: November 26, 2008Date of Patent: June 26, 2012Assignee: Basell Polyolefine GmbHInventors: Fabiana Fantinel, Shahram Mihan
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Patent number: 8188191Abstract: The present invention is a polyolefin polymer containing vinyl groups at both ends thereof, and a composition and a molded product containing the polymer, wherein the polymer contains a constitutional unit derived from at least one selected from the group consisting of ethylene (a), an ?-olefin (b) having 3 to 20 carbon atoms, and a cyclic olefin (c), and (1) a ratio of terminal vinylation is 70% or more relative to all of both ends of molecular chains, and (2) an intrinsic viscosity [?] is in the range of 0.01 to 10 dl/g as measured in a decalin solution at 135° C. The polymer of the present invention may be molded by a LIM molding, an injection molding, a transfer molding, a compression molding, and the like, and is excellent in acid resistance, gas permeation resistance, hydrolysis resistance, and dynamic fatigue resistance. From the polymer, a thermoplastic resin composition and a crosslinkable resin composition, and a crosslinked composition having excellent mechanical characteristics are obtained.Type: GrantFiled: August 29, 2007Date of Patent: May 29, 2012Assignee: Mitsui Chemicals, Inc.Inventors: Shigenobu Ikenaga, Keiji Okada, Yoshiki Shimokawatoko, Akihiro Matsuda, Shigekazu Matsui, Masahiro Enna
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Patent number: 8147720Abstract: An aluminum chelate-based latent curing agent is provided which can cure a thermosetting epoxy resin at a relatively low temperature in a short period of time. A method for producing such an aluminum chelate-based latent curing agent, whose curing conditions can be relatively easily controlled, is also provided. The aluminum chelate-based latent curing agent is made latent by reacting a silsesquioxane-type oxetane derivative with an aluminum chelating agent in the presence of an alicyclic epoxy compound.Type: GrantFiled: December 27, 2007Date of Patent: April 3, 2012Assignees: Sony Corporation, Sony Chemical & Information Device CorporationInventors: Katsuhiko Komuro, Masahiko Ito, Daisuke Masuko
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Patent number: 8148484Abstract: Norbornene-based biocidal polymers having primary, secondary or tertiary amine or phosphine end groups, the parent monomers, processes for preparing the monomers and polymers, and their use.Type: GrantFiled: October 16, 2006Date of Patent: April 3, 2012Assignee: KE Kelit Kunststoffwerk GesmbHInventors: Xaver Norbert Gstrein, Wolfgang Kern, Karl Rametsteiner, Gerhard Seyfriedsberger, Franz Stelzer
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Patent number: 8148472Abstract: This invention relates to a polymer composition comprising a blend comprising: (a) greater than 30 wt (based upon the weight of the composition) of a cyclic olefin polymer having a Tg greater than 60° C.Type: GrantFiled: February 1, 2008Date of Patent: April 3, 2012Assignee: ExxonMobil Research and Engineering CompanyInventors: Lisa Saunders Baugh, Bryan R. Chapman, Enock Berluche
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Patent number: 8123971Abstract: The invention relates to composites made of an elastic carrier medium comprising polynorbornene (PNR) and magnetisable particles which are polarized reversibly in a magnetic field. Thus the mechanical properties, such as e.g. storage modulus G? (describes the elastic behavior or the energy storage) and loss modulus G? (describes the viscous behavior or the energy dissipation), of such elastomer composites can be increased rapidly and reversibly within wide limits (up to approx. two orders of magnitude) as a function of an external magnetic field. Wide-ranging application possibilities are produced herefrom, e.g. for adaptive damping systems, in which the damping force can be adjusted via the strength of the magnetic field.Type: GrantFiled: April 10, 2007Date of Patent: February 28, 2012Assignee: Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V.Inventors: Holger Böse, Rene' Röder, Nikolaus Rennar
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Patent number: 8110633Abstract: A seal for a valve for use in a pharmaceutical dispensing device, which seal is formed from a blend comprising: a thermoplastic elastomer including a propylene component with isotactic crystallinity; and a polymer selected from one or more of polypropylene, polyethylene and copolymers thereof.Type: GrantFiled: September 4, 2007Date of Patent: February 7, 2012Assignee: Consort Medical PLCInventor: Daljit Ohbi
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Patent number: 8088865Abstract: Provided is a method for producing a resin composition by melt-kneading a cyclic olefin polymer (A) having a glass transition temperature of from 60 to 200° C. and a flexible polymer (B) having a glass transition temperature of 0° C. or lower, wherein a part of the cyclic olefin polymer (A) is previously melt-kneaded with the flexible polymer (B) and a radical initiator (C) and then the remaining cyclic olefin polymer (A) is added thereto and melt-kneaded. The cyclic olefin polymer (A) is divided into two portions and added separately at two times, and accordingly, the mixture having a crosslinked structure may be diluted with the cyclic olefin polymer (A) not having a crosslinked structure, and the increase in the melt viscosity of the resin composition may be thereby prevented. A composition having good abrasion resistance and good melt shapability can be obtained.Type: GrantFiled: August 29, 2005Date of Patent: January 3, 2012Assignee: Mitsui Chemicals, Inc.Inventors: Kazuyoshi Kaneko, Toshiyuki Hirose
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Publication number: 20110275764Abstract: Thermoplastic elastomer compositions and methods for making same. The elastomer composition can include at least one partially cured rubber component that is an ethylene-alpha-olefin-vinyl norbornene elastomeric polymer, and at least one thermoplastic component. The rubber component is at least partially cured using a peroxide curative in an amount effective to yield a cure level of the rubber component of at least 85%. The rubber component has a molecular weight distribution (MWD) less than 6, and a branching index greater than 0.60.Type: ApplicationFiled: November 5, 2009Publication date: November 10, 2011Inventors: Maria D. Ellul, Periagaram S. Ravishankar