Solid Polymer Derived From Reactant Containing A Fused- Or Bridged- Ring System Patents (Class 525/210)
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Patent number: 6300419Abstract: Disclosed are propylene polymer compositions comprising a high crystalline propylene polymer, a substantially linear ethylene polymer, linear ethylene polymer or combinations thereof, an optional filler and an optional additional polymer. Said propylene polymer compositions have improved processability with a good balance of stillness and toughness which demonstrates improved scratch resistance in injection molded articles.Type: GrantFiled: December 8, 1999Date of Patent: October 9, 2001Assignee: The Dow Chemical CompanyInventors: Kalyan Sehanobish, Harry Craig Silvis, Marie L. Hare, Wendy D. Hoenig, John Newton
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Stable topical composition comprising a solid elastomeric organopolysiloxane and spherical particles
Publication number: 20010026811Abstract: A stable topical composition, which can be used in the cosmetic or dermatological fields, comprising at least one liquid fatty phase in combination with a solid phase representing at least 10% of the total weight of the fatty phase and further comprising a partially or completely crosslinked elastomeric organopolysiloxane and spherical polymeric particles with a particle diameter of less than 10 &mgr;m.Type: ApplicationFiled: May 21, 2001Publication date: October 4, 2001Applicant: L'OREAL S.A.Inventors: Violaine Rouquet, Jean-Claude Contamin -
Patent number: 6297322Abstract: The present invention provides a medical device of a polymer composition. The composition has a first component obtained by copolymerizing a norbornene monomer and an ethylene monomer, the first component being in an amount from about 1-99% by weight of the composition; and a second component of an ethylene and &agr;-olefin copolymer, the &agr;-olefin having 6 carbons, the second component being in an amount from about 99% to about 1% by weight of the composition.Type: GrantFiled: September 9, 1999Date of Patent: October 2, 2001Assignee: Baxter International Inc.Inventors: Yuan-pang Samuel Ding, Chuan Qin, Lecon Woo, Michael T. K. Ling, Sherwin Shang, Tahua Yang
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Patent number: 6288210Abstract: High refractive index, melt processable polyphosphonates and methods for preparing the same are provided. These polymers are particularly useful for optical and ophthalmic parts, such as lenses. A method of preparing optical and ophthalmic lenses by injection molding the polymers of the present invention into the form of the optical or ophthalmic lenses is also provided.Type: GrantFiled: November 12, 1999Date of Patent: September 11, 2001Assignees: Virginia Tech. Intellectual Properties, Inc., Johnson & Johnson Vision Products, Inc.Inventors: Hosadurga K. Shobha, Venkat Sekharipuram, James E. McGrath, Atul Bhatnagar
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Patent number: 6281290Abstract: Masterbatches comprising high density polyethylene (HDPE) are used for the production of polyolefin articles, particularly films. Employing HDPE in a masterbatch alone or in combination with a hydrocarbon resin and/or a polyolefin ultimately results in extruded polyolefin articles of optimal stiffness and ductility. Employing a high density polyethylene in combination with a hydrocarbon resin and a polyolefin in a masterbatch causes the masterbatch to solidify more rapidly and be pelletized more efficiently.Type: GrantFiled: February 25, 2000Date of Patent: August 28, 2001Assignee: Eastman Chemical CompanyInventor: Daniel W. Klosiewicz
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Publication number: 20010008920Abstract: A phase difference plate is provided which can be formed by a single material at a low cost without a need for forming laminated layers, and which has excellent performance in a wide band. The phase difference plate is formed by using a norbornene based resin composition which includes a norbornene based resin; and a polymer whose birefringence value is negative, and whose wavelength dispersion of birefringence values satisfies |&Dgr;n(450)/&Dgr;n(550)|≧1.02, wherein &Dgr;n(450) and &Dgr;n(550) are birefringence values (&Dgr;n) at a wavelength of 450 nm and a wavelength of 550 nm, respectively. The polymer is preferably a polystyrene based polymer.Type: ApplicationFiled: January 10, 2001Publication date: July 19, 2001Inventor: Kohei Arakawa
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Patent number: 6255396Abstract: The present invention provides a polymer composition having a first component obtained by copolymerizing a norbornene monomer and an ethylene monomer, the first component being in an amount from about 1-99% by weight of the composition; and a second component of an ethylene and &agr;-olefin copolymer, the &agr;-olefin having 6 carbons, the second component being in an amount from about 99% to about 1% by weight of the composition.Type: GrantFiled: September 9, 1999Date of Patent: July 3, 2001Assignee: Baxter International Inc.Inventors: Yuan-pang Samuel Ding, Chuan Qin, Lecon Woo, Michael T. K. Ling, Sherwin Shang, Tahua Yang
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Patent number: 6255395Abstract: Masterbatch including at least about 65 wt % of resin having a R&B softening point as measured in accordance with ASTM 28-67. The masterbatch also includes a carrier polymer having a peak melting temperature, as measured by DSC, up to about 20° C. greater than the R&B softening point of the resin. A masterbatch pellet made by a method, including mixing a resin having a R&B softening point as measured in accordance with ASTM 28-67, and a carrier polymer having a peak melting temperature, as measured by DSC, up to about 20° C. greater than the R&B softening point of the resin, to form masterbatch composition including at least about 65 wt % of resin. The method of making the masterbatch pellet also includes pelletizing the masterbatch composition into masterbatch pellet. Methods of making a masterbatch, methods for making polymer product, and a polymer product.Type: GrantFiled: March 22, 1999Date of Patent: July 3, 2001Assignee: Hercules IncorporatedInventor: Daniel W. Klosiewicz
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Patent number: 6251998Abstract: In the preparation of thermoplastic elastomers by hydrosilylation crosslinking of the elastomeric component, the use of an elastomer containing a non-conjugated diene and having a Mooney viscosity within the MST range of 45 to 100 provides products with a high level of crosslinking and an improved combination of physical properties. This improvement is obtained even at low concentrations of hydrosilylation catalyst.Type: GrantFiled: October 29, 1999Date of Patent: June 26, 2001Assignees: Advanced Elastomer Systems, L.P., Exxon Chemical Patents, Inc.Inventors: Robert E. Medsker, Donald R. Hazelton, Gary W. Gilbertson, Sabet Abdou-Sabet, Kuo-Shein Shen, Ronald L. Hazelton, Periagaram S. Ravishankar
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Patent number: 6251997Abstract: A polypropylene resin composition, which is light weighing, has very high values for the stiffness and heat resistance and is superior in the scratch-proof property with better moldability upon molding and which can be injection-molded into formed articles without occurrence of cracking, comprising 5-25% by weight of a higher molecular weight polypropylene (A) having an intrinsic viscosity [&eegr;], determined in decalin at 135° C., in the range from 6 to 11 dl/g and 95-75% by weight of a lower molecular weight polypropylene (B) having an intrinsic viscosity [&eegr;], determined in decalin at 135° C., in the range from 0.6 to 1.6 dl/g, wherein the said resin composition has the following charactristic features <<1>> and <<2>>, namely, <<1>> an isotactic pentad fraction (mmmm-fraction), determined by 13C-NMR, of at least 96.Type: GrantFiled: February 3, 2000Date of Patent: June 26, 2001Assignee: Grand Polymer Co LtdInventors: Tadashi Imai, Mikio Hashimoto, Shigeru Harima
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Patent number: 6251996Abstract: Gel-type copolymer beads are described which are useful as ion exchange resins such as those used in the treatment of power plant condensate water. The subject copolymer beads possess an interpenetrating polymer network of at least two polymer components including: (i) a first polymer component derived from a first monomer mixture comprising a first monovinylidene monomer having a styrenic content less than about 50 molar percent and (ii) a second polymer component derived from a second monomer mixture comprising: a second monovinylidene monomer having a styrenic content greater than about 50 molar percent and a second crosslinking agent. The ratio of the molar percent crosslinking agent of the first polymer component to the second polymer component is less than about 0.7. Methods for making the subject beads and methods for their use as ion exchange resins for treating aqueous solutions are also provided.Type: GrantFiled: October 26, 1999Date of Patent: June 26, 2001Assignee: The Dow Chemical CompanyInventors: James R. Stahlbush, Kenneth L. Foster
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Patent number: 6252001Abstract: Compounds of ethynyl aromatic compounds form polymers which have high thermal stability. The monomers are useful for coating a wide variety of substances such as dielectric coatings where high thermal resistance is desirable including electronic components such as computer chips.Type: GrantFiled: January 13, 2000Date of Patent: June 26, 2001Assignee: The Dow Chemical CompanyInventors: David A. Babb, Dennis W. Smith, Jr., Steven J. Martin, James P. Godschalx
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Patent number: 6232398Abstract: A resin matrix with resistances to alkali and acid such as a fluorene-containing epoxy acrylate and/or a benzocyclobutene resin includes at least any one of insulative organic particles and insulative composite particles having an organic component and an inorganic component with the total amount of these particles being in the range of 5-50% by volume, wherein the insulative organic particles and the organic component of the insulative composite particles are allowed to be corroded by either alkali or acid, and wherein not less than 90% by volume of the insulative organic particles and insulative composite particles have a particle diameter in the range of 1-20 micrometers.Type: GrantFiled: December 5, 1997Date of Patent: May 15, 2001Assignee: NEC CorporationInventors: Yoshitsugu Funada, Koji Matsui
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Patent number: 6228944Abstract: Pneumatic tire characterized by improved dry traction and durability having a tread comprised of a diene-based elastomer containing olefinic unsaturation and 1-80 phr of a polymeric resinous material comprising: (1) from 5 to 70 weight % units derived from limonene; (2) from 5 to 70% units derived from dimethyl-dicyclopentadiene; (3) from 5 to 45 weight % units derived from indene; and (4) from 5 to 45 weight % units derived from vinyl toluene, wherein the sum of the weight percent units derived from limonene and dimethyl-dicyclopentadiene range from 40 to 75 weight percent units of the resin, and the sum of weight percent units derived from indene and vinyl toluene range from 25 to 60 weight percent units of the resin.Type: GrantFiled: June 24, 1999Date of Patent: May 8, 2001Assignee: The Goodyear Tire & Rubber CompanyInventors: Edward John Blok, Mark Leslie Kralevich, Jr., Lawson Gibson Wideman, Paul Harry Sandstrom
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Patent number: 6194501Abstract: Disclosed herein is an olefin copolymer shrink film comprising an &agr;-olefin/aromatic vinyl compound random copolymer. This &agr;-olefin/aromatic vinyl compound random copolymer comprises 99.9 to 58 mol % of structural units derived from ethylene, 0 to 30 mol % of structural units derived from an &agr;-olefin having 3 to 20 carbon atoms (provided that the total of the structural units derived from ethylene and the structural units derived from an &agr;-olefin having 3 to 20 carbon atoms ranges from 99.9 to 88 mol %), and 0.1 to 12 mol % of structural units derived from an aromatic vinyl compound. The &agr;-olefin/aromatic vinyl compound random copolymer has an intrinsic viscosity [&eegr;], as measured in decalin at 135° C., of 0.1 to 10 dl/g and has a melting point, as measured by a differential scanning calorimeter, of 60 to 125° C. The olefin copolymer shrink film is oriented in at least one direction.Type: GrantFiled: September 23, 1998Date of Patent: February 27, 2001Assignee: Mitsui Chemicals IncInventors: Keiji Okada, Kazuyuki Takimoto, Kenichi Morizono
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Patent number: 6140400Abstract: Redispersible tackifier powder compositions which are redispersible in water are provided and which are comprised of one or more tackifying substances and from 2 to 50% by weight of one or more water-soluble low molecular weight homo or copolymers of olefinically unsaturated mono or dicarboxylic acids or their anhydrides. The copolymers also contain other free-radically polymerizable monomers. Antiblocking agents can also be present. Adhesives containing the compositions are also provided.Type: GrantFiled: May 20, 1998Date of Patent: October 31, 2000Assignee: Wacker-Chemie GmbHInventors: Reiner Figge, Rudolf Weissgerber
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Patent number: 6121383Abstract: Thermoplastic vulcanizate blends are prepared from a semi-crystalline polymer and a rubbery copolymer derived from copolymerizing at least one alpha-olefin monomer and at least one cyclic olefin copolymer. The rubbery copolymer also includes repeat units from at least one polyene monomer. The polyene monomer provides residual unsaturation for crosslinking of said rubbery copolymer. Crosslinking the rubbery copolymer of the blend generally reduces tension set, compression set and oil swell in aliphatic solvents. The cyclic olefin monomer reduces oil swell in aliphatic oils.Type: GrantFiled: April 20, 1998Date of Patent: September 19, 2000Assignees: Advanced Elastomer Systems, L.P., Exxon Chemical Patents, Inc.Inventors: Sabet Abdou-Sabet, Bruce A. Harrington, Patrick Brant, Anthony J. Dias, Sudhin Datta
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Patent number: 6107430Abstract: Disclosed are hot melt adhesives comprising at least one first homogeneous linear etylene polymer having a particular density and melt viscosity at 350.degree.F. (177.degree.C.), and an optional wax and tackifier. In particular, disclosed is a hot melt adhesive characterized by: a) at least one homogeneous linear or substantially linear interpolymer of ethylene with at least ibe C.sub.2 --C.sub.20 .alpha.-olefin interpolymer having a density from 0.850 g/cm.sup.3 to 0.895 g/cm.sup.3 ; and b) optionally at least one tackifying resin; and c) optionally at least one wax wherein the hot melt adhesive has a viscosity of less than about 5000 cPs (50 grams/cm.second) at 150.degree.C. Preferred hot melt adhesives for use in adhering cardboard or paperboard are disclosed, as well as the resultant adhered products. Also disclosed is a dual reactor process for the preparation of the inventive hot melt adhesives.Type: GrantFiled: January 8, 1998Date of Patent: August 22, 2000Assignees: The Dow Chemical Company, H.B. Fuller Licensing & Financing Inc.Inventors: Robert A. Dubois, Cynthia L. Rickey, Steven W. Albrecht, Beth M. Eichler, Thomas F. Kauffman, Maynard Lawrence, Thomas H. Quinn
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Patent number: 6100334Abstract: A blend of a semicrystalline polyolefin, a rubbery polymer containing repeat units from norbornene, and a polymeric compatibilizer is disclosed. This composition has reduced oil swell as compared to thermoplastic vulcanizates from a semicrystalline polyolefin and hydrocarbon rubbers.Type: GrantFiled: January 5, 1999Date of Patent: August 8, 2000Assignee: Advanced Elastomer Systems, L.P.Inventor: Sabet Abdou-Sabet
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Patent number: 6090888Abstract: This invention discloses blends of cyclic olefin polymers and styrene-containing elastomers useful as molding compositions to mold articles therefrom. The articles so molded exhibit improved mechanical properties without any significant effect on optical properties, making them ideally suitable for applications such as optical discs, lenses and the like.Type: GrantFiled: June 6, 1996Date of Patent: July 18, 2000Assignee: Hoechst Celanese CorporationInventors: Garo Khanarian, Thomas J. Dolce
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Patent number: 6087446Abstract: Masterbatches comprising high density polyethylene (HDPE) are used for the production of polyolefin articles, particularly films. Employing HDPE in a masterbatch alone or in combination with a hydrocarbon resin and/or a polyolefin ultimately results in extruded polyolefin articles of optimal stiffness and ductility. Employing a high density polyethylene in combination with a hydrocarbon resin and a polyolefin in a masterbatch causes the masterbatch to solidify more rapidly and be pelletized more efficiently.Type: GrantFiled: March 20, 1996Date of Patent: July 11, 2000Assignee: Hercules IncorporatedInventor: Daniel W. Klosiewicz
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Patent number: 6068936Abstract: A polyolefin film which includes at least one layer containing polyolefin and cycloolefin polymer (COP), where the cycloolefin polymer is amorphous and has a mean molecular weight M.sub.w in the range from 200 to 100,000, and this mean molecular weight M.sub.w of the cycloolefin polymer is at most 50% of the mean molecular weight M.sub.w of the polyolefin, and the cycloolefin polymer is a homopolymer or a copolymer containing at most 20% by weight of comonomer.Type: GrantFiled: September 30, 1996Date of Patent: May 30, 2000Assignee: Ticona GmbHInventors: Herbert Peiffer, Gunter Schlogl, Thomas Dries, Frank Osan
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Patent number: 6033826Abstract: A polymer of polyhydroxystyrene derivative containing an acetal or ketal group which can easily be eliminated in the presence of an acid in the molecule and having a very narrow molecular weight distribution gives a resist material suitable for forming ultrafine patterns excellent in resolution, heat resistance, mask linearity, and other properties without causing problems of delay time and the like.Type: GrantFiled: December 19, 1996Date of Patent: March 7, 2000Assignee: Wako Pure Chemical Industries, Ltd.Inventors: Fumiyoshi Urano, Hirotoshi Fujie, Keiji Oono
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Patent number: 6015626Abstract: Described is a weather-resistant, plasticizer-free, deep-drawable film based on a semicrystalline ethylene/propylene/diene terpolymer and a homo- and/or copolymer of an alkene plus stabilizers and optional fillers, lubricants, pigments, and other ordinary additives. This film is characterized by the fact that the mixture of the semicrystalline ethylene/propylene/diene terpolymer and the homo- and/or copolymer of the alkene contains:70-30 wt % semicrystalline ethylene/propylene/diene terpolymer (A) with approximately 56-76 wt % ethylene, approximately 15-30 wt % propylene, and approximately 9-14 wt % third component,while the terpolymer (A) has a melt-flow index MFI (230/2, 16) of approximately 5-15.0 g/10 min,and 70-30 wt % homo- and/or copolymer (B) of ethylene and/or propylene,while the homo- and/or copolymer has a melt-flow index MFI (230/2, 16) greater than 2.5 g/10 min. This film is especially suited for the interior covering and fittings of motor vehicles.Type: GrantFiled: February 19, 1998Date of Patent: January 18, 2000Assignee: Benecke-Kaliko AGInventor: Walter Kopytko
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Patent number: 6008298Abstract: Polymer alloy comprising a) one or more cycloolefin copolymers and b) one or more types of core/shell particles having a diameter of 0.01 to 0.7 micrometer.Type: GrantFiled: January 22, 1998Date of Patent: December 28, 1999Assignees: Hoechst Aktiengesellschaft, Mitsui Petrochemical Ind., Ltd.Inventors: Wilfried Hatke, Frank Osan, Otto Herrmann-Schonherr
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Patent number: 5994438Abstract: A pulverulent adhesive composition which comprises (a) at least one polymer selected from the group consisting of vinyl ester polymers, (meth)acrylate polymers and styrene(meth)acrylate polymers, (b) at least one tackifying resin (tackifier) and, optionally, (c) one or more protective colloids, and, optionally, (d) one or more anticaking agents. The present composition is suitable for use in formulations used for the adhesive bonding of porous and/or semiporous substrates.Type: GrantFiled: April 3, 1997Date of Patent: November 30, 1999Assignee: Hoeschst AktiengesellschaftInventors: Ulrich Geissler, Helmut Hintz, Ulrike Vogt-Saggau
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Patent number: 5976759Abstract: A polymer composition comprising (i) a polymer (a) having a monomer unit containing a functional group A which becomes alkali-soluble by heating in the presence of an acid, (ii) a polymer (b) having a monomer unit containing a functional group B which also becomes alkali-soluble, but less easily than the functional group A, by heating in the presence of an acid, and if necessary in addition to (i) and (ii) or in place of (ii), (iii) a phenolic compound having a weight-average molecular weight of 300 to 15,000 gives together with an photoacid generator a resist material suitable for forming a pattern excellent in sensitivity, resolution, mask linearity and other properties.Type: GrantFiled: December 19, 1996Date of Patent: November 2, 1999Assignee: Wako Pure Chemical Industries, Ltd.Inventors: Fumiyoshi Urano, Hirotoshi Fujie, Keiji Oono
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Patent number: 5977271Abstract: The subject invention provides a thermoset elastomer comprising a crosslinked pseudorandom or substantially random interpolymer of: (a) from 15 to 70 weight percent of at least one .alpha.-olefin, (b) from 30 to 70 weight percent of at least one vinylidene aromatic compound, and (c) from 0 to 15 weight percent of at least one diene. The subject invention further provides a thermoplastic vulcanizate comprising the thermoset elastomers of the invention as provided in a thermoplastic polyolefin matrix. The subject invention further provides processes for preparing the inventive thermoset elastomers and thermoplastic vulcanizates, as well as parts fabricated therefrom. The inventive materials have a superior balance of properties, as compared to EPM and EPDM based materials. The subject invention also pertains to foams and methods for their preparation.Type: GrantFiled: August 27, 1997Date of Patent: November 2, 1999Assignee: The Dow Chemical CompanyInventors: Kevin W. McKay, Francis J. Timmers, Edwin R. Feig, Thoi H. Ho, Seema V. Karande
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Patent number: 5959010Abstract: Reduction of dust formation for particleized resin is achieved by adding low density high molecular weight polyethylene to molten resin at a temperature and under conditions sufficient to cause the polyethylene to become dispersed within the resin. The resin/polyethylene mixture is then formed into solid particles. The addition of low density, high molecular weight polyethylene significantly reduces the generation of dust during handling, such as in the particleizing and packaging stages of the manufacturing process, while providing resin particles with higher effective softening points as compared to resin particles augmented with polyethylene wax.Type: GrantFiled: April 30, 1997Date of Patent: September 28, 1999Assignee: Arizona Chemical CompanyInventor: Robert W. Schluenz
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Patent number: 5942569Abstract: A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid.Type: GrantFiled: August 31, 1998Date of Patent: August 24, 1999Assignee: H.B. Fuller Licensing & Financing, Inc.Inventors: Eugene R. Simmons, Kevin J. Sweeney, Jeffrey S. Lindquist, Christopher E. Olson, Freddie C. Carter, James R. Farmer
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Patent number: 5922811Abstract: An ethylene propylene rubber blend containing an ethylene-.alpha.-olefin-diene copolymer as the rubber component of the blend. The ethylene-.alpha.-olefin-diene copolymer has a propylene content of about 43% to about 51% by weight, an iodine value of about 33 to about 39, a Mooney viscosity (ML.sub.1+4 100.degree. C.) of about 34 to about 44, and a molecular weight distribution (M.sub.W /M.sub.N) of about 5 or less. The ethylene propylene rubber blend can be used, for example, for formulating articles such as hoses, and in particular brake hoses. At least an inner tube provided inside the hose is preferably formed of the ethylene propylene rubber blend. The ethylene propylene rubber blends have a modulus of elasticity not significantly dependent upon temperature and are excellent in compression set and processability.Type: GrantFiled: August 15, 1996Date of Patent: July 13, 1999Assignee: Toyoda Gosei Co., Ltd.Inventors: Atsushi Suzuki, Masayoshi Ichikawa, Kiyomitsu Terashima
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Patent number: 5874512Abstract: Resins which are the copolymers of an alpha-olefin, a cyclic olefin, and an aromatic-group-containing monomer are provided. The cyclic olefins retain their cyclic structures and the aromatic-group-containing monomers retain their aromatic structures after copolymerization into the resin product. Methods for production of the new resins in the presence of a metallocene catalyst system are also provided. New adhesive compositions containing the resin and articles using the new adhesive compositions are also part of the invention.Type: GrantFiled: September 18, 1997Date of Patent: February 23, 1999Inventors: James McCleod Farley, Martha Hetzel Robertson, Charles Lewis Sims
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Patent number: 5869591Abstract: The subject invention provides a thermoset elastomer comprising a crosslinked pseudorandom or substantially random interpolymer of: (a) from 15 to 70 weight percent of monomer units derived from at least one a-olefin, (b) from 30 to 70 weight percent of monomer units derived from at least one vinylidene aromatic compound, and (c) from 0 to 15 weight percent of monomer units derived from at least one diene. The subject invention further provides a thermoplastic vulcanizate comprising the thermoset elastomers of the invention as provided in a thermoplastic polyolefin matrix. The subject invention further provides processes for preparing the inventive thermoset elastomers and thermoplastic vulcanizates, as well as parts fabricated therefrom. The inventive materials have a superior balance of properties, as compared to EPM and EPDM based materials. The subject invention also pertains to foams and methods for their preparation.Type: GrantFiled: August 27, 1997Date of Patent: February 9, 1999Assignee: The Dow Chemical CompanyInventors: Kevin W. McKay, Francis J. Timmers, Edwin R. Feig, Thoi H. Ho, Seema V. Karande
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Patent number: 5869555Abstract: A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid.Type: GrantFiled: November 18, 1996Date of Patent: February 9, 1999Assignee: H. B. Fuller Licensing & Financing Inc.Inventors: Eugene R. Simmons, Kevin J. Sweeney, Jeffrey S. Lindquist, Christopher E. Olson, Freddie C. Carter, James R. Farmer
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Patent number: 5863986Abstract: Polymer alloy comprising a) one or more cycloolefin copolymers and b) one or more types of core-shell particles and c) one or more block copolymers.Type: GrantFiled: January 23, 1997Date of Patent: January 26, 1999Assignees: Ticona GmbH, Mitsui Petrochemical Industries, LtdInventors: Otto Herrmann-Schonherr, Frank Osan
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Patent number: 5770679Abstract: Polyamide resin compositions which are useful for molding parts with excellent malleability, thoughness, rigidity, and high heat deformation temperatures are prepared from 10 to 89% by weight of a polyamide resin, 1 to 30% by weight of at least one type of elastomer selected from among elastomers composed of ethylene/propylene/dienes, elastomers composed of ethylene/unsaturated carboxylic acid unsaturated carboxylic acid esters, and elastomers obtained by graft-modifying these elastomers, and from 10 to 60% by weight of a copolymer of ethylene and cyclic olefin that is noncrystalline and has a glass transition temperature of from 100.degree. to 190.degree. C.Type: GrantFiled: June 13, 1996Date of Patent: June 23, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Ryuichi Hayashi, Reiko Koshida
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Patent number: 5763532Abstract: Blends of semi-crystalline polymers with rubbery thermoplastic copolymers are provided. The rubbery thermoplastic copolymers are elastic at temperatures above their Tg's and properties similar to thermoplastic elastomers and surface tensions 5 dynes/cm or more different, preferably greater than the surface tension of the semi-crystalline polymer. Improved properties include good elastic recovery, toughness, and high elasticity without significant loss in optical properties.Type: GrantFiled: October 6, 1995Date of Patent: June 9, 1998Assignee: Exxon Chemical Patents, Inc.Inventors: Bruce Allan Harrington, Patrick Brant, Anthony Jay Dias
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Patent number: 5763516Abstract: Hot-melt adhesive compositions useful for packaging are disclosed. These hot-melt adhesive compositions are based on modified polyethylene and contain a linear, low density copolymer or terpolymer of ethylene and another alpha-olefin, a polyethylene graft copolymer, a tackifying resin, and a high-melting low viscosity wax. The hot-melt adhesive compositions disclosed herein produce very good adhesive bonds, even at high speed packaging conditions under a broad range of ambient packaging temperatures. These inventive adhesive compositions have a novel combination of good hot tack and good adhesive bond properties, even at extreme conditions.Type: GrantFiled: April 24, 1996Date of Patent: June 9, 1998Assignee: H.B. Fuller Licensing & Financing, Inc.Inventor: Darryl Aubrey Godfrey
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Patent number: 5756584Abstract: A pressure sensitive adhesive that includes:(a) the polymerization product of:(i) 25-98 parts by weight of an acrylic acid ester of a monohydric alcohol whose homopolymer has a T.sub.g less than 0.degree. C.;(ii) 2-75 parts by weight of a non-polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of no greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(iii) 0-5 parts by weight of a polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(b) at least one tackifier that is miscible in the polymerization product at room temperature.Type: GrantFiled: January 3, 1997Date of Patent: May 26, 1998Assignee: Minnesota Mining and Manufacturing CompanyInventors: Greggory S. Bennett, Christopher A. Haak, Craig A. Gustafson
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Patent number: 5723545Abstract: Blends of semi-crystalline polymers with rubbery thermoplastic copolymers are provided. The rubbery thermoplastic copolymers are elastic at temperatures above their Tg's and properties similar to thermoplastic elastomers and surface tensions 5 dynes/cm or more different, preferably greater than the surface tension of the semi-crystalline polymer. Improved properties include good elastic recovery, toughness, and high elasticity without significant loss in optical properties.Type: GrantFiled: November 4, 1996Date of Patent: March 3, 1998Assignee: Exxon Chemical Patents Inc.Inventors: Bruce Allan Harrington, Patrick Brant, Anthony Jay Dias
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Patent number: 5683798Abstract: A pressure sensitive adhesive that includes:(a) the polymerization product of:(i) 25-98 parts by weight of an acrylic acid ester of a monohydric alcohol whose homopolymer has a T.sub.g less than 0.degree. C.;(ii) 2-75 parts by weight of a non-polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of no greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(iii) 0-5 parts by weight of a polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(b) at least one tackifier that is miscible in the polymerization product at room temperature.Type: GrantFiled: April 25, 1996Date of Patent: November 4, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: Greggory S. Bennett, Christopher A. Haak, Craig A. Gustafson
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Patent number: 5654370Abstract: Ethylene, alpha-olefin, non-conjugated bicyclic diene elastomeric polymers and/or polymer blends when compounded and formed into a calendered sheet, show surprising improvements for the combination in both green strength and peel adhesion in the unvulcanized state. Such green strength and peel adhesion provide benefits during calendering operations and subsequent joining of calendered sheets, while the compounded elastomeric polymers are in their green or unvulcanized state.Type: GrantFiled: August 8, 1996Date of Patent: August 5, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Sudhin Datta, Periagaram S. Ravishankar, Lawrence George Kaufman
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Patent number: 5652308Abstract: Novel tackifier resins having a M.sub.n of 5,000 or less and a T.sub.g of 0.degree. C. or above are produced by combining a metallocene catalyst with an alpha-olefin and a cyclic monomer. New adhesives are produced by blending the novel tackifier with a base polymer.Type: GrantFiled: July 21, 1995Date of Patent: July 29, 1997Assignee: Exxon Chemical Patents Inc.Inventors: Natalie Ann Merrill, James McLeod Farley, Martha Hetzel Robertson, Charles Lewis Sims, Richard Byron Pannell, Angelo Anthony Montagna
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Patent number: 5648443Abstract: A process for effectively producing a cyclic olefin polymer and a cyclic olefin/alpha-olefin copolymer without opening the cyclic olefin, is disclosed. Further, a novel cyclic olefin/alpha-olefin copolymer prepared by the above-mentioned process, compositions and molded articles comprising the novel copolymer, are also disclosed. In the process for producing a cylcic olefin based polymer according to the present invention, homopolymerization of a cyclic olefin or copolymerization of a cyclic olefin and an alpha-olefin is effected in the presence of a catalyst comprising, as main ingredients, the following Compounds (A) and (B), and optionally Compound (C):(A) a transition metal compound;(B) a compound capable of forming an ionic complex when reacted with a transition metal compound; and(C) an organoaluminum compound.Type: GrantFiled: January 22, 1996Date of Patent: July 15, 1997Assignee: Idemitsu Kosan Co., Ltd.Inventors: Takuji Okamoto, Junichi Matsumoto, Masami Watanabe, Hiroshi Maezawa
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Patent number: 5629398Abstract: A process for effectively producing a cyclic olefin polymer and a cyclic olefin/alpha-olefin copolymer without opening the cyclic olefin, is disclosed. Further, a novel cyclic olefin/alpha-olefin copolymer prepared by the above-mentioned process, compositions and molded articles comprising the novel copolymer, are also disclosed. In the process for producing a cylcic olefin based polymer according to the present invention, homopolymerization of a cyclic olefin or copolymerization of a cyclic olefin and an alpha-olefin is effected in the presence of a catalyst comprising, as main ingredients, the following Compounds (A) and (B), and optionally Compound (C):(A) a transition metal compound;(B) a compound capable of forming an ionic complex when reacted with a transition metal compound; and(C) an organoaluminum compound.Type: GrantFiled: June 5, 1992Date of Patent: May 13, 1997Assignee: Idemitsu Kosan Co., Ltd.Inventors: Takuji Okamoto, Junichi Matsumoto, Masami Watanabe, Hiroshi Maezawa
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Patent number: 5574108Abstract: The present invention is directed to extrudable sealants which are particularly well suited for bonding a metal based, lidding material to a polystyrene container. The most preferred sealant compositions of the present invention preferably contain an acid copolymer, a tackifier and a polyolefin.Type: GrantFiled: April 18, 1995Date of Patent: November 12, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Vladimir Antonov, David D. Zhang, Stephen R. Tanny, Alister M. Soutar
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Patent number: 5571868Abstract: Ethylene, alpha-olefin, non-conjugated bicyclic diene elastomeric polymers and/or polymer blends when compounded and formed into a calendered sheet, show surprising improvements for the combination in both green strength and peel adhesion in the unvulcanized state. Such green strength and peel adhesion provide benefits during calendering operations and subsequent joining of calendered sheets, while the compounded elastomeric polymers are in their green or unvulcanized state.Type: GrantFiled: June 15, 1995Date of Patent: November 5, 1996Assignee: Exxon Chemical Patents Inc.Inventors: Sudhin Datta, Periagaram S. Ravishankar, Lawrence G. Kaufman
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Patent number: 5567776Abstract: Provided are cycloolefin copolymer compositions comprising a hydrocarbon elastomer component substantially free from a polymerizable double bond and a cycloolefin random copolymer component obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms and a cycloolefin in the presence of said hydrocarbon elastomer component, said composition containing said hydrocarbon elastomer component in an amount of 1-50% by weight, and a method for preparing said cycloolefin copolymer compositions.Also provided are cycloolefin copolymer compositions comprising a hydrocarbon elastomer component having a polymerizable double bond and a cycloolefin copolymer component obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms and a cycloolefin in the presence of said hydrocarbon elastomer component, said composition containing said hydrocarbon elastomer component in an amount of 1-50% by weight.Type: GrantFiled: May 8, 1995Date of Patent: October 22, 1996Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yoichiro Tsuji, Yoshiharu Abe, Toshihiro Sagane, Toshimasa Takata
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Patent number: 5567777Abstract: Provided are cycloolefin copolymer compositions comprising a hydrocarbon elastomer component substantially free from a polymerizable double bond and a cycloolefin random copolymer component obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms and a cycloolefin in the presence of said hydrocarbon elastomer component, said composition containing said hydrocarbon elastomer component in an amount of 1-50% by weight, and a method for preparing said cycloolefin copolymer compositions.Also provided are cycloolefin copolymer compositions comprising a hydrocarbon elastomer component having a polymerizable double bond and a cycloolefin copolymer component obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms and a cycloolefin in the presence of said hydrocarbon elastomer component, said composition containing said hydrocarbon elastomer component in an amount of 1-50% by weight.Type: GrantFiled: January 26, 1996Date of Patent: October 22, 1996Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Yoichiro Tsuji, Yoshiharu Abe, Toshihiro Sagane, Toshimasa Takata
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Patent number: 5552489Abstract: Tackifiers having Mn's of 5,000 or less and Tg's above 0.degree. C. are produced by combining a single site catalyst with an alpha-olefin and a cyclic monomer under conditions designed to produce low molecular weight.Type: GrantFiled: January 25, 1995Date of Patent: September 3, 1996Assignee: Exxon Chemical Patents Inc.Inventors: . Natalie A. Merrill, James M. Farley, Martha H. Robertson, Charles L. Sims, Richard B. Pannell, Angelo A. Montagna