Solid Polymer Derived From Reactant Containing A Fused- Or Bridged- Ring System Patents (Class 525/210)
  • Patent number: 6300419
    Abstract: Disclosed are propylene polymer compositions comprising a high crystalline propylene polymer, a substantially linear ethylene polymer, linear ethylene polymer or combinations thereof, an optional filler and an optional additional polymer. Said propylene polymer compositions have improved processability with a good balance of stillness and toughness which demonstrates improved scratch resistance in injection molded articles.
    Type: Grant
    Filed: December 8, 1999
    Date of Patent: October 9, 2001
    Assignee: The Dow Chemical Company
    Inventors: Kalyan Sehanobish, Harry Craig Silvis, Marie L. Hare, Wendy D. Hoenig, John Newton
  • Publication number: 20010026811
    Abstract: A stable topical composition, which can be used in the cosmetic or dermatological fields, comprising at least one liquid fatty phase in combination with a solid phase representing at least 10% of the total weight of the fatty phase and further comprising a partially or completely crosslinked elastomeric organopolysiloxane and spherical polymeric particles with a particle diameter of less than 10 &mgr;m.
    Type: Application
    Filed: May 21, 2001
    Publication date: October 4, 2001
    Applicant: L'OREAL S.A.
    Inventors: Violaine Rouquet, Jean-Claude Contamin
  • Patent number: 6297322
    Abstract: The present invention provides a medical device of a polymer composition. The composition has a first component obtained by copolymerizing a norbornene monomer and an ethylene monomer, the first component being in an amount from about 1-99% by weight of the composition; and a second component of an ethylene and &agr;-olefin copolymer, the &agr;-olefin having 6 carbons, the second component being in an amount from about 99% to about 1% by weight of the composition.
    Type: Grant
    Filed: September 9, 1999
    Date of Patent: October 2, 2001
    Assignee: Baxter International Inc.
    Inventors: Yuan-pang Samuel Ding, Chuan Qin, Lecon Woo, Michael T. K. Ling, Sherwin Shang, Tahua Yang
  • Patent number: 6288210
    Abstract: High refractive index, melt processable polyphosphonates and methods for preparing the same are provided. These polymers are particularly useful for optical and ophthalmic parts, such as lenses. A method of preparing optical and ophthalmic lenses by injection molding the polymers of the present invention into the form of the optical or ophthalmic lenses is also provided.
    Type: Grant
    Filed: November 12, 1999
    Date of Patent: September 11, 2001
    Assignees: Virginia Tech. Intellectual Properties, Inc., Johnson & Johnson Vision Products, Inc.
    Inventors: Hosadurga K. Shobha, Venkat Sekharipuram, James E. McGrath, Atul Bhatnagar
  • Patent number: 6281290
    Abstract: Masterbatches comprising high density polyethylene (HDPE) are used for the production of polyolefin articles, particularly films. Employing HDPE in a masterbatch alone or in combination with a hydrocarbon resin and/or a polyolefin ultimately results in extruded polyolefin articles of optimal stiffness and ductility. Employing a high density polyethylene in combination with a hydrocarbon resin and a polyolefin in a masterbatch causes the masterbatch to solidify more rapidly and be pelletized more efficiently.
    Type: Grant
    Filed: February 25, 2000
    Date of Patent: August 28, 2001
    Assignee: Eastman Chemical Company
    Inventor: Daniel W. Klosiewicz
  • Publication number: 20010008920
    Abstract: A phase difference plate is provided which can be formed by a single material at a low cost without a need for forming laminated layers, and which has excellent performance in a wide band. The phase difference plate is formed by using a norbornene based resin composition which includes a norbornene based resin; and a polymer whose birefringence value is negative, and whose wavelength dispersion of birefringence values satisfies |&Dgr;n(450)/&Dgr;n(550)|≧1.02, wherein &Dgr;n(450) and &Dgr;n(550) are birefringence values (&Dgr;n) at a wavelength of 450 nm and a wavelength of 550 nm, respectively. The polymer is preferably a polystyrene based polymer.
    Type: Application
    Filed: January 10, 2001
    Publication date: July 19, 2001
    Inventor: Kohei Arakawa
  • Patent number: 6255396
    Abstract: The present invention provides a polymer composition having a first component obtained by copolymerizing a norbornene monomer and an ethylene monomer, the first component being in an amount from about 1-99% by weight of the composition; and a second component of an ethylene and &agr;-olefin copolymer, the &agr;-olefin having 6 carbons, the second component being in an amount from about 99% to about 1% by weight of the composition.
    Type: Grant
    Filed: September 9, 1999
    Date of Patent: July 3, 2001
    Assignee: Baxter International Inc.
    Inventors: Yuan-pang Samuel Ding, Chuan Qin, Lecon Woo, Michael T. K. Ling, Sherwin Shang, Tahua Yang
  • Patent number: 6255395
    Abstract: Masterbatch including at least about 65 wt % of resin having a R&B softening point as measured in accordance with ASTM 28-67. The masterbatch also includes a carrier polymer having a peak melting temperature, as measured by DSC, up to about 20° C. greater than the R&B softening point of the resin. A masterbatch pellet made by a method, including mixing a resin having a R&B softening point as measured in accordance with ASTM 28-67, and a carrier polymer having a peak melting temperature, as measured by DSC, up to about 20° C. greater than the R&B softening point of the resin, to form masterbatch composition including at least about 65 wt % of resin. The method of making the masterbatch pellet also includes pelletizing the masterbatch composition into masterbatch pellet. Methods of making a masterbatch, methods for making polymer product, and a polymer product.
    Type: Grant
    Filed: March 22, 1999
    Date of Patent: July 3, 2001
    Assignee: Hercules Incorporated
    Inventor: Daniel W. Klosiewicz
  • Patent number: 6251998
    Abstract: In the preparation of thermoplastic elastomers by hydrosilylation crosslinking of the elastomeric component, the use of an elastomer containing a non-conjugated diene and having a Mooney viscosity within the MST range of 45 to 100 provides products with a high level of crosslinking and an improved combination of physical properties. This improvement is obtained even at low concentrations of hydrosilylation catalyst.
    Type: Grant
    Filed: October 29, 1999
    Date of Patent: June 26, 2001
    Assignees: Advanced Elastomer Systems, L.P., Exxon Chemical Patents, Inc.
    Inventors: Robert E. Medsker, Donald R. Hazelton, Gary W. Gilbertson, Sabet Abdou-Sabet, Kuo-Shein Shen, Ronald L. Hazelton, Periagaram S. Ravishankar
  • Patent number: 6251997
    Abstract: A polypropylene resin composition, which is light weighing, has very high values for the stiffness and heat resistance and is superior in the scratch-proof property with better moldability upon molding and which can be injection-molded into formed articles without occurrence of cracking, comprising 5-25% by weight of a higher molecular weight polypropylene (A) having an intrinsic viscosity [&eegr;], determined in decalin at 135° C., in the range from 6 to 11 dl/g and 95-75% by weight of a lower molecular weight polypropylene (B) having an intrinsic viscosity [&eegr;], determined in decalin at 135° C., in the range from 0.6 to 1.6 dl/g, wherein the said resin composition has the following charactristic features <<1>> and <<2>>, namely, <<1>> an isotactic pentad fraction (mmmm-fraction), determined by 13C-NMR, of at least 96.
    Type: Grant
    Filed: February 3, 2000
    Date of Patent: June 26, 2001
    Assignee: Grand Polymer Co Ltd
    Inventors: Tadashi Imai, Mikio Hashimoto, Shigeru Harima
  • Patent number: 6251996
    Abstract: Gel-type copolymer beads are described which are useful as ion exchange resins such as those used in the treatment of power plant condensate water. The subject copolymer beads possess an interpenetrating polymer network of at least two polymer components including: (i) a first polymer component derived from a first monomer mixture comprising a first monovinylidene monomer having a styrenic content less than about 50 molar percent and (ii) a second polymer component derived from a second monomer mixture comprising: a second monovinylidene monomer having a styrenic content greater than about 50 molar percent and a second crosslinking agent. The ratio of the molar percent crosslinking agent of the first polymer component to the second polymer component is less than about 0.7. Methods for making the subject beads and methods for their use as ion exchange resins for treating aqueous solutions are also provided.
    Type: Grant
    Filed: October 26, 1999
    Date of Patent: June 26, 2001
    Assignee: The Dow Chemical Company
    Inventors: James R. Stahlbush, Kenneth L. Foster
  • Patent number: 6252001
    Abstract: Compounds of ethynyl aromatic compounds form polymers which have high thermal stability. The monomers are useful for coating a wide variety of substances such as dielectric coatings where high thermal resistance is desirable including electronic components such as computer chips.
    Type: Grant
    Filed: January 13, 2000
    Date of Patent: June 26, 2001
    Assignee: The Dow Chemical Company
    Inventors: David A. Babb, Dennis W. Smith, Jr., Steven J. Martin, James P. Godschalx
  • Patent number: 6232398
    Abstract: A resin matrix with resistances to alkali and acid such as a fluorene-containing epoxy acrylate and/or a benzocyclobutene resin includes at least any one of insulative organic particles and insulative composite particles having an organic component and an inorganic component with the total amount of these particles being in the range of 5-50% by volume, wherein the insulative organic particles and the organic component of the insulative composite particles are allowed to be corroded by either alkali or acid, and wherein not less than 90% by volume of the insulative organic particles and insulative composite particles have a particle diameter in the range of 1-20 micrometers.
    Type: Grant
    Filed: December 5, 1997
    Date of Patent: May 15, 2001
    Assignee: NEC Corporation
    Inventors: Yoshitsugu Funada, Koji Matsui
  • Patent number: 6228944
    Abstract: Pneumatic tire characterized by improved dry traction and durability having a tread comprised of a diene-based elastomer containing olefinic unsaturation and 1-80 phr of a polymeric resinous material comprising: (1) from 5 to 70 weight % units derived from limonene; (2) from 5 to 70% units derived from dimethyl-dicyclopentadiene; (3) from 5 to 45 weight % units derived from indene; and (4) from 5 to 45 weight % units derived from vinyl toluene, wherein the sum of the weight percent units derived from limonene and dimethyl-dicyclopentadiene range from 40 to 75 weight percent units of the resin, and the sum of weight percent units derived from indene and vinyl toluene range from 25 to 60 weight percent units of the resin.
    Type: Grant
    Filed: June 24, 1999
    Date of Patent: May 8, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Edward John Blok, Mark Leslie Kralevich, Jr., Lawson Gibson Wideman, Paul Harry Sandstrom
  • Patent number: 6194501
    Abstract: Disclosed herein is an olefin copolymer shrink film comprising an &agr;-olefin/aromatic vinyl compound random copolymer. This &agr;-olefin/aromatic vinyl compound random copolymer comprises 99.9 to 58 mol % of structural units derived from ethylene, 0 to 30 mol % of structural units derived from an &agr;-olefin having 3 to 20 carbon atoms (provided that the total of the structural units derived from ethylene and the structural units derived from an &agr;-olefin having 3 to 20 carbon atoms ranges from 99.9 to 88 mol %), and 0.1 to 12 mol % of structural units derived from an aromatic vinyl compound. The &agr;-olefin/aromatic vinyl compound random copolymer has an intrinsic viscosity [&eegr;], as measured in decalin at 135° C., of 0.1 to 10 dl/g and has a melting point, as measured by a differential scanning calorimeter, of 60 to 125° C. The olefin copolymer shrink film is oriented in at least one direction.
    Type: Grant
    Filed: September 23, 1998
    Date of Patent: February 27, 2001
    Assignee: Mitsui Chemicals Inc
    Inventors: Keiji Okada, Kazuyuki Takimoto, Kenichi Morizono
  • Patent number: 6140400
    Abstract: Redispersible tackifier powder compositions which are redispersible in water are provided and which are comprised of one or more tackifying substances and from 2 to 50% by weight of one or more water-soluble low molecular weight homo or copolymers of olefinically unsaturated mono or dicarboxylic acids or their anhydrides. The copolymers also contain other free-radically polymerizable monomers. Antiblocking agents can also be present. Adhesives containing the compositions are also provided.
    Type: Grant
    Filed: May 20, 1998
    Date of Patent: October 31, 2000
    Assignee: Wacker-Chemie GmbH
    Inventors: Reiner Figge, Rudolf Weissgerber
  • Patent number: 6121383
    Abstract: Thermoplastic vulcanizate blends are prepared from a semi-crystalline polymer and a rubbery copolymer derived from copolymerizing at least one alpha-olefin monomer and at least one cyclic olefin copolymer. The rubbery copolymer also includes repeat units from at least one polyene monomer. The polyene monomer provides residual unsaturation for crosslinking of said rubbery copolymer. Crosslinking the rubbery copolymer of the blend generally reduces tension set, compression set and oil swell in aliphatic solvents. The cyclic olefin monomer reduces oil swell in aliphatic oils.
    Type: Grant
    Filed: April 20, 1998
    Date of Patent: September 19, 2000
    Assignees: Advanced Elastomer Systems, L.P., Exxon Chemical Patents, Inc.
    Inventors: Sabet Abdou-Sabet, Bruce A. Harrington, Patrick Brant, Anthony J. Dias, Sudhin Datta
  • Patent number: 6107430
    Abstract: Disclosed are hot melt adhesives comprising at least one first homogeneous linear etylene polymer having a particular density and melt viscosity at 350.degree.F. (177.degree.C.), and an optional wax and tackifier. In particular, disclosed is a hot melt adhesive characterized by: a) at least one homogeneous linear or substantially linear interpolymer of ethylene with at least ibe C.sub.2 --C.sub.20 .alpha.-olefin interpolymer having a density from 0.850 g/cm.sup.3 to 0.895 g/cm.sup.3 ; and b) optionally at least one tackifying resin; and c) optionally at least one wax wherein the hot melt adhesive has a viscosity of less than about 5000 cPs (50 grams/cm.second) at 150.degree.C. Preferred hot melt adhesives for use in adhering cardboard or paperboard are disclosed, as well as the resultant adhered products. Also disclosed is a dual reactor process for the preparation of the inventive hot melt adhesives.
    Type: Grant
    Filed: January 8, 1998
    Date of Patent: August 22, 2000
    Assignees: The Dow Chemical Company, H.B. Fuller Licensing & Financing Inc.
    Inventors: Robert A. Dubois, Cynthia L. Rickey, Steven W. Albrecht, Beth M. Eichler, Thomas F. Kauffman, Maynard Lawrence, Thomas H. Quinn
  • Patent number: 6100334
    Abstract: A blend of a semicrystalline polyolefin, a rubbery polymer containing repeat units from norbornene, and a polymeric compatibilizer is disclosed. This composition has reduced oil swell as compared to thermoplastic vulcanizates from a semicrystalline polyolefin and hydrocarbon rubbers.
    Type: Grant
    Filed: January 5, 1999
    Date of Patent: August 8, 2000
    Assignee: Advanced Elastomer Systems, L.P.
    Inventor: Sabet Abdou-Sabet
  • Patent number: 6090888
    Abstract: This invention discloses blends of cyclic olefin polymers and styrene-containing elastomers useful as molding compositions to mold articles therefrom. The articles so molded exhibit improved mechanical properties without any significant effect on optical properties, making them ideally suitable for applications such as optical discs, lenses and the like.
    Type: Grant
    Filed: June 6, 1996
    Date of Patent: July 18, 2000
    Assignee: Hoechst Celanese Corporation
    Inventors: Garo Khanarian, Thomas J. Dolce
  • Patent number: 6087446
    Abstract: Masterbatches comprising high density polyethylene (HDPE) are used for the production of polyolefin articles, particularly films. Employing HDPE in a masterbatch alone or in combination with a hydrocarbon resin and/or a polyolefin ultimately results in extruded polyolefin articles of optimal stiffness and ductility. Employing a high density polyethylene in combination with a hydrocarbon resin and a polyolefin in a masterbatch causes the masterbatch to solidify more rapidly and be pelletized more efficiently.
    Type: Grant
    Filed: March 20, 1996
    Date of Patent: July 11, 2000
    Assignee: Hercules Incorporated
    Inventor: Daniel W. Klosiewicz
  • Patent number: 6068936
    Abstract: A polyolefin film which includes at least one layer containing polyolefin and cycloolefin polymer (COP), where the cycloolefin polymer is amorphous and has a mean molecular weight M.sub.w in the range from 200 to 100,000, and this mean molecular weight M.sub.w of the cycloolefin polymer is at most 50% of the mean molecular weight M.sub.w of the polyolefin, and the cycloolefin polymer is a homopolymer or a copolymer containing at most 20% by weight of comonomer.
    Type: Grant
    Filed: September 30, 1996
    Date of Patent: May 30, 2000
    Assignee: Ticona GmbH
    Inventors: Herbert Peiffer, Gunter Schlogl, Thomas Dries, Frank Osan
  • Patent number: 6033826
    Abstract: A polymer of polyhydroxystyrene derivative containing an acetal or ketal group which can easily be eliminated in the presence of an acid in the molecule and having a very narrow molecular weight distribution gives a resist material suitable for forming ultrafine patterns excellent in resolution, heat resistance, mask linearity, and other properties without causing problems of delay time and the like.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: March 7, 2000
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Fumiyoshi Urano, Hirotoshi Fujie, Keiji Oono
  • Patent number: 6015626
    Abstract: Described is a weather-resistant, plasticizer-free, deep-drawable film based on a semicrystalline ethylene/propylene/diene terpolymer and a homo- and/or copolymer of an alkene plus stabilizers and optional fillers, lubricants, pigments, and other ordinary additives. This film is characterized by the fact that the mixture of the semicrystalline ethylene/propylene/diene terpolymer and the homo- and/or copolymer of the alkene contains:70-30 wt % semicrystalline ethylene/propylene/diene terpolymer (A) with approximately 56-76 wt % ethylene, approximately 15-30 wt % propylene, and approximately 9-14 wt % third component,while the terpolymer (A) has a melt-flow index MFI (230/2, 16) of approximately 5-15.0 g/10 min,and 70-30 wt % homo- and/or copolymer (B) of ethylene and/or propylene,while the homo- and/or copolymer has a melt-flow index MFI (230/2, 16) greater than 2.5 g/10 min. This film is especially suited for the interior covering and fittings of motor vehicles.
    Type: Grant
    Filed: February 19, 1998
    Date of Patent: January 18, 2000
    Assignee: Benecke-Kaliko AG
    Inventor: Walter Kopytko
  • Patent number: 6008298
    Abstract: Polymer alloy comprising a) one or more cycloolefin copolymers and b) one or more types of core/shell particles having a diameter of 0.01 to 0.7 micrometer.
    Type: Grant
    Filed: January 22, 1998
    Date of Patent: December 28, 1999
    Assignees: Hoechst Aktiengesellschaft, Mitsui Petrochemical Ind., Ltd.
    Inventors: Wilfried Hatke, Frank Osan, Otto Herrmann-Schonherr
  • Patent number: 5994438
    Abstract: A pulverulent adhesive composition which comprises (a) at least one polymer selected from the group consisting of vinyl ester polymers, (meth)acrylate polymers and styrene(meth)acrylate polymers, (b) at least one tackifying resin (tackifier) and, optionally, (c) one or more protective colloids, and, optionally, (d) one or more anticaking agents. The present composition is suitable for use in formulations used for the adhesive bonding of porous and/or semiporous substrates.
    Type: Grant
    Filed: April 3, 1997
    Date of Patent: November 30, 1999
    Assignee: Hoeschst Aktiengesellschaft
    Inventors: Ulrich Geissler, Helmut Hintz, Ulrike Vogt-Saggau
  • Patent number: 5976759
    Abstract: A polymer composition comprising (i) a polymer (a) having a monomer unit containing a functional group A which becomes alkali-soluble by heating in the presence of an acid, (ii) a polymer (b) having a monomer unit containing a functional group B which also becomes alkali-soluble, but less easily than the functional group A, by heating in the presence of an acid, and if necessary in addition to (i) and (ii) or in place of (ii), (iii) a phenolic compound having a weight-average molecular weight of 300 to 15,000 gives together with an photoacid generator a resist material suitable for forming a pattern excellent in sensitivity, resolution, mask linearity and other properties.
    Type: Grant
    Filed: December 19, 1996
    Date of Patent: November 2, 1999
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Fumiyoshi Urano, Hirotoshi Fujie, Keiji Oono
  • Patent number: 5977271
    Abstract: The subject invention provides a thermoset elastomer comprising a crosslinked pseudorandom or substantially random interpolymer of: (a) from 15 to 70 weight percent of at least one .alpha.-olefin, (b) from 30 to 70 weight percent of at least one vinylidene aromatic compound, and (c) from 0 to 15 weight percent of at least one diene. The subject invention further provides a thermoplastic vulcanizate comprising the thermoset elastomers of the invention as provided in a thermoplastic polyolefin matrix. The subject invention further provides processes for preparing the inventive thermoset elastomers and thermoplastic vulcanizates, as well as parts fabricated therefrom. The inventive materials have a superior balance of properties, as compared to EPM and EPDM based materials. The subject invention also pertains to foams and methods for their preparation.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: November 2, 1999
    Assignee: The Dow Chemical Company
    Inventors: Kevin W. McKay, Francis J. Timmers, Edwin R. Feig, Thoi H. Ho, Seema V. Karande
  • Patent number: 5959010
    Abstract: Reduction of dust formation for particleized resin is achieved by adding low density high molecular weight polyethylene to molten resin at a temperature and under conditions sufficient to cause the polyethylene to become dispersed within the resin. The resin/polyethylene mixture is then formed into solid particles. The addition of low density, high molecular weight polyethylene significantly reduces the generation of dust during handling, such as in the particleizing and packaging stages of the manufacturing process, while providing resin particles with higher effective softening points as compared to resin particles augmented with polyethylene wax.
    Type: Grant
    Filed: April 30, 1997
    Date of Patent: September 28, 1999
    Assignee: Arizona Chemical Company
    Inventor: Robert W. Schluenz
  • Patent number: 5942569
    Abstract: A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid.
    Type: Grant
    Filed: August 31, 1998
    Date of Patent: August 24, 1999
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventors: Eugene R. Simmons, Kevin J. Sweeney, Jeffrey S. Lindquist, Christopher E. Olson, Freddie C. Carter, James R. Farmer
  • Patent number: 5922811
    Abstract: An ethylene propylene rubber blend containing an ethylene-.alpha.-olefin-diene copolymer as the rubber component of the blend. The ethylene-.alpha.-olefin-diene copolymer has a propylene content of about 43% to about 51% by weight, an iodine value of about 33 to about 39, a Mooney viscosity (ML.sub.1+4 100.degree. C.) of about 34 to about 44, and a molecular weight distribution (M.sub.W /M.sub.N) of about 5 or less. The ethylene propylene rubber blend can be used, for example, for formulating articles such as hoses, and in particular brake hoses. At least an inner tube provided inside the hose is preferably formed of the ethylene propylene rubber blend. The ethylene propylene rubber blends have a modulus of elasticity not significantly dependent upon temperature and are excellent in compression set and processability.
    Type: Grant
    Filed: August 15, 1996
    Date of Patent: July 13, 1999
    Assignee: Toyoda Gosei Co., Ltd.
    Inventors: Atsushi Suzuki, Masayoshi Ichikawa, Kiyomitsu Terashima
  • Patent number: 5874512
    Abstract: Resins which are the copolymers of an alpha-olefin, a cyclic olefin, and an aromatic-group-containing monomer are provided. The cyclic olefins retain their cyclic structures and the aromatic-group-containing monomers retain their aromatic structures after copolymerization into the resin product. Methods for production of the new resins in the presence of a metallocene catalyst system are also provided. New adhesive compositions containing the resin and articles using the new adhesive compositions are also part of the invention.
    Type: Grant
    Filed: September 18, 1997
    Date of Patent: February 23, 1999
    Inventors: James McCleod Farley, Martha Hetzel Robertson, Charles Lewis Sims
  • Patent number: 5869591
    Abstract: The subject invention provides a thermoset elastomer comprising a crosslinked pseudorandom or substantially random interpolymer of: (a) from 15 to 70 weight percent of monomer units derived from at least one a-olefin, (b) from 30 to 70 weight percent of monomer units derived from at least one vinylidene aromatic compound, and (c) from 0 to 15 weight percent of monomer units derived from at least one diene. The subject invention further provides a thermoplastic vulcanizate comprising the thermoset elastomers of the invention as provided in a thermoplastic polyolefin matrix. The subject invention further provides processes for preparing the inventive thermoset elastomers and thermoplastic vulcanizates, as well as parts fabricated therefrom. The inventive materials have a superior balance of properties, as compared to EPM and EPDM based materials. The subject invention also pertains to foams and methods for their preparation.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: February 9, 1999
    Assignee: The Dow Chemical Company
    Inventors: Kevin W. McKay, Francis J. Timmers, Edwin R. Feig, Thoi H. Ho, Seema V. Karande
  • Patent number: 5869555
    Abstract: A polymeric composition in pellet form comprising a tacky hot melt composition, comprising a) from about 5% by weight to about 90% by weight of a thermoplastic polymer, b) from about 0% by weight to about 65% by weight of a tackifying resin, c) from about 0% to about 50% by weight of a plasticizer, d) up to about 2% by weight of an antioxidant, and a pelletizing aid, wherein the tacky hot melt composition has some minimum amount of tackifier or plasticizer and is a pressure sensitive adhesive having a storage modulus, G', at about 25.degree. C., of less than about 5.times.10.sup.6 dynes/cm.sup.2, and each pellet has a substantially tack-free surface.This invention further discloses a polymeric composition in pellet form suitable for molding articles. The composition comprises a tacky hot melt composition comprising at least one high molecular weight triblock copolymer of the general configuration A-B-A and a plasticizer and a pelletizing aid.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: February 9, 1999
    Assignee: H. B. Fuller Licensing & Financing Inc.
    Inventors: Eugene R. Simmons, Kevin J. Sweeney, Jeffrey S. Lindquist, Christopher E. Olson, Freddie C. Carter, James R. Farmer
  • Patent number: 5863986
    Abstract: Polymer alloy comprising a) one or more cycloolefin copolymers and b) one or more types of core-shell particles and c) one or more block copolymers.
    Type: Grant
    Filed: January 23, 1997
    Date of Patent: January 26, 1999
    Assignees: Ticona GmbH, Mitsui Petrochemical Industries, Ltd
    Inventors: Otto Herrmann-Schonherr, Frank Osan
  • Patent number: 5770679
    Abstract: Polyamide resin compositions which are useful for molding parts with excellent malleability, thoughness, rigidity, and high heat deformation temperatures are prepared from 10 to 89% by weight of a polyamide resin, 1 to 30% by weight of at least one type of elastomer selected from among elastomers composed of ethylene/propylene/dienes, elastomers composed of ethylene/unsaturated carboxylic acid unsaturated carboxylic acid esters, and elastomers obtained by graft-modifying these elastomers, and from 10 to 60% by weight of a copolymer of ethylene and cyclic olefin that is noncrystalline and has a glass transition temperature of from 100.degree. to 190.degree. C.
    Type: Grant
    Filed: June 13, 1996
    Date of Patent: June 23, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Ryuichi Hayashi, Reiko Koshida
  • Patent number: 5763532
    Abstract: Blends of semi-crystalline polymers with rubbery thermoplastic copolymers are provided. The rubbery thermoplastic copolymers are elastic at temperatures above their Tg's and properties similar to thermoplastic elastomers and surface tensions 5 dynes/cm or more different, preferably greater than the surface tension of the semi-crystalline polymer. Improved properties include good elastic recovery, toughness, and high elasticity without significant loss in optical properties.
    Type: Grant
    Filed: October 6, 1995
    Date of Patent: June 9, 1998
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Bruce Allan Harrington, Patrick Brant, Anthony Jay Dias
  • Patent number: 5763516
    Abstract: Hot-melt adhesive compositions useful for packaging are disclosed. These hot-melt adhesive compositions are based on modified polyethylene and contain a linear, low density copolymer or terpolymer of ethylene and another alpha-olefin, a polyethylene graft copolymer, a tackifying resin, and a high-melting low viscosity wax. The hot-melt adhesive compositions disclosed herein produce very good adhesive bonds, even at high speed packaging conditions under a broad range of ambient packaging temperatures. These inventive adhesive compositions have a novel combination of good hot tack and good adhesive bond properties, even at extreme conditions.
    Type: Grant
    Filed: April 24, 1996
    Date of Patent: June 9, 1998
    Assignee: H.B. Fuller Licensing & Financing, Inc.
    Inventor: Darryl Aubrey Godfrey
  • Patent number: 5756584
    Abstract: A pressure sensitive adhesive that includes:(a) the polymerization product of:(i) 25-98 parts by weight of an acrylic acid ester of a monohydric alcohol whose homopolymer has a T.sub.g less than 0.degree. C.;(ii) 2-75 parts by weight of a non-polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of no greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(iii) 0-5 parts by weight of a polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(b) at least one tackifier that is miscible in the polymerization product at room temperature.
    Type: Grant
    Filed: January 3, 1997
    Date of Patent: May 26, 1998
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Greggory S. Bennett, Christopher A. Haak, Craig A. Gustafson
  • Patent number: 5723545
    Abstract: Blends of semi-crystalline polymers with rubbery thermoplastic copolymers are provided. The rubbery thermoplastic copolymers are elastic at temperatures above their Tg's and properties similar to thermoplastic elastomers and surface tensions 5 dynes/cm or more different, preferably greater than the surface tension of the semi-crystalline polymer. Improved properties include good elastic recovery, toughness, and high elasticity without significant loss in optical properties.
    Type: Grant
    Filed: November 4, 1996
    Date of Patent: March 3, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Bruce Allan Harrington, Patrick Brant, Anthony Jay Dias
  • Patent number: 5683798
    Abstract: A pressure sensitive adhesive that includes:(a) the polymerization product of:(i) 25-98 parts by weight of an acrylic acid ester of a monohydric alcohol whose homopolymer has a T.sub.g less than 0.degree. C.;(ii) 2-75 parts by weight of a non-polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of no greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(iii) 0-5 parts by weight of a polar ethylenically unsaturated monomer whose homopolymer has a solubility parameter of greater than 10.50 and a T.sub.g greater than 15.degree. C.; and(b) at least one tackifier that is miscible in the polymerization product at room temperature.
    Type: Grant
    Filed: April 25, 1996
    Date of Patent: November 4, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Greggory S. Bennett, Christopher A. Haak, Craig A. Gustafson
  • Patent number: 5654370
    Abstract: Ethylene, alpha-olefin, non-conjugated bicyclic diene elastomeric polymers and/or polymer blends when compounded and formed into a calendered sheet, show surprising improvements for the combination in both green strength and peel adhesion in the unvulcanized state. Such green strength and peel adhesion provide benefits during calendering operations and subsequent joining of calendered sheets, while the compounded elastomeric polymers are in their green or unvulcanized state.
    Type: Grant
    Filed: August 8, 1996
    Date of Patent: August 5, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Sudhin Datta, Periagaram S. Ravishankar, Lawrence George Kaufman
  • Patent number: 5652308
    Abstract: Novel tackifier resins having a M.sub.n of 5,000 or less and a T.sub.g of 0.degree. C. or above are produced by combining a metallocene catalyst with an alpha-olefin and a cyclic monomer. New adhesives are produced by blending the novel tackifier with a base polymer.
    Type: Grant
    Filed: July 21, 1995
    Date of Patent: July 29, 1997
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Natalie Ann Merrill, James McLeod Farley, Martha Hetzel Robertson, Charles Lewis Sims, Richard Byron Pannell, Angelo Anthony Montagna
  • Patent number: 5648443
    Abstract: A process for effectively producing a cyclic olefin polymer and a cyclic olefin/alpha-olefin copolymer without opening the cyclic olefin, is disclosed. Further, a novel cyclic olefin/alpha-olefin copolymer prepared by the above-mentioned process, compositions and molded articles comprising the novel copolymer, are also disclosed. In the process for producing a cylcic olefin based polymer according to the present invention, homopolymerization of a cyclic olefin or copolymerization of a cyclic olefin and an alpha-olefin is effected in the presence of a catalyst comprising, as main ingredients, the following Compounds (A) and (B), and optionally Compound (C):(A) a transition metal compound;(B) a compound capable of forming an ionic complex when reacted with a transition metal compound; and(C) an organoaluminum compound.
    Type: Grant
    Filed: January 22, 1996
    Date of Patent: July 15, 1997
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Takuji Okamoto, Junichi Matsumoto, Masami Watanabe, Hiroshi Maezawa
  • Patent number: 5629398
    Abstract: A process for effectively producing a cyclic olefin polymer and a cyclic olefin/alpha-olefin copolymer without opening the cyclic olefin, is disclosed. Further, a novel cyclic olefin/alpha-olefin copolymer prepared by the above-mentioned process, compositions and molded articles comprising the novel copolymer, are also disclosed. In the process for producing a cylcic olefin based polymer according to the present invention, homopolymerization of a cyclic olefin or copolymerization of a cyclic olefin and an alpha-olefin is effected in the presence of a catalyst comprising, as main ingredients, the following Compounds (A) and (B), and optionally Compound (C):(A) a transition metal compound;(B) a compound capable of forming an ionic complex when reacted with a transition metal compound; and(C) an organoaluminum compound.
    Type: Grant
    Filed: June 5, 1992
    Date of Patent: May 13, 1997
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Takuji Okamoto, Junichi Matsumoto, Masami Watanabe, Hiroshi Maezawa
  • Patent number: 5574108
    Abstract: The present invention is directed to extrudable sealants which are particularly well suited for bonding a metal based, lidding material to a polystyrene container. The most preferred sealant compositions of the present invention preferably contain an acid copolymer, a tackifier and a polyolefin.
    Type: Grant
    Filed: April 18, 1995
    Date of Patent: November 12, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Vladimir Antonov, David D. Zhang, Stephen R. Tanny, Alister M. Soutar
  • Patent number: 5571868
    Abstract: Ethylene, alpha-olefin, non-conjugated bicyclic diene elastomeric polymers and/or polymer blends when compounded and formed into a calendered sheet, show surprising improvements for the combination in both green strength and peel adhesion in the unvulcanized state. Such green strength and peel adhesion provide benefits during calendering operations and subsequent joining of calendered sheets, while the compounded elastomeric polymers are in their green or unvulcanized state.
    Type: Grant
    Filed: June 15, 1995
    Date of Patent: November 5, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Sudhin Datta, Periagaram S. Ravishankar, Lawrence G. Kaufman
  • Patent number: 5567776
    Abstract: Provided are cycloolefin copolymer compositions comprising a hydrocarbon elastomer component substantially free from a polymerizable double bond and a cycloolefin random copolymer component obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms and a cycloolefin in the presence of said hydrocarbon elastomer component, said composition containing said hydrocarbon elastomer component in an amount of 1-50% by weight, and a method for preparing said cycloolefin copolymer compositions.Also provided are cycloolefin copolymer compositions comprising a hydrocarbon elastomer component having a polymerizable double bond and a cycloolefin copolymer component obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms and a cycloolefin in the presence of said hydrocarbon elastomer component, said composition containing said hydrocarbon elastomer component in an amount of 1-50% by weight.
    Type: Grant
    Filed: May 8, 1995
    Date of Patent: October 22, 1996
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yoichiro Tsuji, Yoshiharu Abe, Toshihiro Sagane, Toshimasa Takata
  • Patent number: 5567777
    Abstract: Provided are cycloolefin copolymer compositions comprising a hydrocarbon elastomer component substantially free from a polymerizable double bond and a cycloolefin random copolymer component obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms and a cycloolefin in the presence of said hydrocarbon elastomer component, said composition containing said hydrocarbon elastomer component in an amount of 1-50% by weight, and a method for preparing said cycloolefin copolymer compositions.Also provided are cycloolefin copolymer compositions comprising a hydrocarbon elastomer component having a polymerizable double bond and a cycloolefin copolymer component obtained by copolymerization of an .alpha.-olefin of at least 2 carbon atoms and a cycloolefin in the presence of said hydrocarbon elastomer component, said composition containing said hydrocarbon elastomer component in an amount of 1-50% by weight.
    Type: Grant
    Filed: January 26, 1996
    Date of Patent: October 22, 1996
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yoichiro Tsuji, Yoshiharu Abe, Toshihiro Sagane, Toshimasa Takata
  • Patent number: 5552489
    Abstract: Tackifiers having Mn's of 5,000 or less and Tg's above 0.degree. C. are produced by combining a single site catalyst with an alpha-olefin and a cyclic monomer under conditions designed to produce low molecular weight.
    Type: Grant
    Filed: January 25, 1995
    Date of Patent: September 3, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: . Natalie A. Merrill, James M. Farley, Martha H. Robertson, Charles L. Sims, Richard B. Pannell, Angelo A. Montagna