Solid Polymer Derived From Cycloaliphatic-containing Reactant Patents (Class 525/216)
  • Patent number: 5039748
    Abstract: High-Strength polypropylene fiber is obtained from polypropylene having incorporated therein from 0.05 to 10,000 ppm by weight of a vinylcycloalkane polymer. The disclosed fiber polypropylene has an intrinsic viscosity of from 0.5 to 2.5 dl/g as measured in a tetralin solution at 135.degree. C. and a ratio of weight average molecular weight to number average molecular weight of not more than 3.5/1.
    Type: Grant
    Filed: May 17, 1990
    Date of Patent: August 13, 1991
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Kizuku Wakatsuki, Noboru Yamaguchi, Kazuki Wakamatsu, Masahiro Kakugo, Tadayuki Ohmae
  • Patent number: 5032645
    Abstract: The polypropylene stretched film of the present invention is prepared by stretching a composition comprising a crystalline propylene polymer and 0.1 ppm by weight to 10% by weight of a nucleating agent, the composition having a melting point of 160.degree. C. or more, a crystallization temperature of 128.degree. C. or more and a 20.degree. C. xylene soluble portion of 3.0% by weight or less. The film has a high rigidity and a beautiful appearance as well as the characteristic properties inherent to crystalline propylene polymers. The film can be suitably used for food packaging and textile packaging.
    Type: Grant
    Filed: November 8, 1989
    Date of Patent: July 16, 1991
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tadatoshi Ogawa, Seiichiro Ima, Kazuki Wakamatsu
  • Patent number: 5008341
    Abstract: A transparent polyblend is formed from(a1) 99.9-0.1% by weight of a methyl (meth)acrylate homopolymer or of a copolymer thereof with up to 20% by weight of units of alkyl (meth)acrylate having an alkyl radical of from 2 to 10 carbon atoms and up to 10% by weight of further comonomers or(a2) 99.9-0.1% by weight of a styrene or .alpha.-methylstyrene and acrylonitrile copolymer containing from 5 to 30% by weight of units of acrylonitrile or(a3) 99.9-0.1% by weight of a possibly impact-modified polyvinyl chloride homopolymer or copolymer with up to 20% by weight of comonomers and(b) 0.1-99.9% by weight of a cycloalkyl (meth)acrylate homopolymer or copolymer with up to 99.9% by weight of units of methyl methacrylate.
    Type: Grant
    Filed: August 31, 1989
    Date of Patent: April 16, 1991
    Assignee: BASF Aktiengesellschaft
    Inventors: Rainer Bueschl, Peter Klaerner
  • Patent number: 4992511
    Abstract: A polymer composition comprising (A) 100 parts by weight of a cyclo-olefinic random copolymer comprising an ethylene component and a cyclo-olefin component and having an intrinsic viscosity [.eta.] of 0.05 to 10 dl/g, a glass transition temperature (Tg) of 50.degree. to 230.degree. C., and a softening point of at least 70.degree. C., (B) 5 to 150 parts by weight of at least one flexible polymer having a glass transition temperature of not more than 0.degree. C. and (C) 0.004 to 1.0 part by weight of an organic peroxide and its reaction product.
    Type: Grant
    Filed: September 28, 1989
    Date of Patent: February 12, 1991
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Yohzoh Yamamoto, Satoru Moriya
  • Patent number: 4983674
    Abstract: A hot melt adhesive composition which comprises:(a) a copolymer of vinyl aromatic compounds and conjugated dienic compounds, or a hydrogenated version thereof in amounts of about 20-70% by weight;(b) a tackifier comprising alicyclic hydrocarbon polymers in amounts of about 30-80% by weight; and(c) a 4-methylpentene-1 polymer in amounts of about 0.3-20% by weight, based on the composition, respectively.
    Type: Grant
    Filed: August 10, 1988
    Date of Patent: January 8, 1991
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Hiromi Shigemoto, Masami Takeda, Tsuneaki Muro
  • Patent number: 4978474
    Abstract: The present invention discloses a heat pumpable expandable weld through sealant comprising a combination of a terpolymer and a copolymer, a curing agent, electrically conductive particles and a blowing agent. Also disclosed is a method of bonding two metal components using this sealant.
    Type: Grant
    Filed: July 24, 1987
    Date of Patent: December 18, 1990
    Assignee: United Technologies Automotive Inc.
    Inventor: Thomas K. Johnston
  • Patent number: 4968764
    Abstract: A rubber compounding material incorporating a cyclopentadiene-based pertroleum resin prepared by thermally copolymerizing 100 parts by weight of a cyclopentadiene-based feed or dicyclopentadiene-based feed with about 5 to 100 parts by weight of an .alpha.-olefin having from 6 to 16 carbon atoms at a temperature of from about 200.degree. to 300.degree. C. for a period of from about 10 minutes to 10 hours in the presence or absence of a solvent.A rubber composition is also disclosed, composed of this rubber compounding material in combination with a diene-based polymer.In rubber compositions for tires, the compounding material and rubber composition of the present invention greatly improve resistance to cutting and chipping of the tread.
    Type: Grant
    Filed: December 23, 1988
    Date of Patent: November 6, 1990
    Assignee: Maruzen Petrochemical Co., Ltd.
    Inventors: Suetou Hayashida, Kirou Yanagimoto
  • Patent number: 4927885
    Abstract: Polypropylene resin compositions suitable for producing polypropylene films with excellent properties are disclosed. The compositions can provide polypropylene films having very excellent transparency, excellent heat-sealability and good anti-blocking property. Such characteristics are essential requirements for packing films. The polypropylene resin compositions comprise 70 to 99 parts by weight of polypropylene and 1 to 30 parts by weight of a specific hydrogenated petroleum resin. The hydrogenated petroleum resin can easily be prepared industrially from valueless by-products of oil and petrochemical industries, such as C.sub.5 fraction and C.sub.9 fraction by-produced in naphtha steam cracking process.
    Type: Grant
    Filed: October 5, 1988
    Date of Patent: May 22, 1990
    Assignee: Maruzen Petrochemical Co., Ltd.
    Inventors: Suetou Hayashida, Kyoichiro Kimura, Eiji Takahashi
  • Patent number: 4912169
    Abstract: Adhesive compositions containing a polymeric additive which is polymerized from monomers selected from C.sub.1 -C.sub.20 alkyl and cycloalkyl acrylate, C.sub.1 -C.sub.20 alkyl and cycloalkyl methacrylate, free-radical polymerizable olefinic acids, and optionally other ethylenically unsaturated monomers wherein said polymeric additive has a number average molecular weight less than about 35,000 and a softening point greater than about 40.degree. C.
    Type: Grant
    Filed: April 27, 1989
    Date of Patent: March 27, 1990
    Assignee: Rohm and Haas Company
    Inventors: Judith L. Whitmire, Patricia M. Lesko, Timothy G. Wood
  • Patent number: 4898912
    Abstract: The invention relates to compatible polymer blends comprised of a polymer component containing cyclohexyl (meth)acrylate as a monomer, and further comprised of a polymer component containing styrene as a monomer.
    Type: Grant
    Filed: September 15, 1987
    Date of Patent: February 6, 1990
    Assignee: Rohm GmbH Chemische Fabrik
    Inventors: Werner Siol, Ulrich Terbrack
  • Patent number: 4892909
    Abstract: A compatible polymer blend consisting of:(I) 0.1-99.9% by weight of a polymerisate P1, which is formed from monomers of formula I: ##STR1## wherein R.sub.1 is hydrogen or methyl, and (II) 99.9-0.1% by weight of copolymerisate P2, which is formed from (a) 5-40% by weight of cyclohexyl methacrylate, (b) 30-70% by weight of a methacrylic ester of formula II: ##STR2## wherein R.sub.2 is methyl or ethyl, (c) 10-50% by weight of a methacrylic ester of formula III: ##STR3## wherein R.sub.3 is a hydrocarbon group having 4-18 carbon atoms, and (d) 0-10 parts by weight of a monomer M which is copolymerizable with monomers of (a)-(c), yet different from these monomers.
    Type: Grant
    Filed: August 19, 1988
    Date of Patent: January 9, 1990
    Assignee: Roehm GmbH Chemische Fabrik
    Inventors: Werner Siol, Ulrich Terbrack
  • Patent number: 4876311
    Abstract: The invention relates to opaque synthetic resins containing 1 to 30% by weight of cross-linked beads consisting of a polymer comprised of:(i) 9.9 to 59.9% by weight of at least one radically polymerizable monomer A containing an aromatic residue or nonaromatic monomers A' which contain a halogen;(ii) 90 to 40% by weight of vinyl monomers B which are copolymerizable with these monomers but different from them;(iii) 0.1 to 20% by weight of at least one cross-linking monomer V and(iv) 0 to 10% by weight of a strongly polar monomer Hand where (a) the refractive index of the polymer is higher than that of the polymer matrix and that (b) the average bead size of the beads is in the range of 20 to 50 microns.
    Type: Grant
    Filed: March 1, 1988
    Date of Patent: October 24, 1989
    Assignee: Rohm GmbH Chemische Fabrik
    Inventors: Jurgen Hennig, Heinz Vetter, Manfred Munzer
  • Patent number: 4849479
    Abstract: Compatible polymer mixtures of a polymer component which contains cyclohexyl (meth)acrylate as a monomer and a polymer component which contains .alpha.-methyl styrene as a monomer.
    Type: Grant
    Filed: September 15, 1987
    Date of Patent: July 18, 1989
    Assignee: Rohm GmbH Chemicsche Fabrik
    Inventors: Werner Siol, Ulrich Terbrack
  • Patent number: 4849478
    Abstract: An oil-resistant rubber composition comprising (A) 90 to 10 parts by weight of an unsaturated nitrile-conjugated diene rubber having a .DELTA.Tg of 58.degree. C. or more and an average bound nitrile content of 15 to 50% by weight, (B) 10 to 90 parts by weight of at least one rubber selected from the group consisting of an ethylene-propylene type copolymer rubber, a natural rubber and a polyisoprene and (C) 0 to 50 parts by weight, per 100 parts by weight of the total of (A) and (B), of at least one component (C) selected from the group consisting of a styrene polymer and a polyalkenamer. Said rubber composition is oil-resistant and excellent in mechanical properties such as tear strength, resistance to crack growth, etc.
    Type: Grant
    Filed: February 16, 1988
    Date of Patent: July 18, 1989
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Yoji Mori, Yoshiaki Kawamura, Hironori Matsumoto, Yasuhiko Takemura
  • Patent number: 4840997
    Abstract: A metallic, gold colored composition comprising an olefin polymer, a mica-based gold pigment, a mica-based bronze pigment, carbon black, and optionally, a yellow pigment is provided. Additionally, a process to produce a glossy, metallic, gold colored polyolefin product in a grit blasted mold is provided.
    Type: Grant
    Filed: November 24, 1987
    Date of Patent: June 20, 1989
    Assignee: Phillips Petroleum Company
    Inventors: James B. Snell, Marjorie B. Skinner
  • Patent number: 4824921
    Abstract: Resins having an improved combination of softening point and tackifying properties together with good color and heat stability are obtained by Freidel-Crafts copolymerization of 4 to 80 wt. % of a C.sub.5 /C.sub.6 unsaturated feed; 5 to 55 wt. % of a terpene and 3 to 55 wt. % of an unsaturated aromatic compound.
    Type: Grant
    Filed: January 7, 1987
    Date of Patent: April 25, 1989
    Assignee: Exxon Research & Engineering Company
    Inventor: Quoc Luvinh
  • Patent number: 4816519
    Abstract: A rubber composition comprising a rubbery copolymer containing an acenaphthylene-type monomer as a copolymer component or a mixture of it with another rubber, and compounding agents. This composition gives a rubber vulcanizate having high strength and high modulus.
    Type: Grant
    Filed: January 4, 1988
    Date of Patent: March 28, 1989
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Mitsuyoshi Aonuma, Koichi Nishimura
  • Patent number: 4803248
    Abstract: A rubber composition comprises 1-30 parts by weight of particular cyclopentadiene series resin based on 100 parts by weight of rubber and exhibits improved cut resistance and chipping resistance.
    Type: Grant
    Filed: April 25, 1988
    Date of Patent: February 7, 1989
    Assignees: Bridgestone Corporation, Nippon Oil Co., Ltd.
    Inventors: Hitoshi Kondo, Makoto Sasaki, Yukio Kobayashi
  • Patent number: 4792141
    Abstract: An improved golf ball cover is disclosed. The cover has balata replaced by polyoctenylene rubber in an amount up to 40 parts without producing a deleterious effect on the cover yet maintaining the good "click" and "feel" of a balata covered golf ball and increasing the toughness of the ball cover.
    Type: Grant
    Filed: April 20, 1987
    Date of Patent: December 20, 1988
    Assignee: Acushnet Company
    Inventor: Francisco M. Llort
  • Patent number: 4785071
    Abstract: A rubber composition comprises 1-30 parts by weight of particular cyclopentadiene series resin based on 100 parts by weight of rubber and exhibits improved cut resistance and chipping resistance.
    Type: Grant
    Filed: February 9, 1987
    Date of Patent: November 15, 1988
    Assignees: Bridgestone Corporation, Nippon Oil Co., Ltd.
    Inventors: Hitoshi Kondo, Makoto Sasaki, Yukio Kobayashi
  • Patent number: 4748207
    Abstract: A crystalline polypropylene sheet is described, characterized by containing a polymer of a vinylcycloalkane having at least 6 carbon atoms in an amount of 0.05 wt ppm to 1 wt % (calculated as a vinylcycloalkane unit). This sheet is excellent in stiffness and transparency and is suitable for use in the production of various articles such as containers and trays.
    Type: Grant
    Filed: July 9, 1985
    Date of Patent: May 31, 1988
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Masahiro Kakugo, Yoshiharu Fukui, Kizuku Wakatsuki, Hideaki Nishio
  • Patent number: 4693772
    Abstract: A hot applicable, heat expandable, thermosetting sealing composition particularly adapted for use in the automotive industry is disclosed. Such a sealant comprises a styrene-butadiene rubber mixed with conventional thermoplastic resin blowing agents, vulcanizing agent, oils and thickening agents wherein the addition of an activator selected from the family of sulfonamide materials results in a sealer which can be hot applied without causing it to prematurely blow or cross-link yet remain affixed to the component until such time as it is desired to blow and cure the sealant.
    Type: Grant
    Filed: December 22, 1986
    Date of Patent: September 15, 1987
    Assignee: United Technologies Automotive, Inc.
    Inventor: William A. Douglas
  • Patent number: 4680316
    Abstract: A hot applicable, heat expandable, thermosetting sealing composition particularly adapted for use in the automotive industry is disclosed. Such a sealant comprises a styrene-butadiene rubber mixed with conventional thermoplastic resin blowing agents, vulcanizing agent, oils and thickening agents wherein the addition of an activator selected from the family of sulfonamide materials results in a sealer which can be hot applied without causing it to prematurely blow or cross-link yet remain affixed to the component until such time as it is desired to blow and cure the sealant.
    Type: Grant
    Filed: October 15, 1985
    Date of Patent: July 14, 1987
    Assignee: United Technologies Automotive, Inc.
    Inventor: William A. Douglas
  • Patent number: 4663394
    Abstract: A crystalline polybutene-1 composition containing from 1.times.10.sup.-6 to 10% byweight of a vinylcycloalkane unit having a melting point of 180.degree. C. or higher in terms of its homopolymer, is disclosed. The composition has a markedly improved rate of crystal conversion of polybutene-1.
    Type: Grant
    Filed: June 20, 1985
    Date of Patent: May 5, 1987
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Masahiro Kakugo, Kizuku Wakatsuki
  • Patent number: 4650829
    Abstract: Hydrogenated hydrocarbon resins from cyclopentadiene and/or substituted cyclopentadiene of softening point below 90.degree. C. and having a (Tg) as from 35 to 70 lower than the softening point with less than 12 wt. % of the resin having a molecular weight above 1000 are particularly useful as tackifiers in pressure sensitive adhesives especially in hydrogenated styrene/butadiene/styrene block copolymer adhesive formulations where their use can obviate the need for plasticizing oil.
    Type: Grant
    Filed: December 11, 1984
    Date of Patent: March 17, 1987
    Assignee: Exxon Research & Engineering Co.
    Inventors: Bernard Bossaert, Andre Lepert, Jacques Lechat, Vincent L. Hughes, Raymond C. C. Yap
  • Patent number: 4551501
    Abstract: A crystalline propylene polymer composition having excellent transparency and rigidity comprising a blend of a crystalline polypropylene with a polymer of a vinyl cycloalkane having at least 6 carbon atoms. The composition contains 0.05 weight ppm to 10,000 weight ppm of the vinyl cycloalkane unit.
    Type: Grant
    Filed: December 27, 1984
    Date of Patent: November 5, 1985
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Akinobu Shiga, Masahiro Kakugo, Junpei Kojima, Kizuku Wakatsuki
  • Patent number: 4460724
    Abstract: A hot melt composition is provided which comprises (1) a hydrogenated resin (II) having a softening point ranging from 50.degree. C. to 140.degree. C., said hydrogenated resin (II) being prepared by hydrogenating a copolymer resin (I) obtained by copolymerizing 20 to 60 wt % of a component (A) selected from the group consisting of five-member cyclic compounds each having a conjugated double bond and represented by the general formula (A) given below and Diels-Alder addition products thereof (A):GENERAL FORMULA (A): ##STR1## wherein H is hydrogen; R is an alkyl group having from 1 to 3 carbon atoms; m and n are zero or integers of not less than 1 and are in the relation of m+n=6;with 25 to 70 wt % of a codimer (component B) of said five-member cyclic compound and an aliphatic conjugated diolefin having 4 to 5 carbon atoms and 2.
    Type: Grant
    Filed: August 13, 1982
    Date of Patent: July 17, 1984
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Shozo Tsuchiya, Akio Ohshima, Hideo Hayashi
  • Patent number: 4388448
    Abstract: Homopolymers of glycidyl methacrylate (GMA) and copolymers of GMA with other methacrylate comonomers; their preparation employing an anionic initiator which is the adduct of a selected organo(alkali metal) compound and at least one mole of methyl methacrylate or another lower alkyl methacrylate; as well as solvolyzed forms of the GMA polymers.
    Type: Grant
    Filed: February 23, 1981
    Date of Patent: June 14, 1983
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Lester R. Melby
  • Patent number: 4380607
    Abstract: A rubber composition consisting essentially of a dispersion in which particles of a high-melting isotactic poly-.alpha.-olefin having a melting point of at least 150.degree. C. are uniformly dispersed in a rubber matrix, said particles having an average particle size of not more than 200.mu., has a high modulus of elasticity and also excellent tear resistance. Such rubber composition can be obtained, for example, by mixing fine powder of said isotactic poly-.alpha.-olefin having an average particle size of not more than 200.mu. with a rubber solution, dispersing the particles uniformly in said rubber solution and recovering a rubber composition from the dispersion.
    Type: Grant
    Filed: April 23, 1981
    Date of Patent: April 19, 1983
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Hiroharu Ikeda, Kohei Goto, Yasuyuki Shimozato
  • Patent number: 4360622
    Abstract: A hot melt adhesive composition comprising (I) a hydrogenated resin having a softening point of 60.degree.-130.degree. C. obtained by the hydrogenation of a copolymer resin prepared by reacting (A) at least one five-membered cyclic compound such as cyclopentadiene with (B) at least one dimer or trimer of the five-membered cyclic compound, isoprene and piperylene in specified ratios by weight, and (II) an ethylene type copolymer and/or wax.
    Type: Grant
    Filed: March 13, 1981
    Date of Patent: November 23, 1982
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Shozo Tsuchiya, Akio Oshima, Hideo Hayshi
  • Patent number: 4360628
    Abstract: Solid copolymer tackifying resins based on dicyclopentadiene, a vinylaromatic hydrocarbon and a benzene carrying 1 to 3 lower alkyl, hydroxyl or halogen substituents and adhesive formulations containing these resins.
    Type: Grant
    Filed: January 19, 1981
    Date of Patent: November 23, 1982
    Assignee: National Starch and Chemical Corporation
    Inventors: Yves Runavot, Georges Billault, Jacques Salvetat
  • Patent number: 4336352
    Abstract: A polyethylene composition comprising a mixture of three kinds of polyethylenes (A), (B) and (C) characterized in that:(i) the viscosity average molecular weight of (A) is 1,000-100,000, the viscosity average molecular weight of (B) is 100,000-1,000,000, the viscosity average molecular weight of (C) is 400,000-6,000,000, the molecular weight ratio of (B) to (A), i.e. B/A, is 2-200 and the molecular weight ratio of (C) to (B), i.e. C/B, is 1.5 or more.(ii) the mixing ratio of (A) to (B) is 30/70 to 70/30 and the mixing ratio of (C) is 1-10% by weight based on the total composition, and(iii) the melt index of the composition is 0.001-1, and a process for producing said composition. This polyethylene composition is excellent in physical properties in that it has an appropriate die swell, a high melt tension and an excellent moldability and exhibits a high stiffness and a high ESCR.
    Type: Grant
    Filed: August 11, 1980
    Date of Patent: June 22, 1982
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventors: Hisaya Sakurai, Yoshihiko Katayama, Tadashi Ikegami, Shigeru Mizutani
  • Patent number: 4288358
    Abstract: This invention relates to blends of plasticizing oils and compatible tackifiers with olefin copolymers containing propylene, either 1-butene or 1-pentene and 3 to 14 mole percent of at least one C.sub.6 to C.sub.10 linear .alpha.-olefin which are useful as hot-melt, pressure-sensitive adhesives. The unmodified copolymer base resins have melt viscosities in the range of 10,000 cp up to about 1,000,000 cp at 190.degree. C. The addition of the plasticizing oils and compatible tackifiers to the copolymer base resin causes a dramatic and unexpected increase in the shear adhesion failure time in addition to improved coatability as well as substantial increases in probe tack and peel adhesion values of the copolymers.
    Type: Grant
    Filed: August 30, 1979
    Date of Patent: September 8, 1981
    Assignee: Eastman Kodak Company
    Inventors: Jimmy R. Trotter, Richard L. McConnell, Frederick B. Joyner
  • Patent number: 4280543
    Abstract: A tire having a tread with improved wet grip characteristics. The tread is made from a composition which has specific loss factor values measured in high and low frequency ranges defined herein.
    Type: Grant
    Filed: March 8, 1977
    Date of Patent: July 28, 1981
    Assignee: Dunlop Limited
    Inventors: Robert Bond, Arthur R. Williams
  • Patent number: 4272436
    Abstract: The green strength of elastomers is improved by the addition of semi-crystalline butene polymers selected from the class consisting of polybutene and interpolymers made from 1-butene monomer and at least one monomer selected from the class consisting of alpha-olefins, non-conjugated dienes, and non-conjugated polyenes. The semi-crystalline butene polymer is mixed with a desired elastomer such as natural or synthetic cis-1,4-polyisoprene, or a synthetic elastomer made from monomers selected from the class consisting of conjugated dienes having from 4 to 10 carbon atoms, interpolymers of said dienes among themselves or with vinyl substituted aromatic hydrocarbon compounds having from 8 to 12 carbon atoms, or polyalkenylenes. The mixing or blending of the butene polymer and the elastomer may be through conventional methods such as cement mixing or mastication.
    Type: Grant
    Filed: May 24, 1979
    Date of Patent: June 9, 1981
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Joginder Lal, Sandra J. Walters
  • Patent number: 4237247
    Abstract: A cured or uncured chlorinated polyethylene composition free from hexamethyl-phosphoric triamide complex comprising (A) chlorinated polyethylene, (B) a mercaptotriazine as cross-linking agent, (C) a cross-linking accelerator selected from the group consisting of specified dithiocarbamic compounds, secondary and tertiary amines, and the carboxylates, mercaptothiazole salts, dithiocarbamates and dithiophosphates of said secondary and tertiary amines and the benzothiazylsulfenamides of said secondary amines, and (D) an acid acceptor of metal compounds; as well as a process for curing uncured chlorinated polyethylene which comprises heating same in the absence of hexamethylphosphoric triamide complex in the presence of (B), (C) and (C) at a temperature of about 120.degree. to about 200.degree. C.
    Type: Grant
    Filed: April 21, 1978
    Date of Patent: December 2, 1980
    Assignee: Osaka Soda Co. Ltd.
    Inventors: Yasuo Matoba, Akira Hashimoto, Mikio Sugahara
  • Patent number: 4228266
    Abstract: A novel copolymer resin having excellent compatibility with rubber and plastics, stable to air, easily soluble in the hydrocarbon solvents and free of gel, said resin being obtained either (1) by copolymerizing one or more of the monomeric substances selected from the group consisting of cyclopentadiene, dicyclopentadiene and alkyl-substituted compounds thereof and one or more of the substances selected from the hydroxystyrene derivatives, or (2) by copolymerizing one or more of the monomeric substances selected from the group consisting of cyclopentadiene, dicyclopentadiene and alkyl-substituted compounds thereof, one or more of the substances selected from the codimers of cyclopentadiene and/or alkyl-substituted compounds thereof and chain conjugated diolefins having 4 to 5 carbon atoms, and one or more of the substances selected from the hydroxystyrene derivatives. There are also provided compositions comprising said resin and rubber or thermoplastic high-molecular weight substances.
    Type: Grant
    Filed: August 21, 1978
    Date of Patent: October 14, 1980
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Ken-ichi Kudo, Yoshihiko Kitagawa, Teruhisa Koyama, Akira Takata, Shuichi Kanagawa, Tetsuo Yamaguchi
  • Patent number: 4220737
    Abstract: An air drying paint composition comprising a chlorinated polymer selected from the group consisting of chlorinated polydiolefin rubbers and chlorinated polyolefins as at least one ingredient of a binder, said composition further comprising 5 to 100 parts by weight, per 100 parts by weight of the chlorinated polymer, of a cyclopentadiene resin having a softening point of 50.degree. to 160.degree. C. prepared by heat polymerization of 50 to 100% by weight of a cyclopentadiene monomer and 50 to 0% by weight of a comonomer copolymerizable with it.
    Type: Grant
    Filed: August 21, 1978
    Date of Patent: September 2, 1980
    Assignee: Nippon Zeon Co. Ltd.
    Inventor: Ryuji Kita
  • Patent number: 4217428
    Abstract: This invention relates to blends of substantially amorphous propylene/higher 1-olefin, 1-butene/higher 1-olefin, or propylene/1-butene/higher 1-olefin copolymers with tackifying resins which provide permanently tacky, low viscosity materials which have useful pressure-sensitive adhesive properties. The copolymers contain 40 to 60 mole % of one or more higher 1-olefins of the group 1-hexene, 1-heptene, 1-octene, 1-nonene and 1-decene and have a melt viscosity range of 10,000 to 75,000 cp. at 190.degree. C.
    Type: Grant
    Filed: November 7, 1977
    Date of Patent: August 12, 1980
    Assignee: Eastman Kodak Company
    Inventors: Richard L. McConnell, Doyle A. Weemes, Frederick B. Joyner
  • Patent number: 4211692
    Abstract: Extrusion coating compositions for woven and non-woven polyolefin substrates are disclosed which employ an ethylene-propylene-diene terpolymer rubber, a high density polyethylene, and ethylene-propylene block copolymer and an ethylene-isobutylacrylate copolymer. Optionally, ultraviolet stabilizers, flame retardants and pigments can be added to each. Also disclosed are woven and non-woven polyolefin substrates which are coated with the above-cited extrusion coating compositions.
    Type: Grant
    Filed: March 29, 1976
    Date of Patent: July 8, 1980
    Assignee: Standard Oil Company (Indiana)
    Inventors: Edward Barkis, Robert R. Crummer, James M. Joyner
  • Patent number: 4189547
    Abstract: A hydrocarbon-derived resin having a softening point in the range of about 0.degree. C. to about 25.degree. C. derived from polymerizing piperylene and selected methyl branched tertiary olefins in the presence of boron trifluoride or boron trifluoride etherate. Such resins are particularly useful for the preparation of pressure sensitive adhesives, especially when such resins are mixed with other hydrocarbon-derived resins having high softening points in the range of about 80.degree. C. to about 110.degree. C.
    Type: Grant
    Filed: April 13, 1978
    Date of Patent: February 19, 1980
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Robert A. Osborn, Herbert L. Bullard
  • Patent number: 4186163
    Abstract: This invention relates to a novel elastomeric foamed material which has surprisingly been found to exhibit a variety of unusual and desirable features both in its physical properties and in its process of manufacture. These foamed compositions of a lightly sulfonated elastomeric gum contain a nonvolatile polar plasticizer and preferably extenders such as oil and fillers. These elastomer foams exhibit an unusual profile of physical properties including melt reprocessability of fabricated articles, and high temperature reshaping of foamed objects while maintaining a good foam structure. These novel foams can be manufactured with relatively uniform cell structures and with small cell sizes at foam densities from near bulk density to less than 0.1 g/cc.
    Type: Grant
    Filed: October 4, 1977
    Date of Patent: January 29, 1980
    Assignee: Exxon Research & Engineering Co.
    Inventors: Douglas Brenner, Robert D. Lundberg
  • Patent number: 4178272
    Abstract: The hot-melt adhesives of the present invention comprise a blend of poly(propylene-co-higher 1-olefin), tackifying resin and crystalline propylene containing polymer. These hot-melt adhesive compositions have a novel combination of properties including strong T-peel and lap shear bonds to both low- and high-density polyethylene with excellent creep resistance at ambient temperatures. Therefore, these new hot-melt adhesives are excellent adhesives for applications such as sealing high-density polyethylene grocery bags and low-density shipping bags.
    Type: Grant
    Filed: March 2, 1977
    Date of Patent: December 11, 1979
    Assignee: Eastman Kodak Company
    Inventors: Max F. Meyer, Jr., Richard L. McConnell, Frederick B. Joyner
  • Patent number: 4169116
    Abstract: This invention relates to blends of compatible tackifiers with substantially amorphous olefin copolymers containing at least one C.sub.3 to C.sub.5 linear .alpha.-olefin and 40 to 60 mole percent of at least one C.sub.6 to C.sub.10 linear .alpha.-olefin which are useful as hot-melt, pressure-sensitive adhesives. The unmodified copolymer base resins have melt viscosities in the range of >75,000 cp up to about 1,000,000 cp at 190.degree. C. The addition of the compatible tackifiers to the copolymer base resin causes a dramatic and unexpected increase in the shear adhesion failure time in addition to improved coatability as well as substantial increases in probe tack and peel adhesion values of the copolymers.
    Type: Grant
    Filed: November 7, 1977
    Date of Patent: September 25, 1979
    Assignee: Eastman Kodak Company
    Inventors: Jimmy R. Trotter, Frederick B. Joyner, Richard L. McConnell