Solid Polymer Derived From Reactant Containing A Carbonyl Group Other Than As Part Of A Carboxylic Acid Or Derivative Patents (Class 525/220)
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Publication number: 20150035207Abstract: A composition for making a cast, thermoformable sheet or slab, comprising: a syrup comprising: about 30-40% SSI—acrylic pre-polymerized syrup at 20% solids; about 30-40% MMA—methyl methacrylate; about 2-3% BA—Butyl acrylate; about 1-15% acrylic chips; and about 1-15% rigid particles with a mean diameter of about 0.5-2000 ?m. The rigid particles may preferably comprise a polymeric material such as poly allyl diglycol carbonate particles. A method for producing a thermoformed article having a textured surface comprising mixing the syrup as above; swelling the acrylic chips; degassing the syrup; heating the syrup; casting the syrup into a sheet; and thermoforming the cast sheet against a mold.Type: ApplicationFiled: August 4, 2014Publication date: February 5, 2015Applicant: Aristech Surfaces LLCInventors: Mark Gatman, Scott LaFollette, Neil Caldwell, Jeff Fields
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Publication number: 20140371396Abstract: A multi-stage emulsion processing aid polymer comprising one or more functionalized ethylenically unsaturated monomer into the emulsion polymerization reactor, wherein the functionality is selected from the group consisting of ?-keto esters, ?-keto amides, ?-diketones, cyanoacetic esters, malonates, nitroalkanes, ?-nitro esters, sulfonazides, thiols, thiol-s-triazines, and amine, where the functionality is incorporated into polymers by polymerizing, ethylenically unsaturated monomers containing these functionalities or by post functionalization of a polymer with additional reactions after polymerization in one of the first or second stages. Foamable halogenated polymers comprising the multi-stage emulsion processing aid polymer is also provided. Also provided are methods for making the multi-stage emulsion processing aid polymer and foamable halogenated polymers.Type: ApplicationFiled: December 28, 2011Publication date: December 18, 2014Inventors: Paul R. Van Rheenen, Steven P. Broadwater
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Publication number: 20140287167Abstract: Provided is a polymerizable composition for providing a thin image-display device that does not exhibit display problems due to deformation of an image-display unit, allows high-brightness, high-contrast image display, and tolerates heat well. A polymerizable composition for forming a polymer layer interposed between an image-display unit in an image-display device and a light-transmitting protective part. Said polymerizable composition is characterized by containing the following: (1) a (meth)acryloyl group-containing compound that has a structural unit derived from a (poly)ester polyol and/or a structural unit derived from a (poly)carbonate polyol; (2) a (meth)acryloyl group-containing compound that has a C9+ hydrocarbon group; and (3) a photopolymerization initiator.Type: ApplicationFiled: December 26, 2012Publication date: September 25, 2014Applicant: Showa Denko K.K.Inventor: Kazuhiko Ooga
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Patent number: 8669398Abstract: The invention relates to novel O-dialkylamino-isoureas and polymerizable compositions comprising these O-dialkylamino-isoureas of compounds of the general formula (I). The invention further relates to the use of O-dialkylamino-isoureas as polymerization initiators, especially to prepare coatings or for controlled degradation of polyolefins.Type: GrantFiled: December 28, 2009Date of Patent: March 11, 2014Assignee: BASF SEInventors: Peter Nesvadba, Lucienne Bugnon Folger, Antoine Carroy, Marc Faller
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Patent number: 8299191Abstract: Disclosed herein are tunable shape memory polymers (SMP's) and methods for manufacturing the disclosed SMP's.Type: GrantFiled: October 18, 2010Date of Patent: October 30, 2012Assignee: Georgia Tech Research Corp.Inventors: Walter E. Voit, Taylor Ware, Kenneth Gall
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Patent number: 8188190Abstract: A method of modifying the rheology of a thermoplastic resin that includes the steps of providing a thermoplastic resin and blending interpolymer resin particles with the thermoplastic resin. The interpolymer resin contains a styrenic polymer intercalated within a polyolefin, such that the thermoplastic resin is present as a continuous phase and the interpolymer resin is present as a dispersed phase. The method provides a rheology modified thermoplastic resin with improved physical characteristics.Type: GrantFiled: October 21, 2011Date of Patent: May 29, 2012Assignee: NOVA Chemicals Inc.Inventor: Eric Vignola
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Patent number: 8053525Abstract: A method of modifying the rheology of a thermoplastic resin that includes the steps of providing a thermoplastic resin and blending interpolymer resin particles with the thermoplastic resin. The interpolymer resin contains a styrenic polymer intercalated within a polyolefin, such that the thermoplastic resin is present as a continuous phase and the interpolymer resin is present as a dispersed phase. The method provides a rheology modified thermoplastic resin with improved physical characteristics.Type: GrantFiled: March 17, 2010Date of Patent: November 8, 2011Assignee: NOVA Chemicals Inc.Inventor: Eric Vignola
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Patent number: 8026313Abstract: A curable polymer composition that is quickly curable to form a cured article having excellent adhesion and followability to a substrate and at least including (A) an acrylic copolymer having a hydrogen atom bonded to a silicon atom, (B) a compound having at least two aliphatic unsaturated bonds in one molecule thereof, (C) a fluoroolefin copolymer including vinylidene fluoride as main component, and (D) a catalyst for hydrosilylation reaction.Type: GrantFiled: December 6, 2007Date of Patent: September 27, 2011Assignee: Daikin Industries, Ltd.Inventors: Katsuhiko Imoto, Tetsuo Shimizu, Masayuki Hayashi, Tomohiro Iimura, Eiji Kitaura, Peter Cheshire Hupfield
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Patent number: 7935761Abstract: The present invention relates to a process for preparing a thermoplastic vulcanizate (TPV) comprising: contacting a thermoplastic polymer, a cross-linkable elastomer, at least one curative, and at least one cure activator in a solvent to form Composition A. The solvent is then removed, and thereafter the cross-linkable elastomer is at least partially cured. The average particle size of the cross-linkable elastomer is 10 microns or less after the solvent is removed.Type: GrantFiled: April 18, 2007Date of Patent: May 3, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Weiqing Weng, Sunny Jacob, Peijun Jiang, Armenag H. Dekmezian, Aspy K. Mehta, Peter W. Manders, Pradeep Shirodkar, Palanisamy Arjunan
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Patent number: 7923512Abstract: The invention provides a medical implant or medical implant part comprising porous ultrahigh molecular weight polyethylene having a weight average molecular weight of about 400,000 atomic mass units or more and a porosity of about 15% to about 65%. The invention further provides a process for producing a medical implant or medical implant part.Type: GrantFiled: July 19, 2010Date of Patent: April 12, 2011Assignee: Depuy Products, Inc.Inventors: Richard S. King, Mark D. Hanes
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Patent number: 7915345Abstract: This invention relates to the preparation of thermoplastic vulcanizates (TPVs) with unique morphological features, more specifically, this invention relates to a method for preparing TPV compositions wherein the mixing of plastomers and elastomers are carried out in solvent with curatives to induce cross-linking.Type: GrantFiled: April 18, 2007Date of Patent: March 29, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Weiqing Weng, Sunny Jacob, Peijun Jiang, Armenag H. Dekmezian, Aspy K. Mehta, James R. Ayers, David J. Lohse, Peter W. Manders, Palanisamy Arjunan
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Publication number: 20110060086Abstract: A copolymer is formed from an isoolefin having from 4 to 7 carbon atoms and an alkylstyrene. The copolymer has a substantially homogeneous compositional distribution. The copolymer has from about 8 to about 12 wt % of alkylstyrene and at least 85 wt % of isoolefin. The copolymer is preferably halogenated with about 1.1 to about 1.5 wt % of a halogen. The copolymer may in elastomeric nanocomposites. To obtain a good dispersion of the nanoclay in a formulated compound, at least one cure accelerator is selected from the group consisting of mercaptobenzothiazole disulfide, mercaptobenzothiazole, cyclohexyl benzothiazole disulfide, dibutyl thiourea, tetramethylthiuram disulfide, 4-4-dithiodimropholine, zinc dimethyldithiocarbamate, and zinc dibutylphosphorodithiate.Type: ApplicationFiled: August 23, 2010Publication date: March 10, 2011Inventors: Michael Brendan Rodgers, Weiqing Weng, John Patrick Soisson, Robert Norman Webb, Sunny Jacob
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Patent number: 7834086Abstract: This invention relates to coating compositions that include water; a latex polymer and a silane coupling agent. The latex polymer preferably comprises acetoacetoxy functionality, or is a multistage latex, or is an acetoacetoxy functional multistage latex. The silane coupling agent is preferably a functionalized silane coupling agent (more preferably an epoxy-functional silane coupling agent). The compositions may be used to coat a variety of substrates, including wood, cement and fiber cement. Articles having the coating applied thereto are also provided.Type: GrantFiled: June 4, 2007Date of Patent: November 16, 2010Assignee: Valspar Sourcing, Inc.Inventors: T. Howard Killilea, Michael C. Wildman, Bruce A. Johnson, Carl H Weber
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Patent number: 7834090Abstract: A torsional vibration damper or other vibration damping device with a rubber vibration absorbing element. The rubber element is a peroxide-cured composition based on 100 parts of ethylene-alpha-olefin elastomer, and 5 to 100 parts of polyvinyl butyral polymer which may have a molecular weight from about 40,000 to about 250,000. The composition may also include a compatibilizer or homogenizer, such as chlorinated polyethylene. The polyvinyl butyral increases the damping of the composition, and the compatibilizer improves the temperature stability of the damping.Type: GrantFiled: August 3, 2007Date of Patent: November 16, 2010Assignee: The Gates CorporationInventors: Yuding Feng, Yahya Hodjat, Lin Zhu
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Patent number: 7781526Abstract: The invention provides a medical implant or medical implant part comprising porous ultrahigh molecular weight polyethylene having a weight average molecular weight of about 400,000 atomic mass units or more and a porosity of about 15% to about 65%. The invention further provides a process for producing a medical implant or medical implant part.Type: GrantFiled: June 20, 2007Date of Patent: August 24, 2010Assignee: DePuy Products, Inc.Inventors: Richard S. King, Mark D. Hanes
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Patent number: 7723458Abstract: An approach is presented for designing a polymeric layer for nanometer scale thermo-mechanical storage devices. Cross-linked polyaryletherketone polymers are used as the recording layers in atomic force data storage devices, giving significantly improved performance when compared to previously reported cross-linked and linear polymers. The cross-linking of the polyaryletherketone polymers may be tuned to match thermal and force parameters required in read-write-erase cycles.Type: GrantFiled: March 25, 2008Date of Patent: May 25, 2010Assignee: International Business Machines CorporationInventors: Richard Anthony DiPietro, Urs T. Duerig, Jane Elizabeth Frommer, Bernd Walter Gotsmann, Erik Christopher Hagberg, James Lupton Hedrick, Armin W. Knoll, Teddie Peregrino Magbitang, Robert Dennis Miller, Russell Clayton Pratt, Charles Gordon Wade
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Patent number: 7655830Abstract: The present invention relates to superabsorbent polymer particles having functionalizers covalently bound to the surface of precursor superabsorbent polymer particles. The functionalizers of the present invention comprise a grafting unit with a radiation activatable group and a functional unit covalently bound to the grafting unit. The grafting unit is bound to an aliphatic C—H group comprised at the surface of the precursor superabsorbent polymer particle. The functional unit comprises chemical structures which are not present in the precursor superabsorbent polymer particle. These functional units add an additional function to the precursor suberabsorbent polymer particle or modifying an existing function of the precursor superabsorbent polymer particle. Moreover, the invention relates to a process for making these superabsorbent polymer particles.Type: GrantFiled: August 5, 2005Date of Patent: February 2, 2010Assignee: The Procter & Gamble Co.Inventors: Andreas Flohr, Torsten Lindner
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Publication number: 20090036609Abstract: A torsional vibration damper or other vibration damping device with a rubber vibration absorbing element. The rubber element is a peroxide-cured composition based on 100 parts of ethylene-alpha-olefin elastomer, and 5 to 100 parts of polyvinyl butyral polymer which may have a molecular weight from about 40,000 to about 250,000. The composition may also include a compatibilizer or homogenizer, such as chlorinated polyethylene. The polyvinyl butyral increases the damping of the composition, and the compatibilizer improves the temperature stability of the damping.Type: ApplicationFiled: August 3, 2007Publication date: February 5, 2009Inventors: Yuding Feng, Yahya Hodjat, Lin Zhu
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Publication number: 20080306217Abstract: The invention provides a comprising one or more ethylene interpolymers, and wherein the interpolymers, or the composition, has a melt viscosity from 1 to 30,000 cP at 177° C., and wherein at least one ethylene interpolymer has an Rv from 0.3 to 0.99. The invention further provides a composition comprising at least one low molecular weight (LMW) ethylene interpolymer, and at least one high molecular weight (HMW) ethylene interpolymer, and wherein the composition has a melt viscosity from 1 to 30,000 cP at 177° C., and wherein the sum of the Rv from the low molecular weight interpolymer and the high molecular weight interpolymer is from 0.3 to 2. The invention further provides for processes of making such compositions, processes for functionalizing the interpolymer(s) of such compositions, and articles comprising at least one component prepared from an inventive composition.Type: ApplicationFiled: December 12, 2006Publication date: December 11, 2008Inventors: Teresa P. Karjala, Selim Yalvac, Cynthia L. Rickey, Sylvie Desjardins, Marc A. Springs
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Patent number: 7399806Abstract: The present invention is directed to the preparation of photoresist polymers via living free radical polymerization techniques. Sterically bulky ester monomers are utilized as the polymerization components. Use of chain transfer agents is included in polymerization processing conditions. Cleavage of polymer terminal end groups that include a heteroatom are described.Type: GrantFiled: April 12, 2007Date of Patent: July 15, 2008Assignee: Symyx Technologies, Inc.Inventors: Didier Benoit, Adam Safir, Han-Ting Chang, Dominique Charmot, Kenji Okamoto, Isao Nishimura, Yong Wang
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Patent number: 7250475Abstract: The present invention is directed to the preparation of photoresist polymers via living free radical polymerization techniques. Sterically bulky ester monomers are utilized as the polymerization components. Use of chain transfer agents is included in polymerization processing conditions. Cleavage of polymer terminal end groups that include a heteroatom are described.Type: GrantFiled: June 25, 2004Date of Patent: July 31, 2007Assignee: Symyx Technologies, Inc.Inventors: Didier Benoit, Adam Safir, Han-Ting Chang, Dominique Charmot, Kenji Okamoto, Isao Nishimura, Yong Wang
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Patent number: 7232613Abstract: The base material for pressure-sensitive adhesive tape or sheet is constituted of a polyolefin based resin as the major component and is obtained by rolling by means of a calender having a measure capable of individually changing the rotational speed of each calender roll. Examples of the measure capable of individually changing the rotational speed of each calender roll include a measure provided with motors capable of individually driving their respective calender rolls and a measure provided with speed regulators capable of individually regulating their respective calender rolls. It may be employed that the number of calender rolls is four and that the roll arrangement is in the reverse L shape. It is preferable that the base material for pressure-sensitive adhesive tape or sheet contains an inorganic compound together with the polyolefin based resin.Type: GrantFiled: June 23, 2004Date of Patent: June 19, 2007Assignee: Nitto Denko CorporationInventors: Yoshio Nakagawa, Masato Shirai, Shuzo Fujiwara, Yoshihide Kawaguchi, Hiroichi Ukei
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Patent number: 7195818Abstract: A sealable multi-layer opaque film. In particular, a sealable multi-layer opaque film that is moisture permeable and water resistant. The sealable multi-layer opaque film is an oriented multilayer film with a core layer comprising an orientation-enhancing polymer, a polypropylene homopolymer and a beta crystal nucleator of polypropylene and at least one sealable skin layer.Type: GrantFiled: May 1, 2002Date of Patent: March 27, 2007Assignee: ExxonMobil Oil CorporationInventors: Dan-Cheng Kong, Michael D. Cleckner
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Patent number: 7157146Abstract: A primer composition comprises (A) a vinyl copolymer obtained through copolymerization of (a-1) a UV-absorbing vinyl monomer, (a-2) an alkoxysilyl group-containing vinyl monomer, and (a-3) another copolymerizable monomer, (B) a curing agent, and (C) a thermoplastic vinyl resin having a Tg of at least 80° C. Polycarbonate resin articles, when covered with an undercoat of the primer composition and an overcoat of an organopolysiloxane composition, exhibit improved transparency, mar resistance, weather resistance, and chemical resistance and find outdoor use as vehicle and building windows and windshields.Type: GrantFiled: October 8, 2003Date of Patent: January 2, 2007Assignee: Shin-Etsu Chemical Co., Ltd.Inventors: Koichi Higuchi, Masahiro Furuya, Masaaki Yamaya
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Patent number: 7011883Abstract: The present invention relates to a display strip to hold commodity-containing bags. It can facilitate to make a process of attaching the bags thereto automate. It enables commodity-containing bags to be removed therefrom without having their appearance degraded. The display strip according to the present invention is utilized to hold and align a plurality of commodity-containing bags vertically for the display. It comprises at least a substrate layer and a sealant layer with the sealant layer containing an ethylene-vinyl acetate copolymer and an adhesive promoting tackifier.Type: GrantFiled: May 6, 2003Date of Patent: March 14, 2006Assignee: Ishida Co., Ltd.Inventors: Yoshio Iwasaki, Yukio Nakagawa, Tadao Oota, Naoji Ichise
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Patent number: 6893731Abstract: This invention provides a water-based composition suitable for use on polyester-based substrates for increasing adhesion between the substrate and a topcoat or overcoat. The composition comprises: (1) a latex polymer formed from the polymerization of at least one monomer selected from the group consisting of bicyclic alkyl (meth)acrylates and aromatic (meth)acrylates and at least one monomer which imparts to the polymer the ability to be crosslinked; (2) a water soluble or water dispersible polymer selected from the group consisting of acrylate-based resins, sulfonated polyester-based resins and combinations thereof; and (3) a crosslinking agent.Type: GrantFiled: September 25, 2001Date of Patent: May 17, 2005Assignee: 3M Innovative Properties CompanyInventor: William L. Kausch
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Patent number: 6887912Abstract: An expanded cellular ethylenic polymer product is provided from an irradiated, noncross-linked linear ethylenic polymer. Linear ethylenic polymers can be irradiated at ambient conditions sufficient to introduce branching in the polymer in the absence of detectable cross-linking as indicated by the absence of gels. The irradiated linear ethylenic polymer is compatible with highly branched low density polyethylene and, when mixed therewith, produces a resin having a single broad based melting temperature range as determined by direct scanning calorimetry, which indicates that the polymers in the mixture have similar crystallization behavior suitable for producing low density foams by extrusion foaming. The linear polymers can be obtained from recycled shrink wrap film. Low densities of from 0.7 to less than 4 pcf can be achieved. The foams typically have improved tear resistance as compared to previous products prepared from low density polyethylene, at comparable low densities.Type: GrantFiled: December 22, 2003Date of Patent: May 3, 2005Assignee: Sealed Air Corporation (US)Inventors: Nelson E. Malwitz, Natarajan S. Ramesh, Shau-Tarng Lee
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Patent number: 6803416Abstract: The present invention provides a moulding composition, which includes: a plurality of bead polymers dispersed in at least one matrix polymer; wherein the bead polymers: have an average particle size of 5 to 40 &mgr;m, and have a refractive index nD at 20° C. which is different from a refractive index nD at 20° C. of said matrix polymer; and wherein the bead polymers are prepared by a process, which includes: contacting: at least one polymerizable mix which includes at least 50% by weight of at least one (meth)acrylate monomer, at least one aluminum compound, and an aqueous phase, to prepare a mixture; dispersing the mixture at a shear rate ≧103 s−1 to form a dispersion, wherein the dispersion is stabilized by the aluminum compound; and polymerizing to produce the bead polymers having an average particle size of 5 to 40 &mgr;m.Type: GrantFiled: December 28, 2001Date of Patent: October 12, 2004Assignee: Roehm GmbH & Co. KGInventors: Klaus Schultes, Thomas Suefke, Markus Parusel, Werner Hoess
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Patent number: 6777496Abstract: We have developed a process and product which provide thermoplastic articles featuring a permanent outer surface which has selectively varied chemical functionality while maintaining the inherent mechanical properties of the base fiber.Type: GrantFiled: February 7, 2001Date of Patent: August 17, 2004Assignee: Honeywell International Inc.Inventors: Kundan M. Patel, Charles Jay Nelson, Frank Mares, Conor Twomey, Yousef Mohajer
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Patent number: 6770709Abstract: The present invention provides a resin composition comprising: (1) a vinyl copolymer obtained from a starting material containing vinyl monomer (a) which comprises at least one carbonyl group or aldehyde group and vinyl monomer (b) which is different from vinyl monomer (a) and capable of copolymerization; (2) a hydrazide derivative represented by general formula (I): (wherein R1 represents substituted or unsubstituted phenylene, substituted or unsubstituted cyclohexylene or alkylene; and R2 and R3, which may be the same or different, each represent a single bond or alkylene) or a hydrazide derivative in which the amino group(s) of the hydrazide derivative represented by general formula (I) are protected with a low molecular carbonyl compound; and (3) a polyamine compound represented by general formula (II): (wherein R4 represents substituted or unsubstituted phenylene, substituted or unsubstituted cyclohexylene or alkylene; and R5 and R6, which may be the samType: GrantFiled: December 27, 2002Date of Patent: August 3, 2004Assignee: Kyowa Yuka Co., Ltd.Inventors: Yoshio Nakano, Shigeru Murata, Shohei Konishi, Iwao Hotta
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Patent number: 6730740Abstract: The invention pertains to an aqueous cross-linkable polymer composition comprising: W a) a water-soluble first polymer comprising acid groups, which is at least partially neutralized with a volatile base; b) a dispersion of a substantially water-insoluble second polymer, which comprises carbonyl-functional groups, which may be produced by emulsion polymerization in the presence of an aqueous solution of the first polymer; c) a cross-linking agent which can react by condensation with the carbonyl-functional groups of the second polymer; and d) a water-soluble, amine-functional third polymer.Type: GrantFiled: September 24, 1999Date of Patent: May 4, 2004Assignee: Akzo Nobel N.V.Inventors: Dirk Emiel Paula Mestach, Maarten Johannes Jacobus Weber, Genevieve Delaunoit, Wincenty Lambertus Stanislaw Pilaszek
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Patent number: 6699934Abstract: There is provided a resin composition comprising; (A) from 1 to 99% by weight of a copolymer, which comprises an ethylene unit and an &agr;-olefin unit of 3 to 12 carbon atoms, and satisfies the specific requirements (A-1) to (A-4), and (B) from 99 to 1% by weight of a copolymer, which comprises an ethylene unit and a unit of a compound having a carbon-carbon double bond and an oxygen atom, and satisfies the specific requirements (B-1) and (B-2).Type: GrantFiled: August 10, 2001Date of Patent: March 2, 2004Assignee: Sumitomo Chemical Company, LimitedInventors: Kenzo Chikanari, Satoru Koyama, Daigo Nakanishi
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Patent number: 6673870Abstract: A composition of polyolefin, ester additive, and hyperbranched polymer with improved tensile energy-to-break value compared to polyolefins wihtout the hyperbranched polymer. The concentration of the hyperbranched polymers can be between about 0.1% and about 10% by weight of the polyolefins. The polyolefins have a melt flow index of about 14 g/10 min or greater.Type: GrantFiled: May 13, 2002Date of Patent: January 6, 2004Assignee: The Procter & Gamble CompanyInventors: Blair Alex Owens, Nancy Eckert Jackson, Dimitris Ioannis Collias
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Patent number: 6593386Abstract: An expanded cellular ethylenic polymer product is provided from an irradiated, noncross-linked linear ethylenic polymer. Linear ethylenic polymers can be irradiated at ambient conditions sufficient to introduce branching in the polymer in the absence of detectable cross-linking as indicated by the absence of gels. The irradiated linear ethylenic polymer is compatible with highly branched low density polyethylene and, when mixed therewith, produces a resin having a single broad based melting temperature range as determined by direct scanning calorimetry, which indicates that the polymers in the mixture have similar crystallization behavior suitable for producing low density foams by extrusion foaming. The linear polymers can be obtained from recycled shrink wrap film. Low densities of from 0.7 to less than 4 pcf can be achieved. The foams typically have improved tear resistance as compared to previous products prepared from low density polyethylene, at comparable low densities.Type: GrantFiled: September 13, 1999Date of Patent: July 15, 2003Assignee: Sealed Air Corporation (U.S.)Inventors: Nelson E. Malwitz, Natarajan S. Ramesh, Shau-Tarng Lee
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Patent number: 6586521Abstract: Aqueous solutions or dispersions of copolymers A) a process of making them and their use in binder compositions. Copolymers A) containing a hydroxy-functional, hydrophobic copolymer I) containing 30 to 85% by weight of (meth)acrylic acid esters having C1 to C18 hydrocarbon radicals in the alcohol portion, aromatic vinyl compounds and/or vinyl esters and 5 to 45% by weight of hydroxy-functional monomers; a hydroxy- and carboxy-functional, hydrophilic-hydrophobic copolymer II) containing 4 to 20% by weight of (meth)acrylic acid esters having C1 to C18 hydrocarbon radicals in the alcohol portion, aromatic vinyl compounds and/or vinyl esters, 4 to 15% by weight of hydroxy-functional monomers and 0.8 to 3.Type: GrantFiled: March 19, 1999Date of Patent: July 1, 2003Assignee: Bayer AktiengesellschaftInventors: Harald Blum, Wieland Hovestadt, Karl Ludwig Noble
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Patent number: 6512051Abstract: An elastomer composition including an elastomer having a functional group, and a compound having a functional group, in which corresponding functional groups form a cross-link by at least one of an ionic bond, a hydrogen bond, and Diels-Alder reaction with temperatures, i.e., by heating, while the cross-link is cleaved at around room temperature, forming and cleaving of the cross-link being reversible.Type: GrantFiled: January 21, 1999Date of Patent: January 28, 2003Assignee: The Yokohama Rubber Co., Ltd.Inventors: Keisuke Chino, Masahiro Ikawa, Makoto Ashiura
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Publication number: 20020198324Abstract: The invention relates to a process for preparing an impact-modified plastic based on grafted crosslinked rubber particles, and also to an impact-modified plastic obtainable by the process. To prepare the impact-modified plastic, (a) particles of a crosslinked rubber are produced from a first monomer mixture which has a content of at least 50% by weight, preferably at least 90% by weight, particularly preferably at least 98% by weight, of diene compounds. The particles of the crosslinked rubber are (b) grafted with a second monomer or monomer mixture, with formation of a graft shell. Particles of the grafted crosslinked rubber are (c) added to a third monomer mixture, and the monomers of the third monomer mixture (d) are polymerized, with formation of a matrix. The process of the invention is simple to carry out and gives impact-modified plastics with very good mechanical properties.Type: ApplicationFiled: July 26, 2002Publication date: December 26, 2002Inventors: Graham Edmund Mc Kee, Hermann Gausepohl, Norbert Niessner
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Patent number: 6388012Abstract: A thermosetting powder paint composition comprising (A) a resin composition component, (B) a hardener component and (C) a solid flow controlling component, wherein the component (A) contains a resin composition component having reactivity with the component (B), the component (B) contains a hardener having reactivity with the component (A), the component (C) contains a vinyl polymer which is solid at 20° C., and the relation between SPA of the component (A) and SPC of the component (C) satisfies the following numerical formula (1) and the following numerical formula (2) simultaneously. By this constitution, excellent blocking-resistance in storing as the powder paint composition and excellent appearance properties of a paint film formed by coating the powder paint composition can be simultaneously manifested. 8≦SPA≦13 (1) 7≦SPC≦SPA (2).Type: GrantFiled: April 4, 2000Date of Patent: May 14, 2002Assignee: Mitsui Chemicals, Inc.Inventors: Hiroyuki Sakayama, Yoshio Kikuta, Mitsuyuki Mizoguchi, Takahisa Miyawaki, Tsuyoshi Matsumoto
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Publication number: 20020013414Abstract: The present invention is directed to a curable, water-based coating composition utilized in waterbome coating systems. The coating composition is the reaction product of a water-based copolymer prepared by free-radical polymerization, and a cross-linking agent. The copolymer is the reaction product of a first block and a second block. The first block is the reaction product of a first ethylenically unsaturated monomer, acrylic acid, and a second ethylenically unsaturated monomer, methyl methacrylate, as well as the reaction product of a vinylaromatic hydrocarbon monomer, diphenylethylene. The second block is the reaction product of a plurality of ethylenically unsaturated monomers, styrene, 2-ethylhexyl methacrylate, cyclohexyl methacrylate, and carbonate-modified glycidyl methacrylate including a carbonate functional group.Type: ApplicationFiled: December 22, 2000Publication date: January 31, 2002Inventors: Swaminathan Ramesh, Paul Lessek, Wolfgang Bremser
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Publication number: 20010034415Abstract: Impact-modified thermoplastic polymer mixtures comprise copolymers (component A) formed from sulfur dioxide (a1), from vinyl aromatic compounds (a2), from unsaturated polar compounds (a31) selected from the group consisting of compounds of the formula (I) 1Type: ApplicationFiled: December 5, 2000Publication date: October 25, 2001Inventors: Joachim Queisser, Peter Barghoorn, Graham Edmund Mc Kee, Rolf Mulhaupt, Rupert Schnell
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Patent number: 6296947Abstract: A film includes at least one layer comprising a blend of an ethylene polymer having a density of at least 0.925 grams per cubic centimeter, and an ethylene copolymer selected from the group consisting of ethylene/ester copolymer, and ethylene/alpha-olefin copolymer. The film is preferably substantially free from linear low density polyethylene. The film can be a monolayer or multilayer film, and can comprises a core layer comprising an ethylene polymer having a density of at least 0.925 grams per cubic centimeter; and one or more outer layers with the above described blend. At least one intermediate layer comprising an ethylene copolymer having a density of less than 0.925 grams per cubic centimeter can also be included. The film preferably has a thickness of less than 0.60 mils; a shrink force of less than 0.35 pounds in the longitudinal direction, and less than 0.Type: GrantFiled: March 5, 1999Date of Patent: October 2, 2001Assignee: Cryovac, Inc.Inventor: Gautam P. Shah
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Patent number: 6156842Abstract: The present invention pertains to structures and fabricated articles having shape/reshape behavior (and processes for their preparation) comprising;(A) from about 1 to 100 wt % (based on the combined weights of Components A and B) of at least one substantially random interpolymer having an I.sub.2 of 0.1 to about 1,000 g/10 min and an M.sub.w /M.sub.n of from about 1.5 to about 20, which comprises;(1) from about 38 to about 65 mol % of polymer units derived from;(a) at least one vinyl or vinylidene aromatic monomer, or(b) at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, or(c) a combination of at least one aromatic vinyl or vinylidene monomer and at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, and(2) from about 35 to about 62 mol % of polymer units derived from ethylene and/or at least one C.sub.3-20 .alpha.Type: GrantFiled: March 10, 1999Date of Patent: December 5, 2000Assignee: The Dow Chemical CompanyInventors: Stephen M. Hoenig, Robert R. Turley, Yunwa W. Cheung, Martin J. Guest, Charles F. Diehl, Kenneth B. Stewart, John Sneddon
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Patent number: 6156872Abstract: The invention is related to non-linear, paraffin-soluble olefin/carbon monoxide and olefin/acetylene/carbon monoxide copolymers. The invention is also related to a method for preparing olefin/carbon monoxide copolymers by heating a feed of at least one olefin, carbon monoxide, carbon dioxide, hydrogen, and methane in the presence of a free radical polymerization initiator. More particularly, the feed comprises at least one olefin, the total olefin amount ranging from about 5 to about 40 mole %, carbon monoxide in an amount ranging from about 1 to about 40 mole %, hydrogen in an amount ranging from about 4 to about 55 mole %, carbon dioxide in an amount ranging from about 3 to about 10 mole %, and methane in an amount ranging from about 4 to about 85 mole %. The feed may also include acetylene in an amount ranging up to about mole %.Type: GrantFiled: January 19, 1999Date of Patent: December 5, 2000Assignee: Exxon Research and Engineering Co.Inventors: Abhimanyu O. Patil, Donald N. Schulz, Raymond A. Cook, Michael G. Matturro
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Patent number: 6103387Abstract: A thermosetting composition comprises (A) a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, (B) a compound having in the molecule two or more reactive functional groups which can form chemical bonds with the blocked carboxyl groups, and (C) a dispersing component of at least one inorganic oxide sol selected from the group consisting of aluminium oxide sol, silica sol, zirconium oxide sol and antimony oxide sol, and optionally (D) a thermal latent acid catalyst which is activated during curing the composition by heating. A method of coating and a coated article comprise applying the composition. The obtained paint film has excellent weathering resistance, stain resistance, stain-removing property, chemical resistance, moisture resistance and excellent appearance.Type: GrantFiled: June 10, 1997Date of Patent: August 15, 2000Assignee: NOF CorporationInventors: Toshio Yamamoto, Masahiro Sano, Hiroki Mizutani, Keiji Komoto, Masahiro Ishidoya
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Patent number: 6077613Abstract: A sound insulating membrane and processes for forming, particularly well suited for use in floor, ceiling and wall constructions. The membrane comprises at least one backing layer in contact with a layer of nonfoam polymeric material. The polymeric material has an elongation factor of about 500% to about 900% and a Shore A hardness of from about 65 to about 80 points, 5 seconds. In a preferred embodiment, the polymeric material comprises 40-70% chlorinated polyethylene, 20-30% ethylene vinyl acetate, and up to 10% polyvinyl chloride. Floor, ceiling and wall constructions and related methods utilizing the sound insulating membranes are also disclosed.Type: GrantFiled: November 12, 1993Date of Patent: June 20, 2000Assignee: The Noble CompanyInventor: Walter J. Gaffigan
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Patent number: 6054198Abstract: A thermally-conductive interface for conductively cooling a heat-generating electronic component having an associated thermal dissipation member such as a heat sink. The interface is formed as a self-supporting layer of a thermally-conductive material which is form-stable at normal room temperature in a first phase and substantially conformable in a second phase to the interface surfaces of the electronic component and thermal dissipation member. The material has a transition temperature from the first phase to the second phase which is within the operating temperature range of the electronic component.Type: GrantFiled: February 14, 1997Date of Patent: April 25, 2000Assignee: Parker-Hannifin CorporationInventors: Michael H. Bunyan, Miksa de Sorgo
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Patent number: 6030571Abstract: A method of molding which comprises preparing a molding material by compounding a filler and a curable composition, the filler being in an amount of 0 to 800 weight parts based on 100 weight parts of the curable composition and optionally aging the molding material at room temperature or by heating, followed by casting the molding material into a mold and curing the molding material under atmospheric pressure or higher, and articles molded by such method.Type: GrantFiled: May 22, 1997Date of Patent: February 29, 2000Assignee: NOF CorporationInventors: Yoshinori Nakane, Hiroki Mizutani, Hayato Ishibashi, Masahiro Ishidoya
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Patent number: 5907011Abstract: Heterogeneous, solvent- and plasticizer-free polyvinyl ester dispersions which are stabilized by protective colloids and which have a minimum filming temperature of below 10.degree. C. are disclosed. These dispersions are made of a mixture of(a) a homopolymer or copolymer A having a glass transition temperature of above 20.degree. C., whereby homopolymer or copolymer A includes(i) from 85 to 100% by weight of at least one vinyl ester of carboxylic acids having 1 to 18 carbon atoms;(ii) from 0 to 5% by weight of at least one .alpha., .beta.-unsaturated carboxylic acid;(iii) from 0 to 5% by weight of at least one mono-olefinically unsaturated compound (a3) having at least one amino or amido group, and(iv) from 0 to 5% by weight of at least one polyethylenically unsaturated monomer, and(b) a copolymer B having a glass transition temperature of below 20.degree. C.Type: GrantFiled: March 31, 1997Date of Patent: May 25, 1999Assignee: Clariant GmbHInventors: Martin Jakob, Detlev Seip, Volker Matz, Stefan Hess
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Patent number: 5859138Abstract: A polymer blend comprised of a polyketone and linear low density polyethylene (LLDPE). The blend is suitable for use with foodstuffs and liquid hydrocarbons. In a preferred form of the invention, the polyketone has an alternating structure of (a) units derived from carbon monoxide and (b) units derived from one or more olefinically unsaturated compounds.Type: GrantFiled: February 20, 1997Date of Patent: January 12, 1999Assignee: BP Chemicals LimitedInventors: James Graham Bonner, Anthony Keith Powell
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Patent number: 5840806Abstract: Disclosed is a curable resin composition which can be applied for various uses such as top-coating compositions for cars, coating compositions for exterior walls of constructions, heat-resistant coating compositions, adhesives, ink compositions, compositions to be infiltrated into fibers and paper, and surface-treating compositions. The composition comprises (A) a resin obtained by condensation of a polymer having both a hydrolyzable silyl group and a particular functional group except such a hydrolyzable silyl group, and a particular polysiloxane, and (B) a compound capable of reacting with the functional group existing in the resin (A).Type: GrantFiled: January 7, 1997Date of Patent: November 24, 1998Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Shigeru Komazaki, Shinichi Kudo, Masataka Ooka