Solid Polymer Derived From Reactant Containing A Carbonyl Group Other Than As Part Of A Carboxylic Acid Or Derivative Patents (Class 525/220)
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Patent number: 5770318Abstract: Compositions comprising a blend of a MPEP (metallocene catalyzed polyethylene plastomer) and a MPEE (metallocene catalyzed olefin copolymer elastomer); self-adhering film materials made from a blend of these metallocene polymers; and methods of making these self-adhering film materials which are useful for sealing and wrapping applications.Type: GrantFiled: January 13, 1995Date of Patent: June 23, 1998Assignee: Norton Performance Plastics CorporationInventor: Michael Friedman
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Patent number: 5663262Abstract: The present invention relates to compounds containing an oxamic acid group, which show high reactivity and have stability for water and are used as paints, adhesives, and plastic materials etc. in the form of a reaction material or a resin. Since into these compounds an oxamic acid group is introduced in a part of the molecule and the oxamic acid group is an ionic functional group, the compounds show superior solubility and dispersing character in water and also, since the oxamic acid group is a group of a disappearing type with heating, the compounds do not remain, after hardening, in the hardened product. Accordingly, the hardened products obtained from these compounds are superior in water-resistant and anticorrosion properties and in durability.Type: GrantFiled: November 8, 1989Date of Patent: September 2, 1997Assignee: Nippon Paint Co., Ltd.Inventors: Shinsuke Shirakawa, Kazunori Kanda, Mitsuo Yamada, Kei Aoki, Satoshi Urano, Nobuaki Tomita
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Patent number: 5661219Abstract: A curable composition comprising (A) a compound having in the molecule two or more specific blocked carboxyl groups: (B) a compound having in the molecule two or more reactive functional groups which can form chemical bonds with the blocked carboxyl groups, and (C) a catalytic component selected from the following: (a) a thermal latent acid catalyst which comprises a compound having a epoxy group, a specific compound having a sulfur atom and a specific Lewis acid; (b) a thermal latent acid catalyst which comprises a specific compound, having at least one of a nitrogen atom, an oxygen atom, a phosphorus atom or a sulfur atom, a specific compound having a halogen atom and a specific Lewis acid having at least one of an aluminum atom, a zinc atom or a tin atom; or a mixture which comprises (c) a metallic chelate compound and a specific organic silicon compound or a condensate thereof.Type: GrantFiled: August 29, 1994Date of Patent: August 26, 1997Assignee: Nof CorporationInventors: Yoshinori Nakane, Hiroki Mizutani, Hayato Ishibashi, Masahiro Ishidoya
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Patent number: 5660937Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.Type: GrantFiled: March 9, 1995Date of Patent: August 26, 1997Assignee: Nippon Oil And Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
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Patent number: 5578677Abstract: A thermosetting composition which comprises:(D) a self-crosslinking compound having in the molecule (a) one or more functional groups of the formula (2): ##STR1## wherein R.sup.5, R.sup.6 and R.sup.7 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.8 is an organic group of 1 to 18 carbons, Y.sup.2 is oxygen or sulfur, or R.sup.7 and R.sup.8 are bonded with each other to form a heterocyclic structure which comprises Y.sup.2 as the heteroatom component; and (b) one or more reactive functional groups which can form a chemical bond with carboxyl functional groups which are regenerated from (a) by heating; (C) optionally, a thermal latent acid catalyst which is activated during curing of the composition by heating; (A) optionally, a compound having in the molecule two or more functional groups of the formula (1): ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.4 is an organic group of 1 to 18 carbons, Y.sup.1 is oxygen or sulfur, or R.Type: GrantFiled: December 27, 1995Date of Patent: November 26, 1996Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
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Patent number: 5559192Abstract: An air curing polymer composition is disclosed which contains acetoacetate functional polymer and an autoxidizable material. The composition cures on exposure to oxygen. One pack stable ambient curing compositions and a method of stabilizing acetoacetate functional groups to prevent hydrolysis are also disclosed.Type: GrantFiled: June 6, 1995Date of Patent: September 24, 1996Assignee: Rohm and Haas CompanyInventors: Daniel A. Bors, Alvin C. Lavoie, William D. Emmons
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Patent number: 5559187Abstract: This invention is directed to a thermoplastic terpolymer excelling in thermal stability and transparency and possessing high mechanical strength, specifically a thermoplastic copolymer (I) composed of 30 to 70% by weight of (A) an aromatic vinyl compound unit, 4 to 40% by weight of (B) a vinyl cyanide unit, and 26 to 50% by weight of (C) an N-substituted maleimide and characterized by having a narrow distribution of molecular weight divisions of copolymer composition as measured by GPC, having substantially no acetone-insoluble content, possessing a weight average molecular weight in the range of 100,000 to 300,000 and a number average molecular weight in the range of 50,000 to 150,000, and having a residual N-substituted maleimide content of not more than 50 ppm.Type: GrantFiled: December 7, 1993Date of Patent: September 24, 1996Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Katsuaki Maeda, Akihiro Watanabe, Hajime Nishihara
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Patent number: 5549932Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxy group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistant and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.Type: GrantFiled: March 9, 1995Date of Patent: August 27, 1996Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
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Patent number: 5523354Abstract: Crosslinked polymers are prepared by reacting mutually reactive side groups, comprising reacting polymer chains containing carbonyl side groups, optionally protected, and 1,2- or 1,3-diol side groups, optionally protected, in the presence of an acid catalyst, thereby forming crosslinking bridges between polymer chains. Crosslinked polymers are also prepared in which polymer chains are bonded together by a low molecular weight crosslinking agent.Type: GrantFiled: July 20, 1994Date of Patent: June 4, 1996Assignee: Roehm GmbH Chemische FabrikInventors: Marita Kaufmann, Volker Kerscher, Werner Siol, Karl J. Folsch
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Patent number: 5506312Abstract: A polyketone is contacted with an organic peroxyacid in a reactive, oxidization, slurry process to produce a polyester polymer.Type: GrantFiled: May 17, 1995Date of Patent: April 9, 1996Assignee: Exxon Chemical Patents Inc.Inventor: Palanisamy Arjunan
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Patent number: 5462992Abstract: This invention provides curable coating compositions which contain acetoacetylated polymers and carbamylmethylaminotriazine crosslinking agents. Active hydrogen containing materials and cure catalysts can, optionally, be added to the curable compositions made in accordance with this invention. The invention further provides articles of manufacture having at least one substrate coated with a curable composition which contains acetoacetylated polymers and triazine crosslinking agents.Type: GrantFiled: March 31, 1995Date of Patent: October 31, 1995Assignee: PPG Industries, Inc.Inventors: Truman F. Wilt, Deborah E. Hayes, Charles R. Krepley, Daniel E. Rardon
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Patent number: 5457155Abstract: A process for preparing a controlled functional density poly(secondary amine) comprising: (a) contacting a polymer containing olefinic unsaturation with carbon monoxide in hydrogen under hydroformylation conditions in the presence of a hydroformylation catalyst to produce a controlled functional density polyaldehyde containing reactive carbon-carbon double bonds, and (b) contacting the polyaldehyde with hydrogen and a primary amine under reductive amination conditions in the presence of a ruthenium-containing imine hydrogenation catalyst or (b.sup.1) contacting the polyaldehyde with a sterically hindered aliphatic or cycloaliphatic primary amine or an aromatic primary amine under reductive amination conditions in the presence of an alkali metal borohydride to produce poly(secondary amine) having a substantially equivalent ratio of secondary amine groups to reactive carbon-carbon double bonds as the ratio of aldehyde groups to reactive carbon-carbon double bonds in the polyaldehyde.Type: GrantFiled: February 3, 1995Date of Patent: October 10, 1995Assignee: Monsanto CompanyInventors: Martin P. McGrath, Samuel J. Tremont
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Patent number: 5457147Abstract: A process for preparing a controlled functional density poly(secondary amine) comprising: (a) contacting a polymer containing olefinic unsaturation with carbon monoxide in hydrogen under hydroformylation conditions in the presence of a hydroformylation catalyst to produce a controlled functional density polyaldehyde containing reactive carbon-carbon double bonds, and (b) contacting the polyaldehyde with hydrogen and a primary amine under reductive amination conditions in the presence of a ruthenium-containing imine hydrogenation catalyst or (b.sup.1) contacting the polyaldehyde with a sterically hindered aliphatic or cycloaliphatic primary amine or an aromatic primary amine under reductive amination conditions in the presence of an alkali metal borohydride to produce poly(secondary amine) having a substantially equivalent ratio of secondary amine groups to reactive carbon-carbon double bonds as the ratio of aldehyde groups to reactive carbon-carbon double bonds in the polyaldehyde.Type: GrantFiled: February 3, 1995Date of Patent: October 10, 1995Assignee: Monsato CompanyInventors: Martin P. McGrath, Samuel J. Tremont
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Patent number: 5419929Abstract: Thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating, a specific vinyl ether or vinyl thioether and a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule. The thermosetting composition gives cured products having excellent chemical properties, physical properties, weathering resistance and storage stability and is advantageously utilized for coating compositions, ink, adhesive and molded plastics.Type: GrantFiled: September 21, 1992Date of Patent: May 30, 1995Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
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Patent number: 5420204Abstract: Curable compositions comprising (a) a fluorine- or silicon-containing copolymer, (b) a (meth)acrylic copolymer and (c) at least one curing agent are described, each of the two copolymers comprising functional groups which can react with the curing agent, wherein the fluorine- or silicon-containing copolymer comprises a UV absorber which is chemically bound by reaction with the free reactive groups of the copolymer. These copolymer compositions can be used as paint binders.Type: GrantFiled: March 11, 1994Date of Patent: May 30, 1995Assignee: Ciba-Geigy CorporationInventors: Andreas Valet, Roger Meuwly, Mario Slongo
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Patent number: 5391624Abstract: A novel thermosettable composition-of-matter is disclosed. One embodiment of the composition-of-matter includes a polymeric thermosettable ingredient having at least three acetoacetoxy-type functional pendant moieties as well as at least three acid-functional pendant moieties. Another embodiment of the composition-of-matter includes at least two polymeric thermosettable ingredients, one of which includes at least three acid-functional pendant moieties and the other of which includes at least three acetoacetoxy-type functional pendant moieties. The novel composition is characterized in that the acid-functional and acetoacetoxy-type functional pendant moieties crosslinkably-react together, when subjected to elevated-temperature conditions for a predetermined period of time, thereby producing a crosslinked polymeric network. The novel thermosettable composition-of-matter can be used "as is" if either of the polymeric thermosettable components is a "fluid" (i.e., is able to flow) at room temperature.Type: GrantFiled: March 25, 1992Date of Patent: February 21, 1995Assignee: S. C. Johnson & Son, Inc.Inventors: Husam A. A. Rasoul, James R. Beam
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Patent number: 5352740Abstract: Thermosetting composition is excellent in storage stability, useful as one component thermosetting composition, gives cured products having excellent chemical properties, physical properties and weathering resistance and is favorably utilized in coating compositions, ink, adhesive and molded plastics.The thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating and optionally a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.Type: GrantFiled: April 4, 1991Date of Patent: October 4, 1994Assignee: Nippon Oil and Fats Company, LimitedInventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
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Patent number: 5264526Abstract: Light-stabilized acrylonitrile polymer fiber and polyurethane elastomer fiber are made by incorporating a copolymer of 20-80 weight % of a benzophenone compound of the formula: ##STR1## wherein R is hydrogen or methyl and X is --O--, --OCH.sub.2 CH.sub.2 O-- or --OCH.sub.2 CH(OH)CH.sub.2 O--, and 80-20 weight % of an ethylenically unsaturated monomer with an acrylonitrile polymer or a polyurethane elastomer; and a dope of the polymer mixture in an organic solvent is wet-spun into a fiber.Type: GrantFiled: November 20, 1991Date of Patent: November 23, 1993Assignee: Ipposha Oil Industries Co., Ltd.Inventors: Kazuto Kashiwai, Michihira Endoh, Shinichi Kumagae
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Patent number: 5128386Abstract: UV-crosslinkable materials based on (meth)acrylate copolymers contain copolymerized monomers of the general formula I ##STR1## where R is a certain alkyl radical, an aryl radical or a radical R.sup.1 and R.sup.1 is a radical ##STR2## where R.sup.2 to R.sup.6 are each H, alkyl, a non-ortho OH group, OCH.sub.3, OC.sub.2 H.sub.3, SH, SCH.sub.3, Cl, F, CN, COOH, COO(C.sub.1 -C.sub.3 -alkyl), CF.sub.3, N(CH.sub.3).sub.2, N(C.sub.2 H.sub.5).sub.2, N(CH.sub.3)C.sub.6 H.sub.5, .sup.+ N(CH.sub.3).sub.3 X.sup.- or .sup.+N(CH.sub.3).sub.X X.sup.-, where X.sup.- is an acid anion, and one or more of the radicals R.sup.2 to R.sup.Type: GrantFiled: December 15, 1989Date of Patent: July 7, 1992Assignee: BASF AktiengesellschaftInventors: Gerd Rehmer, Andreas Boettchher, Gerhard Auchter
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Patent number: 5077166Abstract: An electrophotographic light-sensitive material comprising a support having provided thereon at least one photoconductive layer containing an inorganic photoconductive substance and a binder resin, wherein the binder resin comprises (A) at least one resin having a weight average molecular weight of from 1.times.10.sup.3 to 2.times.10.sup.4 and containing not less than 30% by weight of a copolymerizable component corresponding to a repeating unit represented by the general formula (I) and from 0.5 to 20% by weight of a copolymerizable component having at least one acidic group selected from the group consisting of --PO.sub.3 H.sub.2, --SO.sub.3 H, --COOH, --OH, ##STR1## and (B) at least one copolymer resin having a weight average molecular weight of from 3.times.10.sup.4 to 1.times.10.sup.6 and containing at least one polyester type macromonomer having a weight average molecular weight of from 1.times.10.sup.3 to 1.5.times.10.sup.4.Type: GrantFiled: June 28, 1990Date of Patent: December 31, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Eiichi Kato, Kazuo Ishii
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Patent number: 5073467Abstract: An electrophotographic photoreceptor comprising a support having provided thereon at least one photoconductive layer containing at least inorganic photoconductive particles and a binder resin, wherein the binder resin comprises(A) at least one resin having a weight average molecular weight of from 1.times.10.sup.3 to 2.times.10.sup.4 with at least one substituent selected from the group consisting of (i) --PO.sub.3 H.sub.2, (ii) --SO.sub.3 H, (iii) --COOH, (iv) ##STR1## and (B) at least one copolymer resin comprising a monofunctional macromonomer and a monomer, said monofunctional macromonomer having a weight average molecular weight of not more than 2.times.10.sup.Type: GrantFiled: October 11, 1989Date of Patent: December 17, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Eiichi Kato, Kazuo Ishii
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Patent number: 5064932Abstract: Novel poly(keto-esters) having carbonyl and oxycarbonyl units randomly combined with linking units derived from olefinic monomers to form an essentially straight-chain polymer backbone are provided. The poly(keto-esters) are produced by converting a portion of the carbonyl functionality of a polyketone to oxycarbonyl groups. The conversion is achieved by reacting the polyketone with an organic peroxyacid in an inert liquid medium at a temperature from -20.degree. C. to 150.degree. C.Type: GrantFiled: March 26, 1990Date of Patent: November 12, 1991Assignee: Quantum Chemical CorporationInventors: Biau-Hung Chang, Lester Y. Lee, Jack Kwiatek
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Patent number: 5061753Abstract: The present invention provides a resin composition comprising:(a) a polyolefin resin in an amount of 20-95% by weight,(b) a polyphenylene ether resin in an amount of 80-5% by weight,(c) a partially hydrogenated alkenyl aromatic compound-isoprene block copolymer in an amount of 3-45 parts by weight based on totally 100 parts by weight of the components (a) and (b), and(d) an ethylene-.alpha.-olefin copolymer elastomer modified by grafting thereon a graft monomer such as an unsaturated monocarboxylic acid or a derivative thereof, an unsaturated dicarboxylic acid or a derivative thereof, a styrene compound, or an unsaturated epoxy compound or an .alpha.-olefin-alkyl (meth)acrylate copolymer such as a copolymer of an .alpha.-olefin of 2-6 carbon atoms and an alkyl (meth)acrylate having an alkyl group of 1-8 carbon atoms in an amount of 3-45 parts by weight based on totally 100 parts by weight of the components (a) and (b).Type: GrantFiled: March 19, 1990Date of Patent: October 29, 1991Assignee: Sumitomo Chemical Company, Ltd.Inventors: Takashi Maruyama, Tukio Mizuno
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Patent number: 4871810Abstract: Partially grafted flexible thermoplastic compositions formed by melt blending under high shear, a thermoplastic material which does not contain available graft sites, said thermoplastic material being at least one continuous phase of the composition, an ethylene copolymer containing an unsaturated mono-carboxylic acid, and a polymeric grafting agent having reactive groups capable of reacting with the mono-carboxylic acid in the ethylene copolymer and with the available graft sites in the thermoplastic material.Type: GrantFiled: November 13, 1987Date of Patent: October 3, 1989Assignee: E. I. Du Pont de Nemours and CompanyInventor: Robert P. Saltman
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Patent number: 4621118Abstract: Guayule resin is sulfurized such that it has a high softening point of at least 70.degree. C. The sulfurized guayule resin can be utilized in association with conventional rubbers and the end results in improved properties such as reduced hysteresis loss, increased tensile strength and the like.Type: GrantFiled: March 21, 1985Date of Patent: November 4, 1986Assignee: The Firestone Tire & Rubber CompanyInventors: William W. Schloman, Jr., James A. Davis
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Patent number: 4605441Abstract: An ink composition for indicating progress and completion of vulcanization of rubber articles comprising, per 100 parts by weight of the composition,(i) 0.01 to 10 parts by weight of at least one methine dye,(ii) 1 to 40 parts by weight of at least one member selected from the group consisting of rosin, rosin derivative, petroleum resin, phenol resin, xylene resin, alkyd resin, cumarone-indene resin, acrylic resin, epoxy resin, ketone resin and styrene-maleic acid resin,(iii) 0.5 to 50 parts by weight of at least one high molecular weight component selected from the group consisting of cellulose resin, polyvinyl butyral, vinyl chloride-vinyl acetate copolymer, ethylene-vinyl acetate copolymer, polyamide, synthetic rubber and natural rubber,(iv) 30 to 80 parts by weight of at least one organic solvent capable of dissolving the components (ii) and (iii), and(v) 0.1 to 50 parts by weight of at least one halogenated organic acid.Type: GrantFiled: August 23, 1984Date of Patent: August 12, 1986Assignee: Sakura Color Products CorporationInventors: Yoshiaki Masuda, Hidetoshi Fukuo, Masaji Yamamoto
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Patent number: 4559382Abstract: Poly(vinyl chloride) resin compositions containing an ethylenically-unsaturated compound having carbonylamino or thiocarbonylamino groups. These compositions are readily convertible at low temperatures to crosslinked polymers and are radiation-curable to dimensionally stable articles and films that are clear and that do not exude oily materials.Type: GrantFiled: June 6, 1983Date of Patent: December 17, 1985Assignee: Minnesota Mining and Manufacturing CompanyInventors: John A. Martens, Brian H. Williams
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Patent number: 4440909Abstract: Disclosed are polymer blends of bis(allyl carbonate) polymers with polymers of olefinically unsaturated monomers, and the precursor blends of bis(allyl carbonate) monomers with polymers of olefinically unsaturated monomers, and fabricable resins prepared therefrom. Also disclosed is a method of fabricating, e.g., molding, injection molding, extruding, and the like, the fabricable resins. The bis(allyl carbonate) polymer blend is taken to a fabricable state, i.e., a fusible pseudoplastic that does not lose liquid on fabrication, either by admixture or admixture and reaction. The fabricable resin is then fabricated, e.g., extruded, molded, or the like, and then polymerized to a hard polymer. Also disclosed are blends of bis(allyl carbonates), monomeric and polymeric, with polymers having olefinic unsaturation.Type: GrantFiled: January 27, 1982Date of Patent: April 3, 1984Assignee: PPG Industries, Inc.Inventors: John C. Crano, Ronald L. Haynes
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Patent number: 4346197Abstract: Disclosed are polymer blends of bis(allyl carbonate) polymers with polymers of olefinically unsaturated monomers, and the precursor blends of bis(allyl carbonate) monomers with polymers of olefinically unsaturated monomers, and fabricable resins prepared therefrom. Also disclosed is a method of fabricating, e.g., molding, injection molding, extruding, and the like, the fabricable resins. The bis(allyl carbonate) polymer blend is taken to a fabricable state, i.e., a fusible pseudoplastic that does not lose liquid on fabrication, either by admixture or admixture and reaction. The fabricable resin is then fabricated, e.g., extruded, molded, or the like, and then polymerized to a hard polymer. Also disclosed are blends of bis(allyl carbonates), monomeric and polymeric, with polymers having olefinic unsaturation.Type: GrantFiled: December 22, 1980Date of Patent: August 24, 1982Assignee: PPG Industries, Inc.Inventors: John C. Crano, Ronald L. Haynes
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Patent number: 4254013Abstract: The green strength of elastomer blends of natural or synthetic cis-1,4-polyisoprene and synthetic elastomers is improved by adding to the chain of the synthetic elastomer an ionogenic compound. The said ionogenic compound can be incorporated into the chain of the synthetic elastomer through conventional polymerization with the monomers forming the synthetic elastomer, and the ionogenic group of the compound will be pendant from the chain or backbone of the elastomer. The ionogenic group is combined with a readily ionogenic metal base or salt. This combination yields blends which have greatly improved green strength as compared to rubber blends known to the art.Type: GrantFiled: March 15, 1979Date of Patent: March 3, 1981Assignee: The Goodyear Tire & Rubber CompanyInventors: Emil M. Friedman, Richard G. Bauer
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Patent number: 4210565Abstract: Ambient or low-temperature curable solutions or aqueous dispersions of (1) a polymer containing units polymerized from a monomer mixture of (a) from about 0.25% to about 30% by weight of a polymerizable aldehyde, and (b) at least one copolymerizable mono-ethylenically unsaturated monomer, with (2) a curing agent selected from the group of dicarboxylic acid bis-hydrazides, dicarboxylic acid bis-hydrazones, and acrylic oligomers and low molecular weight acrylic solution polymers containing a plurality of pendant hydrazide or hydrazone groups. The solutions or dispersions are useful as general industrial coatings, maintenance coatings, furniture and appliance coatings, heavy transportation coatings, automobile refinishes and plastics coatings.Type: GrantFiled: February 2, 1979Date of Patent: July 1, 1980Assignee: Rohm and Haas CompanyInventor: William D. Emmons
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Patent number: 4195107Abstract: Plastic tile or similar items are disclosed having an adhesive backing suitable for adhesion to walls. The tiles are formulated from a vinyl chloride based resin and filler, and include a plasticizer of the formula: ##STR1## which R is a lower alkyl radical and R' is an aryl, aralkyl, or an alkaryl radical. A hot melt type pressure sensitive adhesive coating is provided on the plastic tile, the coating comprising a vinylic copolymer made of a minor portion of styrene units or derivatives thereof, and a major portion of butadiene, isoprene, or other similar units.Type: GrantFiled: April 26, 1978Date of Patent: March 25, 1980Assignee: GAF CorporationInventor: Walter C. Timm