Ester Contains At Least Two Carboxylic Acid Ester Groups Patents (Class 525/225)
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Patent number: 11214640Abstract: A multi-stage emulsion processing aid polymer comprising one or more functionalized ethylenically unsaturated monomer into the emulsion polymerization reactor, wherein the functionality is selected from the group consisting of ?-keto esters, ?-keto amides, ?-diketones, cyanoacetic esters, malonates, nitroalkanes, ?-nitro esters, sulfonazides, thiols, thiol-s-triazines, and amine, where the functionality is incorporated into polymers by polymerizing, ethylenically unsaturated monomers containing these functionalities or by post functionalization of a polymer with additional reactions after polymerization in one of the first or second stages. Foamable halogenated polymers comprising the multi-stage emulsion processing aid polymer is also provided. Also provided are methods for making the multi-stage emulsion processing aid polymer and foamable halogenated polymers.Type: GrantFiled: February 3, 2016Date of Patent: January 4, 2022Assignee: Rohm and Haas CompanyInventors: Paul R. Van Rheenen, Steven J. Broadwater
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Patent number: 10927245Abstract: The present invention relates to polymers functionalized with non-migratory internal plasticizers.Type: GrantFiled: February 1, 2019Date of Patent: February 23, 2021Assignee: The Regents of the University of CaliforniaInventors: Rebecca L. Braslau, Chad M. Higa
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Patent number: 9029476Abstract: A composition comprising: a blended product of: a matrix polymer; and from 0.05 to 2.5 wt % diffuser polymeric particles, wherein the diffuser polymeric particles are characterized by an average diameter from 2.0 to 8 micrometers, a particle size distribution such that at least 90 wt % of the polymer particles fall within ±30% of the volume average particle size, a refractive index, RI, from 1.50 to 1.55; a crosslinking level great than 4%; and wherein the diffuser polymeric particles are produced using at least one alkyl(meth)acrylate monomer copolymerized with from 5 wt % to 25 wt % crosslinking monomer selected from the group consisting of aliphatic crosslinking monomers, aromatic crosslinking monomers, and combinations thereof, and optionally, one or more comonomers selected from the group consisting of aryl(meth)acrylate monomers and monovinyl arenes is provided.Type: GrantFiled: March 26, 2013Date of Patent: May 12, 2015Assignee: Rohm and Haas CompanyInventors: Hailan Guo, Eric G. Lundquist, Luu Le
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Publication number: 20150059604Abstract: A resin composition for laser engraving that comprises (Component A) a resin that is a plastomer at 20° C., (Component B) a polymerizable compound, and (Component C) a polymerization initiator, wherein Component A has a constitutional repeating unit having an acid group, and the content of the constitutional repeating unit having an acid group is 0.01 to 15 mass % relative to a total mass of Component A. A flexographic printing plate precursor that has a relief-forming layer formed of the resin composition for laser engraving on a support, and a flexographic printing plate precursor that has a crosslinked relief-forming layer obtained by crosslinking a relief-forming layer formed of the resin composition for laser engraving by heat and/or light.Type: ApplicationFiled: August 13, 2014Publication date: March 5, 2015Applicant: FUJIFILM CORPORATIONInventor: Kazuhiro HAMADA
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Patent number: 8609776Abstract: An ethylenically unsaturated prepolymer comprising an ending X which reacts by condensation being a hydroxyl and/or amine or free isocyanate group and optionally an ending X? having ethylenic unsaturation, the prepolymer being the reaction product of a first component A comprising a mixture of i) a first ethylenically unsaturated resin carrying specific hydroxyl and/or amine reactive endings, and/or ii) optionally a second resin different from resin i), being an ethylenically unsaturated hydroxylated resin and/or a hydroxylated and/or aminated saturated resin, and/or iii) optionally a third reactive saturated resin, iv) optionally an unsaturated monoalcohol up to 30% in equivalents of the OH+NH2 total, and a second component B comprising a polyisocyanate with a functionality equal to 2 or greater than 2, A and B being in proportions to effectively avoid any gelling by crosslinking.Type: GrantFiled: July 4, 2007Date of Patent: December 17, 2013Assignee: CCP CompositesInventors: Patrick Belliard, Jérôme Mazajczyk, Roland Delory, Guillaume Cledat, Francis Verdiere, Serge Herman
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Publication number: 20130211009Abstract: The present invention relates to polyethylene compositions comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, in particular, this invention further relates to polyethylene blends comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, wherein the modifier has: 1) a g?vis value less than 0.75; 2) at least 0.6 ppm ester groups as determined by 1H NMR; 3) a Tm of 100° C. or more; 4) an Mw of 50,000 g/mol or more, as determined by GPC; 5) an average number of carbon atoms between branch points of 70 or more as determined by 1H NMR.Type: ApplicationFiled: August 13, 2012Publication date: August 15, 2013Inventors: Yong YANG, Pradeep P. Shirodkar, Jianya Cheng, Andy H. Tsou, Arnold Lustiger, Johannes M. Soulages
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Publication number: 20120214945Abstract: A cross-linkable nitrile rubber composition obtained by mixing a master batch (B) which contains a nitrile copolymer rubber (b1) having an iodine value of 120 or less and an aromatic polyvalent amine cross-linking agent (b2) into a carboxyl group-containing nitrile copolymer rubber (A) having an iodine value of 120 or less and a cross-linked product obtained by cross-linking the same are provided.Type: ApplicationFiled: October 19, 2010Publication date: August 23, 2012Inventor: Nobuyoshi Emori
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Publication number: 20120139143Abstract: A plasticizing agent and a composition for fabricating a polyacrylonitrile-based fiber precursor and a fabrication method of a polyacrylonitrile-based carbon fiber are provided. The plasticizing agent includes a copolymer represented by formula (I) or a derivative of formula (I): wherein R is methyl or ethyl, z?0.5 mol %, and y=99.5-85.0 mol %. The plasticizing agent has an intrinsic viscosity of between 0.20-0.40 dL/g. The composition for fabricating the polyacrylonitrile-based fiber precursor includes the plasticizing agent and a polyacrylonitrile-based copolymer having an intrinsic viscosity of between 0.41-0.75 dL/g.Type: ApplicationFiled: April 5, 2011Publication date: June 7, 2012Applicant: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Tun-Fun Way, Kai-Jen Hsiao, Shi-Kuang Hwang, Jiun-Jy Chen, Hsiao-Chuan Chang, Yu-Ting Chen
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Patent number: 7960454Abstract: The invention provides for processes to produce elastomeric compositions, the processes including contacting at least one elastomer with a processing aid, wherein the processing aid comprises at least one functionalized polymer having at least one anhydride group. The invention also provides for articles such as innerliners for tires produced from the aforementioned elastomeric compositions.Type: GrantFiled: December 16, 2005Date of Patent: June 14, 2011Assignee: ExxonMobil Chemical Patents Inc.Inventors: Walter Harvey Waddell, David Yen-Lung Chung, Robert Christopher Napier, Donald Sheley Tracey, Dirk Frans Rouckhout
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Publication number: 20100320636Abstract: A thermoplastic resin composition comprising (i) 55 to 95 parts by weight of a thermoplastic resin, and (ii) 5 to 45 parts by weight of a fiber containing 10 to 100% by weight of a diameter-varying fiber which has an enlarged diameter at its one or both ends; and a production process thereof comprising the steps of (1) cutting a continuous fiber under the condition that its cutting spot is heated to its melting temperature or higher, thereby preparing a diameter-varying fiber, and (2) melt-kneading a mixture containing the diameter-varying fiber and a thermoplastic resin.Type: ApplicationFiled: June 9, 2010Publication date: December 23, 2010Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Kenji ATARASHI
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Publication number: 20100298500Abstract: Disclosed is a polyolefin-based adhesive. The adhesive comprises a maleated polyolefin. The maleated polyolefin is let-down in a linear low density polyethylene (LLDPE). The let-down LLDPE is selected from those which have a melt index MI2 within the range of 0.1 dg/min to 5 dg/min, preferably from 1 dg/min to 3 dg/min, and comprises a TREF soluble fraction having an intrinsic viscosity less than 0.9 dl/g. The adhesive composition can be used in multilayer polyolefin films and multilayer pipes.Type: ApplicationFiled: May 22, 2009Publication date: November 25, 2010Inventors: Chun D. Lee, Charles S. Holland, Maged G. Botros
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Publication number: 20100222514Abstract: The present invention provides a recycled building material such as roof/Geo membrane that comprises (i) a polyolefin, (ii) a polymer containing a carboxyl group or a hydroxyl group, and (iii) a compatabilizer for the components (i) and (ii) which contains an epoxy group or an anhydride group. The present invention also provides a method of recycling building material as well as an article of manufacture such as a TPO membrane using the recycled building material. The TPO membrane has gained better physical properties such as consistent product quality, tensile strength, tear strength, wind resistance, and avoidance of tedious screening processes, among others.Type: ApplicationFiled: May 18, 2010Publication date: September 2, 2010Inventor: L. Richard PENG
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Publication number: 20100167016Abstract: A polyester film for molded part having low strain stress in processing, thermoforming in a target shape is easy and appearance is excellent even when a metallic thin membrane is provided. A polyester film for molded part includes a film having a polyester resin composition mixed with a resin (A) of polyethylene terephthalate and a resin (B) of polyester selected from the group consisting of a polybutylene terephthalate resin and a polytrimethylene terephthalate resin where a resin (A) is 10 to 90% by mass and a resin (B) is 90 to 10% by mass based on the total of resin (A) and resin (B), wherein the resin (B) of polyester comprises a resin (B1) of polybutylene terephthalate and a resin (B2) of polytrimethylene terephthalate being mixed such that a resin (B1) is 10 to 90% by mass and a resin (B2) is 90 to 10% by mass based on the total of resin (B1) and resin (B2), and a ratio (D/H) of a half bandwidth D (° C.Type: ApplicationFiled: February 15, 2007Publication date: July 1, 2010Applicant: Toray Industries, Inc.Inventors: Isao Manabe, Ryosuke Matsui, Masahiro Kimura
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Publication number: 20100152309Abstract: In one aspect, the invention relates to recycled polyethylene terephthalate compositions, fibers and articles produced therefrom, and methods for producing same. In a further aspect, the invention relates to homogenized post-consumer polyethylene terephthalate. In a further aspect, the invention relates to extruded polymer compositions, polymer mixtures, fibers, and/or Bulked Continuous Filament fibers comprising post-consumer polyethylene terephthalate. In a further aspect, the invention relates to processes for preparing recycled polyethylene terephthalate compositions. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present invention.Type: ApplicationFiled: September 30, 2009Publication date: June 17, 2010Inventors: Hubert J. Booth, Christopher Eric Bradley, Daniel Ray Johnson, James Henry Keen, JR.
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Publication number: 20100140164Abstract: Use of a material comprising a first polylactic acid and a first non-polylactic acid polyester as a filter base material (2) for a fluid cleaning filter. Furthermore, a method for fabricating a filter base material (2) as well as a filter base material (2) obtainable by the method and a filter comprising the filter base material (2) are provided.Type: ApplicationFiled: May 15, 2008Publication date: June 10, 2010Applicant: DINAIR DEVELOPMENT ABInventors: Björn Claeson, Bo Ekman, Sidsel Kristiansen, Patrik Ödling
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Publication number: 20100099822Abstract: A method comprising contacting at least one conventional elastomer, at least one singlet oxygen functionalized elastomer (SOFE), and a styrene monomer in a reaction zone under conditions suitable for the formation of a styrenic polymer composition. A method comprising contacting a reaction mixture comprising styrene, polybutadiene, and a photoperoxidized polybutadiene in a reaction zone under conditions suitable for the formation of a polymeric composition, wherein the elastomer particle size distribution in the polymeric composition does not linearly correlate with the elastomer particle size distribution in the reaction mixture. A reactor blended polymer comprising styrene, a conventional elastomer, and a singlet oxygen functionalized elastomer.Type: ApplicationFiled: October 22, 2008Publication date: April 22, 2010Applicant: Fina Technology, Inc.Inventor: Olga Khabashesku
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Publication number: 20100016509Abstract: An object of the present invention is to provide a novel method for producing a vinyl polymer (P) having a polar functional group (X) and having in its main chain a branched structure. The object can be achieved by the present invention providing a method for producing a vinyl polymer (P) having a polar functional group (X) and having in its main chain a branched structure, wherein while and/or after polymerization of a vinyl polymer (I) having a protecting group (Y) and having at its molecular terminal a group (A) containing carbon-carbon double bond, the protecting group (Y) is converted to the polar functional group (X).Type: ApplicationFiled: August 16, 2007Publication date: January 21, 2010Applicant: Kaneka CoorporationInventors: Nao Fujita, Shinichi Sakashita, Yoshiki Nakagawa
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Patent number: 7638582Abstract: The present invention relates to a thermoformable sheet, for example, an acrylic sheet, comprising particles proximate to the top surface, wherein the textured sheet, when thermoformed, provides a low-gloss, textured surface that is less sensitive to marring, blemishes (including blemishes resulting from the mold), household wear and tear, and visibly reduces the appearance of oil deposits on its surface.Type: GrantFiled: October 29, 2003Date of Patent: December 29, 2009Assignee: Lucite International, Inc.Inventors: Fareeduddin Farooq, Andrew H. Janowicz, James R. Leach, Philip A. Janowicz
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Publication number: 20090275678Abstract: A thermoplastic resin composition and a molded article thereof, respectively excellent in flowability and mechanical properties, and, in a preferred mode, also excellent in low warping property, laser transmittance and laser weldability, is obtained by mixing (B) 0.1 to 4 parts by weight of a polyfunctional compound having three or more functional groups, in which at least one of the terminal structures having the functional groups is a structure containing alkylene oxide units, with (A) 100 parts by weight of a thermoplastic resin, and further provides a molded particle thereof. It is preferred that the (A) thermoplastic resin is one or more selected from a polyester resin and polycarbonate resin.Type: ApplicationFiled: June 27, 2007Publication date: November 5, 2009Inventors: Sadanori Kumazawa, Hiroyuki Ohme, Yuki Amano, Takamusa Owaki
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Publication number: 20090227739Abstract: The present invention is a composition useful as an impact modifier for polyamide compositions. In one embodiment, impact modifiers of the present invention are ethylene maleic anhydride copolymers having at least 3% maleic anhydride functionality. Compositions comprising copolymers of ethylene and maleic anhydride or its functional equivalents and ethylene copolymers with polar comonomers are disclosed. The compositions provide miscible blends and exhibit improved properties, such as increased temperature resistance and mechanical strength, compared to pure ethylene copolymers with polar comonomers.Type: ApplicationFiled: May 13, 2009Publication date: September 10, 2009Applicant: E. I. DU PONT DE NEMOURS AND COMPANYInventor: RICHARD T. CHOU
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Publication number: 20090149604Abstract: This invention relates to a composition comprising a functionalized C3 to C40 olefin polymer comprising at least 50 mol % of one or more C3 to C40 olefins, and where the olefin polymer, prior to functionalization, has: a) a Dot T-Peel of 1 Newton or more on Kraft paper; b) an Mw of 10,000 to 100,000; and c) a branching index (g?) of 0.98 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 60,000, or a branching index (g?) of 0.95 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 100,000; and where the C3 to C40 olefin polymer comprises at least 0.001 weight % of an functional group, preferably maleic anhydride. This invention further relates to blends of such functionalized polymers with other polymers including non-functionalized C3 to C40 olefin polymers as described above.Type: ApplicationFiled: February 13, 2009Publication date: June 11, 2009Inventors: Ramin Abhari, Charles Lewis Sims, Mun Fu Tse, Patrick Brant, Peijun Jiang, David Raymond Johnsrud
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Publication number: 20090076181Abstract: The present invention describes the synthesis of solvent soluble copolymers containing multiple unsaturations. These copolymers contain reactive vinyl groups, which can be further reacted in a second stage polymerization. The process involves copolymerization of a vinyl monomer with an inclusion complex of a monomer having multiple unsaturations and a cyclic macromolecular compound to yield soluble polymers. These polymers may be cast into films, membranes or may be converted in micro or nanoparticles and then crosslinked in a second step polymerization.Type: ApplicationFiled: October 24, 2008Publication date: March 19, 2009Applicant: COUNCIL OF SCIENTIFIC AND INDUSTRIAL RESInventors: Mohan G. KULKARNI, Rohini N. Karmalkar, Sunita S. Satav
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Publication number: 20090075543Abstract: The present invention relates to malleable polymer monofilaments that show shape malleability under heat and stress. The monofilaments can be used in closely woven industrial fabrics, especially in paper machine fabrics, as weft materials that protect load bearing warp yarns for better wear resistance.Type: ApplicationFiled: September 17, 2007Publication date: March 19, 2009Applicant: VOITH PATENT GmbHInventors: Heping Zhang, Craig Valentine, Matthias Hoehsl
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Publication number: 20080306217Abstract: The invention provides a comprising one or more ethylene interpolymers, and wherein the interpolymers, or the composition, has a melt viscosity from 1 to 30,000 cP at 177° C., and wherein at least one ethylene interpolymer has an Rv from 0.3 to 0.99. The invention further provides a composition comprising at least one low molecular weight (LMW) ethylene interpolymer, and at least one high molecular weight (HMW) ethylene interpolymer, and wherein the composition has a melt viscosity from 1 to 30,000 cP at 177° C., and wherein the sum of the Rv from the low molecular weight interpolymer and the high molecular weight interpolymer is from 0.3 to 2. The invention further provides for processes of making such compositions, processes for functionalizing the interpolymer(s) of such compositions, and articles comprising at least one component prepared from an inventive composition.Type: ApplicationFiled: December 12, 2006Publication date: December 11, 2008Inventors: Teresa P. Karjala, Selim Yalvac, Cynthia L. Rickey, Sylvie Desjardins, Marc A. Springs
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Publication number: 20080281021Abstract: The invention provides for processes to produce elastomeric compositions, the processes including contacting at least one elastomer with a processing aid, wherein the processing aid comprises at least one functionalized polymer having at least one anhydride group. The invention also provides for articles such as innerliners for tires produced from the aforementioned elastomeric compositions.Type: ApplicationFiled: December 16, 2005Publication date: November 13, 2008Applicant: EXXONMOBIL CHEMICAL PATNES INC.Inventors: Walter Harvey Waddell, David Yen-Lung Chung, Robert Christopher Napier, Donald Sheley Tracey, Dirk Frans Rouckhout
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Patent number: 7317043Abstract: There is disclosed an impact modifier which comprises a graft copolymer comprising a rubber polymer (A) obtained from a mixture of one or more kinds of (meth)acrylic monomers as major ingredients, having a glass transfer temperature of 0° C. or lower, and forming particles having each of 80 wt % or more of them has a particle diameter within the range of 400 to 1,000 nm as determined from a particle diameter distribution on a weight basis, and branches (B) grafted thereto obtained from one or more kinds of vinyl monomers; a process for producing thereof; and a thermoplastic resin composition containing the impact modifier.Type: GrantFiled: February 26, 2003Date of Patent: January 8, 2008Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Keiji Nakamura, Kimihiko Hattori, Masahiro Osuka
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Patent number: 7271220Abstract: The present invention relates to a masterbatch composition which contains a polyolefin base resin, polymethylmethacrylate (PMMA) pearls and a further polymeric compound obtained at least from olefinic monomers, olefinic monomers containing an ester functionality and olefinic monomers containing an ether functionality, as well as to the masterbatches obtained from this composition. The present invention is further directed to monolayer as well as multilayer films which are made using the inventive masterbatches, their methods of production and the use of said films for packaging purposes.Type: GrantFiled: August 9, 2004Date of Patent: September 18, 2007Assignee: A. Schulman Plastics N.V.Inventors: Marcel Janssens, Tony Daponte
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Patent number: 7250472Abstract: Acrylic compositions which can be processed into thermoformable acrylic sheet material with variegated non-homogeneous granite appearance are disclosed. The acrylic compositions comprise a matrix of polymethyl methacrylate having dispersed within it particles of a thermoplastic such as polymethyl methacrylate and one or more comonomers wherein the thermoplastic is in the shape of thin wafers 0.05 to 9.53 mm thick, 0.18 to 12.8 wide and 0.18 to 7.62 mm long.Type: GrantFiled: October 25, 1999Date of Patent: July 31, 2007Assignee: Lucite International, Inc.Inventors: Fareeduddin Farooq, James Leach, Michael R. Turbeville, Andrew H. Janowicz, Richard D. Redfearn
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Patent number: 6887940Abstract: A compatible blend of an engineering thermoplastic such as a polyamide and an olefin polymer material is prepared by (1) making an oxidized olefin polymer material containing carboxylic acid groups or derivatives thereof, (2) extruding a mixture of (a) the oxidized olefin polymer material from step (1), (b) an engineering thermoplastic, (c) optionally, an inorganic base, and (d) optionally, a non-oxidized olefin polymer material, and (3) recovering a blend of the engineering thermoplastic, the oxidized olefin polymer material or an ionomer thereof, which acts as a compatibilizer, and, optionally, the non-oxidized olefin polymer material. The oxidized olefin polymer material can be made by treating the olefin polymer material with an organic peroxide initiator while adding a controlled amount of oxygen.Type: GrantFiled: November 27, 2002Date of Patent: May 3, 2005Assignee: Basell Poliolefine Italia S.p.A.Inventors: Vu A. Dang, Dinshong Dong, Tam T. M. Phan, Cheng Q. Song
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Patent number: 6825278Abstract: A modified pressure sensitive adhesive (PSA) is produced by polymerizing at least one ethylenically unsaturated monomer to form a base polymer and reacting the base polymer with a modifying polymer comprising units derived from a n-vinyl lactam to thereby produce a modified polymer. The modified polymer can be used to form modified PSAs having improved adhesion properties over PSAs formed from the unmodified base polymer.Type: GrantFiled: January 16, 2003Date of Patent: November 30, 2004Assignee: Resolution Specialty Materials LLCInventors: Pavel Holub, Edita Moudra, Olga Bernatova, Jiri Horalek, Jiri Havranek
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Patent number: 6759481Abstract: A shape memory polymer which is a reaction product of styrene, a vinyl compound, a multifunctional crosslinking agent and an initiator. The shape memory polymer has particular application as a contact lens mold.Type: GrantFiled: January 24, 2002Date of Patent: July 6, 2004Inventor: Tat Hung Tong
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Patent number: 6699934Abstract: There is provided a resin composition comprising; (A) from 1 to 99% by weight of a copolymer, which comprises an ethylene unit and an &agr;-olefin unit of 3 to 12 carbon atoms, and satisfies the specific requirements (A-1) to (A-4), and (B) from 99 to 1% by weight of a copolymer, which comprises an ethylene unit and a unit of a compound having a carbon-carbon double bond and an oxygen atom, and satisfies the specific requirements (B-1) and (B-2).Type: GrantFiled: August 10, 2001Date of Patent: March 2, 2004Assignee: Sumitomo Chemical Company, LimitedInventors: Kenzo Chikanari, Satoru Koyama, Daigo Nakanishi
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Patent number: 6669953Abstract: Cross-linked block copolymers are disclosed which have drug retention properties, comprising hard and soft segments, with cross-linking between the soft segments. The block copolymers can be based upon (meth)acrylic monomers, and some possess adhesive properties.Type: GrantFiled: May 8, 2000Date of Patent: December 30, 2003Assignee: Strakan LimitedInventor: Fumio Kamiyama
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Patent number: 6646045Abstract: Thermoplastic molding compositions containing graft polymers produced with different initiator systems are disclosed. The compositions are distinguished by a combination of good toughness and reduced opacity. As a result, appreciably smaller quantities of pigment are needed to color the molding composition.Type: GrantFiled: November 30, 2001Date of Patent: November 11, 2003Assignee: Bayer AktiengesellschaftInventor: Herbert Eichenauer
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Patent number: 6638589Abstract: The invention relates to a method and apparatus for using recycled plastic material, and to a plastic product produced by an extruder. In the invention, crosslinked polyethylene is ground to powder form and mixed with e.g. polyethylene so that the proportion of the crosslinked polyethylene in the mixture is less than 30%. The mixture is supplied through an extruder (2) for making an extruded plastic product. In this way, crosslinked polyethylene can be recycled in a cost-effective and simple manner, while producing a plastic product that contains recycled crosslinked polyethylene.Type: GrantFiled: December 1, 1997Date of Patent: October 28, 2003Assignee: Uponor Innovation ABInventor: Jyri Järvenkylä
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Patent number: 6573330Abstract: A process for preparing a water-absorbent resin is provided which enables the water-absorbent resin to ensure the reduction in the release amount of liquid and the increase in the liquid diffusibility. In the preparation process, the water-absorbent resin is prepared by polymerization of a water-soluble ethylenic unsaturated monomer. The polymerization of the water-soluble ethylenic unsaturated monomer is allowed to take place in the presence of a water-absorbent resin having a water-absorbing rate different from that of a water-absorbent resin resulting from polymerization of the water-soluble ethylenic unsaturated monomer. In a preferred mode, the polymerization is performed by a reversed-phase suspension polymerization method.Type: GrantFiled: December 10, 1998Date of Patent: June 3, 2003Assignee: Sumitomo Seika Chemicals, Co., Ltd.Inventors: Masato Fujikake, Yasuhiro Nawata, Magoto Shirakawa, Masakazu Yamamori, Shioko Yoshinaka, Morio Nakamura
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Patent number: 6565616Abstract: The invention relates to blends of copolymers containing structural units of olefins, derivatives of dibasic carboxylic acids and, if required, polyolefins and, structural units of ethylene and vinyl esters of tertiary carboxylic acids, and their use as additives to fuel oils for improving their cold flow properties.Type: GrantFiled: March 14, 2001Date of Patent: May 20, 2003Assignee: Clariant GmbHInventors: Matthias Krull, Thomas Volkmer, Werner Reimann
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Patent number: 6465581Abstract: This invention relates to use of stabilized unsymmetrical coupling agents for use in conjugated diene-based rubber compositions reinforced with silica-based reinforcement, namely use of stabilized 2-benzothiazyl-3-(triethoxysilylpropyl) disulfide and 3-(triethoxysilyl)propyl-N-maleamic acid. Said stabilized unsymmetrical coupling agent materials may be provided for mixing with said diene-based rubber(s), for example, as individual materials, as at least one of said materials being pre-reacted with aggregates of precipitated silica, said precipitated silica having hydroxyl groups (e.g. silanol groups) on its surface. The invention includes an article of manufacture, including a tire, having at least one component comprised of such rubber composition.Type: GrantFiled: January 24, 2001Date of Patent: October 15, 2002Assignee: The Goodyear Tire & Rubber CompanyInventors: Lawson Gibson Wideman, Paul Harry Sandstrom, Theodore Lamson Folk
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Patent number: 6455634Abstract: The present invention relates to a blend of at least one (meth)acrylate polymer and at least one amorphous propylene-derived polymer, and an optional tackifier that provide pressure sensitive adhesive compositions in which improved peel adhesion to at least one of low and relatively high surface energy substrates can be achieved.Type: GrantFiled: December 29, 2000Date of Patent: September 24, 2002Assignee: 3M Innovative Properties CompanyInventors: Ashish K. Khandpur, Eugene G. Joseph, Greggory S. Bennett
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Patent number: 6429239Abstract: The invention concerns a dispersion powder composition which is redispersible in water and is made from water-insoluble organic polymers, the composition being characterized in that it contains 0.1 to 30% by wt., relative to the weight of the organic polymers, of one or more silicon compounds which are dispersible in water and which have a boiling point at normal pressure of 160 degrees C., selected from the group comprising the silanes, polysilanes, oligosiloxanes, carbosilanes, polycarbosilanes, carbosiloxanes, polycarbosiloxanes and polysilylenedisiloxanes. The invention also concerns methods for manufacturing such compounds and their use.Type: GrantFiled: August 16, 2000Date of Patent: August 6, 2002Assignee: Wacker-Chemie GmbHInventors: Herbert Eck, Klaus Adler, Heinrich Hopf, Franz Jodlbauer, Dieter Gerhardinger
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Patent number: 6391973Abstract: The present invention provides a coating composition containing a two-stage polymer emulsion. The two-stage emulsion polymer contains composite polymeric particles of a first stage polymer prepared from about 0.25% to about 5% by weight monomer having at least two polymerizable ethylenically unsaturated groups, about 2.5% to about 10% by weight hydroxyl monomer, preferably at least about 50% by weight of non-functional monomer of hydrophobic monomer, and preferably without addition of any acid-functional monomer; and a second stage polymer having a theoretical glass transition temperature of at least about 50° C. prepared using, by weight, about 25% to about 50% by weight hydroxyl monomer, about 3% to about 9% carboxylic acid monomer, and preferably at least 25% by weight of non-functional monomer of hydrophobic monomer;. The composite polymeric particles have a theoretical glass transition temperature of not more than about 30° C., preferably not more than about 0° C., and include from about 0.Type: GrantFiled: July 24, 2000Date of Patent: May 21, 2002Assignee: BASF CorporationInventors: David Law, Walter H Ohrbom, S. Kendall Scott, Sergio E. Balatan, Thomas E. St. Henry, Robert Weise
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Patent number: 6114029Abstract: Disclosed is a biaxially stretched styrenic resin sheet obtained by biaxially stretching a resin composition comprising (A) a styrenic resin and (B) crosslinked styrenic fine particles having an average particle size of 0.5 to 15 .mu.m in an amount of from 0.001 to 1% by weight based on the resin composition. The resin composition may further comprise (C) a rubber modified styrenic resin containing a rubber component having an average particle size of 0.1 to 4 .mu.m in such an amount that the rubber component concentration attributed to the rubber modified styrenic resin is from 0.005 to 0.1% by weight based on the resin composition. The styrenic stretched sheets exhibit improved blocking resistance owing to fine unevenness uniformly formed on the surface thereof while retaining the transparency. Even when a number of the sheets or formings obtained therefrom are stacked, they are easily separated apart without blocking.Type: GrantFiled: September 7, 1999Date of Patent: September 5, 2000Assignee: Daicel Chemical Industries, Ltd.Inventors: Hiroyuki Yanai, Syozo Yamamoto
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Patent number: 6083659Abstract: A polymer mixture for a photoresist composition, and a photoresist composition containing the polymer mixture. The polymer mixture includes a polymer that has two or more different monomers and an acid-labile di-alkylmalonate group bound to the backbone of the polymer; a polymer that has a monomer of (meth)acrylate derivative and one or more other monomers; or a polymer that has a monomer of alkoxystyrene and one or more other monomers. The polymer mixtures are suitable for forming photoresist compositions that generate a pattern having an excellent profile, due to the high contrast and high thermal decomposition temperature of the photoresist composition. The photoresist composition of the present invention further include a photosensitive acid generator.Type: GrantFiled: December 22, 1998Date of Patent: July 4, 2000Assignee: Samsung Electronics Co., Ltd.Inventor: Sang-jun Choi
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Patent number: 6011119Abstract: A resin composition is provided for an electro-photographic toner. The composition comprises 5 to 95 parts by weight of a high molecular weight vinyl copolymer polymer and 95 to 5 parts by weight of a low molecular weight vinyl copolymer. The former ethylene polymer has a weight average molecular weight (Mw) of from 200,000 to 1,000,000 and a ratio (Mw/Mn) of the weight average molecular weight (Mw) to a number average molecular weight (Mn) of from 8 to 300, and the latter vinyl copolymer has a weight average molecular weight of from 3,000 to 20,000. At least one of the former and latter vinyl copolymer, preferably, the former vinyl copolymer is an ethylene polymer which has been obtained by conducting polymerization in the presence of a monomer having an ionization potential of from 10.0 to 15.0 eV and a difference of from 9.0 to 15.0 eV in level between a highest occupied molecular orbital (HOMO) and a lowest unoccupied molecular orbital (LUMO), both determined by computational chemistry.Type: GrantFiled: July 19, 1996Date of Patent: January 4, 2000Assignee: Mitsui Chemicals, Inc.Inventors: Katsuru Matsumoto, Nobuhiro Hirayama, Eishi Tanaka, Junko Tobita
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Patent number: 5959037Abstract: A novel acrylic copolymer elastomer comprising ?I! an alkyl acrylate; ?II! (a) CH.sub.a .dbd.CRCOOR.sub.2 OCOR.sub.1, (b) CH.sub.2 .dbd.CRCO?O(CH.sub.2) pCO!qOR.sub.1 or (c) CH.sub.2 .dbd.CRCOOR.sub.2 ?CO(CH.sub.2)pO!qCOR.sub.1 ; and ?III! (1) CH.sub.2 .dbd.CRCOO(CH.sub.2)nPhOR', (2) CH.sub.2 .dbd.CRCOO(CH.sub.2)nOCO(CH.sub.2)mPhOR', (3) CH.sub.2 .dbd.CHOCO(CH.sub.2)mPhOR', (4) CH.sub.2 .dbd.CHOCO(CH.sub.2)nOCO(CH.sub.2)mPhOR', (5) CH.sub.2 .dbd.CHO(CH.sub.2)nOCO(CH.sub.2)mPhOR' or (6) CH.sub.2 .dbd.CHPh(CH.sub.2)nOCO(CH.sub.2)mPhOR' where R is a hydrogen atom or a methyl group, R.sub.1 is an alkyl group, R.sub.2 is an alkylene group, R' is a hydrogen atom, an acyl group or a trialkylsilyl group and Ph is a phenylene group, provides a blend rubber having an improved cold resistance and an intermediate heat resistance between the heat resistance of acrylic copolymer elastomer and that of fluorine-containing elastomer, when blended with the fluorine-containing elastomer.Type: GrantFiled: August 6, 1996Date of Patent: September 28, 1999Assignee: Nippon Mektron, LimitedInventors: Kuniyoshi Saito, Iwao Moriyama, Jun Okabe
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Patent number: 5707943Abstract: Mixtures of esterified carboxy-containing interpolymers and additive concentrates and lubricating oil compositions containing same. Residual acidity of the esterified interpolymers may be neutralized by reaction with an amine.Type: GrantFiled: December 16, 1996Date of Patent: January 13, 1998Assignee: The Lubrizol CorporationInventor: Michael J. Covitch
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Patent number: 5639537Abstract: A polypropylene resin composition for oriented film excellent in transparency, slip property and blocking resistance which comprises the following components (a) and (b), and an oriented film obtained by orienting the composition at least in uniaxial direction:(a) 100 parts by weight of a crystalline polypropylene resin, and(b) 0.05 or more but less than 1 part by weight of crosslinked polymer beads which have a weight average particle diameter of 0.5-5 .mu.m, comprise 60-96% by weight of styrenic monomer units, 2-38% by weight of radical-polymerizable monomer units, the refractive index of the polymer of the radical-polymerizable monomer being 1.50 or less, and 2-50% by weight of crosslinkable monomer units, and give an average protuberance height of 60-600 nm on the surface of oriented film obtained by kneading the crosslinked polymer beads into the polypropylene resin followed by working up into oriented film.Type: GrantFiled: December 14, 1995Date of Patent: June 17, 1997Assignee: Sumitomo Chemical Company LimitedInventors: Takeshi Ebara, Hiroyuki Tanimura, Hajime Sadatoshi, Kazuhiro Yamazaki, Taiji Yamada, Tuyoshi Hashimoto
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Patent number: 5625006Abstract: Adhesive beads comprise a core comprising a pressure sensitive adhesive material and an essentially discontinuous organic polymer disposed about the core. The beads are free-flowing at room temperature. Upon application of heat and/or pressure the core is activated and blends with the coating to provide a pressure sensitive adhesive.Type: GrantFiled: January 24, 1996Date of Patent: April 29, 1997Assignee: Minnesota Mining and Manufacturing CompanyInventors: Joseph P. Callahan, Jr., Rudyard M. Enanoza, Mark D. Weigel
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Patent number: 5502110Abstract: A resin composition for an electrophotographic toner is here disclosed which comprises an ethylene series high polymer (Y) and an ethylene series polymer (X) prepared from 100 parts of a bifunctional ethylene series unsaturated monomer and 0.01-10 parts by weight of a substance having three or more peroxide groups in the molecule and/or a substance having one or more unsaturated functional groups and one or more peroxide groups in the molecule, Mw/Mb (Mw is weight-average molecular weight, and Mb is weight-average molecular weight between crosslinking points) of said polymer (X) being from 2 to 99, Mw of said polymer (X) being 50,000 or less. This resin composition is excellent in the balance of various physical properties required for the toner, and particularly, it is excellent in offset resistance and toner strength.Type: GrantFiled: April 27, 1993Date of Patent: March 26, 1996Assignee: Mitsui Toatsu Chemicals, IncorporatedInventors: Katsuru Matsumoto, Nobuhiro Hirayama, Kenji Uchiyama, Shoji Kawasaki, Tamami Fukui, Katsuo Uramoto
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Patent number: 5446101Abstract: A composite vinylidene chloride copolymer composition excellent in processability which comprises a vinylidene chloride copolymer A having a molecular weight of not less than 50,000 and not more than 300,000 and a vinylidene chloride copolymer B having a molecular weight of not less than 5,000 and not more than the smaller one of either 0.8 times the weight average molecular weight of the vinylidene chloride copolymer A or 80,000, and a monolayer film which comprises the composite vinylidene chloride copolymer composition and is excellent in various properties including barrier property, non-extractability by oily foods and high frequency sealability, and is suitable as a barrier packaging material and wrapping film used for ham, sausage and other like foods.Type: GrantFiled: October 18, 1994Date of Patent: August 29, 1995Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Noboru Anazawa, Yoshitaka Shimoda