Ester Contains At Least Two Carboxylic Acid Ester Groups Patents (Class 525/225)
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Patent number: 5395891Abstract: Mixtures of A) polybutadiene gel and B) other rubbers containing C.dbd.C double bonds, the quantity of polybutadiene gel A), based on the sum of A)+B), being 1 to 70% by weight, show as vulcanizates a favorable combination of the properties hysteresis loss and abrasion resistance.Type: GrantFiled: June 14, 1993Date of Patent: March 7, 1995Assignee: Bayer AktiengesellschaftInventors: Werner Obrecht, Peter Wendling, Robert H. Schuster, Andreas Bischoff
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Patent number: 5384370Abstract: The present invention concerns rubber-based composite materials swellable with water and associated methods of production. A swellable rubber material according to the present invention comprises a vulcanized non-silicone rubber selected from the group consisting of natural rubber, butadiene-styrene rubber, bromobutyl rubber, and ethylene-propylene rubber; and a hydrogel filler cross-linked by a crosslinking agent, wherein the composite material is vulcanizable at a temperature up to 150.degree. C., is thermoformable, possesses shape memory after thermoforming, and is swellable with water or aqueous solutions.Type: GrantFiled: January 31, 1994Date of Patent: January 24, 1995Assignee: Ceskoslovenska akademie vedInventors: Petr Vondracek, Petr Lopour, Jiri Sulc
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Patent number: 5252667Abstract: Poly(vinyl chloride) exhibits a useful combination of acceptable flow for injection molding, improved processability, and acceptable heat distortion resistance and toughness when modified with a multi-stage polymer having as one stage an alkyl (meth)acrylate polymer or copolymer containing a low level of a copolymerized unsaturated acid partly to completely in the form of its alkali metal salt. In preferred compositions, the melt viscosity under injection molding conditions of the blend will be equal to or less than that of the PVC alone.Type: GrantFiled: December 7, 1992Date of Patent: October 12, 1993Assignee: Rohm and Haas CompanyInventor: Hsing-Yeh Parker
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Patent number: 5248723Abstract: A vinyl chloride polymer composition comprising from 50 to 90 parts by weight of a vinyl chloride polymer having an average particle size of from 5 to 80 .mu.m and an average degree of polymerization of at least 2500 and from 50 to 10 parts by weight of a vinyl chloride polymer capable of forming a plastisol.Type: GrantFiled: March 12, 1992Date of Patent: September 28, 1993Assignee: Mitsubishi Kasei Vinyl CompanyInventors: Yoji Nakayama, Yasuo Murase
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Patent number: 5232606Abstract: A method is provided for recovering PVC from a material including PVC and one or more non-PVC components, in which the material is mixed with a sufficient amount of a plasticizer at an effective temperature, preferably in the range of 100.degree.-200.degree. C., to give a PVC: plasticizer ratio such that the PVC and plasticizer form a mixture which is a liquid at that temperature so that the liquid PVC/plasticizer can be separated from the non-PVC component or components.Type: GrantFiled: April 21, 1992Date of Patent: August 3, 1993Assignee: Ortech CorporationInventor: Jacob Leidner
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Patent number: 5202381Abstract: This invention relates to improved poly(vinyl chloride) compositions which contain ionomeric additive polymers, and to a process for preparing such compositions.Type: GrantFiled: April 4, 1990Date of Patent: April 13, 1993Assignee: Rohm and Haas CompanyInventor: Hsing-Yeh Parker
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Patent number: 5173535Abstract: Plastic materials having distributed therein discrete particles of crosslinked polymers having functional material entrapped within the polymer lattices during the in situ polymerization of the monomers forming the polymer for the purpose of a controlled release of the functional material.Type: GrantFiled: February 11, 1988Date of Patent: December 22, 1992Assignee: Dow Corning CorporationInventor: Eric S. Abrutyn
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Patent number: 5104925Abstract: A synthetic resin composition comprising 100 parts by weight of a synthetic resin, from 2 to 900 parts by weight of an inorganic filler, and from 0.02 to 20 parts by weight of a copolymer of a compound represented by formula (1) and maleic anhydride, maleic acid, a maleic acid salt or a maleic acid ester; ##STR1## wherein Z is a residue of a compound having from 2 to 8 hydroxyl groups; AO is an oxyalkylene group having from 2 to 18 carbon atoms; R.sup.1 is an unsaturated hydrocarbon group having from 2 to 5 carbon atoms; R.sup.2 is a hydrocarbon or acyl group having from 1 to 40 carbon; a is from 0 to 1,000, b is from 0 to 1,000, c is from 0 to 1,000, l is an integer of from 1 to 8, m is an integer of from 0 to 2, and n is an integer of from 0 to 7, l+m+n=2 to 8, al+bm+cn=1 to 1,000, and n/(l+n).ltoreq.1/3.Type: GrantFiled: September 13, 1989Date of Patent: April 14, 1992Assignee: Nippon Oil & Fats Co., Ltd.Inventors: Susumu Honda, Takahiko Sugihara, Taizo Igarashi, Keiji Hirao, Hisamichi Matsuda
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Patent number: 5001194Abstract: A functionalized polymeric composition, said polymeric composition comprising a first phase and a second phase. The first phase comprises a first copolymer of a monovinylidene monomer and a comonomer selected to have at least one reactive epoxide functionality. The second phase is dispersed with the first phase. The second phase comprises a copolymer of an olefin monomer and one or more ethylenically unsaturated monomers copolymerizable with the olefin monomer wherein at least one of the ethylenically unsaturated monomers copolymerizable with the olefin monomer comprises a reactive functionality capable of reacting with one or more of the reactive epoxide functionalities of the first copolymer.Type: GrantFiled: July 7, 1989Date of Patent: March 19, 1991Assignee: The Dow Chemical CompanyInventor: David E. Henton
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Patent number: 4983687Abstract: Chlorinated polyvinyl chloride resins when crosslinked have improved melt strength in comparison with non-crosslinked chlorinated polyvinyl chloride resins. Moreover, the crosslinked chlorinated polyvinyl chloride resins have unexpected improved processing properties such as reduced processing torque in comparison with crosslinked polyvinyl chloride resins which upon crosslinking exhibit increased processing torque. Various amounts of non-crosslinked chlorinated polyvinyl chloride and/or non-crosslinked polyvinyl chloride which does not affect said improved properties can be blended with the crosslinked chlorinated polyvinyl chloride resins.Type: GrantFiled: May 23, 1988Date of Patent: January 8, 1991Assignee: The B. F. Goodrich CompanyInventors: Dennis L. Lawson, Robert E. Detterman
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Patent number: 4972022Abstract: A rubber composition having excellent cut resistance and chipping resistance comprises 1-30 parts by weight of a particular resin obtained by reacting a particular hydroxyl group-containing cyclopentadiene resin with a compound selected from polyisocyanate and/or polybasic acid or its anhydride or ester at a particular equivalent ratio, based on 100 parts by weight of rubber.Type: GrantFiled: July 22, 1988Date of Patent: November 20, 1990Assignees: Bridgestone Corporation, Nippon Oil Company LimitedInventors: Hitoshi Kondo, Makoto Sasaki, Yukio Kobayashi
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Patent number: 4963621Abstract: Rubber mixtures of hydrogenated nitrile rubber and ethylene/acrylonitrile copolymers, which contain copolymerized units of compounds with at least two (meth-)acryloyl groups, are easy to process and give vulcanized materials of high solvent resistance without any deterioration in the mechanical properties.Type: GrantFiled: February 5, 1990Date of Patent: October 16, 1990Assignee: Bayer AktiengesellschaftInventors: Zsolt Szentivanyi, Werner Obrecht, Jurgen Wassen
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Patent number: 4902545Abstract: A boot for an automobile comprises two terminal annular parts and a barrel part intervening between the two terminal annular parts. This boot is obtained by injection molding a flexible PVC material. The flexible PVC material of one type (I) is composed of a polymer component and a plasticizer, which polymer component is obtained by blending high polymerization degree and low polymerization degree PVC's respectively having an average polymerization degree in specific ranges, with the mixing ratio of the two PVC's being in a specific range. The flexible PVC material of the other type (II) is composed of a polymer component and a plasticizer, which polymer component is obtained by blending a cross-linked resin having a non-gel component average polymerization degree and a cross-linking degree in respectively specific ranges with a non-cross-linked resin having an average polymerization degree in a specific range, with the mixing ratio of the two PVC's in a fixed range.Type: GrantFiled: June 17, 1988Date of Patent: February 20, 1990Assignee: Toyoda Gosei Co., Ltd.Inventors: Satoshi Ohta, Mashiro Takimoto, Yoshio Yamazaki, Haruyasu Mizutani
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Patent number: 4855363Abstract: A crosslinkable polymer composition comprising:(I) 1% to 99% by weight of at least one olefin copolymer selected from the group consisting of:(A) copolymers composed of (i) .alpha.-olefins, (ii) unsaturated dicarboxylic acid anhydrides, and (iii) at least one compound selected from the group consisting of unsaturated carboxylic acid esters, and vinyl esters;(B) copolymers at least composed of olefins and unsaturated monocarboxylic acids;(C) copolymers obtained by saponifying and neutralizing olefin copolymers at least composed of olefins and unsaturated carboxylic esters; and(D) copolymers at least composed of olefins and unsaturated dicarboxylic acids or the half esters thereof; and(II) 99% to 1% by weight of at least one olefin copolymer selected from the group consisting of:(A) copolymers at least composed of olefins and glycidyl alkyl (meth) acrylates; and(B) copolymers composed of (i) at least one .alpha.Type: GrantFiled: September 15, 1987Date of Patent: August 8, 1989Assignee: Showa Denko Kabushiki KaishaInventor: Yoshihiro Moteki
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Patent number: 4828946Abstract: The invention provides a process for the production of sinterable, finely divided molding compounds based on polyvinyl chloride by suspension polymerization of vinyl chloride in the presence of a suspending agent mixture of sulfated carbohydrate ester and cellulose ether. The compounds are useful for the production of sintered molded articles, such as separator plates. The molded articles or plates exhibit a slight electrical resistance and a high porosity with good acid storage volume.Type: GrantFiled: December 7, 1987Date of Patent: May 9, 1989Assignee: Huels AktiengesellschaftInventors: Heimo Bieringer, Klaus Engel
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Patent number: 4728463Abstract: Brominated styrene-maleate copolymer containing at least 50 weight percent bromine and its use as a fire retardant.Type: GrantFiled: August 18, 1986Date of Patent: March 1, 1988Assignee: Ethyl CorporationInventors: Burton J. Sutker, Gen-Shing Ti, Mo A. Khuddus
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Patent number: 4654403Abstract: Polymeric compositions are described which comprise a mixture of(A) at least one oil-soluble polymer which is a homopolymer of a non-aromatic monoolefin or a copolymer of said non-aromatic monoolefin with an aromatic monoolefin, and(B-1) at least one nitrogen-containing ester of a carboxy-containing interpolymer, and/or(B-2) at least one oil-soluble acrylate polymerization product of at least one acrylate ester, or a mixture of one or more of (B-1) and (B-2). The polymeric compositions of the invention also may contain (C) an effective amount of at least one viscosity-reducing liquid organic diluent such as a naphthenic oil or an alkylated aromatic material.Type: GrantFiled: February 5, 1986Date of Patent: March 31, 1987Assignee: The Lubrizol CorporationInventor: Craig D. Tipton
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Patent number: 4619969Abstract: A polypropylene-based resin composition comprising (A) from 60 to 99 parts by weight of a polypropylene-based resin and (B) from 1 to 40 parts by weight of an ethylene copolymer composed of from 25 to 98.5% by weight of ethylene, from 0.5 to 15% by weight of an unsaturated dicarboxylic acid anhydride and from 1 to 60% by weight of an unsaturated ester compound having from 4 to 12 carbon atoms and/or a modified copolymer obtained by ring opening addition reaction of the acid anhydride group of said ethylene copolymer with an alcohol having from 1 to 20 carbon atoms. The composition provides a molded particle having excellent finishing workability and improved mechanical properties.Type: GrantFiled: November 5, 1985Date of Patent: October 28, 1986Assignee: Sumitomo Chemical Company, LimitedInventors: Toshiki Doi, Hideo Shinonaga, Tadayuki Omae
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Patent number: 4594378Abstract: Polymeric compositions are described which comprise a mixture of(A) at least one oil-soluble polymer which is a homopolymer of a non-aromatic monoolefin or a copolymer of said non-aromatic monoolefin with an aromatic monoolefin, and(B-1) at least one nitrogen-containing ester of a carboxy-containing interpolymer, and/or(B-2) at least one oil-soluble acrylate polymerization product of at least one acrylate ester, or a mixture of one or more of (B-1) and (B-2). The polymeric compositions of the invention also may contain(C) an effective amount of at least one viscosity-reducing liquid organic diluent such as a naphthenic oil or an alkylated aromatic material.Type: GrantFiled: March 25, 1985Date of Patent: June 10, 1986Assignee: The Lubrizol CorporationInventors: Craig D. Tipton, Kent B. Grover
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Patent number: 4588776Abstract: A polymer composition adapted for use in producing polyvinyl halide polymer products comprising a blend of a vinyl halide polymer and a particulate terpolymer having a molecular weight of at least about 100,000 and a glass transition temperature of at least about 50.degree. C. The terpolymer comprises repeating units derived from an olefin, a diester of an addition polymerizable unsaturated dicarboxylic acid, and a solubilizing monomer which promotes compatibility of the terpolymer with the vinyl halide polymer. A shaped plastic article produced from this composition, and method of producing the shaped article are also disclosed.Type: GrantFiled: June 29, 1984Date of Patent: May 13, 1986Assignee: Monsanto CompanyInventors: Vladimir Bekker, Wayne J. Buchheim, William Vanderlinde, Donald S. T. Wang
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Patent number: 4567217Abstract: A steering wheel is disclosed, which is produced by injection molding a resin composition comprising (i) a crosslinked vinyl chloride polymer having a gel fraction of at least 20% and a non-gelled portion having an average polymerization degree of from 2000 to 3000, (ii) a non-crosslinked vinyl chloride homopolymer having an average polymerization degree of from 800 to 1000, and (iii) a liquid plasticizer, wherein the weight ratio of polymer component (i) to polymer component (ii) is from 50/50 to 80/20 and (iii) the amount of liquid plasticizer is from 70 to 130 parts by weight per 100 parts by weight of the total amount of the two polymers (i) and (ii). The steering wheel has excellent properties with respect to uniformity in matte surface, wear resistance and lightfastness.Type: GrantFiled: January 24, 1985Date of Patent: January 28, 1986Assignee: Toyoda Gosei Co. Ltd.Inventors: Yoshio Yamazaki, Masahiro Takimoto, Satoshi Ohta
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Patent number: 4536548Abstract: Highly transparent, impact-resistant molded articles can be produced from a molding composition, comprising: (1) a major portion of polyvinyl chloride or a copolymer comprising at least 70% by weight of vinyl chloride units; and (2) an amount effective to impart impact resistance of: (a) at least one homopolymer of an acrylate monomer having the formula ##STR1## wherein R is a straight-chain or branched alkylene residue of 3-8 carbon atoms, optionally interrupted by 1-2 ether oxygen atoms, wherein the straight-chain portion of said alkylene residue contains at least 3 carbon atoms; or (b) a copolymer of said acrylate monomer and up to 30% by weight of at least one acrylate ester of a C.sub.4-12 aliphatic alcohol.Type: GrantFiled: May 5, 1983Date of Patent: August 20, 1985Assignee: Chemische Werke Huels, A.G.Inventor: Bernhard Stutzel
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Patent number: 4407975Abstract: A polymeric membrane having maleic anhydride residues which comprises a blend of a maleic anhydride copolymer and a support polymer, said blend being partially cross-linked with a bifunctional cross-linking reagent. When hydrolyzed, this membrane turns into an ion exchange membrane or a membrane on which an enzyme is immobilized.Type: GrantFiled: February 26, 1982Date of Patent: October 4, 1983Assignee: Agency of Industrial Science and TechnologyInventor: Tomohiko Yamaguchi
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Patent number: 4318742Abstract: Odontologic compositions suited for use as denture adhesives, the compositions containing a major amount of gum base and a quantity of a hydrophilic polymer to modify the adhesive properties of the gum base together with processes for producing such compositions.Type: GrantFiled: September 27, 1979Date of Patent: March 9, 1982Assignee: Solar Dental Co., Inc.Inventor: Oddvin Lokken
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Patent number: 4268433Abstract: Flame retardation of 1,2-polybutadiene based upon the use of halogenated bisphenol bisacrylate reactive flame retardants, for example, 2,2-bis(4-methacryloyl-3,5-dibromophenyl)-propane. Flame retardancy performance of UL 94 V-0 or V-1 has been achieved without impairing desirable dielectric properties and heat resistance inherently possessed by 1,2-polybutadiene. If an aromatic bismaleimide modifier, for example, N,N'-4,4'-diphenylmethane bismaleimide, is jointly used, a thermal expansion coefficient less than a half of the thermal expansion coefficient of cured 1,2-polybutadiene can be achieved.Type: GrantFiled: August 29, 1979Date of Patent: May 19, 1981Assignee: Fujitsu LimitedInventors: Norio Sawatari, Isao Watanabe, Kazumasa Saito, Katsura Adachi
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Patent number: 4238577Abstract: A vulcanizable elastomeric composition comprising(a) from about 89-40%, by weight, based on the total weight of the composition, of an acrylic acid ester, or mixture thereof, having the formula ##STR1## wherein R is an alkyl (C.sub.1 -C.sub.4) radical, --CH.sub.2 CH.sub.2 OR', wherein R' is an alkyl (C.sub.1 -C.sub.4) radical, or --CH.sub.2 CH.sub.2 CN;(b)from about 10-45%, by weight, same basis, of bis(2-methoxyethyl)fumarate, bis(2-methoxyethyl)maleate, or mixtures thereof,(c) from about 1-10%, by weight, same basis, of an unsaturated monomer containing a halogen atom or an epoxy group, and(d) from 0 to 5%, by weight, of polybutadiene, polychloroprene or polyisoprene.Type: GrantFiled: December 8, 1978Date of Patent: December 9, 1980Assignee: American Cyanamid CompanyInventor: Volker D. Arendt
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Patent number: 4206292Abstract: A vinyl chloride resin composition having surface smoothness comprises:(1) 100 parts of vinyl chloride polymer; and(2) 0.1 to 30 parts of a polymer processing aid comprising:(A) 10 to 100 parts of a copolymer comprising 20 to 99% of an alkyl methacrylate, 1 to 70% of a dialkyl itaconate, and 0 to 60% of a monomer copolymerizable therewith; and(B) 0 to 90 parts of a copolymer comprising 80 to 100% of an alkyl methacrylate, and 0 to 20% of a monomer copolymerizable therewith,the sum of the quantities of the copolymers (A) and (B) producing 100 parts of the polymer processing aid, all quantities expressed in parts and percentages being by weight.This vinyl chloride resin composition comprising a novel polymer processing aid not only shows an increased gelation rate, yields less ungelled particles and possesses excellent processability such as an increased elongation at a high temperature, but particularly affords a formed product of notably improved surface smoothness.Type: GrantFiled: March 7, 1979Date of Patent: June 3, 1980Assignee: Kureha Kagaku Kogyo Kabushiki KaishaInventors: Masaki Ohya, Yo Iizuka, Susumu Midorikawa
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Patent number: 4165308Abstract: Coating compositions comprising intimate blends of a styrene interpolymer or a vinyl acetate polymer and a low molecular weight polystyrene or poly(.alpha.-methylstyrene) of relative viscosity in the range of about 1.04 to about 1.15. The coating compositions may contain up to 500 parts by weight of an inert non-photoconductive pigment per 100 parts by weight of polymer blend. The compositions are useful for the preparation of electrographic recording media which possess improved toner adhesion and decreased toner smear.Type: GrantFiled: May 26, 1978Date of Patent: August 21, 1979Assignee: Monsanto CompanyInventor: Irving Serlin