At Least Two Polymers Derived From Reactants Containing Two Or More Ethylenic Groups And Devoid Of An Aryl Ring Patents (Class 525/236)
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Patent number: 6114451Abstract: In a rubber blend consisting of:a polybutadiene blend (A)+(B) composed of:(A) not less than 30% by weight but less than 70% by weight of a high molecular weight polybutadiene comprising as the main component a polybutadiene having an intrinsic viscosity [.eta.] of 3.0 to 7.0 as measured in toluene at 30.degree. C. and a cis-1,4-configuration content of at least 80% and(B) more than 30% by weight but not more than 70% by weight of a low molecular weight polybutadiene comprising, as the main component, a polybutadiene having an intrinsic viscosity [.eta.] of 0.1 to 0.5 as measured in toluene at 30.degree. C., and(C) a diene type rubber other than the above components (A) and (B),the rubber blend (A)+(B) is contained in a proportion of 35 to 95 percent by total weight of rubber blend (A)+(B)+(C), thereby providing a rubber blend suitable for a tire; said blend being greatly improved in wet skid performance and ice skid performance with retention of the abrasion resistance of a conventional polybutadiene.Type: GrantFiled: August 19, 1998Date of Patent: September 5, 2000Assignees: Ube Industries, Ltd., Bridgestone CorporationInventors: Takeshi Shoda, Naomi Okamoto, Koji Ohkawa
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Patent number: 6110549Abstract: A sealant resin composition for retort packaging film comprises a high density polyethylene as the main resin component and a linear low density polyethylene polymerized by use of the metallocene catalyst. A sealant film produced therefrom is resistant to whitening, heat fusion, heat deformation after being subjected to boiling sterilization treatment and prevent breakage of pouches produced therefrom even at low temperatures because of its high impact strength and heat sealing strength.Type: GrantFiled: April 30, 1998Date of Patent: August 29, 2000Assignee: Mitsui Chemicals Inc.Inventors: Naoshi Hamada, Sadamu Hirakawa, Shigeo Ozaki
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Patent number: 6107379Abstract: Provided is an automobile vibration-isolating rubber composition, characterized in that a rubber component comprises from 10 to 80% by weight of a polybutadiene rubber which is obtained through the polymerization using a rare-earth element catalyst and which has a cis content of 97% or more, and from 90 to 20% by weight of at least one type of a rubber selected from a natural rubber, a synthetic polyisoprene rubber and a polystyrene-butadiene copolymer rubber. The automobile vibration-isolating rubber obtained by vulcanizing the rubber composition of the present invention has a low dynamic factor compared to the conventional product, making it possible to decrease a room noise caused by a road noise.Type: GrantFiled: August 14, 1998Date of Patent: August 22, 2000Assignee: Toyo Tire & Rubber Co., Ltd.Inventors: Tsuneo Kamata, Makoto Niki, Yoshihide Ueda
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Patent number: 6084022Abstract: This invention relates to a tire tread compound that is easily processable which can be used to improve the treadwear, rolling resistance and traction characteristics of tires. The tire tread compounds of this invention are a blend of tin-coupled polybutadiene, high vinyl polybutadiene and natural rubber. This blend of low glass transition temperature rubber and high glass transition temperature rubber is surprisingly easy to process which makes the concept of this invention commercially feasible. Thus, the tire tread compounds of this invention can be utilized in making tires having greatly improved traction characteristics and treadwear without sacrificing rolling resistance. These improved properties may be due, in part, to better interaction and compatibility with carbon black and/or silica fillers. The polybutadiene in the blend can be asymmetrical tin-coupled to further improve the cold flow characteristics of the rubber blend.Type: GrantFiled: September 22, 1997Date of Patent: July 4, 2000Assignee: The Goodyear Tire & Rubber CompanyInventors: Edward John Blok, Paul Harry Sandstrom, Cheryl Ann Losey, Adel Farhan Halasa, Wen-Liang Hsu, David John Zanzig, John Joseph Andre Verthe
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Patent number: 6072004Abstract: The present invention provides a thermofusible elastomer composition comprising:(a) 100 phr of a selectively hydrogenated block copolymer component comprising an A'B' block copolymer and a multiblock copolymer having at least two end blocks A and at least one mid block B wherein the A' and A blocks are monoalkenyl arene polymer blocks and the B' and B blocks are substantially completely hydrogenated conjugated diene polymer blocks, the number average molecular weight of the A' and A blocks are between about 3,000 and about 7,000 and the monoalkenyl arene content of the multiblock copolymer is between about 7% and about 22% by weight;(b) 20 to 50 phr of at least one high melt flow polyolefin;(c) 0 to 19 phr of a plasticizing oil selected from naphthenic oils and paraffinic oils; and(d) 0 to 40 phr of at least one poly(conjugated diene) block compatible resin wherein the elastomer composition has a particle size of 1400 .mu.m or less.This composition is used in low shear processes.Type: GrantFiled: November 25, 1998Date of Patent: June 6, 2000Assignee: Shell Oil CompanyInventors: Peter Migchels, Margaret Ann Burns Clawson
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Patent number: 6028144Abstract: A composition, suitable for use in producing a tire carcass, is provided. The composition comprises a halogen-containing copolymer of a C.sub.4 to C.sub.7 isomonoolefin and a para-alkylstyrene; a rubber such as a blend of natural rubber and a copolymer of styrene and butadiene; carbon black, and a plasticizer oil. Tires comprising carcasses made of the composition are also provided.Type: GrantFiled: January 5, 1993Date of Patent: February 22, 2000Assignee: Exxon Chemical Patents, Inc.Inventors: Vi Thi Nguyen, Patrick Anthony Grosso
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Patent number: 6025430Abstract: This invention relates to a tire tread compound that is easily processable which can be used to improve the treadwear, rolling resistance and traction characteristics of tires. The tire tread compounds of this invention are a blend of tin-coupled polybutadiene, high vinyl polybutadiene and natural rubber. This blend of low glass transition temperature rubber and high glass transition temperature rubber is surprisingly easy to process which makes the concept of this invention commercially feasible. Thus, the tire tread compounds of this invention can be utilized in making tires having greatly improved traction characteristics and treadwear without sacrificing rolling resistance. These improved properties may be due, in part, to better interaction and compatibility with carbon black and/or silica fillers. The polybutadiene in the blend can be asymmetrical tin-coupled to further improve the cold flow characteristics of the rubber blend.Type: GrantFiled: September 2, 1999Date of Patent: February 15, 2000Assignee: The Goodyear Tire & Rubber CompanyInventors: Edward John Blok, Paul Harry Sandstrom, Cheryl Ann Losey, Adel Farhan Halasa, Wen-Liang Hsu, David John Zanzig, John Joseph Andre Verthe
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Patent number: 6017988Abstract: This invention relates to a tire tread compound that is easily processable which can be used to improve the treadwear, rolling resistance and traction characteristics of tires. The tire tread compounds of this invention are a blend of tin-coupled polybutadiene, high vinyl polybutadiene and natural rubber. This blend of low glass transition temperature rubber and high glass transition temperature rubber is surprisingly easy to process which makes the concept of this invention commercially feasible. Thus, the tire tread compounds of this invention can be utilized in making tires having greatly improved traction characteristics and treadwear without sacrificing rolling resistance. These improved properties may be due, in part, to better interaction and compatibility with carbon black and/or silica fillers. The polybutadiene in the blend can be asymmetrical tin-coupled to further improve the cold flow characteristics of the rubber blend.Type: GrantFiled: August 3, 1999Date of Patent: January 25, 2000Assignee: The Goodyear Tire & Rubber CompanyInventors: Edward John Blok, Paul Harry Sandstrom, Cheryl Ann Losey, Adel Farhan Halasa, Wen-Liang Hsu, David John Zanzig, John Joseph Andre Verthe
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Patent number: 5994448Abstract: This invention relates to a tire tread compound that can be used in manufacturing tires having outstanding traction characteristics without compromising treadwear and rolling resistance. The tire tread compounds of this invention are made utilizing an isoprene-butadiene rubber having a high glass transition temperature and having SnR.sub.3 end groups, wherein R represents an alkyl group, such as a tertiary-butyl group. These isoprene-butadiene rubbers are made by reacting an isoprene-butadiene rubber having a glass transition temperature which is within the range of about -50.degree. C. to about 0.degree. C. with a tin compound of the formula SnR.sub.3 X, wherein R represents an alkyl group and wherein X represents a halogen. This invention more specifically discloses a tire tread rubber composition which is comprised of (1) about 60 phr to about 95 phr of an isoprene-butadiene rubber having a glass transition temperature which is within the range of about -50.degree. C. to about 0.degree. C.Type: GrantFiled: August 12, 1998Date of Patent: November 30, 1999Assignee: The Goodyear Tire & Rubber CompanyInventors: Edward John Blok, Paul Harry Sandstrom, Wen-Liang Hsu, Adel Farhan Halasa
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Patent number: 5977260Abstract: Adhesive thermoplastic composition basically consisting of:1) dynamically vulcanized thermoplastic elastomer;2) polyethylene having a density equal to or less than 0.920 g/cm.sup.3 ;3) additives.The above composition is particularly useful for being firmly bound to articles made of EPM and/or EPDM vulcanized rubbers and for binding parts of vulcanized EPM and/or EPDM to each other.Type: GrantFiled: July 10, 1996Date of Patent: November 2, 1999Assignee: Enichem Elastomeri S.r.l.Inventors: Vittorio Ciaccia, Eugenio Longo, Patrizia Piancastelli
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Patent number: 5965661Abstract: The invention pertains to a sulfur cross-linkable unvulcanized rubber mixture for the manufacture of treads, in particular for winter tires. The rubber mixture contains polyisoprene, polybutadiene and styrene-butadiene copolymer as well as further fillers and additives. In order to prepare vehicle pneumatic tires which exhibit excellent traction on ice and snow while at least maintaining their wet-gripping ability, the rubber mixture preferably contains, relative to 100 parts of total rubber, 20-100 parts by weight cis-1,4 polyisoprene; 0-65 parts by weight polybutadiene with a cis content of greater than about 90 mole %; and 0-65 parts by weight solution-polymerized styrene-butadiene copolymer; as well as 65-120 parts by weight silicic acid.Type: GrantFiled: December 19, 1997Date of Patent: October 12, 1999Assignee: Continental AktiengesellschaftInventors: Andre du Bois, Joachim Dumke, Anja Schneider, Wolfgang Loreth
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Patent number: 5959039Abstract: A tire having a portion formed of a rubber composition which comprises a high-molecular-weight polymer component which contains bound styrene in an amount not greater than 30% by weight, is a styrene-butadiene copolymer or a conjugated diene polymer such as polybutadiene, and has a weight-average molecular weight of at least 30.times.10.sup.4 ; and a low-molecular-weight polymer component which contains bound styrene in an amount not greater than 30% by weight, is a styrene-butadiene copolymer or a conjugated diene polymer such as polybutadiene, and has a weight-average molecular weight of from 0.2.times.10.sup.4 to 8.times.10.sup.4. The rubber composition contains 30 parts by weight of the low-molecular-weight polymer component relative to 100 parts by weight of the high-molecular-weight polymer component. The ratio between the amount of bound styrene and the vinyl linkage content falls within specific ranges.Type: GrantFiled: June 28, 1996Date of Patent: September 28, 1999Assignee: Bridgestone CorporationInventors: Hideaki Yokoyama, Toshiyuki Ishikuro, Tadashi Shibata
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Patent number: 5945481Abstract: A case for memory disks having excellent antistatic properties, which comprises a thermoplastic resin composition comprising 100 parts by weight of the following component (A), 3 to 30 parts by weight of the following component (B) and 5 to 40 parts by weight of the following component (C):component (A): a crystalline propylene resin having a melt flow rate (MFR) of 1 to 80 g/10 min;component (B): a thermoplastic elastomer selected from (b.sup.1) olefin copolymer elastomers having a Mooney viscosity (ML.sub.1+4 (100.degree. C.)) of 10 to 85, and (b.sup.2) hydrogenated products of a block copolymer of styrene or a derivative thereof and a conjugated diene, containing 15 to 50% by weight of styrene or a derivative thereof, having a weight-average molecular weight of 50,000 to 220,000; andcomponent (C): an acrylamide copolymer.Type: GrantFiled: July 9, 1997Date of Patent: August 31, 1999Assignee: Mitsubishi Chemical CorporationInventors: Toshikazu Mizutani, Jichio Deguchi
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Patent number: 5916961Abstract: The reduction of hysteresis in a silica-filled, vulcanized elastomeric compound is produced by mixing diene monomer and optionally monovinyl aromatic monomer with a lithium amine initiator and, optionally, a modifier; effecting polymerization conditions; terminating polymerization with an amino group producing terminator to form an amine functionalized diene elastomer; compounding the amine functionalized diene elastomer with an amorphous silica filler and a vulcanization agent; and, effecting vulcanization. A pneumatic tire tread stock incorporating the vulcanized elastomer compound exhibits decreased rolling resistance in the tire.Type: GrantFiled: July 11, 1997Date of Patent: June 29, 1999Assignee: Bridgestone CorporationInventors: William L. Hergenrother, Thomas J. Lynch
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Patent number: 5916973Abstract: The present invention relates to compounds of the formula ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are independently selected from alkoxy radicals having from 1 to 8 carbon atoms, x is O or an integer of from 1 to 10; and Y is Li, K or Na. These compounds may be used as silica couplers in rubber compositions.Type: GrantFiled: August 13, 1997Date of Patent: June 29, 1999Assignee: The Goodyear Tire & Rubber CompanyInventors: Rene Jean Zimmer, Friedrich Visel, Uwe Ernst Frank, Thierry Florent Edme Materne
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Patent number: 5912374Abstract: The present invention relates to asymmetrical siloxy compounds of the formulae ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R.sup.4 is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms; R.sup.Type: GrantFiled: August 13, 1997Date of Patent: June 15, 1999Assignee: The Goodyear Tire & Rubber CompanyInventors: Giorgio Agostini, Thierry Florent Edme Materne, Marc Junio, Friedrich Visel, Uwe Ernst Frank
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Patent number: 5901766Abstract: The present invention relates to a pneumatic tire having a tread containing (a) from 50 to 90 phr (parts by weight of rubber per 100 total parts of rubber) of a rubber which, in its uncured state, has a glass transition temperature in the range of from -80.degree. C. to -110.degree. C. and (b) from 15 to 50 phr of a resin.Type: GrantFiled: August 26, 1997Date of Patent: May 11, 1999Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul Harry Sandstrom, Edward John Blok, John Joseph Andre Verthe
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Patent number: 5902856Abstract: A diene rubber (iii) can be obtained by mixing in a solution state:a modified styrene-butadiene rubber (i) having a weight-average molecular weight of 150,000-500,000, obtained by reacting a diene polymer having a bound active metal in the molecule, with a modifier such as N-methyl-.epsilon.-caprolactam or the like, anda branched styrene-butadiene rubber (ii) having a weight-average molecular weight of 800,000 or more.This diene rubber (iii) and a rubber composition comprising the diene rubber (iii) and other diene rubber (iv) have superior processability when unvulcanized and give a vulcanized rubber having improved abrasion resistance, resiliency and low-temperature properties.Type: GrantFiled: May 22, 1997Date of Patent: May 11, 1999Assignee: Nippon Zeon Co., Ltd.Inventors: Fumitoshi Suzuki, Masao Nakamura, Manabu Tomisawa
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Patent number: 5895798Abstract: A liquid rubber composition including a 1,2-polybutadiene resin component dispersed in the form of fine particles in a liquid rubber component in a weight ratio of 1:100 to 50:100 has a high dispersion stability and a low specific gravity and is useful for forming a cured rubber article having a high elastic modulus and a satisfactory mechanical strength and ultimate elongation.Type: GrantFiled: October 6, 1997Date of Patent: April 20, 1999Assignee: Ube Industries, Ltd.Inventors: Naomi Okamoto, Takeshi Shoda
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Patent number: 5889119Abstract: A method of recycling vulcanized rubber comprising the steps of grinding vulcanized rubber into particles having an average diameter in the range from about 50 .mu.m to about 1.2 mm, and adding the ground tire rubber to a low-modulus binder to form a thermoplastic rubbery composition comprising from about 10 to about 80 parts by weight of the low-modulus binder including from about 25 to about 75 parts by weight of a crystalline polyolefin resin, and from about 25 to about 75 parts by weight of a binder rubber, wherein the rubber is vulcanized by dynamic vulcanization to form fine particles the binder resin, and from about 90 to about 20 parts by weight of ground vulcanized rubber wherein said step of adding the ground rubber occurs at a temperature above the melting point of the crystalline polyolefin resin.Type: GrantFiled: July 17, 1997Date of Patent: March 30, 1999Assignee: The University of AkronInventors: Aubert Y. Coran, Faith Howard
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Patent number: 5885389Abstract: A pneumatic rubber tire with a chafer positioned around at least a portion of its bead component and intended for contacting a rigid rim of a wheel, wherein said chafer is composed of a rubber composition which is based upon a combination of a specified trans 1,4-polybutadiene polymer and a high cis 1,4-polybutadiene rubber. The rubber composition for the tire chafer component may also contain cis 1,4-polyisoprene rubber and/or styrene/butadiene rubber.Type: GrantFiled: March 6, 1997Date of Patent: March 23, 1999Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul Harry Sandstrom, Neil Arthur Maly
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Patent number: 5859133Abstract: The subject invention discloses a pneumatic tire having an outer circumferential tread wherein said tread is a sulfur-cured rubber composition comprised of (a) an isoprene-butadiene diblock rubber, said isoprene-butadiene diblock rubber being comprised of a butadiene block and an isoprene-butadiene block, wherein said butadiene block has a number average molecular weight which is within the range of about 25,000 to about 350,000, wherein said isoprene-butadiene block has a number average molecular weight which is within the range of about 25,000 to about 350,000, wherein said isoprene-butadiene diblock rubber has essentially one glass transition temperature which is within the range of about -100.degree. C. to about -70.degree. C., wherein said isoprene-butadiene diblock polymer has a Mooney ML-4 viscosity at 100.degree. C.Type: GrantFiled: March 18, 1996Date of Patent: January 12, 1999Assignee: The Goodyear Tire & Rubber CompanyInventors: David John Zanzig, Adel Farhan Halasa, Wen-Liang Hsu, Paul Harry Sandstrom, Laurie Elizabeth Austin
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Patent number: 5859142Abstract: A rubber composition suitable for reinforcing beads of tires, having high hardness, high durability and high aging resistance, which comprises a rubber component containing 30 to 70% by weight of a butadiene rubber containing syndiotactic crystals, 60 to 75 parts by weight of a carbon black having a specified iodine adsorption number and a specified oil absorption, 1 to 2 parts by weight of sulfur and 2 to 4 parts by weight of a sulfenamide accelerator, respectively, per 100 parts by weight of the rubber component, wherein the total amount of sulfur and the sulfenamide accelerator is from 3 to 5 parts by weight.Type: GrantFiled: September 29, 1994Date of Patent: January 12, 1999Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Kiyoshige Muraoka, Yoko Nakada, Takahiro Fukumoto, Toru Iizuka, Kaoru Koyama
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Patent number: 5859114Abstract: An adhesive tape composition includes a polymer blend comprising at least one ethylene-propylene-diene terpolymer and at least one fully saturated adhesive-enhancing polymer miscible with said at least one ethylene-propylene-diene terpolymer. The tape adhesive composition further includes at least one tackifying additive compatible with said polymer blend and a sulfur and organic accelerator cure package for said polymer blend, the adhesive composition being devoid of butyl rubber which is found in most other adhesive tape compositions. This composition is seen as providing excellent long-term heat aging, weathering resistance, and low temperature properties as compared to adhesive tape compositions containing butyl rubber. Moreover, the adhesive tape composition provides more surface tack, better "quick-grab", and higher green strength as compared to adhesive tape compositions containing 100 percent EPDM rubber.Type: GrantFiled: April 1, 1996Date of Patent: January 12, 1999Assignee: Bridgestone/Firstone, Inc.Inventors: James A. Davis, John W. Fieldhouse
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Patent number: 5849392Abstract: The present invention provides a thread wound golf ball having improved flight performances, which comprises a solid center, a thread layer and an outer cover. The solid center is formed from a rubber component with crosslinked structure which contains an oily substance. Impact resilience of the solid center is 90 cm or more.Type: GrantFiled: June 7, 1993Date of Patent: December 15, 1998Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Akihiko Hamada, Akira Kato, Keiji Moriyama, Kuniyasu Horiuchi, Tadahiro Ebisuno
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Patent number: 5798416Abstract: Provided is an automobile vibration-isolating rubber composition, characterized in that a rubber component comprises from 10 to 80% by weight of a polybutadiene rubber which is obtained through the polymerization using a rare-earth element catalyst and which has a cis content of 97% or more, and from 90 to 20% by weight of at least one type of a rubber selected from a natural rubber, a synthetic polyisoprene rubber and a polystyrene-butadiene copolymer rubber. The automobile vibration-isolating rubber obtained by vulcanizing the rubber composition of the present invention has a low dynamic factor compared to the conventional product, making it possible to decrease automobile passenger compartment noise caused by road noise.Type: GrantFiled: July 11, 1996Date of Patent: August 25, 1998Assignee: Toyo Tire & Rubber Co., Ltd.Inventors: Tsuneo Kamata, Makoto Niki, Yoshihide Ueda
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Patent number: 5780551Abstract: This invention concerns novel, unsymmetrically protected, telechelically functionalized linear and star or multi-arm polymers, their optionally hydrogenated analogues, the polymers produced by selective removal of the protecting groups, the segmented block polymers produced by further reaction of these selectively deprotected polymers with selected comonomers, and the processes to prepare these polymers.Type: GrantFiled: June 3, 1996Date of Patent: July 14, 1998Assignee: FMC CorporationInventors: John F. Engel, James A. Schwindeman, Roderic P. Quirk, Conrad W. Kamienski
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Patent number: 5753761Abstract: The present invention relates to the utilization of trans 1,4-polybutadiene resin having a melting point of at least 30.degree. C. in rubber compositions. The invention, in one aspect, relates to replacing, or at least partially replacing, natural rubber with a pre-blend of trans 1,4-polybutadiene resin and synthetic cis 1,4-polyisoprene rubber. The invention particularly relates to preparation and utilization of a pre-blend of trans 1,4-polybutadiene resin and synthetic cis 1,4-polyisoprene rubber by blending individual polymerizate cements, drying the pre-blend, and use of such pre-blend in the preparation of rubber compositions and of manufactured products such as, for example, tires.Type: GrantFiled: December 27, 1996Date of Patent: May 19, 1998Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul Harry Sandstrom, David John Zanzig, Nissim Calderon
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Patent number: 5736593Abstract: The present invention relates to a ternary polymer blend particularly suited for use in tire treads and carcass ply compounds. The ternary blend is composed of, based on 100 parts by weight of the ternary polymer blend, from about 76 to 94 parts by weight of polyisoprene; 3 to 12 parts by weight of epoxidized natural rubber; from about 3 to 12 parts of chlorosulfonated polyethylene.Type: GrantFiled: January 23, 1997Date of Patent: April 7, 1998Assignee: The Goodyear Tire & Rubber CompanyInventor: Paul Harry Sandstrom
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Patent number: 5728766Abstract: Compounds having improved properties of processability and elasticity after heat aging for molded and extruded rubber parts can be prepared by utilizing improved processability EPM and/or EPDM rubber with effective amounts of carbon black prepared in a manner such that it has an average particle size of from 70 to 120 nanometers, a particle size distribution including from 40 to 225 nanometers sized particles, a surface area of 16 to 30 m.sup.2 /g as measured by the BET adsorption, and a structure of 90 to 125 as measured by DBP absorption. The EPM and EPDM rubber useful in accordance with the invention will include those multimodal polymer blends that comprise at least two fractions having different molecular weight and, optionally, monomer composition. The invention compounds find particular use in automotive industry parts requiring high temperature tolerance, such as coolant hoses.Type: GrantFiled: January 9, 1995Date of Patent: March 17, 1998Assignee: Exxon Chemical Co.Inventors: Jean-Roch Hector Schauder, Timothy Arthur Mills
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Patent number: 5710218Abstract: The invention provides ethylene-propylene-diene rubbers capable of imparting excellent heat resistance, weather resistance and dynamic fatigue resistance to vulcanized rubbers made therefrom. The ethylene-propylene-diene rubbers have sulfur dispersed therein at a temperature of 90.degree. to 160.degree. C. prior to the addition of vulcanization accelerators or other rubber additives. The ethylene-propylene-diene rubbers contain (A) 90 to 40% by weight of a high-molecular weight ethylene-propylene-diene copolymer rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 3.0 to 5.0 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, (B) 10 to 60% by weight of a low-molecular-weight ethylene-propylene-diene copolymer rubber having an ethylene content of 60 to 82 mol %, an intrinsic viscosity (.eta.) of 0.15 to 0.8 dl/g as measured at 135.degree. C. in decalin and an iodine value of 8 to 35, and (C) sulfur in an amount of 0.Type: GrantFiled: April 28, 1995Date of Patent: January 20, 1998Assignee: Mitsui Petrochemical IndustriesInventors: Hidenari Nakahama, Takashi Mishima
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Patent number: 5698639Abstract: The invention provides ethylene-propylene-diene rubbers capable of imparting excellent heat resistance, weather resistance and dynamic fatigue resistance to vulcanized rubbers made therefrom. The ethylene-propylene-diene rubbers have sulfur uniformly dispersed therein by mixing a solution of the sulfur with a solution of the ethylene-propylene-diene rubber prior to the addition of vulcanization accelerators or other rubber additives to the rubbers. The vulcanized rubbers are particularly suitable for use as automobile components which require dynamic fatigue resistance such as muffler hangers, belts, rubber vibration insulators, engine mounts, tire treads for pneumatic tires, sidewalls for pneumatic tires and white sidewalls.Type: GrantFiled: August 21, 1996Date of Patent: December 16, 1997Assignee: Mitsui Petrochemical Industries, Ltd.Inventors: Hidenari Nakahama, Takashi Mishima
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Patent number: 5695850Abstract: The present invention provides performance enhancing shoe components, and methods of making the same, comprising 1,4-polybutadiene and a rubber selected from the group consisting of natural rubber, synthetic isoprene rubber, polyisoprene, butadiene acrylonitrile rubber and ethylenepropylene diene modified rubber. The shoe components are most advantageously placed in the user shoe beneath the ball of the foot to increase energy return and thereby enhance athletic performance. The shoe components may be formed as midsoles and parts of midsoles, insoles and parts of insoles, or shoe inserts.Type: GrantFiled: March 15, 1996Date of Patent: December 9, 1997Inventor: William R. Crow
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Patent number: 5684089Abstract: A pregellable adhesive containing several polymers, of which at least one is olefinically unsaturated and the other capable of curing by esterification, prepared in such a way that it cures by two different chemical reaction mechanisms which can be activated successively and catalyzed at least substantially independently of one another.Type: GrantFiled: December 13, 1996Date of Patent: November 4, 1997Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Thierry Lanoye, Anne-Marie Garnault
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Patent number: 5644000Abstract: A low shear modulus vulcanizate for construction of flexible bearings, particularly for rocket motors, consisting essentially of a mixture of two natural or synthetic rubber copolymers, the first having about 92% cis-1,4-polyisoprene and about 8% trans-1,4-polyisoprene moieties and the second having about 98% by weight cis-1,4-polyisoprene and about 2% by weight trans-1,4-polyisoprene moieties. The composition is lightly filled and contains a low proportion of sulfur, so the vulcanizate has the required low shear modulus, low rate of thermal crystallization at low temperatures, and an acceptably high shear strength.Type: GrantFiled: March 10, 1989Date of Patent: July 1, 1997Assignee: Thiokol CorporationInventor: David G. Guillot
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Patent number: 5637645Abstract: The invention relates to a caoutchouc mixture for the manufacture of rubber products with low-temperature application capability, resistance to oil, low crystallization tendency, and high dynamic stressability, on the basis of natural caoutchouc, in particular viscosity-stabilized natural caoutchouc, and the usual mixture ingredients. The essence of said invention lies in that the caoutchouc mixture additionally contains 5 to 30% by weight 1,4-polybutadiene with a high cis-proportion, and 5 to 30% by weight epoxidized natural caoutchouc. An additional mixture variation is introduced.Type: GrantFiled: May 23, 1994Date of Patent: June 10, 1997Assignee: Phoenix AktiengesellschaftInventors: Manfred Klerk, Gerhard Merkmann, Karl-Heinz Krause
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Patent number: 5626697Abstract: A pneumatic rubber tire having a rubber sidewall composition containing trans 1,4-polybutadiene rubber and at least one additional rubber.Type: GrantFiled: June 27, 1996Date of Patent: May 6, 1997Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul H. Sandstrom, Thomas J. Segatta, Johnny D. Massie, II
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Patent number: 5627237Abstract: This invention reveals a pneumatic tire having an outer circumferential tread wherein said tread is a sulfur-cured rubber composition comprised of, based on 100 parts by weight of rubber, (1) from about 5 to about 50 parts of 3,4-polyisoprene rubber, wherein said 3,4-polyisoprene rubber has (a) a 3,4-isomer content of from 75 percent to 95 percent, (b) a 1,2-isomer content of from 5 percent to 25 percent, (c) a glass transition temperature from 0.degree. to 25.degree. C. and (d) a number average molecular weight which is within the range of 30,000 to 180,000; and (2) from about 50 to about 95 parts of a rubbery polymer which is co-curable with the 3,4-polyisoprene rubber.Type: GrantFiled: May 6, 1996Date of Patent: May 6, 1997Assignee: The Goodyear Tire & Rubber CompanyInventors: Adel F. Halasa, Wen-Liang Hsu, David J. Zanzig, Gerald L. Allen, Laurie E. Austin
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Patent number: 5616639Abstract: The invention relates to a tire with a rubber tread which is primarily reinforced with silica where the rubber of the said tread is composed of an elastomer base of at least three butadiene based synthetic rubbers comprised of two isoprene/butadiene copolymer elastomers having spatially defined Tg's, and a cis 1,4-polybutadiene elastomer.Type: GrantFiled: May 24, 1995Date of Patent: April 1, 1997Assignee: The Goodyear Tire & Rubber CompanyInventor: Danielle Lucas
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Patent number: 5612436Abstract: The subject invention discloses an isoprene-butadiene diblock rubber which is particularly valuable for use in making treads for tires which have improved wear characteristics without compromising traction characteristics or rolling resistance. Said isoprene-butadiene diblock rubber is comprised of (1) a first block which is comprised of repeat units which are derived from 1,3-butadiene and (2) a second block which is comprised of repeat units which are derived from both 1,3-butadiene and isoprene, wherein the repeat units derived from isoprene and 1,3-butadiene in the second block are in an essentially random order, wherein the diblock rubber has a glass transition temperature which is within the range of about -100.degree. C. to about -70.degree. C., and wherein the diblock rubber has a Mooney viscosity which is within the range of about 50 to about 140.Type: GrantFiled: September 8, 1995Date of Patent: March 18, 1997Assignee: The Goodyear Tire & Rubber CompanyInventors: Adel F. Halasa, Wen-Liang Hsu, David J. Zanzig, Paul H. Sandstrom, Laurie E. Austin
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Patent number: 5597860Abstract: The present invention provides a vulcanizable rubber composition comprising 100 parts by weight of a polymer component consisting of 30 to 80 wt. % of an ethylene.cndot..alpha.-olefin.cndot.non-conjugated diene copolymer having a Mooney viscosity of 10 to 100 (ML.sub.1+4 100.degree. C.) and an iodine value of 20 to 45 and containing ethylene and .alpha.-olefin in a weight ratio of 50:50 to 90:10, and 20 to 70 wt. % of a styrene-conjugated diolefin block copolymer, 20 to 150 parts by weight of a reinforcing filler, 3 to 30 parts by weight of sulfur, 0 to 50 parts by weight of a styrene resin and 0 to 100 parts by weight of an extending oil.Type: GrantFiled: July 21, 1995Date of Patent: January 28, 1997Assignees: Sumitomo Chemical Company Limited, Toyoda Gosei Co., Ltd.Inventors: Masashi Aoshima, Hironobu Shigematsu, Takeru Wadaki, Toshikatsu Kanehara, Kazuya Watanabe, Toshiyuki Tanaka
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Patent number: 5591279Abstract: A pneumatic tire having a tread composed of a matrix rubber, a low hardness rubber powder, hollow particulates, and short fibers, and optionally a liquid polymer, wherein the low hardness rubber powder has an average particle size of less than 1000 .mu.m, including or not including no more than 20 parts by weight of carbon per 100 parts by weight of the rubber component in the low hardness rubber powder, and is contained in an amount of 1 to 10 parts by weight per 100 parts by weight of the matrix rubber, the hollow particulates have an average particle size of 10 to 120 .mu.m and an average thickness of 0.1 to 15 .mu.m, and the short fibers have an aspect ratio (ratio of length/diameter) of 10 to 1000.Type: GrantFiled: May 19, 1994Date of Patent: January 7, 1997Assignee: The Yokohama Rubber Co., Ltd.Inventors: Shingo Midorikawa, Masaaki Harada, Takanori Kondoh
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Patent number: 5585440Abstract: The present invention provides a rubber composition having high impact residence, preferred processability and workability which may be used for the manufacture of one-piece solid golf ball, solid core of multi-layered solid golf ball, solid center of thread-wound golf ball, etc. The rubber composition is characterized by that a rubber component is made from a mixture of:(1) 60 to 95 wt % of a polybutadiene containing at least more than 40% of cis-1,4 bond and having a Mooney viscosity [ML.sub.1+4 (100.degree. C.)] of 50 to 70, obtained by using lanthanum rare earth-based catalyst, nickel-based catalyst or cobalt-based catalyst, or a mixture thereof with another polybutadiene obtained by using a catalyst other than the above mentioned one, and(2) 5 to 40 wt % of a polyisoprene containing at least more than 90% of cis-1,4 bond and a Mooney viscosity of 70 to 90.Type: GrantFiled: December 21, 1993Date of Patent: December 17, 1996Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Mikio Yamada, Yoshikazu Yabuki, Seiichiro Endo
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Patent number: 5580930Abstract: Diene polymers having a high content of trans-1,4 addition and two distinct melting points in the ranges of 30.degree. C. to 60.degree. C. and 70.degree. C. to 130.degree. C. are useful as additives to tire rubbers to improve processability by reducing compound Mooney viscosity and reducing the shrinkage of various compound stocks.Type: GrantFiled: June 6, 1995Date of Patent: December 3, 1996Assignee: Bridgestone CorporationInventors: Jung W. Kang, Thomas J. Lynch, Jason T. Poulton
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Patent number: 5571350Abstract: A pneumatic tire for all seasons comprises a tread provided with a foamed rubber containing a given amount of a particular resin such as crystalline syndiotactic 1,2 -polybutadiene having specified hardness and average particle size, and having specified expansion ratio, average expanded cell size and storage modulus (E') at -20.degree. C. of a given range, and exhibits satisfactory braking and traction performances at not only dry-on-ice state but also wet-on-ice state while sufficiently holding the steering stability, durability and low fuel consumption in summer season.Type: GrantFiled: June 6, 1995Date of Patent: November 5, 1996Assignee: Bridgestone CorporationInventors: Hiroyuki Teratani, Masanori Aoyama
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Patent number: 5554694Abstract: Performance enhancing shoe components, and methods of making the same, comprising 1,4-polybutadiene and a rubber selected from the group consisting of natural rubber, synthetic isoprene rubber, polyisoprene, butadiene acrylonitrile rubber and ethylenepropylene diene modified rubber. The shoe components may be formed as shoe midsoles and parts of midsoles, shoe soles and parts of soles, shoe insoles and parts of insoles, and shoe inserts.Type: GrantFiled: March 23, 1995Date of Patent: September 10, 1996Inventor: William R. Crow
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Patent number: 5545685Abstract: An adhesive tape composition includes a polymer blend comprising at least one EPDM rubber, and preferably three EPDM rubbers in substantially equal amounts, and an adhesive-enhancing polymer selected from the group consisting of polyisoprene, polybutadiene, and ethylene-propylene copolymer and mixtures thereof. The tape adhesive composition further includes at least one tackifying additive compatible with said polymer blend and a sulfur and organic accelerator cure, package for said polymer blend, the adhesive composition being devoid of butyl rubber which is found in most other adhesive tape compositions. This composition is seen as providing excellent long-term heat aging, weathering resistance, and low temperature properties as compared to adhesive tape compositions containing butyl rubber. Moreover, the adhesive tape composition provides more surface tack, better "quick-grab", and higher green strength as compared to adhesive tape compositions containing 100 percent EPDM rubber.Type: GrantFiled: April 28, 1995Date of Patent: August 13, 1996Assignee: Bridgestone/Firestone, Inc.Inventors: James A. Davis, Joseph R. Hoppert, Chester T. Chmiel, Brian S. Alexander
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Patent number: 5534592Abstract: This invention reveals a high performance polybutadiene rubber blend comprised of (a) a first polybutadiene rubber, (b) a second polybutadiene rubber, and (c) a third polybutadiene rubber; wherein the first polybutadiene rubber, the second polybutadiene rubber, and the third polybutadiene rubber are selected from the group of consisting of super-high vinyl polybutadiene rubbers having a vinyl content which is within the range of 80 percent to 100 percent, high vinyl polybutadiene rubbers having a vinyl content which is within the range of 60 percent to 79 percent, medium vinyl polybutadiene rubbers having a vinyl content which is within the range of 35 percent to 59 percent, and low vinyl polybutadiene rubbers having a vinyl content which is within the range of 8 percent to 34 percent; wherein at least three members selected from the group consisting of super-high vinyl polybutadiene rubbers, high vinyl polybutadiene rubbers, medium vinyl polybutadiene rubbers, and low vinyl polybutadiene rubbers are includedType: GrantFiled: September 22, 1995Date of Patent: July 9, 1996Assignee: The Goodyear Tire & Rubber CompanyInventors: Adel F. Halasa, Wen-Liang Hsu, David J. Zanzig, Paul H. Sandstrom, Steven K. Henning, Danielle Lucas
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Patent number: 5523356Abstract: The invention provides plastoelastomer compositions obtained by dynamic vulcanization, in the presence of vulcanizing agents, of a polymeric mixture comprising:a) 15-70 wt % of polypropylene,b) 2-20 wt % of polyisobutene,c) 20-70 wt % of ethylene/propylene/diene elastomer terpolymer (EPDM),d) 0-35 wt % of ethylene/propylene elastomer copolymer (EPM),e) 3-30 wt % of polybutadiene.Type: GrantFiled: August 30, 1995Date of Patent: June 4, 1996Assignee: Enichem Elastomeri S.r.l.Inventors: Enrico Aldrovandi, Luca Norfo, Patrizia Piancastelli, Gian A. Saggese, Roger Lionnet
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Patent number: RE35293Abstract: Disclosed is a solid golf ball containing at least one rubber portion formed from a rubber composition comprising a base rubber, a co-crosslinking agent and an organic peroxide; an improvement being present in that the base rubber is a mixture of(A) a solid polybutadiene rubber containing cis-1,4 bonds in an amount of at least 40%, and(B) either a liquid polybutadiene rubber or a liquid isoprene-butadiene copolymer rubber, or both.Type: GrantFiled: March 16, 1995Date of Patent: July 9, 1996Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Hidenori Hiraoka, Akihiko Hamada