At Least Two Polymers Derived From Reactants Containing Two Or More Ethylenic Groups And Devoid Of An Aryl Ring Patents (Class 525/236)
  • Patent number: 5514721
    Abstract: A composition containing reclaimed vulcanized rubber particles and capable of being recycled by melting is disclosed. A thermoplastic substrate is first melted, and an acid or base deflocculant and emulsifier for the rubber particles is added and mixed. The rubber particles are then added and heated with the substrate under high shear forces to redo the size of the particles, cause them to swell, and to emulsify the surface. The acid or base deflocculant is then neutralized to its isoelectric point, with the surfaces of the altered rubber particles in phase with the thermoplastic substrate.
    Type: Grant
    Filed: November 9, 1994
    Date of Patent: May 7, 1996
    Assignee: Laser Supply, Inc.
    Inventor: Eric R. Hart
  • Patent number: 5512638
    Abstract: The present invention provides for sulfur curable compositions containing a halogenated copolymer of a C.sub.4 to C.sub.7 isomonoolefin, e.g., isobutylene and a para-alkylstyrene, e.g., para-methylstyrene, and further containing a polyunsaturated fatty acid glyceride having an iodine value in excess of 100, e.g. tung oil. The composition may comprise a mixture of the halogenated copolymer and at least one other unsaturated elastomer. In-situ reaction between the halogenated copolymer and the fatty acid glyceride during rubber compounding imparts unsaturation to the halogenated copolymer which permits facile vulcanization and covulcanization using conventional sulfur curatives.
    Type: Grant
    Filed: April 4, 1995
    Date of Patent: April 30, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Kevin O'Donnell
  • Patent number: 5512626
    Abstract: Rubber composition for a base tread, which is obtainable by blending, per 100 parts by weight of a rubber component, 30 to 55% by weight of a carbon black having an iodine adsorption value of from 40 to 100 g/kg, wherein the rubber component comprises (A) 20 to 55% by weight of a star shaped solution-polymerized butadiene rubber and (B) 45 to 80% by weight of a natural rubber or a natural rubber containing a diene rubber other than a star shaped solution-polymerized rubber in an amount of not more than 50% by weight. When using the above-mentioned rubber composition for the base tread of a base portion of a tread having a cap/base two-layer structure, it is possible to save fuel consumption of the tire because of small deformation and uniform shape.
    Type: Grant
    Filed: October 7, 1994
    Date of Patent: April 30, 1996
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Toshiro Matsuo, Naohiko Kikuchi
  • Patent number: 5504140
    Abstract: Pneumatic rubber tire with a tread composed of a rubber blend of a base of at least two synthetic elastomers composed of (i) specialized isoprene/butadiene copolymer elastomer having a low Tg in a range of about -70.degree. to about -100.degree. C. and (ii) a diene based elastomer having a Tg in a range of about -5.degree. to about -30.degree. C. together with a minor amount of natural cis 1,4-polyisoprene rubber. Selection of the base of the said two synthetic elastomers having spaced apart, or spatially defined, Tg's of at least 40.degree. C. is an important feature of the tread rubber blend. Representative examples of contemplated elastomers with Tg's in a range of about -5.degree. to about -30.degree. C. are 3,4-polyisoprene elastomer, styrene/isoprene copolymer elastomer and high vinyl polybutadiene elastomers.In one aspect, the tread rubber blend is reinforced with reinforcing filler composed of carbon black or a combination of carbon black and silica accompanied by a coupling agent.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: April 2, 1996
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: David J. Zanzig, Paul H. Sandstrom, John J. A. Verthe, Raymond R. DiRossi, Gregory M. Holtzapple
  • Patent number: 5504136
    Abstract: An adhesive tape composition includes a polymer blend comprising at least one EPDM rubber, and preferably three EPDM rubbers in substantially equal amounts, and an adhesive-enhancing polymer selected from the group consisting of polyisoprene, polybutadiene, and ethylene-propylene copolymer and mixtures thereof. The tape adhesive composition further includes at least one tackifying additive compatible with said polymer blend and a sulfur and organic accelerator cure package for said polymer blend, the adhesive composition being devoid of butyl rubber which is found in most other adhesive tape compositions. This composition is seen as providing excellent long-term heat aging, weathering resistance, and low temperature properties as compared to adhesive tape compositions containing butyl rubber. Moreover, the adhesive tape composition provides more surface tack, better "quick-grab", and higher green strength as compared to adhesive tape compositions containing 100 percent EPDM rubber.
    Type: Grant
    Filed: October 27, 1994
    Date of Patent: April 2, 1996
    Assignee: Bridgestone/Firestone, Inc.
    Inventors: James A. Davis, Joseph R. Hoppert, Chester T. Chmiel, Brian S. Alexander
  • Patent number: 5480932
    Abstract: A polypropylene resin composition comprising: (a) 50 to 90% by weight of polypropylene, (b) 50 to 10% by weight of an ethylene-.alpha.-olefin copolymer elastomer having a Mooney viscosity (ML 1+4 (100.degree. C.)) of 10 to 100, (c) 0.5 to 10 parts by weight per 100 parts by weight of the total of the amounts of the components (a) and (b) of a linear olefinic polymer containing hydroxyl group which is liquid at room temperature, and (d) 0.5 to 15 parts by weight per 100 parts by weight of the total of the amounts of the components (a) and (b) of a linear olefinic polymer having a melting point of about 70.degree. to about 90.degree. C. and a number-average molecular weight of 1500 to 6000 and containing hydroxyl group or carbonyl group; and a protective strip for automobiles using the polypropylene resin composition are disclosed. Coating immediately after degreasing is made possible and excellent property for coating can be provided by using the polypropylene resin composition.
    Type: Grant
    Filed: June 27, 1994
    Date of Patent: January 2, 1996
    Assignees: Idemitsu Petrochemical Co., Ltd., Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Yutaka Kobayashi, Osamu Aoki, Kenji Hamabe, Atsushi Takeuchi, Takayuki Onda
  • Patent number: 5468822
    Abstract: A 1,2-polybutadiene composition having an excellent reinforcing effect for rubber and synthetic resin materials including at least two polybutadiene components different in melting point from each other and each having, as a main structure, a 1,2-polybutadiene structure, produced by polymerizing a 1,3-butadiene-containing monomer in a water-containing polymerization system in the presence of a catalyst comprising a transition metal compound, an organic compound of one of the Group I to III metals, and one of carbon disulfide, phenyl isothiocyanate, and xanthic acid compounds, while adding a melting point-regulating agent comprising at least one of ketones, aldehydes, alcohols, esters, nitriles, sulfoxides, amides, and phosphoric acid esters in one or two or more separate adding operations or a continuous adding operation.
    Type: Grant
    Filed: February 8, 1994
    Date of Patent: November 21, 1995
    Assignee: UBE Industries, Ltd.
    Inventors: Nohiro Tsujimoto, Kenichi Hongyo, Yoshisuke Baba, Michinori Suzuki, Kazuhiro Akikawa
  • Patent number: 5457159
    Abstract: Process for the preparation of plastoelastomeric preparations comprising an elastomeric phase of an EPDM elastomer and a plastomeric phase of a thermoplastic olefinic polymer, wherein the elastomeric phase is dynamically vulcanized with a vulcanizing binary agent consisting of an alkylphenol-formaldehydic resin and sodium bisulphite.
    Type: Grant
    Filed: December 9, 1993
    Date of Patent: October 10, 1995
    Assignee: Paranova Articoli Tecnici S.r.l.
    Inventors: Roberto Fassina, Alessandro Fassina
  • Patent number: 5453466
    Abstract: Disclosed are polyolefin compositionshaving high balance of stiffness and impact strength, which comprise (percentage by weight):A) 30%-60% of a propylene homopolymer or copolymer;B) 14%-30% of a fraction comprising copolymers of propylene with ethylene;C) 10%-25% of a copolymer of ethylene with a C.sub.3 -C.sub.8 .alpha.-olefin;D) 5%-45% of a mineral filler.
    Type: Grant
    Filed: August 29, 1994
    Date of Patent: September 26, 1995
    Assignee: Montell North America Inc.
    Inventors: Giampaolo Pellegatti, Anteo Pelliconi, Antonio Ciarrocchi
  • Patent number: 5447971
    Abstract: The invention relates to a tire with a tread which is reinforced with silica where the tread rubbers are of a blend of emulsion SBR with medium to high styrene content, isoprene/butadiene copolymer rubber, cis 1,4-polybutadiene rubber and natural rubber.
    Type: Grant
    Filed: October 12, 1994
    Date of Patent: September 5, 1995
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Jean Bergh, Marc Junio, Jean-Claude J. M. Kihn
  • Patent number: 5434212
    Abstract: A rubber composition for an inner liner comprises a coumarone resin and a member selected from the group consisting of natural rubber, synthetic rubber, a blend of natural rubber and synthetic rubber, and a blend of synthetic rubbers. The rubber composition for inner liner exhibits good shrinkage resistance and good inner pressure retaining property without deteriorating a running durability of a tire where the rubber composition is used as an inner liner.
    Type: Grant
    Filed: November 7, 1994
    Date of Patent: July 18, 1995
    Assignee: Bridgestone Corporation
    Inventors: Joji Yatsunami, Takuo Yasuda
  • Patent number: 5420193
    Abstract: A heavy duty vehicle pneumatic tire comprising a tread, wherein the tread is composed of a diene-based rubber composition, and crystalline syndiotactic-1,2-polybutadiene is incorporated into said rubber composition in an amount of 5 to 60 parts by weight relative to 100 parts by weight of a diene-based rubber component of the rubber composition. The syndiotactic 1,2-polybutadiene has a melting point of 130.degree. to 170.degree. C., an average particle diameter of not more than 100 .mu.m, and a ratio of a major axis to a minor axis (L/D) being not more than 3. The content of 1,2-structural units in the syndiotactic-1,2 polybutadiene is not less than 75% by weight, and a syndiotacticity of the 1,2-structural units is not less than 75%.
    Type: Grant
    Filed: September 21, 1993
    Date of Patent: May 30, 1995
    Assignee: Bridgestone Corporation
    Inventors: Akihiko Matsue, Toru Ohtake
  • Patent number: 5412035
    Abstract: Pressure-sensitive adhesive (PSA) compositions containing a crystalline polymeric additive having an M.sub.w of less than 25,000 and a melting point (T.sub.a) greater than 23.degree. C., preferably 30.degree. to 60.degree. , and PSA composites of a backing, preferably a flexible backing, with such a PSA composition coated thereon. The presence of the additive causes the PSA to lose adhesive strength when heated to T.sub.a. The base resin of the PSA is preferably a polyacrylate or a styrene/butadiene copolymer. The additive, which is preferably present in amount 1 to 35%, e.g. 5 to 30%, is preferably a side chain crystallizable (SCC) polymer.
    Type: Grant
    Filed: August 12, 1992
    Date of Patent: May 2, 1995
    Assignee: Landec Corporation
    Inventors: Edward E. Schmitt, Raymond Clarke, Andrew W. Larson, Steven P. Bitler, Ross S. Tsugita, Donald A. Schultz
  • Patent number: 5409988
    Abstract: The present invention provides a rubber composition comprising:(i) a rubber component comprising 70 to 90% by weight of a styrene-butadiene copolymer rubber (A) containing 20 to 40% by weight of a styrene content and 30 to 60% by weight of a vinyl content in a butadiene portion, which is obtained by solution polymerization, and 10 to 30% by weight of a polybutadiene rubber (B)(ii) a vulcanizing agent in an amount of 0.75 to 1.75 parts by weight based on 100 parts by weight of the rubber component (i) and(iii) a plasticizer;wherein the plasticizer is present in an amount such that the amount of acetone extract obtained by extracting a vulcanized rubber sample obtained from the rubber composition with a Soxhlet apparatus in an acetone solvent for 24 hours is 20 to 26% by weight of the vulcanized rubber sample, and at least 80% by weight of the acetone extract being the plasticizer.
    Type: Grant
    Filed: June 8, 1993
    Date of Patent: April 25, 1995
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventor: Naohiko Kikuchi
  • Patent number: 5408007
    Abstract: A rubber composition permits good adhesion upon crosslinking to fiber materials and offers good adhesion after thermal aging. The rubber composition includes about 1/10 to about 1/1000 mol of an organic peroxide and either about 0.5 or about 10 parts by weight of an organic compound having two or more acrylate groups or methacrylate groups and one or more carboxyl groups in the molecular structure or about 1 to about 30 parts by weight of a carboxy-modified rubber per 100 parts by weight of a rubber crosslinkable with the organic peroxide.
    Type: Grant
    Filed: May 22, 1992
    Date of Patent: April 18, 1995
    Assignee: Mitsuboshi Belting Ltd.
    Inventors: Takahide Mizuno, Masayoshi Nakajima, Takashi Hamada, Nobutake Osako, Kasutoshi Ishida
  • Patent number: 5395891
    Abstract: Mixtures of A) polybutadiene gel and B) other rubbers containing C.dbd.C double bonds, the quantity of polybutadiene gel A), based on the sum of A)+B), being 1 to 70% by weight, show as vulcanizates a favorable combination of the properties hysteresis loss and abrasion resistance.
    Type: Grant
    Filed: June 14, 1993
    Date of Patent: March 7, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Werner Obrecht, Peter Wendling, Robert H. Schuster, Andreas Bischoff
  • Patent number: 5386865
    Abstract: A pneumatic rubber tire having a rubber sidewall composition containing trans 1,4-polybutadiene rubber and at least one additional rubber.
    Type: Grant
    Filed: October 21, 1991
    Date of Patent: February 7, 1995
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Paul H. Sandstrom, Thomas J. Segatta, Johnny D. Massie, II
  • Patent number: 5382629
    Abstract: Vulcanizable rubber compositions are disclosed which contain co-activator of vulcanization which is a polymeric amine, that is, a hydrocarbon polymer with pendent alkyl amine groups. The co-activators impart increased rates of vulcanization with little decrease in scorch delay and very little increase in the modulus of the cured compositions. No increase in heat build-up or decrease in flex-fatigue life is shown. Typical polymers forming the backbone of the co-activators include EPDM rubber and polymers from butadiene or isoprene, with optional co-monomers.
    Type: Grant
    Filed: January 18, 1994
    Date of Patent: January 17, 1995
    Assignee: Monsanto Company
    Inventors: Aubert Y. Coran, Samuel J. Tremont, Leonard H. Davis, Frederick Ignatz-Hoover, Martin P. McGrath
  • Patent number: 5371146
    Abstract: Disclosed is an ethylene copolymer composition having a density of 0.980 to 0.955 g/cm.sup.3 and a melt flow rate (MFR) of 0.1 to 100 g/10 min., which is formed from two kinds of ethylene/.alpha.-olefin copolymers having specific properties and having density and MFR different from each other. The ethylene copolymer composition of the invention is excellent in melt tension and flow index within the high-shear-region, and able to form films of high transparency, high mechanical strength and blocking resistance.
    Type: Grant
    Filed: September 3, 1993
    Date of Patent: December 6, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Mamoru Takahashi, Akira Todo, Shin-ya Matsunaga, Toshiyuki Tsutsui
  • Patent number: 5356939
    Abstract: A process of producing a rubber article which is economical and environmentally beneficial in that it provides for the recycling of ground cured rubber into uncured rubber compositions which need only be molded or shaped into their final form.
    Type: Grant
    Filed: June 21, 1993
    Date of Patent: October 18, 1994
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Thomas G. Burrowes, Bobby L. Purviance, Charles W. Quiner, Delyn M. Stork
  • Patent number: 5354487
    Abstract: Compositions of high lubrication and light coloration are disclosed in which a selected class of resins and rubbers is blended with a specified cured polybutadiene product. The cured product results from crosslinking more than 10% of vinyl bonds in a butadiene polymer having a vinyl bond content of not less 20% by mol in terms of its monomer unit. Also disclosed are solid lubricants comprising a specified fluorinated cured polybutadiene and compositions containing the solid lubricant.
    Type: Grant
    Filed: April 5, 1991
    Date of Patent: October 11, 1994
    Assignee: Nippon Oil Co., Ltd.
    Inventors: Nobuo Aoki, Shinichiro Suzuki, Hisatake Sato
  • Patent number: 5349020
    Abstract: There is provided a composition comprising a higher a-olefin copolymer (1) obtained by copolymerization in the presence of a specific olefin polymerization catalyst of a specific higher .alpha.-olefin, a specific .alpha., .omega.-diene of the formula (I) and a specific non-conjugated diene of the formula (II), and a rubber (2) selected from the group consisting of a diene rubber, an ethylene/a-olefin copolymer, a nitrile rubber and a hydrogenated nitrile rubber. The composition is excellent in workability strength characteristics, weatherability, ozone resistance and dynamic fatigue resistance, as well as excellent in adhesive properties to fiber and in vibration-insulating properties and damping properties.
    Type: Grant
    Filed: March 5, 1993
    Date of Patent: September 20, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Keiji Okada, Kazuhiko Murata, Tetsuo Tojo, Masaaki Kawasaki, Toshimasa Takata
  • Patent number: 5341863
    Abstract: A pneumatic tire having a sulfur cured tread is provided comprised of at least one diene rubber and a low density polyethylene having a crystalline melt point in a range of about 104.degree. C. to about 115.degree. C., wherein the said LDPE is mixed with the said rubber at a temperature of about 120.degree. C. to about 170.degree. C. prior to sulfur vulcanizing the blend.A process is also provided for producing a tire in which a hot cured tire is removed from its rigid mold where the tread is comprised of at least one diene rubber and a low density polyethylene (LDPE) having a crystalline melt point in a range of about 104.degree. C. to about 115.degree. C.; and wherein the said LDPE is mixed with the said unvulcanized rubber at a temperature of about 120.degree. C. to about 170.degree. C.
    Type: Grant
    Filed: May 17, 1993
    Date of Patent: August 30, 1994
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Paul H. Sandstrom, Raymond B. Roennau
  • Patent number: 5317062
    Abstract: The subject invention discloses a styrene-isoprene-butadiene rubber which is particularly valuable for use in making truck tire treads, said rubber being comprised of repeat units which are derived from about 5 weight percent to about 20 weight percent styrene, from about 7 weight percent to about 35 weight percent isoprene, and from about 55 weight percent to about 88 weight percent 1,3-butadiene, wherein the repeat units derived from styrene, isoprene and 1,3-butadiene are in essentially random order, wherein from about 25% to about 40% of the repeat units derived from the 1,3-butadiene are of the cis-microstructure, wherein from about 40% to about 60% of the repeat units derived from the 1,3-butadiene are of the trans-microstructure, wherein from about 5% to about 25% of the repeat units derived from the 1,3-butadiene are of the vinyl-microstructure, wherein from about 75% to about 90% of the repeat units derived from the isoprene are of the 1,4-microstructure, wherein from about 10% to about 25% of the re
    Type: Grant
    Filed: July 14, 1993
    Date of Patent: May 31, 1994
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Michael B. Rodgers, Stanley M. Mezynski, Adel F. Halasa, Wen-Liang Hsu, Barry A. Matrana, Joel L. Cox
  • Patent number: 5314187
    Abstract: A golf ball includes a core and a cover which is formed from two separate inner and outer layers. The inner layer is molded over the core and is formed from ionomer resin. The outer layer is molded over the inner layer and is formed from a blend of natural or synthetic balata and a crosslinkable elastomer such as polybutadiene. The elastomer is thermally crosslinked with a metallic salt of an unsaturated fatty acid, such as zinc diacrylate, and a crosslinking initiator such as organic peroxide.
    Type: Grant
    Filed: June 29, 1992
    Date of Patent: May 24, 1994
    Assignee: Wilson Sporting Goods Co.
    Inventor: James R. Proudfit
  • Patent number: 5312870
    Abstract: A method for bleaching hydrocarbon tackifier resins which comprises adding a bleaching agent to a molten resin and recovering a bleached hydrocarbon tackifier resin. The bleaching agent comprises from about 0.04 wt. % to about 0.06 wt. %, based on the weight of the reaction mixture, of an iodine supplying compound and from about 2.0 wt. % to about 10.0 wt. %, based on the weight of the reaction mixture, of an activating terpene compound. The iodine supplying compound is selected from the group consisting of elemental iodine and hydrogen iodide. The activating compound is selected from the group consisting of .alpha.-terpinene, .gamma.-terpinene, d-limonene, 1,4-cyclohexadiene and abietic acid.
    Type: Grant
    Filed: May 25, 1993
    Date of Patent: May 17, 1994
    Assignee: Arizona Chemical Company
    Inventor: Theodore J. Williams
  • Patent number: 5294663
    Abstract: The present invention provides an emulsion polymerization synthetic isoprene-styrene/butadiene rubber for use in improved tire tread compositions is provided. The improved composition is a blend of a 1,4 cis-polyisoprene such as natural rubber and a synthetic rubber produced by emulsion polymerization which synthetic rubber includes isoprene and either styrene or butadiene or both styrene and butadiene. The tire tread composition has an excellent balance of good wear resistance and low rolling resistance as well as a low T.sub.g and good traction. These improved qualities for tire tread compositions have heretofore been unavailable in rubbers utilizing emulsion polymers, and have been achievable only with tire compositions including synthetic rubbers that are produced by solution polymerization.
    Type: Grant
    Filed: August 28, 1992
    Date of Patent: March 15, 1994
    Assignee: General Tire, Inc.
    Inventors: Hubert J. Fabris, Ivan G. Hargis, Russell A. Livigni, Richard M. Wise
  • Patent number: 5292845
    Abstract: The ethylene/.alpha.-olefin/7-methyl-1,6-octadiene copolymer rubber of the invention is a random copolymer rubber prepared using a Group IVB transition metal type catalyst containing a specific zirconium catalyst component, and in this copolymer rubber, a molar ratio of ethylene to .alpha.-olefin, a diene content, an intrinsic viscosity [.eta.], an intensity ratio D of T.alpha..beta. to T.alpha..alpha. in a .sup.13 C-NMR spectrum of said copolymer rubber, a B value which is a measure of distribution of each monomer and a glass transition temperature are all within specific ranges. The rubber composition of the invention comprises the above-mentioned random copolymer rubber and a conjugated diene rubber. The random copolymer rubber has high stereoregularity, narrow composition distribution and excellent low-temperature flexibility, and shows extremely high covulcanizability with the conjugated diene rubber.
    Type: Grant
    Filed: January 21, 1993
    Date of Patent: March 8, 1994
    Assignee: Mitsui Petrochemical Industries, Ltd.
    Inventors: Masaaki Kawasaki, Toshimasa Takata, Mitsuhiko Onda, Hidenari Nakahama, Kiyoshi Honma
  • Patent number: 5281671
    Abstract: An abrasion-resistant rubber composition comprises as rubber components (A) 30-95 wt. % of an end-modified butadiene polymer and (B) 70-5 wt. % of a diene rubber other than the end-modified butadiene polymer (A). The end-modified butadiene polymer (A) is obtained by reacting at least one compound to active terminals of a starting butadiene polymer having a trans 1,4 bond content of 70-95 wt. %. The at least one compound is selected from N-substituted aminoketones, N-substituted thioaminoketones, N-substituted amino-aldehydes, N-substituted thioaminoaldehydes and compounds containing in the molecules thereof an atomic group represented by the following formula: ##STR1## in which M stands for an oxygen or sulfur atom.
    Type: Grant
    Filed: December 12, 1990
    Date of Patent: January 25, 1994
    Assignees: Nippon Zeon Co., Ltd., The Yokohama Rubber Co., Ltd.
    Inventors: Fumitoshi Suzuki, Yoshihiro Chino, Shuichi Akita
  • Patent number: 5255922
    Abstract: A golf ball cover includes a blend of natural or synthetic balata and a crosslinkable elastomer such as polybutadiene. The elastomer is thermally crosslinked with a metallic salt of an unsaturated fatty acid, such as zinc diacrylate, and a crosslinking initiator such as organic peroxide.
    Type: Grant
    Filed: November 23, 1992
    Date of Patent: October 26, 1993
    Assignee: Wilson Sporting Goods Co.
    Inventor: James R. Proudfit
  • Patent number: 5254653
    Abstract: A styrene, isoprene, butadiene terpolymer rubber with a characterization according to its glass transition temperatures and unit structure and a pneumatic tire with a tread composed of such terpolymer rubber specifically in combination with selected other rubber.
    Type: Grant
    Filed: May 18, 1992
    Date of Patent: October 19, 1993
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Adel F. Halasa, Jean Bergh, Fernand A. J. Fourgon
  • Patent number: 5254628
    Abstract: Diene polymers or copolymers having improved raw polymer viscosity and reduced hysteresis in the cured and carbon black reinforced state are provided. These diene polymers or copolymers comprise a mixture of diene polymer or copolymer chains containing carbon-tin bonds in the main polymer or copolymer chains and diene polymer or copolymer chains containing terminals derived from aromatic nitrile coumpounds.The diene polymer or copolymers are prepared by first coupling a portion of the living diene polymer or copolymer chains obtained by anionic polymerization using a tin polyhalide coupling agent and then terminating the remaining living diene polymer or copolymer chains using aromatic nitrile compounds. The resultant diene polymers or copolymers have improved raw polymer viscosity and when compounded with carbon black and cured have reduced hysteresis properties. The polymers can be utilized to form elastomer compositions for tire treads having reduced rolling resistance.
    Type: Grant
    Filed: November 18, 1991
    Date of Patent: October 19, 1993
    Assignee: Bridgestone Corporation
    Inventors: David F. Lawson, Mark L. Stayer, Jr., Thomas A. Antkowiak
  • Patent number: 5242727
    Abstract: A cured adhesive tape composition for adhering together roofing materials such as synthetic EPDM rubber and which provides long term water tightness is provided. The adhesive composition includes substantially equal amounts by weight of a) a rubbery polymer comprising a blend of an ethylene-propylenediene terpolymer, a halogenated butyl rubber or a halogenated copolymer of p-methylstyrene and isobutylene, and polyisobutylene b) a compatible tackifier, and c) an accelerator/cure package for the rubbery polymer. The cured composition exhibits a peel strength of at least 715 grams/cm at room temperature, at least 300 grams/cm at 70.degree. C., and supports a static load of at least 300 grams at 70.degree. C.
    Type: Grant
    Filed: November 15, 1991
    Date of Patent: September 7, 1993
    Assignee: Adco Products, Inc.
    Inventors: Brian J. Briddell, Michael J. Hubbard
  • Patent number: 5229459
    Abstract: The present invention relates to a rubber stock comprising(A) based on 100 parts by weight of rubber (1) from about 5 to about 15 weight percent of a trans 1,4-polybutadiene rubber wherein at least 65 percent of its butadiene repeat units are a trans 1,4-isomeric structure; and (2) from about 50 to about 95 weight percent of cis 1,4-polyisoprene, and (3) from about 0 to about 30 weight percent of the rubber selected from the group consisting of styrene-butadiene rubber, medium vinyl polybutadiene rubber wherein from about 40 to about 60 percent of its butadiene repeat units are a 1,2-vinyl isomeric structure and a cis 1,4-polybutadiene rubber wherein at least 90 percent of its butadiene repeat units are a cis 1,4-isomeric structure; (B) from about 0.1 to about 10 phr of a methylene acceptor; and (C) from about 0.1 to about 10 phr of a methylene donor.
    Type: Grant
    Filed: October 17, 1991
    Date of Patent: July 20, 1993
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Paul H. Sandstrom, Jerry L. Brenner, Eric C. Mizner
  • Patent number: 5229463
    Abstract: A thermoplastic resin composition which comprises 100 parts by weight of a copolymer of propylene with at least one particular diene monomer or a mixture of said propylene copolymer with another crystalline propylene polymer, of the content of the diene monomer polymerized of 0.05 to 20 mol %; 90 to 300 parts by weight of an olefin copolymer rubber that can be crosslinked by dynamic heat treatment with a crosslinking agent; 50 to 1900 parts by weight relative to a total of 100 parts by weight of the 1st and 2nd components of a crystalline propylene polymer; and 0 to 100 parts by weight relative to a total of 100 parts by weight of the 1st, 2nd and 3rd components of a filler.
    Type: Grant
    Filed: November 15, 1991
    Date of Patent: July 20, 1993
    Assignee: Mitsubishi Petrochemical Company Limited
    Inventors: Kazunori Yano, Akiharu Wakayama
  • Patent number: 5227431
    Abstract: Diene polymer or copolymer compositions having reduced hysteresis are provided. The compositions comprise a mixture of diene polymers or copolymers containing carbon-tin bonds in the main polymer or copolymer chains prepared by coupling polymer or copolymer chains with tin polyhalides and diene polymers or copolymer chains containing terminals derived from substituted imines having the formula: ##STR1## wherein R.sub.1 and R.sub.2 are selected from the group consisting of H, alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl and aprotic O, N and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; wherein R.sub.3 is selected from the group consisting of alkyl, cycloalkyl, aryl, dialkylaminoaryl, aralkyl and aprotic O, N, and S- containing alkyl, cycloalkyl, aryl and aralkyl groups; with the proviso that at least one of the R.sub.1, R.sub.2 and R.sub.3 groups must be a dialkylaminoaryl group and that not all of the R.sub.1, R.sub.2 and R.sub.
    Type: Grant
    Filed: April 12, 1991
    Date of Patent: July 13, 1993
    Assignee: Bridgestone/Firestone, Inc.
    Inventors: David F. Lawson, Mark L. Stayer, Jr., Thomas A. Antkowiak, John R. Schreffler
  • Patent number: 5225258
    Abstract: A rubber composition suitable for producing hollow cores of pressureless tennis balls and superior in rebound properties and feeling of striking balls by racket, which contains, as a rubber component, 30 to 100% by weight of a polybutadiene rubber having a content of cis-1,4 bond of at least 97% by weight and a Z-average molecular weight of 5.times.10.sup.6 to 2.times.10.sup.7 and 70 to 0% by weight of other diene rubbers.
    Type: Grant
    Filed: April 24, 1991
    Date of Patent: July 6, 1993
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Yoshinobu Nakamura, Kuniyasu Horiuchi
  • Patent number: 5223568
    Abstract: A forming process for producing a hard shaped molded article that includes subjecting a moldable thermosetting composition to a high temperature cure condition at a temperature greater than about 250.degree. C. and less than the decomposition temperature of the composition to form a crosslinked polymeric network. In particular, the invention features a forming process for producing a hard shaped molded article that includes the steps of(a) providing a moldable thermosetting composition that includes 1) a polybutadiene or polyisoprene resin which is a liquid at room temperature and which has a molecular weight less than 5,000 and a large number of pendent vinyl groups and 2) a solid butadiene- or isoprene-containing polymer (e.g, a thermoplastic elastomer);(b) forming the composition into a shape; and(c) curing the composition to produce the article including subjecting the composition to a high temperature cure condition at a temperature greater than about 250.degree. C.
    Type: Grant
    Filed: May 9, 1989
    Date of Patent: June 29, 1993
    Assignee: Rogers Corporation
    Inventors: Vincent R. Landi, J. Mark Mersereau, Walter A. Robbins
  • Patent number: 5221714
    Abstract: The present invention relates to a blend of rubber latices comprising, based on dry weight,(A) from about 80 to about 50 phr of a latex selected from the group consisting of polybutadiene latex, natural rubber or polyisoprene latex, styrene-butadiene copolymer latex, acrylonitrile-butadiene copolymer latex, butadiene-isoprene copolymer latex, isoprene-isobutylene copolymer latex, styrene-isoprene-butadiene copolymer latex and mixtures thereof: and(B) from about 20 to about 50 phr of a hydrogenated rubber latex that is prepared in accordance with a process comprising:(1) combining an unsaturated polymer in latex form, which is derived from 5 to 100 percent by weight of a conjugated diene monomer and 95 to 0 percent by weight of an ethylenically unsaturated monomer, with(a) an oxidant selected from the group consisting of oxygen, air and hydroperoxides;(b) a reducing agent selected from hydrazine and hydrates thereof: and(c) a metal ion activator;(2) heating the mixture to a temperature from 0.degree. C.
    Type: Grant
    Filed: April 4, 1991
    Date of Patent: June 22, 1993
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Dane K. Parker
  • Patent number: 5219942
    Abstract: A rubber composition comprises as rubber components (A) 30-95 wt. % of an end-modified styrene-butadiene copolymer and (B) 70-5 wt. % of a diene rubber other than the end-modified styrene-butadiene copolymer (A). The end-modified styrene-butadiene copolymer (A) is obtained by reacting at least one compound to active terminals of a starting styrene-butadiene copolymer containing butadiene moieties, the trans-1,4 bond content of which is 70-95 wt. %, and having a styrene content of 5-60 wt. %. The at least one compound is selected from N-substituted aminoketones, N-substituted thioaminoketones, N-substituted aminoaldehydes, N-substituted thioaminoaldehydes and compounds containing in the molecules thereof an atomic group represented by the following formula: ##STR1## in which M stands for an oxygen or sulfur atom. The diene rubber (B) has a glass transition temperature higher than -60.degree. C.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: June 15, 1993
    Assignees: Nippon Zeon Co., Ltd., The Yokohama Rubber Co., Ltd.
    Inventors: Fumitoshi Suzuki, Yoshihiro Chino, Shuichi Akita
  • Patent number: 5215308
    Abstract: Disclosed is a solid golf ball containing at least one rubber portion formed from a rubber composition comprising a base rubber, a co-crosslinking agent and an organic peroxide; an improvement being present in that the base rubber is a mixture of(A) a solid polybutadiene rubber containing cis-1,4 bonds in an amount of at least 40%, and(B) either a liquid polybutadiene rubber or a liquid isoprene-butadiene copolymer rubber, or both.
    Type: Grant
    Filed: July 2, 1991
    Date of Patent: June 1, 1993
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Hidenori Hiraoka, Akihiko Hamada
  • Patent number: 5212219
    Abstract: A degradable polymer composition is disclosed which comprises a blend of a normally stable chemically saturated polymer, such as polyethylene, a less stable chemically unsaturated polymer or copolymer, such as a styrene/butadiene block copolymer, or natural rubber, an antioxidant active over a limited period and a latent pro-oxidant, such as an organic salt of a transition metal, e.g. cobalt naphthenate. The presence together of the anti-oxidant and the pro-oxidant give rise to a period of induction before a sharp loss of physical strength occurs, whereby the period of induction can be exploited as the effective working life of the polymer composition.
    Type: Grant
    Filed: September 4, 1991
    Date of Patent: May 18, 1993
    Assignee: Epron Industries Limited
    Inventor: Gerald J. L. Griffin
  • Patent number: 5209471
    Abstract: A pressureless tennis ball which has excellent rebound properties and produces a satisfactory feeling of striking retained over a long period of time, the tennis ball having a hollow spherical core made from a rubber composition containing a rubber and 5 to 60 parts by weight of polyethylene per 100 parts by weight of the rubber.
    Type: Grant
    Filed: May 31, 1991
    Date of Patent: May 11, 1993
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Kuniyasu Horiuchi, Yoshinobu Nakamura
  • Patent number: 5196263
    Abstract: A rubber article formed from a rubber composition having a rubber component is provided wherein the article has a texture coating thereon. A texture coating mixture is formed from a mixture of a rubber composition having a rubber component substantially the same as employed to form the rubber article, and rubber particles also having a rubber component substantially the same as that of the rubber article. A method of forming a rubber article is also provided which includes coating a rubber article with such a texture coating mixture.
    Type: Grant
    Filed: October 25, 1991
    Date of Patent: March 23, 1993
    Assignee: H & M Rubber Company, Inc.
    Inventors: Dennis W. Melby, James C. Moore
  • Patent number: 5194485
    Abstract: A rubber composition for tire treads which comprises 100 parts by weight of a rubber component comprising 10 to 100 parts by weight of a styrene-butadiene copolymer rubber produced by a solution polymerization and 90 to 0 parts by weight of at least one of other diene rubbers having a glass transition temperature (Tg) of -60.degree. C. at lowest, and at least 70 parts by weight of a carbon black mixed in the rubber component, the styrene-butadiene copolymer rubber having a styrene content of 45 to 65% by weight, a content of butadiene derived vinyl groups of 20 to 70 parts by weight and a content of a styrene sequence consisting of not less than 8 bonded styrene monomer units of at largest 10% by weight of the above styrene content.
    Type: Grant
    Filed: October 4, 1991
    Date of Patent: March 16, 1993
    Assignees: The Yokohama Rubber Co., Ltd., Nippon Zeon Co., Ltd.
    Inventors: Yasushi Kikuchi, Masayoshi Daio, Kazuyoshi Kayama, Hideyuki Oishi, Shuichi Akita, Fumitoshi Suzuki
  • Patent number: 5191028
    Abstract: A rubber composition containing 100 parts by weight of a diene rubber material, 0.5 to 2.0 parts by weight of N-cyclohexyl-2-benzothiazyl sulfenamide, and 0.02 to 1.0 part by weight of a condensation product of n-butylaldehyde and aniline. Further disclosed is another rubber composition containing 100 parts by weight of a diene rubber material, 1.5 to 2.5 parts by weight of N-cyclohexyl-2-benzothiazyl sulfenamide, 0.02 to 1.0 part by weight of a condensation product of n-butylaldehyde and aniline, and 0.3 to 1.5 part by weight of tetrabutylthiuram disulfide.
    Type: Grant
    Filed: August 26, 1991
    Date of Patent: March 2, 1993
    Assignee: Tokai Rubber Industries, Ltd.
    Inventor: Yutaka Ishioka
  • Patent number: 5171790
    Abstract: An elastomer blend is provided for dissipation of mechanical and sonic eny over a broad temperature range. This blend of elastomers comprises from about 60-95% by weight of polybutadiene having more than about 90% 1,2-microstructure and a molecular weight of at least 80,000, the balance being predominantly polyisoprene having at least about 70% cis-1,4-microstructure and a molecular weight of at least 120,000. The blend has a single glass transition ranging over at least sixty Centigrade degrees.
    Type: Grant
    Filed: April 4, 1990
    Date of Patent: December 15, 1992
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Charles M. Roland, Craig A. Trask
  • Patent number: 5169890
    Abstract: The present invention relates to a thermoplastic hot melt adhesive comprising(a) a block copolymer, said block copolymer being prepared utilizing a bromide based coupling agent, said block copolymer comprising at least two monoalkenyl arene polymer end blocks A and at least one elastomeric conjugated diene polymer mid block B, and said block copolymer having about 8 to about 65 percent by weight of said monoalkenyl arene polymer block content, each polymer block A having an average molecular weight of between about 5,000 and about 125,000, and each polymer block B having an average molecular weight of between about 10,000 and about 300,000,(b) a polyisobutylene rubber,(c) a partially cross-linked polyisobutylene rubber(d) a compatible tackifying resin,(e) a phenolic antioxidant,(f) a non-reactive phenolic resin,(g) a fluorocarbon surface active agent, and(h) a petroleum derived wax.
    Type: Grant
    Filed: October 11, 1991
    Date of Patent: December 8, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Rajan Eadara, Julie Szymborski, Irvin Jackson
  • Patent number: 5164450
    Abstract: Disclosure is herein made of a rubber composition containing at least 30% by weight of a butadiene copolymer which is characterized in that: (i) the content of vinyl bonds in a polybutadiene portion is from 40 to 70%; (ii) the content of bound vinyl aromatic compound is from 25 to 50% by weight: (iii) the ratio Mw/Mn between the weight average molecular weight (Mw) and the number average molecular weight (Mn) when calculated as polystyrene according to the gel permeation chromatograph (GPC) method is from 1.8 to 5, and the distribution of the molecular weight is unimodal; (iv) the rate of the copolymer having the weight average molecular weight of not more than 100,000 when calculated as polystyrene is from 10 to 30%; (v) the rate of the copolymer having the weight average molecular weight of not less than 2,000,000 when calculated as polystyrene is from 10 to 30%; and (vi) the Mooney viscosity (ML.sub.1+4 100.degree. C.) is from 20 to 100.
    Type: Grant
    Filed: September 14, 1990
    Date of Patent: November 17, 1992
    Assignees: Japan Synthetic Rubber Co., Bridgestone Corporation
    Inventors: Fumio Tsutsumi, Mitsuhiko Sakakibara, Yoshihisa Fujinaga, Noboru Oshima, Tatsuo Fujimaki
  • Patent number: H1464
    Abstract: A method for preparing asymmetric radial polymers wherein the different polymeric arms are contacted sequentially with a coupling agent. The method narrows the relative arm distribution of the several asymmetric radial polymers produced and significantly increases the amount of total product having the desired ratio of polymeric arms. Any coupling agent known in the prior art to be useful in the production of asymmetric radial polymers may be used in the method of this invention but coupling agents having from three to about twelve functional groups are most effective.
    Type: Grant
    Filed: November 9, 1993
    Date of Patent: July 4, 1995
    Assignee: Shell Oil Company
    Inventors: Steven S. Chin, Ronald J. Hoxmeier, Bridget A. Spence