Solid Polymer Derived From (meth)acrylonitrile Patents (Class 525/238)
  • Publication number: 20100240834
    Abstract: A method of improving the stress crack resistance of an impact modified styrenic polymer comprising (a) combining about 95 to about 99.5 wt. % of an impact modified styrenic polymer with about 0.5 to about 5 wt. % of a polymer solution comprising about 25 to about 75 wt. % polyisobutylene and about 25 to about 75 wt. % of a polyolefin comprising one or more C2 to C12 alpha olefins.
    Type: Application
    Filed: February 23, 2010
    Publication date: September 23, 2010
    Applicant: INEOS NOVA LLC
    Inventors: Thomas Cochran, Jeffrey P. Viola
  • Patent number: 7795343
    Abstract: A polymer composition including polymer particles comprising a first polymer and a second polymer is disclosed. The first polymer optionally has a crosslinked core and has a glass transition temperature in the range of ?30° C. to 100° C. The second polymer comprising select crosslinking groups has a glass transition temperature in the range of ?10° C. to less than 18° C. A coating composition comprising the polymer composition is provided. The polymer composition has good low temperature film formation and provides a film with an acceptable level of hardness.
    Type: Grant
    Filed: December 12, 2006
    Date of Patent: September 14, 2010
    Assignee: Rohm and Haas Company
    Inventors: Keith Allen Alderfer, Gary William Dombrowski, John Charles Halligan, Kenneth Lennon, Jr.
  • Publication number: 20100204407
    Abstract: A process for the anionic polymerization of monomers, by the step of polymerizing the monomers in the presence of an initiator composition comprising a metal hydride such as sodium hydride and an organyl metal compound such as triisobutylaluminum, the monomers comprising one or more vinylic monomers comprising one or more elements different from carbon and hydrogen.
    Type: Application
    Filed: September 12, 2008
    Publication date: August 12, 2010
    Inventors: Gilbert C.E. Bouquet, Sascha Rulhoff
  • Publication number: 20100075165
    Abstract: The present invention relates to a low surface gloss styrene resin composition. The composition of the present invention is composed of (A) 80-99.9 weight % of the basic resin comprising rubber-modified styrene resin and (B) 0.1-20 weight % of syndiotactic polystyrene, the matting agent. The composition also includes (C) hydrogenated styrene block copolymer comprising styrene block and butadiene rubber block as a compatibilizer by 0.1-20 weight % for the total weight of the low surface gloss styrene resin composed of (A) the basic resin and (B) the matting agent and additionally includes (D) a plasticizer by 0.1-30 weight %. The composition of the present invention has excellent weatherability and impact-resistance in addition to the low surface gloss properties, so that it can be applied in various products, particularly exterior products for structures such as sidings and window frames, etc.
    Type: Application
    Filed: January 30, 2008
    Publication date: March 25, 2010
    Applicant: LG CHEM, LTD.
    Inventors: Yun-kyoung Cho, Seon-mo Son, Bong-keun Lee, Tae-bin Ahn, Han-jong You, Sung-tae Ahn
  • Patent number: 7683131
    Abstract: The invention relates to a moulding composition, comprising a) 50 to 99.9% by weight of a matrix composed of a thermoplastic polymer and b) from 0.1 to 50% by weight of a matting agent in the form of a (meth)acrylate copolymer dispersed in the matrix, characterized in that the matting agent is a (meth)acrylate copolymer which has been prepared from the following monomers, b1) from 50 to 95% by weight of methyl methacrylate b2) from 5 to 50% by weight of C1-C6-alkyl acrylates b3) from 0.01 to less than 0.5% by weight of a crosslinking monomer and/or graft-linking agent having two or more ethylenically unsaturated radicals capable of free-radical polymerization, b4) from 0 to 20% by weight of one or more other, non-crosslinking ethylenically unsaturated monomers capable of free-radical polymerization, where the entirety of the constituents b1) and b2) and, where appropriate, b3) and/or b4) gives 100% by weight, and the glass transition temperature Tmg of the matting agent is at least 20° C.
    Type: Grant
    Filed: September 15, 2004
    Date of Patent: March 23, 2010
    Assignee: Röhm GmbH & Co. KG
    Inventors: Thorsten Goldacker, Andreas Spiess, Reiner Mueller, Klaus Schultes, Uwe Numrich
  • Publication number: 20100041833
    Abstract: An antistatic agent for a thermoplastic resin is provided and includes a sulfonate group introduced into a surface layer part of an aromatic ring-containing thermoplastic resin.
    Type: Application
    Filed: August 5, 2009
    Publication date: February 18, 2010
    Applicant: SONY CORPORATION
    Inventors: Satoru Wakiyama, Yasuhito Inagaki
  • Patent number: 7645833
    Abstract: Novel crosslinkable compositions based on elastomers, at least one of which has carboxyl and/or carboxylate groups, are provided, these crosslinkable compositions containing special unsaturated organic salts of metal ions and a crosslinking system which acts as a free radical donor. Crosslinked elastomers which have excellent physical properties are obtainable therefrom. The novel crosslinkable compositions have a wide range of uses.
    Type: Grant
    Filed: September 25, 2006
    Date of Patent: January 12, 2010
    Assignee: LANXESS Deutschland GmbH
    Inventors: Dirk Achten, Claus Wrana, Christopher Ong, Martin Mezger, Hans Magg, Jürgen Ismeier, Hans-Rafael Winkelbach
  • Publication number: 20090258208
    Abstract: A composition comprising a first polymeric component comprising chlorinated polyvinyl chloride (CPVC); a second polymeric component comprising at least one of (i) a mixture of styrene acrylonitrile (SAN) and an impact modifier, and (ii) a reaction product of the mixture; and a third polymeric component comprising alpha-methylstyrene acrylonitrile (AMSAN). The second and third polymeric components are present in a combined amount of at least about 7 parts by weight based on 100 parts by weight of the composition. The composition has a heat distortion temperature greater than about 180° F. according to ASTM D 648. A composite article comprises a capstock layer comprising a weatherable thermoplastic and a substrate layer comprising the composition.
    Type: Application
    Filed: April 10, 2008
    Publication date: October 15, 2009
    Inventors: Brad J. Martin, Lisa H. Perricane, Michael L. Jackson, Michael J. Haspel
  • Patent number: 7585914
    Abstract: The present invention provides a thermoplastic composition which may be unvulcanized or vulcanized. The thermoplastic composition can be a blend of a thermoplastic engineering resin, a halogenated terpolymer of a C4 to C7 isomonoolefin, a para-alkylstyrene, and a multiolefin. The engineering resin can be a polyamide, such as nylon 6/66 copolymers for example. The isomonoolefin can be an isobutylene for example. The multiolefin can be a C4 to C14 diene, such as isoprene for example.
    Type: Grant
    Filed: November 9, 2005
    Date of Patent: September 8, 2009
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Andy Haishung Tsou, David Yen-Lung Chung
  • Publication number: 20090220786
    Abstract: Methods for modulated degenerative transfer living polymerization and isotactic-atactic stereoblock and stereogradient poly(olefins) thereby Abstract A method of producing a multiblock, stereoblock polyolefin having substantially uniform microstructure is disclosed. The method includes contacting a Ziegler-Natta pre-catalyst with a co-catalyst and an olefin to polymerize the olefin and form a first stereoblock, adding a methyl donator that changes the stereoregularity of the polymerization, and polymerizing the olefin to form a second stereoblock. The methods of the present invention allow for the production of poly(olefin)s having predictable degrees of incorporation of stereoerrors of a known type. The methods allows for the production of a variety of poly(olefin) microstructures, ranging from stereoblock to stereogradient poly(olefin)s and poly(olefin)s having fully isotactic to fully atactic microstructures.
    Type: Application
    Filed: March 17, 2006
    Publication date: September 3, 2009
    Inventors: Lawrence R. Sita, Matthew B. Harney, Yonghui Zhang
  • Patent number: 7572858
    Abstract: Process for the preparation of a thermoplastic elastomer by melt mixing a partially vulcanized rubber concentrate, a thermoplastic polymer and/or additives, optionally oil and a curing agent. The partially vulcanized rubber concentrate is prepared by melt mixing at least one elastomer and optionally oil with a thermoplastic polymer and a curing agent. The elastomer may be EPDM or EPM. The thermoplastic polymer may be chosen from a thermoplastic polyolefin. Useful curing agents are for example sulfur, sulfurous compounds, metal oxides, maleimides, phenol resins, siloxanes or peroxides.
    Type: Grant
    Filed: January 28, 2003
    Date of Patent: August 11, 2009
    Assignee: DSM IP Assets B.V.
    Inventors: Yundong Wang, Ryszard Brozoskowski
  • Patent number: 7572861
    Abstract: The present invention relates to hydrogenated carboxylated nitrile-butadiene rubber (HXNBR), which contain molecularly dispersed triphenylphosphine, and which is useful as a cross-linking agent for elastomers, plastics and/or adhesive systems. The present invention also relates to products which are obtainable from the HXNBR having molecularly dispersed triphenylphosphine and elastomer, plastics and/or adhesive systems, a composition containing a HXNBR having molecularly dispersed triphenylphosphine and further non-molecularly dispersed activators, a process for the preparation of the composition as well as the use of HXNBR having molecularly dispersed triphenylphosphine, as an elasticizing agent for elastomer, plastics and/or adhesive systems.
    Type: Grant
    Filed: October 24, 2007
    Date of Patent: August 11, 2009
    Assignee: Lanxess Deutschland GmbH
    Inventors: Dirk Achten, Hans-Rafael Winkelbach, Martin Mezger
  • Patent number: 7569640
    Abstract: An adhesive sheet comprising at least one heat-activatable adhesive based on a blend of at least one nitrile rubber S1 and at least one nitrile rubber S2, said at least one nitrile rubber S1 having an acrylonitrile fraction of not more than 25% by weight and said at least one nitrile rubber S2 having an acrylonitrile fraction of not less than 30% by weight, and at least one reactive resin.
    Type: Grant
    Filed: December 29, 2005
    Date of Patent: August 4, 2009
    Assignee: tesa SE
    Inventors: Marc Husemann, Frank Hannemann, Matthias Koop
  • Patent number: 7557162
    Abstract: Toughened thermoplastic compositions comprising a thermoplastic polymer toughened by the inclusion of a thermoplastic elastomer derived from a particulate rubber dynamically vulcanized in the presence of a matrix polymer. The toughened thermoplastic composition exhibits properties including toughness, improved impact resistance, and improved hardness. The compositions are utilized wherever toughened, high performance polymers are desired. A method for forming the toughened polymer compositions is also described. Processing methods, such as rotational molding, utilizing the toughened polymer compositions are described.
    Type: Grant
    Filed: January 8, 2004
    Date of Patent: July 7, 2009
    Assignee: Teknor Apex Company
    Inventors: Raman Patel, Harry Howard, Marc Caruthers, Tonya McBride, John J. Wood, III, John C. Andries
  • Patent number: 7550536
    Abstract: The objective of the present invention is to provide an acrylic ester-based copolymer rubber which gives a rubber product excellent in fuel oil resistance and tensile strength and which is crosslinkable with sulfur and/or an organic peroxide and to provide a process for producing the same, as well as a rubber composition, an oil-resistant and weather-resistant rubber composition, and an oil-resistant and weather-resistant rubber product. The acrylic ester-based copolymer rubber of the present invention comprises a structural unit derived from at least one monomer selected from the group consisting of an acrylic acid alkyl ester and an acrylic acid alkoxyalkyl ester in an amount from 40 to 91.9% by mass, a structural unit derived from an unsaturated nitrile monomer in an amount from 8 to 40% by mass, and a structural unit derived from at least one monomer selected from the group consisting of a non-conjugated cyclic polyene and a compound having a specific structure in an amount from 0.
    Type: Grant
    Filed: December 25, 2002
    Date of Patent: June 23, 2009
    Assignee: JSR Corporation
    Inventors: Nobutoshi Kobayashi, Minoru Tsuneyoshi, Katsutaka Yokoi
  • Publication number: 20090110943
    Abstract: A thermoplastic resin composition that has high chemical resistance, excellent appearance of a molded product thereof, and, as a surface layer material, good adhesion to a base material resin, particularly a PS resin or its waste resin, and that can provide a composite molded product having excellent processibility (for example, chipping resistance) and high durability (for example, heat-cycle resistance), and a composite molded product including the thermoplastic resin composition as a surface layer material.
    Type: Application
    Filed: May 8, 2007
    Publication date: April 30, 2009
    Applicant: UMG ABS, LTD.
    Inventors: Kazuo Nishimoto, Katsuya Furushige, Koji Hirata, Yoshito Nagao
  • Patent number: 7521508
    Abstract: Two-phase or single-phase admixtures of a plastic and an elastomer, two or more thermoplastics, or two or more elastomers are irradiated (preferably with electron beam radiation) to cross-link the thermoplastic and, in the case of elastomer and thermoplastic admixtures, generate bi-modal molecules having moieties derived from both the elastomer and the thermoplastic.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: April 21, 2009
    Assignee: Freudenberg-NOK General Partnership
    Inventors: Edward Hosung Park, Francis Joseph Walker
  • Publication number: 20090076181
    Abstract: The present invention describes the synthesis of solvent soluble copolymers containing multiple unsaturations. These copolymers contain reactive vinyl groups, which can be further reacted in a second stage polymerization. The process involves copolymerization of a vinyl monomer with an inclusion complex of a monomer having multiple unsaturations and a cyclic macromolecular compound to yield soluble polymers. These polymers may be cast into films, membranes or may be converted in micro or nanoparticles and then crosslinked in a second step polymerization.
    Type: Application
    Filed: October 24, 2008
    Publication date: March 19, 2009
    Applicant: COUNCIL OF SCIENTIFIC AND INDUSTRIAL RES
    Inventors: Mohan G. KULKARNI, Rohini N. Karmalkar, Sunita S. Satav
  • Publication number: 20080306217
    Abstract: The invention provides a comprising one or more ethylene interpolymers, and wherein the interpolymers, or the composition, has a melt viscosity from 1 to 30,000 cP at 177° C., and wherein at least one ethylene interpolymer has an Rv from 0.3 to 0.99. The invention further provides a composition comprising at least one low molecular weight (LMW) ethylene interpolymer, and at least one high molecular weight (HMW) ethylene interpolymer, and wherein the composition has a melt viscosity from 1 to 30,000 cP at 177° C., and wherein the sum of the Rv from the low molecular weight interpolymer and the high molecular weight interpolymer is from 0.3 to 2. The invention further provides for processes of making such compositions, processes for functionalizing the interpolymer(s) of such compositions, and articles comprising at least one component prepared from an inventive composition.
    Type: Application
    Filed: December 12, 2006
    Publication date: December 11, 2008
    Inventors: Teresa P. Karjala, Selim Yalvac, Cynthia L. Rickey, Sylvie Desjardins, Marc A. Springs
  • Patent number: 7393895
    Abstract: A method of forming a poly(arylene ether)-containing solid concentrate is described. The method includes blending a poly(arylene ether), a thermosetting resin, and a compatibilizing agent in the presence of a solvent to form a homogeneous solution, and removing the solvent to yield the solid concentrate. The solid concentrate is useful for preparing curable conditions.
    Type: Grant
    Filed: August 23, 2007
    Date of Patent: July 1, 2008
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Michael John Davis, James Estel Tracy
  • Publication number: 20080139705
    Abstract: A polyvinyl chloride-based fiber of the present invention is a fiber formed with a vinyl chloride resin composition that comprises (a) 100 parts by weight of vinyl chloride resin, and (b) 0.2 to 20 parts by weight of crosslinked vinyl chloride resin in which a weight fraction of constituents that are insoluble in tetrahydrofuran is 18 to 45% and a viscosity average degree of polymerization of constituents that are soluble in tetrahydrofuran is 500 to 1800, in which a cross-sectional shape of the fiber comprises a combination of at least two of circles, ellipses, and parabolas. When this fiber is used as artificial hair, it is possible to provide style changeability without impairing matte properties and touch of the vinyl chloride-based fiber. Furthermore, the fiber of the present invention can be produced stably by melt-spinning, and thus an industrial advantage also is provided.
    Type: Application
    Filed: February 23, 2006
    Publication date: June 12, 2008
    Applicant: KANEKA CORPORATION
    Inventor: Masayuki Adachi
  • Patent number: 7365131
    Abstract: A thermoplastic vulcanizate composition comprised of (a) thermoplastic resin selected from the group consisting of polyphenylene ether, polypropylene, polyethylene, and polystyrene, (b) at least one elastomer selected from the group consisting of butadiene-isoprene copolymer rubbers, copolymers of a conjugated diolefin monomer and an acrylate monomer, copolymers of a conjugated diolefin monomer and an methacrylate monomer, copolymers of a conjugated diolefin monomer and a vinyl aromatic monomer, copolymers of a conjugated diolefin monomer and an acrylonitrile monomer, blends of polyisoprene rubber with styrene-butadiene rubber, wherein the elastomer is at least partially crosslinked, wherein the repeat units in the elastomer are distributed throughout the elastomer in an essentially random manner, and (c) oil.
    Type: Grant
    Filed: April 15, 2005
    Date of Patent: April 29, 2008
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Manoj Ajbani, Christopher Kiehl, Thierry Florent Edme Materne
  • Patent number: 7364672
    Abstract: In accordance with the present invention, we have developed compositions useful for the preparation of prepregs, laminates, and the like having excellent performance properties. Invention compositions comprise a combination of a first component (i.e., a low loss, low dielectric constant, hydrocarbyl thermoplastic resin), a second component (i.e., a component which is capable of crosslinking to produce a thermoset in the presence of the first component), a free radical source, and optionally, one or more additives and/or diluents. Invention compositions can be prepared from widely available and inexpensive starting materials. As a result, invention compositions not only provide fabricated articles having outstanding performance properties, in addition, the cost of producing the resulting articles compares quite favorably with the cost of making competitive materials which require the use of more expensive, less readily available starting materials.
    Type: Grant
    Filed: December 6, 2004
    Date of Patent: April 29, 2008
    Assignee: Arlon, Inc.
    Inventors: Thomas Allan Koes, Ousama Najjar
  • Patent number: 7323516
    Abstract: The present invention is directed to a peroxide curable rubber compound containing a butyl rubber polymer and an olefin polymer of ethylene and at least one ?-olefin. The present invention is also directed to a peroxide curable rubber compound containing a butyl polymer and an EP(D)M rubber polymer.
    Type: Grant
    Filed: December 6, 2004
    Date of Patent: January 29, 2008
    Assignee: Lanxess Inc.
    Inventors: Akhtar Osman, Adam Gronowski
  • Patent number: 7294676
    Abstract: Styrenic resin composition comprising a rubber modified styrene maleic anhydride copolymer and polybutene. The resin is prepared by several methods including adding polybutene into the reactor, or adding polybutene to the syrup exiting the reactor and prior to entering the devolatilizer, or compounding polybutene into the polymer in an extruder after the polymer exits the devolatilizer. The polybutene ranges from 0.1 to 8% by weight and has a number average molecular weight from 900 to 2500. The rubber ranges from 4% to 20% by weight and has a particle size from 0.1 micron to 11 microns. The resin can be extruded into sheet and thermoformed into an article or can be coextruded to produce a laminated article, which may be a container for packaged foods that can be heated in microwave ovens and which container has improved toughness, elongation, and heat distortion resistance properties.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: November 13, 2007
    Assignee: NOVA Chemicals Inc.
    Inventors: John Chi Hee Kwok, Richard Albert Cooper, Steven Michael Krupinski
  • Patent number: 7291663
    Abstract: A conductive roller or a conductive belt is composed of a conductive elastomer composition including a polymer composition having a plurality of carbon-to-carbon double bonds and containing not less than 40 mol % of ethylene oxide; an organometallic salt containing a fluoro group or/and a sulfonyl group; and an elastomer having a plurality of carbon-to-carbon double bonds.
    Type: Grant
    Filed: June 16, 2003
    Date of Patent: November 6, 2007
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Takayuki Hattori, Tetsuo Mizoguchi
  • Patent number: 7262249
    Abstract: A thermoplastic resin composition comprising: a graft copolymer obtained by polymerizing 10 to 70 parts by weight of a monomer containing 60 to 100% by weight of at least one vinyl monomer selected from the group consisting of a (meth)acrylate ester compound, an aromatic vinyl compound and a vinyl cyanide compound and 0 to 40% by weight of a monomer which is copolymerizable therewith, in the presence of 30 to 90 parts by weight of hollow rubber particles which are rubber obtained by polymerizing a polymerization component comprising a butadiene without using a crosslinking agent and have a porosity of 3 to 90% in the form of a latex, wherein the total amount of the monomer and the rubber particles is 100 parts by weight; and a thermoplastic resin.
    Type: Grant
    Filed: April 17, 2002
    Date of Patent: August 28, 2007
    Assignee: Kaneka Corporation
    Inventors: Akira Takaki, Toshio Mizuta, Akio Sato
  • Patent number: 7211309
    Abstract: An antistatic film having an antistatic coating film on at least one surface of a polyester film, the antistatic coating film comprising a polymer having a polymerized unit represented by the following formula (1): wherein R1 and R2 each independently represent a hydrogen atom or a methyl group, R3 represents an alkylene group having 2 to 10 carbon atoms, R4 and R5 each independently represent an alkyl group having 1 to 5 carbon atoms, R6 represents a hydrogen atom, an alkyl group having 1 to 5 carbon atoms or a hydroxyalkyl group having 2 to 10 carbon atoms, and Y? represents a halogen ion, a halogenated alkyl ion, a nitrate ion, a sulfate ion, an alkyl sulfate ion, a sulfonate ion or an alkyl sulfonate ion. The film is used in such applications requiring an antistatic property such as a protective film for a liquid crystal polarizing plate.
    Type: Grant
    Filed: March 24, 2004
    Date of Patent: May 1, 2007
    Assignee: Teijin Dupont Films Japan Limited
    Inventors: Satoshi Kitazawa, Koji Kubo, Takeshi Asada, Shigeyuki Watamabe
  • Patent number: 7205342
    Abstract: A low gloss thermoplastic composition comprises poly(arylene ether), a rubber-modified poly(alkenyl aromatic) resin and an acrylonitrile containing polymer gel.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: April 17, 2007
    Assignee: General Electric Company
    Inventors: Cynthia Gerus, Steven R. Klei, Geoffrey Riding
  • Patent number: 7173093
    Abstract: The invention relates to a novel, impact-resistant polymer based on PMMA.
    Type: Grant
    Filed: January 15, 2003
    Date of Patent: February 6, 2007
    Assignee: Roehm GmbH & Co. KG
    Inventors: Klaus Kabs, Oliver Mueck
  • Patent number: 7105606
    Abstract: The present invention relates to a polymer blend containing at least one nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) below 10 and at least one nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) above 30 wherein said polymer blend has a multi-modal molecular weight distribution, a process for preparing said polymer blend wherein at least one nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) below 10 and at least one nitrile rubber polymer having a Mooney viscosity (ML 1+4 @ 100° C.) above 30 are mixed in a solvent and the blend is isolated from the solvent. The present invention also relates to a process for the manufacture of a shaped article including the step of injection molding the polymer blend.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: September 12, 2006
    Assignee: LANXESS Inc.
    Inventors: Christopher M. Ong, Frederic Guerin
  • Patent number: 7060751
    Abstract: A thermoplastic molding composition comprising a graft polymer is disclosed. The graft polymer contains: a) a continuous phase containing the polymerized product of at least one vinylaromatic monomer and at least one ethylenically unsaturated nitrile monomer, and b) a disperse phase containing ethylene/?-olefin rubber that is grafted with the polymerization product of at least one vinylaromatic monomer and at least one ethylenically unsaturated nitrile monomer. The weight average molecular weight of the continuous phase is 130,000 to 275,000 g/mole and the disperse phase is characterized in that its, weight average particle size is less than 0.90 ?m. The molding composition is characterized in improved resistance to weathering.
    Type: Grant
    Filed: December 15, 2003
    Date of Patent: June 13, 2006
    Assignee: Bayer Aktiengesellschaft
    Inventors: Gisbert Michels, Holger Warth, Pierre Vanhoorne
  • Patent number: 7049368
    Abstract: The present invention relates to a rubber modified thermoplastic resin composition comprising a discontinuous elastomeric phase dispersed in a rigid thermoplastic phase, wherein at least a portion of the rigid thermoplastic phase is grafted to the elastomeric phase, which is prepared by a method comprising the steps of: (a) polymerizing a mixture of monomers in a first stage in the presence of the elastomeric phase, at least one of which monomers is selected from the group consisting of vinyl aromatic monomers and at least one of which monomers is selected from the group consisting of monoethylenically unsaturated nitrile monomers, followed by (b) polymerizing one or more monomers in at least one subsequent stage in the presence of the elastomeric phase from (a), wherein the one or more monomers comprise at least one monomer selected from the group consisting of (C1-C12)alkyl- and aryl-(meth)acrylate monomers. The method is also provided.
    Type: Grant
    Filed: May 5, 2004
    Date of Patent: May 23, 2006
    Assignee: General Electric
    Inventors: Albin Peter Berzinis, Satish Kumar Gaggar
  • Patent number: 7041741
    Abstract: Toughened thermoplastic compositions comprising a thermoplastic polymer toughened by the inclusion of a thermoplastic elastomer derived from a particulate rubber dynamically vulcanized in the presence of a matrix polymer. The toughened thermoplastic composition exhibits properties including toughness, improved impact resistance, and improved hardness. The compositions are utilized wherever toughened, high performance polymers are desired. A method for forming the toughened polymer compositions is also described. Processing methods, such as rotational molding, utilizing the toughened polymer compositions are described.
    Type: Grant
    Filed: January 6, 2005
    Date of Patent: May 9, 2006
    Assignee: Teknor Apex Company
    Inventors: Raman Patel, Harry Howard, Marc Caruthers, Tonya McBride, John J. Wood, III, John C. Andries
  • Patent number: 7041739
    Abstract: A thermoplastic elastomer composition characterized in that the composition comprises a resin component and at least two kinds of rubber components, wherein at least one kind of the rubber components makes a continuous phase and/or a network-like phase, and the remaining at least one kind of the rubber components makes an isolated phase; and a process for producing the same.
    Type: Grant
    Filed: March 20, 2002
    Date of Patent: May 9, 2006
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroshi Toyoda, Nobuo Oi, Eiji Nakaishi
  • Patent number: 6987148
    Abstract: A thermoplastic polyolefin blend comprising of a base polymer and up to 25% by wt of an ethylene propylene diene monomer (EPDM), the balance if any consisting of a conventional filler and/or a conventional compatibilizer or interfacial agent is disclosed. The blend of the present invention is prepared by extruding a base polymer with ethylene propylene diene monomer (EPDM) at a temperature in the range of from 150 to 230° C. The blends of the invention exhibit very high mechanical properties at moderate concentrations of EPDM and/or filler, and can be made into industrial pallets either by injection molding or by thermoforming.
    Type: Grant
    Filed: June 7, 2002
    Date of Patent: January 17, 2006
    Assignee: Indian Petrochemicals Corporation Limited
    Inventors: Francis Xavier Sodagudi, Pendyala Veera Nageswara Sastry, Bhaskaran Ramasami
  • Patent number: 6927257
    Abstract: A resin composition comprising (A) an elastomeric copolymer which comprises styrene monomeric units and diene monomeric units, and (B) a copolymer which comprises styrene monomeric units and (meth)acrylate monomeric units, which has a saturated water absorption of 0.8% or less at a temperature of 60° C. and a relative humidity of 90%, a flexural modulus of at least 1,800 MPa, a notched Izod impact strength of at least 2 kJ/m2, a total light transmittance of at least 85% and a haze value of 5% or less when providing a sheet having a thickness of 2 mm, and a Vicat softening point of at least 90° C. This resin composition can suitably be used as a base material of a sheet for a screen which has good transparency, suffers from less deformation such as warp or deflection, and is hardly cracked or chipped.
    Type: Grant
    Filed: January 21, 2002
    Date of Patent: August 9, 2005
    Assignees: Sumitomo Chemical Company, Limited, Dai Nippon Printing Co., Ltd.
    Inventors: Katsumi Akada, Norihiko Ootaka
  • Patent number: 6919406
    Abstract: Disclosed are techniques and related material blends for improving adhesion between a polyolefin film and a pressure sensitive adhesive, and also significantly decreasing the coefficient of thermal expansion of a polyolefin film by modifying the chemical properties of the film. Specifically, particular amounts of a modifying polymer and/or copolymer such as ethylene vinyl acetate are incorporated into the polyolefin film. The polyolefin film may for instance be either a polyethylene or polypropylene film.
    Type: Grant
    Filed: May 12, 2003
    Date of Patent: July 19, 2005
    Assignee: The XLO Group of Companies, Inc.
    Inventors: John A. Petroski, Rachna Mohan
  • Patent number: 6919408
    Abstract: Disclosed is a thermoplastic transparent resin composition and a method for manufacturing the same. The resin composition includes 3-15 parts by weight of small aperture polybutadiene rubber latex; 5-25 parts by weight of large aperture polybutadiene rubber latex; 40-70 parts by weight of a methacrylic acid alkylester compound or an acrylic acid alkylester compound; 15-30 parts by weight of an aromatic vinyl compound; and 1-20 parts by weight of a vinylcyan compound. The method includes the steps of a) producing a small aperture polybutadiene rubber latex having an average particle diameter of 600-1500 A, a gel content of 70-95%, and a swelling index of 12-30 by reacting butadiene at 55-70° C. using a polymerization initiator, b) producing a large aperture polybutadiene rubber latex having a particle diameter of 2600-5000 A, a gel content of 70-95%, and a swelling index of 12-30 by enlarging the small aperture polybutadiene rubber latex particles; c) performing graft copolymerization at 65-80° C.
    Type: Grant
    Filed: March 4, 1999
    Date of Patent: July 19, 2005
    Assignee: LG Chemical Ltd.
    Inventors: Keon-Hoon Yoo, Yang-Hyun Shin, Chan-Hong Lee
  • Patent number: 6906142
    Abstract: The invention relates to an impact-modified moulding composition which has particularly high impact resistance at low temperatures (?20° C., ?40° C.). This low-temperature impact resistance is achieved by using a silicone elastomer.
    Type: Grant
    Filed: October 22, 2001
    Date of Patent: June 14, 2005
    Assignee: Roehm GmbH & Co. KG
    Inventors: Klaus Schultes, Michael Wicker, Werner Hoess, Klaus Albrecht, Hans-Juergen Kress
  • Patent number: 6890993
    Abstract: The invention relates to an impact-modified molding composition which has particularly high impact resistance at low temperatures (?20° C., ?40° C.). This low-temperature impact resistance is achieved by using a silicone elastomer.
    Type: Grant
    Filed: October 22, 2001
    Date of Patent: May 10, 2005
    Assignee: Roehm GmbH & Co. KG
    Inventors: Klaus Schultes, Michael Wicker, Werner Hoess, Klaus Albrecht, Hans-Juergen Kress
  • Patent number: 6887942
    Abstract: A low softening temperature thermal conductive adhesive composition is made from a blend of liquid NBR in molecular weight of 300˜100,000 and ethylene vinyl acetate (EVA) to have a softening point of 38˜65° C. With proper addition of sub-micron or nano powder thermal conductive agents like aluminum oxide, zinc oxide, aluminum nitride, boron nitride, graphite, metal powder or nano clay, the adhesive can be made into a membrane with thickness of 0.01˜5 mm and thermal conductivity of 0.5˜5 W/m-K, and thermal conductive plate with thermal resistance of 0.005˜0.2° C.in2/W. The thermal conductive plate has softening point of 38˜65° C., preferably 45° C. to avoid liquidation during storage and transportation. Further application includes use as the sealant or thermal conductive interface in electronic components and heat dissipaters to reduce heat resistance and improve thermal conductive efficiency.
    Type: Grant
    Filed: April 11, 2003
    Date of Patent: May 3, 2005
    Assignee: Chung Shan Instruments Co., Ltd.
    Inventors: Chung-Yi Chien, Yu-Lung Chen
  • Patent number: 6884483
    Abstract: Multilayer blow molded containers, which comprise a layer of an ethylene-vinyl alcohol copolymer (A) having an ethylene content of 5 to 60% by mol and a degree of saponification of 85% or more and a layer of a resin composition (B), characterized in that the resin composition (B) comprises 1 to 40% by weight of a thermoplastic resin (b1) having at least one functional group selected from the group consisting of boron-containing groups that are convertible to a boronic acid group in the presence of water and a boronic acid group (hereinafter, referred to as a boron-containing functional group), and 60 to 99% by weight of polypropylene (b2), exhibit excellent gas-barrier properties, have good interlayer adhesion, have excellent thermal stability, and are low in production cost.
    Type: Grant
    Filed: December 6, 2002
    Date of Patent: April 26, 2005
    Assignee: Kuraray Co., Ltd.
    Inventors: Nahoto Hayashi, William Scott Lambert, Hiroshi Kawai, Kaoru Ikeda, Shinji Tai
  • Patent number: 6884847
    Abstract: A transparent elastomer composition is obtained by co-coagulation of an emulsion of fluorine-containing resin fine particles having an average particle size of from 20 to 150 nm and an emulsion of elastomer particles, in which the fluorine-containing resin fine particles are finely dispersed uniformly in the elastomer. The transparent elastomer composition provides an elastomeric molded article having excellent mechanical strength, abrasion resistance and transparency.
    Type: Grant
    Filed: January 16, 2004
    Date of Patent: April 26, 2005
    Assignee: Daikin Industries, Ltd.
    Inventors: Sadashige Irie, Kazuyoshi Mimura, Hirofumi Nishibayashi, Hiroyuki Tanaka, Tsuyoshi Noguchi, Mitsuru Kishine
  • Patent number: 6881767
    Abstract: A rubber modified polystyrene composition comprising polybutadiene particles dispersed in polystyrene, wherein the polybutadiene particles have an average volume particle diameter of 6 to 13 microns, and the composition has a gel content of 25 to 35% by weight and a degree of swelling of 13 to 22, is prepared by polymerizing the polybutadiene particles in the presence of styrene. The rubber modified polystyrene composition of the present invention may be used for components contacting flon compounds, such as components of refrigerators.
    Type: Grant
    Filed: October 24, 2001
    Date of Patent: April 19, 2005
    Assignee: Toyo Engineering Corporation
    Inventors: Koji Kawano, Kenichiro Matsuba
  • Patent number: 6867263
    Abstract: The present invention provides a method of vulcanized bonding of heat resistant rubber. Vulcanized bonding of a hydrogenated acrylonitrile butadiene rubber (H-NBR) and an acrylic rubber (ACM) comprises a step for mixing zinc oxide (ZnO) and magnesium oxide (MgO) as acid acceptors into non-vulcanized H-NBR; and a step for the peroxide vulcanization of the H-NBR at the same time as the vulcanized bonding of the ACM, which is of an epoxy cross-linking type. Thus, hydrogenated acrylonitrile butadiene rubber (H-NBR) and acrylic rubber (ACM) are vulcanized bonded securely while also providing heat resistance.
    Type: Grant
    Filed: March 20, 2003
    Date of Patent: March 15, 2005
    Assignee: Tokai Rubber Industries, Ltd.
    Inventor: Shinobu Kanbe
  • Patent number: 6861477
    Abstract: A superabsorbent composition comprising a superabsorbent material and an elastomer. The superabsorbent composition has a two-phase morphology resulting in one of the superabsorbent material and elastomer being dispersed as aggregates in the other continuous material. The superabsorbent composition has a low glass transition temperature. The low glass transition temperature gives the superabsorbent composition many beneficial properties. This invention also discloses novel superabsorbent particles, fibers, films, and microporous films. Also disclosed in this invention are personal care articles comprising such particles, fibers, films and microporous films.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: March 1, 2005
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: James Hongxue Wang, Jayant Chakravarty, Thomas Kremer, David Glen Biggs, Xiaomin Zhang
  • Patent number: 6861476
    Abstract: Compositions of elastoplastic ionomeric polymers having hardness below 92 points Shore A. comprising polar elastomers (10-45 wt. %), such as polyacrylic and nitrile rubbers, apolar crystalline polyolefins (15-40 wt. %) and elastoplastic polyolefins (25-75 wt. %). These compositions are used for making single-layer and multilayer laminar products that can be bonded by radio-freqeuncy welding, and manufactured articles possessing antistatic properties.
    Type: Grant
    Filed: May 19, 2001
    Date of Patent: March 1, 2005
    Assignee: Basell Poliolefine Italia S.p.A.
    Inventors: Vittorio Braga, Virginie Lietard
  • Patent number: 6835780
    Abstract: A rubber composition comprising a nitrile rubber and incorporated therein an organic sulfonic acid salt. A vulcanized rubber article obtained by vulcanization of the rubber composition exhibits a reduced deterioration in tensile strength and elongation when kept in a hot-temperature air atmosphere.
    Type: Grant
    Filed: May 12, 2003
    Date of Patent: December 28, 2004
    Assignee: Zeon Corporation
    Inventors: Yoshiaki Aimura, Suguru Ito
  • Patent number: 6825277
    Abstract: The present invention relates to a high-frequency weldable thermoplastic rubber composition, to a method of rendering non-polar thermoplastic rubbers high-frequency weldable, to a high-frequency weldable shaped article obtainable from the composition according to the invention, to a method for manufacturing said shaped articles and to a method of high-frequency welding of said articles. Furthermore, the present invention relates to shaped high-frequency welded articles obtainable by the method according to the present invention.
    Type: Grant
    Filed: October 17, 2002
    Date of Patent: November 30, 2004
    Assignee: Advanced Elastomer Systems, L.P.
    Inventors: Ernst van Issum, Purushottam Agrawal, Phillip Neal, Antonius van Meesche