Solid Polymer Derived From (meth)acrylonitrile Patents (Class 525/238)
-
Patent number: 6815506Abstract: A thermoplastic elastomer composition having excellent heat aging characteristics, weather resistance, low-temperature physical properties, oil resistance and flexibility, and moldings using the same, such as hoses, are disclosed. The thermoplastic elastomer composition is obtained by dynamically heat treating a mixture containing (A) an olefin resin, (B) an unsaturated group-containing acrylic rubber, and (D) an inorganic filler in the presence of (E) a crosslinking agent, the component (B) comprising (B1) from 55 to 94.99% by weight of a structural unit derived from an acrylic acid alkyl ester monomer and/or an acrylic acid alkoxyalkyl ester monomer, (B2) from 0.Type: GrantFiled: October 11, 2002Date of Patent: November 9, 2004Assignee: JSR CorporationInventors: Masaaki Takashima, Katsutaka Yokoi, Minoru Tsuneyoshi
-
Patent number: 6812294Abstract: In one embodiment, this invention relates to a solventless liquid nitrile compound. The compound includes a liquid nitrile rubber. The compound also includes a curing agent selected from sulfur and/or sulfur donors. The curing agent is present in an amount of at least about 3% by weight of the compound. The compound contains substantially no solvent. In another embodiment, this invention relates to a solventless liquid nitrile compound. The compound includes a liquid nitrile rubber. The compound also includes a nonsulfur curing agent. The curing agent is present in an amount of at least about 5% by weight of the compound. The compound contains substantially no solvent.Type: GrantFiled: December 23, 2002Date of Patent: November 2, 2004Assignee: Freudenberg-NOK General PartnershipInventor: Paul J. Hochgesang
-
Patent number: 6807994Abstract: A pneumatic tire having a rubber component where the rubber in said component is comprised of (A) from 10 to 75 phr of a rubber gel selected from the group consisting of polybutadiene gel, styrene butadiene gel, acrylonitrile-butadiene gel, chloroprene gel, natural rubber gel, and mixtures thereof; (B) from 1 to 25 phr of syndiotactic 1,2-polybutadiene; and (C) a rubber containing olefinic unsaturation.Type: GrantFiled: February 8, 2002Date of Patent: October 26, 2004Assignee: The Goodyear Tire & Rubber CompanyInventors: Stephan Franz Westermann, Georges Marcel Victor Thielen, Ghislain Adolphe Leon Thise
-
Patent number: 6806315Abstract: A method for preparing a weatherable thermoplastic resin, having superior weatherability and colorability and a weatherable thermoplastic resin prepared by the method are provided. The method includes preparing a seed by adding a water-soluble initiator to either an aromatic vinyl compound or a (meth)acrylic acid alkyl ester to obtain a first compound and performing polymerization with respect to the first compound; preparing an alkyl acrylate rubber polymer by adding an alkyl acrylate monomer, a first emulsifier of pH about 3 to about 9, and an oil-soluble initiator to the seed to obtain a second compound and performing polymerization with respect to the second compound; and preparing graft copolymer by adding the aromatic vinyl compound, a vinyl cyanide compound, a second emulsifier of pH about 9 to about 13, and the oil-soluble initiator to the alkyl acrylate rubber polymer to obtain a third compound and performing graft copolymerization with respect to the third compound.Type: GrantFiled: March 4, 2003Date of Patent: October 19, 2004Assignee: LG Chem, Ltd.Inventors: Yang-Hyun Shin, Keun-Hoon Yoo, Tae-Bin Ahn, Chan-Hong Lee
-
Patent number: 6803416Abstract: The present invention provides a moulding composition, which includes: a plurality of bead polymers dispersed in at least one matrix polymer; wherein the bead polymers: have an average particle size of 5 to 40 &mgr;m, and have a refractive index nD at 20° C. which is different from a refractive index nD at 20° C. of said matrix polymer; and wherein the bead polymers are prepared by a process, which includes: contacting: at least one polymerizable mix which includes at least 50% by weight of at least one (meth)acrylate monomer, at least one aluminum compound, and an aqueous phase, to prepare a mixture; dispersing the mixture at a shear rate ≧103 s−1 to form a dispersion, wherein the dispersion is stabilized by the aluminum compound; and polymerizing to produce the bead polymers having an average particle size of 5 to 40 &mgr;m.Type: GrantFiled: December 28, 2001Date of Patent: October 12, 2004Assignee: Roehm GmbH & Co. KGInventors: Klaus Schultes, Thomas Suefke, Markus Parusel, Werner Hoess
-
Patent number: 6800693Abstract: An olefin polymer composition, which comprises a cross-linked olefin polymer composition comprising at least one cross-linking rubber like polymer (A) and an olefin resin (B), the cross-linking rubber like polymer (A) being selected from the group consisting of (1) an ethylene-&agr;-olefin copolymer, which contains an ethylene unit and an &agr;-olefin unit having 3 to 20 carbon atoms, and which is produced using a metallocene catalyst, and (2) at least one hydrogenated rubber selected from the group consisting of a homopolymer of a conjugated diene monomer and a copolymer thereof, in which rubber not less than 50% of all olefinic double bonds are hydrogenated, wherein the cross-linking rubber like polymer (A) has a weight average particle diameter of from 0.01 to 3 &mgr;m.Type: GrantFiled: December 13, 2002Date of Patent: October 5, 2004Assignee: Asahi Kasei Kabushiki KaishaInventors: Hajime Nishihara, Ikuji Ohtani
-
Patent number: 6794452Abstract: Polymeric materials that differ from each other in solubility parameters and other properties are covulcanized by reaction with a hydrogenated carboxylated nitrile rubber, a multivalent salt of an organic acid and a curing agent.Type: GrantFiled: July 15, 2002Date of Patent: September 21, 2004Assignee: Bayer Inc.Inventor: Carl Walter von Hellens
-
Patent number: 6790911Abstract: A thermoplastic vulcanizate prepared by dynamically vulcanizing a halogenated butyl rubber within a mixture that includes the halogenated butyl rubber and from about 10 to about 100 parts by weight of a crystalline thermoplastic resin per 100 parts by weight rubber, to thereby form a thermoplastic vulcanizate, where the thermoplastic resin includes a resin other than polyethylene, melt mixing the thermoplastic vulcanizate with about 5 to about 75 parts by weight of polyethylene resin per 100 parts by weight rubber, from about 3 to about 60 parts by weight of a tackifier per 100 parts by weight rubber, and from about 5 to about 250 parts by weight of a block copolymer containing at least the structure S-B/S-S per 100 parts by weight rubber, where the S block of the block copolymer has a glass transition temperature above about 25° C., the B/S block has a glass transition temperature below about 25° C.Type: GrantFiled: December 26, 2002Date of Patent: September 14, 2004Assignee: Advanvced Elastomer Systems, L.P.Inventors: Kathleen A. Perevosnik, Sunny Jacob, William Gary Stevenson, Curtis Waddle
-
Patent number: 6765064Abstract: This invention relates to a mixture containing one or more olefin rubbers and one or more nitrile rubbers, to a process for the production thereof, to a vulcanizable mixture and to a process for the production thereof as well as to moldings of all kinds producible from the mixtures.Type: GrantFiled: May 22, 2003Date of Patent: July 20, 2004Assignee: Bayer AktiengesellschaftInventor: Hans Magg
-
Patent number: 6765063Abstract: The present invention relates to a pneumatic rubber tire having an integral innerliner of a rubber composition comprised of butyl rubber and/or halogenated butyl rubber and low molecular weight trans 1,4-polybutadiene rubber, wherein said rubber composition may also contain a minor amount of at least one additional, sulfur curable, elastomer.Type: GrantFiled: July 29, 2002Date of Patent: July 20, 2004Assignee: The Goodyear Tire & Rubber CompanyInventors: Paul Harry Sandstrom, Wen-Liane Hsu, Roger Neil Beers, Adel Farhan Halasa
-
Patent number: 6756445Abstract: A transparent elastomer composition is obtained by co-coagulation of an emulsion of fluorine-containing resin fine particles having an average particle size of from 20 to 150 nm and an emulsion of elastomer particles, in which the fluorine-containing resin fine particles are finely dispersed uniformly in the elastomer. The transparent elastomer composition provides an elastomeric molded article having excellent mechanical strength, abrasion resistance and transparency.Type: GrantFiled: March 29, 2002Date of Patent: June 29, 2004Assignee: Daikin Industries, Ltd.Inventors: Sadashige Irie, Kazuyoshi Mimura, Hirofumi Nishibayashi, Hiroyuki Tanaka, Tsuyoshi Noguchi, Mitsuru Kishine
-
Patent number: 6750293Abstract: Disclosed are a precursor composition, a rubber component and a shear ply prepared from the precursor composition, and methods for making and using the same. The precursor composition includes a first hydrogenated nitrile conjugated-diene copolymer modified by a metal salt unsaturated carboxylic acid ester, wherein the first hydrogenated nitrile conjugated-diene copolymer is derived from a first ethylenically unsaturated nitrile and a first conjugated diene a second hydrogenated nitrile conjugated-diene copolymer derived from a second ethylenically unsaturated nitrile and a second conjugated diene; and a curing agent.Type: GrantFiled: March 27, 2002Date of Patent: June 15, 2004Assignee: Alliant Techsystems, Inc.Inventors: Albert R. Harvey, John W. Ellertson
-
Patent number: 6750297Abstract: The present invention relates to an artificial pigment and a method of preparing the same, specifically, to an artificial pigment with excellent dry pick resistance and to a method of preparing the same. In order to accomplish the present invention, there is provided an artificial pigment of inverted core-shell structure comprising: a) a shell of butadiene polymer including: i) a seed of butadiene polymer having glass transition temperature of −10 to 50° C.; and ii) a seed covering of butadiene polymer having a glass transition temperature of −10 to 20° C.; and b) a core of styrene polymer having a glass transition temperature of 40 to 120° C. Also provided is method of preparing artificial pigment comprising: a) preparing a shell of butadiene polymer; and b) preparing a core of styrene polymer on the inner side of said shell of step a).Type: GrantFiled: July 29, 2002Date of Patent: June 15, 2004Assignee: LG Chem, Ltd.Inventors: Seung-Uk Yeu, Ho-Yeul Choi, Chang-Sun Han, Wan-Sik Cha
-
Patent number: 6716923Abstract: The invention provides an olefin resin composition for powder molding comprising 100 parts by weight of an olefin resin (A) having a glass transition temperature of 25° C. or lower such as a propylene homopolymer or hydrogenated styrene-butadiene block copolymer and 0.5 to 30 parts by weight of a non-halogen type thermoplastic resin (B) such as methyl methacrylate having a glass transition temperature of 60 to 200° C., an average particle diameter of 0.1 to 10 &mgr;m and a sphericity of 0.8 to 1.0. The resin composition is very excellent in powder flowability and can be easily molten even under conditions where there is little or no pressure or shear stress action, and so best suited for use as powder slush molding compositions.Type: GrantFiled: May 30, 2002Date of Patent: April 6, 2004Assignee: Zeon Kasei Co., Ltd.Inventors: Manabu Ogiwara, Seiki Yada
-
Patent number: 6710129Abstract: The injection molding soft resin composition of the invention comprises (A) an ethylene/&agr;-olefin copolymer using an &agr;-olefin of 3 to 10 carbon atoms as a comonomer and (B) a thermoplastic elastomer composition obtained by dynamically heat treating a crystalline polyolefin resin and an olefin copolymer rubber in the presence of a crosslinking agent, in a specific ratio. The component (A) has a Shore A hardness of 40 to 95, MRF2.16 of 1.0 to 100 g/10 min and a density of 855 to 900 kg/cm3, and the component (B) has a gel content of 30 to 100% and a Shore A hardness of 40 to 95. The injection molded article of the invention comprises the soft resin composition and may have been subjected to painting on its surface. Each of the toy and the daily use miscellaneous article of the invention comprises the injection molded article.Type: GrantFiled: January 17, 2002Date of Patent: March 23, 2004Assignee: Mitsui Chemicals, Inc.Inventors: Tomoya Matayoshi, Naoto Yasaka, Tetsuya Nakamura
-
Patent number: 6706814Abstract: Disclosed are rubber-modified monovinylidene aromatic polymers with improved toughness and rigidity as well as a process for the preparation thereof. The polymer comprises a) a monovinylidene aromatic polymer matrix; and b) rubber particles dispersed therein, characterized in that the rubber particles are produced from a diene rubber having substantially linear structure containing less than one long chain branch per 10,000 carbon atoms in the polymer backbone with a solution viscosity of 5 cPoise to 1000 cPoise and a Mooney Viscosity of 5 to 120.Type: GrantFiled: July 3, 2002Date of Patent: March 16, 2004Assignee: Dow Global Technologies Inc.Inventor: Mehmet Demirors
-
Patent number: 6699937Abstract: The invention relates to rubber compounds that contain rubbers polymerized in solution with a secondary hydroxyl group content of 0.1 to 5 wt.- % that are not more than 4 carbon atoms away from the respective side chain end. The invention also relates to mixtures thereof with fillers, optionally additional rubbers and rubber auxiliary agents and the vulcanized rubbers produced thereof. The inventive rubber compounds are useful for producing highly reinforced, abrasion-resistant molded bodies, especially for producing tires that are characterized by excellent non-skid properties on wet surfaces.Type: GrantFiled: January 23, 2002Date of Patent: March 2, 2004Assignee: Bayer AktiengesellschaftInventors: Thomas Scholl, Jürgen Trimbach
-
Patent number: 6696525Abstract: In the present invention, the polymer composition is produced by polymerizing an anionically or cationically polymerizable monomer in the presence of a highly syndiotactic styrenic polymer and optionally a rubber-like polymer. The polymer composition thus obtained is improved in its solvent resistance without using any particular compatibilizer and has a good moldability.Type: GrantFiled: August 1, 2002Date of Patent: February 24, 2004Assignee: Idemitsu Petrochemical Co., Ltd.Inventor: Norio Tomotsu
-
Patent number: 6667083Abstract: A multilayer injection blow molded container of this invention, containing a layer of a specific ethylene-vinyl alcohol copolymer (A) and a layer of a resin composition (B) comprising a thermoplastic resin (b1) having a specific functional group and polypropylene (b2), is disclosed, having characteristics that it has excellent gas-barrier properties, has good interlayer adhesion, has excellent thermal stability and can be produced with a low cost.Type: GrantFiled: May 9, 2001Date of Patent: December 23, 2003Assignee: Kuraray Co., Ltd.Inventors: Nahoto Hayashi, William Scott Lambert, Hiroshi Kawai, Kaoru Ikeda, Shinji Tai
-
Patent number: 6657010Abstract: An oil resistant rubber modified polystyrene composition comprises polybutadiene rubber particles having an average volume particle diameter of 6 to 13 &mgr;m dispersed in polystyrene. The oil resistant rubber modified polystyrene of the present invention has a gel content of 25 to 35% by weight, a degree of swelling of 13 to 22, a residual volatile content of 2000 ppm or less, and a total amount of dimer and trimer of 8000 ppm or less. The oil resistant rubber modified polystyrene composition may be prepared by polymerizing styrene in the presence of polybutadiene rubber, foaming a solution of the rubber modified polystyrene under a reduced pressure of 3 to 40 mm Hg, heating the solution in a tubular heater to a temperature of 190 to 230° C., and then flushing the heated solution into a gas-liquid separator to devolatilize an unreacted monomer and a solvent therefrom.Type: GrantFiled: October 24, 2001Date of Patent: December 2, 2003Assignee: Toyo Engineering CorporationInventors: Koji Kawano, Kenichiro Matsuba
-
Patent number: 6639022Abstract: A process for the preparation of superabsorbent polymers by alkaline hydrolysis of polyacrylonitrile emulsions is disclosed. In an embodiment of the invention the process comprise preparing a PAN emulsion, subjecting the emulsion to alkaline hydrolysis, neutralizing the hydrolysate followed by drying, granulation and modifying the surface of the granular polymer by crosslinking. The process is characterized in that the isolation of the superabsorbent polymer entails neither alcohols nor organic solvents.Type: GrantFiled: April 16, 2001Date of Patent: October 28, 2003Assignee: Bayer AktiengesellschaftInventors: Gisbert Michels, Thomas Gross
-
Patent number: 6635712Abstract: There are disclosed a molding material which is used for molding a styrenic polymer and which is capable of affording moldings that are excellent in solvent resistance and mechanical strength even when produced at a molding temperature almost same as that of ordinary atactic polystyrene, namely at a resin temperature of 260° C. or lower, dispensing with a melt kneading step; a process for producing a molding by molding the above molding material, which process enables to shorten molding cycle time and curtail the producton cost; and the moldings produced thereby. The molding material comprises a dry blend of 10 to 95% by weight of a (A) styrenic polymer having atactic configuration and 2 to 90% by weight of a (B) styrenic polymer having a melting point of 250° C. or lower, a weight average molecular weight of at most 200,000 and mainly syndiotactic configuration.Type: GrantFiled: June 5, 2001Date of Patent: October 21, 2003Assignee: Idemitsu Petrochemical Co., Ltd.Inventors: Takuma Aoyama, Akihiko Okada
-
Patent number: 6608140Abstract: A polymer blend is disclosed which comprises a blend of (1) one or more polymers made using a late transition metal catalyst, and (2) one or more polyolefins made using a free radical process or polymerized using a Phillips type (chromium oxide) catalyst, a metallocene catalyst, or a Ziegler-Natta catalyst.Type: GrantFiled: February 6, 2001Date of Patent: August 19, 2003Assignee: BP Chemicals LimitedInventors: Susan Katherine Christie, Warren Reed, John Norman Reid Samson
-
Patent number: 6605672Abstract: There is provided an excellent impact modifier for a vinyl chloride resin. There is used, as an excellent impact modifier, a copolymer which is prepared by polymerizing 10 to 70% by weight of a monomer or monomers containing 60 to 100% by weight of at least one vinyl monomer selected from the group consisting of a (meth)acrylate compound, an aromatic vinyl compound, a vinyl cyanide compound and vinyl chloride, and 0 to 40% by weight of the other monomer copolymerizable therewith, in the presence of 30 to 90% by weight of a hollow rubber particle of which glass transition temperature Tg is at most 0° C. and a void ratio is 3 to 90% by volume in a latex state, and which contains a cross linking agent in an amount of 0.1 to 5 parts by weight based on 100 parts by weight of the total rubber component monomer.Type: GrantFiled: June 6, 2001Date of Patent: August 12, 2003Assignee: Kaneka CorporationInventors: Akira Takaki, Toshio Mizuta, Tomomichi Hashimoto, Toshiyuki Mori
-
Patent number: 6602957Abstract: The present invention provides a thermoplastic elastomer composition comprising a high-molecular-weight thermoplastic elastomer, a low-molecular-weight thermoplastic elastomer affinitive for the high-molecular-weight thermoplastic elastomer, and a rubber component. The ratio of the number-average molecular weight (Mn1) of the high-molecular-weight thermoplastic elastomer to the number-average molecular weight (Mn2) of the low-molecular-weight thermoplastic elastomer is not less than 1.2 nor more than 500. The rubber is dynamically cross-linked and dispersed in the thermoplastic elastomers.Type: GrantFiled: September 25, 2002Date of Patent: August 5, 2003Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Takayuki Hattori, Tetsuo Mizoguchi, Yoshihisa Mizumoto, Hideyuki Okuyama
-
Patent number: 6602958Abstract: Adhesive composition, including a mixture of about 1 percent to about 35 percent by weight of chlorinated polymer, about 1 percent to about 35 percent by weight of a nitrile elastomer, a rubber-modified acrylonitrile copolymer, or mixtures thereof, and about 25 percent to about 90 percent by weight of an alkyl acrylate or methacrylate monomer.Type: GrantFiled: July 10, 2001Date of Patent: August 5, 2003Assignee: IPS CorporationInventors: Paul C. Briggs, Masaki Minato, Samuel B. Osae
-
Patent number: 6599981Abstract: This invention relates to a method for manufacturing an olefinic thermoplastic elastomer composition, characterized by disposing specific kneading segment at least at one place of the screw on the occasion of manufacturing an olefinic thermoplastic elastomer composition comprising a polyolefin resin and a crosslinked rubber by dynamic crosslinking with a twin screw extruder.Type: GrantFiled: November 16, 2001Date of Patent: July 29, 2003Assignee: Mitsui Chemicals, Inc.Inventors: Yuichi Itoh, Akira Uchiyama
-
Patent number: 6593386Abstract: An expanded cellular ethylenic polymer product is provided from an irradiated, noncross-linked linear ethylenic polymer. Linear ethylenic polymers can be irradiated at ambient conditions sufficient to introduce branching in the polymer in the absence of detectable cross-linking as indicated by the absence of gels. The irradiated linear ethylenic polymer is compatible with highly branched low density polyethylene and, when mixed therewith, produces a resin having a single broad based melting temperature range as determined by direct scanning calorimetry, which indicates that the polymers in the mixture have similar crystallization behavior suitable for producing low density foams by extrusion foaming. The linear polymers can be obtained from recycled shrink wrap film. Low densities of from 0.7 to less than 4 pcf can be achieved. The foams typically have improved tear resistance as compared to previous products prepared from low density polyethylene, at comparable low densities.Type: GrantFiled: September 13, 1999Date of Patent: July 15, 2003Assignee: Sealed Air Corporation (U.S.)Inventors: Nelson E. Malwitz, Natarajan S. Ramesh, Shau-Tarng Lee
-
Patent number: 6579946Abstract: A low-gloss biaxially oriented polymer film containing a vinyl aromatic polymer and substantially non-spherical rubber particles is useful for window film applications. The rubber particles, when unconstrained, are essentially spherical and have a rubber particle size of 2.5 micrometers or more.Type: GrantFiled: January 10, 2002Date of Patent: June 17, 2003Assignee: Dow Global Technologies Inc.Inventor: Chieh-Chun Chau
-
Patent number: 6579944Abstract: A thermoplastic vulcanizate (TPV) is produced by melt blending until the volume fraction of dispersed rubber particles is greater than 0.5 preferably from 0.55 to 0.95, the remaining being the dispersed continuous plastic phase in a manner so as to develop a morphology which generates optimum elastic recovery. The majority (by volume) of large rubber particles are adjacent a small particle which is separated from one or more large particles by a critically thin, less than 0.1 $G(m)m thick, ligament of deformable plastic. When the majority of large particles evidence this morphology, as seen in a transmission electron microscope (TEM) photomicrograph, the TPV exhibits unexpectedly higher elastic recovery than if the ligaments were thicker. The foregoing is simulated in a micromechanical model which confirms, and in retrospect, predicts the observed actual elastic recovery of the TPV.Type: GrantFiled: January 15, 2002Date of Patent: June 17, 2003Assignee: Advanced Elastomer Systems LPInventors: Sabet Abdou-Sabet, Kenneth Emery Kear, Mary C. Boyce, Karla Drew Shaw
-
Patent number: 6573333Abstract: This invention relates to a mixture containing one or more olefin rubbers and one or more nitrile rubbers, to a process for the production thereof, to a vulcanizable mixture and to a process for the production thereof as well as to moldings of all kinds producible from the mixtures.Type: GrantFiled: August 20, 2001Date of Patent: June 3, 2003Assignee: Bayer AktiengesellschaftInventor: Hans Magg
-
Publication number: 20030096913Abstract: A hydrogenated nitrile rubber having lower molecular weights and narrower molecular weight distributions than those known in the art can be prepared by the olefin metathesis of nitrile butadiene rubber, followed by hydrogenation of the resulting metathesized NBR.Type: ApplicationFiled: June 10, 2002Publication date: May 22, 2003Inventor: Frederic Guerin
-
Publication number: 20030040582Abstract: Compositions of elastoplastic ionomeric polymers having hardness below 92 points Shore A. comprising polar elastomers (10-45 wt. %), such as polyacrylic and nitrile rubbers, apolar crystalline polyolefins (15-40 wt. %) and elastoplastic polyolefins (25-75 wt. %). These compositions are used for making single-layer and multilayer laminar products that can be bonded by radio-freqeuncy welding, and manufactured articles possessing antistatic properties.Type: ApplicationFiled: November 26, 2001Publication date: February 27, 2003Inventors: Vittorio Braga, Virginie Lietard
-
Patent number: 6515075Abstract: Novel breathable environmentally stable, water weakenable films, fibers, and articles, useful for disposable applications and methods for making them are disclosed. The films, fibers and articles are manufactured from novel polymer blends and demonstrate improved stability and enhanced strength when exposed to environmental conditions of increased humidity and elevated temperature. The breathable, environmentally stable, water weakenable films, fibers, and articles manufactured from the novel polymer blends are particularly useful for the manufacture of disposable products.Type: GrantFiled: July 12, 2001Date of Patent: February 4, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Bridget A. Balogh, Vasily A. Topolkaraev
-
Patent number: 6509419Abstract: Novel polymer blends useful for manufacturing breathable, environmentally stable, and water weakenable disposable films, fibers, and articles, and methods for making the blends are disclosed. The films, fibers and articles manufactured from these novel blends demonstrate improved stability and enhanced strength when exposed to environmental conditions of increased humidity and elevated temperature. Films, fibers, and articles manufactured from the novel polymer blends are particularly useful for the manufacture of disposable products.Type: GrantFiled: July 12, 2001Date of Patent: January 21, 2003Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Bridget A. Balogh, Vasily A. Topolkaraev
-
Patent number: 6506839Abstract: An elastomer composition obtained by crosslinking 1-99 parts by weight of a crosslinkable rubber-like polymer (A) and 1-99 parts by weight of a polypropylene resin (B) [the total amount of (A) and (B) being 100 parts by weight], where (B) is a crosslinking type polypropylene resin, has a flexural modulus of 100-10000 kgf/cm2 as specified in JIS K6758 and has a melting point peak in the range of 100-150° C. in differential scanning calorimetry (DSC), the melting point peak calorie being in the range of 10-600 J/g, especially the above elastomer composition wherein (A) has a crosslinking degree of 1-95% and a swelling degree of 3-100.Type: GrantFiled: October 13, 2000Date of Patent: January 14, 2003Assignee: Asahi Kasei Kabushiki KaishaInventors: Hajime Nishihara, Shinichi Shibayama
-
Patent number: 6506843Abstract: To provide a thermosetting powder coating composition which comprises a powder of a composite resin comprising a vinylidene fluoride polymer having crosslinkable functional group and a methyl methacrylate polymer and having a melt flow rate of 1 to 1,000 g/10 min when measured at 130° C. at a load of 2.1 kg. The coating composition has advantages that the preparation thereof is easy because pulverization can be carried out at room temperature as well as at low temperatures, the composite resin has excellent compatibility with various curing agents and the composition gives a coating film having excellent properties.Type: GrantFiled: April 6, 2001Date of Patent: January 14, 2003Assignee: Dajkin Industries, Ltd.Inventors: Nobuhiko Tsuda, Takahiro Kitahara, Ryuji Iwakiri, Masaru Nagato, Ryoichi Fukagawa, Go Nagai
-
Patent number: 6506840Abstract: A process for producing a succinimide resin composition is provided which comprises reacting a maleic anhydride-olefin type copolymer constituted of 40-60 mol % of maleic anhydride units, 60-40 mol % of olefin units, and 0-20 mol % of a copolymerizable monomer units with one or more amine compounds for imide formation in the presence of a second polymer other than the succinimide resin. This process improves the productivity by lowering the torque in the extrusion reaction, giving a succinimide copolymer resin composition having low yellowness and high transparency with high production efficiency.Type: GrantFiled: April 16, 2001Date of Patent: January 14, 2003Assignee: Tosoh CorporationInventors: Takeshi Harunari, Yoshiki Uchida, Toru Doi
-
Patent number: 6500899Abstract: A molded or formed product obtained by molding or forming a resin composition comprising (A) at least one vinyl cyclic hydrocarbon polymer selected from the group consisting of hydrogenated products of aromatic vinyl polymers, vinylcyclohexene polymers or hydrogenated products thereof, and vinylcyclohexane polymers, and (B) at least one substance selected from the group consisting of compounding additives incompatible with the polymer, organic compounds having at least one alcoholic hydroxyl group and at least one ether linkage, and organic compounds having at least one alcoholic hydroxyl group and at least one ester linkage, wherein the initial light transmittance (a) of the molded or formed product at an optional wavelength within a range of 400 to 800 nm and the light transmittance (b) of the molded or formed product after the molded or formed product is held for 1,000 hours in an atmosphere of 65° C.Type: GrantFiled: November 21, 2001Date of Patent: December 31, 2002Assignee: Nippon Zeon Co., Ltd.Inventors: Teruhiko Suzuki, Tsutomu Nagamune, Teiji Kohara
-
Publication number: 20020198324Abstract: The invention relates to a process for preparing an impact-modified plastic based on grafted crosslinked rubber particles, and also to an impact-modified plastic obtainable by the process. To prepare the impact-modified plastic, (a) particles of a crosslinked rubber are produced from a first monomer mixture which has a content of at least 50% by weight, preferably at least 90% by weight, particularly preferably at least 98% by weight, of diene compounds. The particles of the crosslinked rubber are (b) grafted with a second monomer or monomer mixture, with formation of a graft shell. Particles of the grafted crosslinked rubber are (c) added to a third monomer mixture, and the monomers of the third monomer mixture (d) are polymerized, with formation of a matrix. The process of the invention is simple to carry out and gives impact-modified plastics with very good mechanical properties.Type: ApplicationFiled: July 26, 2002Publication date: December 26, 2002Inventors: Graham Edmund Mc Kee, Hermann Gausepohl, Norbert Niessner
-
Patent number: 6498215Abstract: A molded or formed product obtained by molding or forming a resin composition comprising (A) at least one vinyl cyclic hydrocarbon polymer selected from the group consisting of hydrogenated products of aromatic vinyl polymers, vinylcyclohexene polymers or hydrogenated products thereof, and vinylcyclohexane polymers, and (B) at least one substance selected from the group consisting of compounding additives incompatible with the polymer, organic compounds having at least one alcoholic hydroxyl group and at least one ether linkage, and organic compounds having at least one alcoholic hydroxyl group and at least one ester linkage, wherein the initial light transmittance (a) of the molded or formed product at an optional wavelength within a range of 400 to 800 nm and the light transmittance (b) of the molded or formed product after the molded or formed product is held for 1,000 hours in an atmosphere of 65° C.Type: GrantFiled: November 21, 2001Date of Patent: December 24, 2002Assignee: Nippon Zeon Co., Ltd.Inventors: Teruhiko Suzuki, Tsutomu Nagamune, Teiji Kohara
-
Patent number: 6486259Abstract: An ebonite tape for coating metal substrates is made either of a single component mixture or a two-component mixture. A single component mixture includes unsaturated polymers, a sulfur vulcanization agent, a sulfur solubilizer, a vulcanization accelerator, and a vulcanization activator. Preferably, the sulfur solubilizer is polyamine, and the vulcanization accelerator is tetramethylthiuram disulfide. Reaction of polyamine and tetramethylthiuram disulfide causes a gelation in the mixture at ambient condition. A two-component mixture includes first and second components. First component includes first unsaturated polymers having first functional groups capable of reaction at ambient temperature, a sulfur vulcanization agent, and a vulcanization activator. Second component includes second unsaturated polymers having second functional groups that will react with first functional groups of the first unsaturated polymers at ambient condition, which causes a gelation in the mixture.Type: GrantFiled: November 28, 2000Date of Patent: November 26, 2002Assignee: 3L&T, Inc.Inventors: William L. Betts, III, Rong Jong Change
-
Patent number: 6486258Abstract: A conjugated diene rubber composition for tires comprising (I) 2-100 weight parts of a high-cis conjugated diene polymer rubber, which is a polymer of conjugated diene monomer alone or with a copolymerizable monomer, and has a cis-bond unit content of at least 40% in the conjugated diene monomer units, and a weight average molecular weight (Mw) of 20,000-10,000,000, and in which the ratio (Mw/Mn) of weight average molecular weight (Mw) to number average molecular weight (Mn) and the weight average molecular weight (Mw) satisfy the formula: log(Mw/Mn)<0.162×log(Mw)−0.682, and (II) 0-98 weight parts of other polymer rubber. A tire comprising at least a tread composed of the above-mentioned conjugated diene rubber composition has very high rebound resilience.Type: GrantFiled: December 13, 2000Date of Patent: November 26, 2002Assignee: Zeon CorporationInventors: Koukichi Noguchi, Takahiko Fukahori, Masao Nakamura
-
Patent number: 6482892Abstract: An olefinic thermoplastic elastomer composition which does not exhibit problems due to a softening agent such as an oil is superior in molding processability. The thermoplastic elastomer composition is produced by a heat crosslinking process of a resin-rubber composition that contains an olefinic and/or diene rubber, an olefinic resin, and a vinyl copolymer. The vinyl copolymer is obtained by copolymerizing 20 wt % or more of a vinyl monomer represented by CH2═CHOCOR1 or CH2═CHOR2 wherein R1 and R2 are alkyl groups having 1-6 carbon atoms. The thermoplastic elastomer composition can include a vinyl copolymer that has not undergone a heat crosslinking process.Type: GrantFiled: June 27, 2000Date of Patent: November 19, 2002Assignee: JSR Elastomix Co., Ltd.Inventors: Seizo Katayama, Kazuo Kimura, Kazuhiro Ohashi, Minoru Horie
-
Patent number: 6479590Abstract: The present invention relates to a resin material for an electrical insulating material, an electrical insulating material and electric wire and cable using the same. A resin material for an electrical insulating material according to present invention is characterized in that the resin component thereof comprises an ethylene &agr;-olefin copolymer (A) which satisfies specific conditions, such as a density of 0.92˜0.96 g/cm3, a melt flow rate (MFR) of 0.01˜200 g/10 minutes, a molecular weight distribution (Mw/Mn) of 1.5˜5.0, and possessing only one peak in terms of the number of peaks observed in an elution temperature-eluted amount curve as measured by the temperature raising elution fractionation (TREF) method, etc.Type: GrantFiled: March 16, 2001Date of Patent: November 12, 2002Assignee: Japan Polyolefins Co., Ltd.Inventors: Masaaki Ikeda, Yoshimi Shimizu
-
Patent number: 6476140Abstract: The present invention provides a thermoplastic elastomer composition comprising a high-molecular-weight thermoplastic elastomer, a low-molecular-weight thermoplastic elastomer affinitive for the high-molecular-weight thermoplastic elastomer, and a rubber component. The ratio of the number-average molecular weight (Mn1) of the high-molecular-weight thermoplastic elastomer to the number-average molecular weight (Mn2) of the low-molecular-weight thermoplastic elastomer is not less than 1.2 nor more than 500. The rubber is dynamically cross-linked and dispersed in the thermoplastic elastomers.Type: GrantFiled: May 23, 2001Date of Patent: November 5, 2002Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Takayuki Hattori, Tetsuo Mizoguchi, Yoshihisa Mizumoto, Hideyuki Okuyama
-
Patent number: 6476141Abstract: A blend composition (and fabricated articles therefrom) comprising; (A) one or more alkenyl aromatic polymers; (B) one or more substantially random interpolymers comprising (1) polymer units derived from; (a) at least one vinyl or vinylidene aromatic monomer, or (b) at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, or (c) a combination of at least one aromatic vinyl or vinylidene monomer and at least one hindered aliphatic or cycloaliphatic vinyl or vinylidene monomer, and (2) polymer units derived from at least one of ethylene and/or a C3-20 &agr;-olefin; and (3) polymer units derived from one or more of ethylenically unsaturated polymerizable monomers other than those derived from (1) and (2); and, (C) one or more compatibilizers; and wherein said blend has; a) a tensile strength greater than 1500 psi; b) a pull force test (⅛″ diameter) greater than 15 lb; c) a Shore A Hardness greater than 79; d) a cycle time in injection molding of less than 30 sec.Type: GrantFiled: September 27, 2001Date of Patent: November 5, 2002Assignee: Dow Global Technologies Inc.Inventors: Dane Chang, Yunwa Wilson Cheung, Charles F. Diehl, Martin J. Guest, Bharat I. Chaudhary, Andre J. Uzee
-
Patent number: 6476136Abstract: The present invention relates generally to compositions prepared by polymerizing vinyl neo C9-C13 carboxylic acid esters. Such compositions include latex compositions that are formed by polymerizing vinyl neo C9-C13 carboxylic acid esters with ethylenically unsaturated comonomers such as acrylic acid esters and vinyl acetate. The polymer compositions of the present invention are particularly suitable for use in applications such as architectural (both interior and exterior), direct-to-metal and marine coatings and transportation maintenance applications.Type: GrantFiled: February 6, 2001Date of Patent: November 5, 2002Assignee: ExxonMobil Chemical Patents Inc.Inventors: Vijay Swarup, Peter S. Ellis, Henry W. Yang, Oliver W. Smith, Thomas H. Henry
-
Patent number: 6455634Abstract: The present invention relates to a blend of at least one (meth)acrylate polymer and at least one amorphous propylene-derived polymer, and an optional tackifier that provide pressure sensitive adhesive compositions in which improved peel adhesion to at least one of low and relatively high surface energy substrates can be achieved.Type: GrantFiled: December 29, 2000Date of Patent: September 24, 2002Assignee: 3M Innovative Properties CompanyInventors: Ashish K. Khandpur, Eugene G. Joseph, Greggory S. Bennett
-
Patent number: 6451902Abstract: A nitrite polymer vulcanizate having improved hot air aging characteristics is described. The nitrile polymer vulcanizate may be produced admixing a composition comprising: (i) a nitrite polymer; (ii) a filler; (iii) an additive selected from the group comprising a strong base, a salt of a strong base and a weak acid, a salt of a weak acid, a carbodiimide, a polycarbodiimide and mixtures thereof; and (iv) a vulcanization system. A vulcanizable composition useful for producing such a vulcanizate and a method for improving the hot air aging characteristics of a nitrite polymer are also described.Type: GrantFiled: March 20, 2001Date of Patent: September 17, 2002Assignee: Bayer Inc.Inventor: Ezio Campomizzi