Abstract: This invention relates to thermoplastic moulding compositions of vinyl chloride polymers, certain graft polymers, certain resin-like copolymer additives and certain rubber-like copolymers for the production of films having improved resistance to ageing.

Abstract: A molding composition which is essentially composed of a mixture of at least two polymers based on vinyl chloride and at least one water-soluble surfactant is described. One of the polymers is a sinterable vinyl chloride/alkyl acrylate copolymer which can contain, in addition, polymerized units of vinyl acetate and ethylene. At least one further polymer is a vinyl chloride polymer which can contain up to 5% by weight of polymerized units of vinyl acetate and ethylene. The molding composition is suitable for the production of sintered, porous, flexible moldings, in particular separator compartments for electric cells.

Abstract: A continuous process for the grafting of ethylenically unsaturated monomers onto homopolymers of ethylene and copolymers of ethylene and C.sub.4 -C.sub.10 higher alpha-olefins is disclosed. The process involves feeding to an extruder an admixture comprising (i) a major portion of the above polymer of ethylene, (ii) the monomer, (iii) 25-500 ppm of an organic peroxide and (iv) a minor portion of a normally solid thermoplastic polymer having a melting point of less than 185.degree. C. and a shear viscosity at 200.degree. C. and a shear rate of 400 sec.sup.-1 that is not more than 50% of that of the polymer of ethylene. The organic peroxide is in the form of a composition with the thermoplastic polymer. The admixture is mixed in a first zone at a temperature above the melting point of the polymers for at least ten seconds but for less than 25% decomposition of the peroxide and then in a second zone for a period that is at least four times the half-life of the peroxide.

Abstract: A polymer composition adapted for use in producing polyvinyl halide polymer products comprising a blend of a vinyl halide polymer and a particulate terpolymer having a molecular weight of at least about 100,000 and a glass transition temperature of at least about 50.degree. C. The terpolymer comprises repeating units derived from an olefin, a diester of an addition polymerizable unsaturated dicarboxylic acid, and a solubilizing monomer which promotes compatibility of the terpolymer with the vinyl halide polymer. A shaped plastic article produced from this composition, and method of producing the shaped article are also disclosed.

Abstract: A plastic film made from polyvinyl chloride homopolymers and/or copolymers that is produced with the use of olefinic unsaturated monomers is disclosed that includes a plasticizing agent and a thermoplastic rubber. The plastic film has high strength, behaves like rubber and has improved aging properties and low temperature properties. External softening is not necessary to obtain elastic properties.

Abstract: Low temperature impact properties of poly(vinyl chloride) are improved by adding to the poly(vinyl chloride) chlorosulfonated polyethylene and chlorinated polyethylene wherein the base polyethylene of each additive has a density of at least 0.94. The use of all three components provides a synergistic lowering of the brittleness temperature as compared to either chlorosulfonated polyethylene or chlorinated polyethylene when added to the poly(vinyl chloride).

Abstract: The incorporation of a high melt flow rate propylene-based polymer additive into a PVC molding compound serves to retard the fusion rate of the PVC compound during processing.

Abstract: The incorporation of a high melt flow rate propylene-based polymer additive into a vinylidene chloride copolymer-based molding compound serves to retard the fusion rate of the resulting compound during processing.

Abstract: The incorporation of a high melt flow rate propylene-based polymer additive into a CPVC molding compound serves to retard the fusion rate of the CPVC compound during processing.

Abstract: A process for the production of sheet structure, including fibres from plastics solutions containing deped, burr-shaped or fibrous polyacetylene particles, in which process the solution is shaped to form a sheet and the solvent is removed and the sheet structure thus prepared.

Abstract: The invention relates to a thermoplastic composition which comprises vinyl chloride polymers and chlorinated polyethylene and which contains finely divided fluoropolymers and has a markedly improved processability, particularly when shaped by extrusion.

Abstract: A delustered thermoplastic resin composition obtained by incorporating in 100 parts by weight of a thermoplastic resin up to 40 parts by weight of a cross-linked polymer having an average particle diameter of 35-500.mu. which polymer is obtained by suspension-polymerizing a non-crosslinking monomer composition comprising 50-70 wt. % of a vinyl aromatic monomer, 10-40 wt. % of at least one monomer selected from the group consisting of alkyl acrylates having 1-13 carbon atoms in the alkyl group, 10-40 wt. % of a monomer selected from alkyl methacrylates having 1-4 carbon atoms in the alkyl group and 0-40 wt. % of another monoethylenically unsaturated monomer with 0.5-5 parts by weight, per 100 parts by weight of the non-cross-linking monomer composition, of a cross-linking monomer having at least two double bonds in the molecule.

Abstract: Polymers, the surfaces of which have been modified, are disclosed. The polymer surface is modified by embedding therein a second polymer. The modified polymer substantially retains its bulk properties while also possessing, at its surface, properties of the second polymer.

Abstract: A copolymer comprising (a) vinyl chloride or a mixture of vinyl chloride and a monomer copolymerizable therewith and (b) 1,2-polybutadiene oligomer and/or epoxidized 1,2-polybutadiene oligomer. The plasticized copolymer can be molded into soft moldings having a low compression set and high tensile and tear strenghts. Also, by the incorporation of the copolymer into vinyl chloride homopolymer or copolymers, hard moldings having delustered surface can be obtained without conducting delustering operation.

Abstract: Lubricant compositions comprising .alpha.-olefin/maleinimide copolymers is disclosed. Also disclosed is a process for the shaping of thermoplastic synthetic resins utilizing .alpha.-olefin/maleinimide copolymers.

Abstract: A polymer blend capable of being molded to an impact resistant, article which comprises a vinyl halide homopolymer or copolymer, a conventional impact resistant enhancing polymer agent for polyvinyl halide wherein the monomer units consist essentially of acrylonitrile, 1,3-butadiene and styrene residues and a thermoplastic block elastomer wherein the essential and predominant monomer units are the residue of a mono-alkenyl aromatic hydrocarbon and the residue of an alkadiene hydrocarbon. The thermoplastic elastomer is normally incompatible with the vinyl halide polymer or copolymer. The vinyl halide polymer or copolymer constitutes the major proportion of said blend and the block and methacrylate polymers together constitute a minor proportion of the composition. The weight ratio of block polymer to acrylonitrile-butadiene-styrene polymer is preferably about 1:5 to about 5:1.

Abstract: An eraser based on polyvinyl chloride having particles of a crosslinked polymeric natural or synthetic rubber embedded in the polyvinyl chloride structure. Such erasers have high strength and good aging resistance. Additionally, conventional softeners in the eraser do not undergo significant migration and consequently, the eraser does not smudge. A process for manufacturing the eraser is also disclosed.

Abstract: A process is disclosed for the preparation of chlorinated poly(vinyl chloride), (hereinafter "CPVC" for brevity), in the form of free-flowing macrogranules which are derived from solid free-flowing macrogranules of poly(vinyl chloride), (hereinafter "PVC" for brevity), by causing from about 0.6 to about 3.0 parts by weight (wt) of liquid chlorine which are absorbed perunit wt of solid PVC macrogranules to react with the PVC, without shedding reacted material from the macrogranules. The macrogranules of PVC containing absorbed liquid chlorine held therewithin, are maintained in a wetted but free-flowing, apparently dry reaction mass (due to which the process is referred to as "the relatively dry chlorination" or "the low liquid chlorine" process), in a reaction zone maintained at a temperature in the range from about -50.degree. C. to about 50.degree. C., and a pressure sufficient to maintain the chlorine in its liquid state.

Abstract: A solid chlorinated polymer product having reduced residual solvent content is prepared by treatment of a solution thereof with steam or hot water in the presence of a separately prepared added chlorinated polymer having a second-order transition temperature at least 20.degree. below that of the chlorinated polymer product which would be obtained in the absence of the added chlorinated polymer.

Abstract: A process for producing a shelf-stable ethylene-.alpha.-olefin (diene) elastomer powder which comprises a release agent, comprising grinding crumbs or preliminarily comminuted particles of an ethylene-.alpha.-olefin (diene) elastomer having a green strength of 5-20 MPa and a Mooney viscosity ML (1+4) 100.degree. C. of 50-150, and, prior to, during or after the grinding step, adding 0.5-10 parts by weight per 100 parts by weight of the ethylene-.alpha.-olefin (diene) elastomer, of a release agent which is(a) polyethylene of a density of 0.910-0.975 g/cm.sup.3, a viscosity number of 50-330 cm.sup.3 /g and a melt index of 0.2-50 g/10 min, polypropylene of a density of 0.90-0.910 g/cm.sup.3, a viscosity number of 100-1000 cm.sup.3 /g and a melt index of 0.1-50 g/10 min, polybutene-1 of a density of 0.910-0.975 g/cm.sup.3, a viscosity number of 100-1000 cm.sup.3 /g and a melt index of 0.1-100 g/10 min, polyvinyl chloride of a viscosity number of 50-200, all having an average secondary particle size of 5-50 .mu.

Abstract: A composition comprises 100 parts by weight of a vinyl chloride type resin and 25 to 200 parts by weight of a plasticizer, the vinyl chloride type resin being composed of 1 to 90% by weight of tetrahydrofuran-insoluble gel fraction and the balance of tetrahydrofuran-soluble fraction. This composition gives a rubbery elastomer having an excellent heat deformation resistance and an excellent matt finish and a small compression permanent set. Though it is close to rubber in properties, the composition has a moldability and processability similar to those of conventional thermoplastic resins, and can be formed into a sheet for interior material of automobile, a packing, a tube, etc.

Abstract: A monomer mixture comprising .alpha.-methylstyrene or 2-isopropenylnaphthalene, methyl methacrylate, and acrylonitrile is polymerized in the presence of a crosslinked polymer obtained by copolymerizing a monofunctional monomer such as .alpha.-methylstyrene with a small quantity of a polyfunctional monomer such as divinylbenzene to obtain a copolymer (C). A vinyl chloride resin composition formulated by blending the copolymer (C) thus obtained with a vinyl chloride resin and an impact strength modifier resin in a specific proportion possesses improved thermal deformation resistance and impact strength while retaining processability comparable to that of the vinyl chloride resin mixed with the impact strength modifier resin.

Abstract: An eraser based on polyvinyl chloride having particles of a crosslinked polymeric natural or synthetic rubber embedded in the polyvinyl chloride structure. Such erasers have high strength and good aging resistance. Additionally, conventional softeners in the eraser do not undergo significant migration and consequently, the eraser does not smudge. A process for manufacturing the eraser is also disclosed.

Abstract: An opaque recording material has an opaque sensitive layer which can be transparentized by application of heat or a suitable solvent for the opacifying styrene resin pigment which is dispersed in a polyvinylidene chloride film-forming resin binder. In a particular application, useful for overhead transparencies or for making photographic negatives for reproduction, heat and solvent are both applied to the opaque layer in selected different areas to transparentize the opaque layer. The opaque layer may be deposited on a transparent clear or colored support such as transparent polyester.

Abstract: Preferred blends with improved processability of CPVC resin and polymers of alpha methylstyrene, styrene or methyl methacrylate, and acrylonitrile, said polymers having dilute solution viscosity of less than 2.

Abstract: Blends of PVC and polystyrene are made compatible by the addition of from 1 to 20 wt %, based on final composition, of a chlorinated styrene-butadiene block copolymer.

Abstract: Polymer surfaces which are rendered nonthrombogenic are disclosed. Polymers, including hydrophobic polymers, which can be swollen by selected solvents, are rendered nonthrombogenic by absorbing into the surface of said polymers pendant aliphatic side chains which are attached to a linear polymer having reactive pendant groups which are negatively charged or which may be reacted with compounds having a negative charge, such as heparin. The compounds absorbed into the substrate surface have multi-point attachment to the surface.

Abstract: The present invention relates to transparent thermoplastic compositions on the basis of vinyl chloride polymers which can easily be processed and simultaneously have a good viscosity and good resistance to light and weather. They consist of a mixture of a special vinyl chloride polymer and two different, differently chlorinated chloropolyethylenes.

Abstract: A novel process is proposed for the preparation of vinyl chloride based resins modified with a polymer latex, according to which the latex polymer is absorbed so completely and uniformly on the polyvinyl chloride resin that the effect of the modification of the resin properties is remarkably enhanced along with no adverse effects on the particle size distribution of the resin product and no effluence of the latex into the waste water discharged in the dehydration of the aqueous polymerizate slurry after completion of the polymerization. The process of the invention comprises introducing the modifier polymer latex into the polymerization mixture only when the monomer conversion is in the range from 30 to 95% and introducing an inorganic fine powder such as fume silica, bentonite and diatomaceous earth into the polymerization mixture at the same time as or before the introduction of the modifier polymer latex.

Abstract: This invention relates to a process of producing elastomeric particles, such as those of natural and synthetic powdered and crumb rubbers and to the compositions prepared in accordance with such process. Specifically, the invention comprises encapsulating the elastomeric particles with a coating or film of a preplasticized vinyl resin, such as, for example, polymers and copolymers of vinyl and vinylidene halides and the like. The resultant composite particles are free-flowing and free of irreversible agglomeration and can be used in dry-blending with other materials prior to being formed into useful articles.

Abstract: The present invention provides a vinyl chloride polymer composition comprising an intimate mixture of a first vinyl chloride polymer containing a sulfide linkage in the molecular chain and a second vinyl chloride polymer having a higher molecular weight than the first polymer, and a process for producing a first vinyl chloride polymer for use in the composition, comprising polymerizing vinyl chloride or a mixture of vinyl chloride and an ethylenically unsaturated monomer in the presence of a free radical initiator using as a chain transfer agent a mercapto compound or a disulfide compound. Said vinyl chloride polymer composition has been improved in heat stability and processability.

Abstract: In the process of melting a blend of nitrile polymer and lubricous additive with a screw-plasticizing unit, the improvement which involves having an absorptive anti-slip agent such as rubber crumb in admixture with the blend when charging the plasticator to minimize feeding problems.

Abstract: Free-flowing chloropolyethylene in powder form which keeps this property after prolonged storage and has good processing properties is impregnated substantially on the particle surface with definite amounts of fine-grained vinyl chloride polymer and fine-grained organic substance in a definite proportion. The invention also relates to a process for the manufacture of such an improved chloropolyethylene and the use thereof.

Abstract: Improved rubbery compositions comprise vinyl chloride polymers, butadiene-acrylonitrile polymers and butadiene-styrene-tertiary amine polymers. Such compositions may be compounded and vulcanized and the vulcanizates may be used in hoses, rolls and gaskets.

Abstract: Disclosed is a film or sheet product comprising a closed cell foam comprised of a mixture of low density polyethylene and at least one ethylene polymer containing polar groups, and, optionally, a crystalline olefin polymer in which the mixture contains from about 0.025 to 1 percent by weight of said polar groups. Also disclosed is a method of making this film or sheet product and a wall covering material based thereon.

Abstract: Ion exchange resins exhibiting increased crush strength and/or higher density are prepared from a cross-linked polymer by imbibing a halo-substituted olefin within the cross-linked polymer's structure and subsequently polymerizing the imbibed olefin. For example, imbibing vinylidene chloride within a chloromethylated, cross-linked copolymer of styrene and subsequently polymerizing the vinylidene chloride forms a high density resin, which resin is useful in the preparation of ion exchange and chelate type resins having improved crush strength.

Abstract: Thermoplastic compositions are disclosed which contain, as principle ingredients, a relatively rigid polymer, such as polyvinyl chloride and/or chlorinated polyvinyl chloride and an EPM and/or an EPDM type elastomer. In addition to the above components, the composition can have incorporated therein a phase compatibility promotion agent, such as chlorinated polyethylene or poly(ethylene-co-vinyl acetate), or mixtures thereof. This phase compatibility promotion agent helps insure more uniform distribution of the elastomer throughout the relatively rigid polymer and improved cohesion of the resultant composition. Also disclosed are methods for enhancement in the compatibility of relatively rigid polymers and elastomers through the use of such phase compatibility promotion agents.

Abstract: A stabilizer composition for molding compositions based on polyvinyl chloride and/or mixed polymers containing predominantly vinyl chloride comprising(a) a partial ester of pentaerythritol with a fatty acid,(b) calcium and/or zinc stearate, and/or the corresponding palmitate,(c) a waxy hydrocarbon and/or a fatty acid, and(d) an antioxidant.

Abstract: Particulate rubber is intimately and uniformly coated with an anti-cake(s) and pressed at mild temperatures to form friable rubber bales. The bales have a bulk density from about 1.3 to about two times that of the original particulate rubber and are capable of being handled as a slab and of supporting a direct load, yet break down under shear to form particles substantially similar in size and distribution to that of the original particulate rubber.

Abstract: A method of promoting peroxide initiated crosslinking of polar polymers whereby the solubility of peroxide vulcanizing agents in these materials is increased. Increased peroxide solubility and/or processibility is accomplished by blending certain ethylene copolymers with these highly polar polymers. The blending of ethylene copolymers with the polar polymers substantially reduces the viscosity of the latter polymers thereby enhancing their processibility.