Solid Polymer Derived From Ethylene Or Propylene Patents (Class 525/240)
  • Patent number: 8481646
    Abstract: This invention relates to the preparation of thermoplastic vulcanizates (TPVs) with unique morphological features, more specifically, this invention relates to a method for preparing TPV compositions wherein the mixing of plastomers and elastomers are carried out in solvent with curatives to induce cross-linking.
    Type: Grant
    Filed: February 23, 2011
    Date of Patent: July 9, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Weiqing Weng, Sunny Jacob, Peijun Jiang, Armenag H. Dekmezian, Aspy K. Mehta, James R. Ayers, David J. Lohse, Peter W. Manders, Palanisamy Arjunan
  • Patent number: 8481647
    Abstract: This invention relates to an in-reactor polymer blend comprising: (a) a first ethylene-containing polymer having a density of greater than 0.90 g/cm3 and a Mw of more than 20,000 g/mol and (b) a second ethylene-containing polymer having a density of less than 0.90 g/cm3 wherein the polymer blend has a Tm of at least 90° C. (DSC second melt), a density of less than 0.92 g/cm3, and the densities of the first and second polymers differ by at least 1%.
    Type: Grant
    Filed: December 19, 2011
    Date of Patent: July 9, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Armenag H. Dekmezian, Kevin R. Squire, Cesar A. Garcia-Franco
  • Patent number: 8475621
    Abstract: Hot melt adhesive compositions which have enhanced adhesion to difficult substrates, particularly at refrigerator/freezer temperatures or at elevated temperatures. The inventive compositions require a base polymer comprising at least one metallocene ethylene-containing polymer or at least one non-metallocene, amorphous, propylene containing polymer; a tackifier; an optional wax; and an adhesion promoting additive comprising at least one semi-crystalline polymer having a weight average molecular weight of about 30,000 daltons or less. It has been found that the adhesion promoting additive of this invention enhances the adhesion properties of a hot melt adhesive composition having a metallocene ethylene-containing base polymer or non-metallocene, amorphous, propylene containing base polymer, particularly at elevated temperatures or at low refrigerator and freezer temperatures where other conventional adhesives have been unsuccessful.
    Type: Grant
    Filed: April 24, 2007
    Date of Patent: July 2, 2013
    Assignee: Honeywell International Inc.
    Inventors: Natalie A. Merrill, Thomas Quinn, Michael Jablon
  • Patent number: 8475900
    Abstract: The invention relates to a container prepared from a PCR HDPE blend comprising PCR HDPE and an effective amount of an impact modifier to provide acceptable ESCR results.
    Type: Grant
    Filed: October 29, 2010
    Date of Patent: July 2, 2013
    Assignee: Albea Services
    Inventor: Robert Daniel Miskevich
  • Patent number: 8476370
    Abstract: The present invention deals with polymer compositions suitable for making pipes. The compositions comprise a multimodal copolymer of ethylene and one or more alpha-olefins having from 4 to 10 carbon atoms wherein the multimodal ethylene copolymer has a density of from 937 to 950 kg/m3, a melt index MFR5 of from 0.3 to 3.0 g/10 min, a melt index MFR2 of from 0.1 to 2.0 g/10 min and a shear thinning index SHI2.7/210 of from 2 to 30.
    Type: Grant
    Filed: May 25, 2009
    Date of Patent: July 2, 2013
    Assignee: Borealis AG
    Inventors: Mats Backman, Carl-Gustaf Ek, Anneli Pakkanen, Magnus Palmlof, Tarja-Tuulikki Turpeinen, John Severn
  • Patent number: 8476392
    Abstract: A process for the production of an ethylene alpha-olefin copolymer is disclosed, the process including polymerizing ethylene and at least one alpha-olefin by contacting the ethylene and the at least one alpha-olefin with a metallocene catalyst in at least one gas phase reactor at a reactor pressure of from 0.7 to 70 bar and a reactor temperature of from 20° C. to 150° C. to form an ethylene alpha-olefin copolymer. The resulting ethylene alpha-olefin copolymer may have a density D of 0.927 g/cc or less, a melt index (I2) of from 0.1 to 100 dg/min, a MWD of from 1.5 to 5.0. The resulting ethylene alpha-olefin copolymer may also have a peak melting temperature Tmax second melt satisfying the following relation: Tmax second melt>D*398?245.
    Type: Grant
    Filed: October 22, 2010
    Date of Patent: July 2, 2013
    Assignee: Univation Technologies, LLC
    Inventors: Rainer Kolb, Agapios K. Agapiou, James M. Farley, Eric J. Markel, Bruce J. Savatsky, Christopher R. Davey, Richard B. Pannell
  • Patent number: 8476371
    Abstract: Interpolymer resin particles that include from about 20% to about 60% by weight based on the weight of the particles of uncross-linked polyolefin resin particles having a VICAT softening temperature greater than 85° C. and from about 40% to about 80% by weight based on the weight of the interpolymer particles of polymerized vinyl aromatic monomer composition particles that have been polymerized in the uncross-linked polyolefin resin particles to form an interpenetrating network of polyolefin resin particles and polystyrene particles. The interpolymer resin particles have a gel content ranging from about 0 to about 1.5% by weight based on the weight of the interpolymer resin particles, a VICAT softening temperature ranging from about 90° C. to about 115° C., and a melt index value ranging from about 0.2 to about 35.0 g/10 minutes (Condition G).
    Type: Grant
    Filed: December 1, 2011
    Date of Patent: July 2, 2013
    Assignee: NOVA Chemicals Inc.
    Inventor: Steven M. Krupinski
  • Patent number: 8475898
    Abstract: Resin blends useful for pipe and blow-molded articles are disclosed. The blends comprise a low-molecular-weight, high-density polyethylene and a high-molecular-weight, low-density ethylene copolymer. The high-molecular-weight component is made with a bridged indenoindolyl Group 4 metal complex having open architecture. Blends of the invention uniquely have high molecular weight (Mw>200,000) and low levels of long-chain branching. A quick, convenient approach for estimating levels of long-chain branching in polyethylenes from gel permeation chromatography and dynamic oscillatory rheometry (“viscosity enhancement factor”) is disclosed.
    Type: Grant
    Filed: August 29, 2007
    Date of Patent: July 2, 2013
    Assignee: Equistar Chemicals, LP
    Inventors: Shaotian Wang, Gregory G. Hlatky, Sebastian Joseph, Jean A. Merrick-Mack, Kenneth J. Klug, Wallace W. Yau
  • Patent number: 8476366
    Abstract: Embodiments of the invention provide block composites and their use in thermoplastic vulcanizate compounds.
    Type: Grant
    Filed: October 1, 2010
    Date of Patent: July 2, 2013
    Assignee: Dow Global Technologies, LLC
    Inventors: Kim L. Walton, Brian W. Walther, Robert T. Johnston, Jose M. Rego, Xiaosong Wu
  • Publication number: 20130165590
    Abstract: A blown film composition including a first high density polyethylene component and a second high density polyethylene component, wherein the blown film contains a mixture of three or more discrete molecular weight distributions, and wherein the second high density polyethylene component has at least one more discrete molecular weight distribution than the first high density polyethylene component.
    Type: Application
    Filed: November 14, 2012
    Publication date: June 27, 2013
    Inventors: Michael McLeod, Marco Araya, Sam Curtis, John Ashbaugh, Leonardo Cortes
  • Publication number: 20130165591
    Abstract: Polyolefin compositions comprising, all percentages being by weight: A) from 70 to 97% of a copolymer of propylene with hexene-1 containing from 3 to 9% by weight of recurring units derived from hexene-1, said copolymer having a melting temperature from 125° C. to 143° C.; B) from 3 to 30% of a butene-1 homopolymer or copolymer.
    Type: Application
    Filed: August 31, 2011
    Publication date: June 27, 2013
    Applicant: Basell Poliolefine Italia S.r.l.
    Inventors: Michele Grazzi, Giampaolo Pellegatti, Letizia Baraldi
  • Publication number: 20130165008
    Abstract: The present invention is directed to fibers, nonwoven fabrics, and nonwoven laminates comprising a blend of at least one impact copolymer and at least one propylene-based elastomer. The blends comprise from about 45 to about 85 wt % of an impact copolymer, where the impact copolymer comprises a blend of a propylene homopolymer and a copolymer comprising from about 20 to about 80 wt % propylene-derived units and from about 20 to about 80 wt % ethylene-derived units. The blends further comprise from about 15 to about 55 wt % of a propylene-based elastomer, where the propylene-based elastomer comprises from about 5 to about 25 wt % units derived from one or more C2 or C4-C12 alpha-olefins and has a triad tacticity greater than about 90% and a heat of fusion less than about 75 J/g.
    Type: Application
    Filed: December 22, 2011
    Publication date: June 27, 2013
    Inventors: Vincent B. Gallez, William M. Ferry
  • Publication number: 20130164552
    Abstract: A composition of matter suitable for use in extrusion coating applications is disclosed. The composition comprises a blend of particular LLDPE with particular LDPE. The LLDPE has the following characteristics: a density in the range of from 0.89 g/cc to 0.97 g/cc; an MWD less than 2.8; a melt index (I2) in the range of 4.0 to 25 g/10 min; a Comonomer Distribution Constant in the range of from greater than from 45 to 400; and a vinyl unsaturation of less than 0.12 vinyls per one thousand carbon atoms present in the backbone of the ethylene-based polymer composition. The LDPE has a melt index (I2) in the range of 0.1 to 15 g/10 min, and has a melt strength which satisfies the inequality: Log Melt strength (cN)>1.14?0.6×Log I2 (g/10 min, 190° C.
    Type: Application
    Filed: December 27, 2011
    Publication date: June 27, 2013
    Applicant: Dow Global Technologies LLC
    Inventor: Jian Wang
  • Patent number: 8470449
    Abstract: It is an object of the present invention to provide a propylene-based polymer composition which is excellent in transparency and heat resistance (particularly, heat resistance at high heat deformation temperature) and is free from occurrence of stickiness even when it is used at a high temperature for a long period of time. The propylene-based polymer composition of the invention comprises (A) a propylene-based polymer (PP) satisfying the following requirements (1) and (2), in an amount of 1 to 99 parts by weight, and (B) a propylene/ethylene/?-olefin copolymer satisfying the following requirements (I) to (IV), in an amount of 99 to 1 part by weight, with the proviso that the total amount of the component (A) and the component (B) is 100 parts by weight; (1) the polymer (A) has a melting point (Tm), as measured by a differential scanning calorimeter (DSC), of not lower than 110° C. but not higher than 170° C.
    Type: Grant
    Filed: December 23, 2008
    Date of Patent: June 25, 2013
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hiroshi Hoya, Koji Matsunaga, Yoji Hayakawa, Kunihiko Mizumoto
  • Publication number: 20130157051
    Abstract: A composition can be provided with superior adhesiveness toward adherends, for example, made of plastic (in particular, polypropylene, and the like). The composition includes the following (A) and (B).
    Type: Application
    Filed: June 10, 2011
    Publication date: June 20, 2013
    Applicant: SUMITOMO CHEMICAL COMPANY, LIMITED
    Inventors: Masashi Nagano, Mutsuko Higo
  • Patent number: 8466235
    Abstract: Polypropylene resin compositions are provided that are useful in the production of thermoformed articles and biaxially oriented polypropylene films (BOPPs), tapes and fibers. The resins of the present invention are blends of high crystalline (low solubles) polypropylene homopolymer and an ethylene/propylene random copolymer (RCP). These blends can be used to replace standard high solubles BOPP grade polypropylene homopolymers. In addition, the use of high crystalline polypropylene homopolymers in the blends imparts improved stiffness to the finished films while maintaining good processability of the blends. Such polypropylene compositions are effectively produced by in-reactor blending of a high crystalline propylene homopolymer and a propylene/ethylene random copolymer.
    Type: Grant
    Filed: May 10, 2010
    Date of Patent: June 18, 2013
    Assignee: Braskem America, Inc.
    Inventors: Sehyun Kim, Rubén A. Migone, Richard G. Michael, Jr.
  • Publication number: 20130150531
    Abstract: This invention relates to a composition comprising a functionalized C3 to C40 olefin polymer comprising at least 50 mol % of one or more C3 to C40 olefins, and where the olefin polymer, prior to functionalization, has: a Dot T-Peel of 1 Newton or more on Kraft paper; an Mw of 10,000 to 100,000; and a branching index (g?) of 0.98 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 60,000, or a branching index of 0.95 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 100,000; and where the C3 to C40 olefin polymer comprises at least 0.001 wt % of a functional group. This invention further relates to blends of such functionalized polymers with other polymers including non-functionalized C3 to C40 olefin polymers as described above.
    Type: Application
    Filed: June 15, 2012
    Publication date: June 13, 2013
    Inventors: Ramin Abhari, Charles Lewis Sims, Mun Fu Tse, Patrick Brant, Peijun Jiang, David Raymond Johnsrud
  • Publication number: 20130149478
    Abstract: Provided herein is a powder comprising at least one of: (a) a propylene-based elastomer comprising, based on the total weight of said propylene-based elastomer, (i) at least about 60 wt % of propylene-derived units, (ii) about 5 wt % to about 35 wt % of units derived from at least one of ethylene and a C4-C10 alpha-olefin, and said propylene-based elastomer having a heat of fusion, as determined by DSC, of about 75 J/g or less; and (b) a polyolefin-based elastomer having a Shore A hardness, as determined by ISO 868, of less than 95; wherein the powder has an average particle size of from about 30 ?m to about 850 ?m. The powder is useful for rotational molding and for making articles having unique combination of elasticity, flexibility, and toughness.
    Type: Application
    Filed: November 16, 2012
    Publication date: June 13, 2013
    Applicant: ExxonMobil Chemical Patents Inc.
    Inventor: ExxonMobil Chemical Patents Inc.
  • Patent number: 8461261
    Abstract: Provided is a resin composition containing a resin component prepared by blending a graft copolymer with an engineering plastic, wherein the above graft copolymer is a graft copolymer satisfying (a) to (e) shown below: (a) a graft rate is 1 to 150% by mass, (b) a weight average molecular weight measured by GPC is 500 to 400000, (c) a molecular weight distribution (Mw/Mn) is 1.5 to 4, (d) a main chain is a polymerization chain containing 1 to 100% by mass of a monomer unit having a functional group interacting with the engineering plastic and (e) a side chain is a homopolymerization chain of a single kind selected from ?-olefins having 3 to 28 carbon atoms or a copolymerization chain of two or more kinds selected therefrom or a copolymerization chain comprising an ?-olefin unit having 3 to 28 carbon atoms and an ethylene unit which accounts for 50% by mass or less, and a mesopentad ratio [mmmm] of the polymerization chain is 30 to 80 mole %.
    Type: Grant
    Filed: January 14, 2009
    Date of Patent: June 11, 2013
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Manabu Nomura, Susumu Kanno, Ryo Aburatani, Shuji Machida
  • Patent number: 8461222
    Abstract: There is provided a shoe sole component that has properties such as strength and cushioning property that are suppressed from being changed even under a wide temperature range from severe cold at ?10° C. or lower to high temperature conditions exceeding 30° C. A shoe sole component includes a cross-linked foam of a resin composition, the resin composition containing a thermoplastic polyolefin resin, in which tan ? (?20° C. to 40° C.) at a frequency of 10 Hz measured according to JIS K 7244-4 is 0.01 to 0.5, and tan ? (?20° C.)/tan ? (40° C.) at a frequency of 10 Hz is 0.7 to 1.3.
    Type: Grant
    Filed: July 19, 2011
    Date of Patent: June 11, 2013
    Assignee: ASICS Corporation
    Inventors: Sadaki Mori, Katsuhiro Imazato, Kenichi Harano, Akiyuki Morikawa
  • Patent number: 8461276
    Abstract: Propylene polymerization processes, polymers and films formed therefrom are described herein. The propylene polymerization processes generally include contacting propylene and an amount of ethylene with a first metallocene catalyst and a second metallocene catalyst within a polymerization reaction vessel to form a propylene based polymer, wherein the amount is an amount effective to form the propylene based polymer including from about 2 wt. % to about 6 wt. % ethylene, the second metallocene catalyst is capable of incorporating a greater amount of ethylene into the propylene based polymer than the first metallocene catalyst and wherein the first metallocene catalyst is capable of forming a propylene/ethylene random copolymer exhibiting a melting temperature that is greater than that of a propylene/ethylene random copolymer formed from the second metallocene catalyst.
    Type: Grant
    Filed: June 18, 2012
    Date of Patent: June 11, 2013
    Assignee: Fina Technology, Inc.
    Inventors: Tim Coffy, Kenneth Blackmon, Joseph Thorman, David Rauscher, Jun Tian, William Gauthier, Nathan Williams
  • Patent number: 8459283
    Abstract: This invention is related to the preparation of polyethylene pipe resins suitable for transporting hot and cold water containing chlorine dioxide.
    Type: Grant
    Filed: September 2, 2008
    Date of Patent: June 11, 2013
    Assignee: Total Petrochemicals Research Feluy
    Inventors: Pierre Belloir, Christine Bertrand
  • Patent number: 8461270
    Abstract: The present invention relates to such a copolymer comprising an olefin and an aromatic vinyl compound that has a syndiotactic structure, high block property and a wide molecular weight distribution. Specifically, it relates to a copolymer comprising an olefin and an aromatic vinyl compound, in which a content of the aromatic vinyl compound is from 1 to 99% by mol; a molecular distribution is 1.
    Type: Grant
    Filed: May 29, 2008
    Date of Patent: June 11, 2013
    Assignees: Idemitsu Kosan Co., Ltd., Riken
    Inventors: Nobuhide Ishihara, Zhaomin Hou
  • Patent number: 8461266
    Abstract: The present invention relates to a cable comprising a conductor surrounded by one or more layers, wherein at least one layer comprises a polymer composition comprising a multimodal copolymer of ethylene with one or more comonomers, to a process for producing the cable and to a polymer composition suitable as a cable layer material.
    Type: Grant
    Filed: October 12, 2009
    Date of Patent: June 11, 2013
    Assignee: Borealis AG
    Inventors: Jonas Junqvist, Hans Eklind, Bernt-Ake Sultan, Katrin Nord-Varhaug, Philipp Walter
  • Patent number: 8461271
    Abstract: Provided is a production process for a graft copolymer or a thermoplastic resin composition containing the above graft copolymer, which comprises graft-polymerizing 100 parts by mass of a combination of 20 to 100% by mass of a reactive polyolefin and 0 to 80% by mass of a polyolefin other than the reactive polyolefin with 0.2 to 300 parts by mass of at least one specific monomer under the presence of a radical initiator and which is useful as a sealant, a modifier for polyolefins, a surface treating agent, a primer treating agent, a coating agent component and the like.
    Type: Grant
    Filed: November 30, 2007
    Date of Patent: June 11, 2013
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Shuji Machida, Ryo Aburatani, Takenori Fujimura, Harumi Nakashima
  • Publication number: 20130143461
    Abstract: Propylene-based polymer compositions are provided comprising propylene and from about 5 wt % to about 20 wt % of one or more C2 and/or C4-C12 ?-olefins. The polymer compositions have a triad tacticity greater than about 90%, a heat of fusion less than about 75 J/g, and a melt flow rate (MFR) greater than or equal to about 25 g/10 min (230° C., 2.16 kg). Further, the polymer compositions are reactor grade compositions comprising a reactor blend of a first polymer and a second polymer, preferably where both of the first and second polymers are prepared using the same catalyst system. Meltspun nonwoven fabrics, such as meltblown or spunbond fabrics, comprising such polymer compositions are also provided, as well as processes for forming the nonwoven fabrics.
    Type: Application
    Filed: December 2, 2011
    Publication date: June 6, 2013
    Inventors: Galen C. Richeson, Rainer Kolb, Jean-Roch Schauder, Thomas T. Sun
  • Publication number: 20130143015
    Abstract: Disclosed are multi-microlayer films having alternating first and second layers, the first layers including an ethylene-based copolymer composition and the second layers comprising a propylene-based copolymer composition, wherein each layer optionally comprises from about 0 to about 20% by weight of a polyolefin polymer. The multi-microlayer films have desirable tensile properties and are useful as components in absorbent personal care products.
    Type: Application
    Filed: December 5, 2011
    Publication date: June 6, 2013
    Inventors: Shawn E. Jenkins, Renee L. Johns
  • Patent number: 8455589
    Abstract: This invention relates to a propylene polymer comprising a component having a crystallinity of 10% or less and a component having a crystallinity of 20% or more, said propylene polymer having: a) a melting point of X° C. or more where X=?0.0038(Tp)2+0.36(Tp)+150, where Tp is the temperature of polymerization in ° C.; b) an Mw of 10,000 g/mol or more; c) a heat of fusion of from 1-70 J/g; d) Stereodefects per 10,000 monomer units of Y or less where Y=2.35(Tp)?100 (where Tp is the temperature of polymerization in ° C.) for the portion of the blend that is insoluble in hexane at 23° C.; e) a dot T-Peel on Kraft paper of 1 N or more; and f) a branching factor of 0.98 or less, where the branching factor is the ratio of g? measured at Mz to g? measured at Mw, and process to produce such polymers.
    Type: Grant
    Filed: February 15, 2012
    Date of Patent: June 4, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Jo Ann M. Canich, Peijun Jiang
  • Patent number: 8455072
    Abstract: A polyolefin composition, and pipe systems and sheets made therefrom, the composition comprising (percent by weight), 1) 10-60% of a copolymer of propylene and hexene-1 comprising from 0.2 to 10% of recurring units derived from hexene-1; 2) 10-85% of a propylene polymer selected from propylene homopolymer and a polymer of propylene with 0.1-10% of an ?-olefin selected from ethylene, a C4-C10 a-olefin, hexene-1 excluded, and a mixture thereof, the propylene polymer being insoluble in xylene at ambient temperature in an amount over 85% and having a Polydispersity Index ranging from 4.5 to 12; and 3) 5-30% of a copolymer of ethylene with a C3-C10 ?-olefin and optionally a diene, having an ethylene content ranging from 15 to 60% and an intrinsic viscosity value of at least 1 dl/g.
    Type: Grant
    Filed: December 11, 2007
    Date of Patent: June 4, 2013
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Roberto De Palo, Roberta Marzolla
  • Patent number: 8455588
    Abstract: Modular plastic structural composites formed from a mixture of (A) high density polyolefin and one or both of: (B) a thermoplastic-coated fiber material, or (C) polystyrene, poly(methyl methacrylate), or a combination thereof. Composites molded in the form of I-Beams and bridges constructed therefrom are also disclosed.
    Type: Grant
    Filed: July 28, 2011
    Date of Patent: June 4, 2013
    Assignee: Rutgers, The State University of New Jersey
    Inventors: Jennifer Lynch, Thomas Nosker, Richard Lehman, James D. Idol, Kenneth Van Ness, Richard W. Renfree, Maryann Renfree
  • Publication number: 20130137826
    Abstract: The propylene-based polymer composition includes a specific amount of a propylene-based polymer (A) having a syndiotactic pentad fraction (rrrr fraction) of 85% or more and containing 90 to 100 mol % of a structural unit derived from propylene; a specific amount of a propylene-based copolymer (B) containing 40 to 89 mol % of a structural unit derived from propylene and 11 to 60 mol % of a structural unit derived from an ?-olefin and satisfying a specific equation of intrinsic viscosity [?] and MFR; and specific amount(s) of at least one polymer of an olefin-based thermoplastic elastomer (C), a styrene-based elastomer (D), a propylene/ethylene/?-olefin copolymer (E) and an isotactic propylene-based polymer (F), and optionally an ethylene/vinyl acetate copolymer (G) and/or an ethylene-based polymer (H).
    Type: Application
    Filed: June 28, 2012
    Publication date: May 30, 2013
    Inventors: Naomi URAKAWA, Makoto Nakano, Yasuhiro Kitahara, Ryosuke Aburaki, Akihiro Matsuda
  • Publication number: 20130137825
    Abstract: The present invention aims to provide a dynamically-crosslinked thermoplastic elastomer composition that can provide a molded product exhibiting low compression set especially in the case of being cooled under stress. The present invention relates to a thermoplastic elastomer composition, including a dynamically-crosslinked butyl rubber and a thermoplastic resin; and having a thermoplastic resin content of not more than 8% by mass. The dynamically-crosslinked butyl rubber is preferably a halogen-containing butyl rubber.
    Type: Application
    Filed: September 14, 2012
    Publication date: May 30, 2013
    Inventors: Kazuo HOCHI, Yasuhisa Minagawa
  • Publication number: 20130137827
    Abstract: A process for producing an olefin-based polymer in a polymerization reactor including a fluidized bed, a disengaging section and a neck connecting the bed and disengaging section, at least one monomer, in the gas phase, in the presence of at least one catalyst containing at least two transition metals, one of the at least two transition metals being Ti, at least one cocatalyst, a composition having at least one compound selected from formula (I), and/or at least one compound selected from formula (II): (R1CO2)2AlOH (I), (R2)xN(R3OH)y (II); wherein R1 is a hydrocarbon radical containing from 13 to 25 carbons; R2 is a hydrocarbon radical containing from 14 to 26 carbons; R3 is a hydrocarbon radical containing from 1 to 4 carbons; and x+y=3, and x has a value of 1 or 2; and wherein the reactor is operated in a condensed mode and the average height of the fluidized bed is maintained above the neck of the polymerization reactor is provided. The reaction product of the process is also provided.
    Type: Application
    Filed: April 4, 2011
    Publication date: May 30, 2013
    Applicant: Dow Global Technologies LLC
    Inventors: Robert J. Jorgensen, Robert Reib, Stephanie M. Whited, Timothy J. Hogan, Darin G. Clark, Troy M. Tambling
  • Publication number: 20130137828
    Abstract: The invention is related to compositions suitable for the fabrication of pipes, and other articles, with excellent performance properties. The invention provides a composition, comprising a blend, wherein said blend comprises a high molecular weight ethylene-based interpolymer and a low molecular weight ethylene-based interpolymer, and the high molecular weight ethylene-based interpolymer is a heterogeneously branched linear or a homogeneously branched linear ethylene-based interpolymer, and has a density from 0.922 g/cc to 0.929 g/cc, and a high load melt index (I21) from 0.2 g/10 min to 1.0 g/10 min, and the low molecular weight ethylene-based interpolymer is heterogeneously branched linear or a homogeneously branched linear ethylene-based interpolymer, and has a density from 0.940 g/cc to 0.955 g/cc, and a melt index (I2) from 6 g/10 min to 50 g/10 min. The blend has a single peak in an ATREF profile eluting above 30° C., and has a coefficient of viscosity average molecular weight (CMv) less than ?0.
    Type: Application
    Filed: December 17, 2012
    Publication date: May 30, 2013
    Applicant: Dow Global Technologies LLC
    Inventor: Dow Global Technologies LLC
  • Patent number: 8450421
    Abstract: Cable layer comprising a propylene polymer composition comprising (a) a polypropylene (A) (b) an elastomeric copolymer (E) comprising units derived from propylene and ethylene and/or C4 to C20 ?-olefin and (c) a polar ethylene polymer (C) wherein the cable layer and/or the propylene polymer composition has a gel content of equal or more than 0.20 wt.-%.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: May 28, 2013
    Assignee: Borealis AG
    Inventors: Tung Pham, Doris Machl, Sybille Simon, Katja Klimke, Christer Svanberg, Thomas Steffl, David Friel
  • Patent number: 8450422
    Abstract: A masterbatch composition comprising, all percent amounts being by weight: A) 10-45% of a homopolymer or a copolymer of propylene; B) 10-30% of a copolymer of propylene with ethylene, containing from 18 to 45% of ethylene; C) 42-60% of a copolymer of propylene with ethylene, containing from 55 to 85% of ethylene; said composition having a MFR L value from 0.01 to 10 g/10 min., a value of the intrinsic viscosity [?]sol of the fraction soluble in xylene at room temperature from 1.5 to 2.5 dl/g and a value of the ratio [?]sol/MFR L equal to or lower than 6.
    Type: Grant
    Filed: March 17, 2010
    Date of Patent: May 28, 2013
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Michele Grazzi, Giampaolo Pellegatti
  • Patent number: 8450426
    Abstract: The present invention relates to a polyethylene composition comprising a polyethylene base resin, which comprises a. an ethylene copolymer as fraction (A), and b. an ethylene homo- or copolymer as fraction (B), with fraction (A) having a lower molecular weight than fraction (B), wherein the polyethylene base resin is obtainable in a polymerisation process in which a single-site catalyst. (SSC) is used in the polymerisation of at least one of fractions (A) and (B), and the base resin has (i) a density of below 940 kg/m3, and (ii) a MFR2 at 190 ° C./2.16 kg of 0.001 to 10 g/10 min, and the composition has (iii) a flexural modulus of from 300 to 820 MPa, and to a process for the production of such a composition, and to a pipe produced from such a composition.
    Type: Grant
    Filed: November 21, 2007
    Date of Patent: May 28, 2013
    Assignee: Borealis Technology Oy
    Inventors: Magnus Palmlöf, Solveig Johansson, Per-Ola Hagstrand, Sune Olsson
  • Patent number: 8450430
    Abstract: In one aspect the invention provides a melt process for preparing a functionalized olefin multiblock interpolymer, said process comprising grafting onto the backbone of the olefin multiblock interpolymer at least one compound comprising at least one “amine-reactive” group to form a grafted olefin multiblock interpolymer, and reacting a primary-secondary diamine or an alkanolamine with the grafted olefin multiblock interpolymer, without the isolation of the grafted olefin multiblock interpolymer.
    Type: Grant
    Filed: December 21, 2007
    Date of Patent: May 28, 2013
    Assignee: Dow Global Technologies, LLC
    Inventors: H. Craig Silvis, Stephen F. Hahn, David F. Pawlowski, Patricia Ansems, Laura K. Mergenhagen, Hamed Lakrout
  • Patent number: 8450423
    Abstract: A fluoroelastomer mixture, including: a peroxide-vulcanizable fluoroelastomer (A) containing an iodine atom; and a peroxide-vulcanizable fluoroelastomer (B) containing an iodine atom. The fluoroelastomer (A) is a copolymer (a1) consisting of 50 to 85 mol % of a vinylidene fluoride unit and 15 to 50 mol % of a perfluoro(alkyl vinyl ether) unit, or a copolymer (a2) consisting of 45 to 85 mol % of a vinylidene fluoride unit, 1 to 30 mol % of a tetrafluoroethylene unit, and 14 to 30 mol % of a perfluoro(alkyl vinyl ether) unit. Further the fluoroelastomer (B) has a fluorine content of 70.0% or more. Also disclosed is a composition for peroxide vulcanization containing the above fluoroelastomer composition (i), a polyfunctional unsaturated compound (ii) and a peroxide (iii), as well as a method for producing the fluoroelastomer mixture.
    Type: Grant
    Filed: March 30, 2010
    Date of Patent: May 28, 2013
    Assignee: Daikin Industries, Ltd.
    Inventors: Shoji Fukuoka, Keiko Washino, Shuumi Nishii, Daisuke Ota, Mitsuru Kishine
  • Publication number: 20130131256
    Abstract: Disclosed are rheology modifiers comprising compositionally disperse polymeric compositions and/or crystallinity disperse polymeric compositions that may be useful in modifying the rheological properties of lubrication fluids, and methods for making such compositions. The compositionally disperse polymeric composition are formed from at least two discrete compositions of ethylene copolymers. The crystallinity disperse polymeric composition are formed from ethylene copolymers having at least two discrete values of residual crystallinity.
    Type: Application
    Filed: January 18, 2013
    Publication date: May 23, 2013
    Applicant: ExxonMobil Chemical Patents Inc.
    Inventors: Sudhin Datta, Jo Ann M. Canich, Liehpao O. Farng, Rainer Kolb, Vera Minak-Bernero, Eric B. Sirota, Thomas T. Sun, Mun-Fu Tse, Manika Varma-Nair
  • Publication number: 20130131274
    Abstract: The present invention relates to polypropylene impact copolymer compositions which exhibit improved stiffness without degrading the impact resistance performance. The polypropylene impact copolymer comprises a matrix and a dispersed phase. The matrix comprises a polypropylene homopolymer or a propylene/alpha-olefin random copolymer which comprises more than 50 wt. % of units derived from propylene monomer. The matrix should have a relatively high crystallinity, preferably 50% or greater. The polypropylene homopolymer or a propylene/alpha-olefin random copolymer preferably has a MWD between 4 and 8, such as typically obtained using Ziegler-Natta catalysts. The dispersed phase in the impact copolymer comprises an ethylene-propylene copolymer which comprises from 45 to 70 wt. % of units derived from an ethylene monomer. Preferably the dispersed phase comprises from 20 to 50 percent by weight of the polypropylene impact copolymer.
    Type: Application
    Filed: June 6, 2011
    Publication date: May 23, 2013
    Applicant: Dow Global Technologies LLC
    Inventor: Chai-Jing Chou
  • Patent number: 8445598
    Abstract: The present invention relates to a heterophasic polypropylene resin comprising a propylene homo- or copolymer matrix (A) and an ethylene-propylene rubber phase (B) dispersed within the matrix, wherein the heterophasic polypropylene resin has a fraction insoluble in p-xylene at 25° C. (XCU) with an intrinsic viscosity of 1.5 dl/g or less, determined according to DIN EN ISO 1628-1 and -3 and an amount of propylene monomer units of at least 95 mol %, and a fraction soluble in p-xylene at 25° C. (XCS) with an intrinsic viscosity of 1.5 to 3.0 dl/g, determined according to DIN EN ISO 1628-1 and -3, and an amount of propylene monomer units of 50 to 75 mol %, and a MFR (2.16 kg, 230° C.) of more than 100 g/10 min, determined according to ISO 1133, a heterophasic polypropylene composition comprising such a resin, a process for preparing that resin, and an article made thereof.
    Type: Grant
    Filed: October 28, 2008
    Date of Patent: May 21, 2013
    Assignee: Borealis Technology Oy
    Inventors: Svein Nenseth, Petar Doshev
  • Patent number: 8445599
    Abstract: The present inventions relates to a process for producing polyethylene compositions comprising polymerizing polyethylene resins in a cascaded multi-stage reaction in which the reaction steps are performed in at least two slurry phase reactors (A) and (B) and at least one gas phase reactor (C) which are arranged in series in any order wherein in reactor (A) a low molecular weight ethylene homo- or copolymer fraction having a MFR2 of 100 to 2000 g/10 min, in reactor (B) a low molecular weight ethylene homo- or copolymer fraction having an MFR2 of 100 to 2000 g/10 min, and in reactor (C) a high molecular weight ethylene copolymer fraction are polymerized, and further comprising a compounding step after polymerization, wherein the final polyethylene composition has a MFR21 of 3 to 50 g/10 min, the melt flow rates being determined according to ISO 1133.
    Type: Grant
    Filed: October 16, 2009
    Date of Patent: May 21, 2013
    Assignee: Borealis AG
    Inventors: Bill Gustafsson, Jari Hatonen, Petri Rekonen, Markku Vahteri, Siw Bodil Fredriksen, Arild Follestad, Karl Isak Skau
  • Patent number: 8445594
    Abstract: The instant invention is a high-density polyethylene composition, method of producing the same, articles made therefrom, and method of making such articles. The high-density polyethylene composition of the instant invention includes a first component, and a second component. The first component is a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm3, and a melt index (I21.6) in the range of 0.5 to 10 g/10 minutes. The second component is a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm3, and a melt index (I2) in the range of 50 to 1500 g/10 minutes. The high-density polyethylene composition has a melt index (I2) of at least 1, a density in the range of 0.950 to 0.960 g/cm3, and g? of 1.
    Type: Grant
    Filed: May 2, 2007
    Date of Patent: May 21, 2013
    Assignee: Dow Global Technologies LLC
    Inventors: William J. Michie, Jr., Thomas W. Kay, Stephanie M. Whited, Dale M. Elley-Bristow, David T. Gillespie, Lonnie G. Hazlitt
  • Patent number: 8445087
    Abstract: The present invention comprises a molding composition comprising at least about 70% wt. polypropylene or polypropylene random copolymer; up to about 30 wt. % of a block copolymer composition comprising at least one selectively hydrogenated block copolymer which substantially matches the index of refraction of the polypropylene or polypropylene random copolymer, and up to about 0.70% by wt. of a clarifying agent, wherein the weight % of the total blend is 100%. The present invention also may be a molded article produced from the molding composition. A molded article formed from such a composition at a thickness of 0.125 inches will have a haze of less than about 50% and an instrumented impact toughness of at least 100 inch-lbs at ?20° C. to ?30° C.
    Type: Grant
    Filed: December 14, 2009
    Date of Patent: May 21, 2013
    Assignees: Kraton Polymers U.S. LLC, Milliken and Company
    Inventors: David Hansen, Ruidong Ding, Daniel Connor, Nathan Mehl
  • Publication number: 20130123432
    Abstract: A propylene polymer composition comprising (percent by weight): A) 68%-80%, of a propylene homopolymer having a Polydispersity Index (P.I.) value of from 4.7 to 10 and MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) from 10 to 30 g/10 min; B) 20%-32%, of a copolymer of propylene containing from 40.1% to 42.5% extremes included of ethylene derived units; the composition having an intrinsic viscosity of the fraction soluble in xylene at 25° C. comprised between 3 and 6 dl/g and a MFR L from 4 to 12 g/10 min Said Propylene polymer composition being particularly suitable for injection moulded articles having high rigidity and high impact properties at room and at low temperatures.
    Type: Application
    Filed: July 22, 2011
    Publication date: May 16, 2013
    Inventors: Marco Ciarafoni, Paola Massari, Manikanden Rathinakumar, Gisella Bindini, Tiziana Caputoi
  • Publication number: 20130123431
    Abstract: The present invention relates to a polypropylene composition showing a high melt flow rate and high melt strength while maintaining high impact strength. The composition of the present invention is obtainable by using a low molecular weight linear isotactic polypropylene as melt flow enhancer for a high molecular weight polypropylene having a high melt strength and impact strength. The inventive composition could be used for the production of different articles.
    Type: Application
    Filed: November 29, 2010
    Publication date: May 16, 2013
    Applicant: BOREALIS AG
    Inventors: Susana Filipe, Katja Klimke, Anh Tuan Tran, Petar Doshev, Antti Tynys, Martin Obadal, Cornelia Kock, David Friel
  • Publication number: 20130123430
    Abstract: Processes and compounds are described herein for single polymer composites based on a process for making the single polymer composites that includes the steps of heating a matrix material to create polymer melt, cooling the polymer melt to below its Tm to create an undercooled polymer melt, or quasi-melt, and combining the melt with an enhancing or reinforcing material to produce a single polymer composite. The process can produce materials that do not have any degradation of the polymer characteristic of the enhancing material due to melting of the polymer in the enhancing material.
    Type: Application
    Filed: May 3, 2012
    Publication date: May 16, 2013
    Applicant: Georgia Tech Research Corporation
    Inventors: Donggang Yao, Youjiang Wang, Pan Dai, Jinnan Chen
  • Publication number: 20130123414
    Abstract: A composition comprising a low density polyethylene (LDPE) and a metallocene-catalyzed linear low density polyethylene (mLLDPE) wherein the composition when extruded as a molten resin displays a neck-in value that is about equal to or increased by less than about 10% of the neck-in value observed when using the LDPE alone. A method comprising blending a LDPE and a mLLDPE of this disclosure to form a polymer blend having a miscibility factor of 1; extruding the polymer blend onto a substrate wherein the extruded polymer blend has a neck-in that is about equal to or increased by less than about 10% of the neck-in value observed when using the LDPE alone and wherein an amount of trim waste produced is equal to or about 10% less trim waste than the amount of trim waste produced when utilizing an extrusion coating using LDPE alone.
    Type: Application
    Filed: October 30, 2012
    Publication date: May 16, 2013
    Applicant: Chevron Phillips Chemical Company LP
    Inventor: Chevron Phillips Chemical Company LP
  • Publication number: 20130115458
    Abstract: Provided are thermoplastic organic fibers including a copolymerized resin of maleic anhydride with polypropylene, a method for preparing the same, a fiber composite board using the thermoplastic organic fibers as a matrix, and a method for manufacturing the fiber composite board. The thermoplastic organic fibers solve the problem of a limitation in improvement of strength caused by low wettability and adhesion between the thermoplastic organic materials used as a matrix according to the related art and reinforcing fibers.
    Type: Application
    Filed: July 12, 2011
    Publication date: May 9, 2013
    Applicant: LI&S CO., LTD.
    Inventors: Chan Whan Park, Seung Gyoo Kim