Solid Polymer Derived From Ethylene Or Propylene Patents (Class 525/240)
  • Patent number: 8674028
    Abstract: The present invention is directed to polymeric article comprising a blend of (a) a first polymeric component; (b) a second polymeric component, the second polymeric component including a propylene elastomer or a substantially linear or linear ethylene polymer; and (c) at least one reinforcement material. The polymeric articles desirably have one or more of the following characteristics: a soft touch feel, low gloss appearance, or a high surface durability.
    Type: Grant
    Filed: September 14, 2012
    Date of Patent: March 18, 2014
    Assignee: Dow Global Technologies LLC
    Inventors: Norwin Van Riel, Pascal E.R.E.J. Lakeman
  • Publication number: 20140072787
    Abstract: The present invention relates to a film structure comprising an outer layer, a core and an inner layer (or sealant layer). The outer layer comprises a polyolefinic material having a Vicat softening temperature of 85° C. or greater, and a total crystallinity in the range of 25 to 45%. The core comprises a linear low density polyethylene having a density of 0.925 g/cm3 or less, and a melt index of 4.0 g/10 min or less. The inner layer comprises linear low density polyethylene having a density of from 0.865 to 0.926 g/cm3 and a melt index of less than 4.0 g/10 minutes. The films of the present invention have less than 25% of polyethylenes having a density of 0.930 g/cm3 or greater. Further, the films of the present invention can be characterized by the substantial absence of polyamide, polyester, ethylene vinyl acetate, ionomers, polyvinyl chloride, and/or cyclic olefin polymers.
    Type: Application
    Filed: September 13, 2012
    Publication date: March 13, 2014
    Applicants: DOW BRASIL S.A., DOW GLOBAL TECHNOLOGIES LLC
    Inventors: Joao Gargalaka, JR., Felipe Martinez Barreneche, Jorge C. Gomes, Nicolas C. Mazzola
  • Patent number: 8669329
    Abstract: A thermoplastic elastomer is provided that includes a propylene-based resin and an ethylene-?-olefin copolymer rubber, and has a crystallization time at 130° C. measured by differential scanning calorimeter (DSC) of from 250 to 1,000 sec. There are also provided a method for producing a molded body, the method including a step of preparing the thermoplastic elastomer composition and a step of injection molding the thermoplastic elastomer composition, and a molded body produced by the method.
    Type: Grant
    Filed: April 15, 2009
    Date of Patent: March 11, 2014
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kohsuke Ohtani, Yasuhito Ijichi
  • Patent number: 8669327
    Abstract: A cross-linked composition obtained by cross-linking a polyolefin composition (I) comprising, all percentages being by weight: A) from 5 to 38% of a polypropylene; B) from 35 to 85% of a copolymer of ethylene with propylene, containing from 42 to 70% of ethylene and having solubility in xylene at room temperature greater than 50%; C) from 5 to 40% of a butene-1 homopolymer or copolymer having: a content of butene-1 derived units of 75% or more; a flexural modulus of 100 MPa or less; and optionally, D) from 5 to 35% of one or more polymers different from B) in composition, having a Shore A hardness value equal to or lower than 90 points, wherein the content of butene-1, if present, is of less than 50%; in which composition (I) the amounts of A), B), C) and D) are referred to the total weight of A)+B)+C) and optionally D), and when D) is present, the total weight of C)+D) is of 50% or less, referred to the total weight of A)+B)+C)+D).
    Type: Grant
    Filed: June 23, 2011
    Date of Patent: March 11, 2014
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Kazuhiko Minowa, Yukihiro Hisanaga, Paolo Goberti, Giampaolo Pellegatti
  • Publication number: 20140066574
    Abstract: Disclosed is an injection molded article made of a resin composition comprising 15 to 40% by mass of ultrahigh molecular weight polyethylene fibers, and 60 to 85% by mass of a thermoplastic resin having a melt flow rate of 70 to 500 g/10 min. measured at a temperature of 230° C. and a load of 21.2 N, and a fusion peak temperature lower than 160° C. measured with a differential scanning calorimeter, where the combined mass of the ultrahigh molecular weight polyethylene fibers and the thermoplastic resin is taken as 100% by mass, wherein the injection molded article satisfies the following requirements: the intrinsic volume resistivity is 1.0×1015 ?·cm or more, the thermal conductivity is 1 W/m·K or more, and the specific gravity is 1.2 or less. The article is high in rigidity, impact resistance, electrically insulating property, and thermal conductivity.
    Type: Application
    Filed: September 6, 2013
    Publication date: March 6, 2014
    Inventors: Kenji ATARASHI, Tetsuro DOBASHI
  • Publication number: 20140064683
    Abstract: The present disclosure provides filler rods that have higher melting temperature than the conventional filler rods and methods of making the filler rods. For some embodiments, the filler rod is made from a blend of polyethylene and polypropylene.
    Type: Application
    Filed: August 27, 2013
    Publication date: March 6, 2014
    Inventor: Peter A. Weimann
  • Patent number: 8663790
    Abstract: The invention relates to a polyethylene molding composition having a multimodal molecular mass distribution and comprising a first ethylene homopolymer fraction (I), a second ethylene copolymer fraction (II) and a third ethylene copolymer fraction (III). The molding composition has a density at a temperature of 23° C. in the range from 0.945 to 0.953 g/cm3, an MFR (190° C./5 kg) in the range from 2 to 7 g/10 min and a viscosity number VN3 of the total mix of ethylene homopolymer fraction (I), copolymer fraction (II) and ethylene copolymer fraction (III), measured in accordance with ISO/R 1191 in decalin at a temperature of 135° C., in the range from 200 to 250 cm3/g. The invention further relates to the use of such a molding composition for producing high-strength injection-molded screw cap closures for bottles comprising beverages, especially carbonated beverages.
    Type: Grant
    Filed: December 13, 2008
    Date of Patent: March 4, 2014
    Assignee: Basell Polyolefine GmbH
    Inventors: Joachim Berthold, Diana (nee Boos) Doetsch, Gerhardus Meier, Albert Weber
  • Patent number: 8664336
    Abstract: A method for forming a fiber, the method comprising charging to a reactive extruder a first polymer and a second polymer to form an initial blend, where the first polymer is a propylene-based elastomer including up to 35% by weight ethylene-derived units and a heat of fusion, as determined according to DSC procedures according to ASTM E-793, of less than 80 J/g and a melt temperature of less than 110° C., where the second polymer is a propylene-based polymer having a melt temperature in excess of 110° C. and a heat of fusion in excess of 80 J/g, and introducing the reactive blend to a spinneret to form a fiber or extruding the reacted blend through a plurality of die capillaries to form molten threads or filaments which are attenuated in a gas stream to form meltblown fibers.
    Type: Grant
    Filed: October 22, 2012
    Date of Patent: March 4, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Vetkav R. Eswaran, Bruce A. Harrington, Robert F. Bahm, Smita Kacker, Paul E. Rollin, Jr.
  • Patent number: 8663763
    Abstract: An oriented monolayer or multilayer film, wherein the monolayer film comprises a copolymer (A1) of propylene with hexene-1 containing from 4 to 10% by weight of hexene-1 and having MFR from 0.5 to 10 g/10 min., and the multilayer film comprises at least 30% by weight of said copolymer (A1), both the monolayer and the multilayer film being obtainable with a process comprising a drawing step wherein the film is drawn with a draw ratio of at least 3, in at least one direction.
    Type: Grant
    Filed: November 5, 2010
    Date of Patent: March 4, 2014
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Michele Grazzi, Paulo Bassi, Andrea Felisati, Giampaolo Pellegatti
  • Patent number: 8664337
    Abstract: The present invention is a film having a thickness greater than 100 microns comprising from 10 to 100 percent by weight of a polyethylene polymer made by the process of a) selecting a target polyethylene resin having a density, as determined according to ASTM D792, in the range of from 0.90 g/cm3 to 0.955 g/cm3, and a melt index, as determined according to ASTM D1238(2.16 kg, 190 C), in the range of from 0.01 g/10 min to 10 g/10 min; b) reacting said target polyethylene with an alkoxy amine derivative in an amount less than 900 parts derivative per million parts by weight of total polyethylene resin under conditions sufficient to increase the melt strength of the target polyethylene resin; and c) forming a thick film from the modified target resin. The present films include those which can achieve similar processability as those containing unmodified linear polyethylene despite having at least 10% less LDPE resins in the formulation.
    Type: Grant
    Filed: January 11, 2011
    Date of Patent: March 4, 2014
    Assignee: Dow Global Technologies LLC and Dow Brasil S.A.
    Inventors: Nicolas Mazzola, Jorge Gomes, Maria Pollard, Michael Turner
  • Publication number: 20140058039
    Abstract: A process for preparing a homogeneous polyethylene product can include producing a first polyethylene resin in the presence of a metallocene catalyst in a reactor. The first polyethylene resin can have a density of from 0.940 to 0.970 g/cm3. The first polyethylene resin can have a Low Molecular Weight (LMW) with an MI2 of between 2 and 250 g/10 min. The process can include separately producing a second polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The second polyethylene resin can have a High Molecular Weight (HMW) with an MI2 of between 0.01 and 15 g/10 min. The process can include physically blending together the first polyethylene resin and the second polyethylene resin to produce the homogeneous polyethylene product.
    Type: Application
    Filed: March 2, 2012
    Publication date: February 27, 2014
    Inventors: Daan Dewachter, Eric Damme
  • Publication number: 20140051771
    Abstract: A molded polyethylene component that comprises polyethylene having a melt flow index of about 3.5 g/10 min or greater as measured by ASTM D1238 at 190° C./21.5 kg weight and having an ash content of about 500 ppm or less may be useful biomedical devices, including kits and methods relating thereto.
    Type: Application
    Filed: August 12, 2013
    Publication date: February 20, 2014
    Applicant: Ticona LLC
    Inventors: Julia Hufen, Anthony Verrocchi, Rainer Walkenhorst
  • Patent number: 8653170
    Abstract: Described in one aspect is a process for preparing a low durometer thermoplastic vulcanizate composition comprising melt blending one or more thermoplastic polymer(s) with a cross-linkable elastomer under conditions of dynamic vulcanization; adding at or after the start of the melt blending at least one curative agent for the elastomer so as to cross-link the elastomer during the melt blending; introducing process oil into the melt blending before, during and/or after the addition of the curative agent; and, extruding a fully crosslinked thermoplastic vulcanizate having a Shore A Hardness of less than 25.
    Type: Grant
    Filed: March 15, 2006
    Date of Patent: February 18, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Hari Prasad Nadella, Ronald DeYoung, Jianya Cheng
  • Patent number: 8653199
    Abstract: This invention relates to a composition comprising a functionalized C3 to C40 olefin polymer comprising at least 50 mol % of one or more C3 to C40 olefins, and where the olefin polymer, prior to functionalization, has: a Dot T-Peel of 1 Newton or more on Kraft paper; an Mw of 10,000 to 100,000; and a branching index (g?) of 0.98 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 60,000, or a branching index of 0.95 or less measured at the Mz of the polymer when the polymer has an Mw of 10,000 to 100,000; and where the C3 to C40 olefin polymer comprises at least 0.001 wt % of a functional group. This invention further relates to blends of such functionalized polymers with other polymers including non-functionalized C3 to C40 olefin polymers as described above.
    Type: Grant
    Filed: June 15, 2012
    Date of Patent: February 18, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Ramin Abhari, Charles Lewis Sims, Mun Fu Tse, Patrick Brant, Peijun Jiang, David Raymond Johnsrud
  • Patent number: 8653198
    Abstract: Methods for preparing an impact copolymer by selecting a continuous phase polymer having a first melt flow rate and selecting a rubber phase polymeric material such that the final melt flow rate of the impact copolymer is within 2 g/10 min of the first melt flow rate. Impact copolymers made from such methods and films and molded articles produced from such impact copolymers are also included.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: February 18, 2014
    Assignee: Fina Technology, Inc.
    Inventor: Mark Leland
  • Patent number: 8653196
    Abstract: The present invention is a method for increasing the melt strength of a polyethylene resin comprising reacting the polyethylene resin with an alkoxy amine derivative corresponding to the formula: (R1)(R2)N—O—R3 where R1 and R2 are each independently of one another, hydrogen, C4-C42 alkyl or C4-C42 aryl or substituted hydrocarbon groups comprising O and/or N, and where R1 and R2 may form a ring structure together; and where R3 is hydrogen, a hyrdrocarbon or a substituted hydrocarbon group comprising O and/or N. Preferred groups for R3 include —C1-C19alkyl; —C6-C10aryl; —C2-C19akenyl; —O—C1-C19alkyl; —O—C6-C10aryl; —NH—C1-C19alkyl; —NH—C6-C10aryl; —N—(C1-C19alkyl)2. R3 most preferably contains an acyl group.
    Type: Grant
    Filed: January 11, 2010
    Date of Patent: February 18, 2014
    Assignee: Dow Global Technologies, LLC
    Inventors: Nicolas C. Mazzola, Mariana D. Mancini, Jorge C. Gomes
  • Patent number: 8653193
    Abstract: A polymeric composition that is suitable for use as a film or a coating. The polymeric composition comprises: (a) a first component comprising copolymer derived from ethylene and one or more C3 to C20 ?-olefin comonomers. The first component has a density of about 0.911 to about 0.918 g/cm3, a compositional distribution breadth index (CDBI) of about 60% to about 85%, a melt index (MI) of about 16.0 to about 30.0 g/10 min, a molecular weight distribution (MWD) of about 1.5 to about 4.0, and a melt index ratio (MIR) of less than about 25; and (b) a second component comprising a low density polyethylene (LDPE). The second component has a g? of about 0.8 to about 0.15 and a MI that is lower than the MI of the first component.
    Type: Grant
    Filed: September 28, 2009
    Date of Patent: February 18, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Linda M. Van Den Bossche, Nancy G. Vogelaers, Jean-Marc C. Dekoninck, Arnaud F. Alabrune, Michael E. Sieloff, Bernard K. Beh
  • Patent number: 8653197
    Abstract: The disclosure is directed to a thermoplastic vulcanizate composition comprising a dynamically-cured rubber; from about 20 to about 300 parts by weight of a thermoplastic resin per 100 parts by weight rubber and from about 30 to about 250 parts by weight additional oil per 100 parts by weight rubber; wherein the rubber comprises a multimodal polymer composition cured with a curing agent, the multimodal polymer composition comprising 45 to 75 wt % of a first polymer fraction and 25 to 55 wt % of a second polymer fraction, each comprising ethylene, a C3-C10 alpha-olefin, and a non-conjugated diene. A method of producing the thermoplastic vulcanizate is also disclosed.
    Type: Grant
    Filed: April 13, 2012
    Date of Patent: February 18, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Maria D. Ellul, Periagaram S. Ravishankar, Jianya Cheng, Paul E. McDaniel
  • Patent number: 8653194
    Abstract: Processes and compounds are described herein for single polymer composites based on a process for making the single polymer composites that includes the steps of heating a matrix material to create polymer melt, cooling the polymer melt to below its Tm to create an undercooled polymer melt, or quasi-melt, and combining the melt with an enhancing or reinforcing material to produce a single polymer composite. The process can produce materials that do not have any degradation of the polymer characteristic of the enhancing material due to melting of the polymer in the enhancing material.
    Type: Grant
    Filed: May 3, 2012
    Date of Patent: February 18, 2014
    Assignee: Georgia Tech Research Corporation
    Inventors: Donggang Yao, Youjiang Wang, Pan Dai, Jinnan Chen
  • Patent number: 8653189
    Abstract: The present invention relates to oil-extended styrenic block copolymer compositions that include a thermoplastic polymer, such as polystyrene, and a styrenic block copolymer, especially a linear styrene-butadiene-styrene triblock copolymer, with a styrene content less than 23 percent by weight, based upon total composition weight. The compositions yield very thin polymeric films with satisfactory physical properties.
    Type: Grant
    Filed: February 18, 2008
    Date of Patent: February 18, 2014
    Assignee: TSRC (USA) Investment Corporation
    Inventor: Andre J. Uzee
  • Publication number: 20140045994
    Abstract: Reactor grade thermoplastic polyolefins with high flowability and excellent surface quality comprising (A) 40-90 wt % of a propylene homo- or copolymer matrix with an MFR in accordance with ISO 1 133 (230° C., 2.16 kg load) of ?200 g/10 min and (B) 2-30 wt % of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of ?2.8 dl/g and an ethylene content of >50 to 80 wt % and (C) 8-30 wt % of an elastomeric ethylene-propylene copolymer having an intrinsic viscosity IV (according to ISO 1628 with decalin as solvent) of 3.0-6.
    Type: Application
    Filed: October 18, 2013
    Publication date: February 13, 2014
    Applicant: Borealis AG
    Inventors: Christelle Grein, Klaus Bernreitner
  • Publication number: 20140045998
    Abstract: The present invention is a polyolefin composition, which comprises a thermoplastic olefin polymer and a polyethylene. The thermoplastic olefin polymer (TPO) comprises a polypropylene and an olefin copolymer and is present in an amount of about 10 weight percent to about 50 weight percent; the TPO has a density in the range of about 0.85 g/cm3 to about 0.92 g/cm3 and a flexural modulus of less than about 700 MPa as measured by ISO 178. The polyethylene is either a medium density polyethylene or a high density polyethylene and present in an amount of about 50 weight percent to about 90 weight percent. The polyolefin composition is useful for preparing articles of manufacture such as sheets, roofing membranes, geomembranes, soft skins, drawn tapes, drawn fibers, and drawn filaments.
    Type: Application
    Filed: August 8, 2013
    Publication date: February 13, 2014
    Applicants: Basell Poliolefine Italia, S.r.l., Equistar Chemical, LP
    Inventors: Fabio Ceccarani, Paolo Goberti
  • Publication number: 20140045988
    Abstract: A novel polymer composition is described comprising ethylene homopolymers and/or copolymers of ethylene with C3-C8-alpha-olefins which polymer composition has a density of from 0.940 to 0.949 g/cm3, a melt index (HLMI) according to DIN EN ISO 1133:2005, condition G at 190° C. and 21.6 kg, of from 3 to 7 g/10 min. and a Hostalen Long Chain Branching Index (HLCBI) of from 3 to 8, and which polymer composition is produced by polymerisation with one or more Ziegler catalysts in a series of at least two polymerization reactors. The new polymer composition can in particular be used for blow moulding of intermediate bulk containers.
    Type: Application
    Filed: April 19, 2012
    Publication date: February 13, 2014
    Applicant: Basell Polyolefine GmbH
    Inventors: Diana Dotsch, Bernd Lothar Marczinke, Gerhardus Meier, Maclovio Herrera Salinas
  • Publication number: 20140039124
    Abstract: Polypropylene composition comprising propylene homopolymer (H-PP) and a propylene copolymer (C-PP), said copolmyer comprises (a) a propylene copolymer fraction (A) having a comonomer content of equal or above 1.0 wt.-%, the comomers are C5 to C12 ?-olefins, and (b) a propylene copolymer action (B) having a comonomer content of 4.0 to 20.0 wt-%, the comomers are C5 to C12 ?-olefins, wherein further (i) the comonomer content in propylene copolymer fraction (A) is lower compared to the comonomer content in the propylene copolymer fraction (B), (ii) the propylene copolymer (C-PP) has a comonomer content of at least 2.0 wt.-%, the comomers are C5 to C12 ?-olefins, (iii) the weight ratio [(A)/(B)] of the propylene copolymer fraction (A) to the propylene copolymer fraction (B) is in the range of 20/80 to 80/20, and (iv) the weight ratio [(C-PP)/(H-PP)] of the propylene copolymer (C-PP) to the propylene homopolymer (H-PP) is in the range of 95/5 to 75/25.
    Type: Application
    Filed: January 2, 2012
    Publication date: February 6, 2014
    Applicant: Borealis AG
    Inventors: Kristin Reichelt, Wolfgang Stockreiter, Pablo Ivan Aguayo Arellano
  • Patent number: 8642701
    Abstract: Injection stretch blow molded (ISBM) articles containing a bio-based polymers and methods of forming the same are described herein. The method generally includes providing a propylene-based polymer; contacting the propylene-based polymer with polylactic acid to form a polymeric blend; injection molding the blend into a preform; and stretch-blowing the preform into an article.
    Type: Grant
    Filed: February 8, 2011
    Date of Patent: February 4, 2014
    Assignee: Fina Technology, Inc.
    Inventors: Fengkui Li, Luyi Sun, John Ashbaugh, David Rauscher, Leland Daniels, Robert Dotter
  • Patent number: 8642703
    Abstract: A composition including polyhydroxyalkanoic acid (PHA), an elastomeric compound of core-shell type, and an olefinic copolymer including an ethylenic monomer bearing an epoxy function. The PHA composition exhibits improved impact strength.
    Type: Grant
    Filed: January 17, 2012
    Date of Patent: February 4, 2014
    Assignee: Arkema France
    Inventors: Alain Bouilloux, Sébastien Quinebeche, Stephane Girois
  • Patent number: 8642702
    Abstract: The invention pertains to a thermoplastic VDF polymer composition comprising: at least one thermoplastic vinylidene fluoride (VDF) polymer comprising at least 85% by moles of recurring units derived from VDF; and at least one ethylene/chlorotrifluoroethylene (ECTFE) polymer, wherein said ECTFE polymer possesses a melting point of less than 210° C. and it is comprised in an amount of from 0.1 to 20% wt with respect to the total weight of VDF polymer and ECTFE polymer. The invention also pertains to a process for making the VDF polymer and to the uses thereof for manufacturing films, in particular transparent films.
    Type: Grant
    Filed: April 26, 2011
    Date of Patent: February 4, 2014
    Assignee: Solvay Specialty Polymers Italy S.p.A.
    Inventors: Julio A. Abusleme, Stefano Mortara
  • Publication number: 20140031496
    Abstract: Methods of forming polymeric articles using plasma treated polymer resins, and orthopedic implants comprising a polymeric article wherein the polymeric article has reactive groups bonded to polymer molecules in an interior region of the polymeric article.
    Type: Application
    Filed: November 2, 2011
    Publication date: January 30, 2014
    Applicant: Zimmer, Inc.
    Inventors: Brian H. Thomas, Donald L. Yakimicki, Oludele O. Popoola, Michael Wallick
  • Publication number: 20140031492
    Abstract: Polypropylene composition comprising a propylene homopolymer having a melt flow rate MFR2 (230° C.) in the range of 1.0 to 20.0 g/10 min and a propylene copolymer, said copolmyer comprisesa polypropylene fraction having a comonomer content of not more than 1.0 wt.-%, the comomers are C5 to C12 ?-olefins, anda propylene copolymer fraction having a comonomer content 4.0 to 20.0 wt.-%, the comomers are C5 to C12 ?-olefins, wherein furtherthe propylene copolymer has a comonomer content of at least 2.5 wt.-%, the comomers are C5 to C12 ?-olefins, the melt flow rate MFR2 (230° C.) of the propylene homopolymer is higher than the melt flow rate MFR2 (230° C.) of the polypropylene fraction, the weight ratio of the polypropylene fraction to the propylene copolymer fraction is in the range of 30/70 to 70/30, andthe weight ratio of the propylene copolymer to the propylene homopolymer is in the range of 95/5 to 75/25.
    Type: Application
    Filed: January 2, 2012
    Publication date: January 30, 2014
    Applicant: Borealis AG
    Inventors: Kristin Reichelt, Wolfgang Stockreiter, Pablo Ivan Aguayo Arellano
  • Patent number: 8637607
    Abstract: Disclosed are polyethylene blends and films. The blend comprises from 1 to 99%, based on the weight of the blend, of a medium density polyethylene (MDPE) and from 1 to 99% a polyolefin selected from the group consisting of high density polyethylene (HDPE), linear low density polyethylene (LLDPE), low density polyethylene (LDPE), polypropylene, polybutene, and mixtures thereof. The MDPE is made by high pressure, free radical polymerization and has a density within the range of greater than 0.928 to 0.940 g/cm3 and an MI2 within the range of 0.1 to 1 dg/min. The shrink films made from the blend have strong contraction force and low creep.
    Type: Grant
    Filed: July 28, 2010
    Date of Patent: January 28, 2014
    Assignee: Equistar Chemicals, LP
    Inventors: Anil W. Saraf, Stephen M. Imfeld
  • Patent number: 8633286
    Abstract: A catalyst composition that includes a support material having an improved particle-size distribution is provided. Processes for producing polyolefin composition also are provided. Polymers and films also are provided. An example of a catalyst composition is a supported multi-transition-metal catalyst composition that includes: (a) at least two catalyst components selected from the group consisting of: a nonmetallocene catalyst component and a metallocene catalyst component; (b) a support material that has a D50 of less than about 30 microns and a particle size distribution having a D90/D10 ratio of less than about 6; and (c) an activator.
    Type: Grant
    Filed: April 4, 2011
    Date of Patent: January 21, 2014
    Assignee: Univation Technologies, LLC
    Inventors: Chi-I Kuo, Tae Hoon Kwalk, Dongming Li, Porter Clarke Shannon
  • Patent number: 8629214
    Abstract: An ethylene-based polymer composition has been discovered and is characterized by a Comonomer Distribution Constant greater than about 45. The new ethylene-based polymer compositions and blends thereof with one or more polymers, such as LDPE, are useful for making many articles, especially including films.
    Type: Grant
    Filed: April 23, 2012
    Date of Patent: January 14, 2014
    Assignee: Dow Global Technologies LLC.
    Inventors: Teresa P. Karjala, Rongjuan Cong, Colleen M. Tice, Sarah M. Hayne, Mehmet Demirors, Lori L. Kardos
  • Patent number: 8629217
    Abstract: The present invention relates to polyethylene compositions comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, in particular, this invention further relates to polyethylene blends comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, wherein the modifier has: 1) a g?vis value less than 0.75; 2) at least 0.6 ppm ester groups as determined by 1H NMR; 3) a Tm of 100° C. or more; 4) an Mw of 50,000 g/mol or more, as determined by GPC; 5) an average number of carbon atoms between branch points of 70 or more as determined by 1H NMR.
    Type: Grant
    Filed: August 13, 2012
    Date of Patent: January 14, 2014
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Yong Yang, Pradeep P. Shirodkar, Jianya Cheng, Andy H. Tsou, Arnold Lustiger, Johannes M. Soulages
  • Patent number: 8629215
    Abstract: Thermoplastic polyolefin polymer composition, polymer chip, fiber, woven or nonwoven fabric, film, closures, laminates can comprise a polymer, a polymer and a nonvolatile polymer-compatible carboxylic acid. Thermoplastic polyolefin polymer composition can also comprise a polymer, a cyclodextrin-modified polymer and a nonvolatile polymer-compatible carboxylic acid. The carboxylic acid moiety of the polymer composition can react with basic materials in the polymer environment and reduce release of the basic material. The cyclodextrin can act to absorb or trap other contaminants or odors in the environment.
    Type: Grant
    Filed: July 11, 2012
    Date of Patent: January 14, 2014
    Assignee: Cellresin Technologies, LLC
    Inventors: Willard E. Wood, Neil J. Beaverson
  • Patent number: 8627840
    Abstract: This invention is related to the preparation of polyethylene pipe resins suitable for transporting hot and cold water containing chloramine.
    Type: Grant
    Filed: September 2, 2008
    Date of Patent: January 14, 2014
    Assignee: Total Petrochemicals Research Feluy
    Inventors: Pierre Belloir, Christine Bertrand
  • Publication number: 20140011927
    Abstract: An ethylene/?-olefin copolymer comprising units derived from ethylene; and units derived from at least one ?-olefin; wherein the ethylene/?-olefin copolymer has a density in the range of from 0.90 to 0.94 g/cc; a melt index (I2) in the range of from 0.05 to 50 dg/min; an Mw/Mn of from 3 to 5; and from 300 to 500 vinyl unsaturations per 1,000,000 carbon atoms in the ethylene/?-olefin copolymer is provided. Also provided is a process for producing an ethylene/?-olefin copolymer comprising: (1) polymerizing ethylene and one or more ?-olefins in a polymerization reactor; (2) thereby producing an enhanced melt strength ethylene/?-olefin copolymer having from 300 to 500 vinyl unsaturation units per 1,000,000 carbon atoms, a density in the range of from 0.90 to 0.94 g/cc; a melt index (I2) in the range of from 0.05 to 50 dg/min; and a Mw/Mn of from 3 to 5.
    Type: Application
    Filed: March 1, 2012
    Publication date: January 9, 2014
    Applicant: Dow Global Technologies LLC
    Inventors: Lawrence J. Effler, Teresa P. Karjala, Mehmet Demirors, Nilesh R. Savargaonkar, Selim Bensason, Zhe Zhou
  • Patent number: 8623980
    Abstract: A process for making a substantially saturated dendritic hydrocarbon polymer. The process has the following steps: (a) polymerizing an amount of a first alkadiene monomer under anionic conditions in the presence of a first organic monolithium initiator to produce a linear polyalkadiene having a lithiated chain end; (b) reacting the linear polyalkadiene with an amount of a second organic monolithium initiator in the presence of tetramethylethylene diamine to form a multilithiated polyalkadiene; (c) reacting the multilithiated polyalkadiene with an amount of a second alkadiene monomer to form a branched polyalkadiene; (d) repeating steps (b) and (c) with the branched polyalkadiene one or more times to prepare a dendritic polyalkadiene; and (e) hydrogenating the dendritic polyalkadiene to form the substantially saturated dendritic hydrocarbon polymer.
    Type: Grant
    Filed: December 19, 2011
    Date of Patent: January 7, 2014
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: David John Lohse, Nikos Hadjichristidis, Andy Haishung Tsou, Pamela J. Wright, Suzzy Chen Hsi Ho, Paul Edward Schuenzel
  • Patent number: 8623932
    Abstract: A foamed polyolefin composition comprising (all percent amounts being by weight): A) 50%-90% of a polypropylene component; and B) 10%-50% of a copolymer component of ethylene and at least one C3-C10 ?-olefin, the copolymer containing from 15% to 50% of ethylene, and optionally minor amounts of a diene; the said amounts of (A) and (B) being referred to the total weight of (A) and (B); said composition having at least one of the following features i) and ii), or both: i) a Polydispersity Index of component (A) of 4 or more; ii) a value of viscosity [?] of the fraction soluble in xylene at room temperature equal to or higher than 3.5 dl/g.
    Type: Grant
    Filed: November 16, 2009
    Date of Patent: January 7, 2014
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Luca Lunghi, Alessandro Medri
  • Publication number: 20140005337
    Abstract: A propylene random copolymer composition is disclosed, comprising (A) 60-80 wt % of a copolymer of propylene and from 0.1 to 2 wt % of units derived from ethylene; and (B) 20-40 wt % of a copolymer of propylene and from 7 to 15 wt % of units derived from ethylene, said composition having a total ethylene content of from 3 to 4.5 wt % and a melt flow rate value according to ISO 1133 (230° C., 2.16 kg) of from 10 to 120 g/100 min. Cast films, sheets, or injection moulded or injection stretch blow moulded articles made from the above composition are also disclosed.
    Type: Application
    Filed: March 12, 2012
    Publication date: January 2, 2014
    Applicant: INEOS MANUFACTURING BELGIUM NV
    Inventors: Gaetane Hallot, Jean-Marc Roland Ghislain Vion
  • Publication number: 20140005324
    Abstract: Propylene copolymer composition comprising a propylene copolymer (A) having a comonomer content in the range of equal or more than 0.5 to equal or below 2.0 wt.-%, the comonomers are C5 to C12 ?-olefins, and a propylene copolymer (B) having a comonomer content in the range of equal or more than 4.0 to equal or below 10.0 wt.-%, the comonomers are C5 to C12 ?-olefins, wherein further the propylene copolymer composition has a comonomer content in the range of equal or more than 3.5 to equal or below 7.0 wt.-%, the comonomers are C5 to C12 ?-olefins, and the weight ratio of the propylene copolymer (A) to the propylene copolymer (B) is in the range of 20/80 to below 55/45.
    Type: Application
    Filed: February 7, 2012
    Publication date: January 2, 2014
    Inventors: Kristin Reichelt, Luigi Resconi, Juha Paavilainen
  • Patent number: 8618214
    Abstract: Provided is a fiber-reinforced composite. The composite has a propylene polymer including 90 wt % or more of propylene monomeric units based on the weight of the propylene polymer; a plurality of fibers of a solid, flexible material grafted to the propylene polymer; and an elastomer. The fibers are present in the composite at 10 wt % to 80 wt % based on the total weight of the composite. The propylene polymer is present in the composite at from 30 wt % to 95 wt % based on the total weight of the composite. The elastomer is present in the composite at from 5 wt % to 50 wt % based on the total weight of the composite. Greater than 50 wt % of the fibers are dispersed within the propylene polymer based on the total weight of the fibers in the composite. There is also provided a process for making a fiber-reinforced composite.
    Type: Grant
    Filed: December 17, 2010
    Date of Patent: December 31, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Andy Haishung Tsou, John Henry Dunsmuir, Donald Andrew Winesett
  • Patent number: 8618215
    Abstract: A modified polypropylene-based polymer obtained by graft modification of a propylene/?-olefin copolymer with a xylene-soluble portion of at least 40 mass % and no greater than 85 mass %, a xylene-soluble portion (XS) intrinsic viscosity (XSIV) of at least 2.5 dl/g, and an MFR value of no greater than 3.0 g/10 min at 230° C. under a load of 2.16 kg, using an unsaturated carboxylic acid or its derivative, and a flame retardant polyolefin-based resin composition having prescribed contents of a polyolefin-based resin component comprising 60-95 mass % of a polyolefin-based resin and 40-5 mass % of a modified polypropylene-based polymer, and an inorganic flame retardant component comprising an inorganic filler.
    Type: Grant
    Filed: January 19, 2007
    Date of Patent: December 31, 2013
    Assignee: Sunallomer Ltd.
    Inventors: Kazuhisa Yasumoto, Tomohiro Mochida
  • Patent number: 8618220
    Abstract: Propylene copolymer composition comprising a propylene homopolymer (A) as a matrix polymer and a propylene copolymer (B) containing 10-35 wt. % calculated with respect to the amount of B of an olefin other than propylene. The propylene homopolymer and the propylene copolymer are prepared using a Ziegler-Natta catalyst system. The propylene copolymer composition has a transparency higher than 8.
    Type: Grant
    Filed: June 17, 2005
    Date of Patent: December 31, 2013
    Assignee: Saudi Basic Industries Corporation
    Inventors: Ron Reijntjens, Klaas Remerie, Maria Soliman, Henrica Norberta Alberta Maria Steenbakkers-Menting
  • Patent number: 8618219
    Abstract: Disclosed herein is an in-reactor produced multi-component copolymer comprises a semi-crystalline component having a crystallinity of 20% or more, and an amorphous component having a crystallinity of 5% or less. The copolymer comprises at least 80 wt % of units derived from propylene and from about 1 to about 20 wt % of units derived from at least one C6 to C12 alpha-olefin. The copolymer has a viscosity at 190° C. of at least 530 mPa sec and a heat of fusion between about 10 and about 70 J/g. An adhesive containing the copolymer exhibits a good balance of adhesive properties and mechanical strength.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: December 31, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Patrick Brant, David Aaron Henning, David R. Johnsrud, Charles L. Sims
  • Patent number: 8617717
    Abstract: A film structure having a base layer comprising a film-forming thermoplastic polymer; and a heat-seal layer having a seal-initiation temperature less than or about 130° C. and comprising from about 50 to about 98 wt % of a first polymer component and about 2 to about 50 wt % of a second polymer component. The first polymer component comprising propylene-derived units and, optionally, up to about 20 wt % of comonomer units derived from a C2 and/or C4-C20 ?-olefin, and having a heat of fusion greater than 75 J/g and a melting point greater than or equal to 105° C. The second polymer component comprising at least 75 wt % propylene-derived units, and having a melting point less than 105° C. and a heat of fusion less than 75 J/g.
    Type: Grant
    Filed: October 26, 2006
    Date of Patent: December 31, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Michael Glenn Williams, Hans Joachim Pip
  • Patent number: 8617440
    Abstract: A polyethylene composition, in particular suitable for the preparation of monofilaments, mono-tapes and stretched tapes, is described. The polyethylene composition of the invention comprises 95.1%-99.5% by weight of polyethylene having a density above 0.930 g/cm3 and a polydispersity Mw/Mn from 2.0 to 5.9, and 4.9%-0.5% by weight of polybutene. The bubble stability and the me-chanical properties of the films prepared from this composition are advantageously improved. The use of a polyethylene composition comprising 90.0%-99.5% by weight of polyethylene having a density above 0.930 g/cm3, and 10.0%-0.5% by weight of polybutene, for preparing monofila-ments, monotapes or stretched tapes is also described.
    Type: Grant
    Filed: January 9, 2007
    Date of Patent: December 31, 2013
    Assignee: Basell Polyolefine GmbH
    Inventors: Franco Sartori, Siegfried Grabowski
  • Publication number: 20130344273
    Abstract: A molded article formed of a composition including 100 parts by weight of at least one kind of resin selected from the group consisting of thermoplastic resins and thermosetting resins, and 0.01 parts by weight to 10,000 parts by weight of a silylated polyolefin, which is obtained by a reaction between a silicon-containing compound containing a structural unit represented by Formula (1) and a vinyl group-containing compound having a defined number average molecular weight, a derivative thereof, or a mixture of these, —Si(R1)H—Y1—??(1) wherein R1 and Y1 are defined and with the proviso that the silylated polyolefin is not obtained by a reaction between a silicon-containing compound containing a structural unit represented by Formula (1) and having two or more SH groups per molecule and a compound having 2.0 or more vinyl groups on average per molecule as the vinyl group-containing compound.
    Type: Application
    Filed: January 18, 2012
    Publication date: December 26, 2013
    Applicant: Mitsui Chemicals, Inc.
    Inventors: Kaori Matoishi, Takuma Yano, Hiromasa Marubayashi, Naoki Tomoshige, Naoshi Nagai, Tamotsu Harada, Kuniaki Kawabe
  • Publication number: 20130343808
    Abstract: Disclosed is a high-density polyethylene (HDPE) composition that comprises at least a first high density polyethylene component having a density of 0.940-0.968 g/cm3 and a melt index I2.16 of 0.5-10.0 dg/min and a melt flow ratio (flow index I21.6 at 190° C. divided by melt index I2.16 at 190° C.) of at least 25. A second HDPE component may be included in the composition with melt index I2.16 of greater than 10 dg/min and melt flow ratio of 30 or less. The disclosed compositions are suitable for use in living hinge closure applications.
    Type: Application
    Filed: June 10, 2013
    Publication date: December 26, 2013
    Inventors: Brett Christopher Domoy, Barrett Albert Unger, Mark T. Joblonka
  • Patent number: 8614277
    Abstract: Isotactic polypropylene ethylene-propylene copolymer blends and in-line processes for producing. The blends may have between 1 and 50 wt % of isotactic polypropylene with a melt flow rate of between 0.5 and 20,000 g/10 min and a melting peak temperature of 145° C. or higher, and wherein the difference between the DSC peak melting and the peak crystallization temperatures is less than or equal to 0.5333 times the melting peak temperature minus 41.333° C., and between 50 and 99 wt % of ethylene-propylene copolymer including between 10 wt % and 20 wt % randomly distributed ethylene with a melt flow rate of between 0.5 and 20,000 g/10 min, wherein the copolymer is polymerized by a bulk homogeneous polymerization process, and wherein the total regio defects in the continuous propylene segments of the copolymer is between 40 and 150% greater than a copolymer of equivalent melt flow rate and wt % ethylene polymerized by a solution polymerization process.
    Type: Grant
    Filed: February 13, 2012
    Date of Patent: December 24, 2013
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Gabor Kiss, Patrick Brant, Robert Patrick Reynolds, Jr., Aspy K. Mehta, Manika Varma-Nair, John W. Chu, Steven P. Rucker
  • Publication number: 20130338314
    Abstract: A process for preparing a multimodal polyethylene product with at least two different polyethylene resins can include producing a first polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The Ziegler-Natta catalyst used for the production of the first polyethylene resin has an average particle size (D50) of at most 15 ?m. The HLMI of the first polyethylene resin is between 0.01 and 5 g/10 min. The process can include separately producing a second polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The MI2 of the second polyethylene resin is between 1 and 150 g/10 min. The process can include physically blending together the first and second polyethylene resins to produce a multimodal polyethylene product. The physical blending can be performed in a device for continuously melting and blending the first and second polyethylene resins.
    Type: Application
    Filed: March 2, 2012
    Publication date: December 19, 2013
    Applicant: TOTAL RESEARCH & TECHNOLOGY FELUY
    Inventors: Daan Dewachter, Eric Damme