Specified Material Contains A Peroxy Group, I.e., -o-o- Patents (Class 525/263)
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Patent number: 6911498Abstract: A curing composition of a fluororubber comprising a fluororubber which is curable with an organic peroxide, for example, an iodine-containing fluororubber, a polyfunctional unsaturated compound, and an organic peroxide, for example, dicumyl peroxide, in which the total amount of acetone and tert.-butanol contained in the decomposed products of the organic peroxide, which are generated at a curing temperature, is 2 moles or less per one mole of the decomposed products.Type: GrantFiled: April 14, 1998Date of Patent: June 28, 2005Assignee: Daikin Industries Ltd.Inventors: Koji Matsumoto, Yoshihiro Shirai
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Patent number: 6911511Abstract: The invention relates to a process for the polymerization of at least one monomer which can be polymerized via a radical route, in the presence of a stable free radical and of a polymerization initiator, such that, per 100 mol of monomer, the molar amounts of stable radical (SFR) and of initiator (INIT) are such that [(SFR)×FSFR]/[(INIT)×FINIT]<0.15 and FSFR×(SFR)<0.2 mol, in which FSFR represents the functionality of the stable free radical and FINIT represents the functionality of the initiator. The process according to the invention has advantageous kinetics, allows the production of grafted or block copolymers and can be carried out in an extruder.Type: GrantFiled: December 18, 1998Date of Patent: June 28, 2005Assignee: Elf Atochem S.A.Inventor: Denis Bertin
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Patent number: 6887940Abstract: A compatible blend of an engineering thermoplastic such as a polyamide and an olefin polymer material is prepared by (1) making an oxidized olefin polymer material containing carboxylic acid groups or derivatives thereof, (2) extruding a mixture of (a) the oxidized olefin polymer material from step (1), (b) an engineering thermoplastic, (c) optionally, an inorganic base, and (d) optionally, a non-oxidized olefin polymer material, and (3) recovering a blend of the engineering thermoplastic, the oxidized olefin polymer material or an ionomer thereof, which acts as a compatibilizer, and, optionally, the non-oxidized olefin polymer material. The oxidized olefin polymer material can be made by treating the olefin polymer material with an organic peroxide initiator while adding a controlled amount of oxygen.Type: GrantFiled: November 27, 2002Date of Patent: May 3, 2005Assignee: Basell Poliolefine Italia S.p.A.Inventors: Vu A. Dang, Dinshong Dong, Tam T. M. Phan, Cheng Q. Song
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Patent number: 6875823Abstract: There is provided a process for producing a modified polyolefin resin, which comprises the steps of: (1) blending at least the following components (A) to (D) to produce a blend: (A) 100 parts by weight of a polyolefin resin, (B) from 0.1 to 20 parts by weight of a compound having an epoxy group and an unsaturated bond, (C) from 0.01 to 20 parts by weight of an organic peroxide having a decomposition temperature of from 50 to 115° C., at which temperature a half-life thereof is 1 minute, and (D) from 0 to 20 parts by weight of an organic peroxide having a decomposition temperature of from 150 to 200° C., at which temperature a half-life thereof is 1 minute, and (2) melt-kneading said blend to produce a modified polyolefin resin.Type: GrantFiled: August 7, 2003Date of Patent: April 5, 2005Assignee: Sumitomo Chemical Company, LimitedInventors: Shinichi Kondo, Takashi Sanada
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Patent number: 6875817Abstract: Separation of a variety of analytes that are polar, nonpolar and ionic using functionalized polymeric media is disclosed. Preformed rigid particles of highly crosslinked homopolymer of polyvinylidene compounds are functionalize using the residual vinyl groups onto which monovinyl compounds are covalently bonded through polymerization. The functionalization imparts desirable surface properties for separation applications such as liquid chromatography and solid phase extraction.Type: GrantFiled: August 21, 2001Date of Patent: April 5, 2005Assignee: Mallinckrodt Inc.Inventors: Nandkumar V. Deorkar, James Farina, Paul A. Bouis
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Patent number: 6870003Abstract: A process for producing modified thermoplastic resin by subjecting a thermoplastic resin to a modifying reaction in a molten state, comprising performing the modifying reaction using carbon dioxide as the reaction medium, wherein carbon dioxide is used in a proportion of 2-200 parts by weight per 100 parts by weight of the thermoplastic resin, whereby the efficiency and the uniformity of the reaction can be increased to a high extent while attaining considerable decrease in the remaining amount of the unreacted components in the resulting modified thermoplastic resin without having recourse to the use of an organic reaction solvent, so that the production can be realized easily at a low cost in an efficient manner.Type: GrantFiled: February 25, 2002Date of Patent: March 22, 2005Assignee: Mitsui Chemical, Inc.Inventors: Shigeo Nishikawa, Haruo Inoue, Naohiro Yamada
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Patent number: 6861461Abstract: A composition of matter or modifier for use in modifying unfunctionalized polymers comprising a metal oxide substrate that can be formed into a sol, a water soluable, acid moiety, having a hydrocarbyl group with olefinic unsaturation, bound to the metal oxide substrate and a water soluble, free radical initiator, the composition of matter generally being in the form of a dry powder that can be mixed with a polymer lacking functional groups whereupon when the mixture is subjected to conditions which result in the decomposition of the free radical initiator to form free radicals.Type: GrantFiled: October 29, 2003Date of Patent: March 1, 2005Assignee: Sasol North America Inc.Inventor: Thomas J. Martin
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Patent number: 6855771Abstract: A process for manufacturing block polymer or copolymer from isotactic polypropylene. Polyolefins are introduced into an extruder. Free radical generator is mixed with the polyolefins to form a mixture at room temperature for free radical formation. The mixture is brought up to a temperature of between 175° C. to 220° C. Chain degradation of the polyolefins is induced by the free radical formation to form degraded polymer. Alkenically unsaturated monomers or polymer segments are mixed with the degraded polymer to form a second mixture. The temperature of the second mixture may be lowered to a temperature of between 90° C. to 150° C. The temperature of the second mixture is then adjusted to a temperature between 100° C. to 250° C. to form a novel block polymer or copolymer.Type: GrantFiled: October 31, 2002Date of Patent: February 15, 2005Inventors: Grant Doney, Keith Salsman
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Patent number: 6849688Abstract: Novel polystyrene grafted polyolefin compositions having a high level of grafting are made using a novel process which involves suspending styrene in water. The polystyrene grafted polyolefin compositions can then be converted into ion exchange membranes that are particularly useful in electrolytic cells.Type: GrantFiled: March 26, 2002Date of Patent: February 1, 2005Assignee: Sachem, Inc.Inventor: Mark Hellums
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Patent number: 6830777Abstract: In a method for producing electrical cables coated with cross-linked polyethylene, a polyethylene granulate is mixed with a liquid silane-containing cross-linking agent, the granulate thus prepared is melted in an extruder and extruded onto the electrical cable, and the extruded coating is cross-linked in the presence of water or steam. A mixture of granular material of a polyethylene homopolymer and a polyethylene copolymer is coated with the cross-linking agent. The copolymer content in the coating on the cable is between 1 and 8% by weight.Type: GrantFiled: July 24, 2001Date of Patent: December 14, 2004Assignee: NexansInventors: Franz Danekas, Marc Strittmatter
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Patent number: 6831132Abstract: In accordance with the present invention, there are provided film adhesive compositions comprising at least one macromonomer having at least one unit of ethylenic unsaturation, at least one thermoplastic elastomer co-curable with the macromonomer, and at least one cure initiator, and methods for use thereof. Invention compositions are useful as adhesives in the microelectronics industry. In particular, invention film adhesives may be used to produce microelectronic assemblies with very thin bond lines without compromising adhesive strength.Type: GrantFiled: March 28, 2002Date of Patent: December 14, 2004Assignee: Henkel CorporationInventors: Puwei Liu, Stephen M. Dershem, Kang Yang, Carolyn C. Albino
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Patent number: 6828380Abstract: A molding composition having good surface gloss, high elongation at break and good thermoplastic processability is disclosed. The composition contains (A) a graft polymer that is obtained by free-radical polymerization of resin-forming vinyl monomers in the presence of rubber in latex form, (B) a copolymer of styrene and acrylonitrile and an optional (C) a resin selected from the group consisting of polycarbonates, polyester-carbonates, polyesters and polyamides. The preparation of the graft polymer is characterized in that (i) before the start of the grafting polymerization reaction the rubber latex is brought to a pH of 9 to 11, (ii) the redox initiator components are employed in amounts of 0.1 to 2.5 wt. % (based on the monomers metered in) and (iii) during the entire grafting polymerization reaction the pH remains constant±0.5 and in the range of 11.0 to 8.8, and (iv) the temperature difference between the start and end of the reaction is at least 10° C.Type: GrantFiled: November 21, 2002Date of Patent: December 7, 2004Assignee: Bayer AktiengesellschaftInventors: Liqing-Lee Sun, Eckhard Wenz, Herbert Eichenauer, Stefan Moss, Heinrich Alberts, Hans-Bernhard Hauertmann, Karl Zabrocki, Hans-Erich Gasche, Ulrich Jansen
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Patent number: 6822046Abstract: A process is disclosed for improving the environmental stress crack resistance and other desirable properties of impact-resistant, elastomer-modified monovinylaromatic compounds, said process utilizing a combination of polymerization initiators, including perketals and peroxycarbonates.Type: GrantFiled: January 17, 2002Date of Patent: November 23, 2004Assignee: Fina Technology, Inc.Inventors: Jianbo Li, Jose M. Sosa, Aron Griffith
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Patent number: 6815500Abstract: The invention concerns a method for preparing a composition comprising a vinylaromatic polymer enclosing rubber nodules. The invention is characterised in that it includes a step for polymerising at least one vinylaromatic monomer in the presence of rubber, a polymerisation initiator and a stable free radical, said step being such that [FSFR×(SFR)]: [FAMO×(AMO)] range from 0.05 to 1, FFSR and FAMO representing the functionality of the stable free radical and the initiator respectively and (SFR) and (AMO) representing the molar quantities of the stable free radical and the initiator respectively, The final composition is particularly resistant to shock and/or shiny.Type: GrantFiled: August 31, 2001Date of Patent: November 9, 2004Assignee: AtofinaInventor: Jean-Marc Boutillier
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Patent number: 6815498Abstract: A process for the preparation of a reaction product (A), which comprises the following stage (i): (i) Reaction, under free radical conditions, of a reaction mixture comprising at least one monomer (a), capable of free radical reaction in the presence of at least one free radical initiator and a compound of the formula (I) where R1 to R4, independently of one another, are each hydrogen, an alkyl radical, cycloalkyl radical or aralkyl radical, each of which is unsubstituted or substituted, an unsubstituted or substituted aromatic hydrocarbon radical, with the proviso that at least two of the radicals R1 to R4 are an unsubstituted or substituted aromatic hydrocarbon radical, or R1 and R2 or R3 and R4, in each case in pairs, are a substituted or unsubstituted aromatic hydrocarbon having 6 to 18 carbon atoms and a functional group which, in conjugation with the C—C double bond in the formula I, has a multiple bond between a carbon atom and a heteroatom, 10% by weight or less of wateType: GrantFiled: June 13, 2002Date of Patent: November 9, 2004Assignee: BASF AktiengesellschaftInventors: Roman Benedikt Raether, Bernd Modery, Frank Braun, Susanne Brinkmann-Rengel, David Christie, Sylke Haremza
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Publication number: 20040197587Abstract: A two-part adhesive systems exhibiting improved fixture and open times are disclosed. In one embodiment, the system includes (a) an adhesive part being a mixture formed from (I) an ethylenically unsaturated monomer, (II) a metal molybdate, (III) a metal salt of an ethylenically unsaturated carboxylic acid in an amount less than 3 weight percent, and (IV) an ethylenically unsaturated carboxylic acid, and (b) an activator part which includes a free radical generator. In another embodiment, the system includes the above-described adhesive part substantially free of a metal salt of an ethylenically unsaturated carboxylic acid. Curable adhesives and laminates prepared with the two-part system are also disclosed.Type: ApplicationFiled: April 9, 2004Publication date: October 7, 2004Inventors: Daniel Keith Doe, Donald Edmond Gosiewski
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Publication number: 20040198914Abstract: A process for producing a modified polyethylene resin, which comprises the step of melt kneading at least:Type: ApplicationFiled: March 16, 2004Publication date: October 7, 2004Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Shinichi Kondo, Takashi Sanada
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Patent number: 6790909Abstract: The invention relates to a process for preparing a reaction product (RP) which is functionalized by groups containing halogen or sulfonyl chloride by reaction of at least one free-radically polymerizable monomer, at least one compound of the formula (I), at least one free-radical initiator and at least one free-radically polymerizable monomer containing halogen or sulfonyl chloride groups under free-radical conditions, and to a reaction product (RP) which can be prepared by the process of the present invention and to the use of the reaction product (RP) as macroinitiator for the preparation of graft copolymers. Furthermore the invention relates to a process for preparing graft copolymers by reaction of the reaction product (RP) with at least one suitable monomer and to graft copolymers which can be prepared by the process of the present invention and also to the use of the graft copolymers of the present invention.Type: GrantFiled: July 14, 2003Date of Patent: September 14, 2004Assignee: BASF AktiengesellschaftInventors: Yvonne Heischkel, Nicolas Stöckel, Philipp Wieland, Marcus Schäfer, Oskar Nuyken
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Patent number: 6790908Abstract: The invention relates to a block copolymer and more especially to a thermoplastic elastomer block copolymer. The block copolymer is a diblock (block A)-(bloc B) copolymer, a triblock (block A)-(block B)-(block A), or a triblock (block A)-(block B)-(block C) copolymer, wherein block A is a stiff block, block B is a soft block, and block C is a stiff block. Block A or Block B comprises repetitive units deriving from segregation monomers.Type: GrantFiled: May 9, 2002Date of Patent: September 14, 2004Assignee: Rhodia Inc.Inventors: Denis Bendejacq, Mathieu Joanicot, Gilda Lizarraga, Virginie Ponsinet
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Patent number: 6784253Abstract: An emulsion polymerization process for the preparation of polybutadiene grafted with styrene and acrylonitrile monomers in a reaction system is provided. The resultant product has a low end content of unreacted residual monomers, low yellowness index, and improved impact strength. The diene rubber is prepared via a process wherein a chain transfer agent is added on a continuous basis to give a rubber substrate having a low crosslink density. In one embodiment of the invention, the process includes charging the reaction system with a pre-selected diene emulsion with a low crosslink density, adding a first portion of at least one of a styrene monomer and acrylonitrile monomer to the diene emulsion, adding to the reaction system, over a predetermined time, an initiator and a second portion of acrylonitrile and styrene monomer, and polymerizing the catalyzed reaction mixture of diene substrate, styrene and acrylonitrile to form ABS graft polymers.Type: GrantFiled: July 23, 2002Date of Patent: August 31, 2004Assignee: General Electric CompanyInventors: Shripathy Vilasagar, Vern Lowry, Dane M. Ferraris, Ke Feng, Robert E. Colborn, Matthew Hal Littlejohn, David Francis Townsend
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Patent number: 6784251Abstract: An emulsible polyolefin wax having sufficient functionality to be emulsible in an aqueous medium, a melt viscosity of less than 1,000 cps at 190° C., and an emulsion light transmittance of at least 10% at 525 nm with a 20 mm light pathlength.Type: GrantFiled: February 5, 2002Date of Patent: August 31, 2004Assignee: Honeywell International Inc.Inventors: Charles Lences, Peter F. Romeo, Manfred Seven
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Patent number: 6780932Abstract: Disclosed is a process for preparation of final graft polyols via a continuous process. In, addition, a final graft polyol formed by the process is disclosed. The process includes the steps of reacting a plurality of ethylenically unsaturated monomers and a reaction moderator with a macromer having induced unsaturation in the presence of a carrier polyol, a free radical polymerization initiator, and a first graft polyol. The process provides for the preparation of a final graft polyol having a solids level of from 30 to 70% in a continuous process. The final graft polyol produced by the process has a lower viscosity over a range of solids levels, a reduced amount of very large irregularly shaped particles, a reduced viscosity change in response to a change in reaction temperature compared to a typical graft polyol, a reduced tendency to foul the continuous reactor, and a broader particle size distribution compared to an identical graft polyol prepared by a semi-batch process.Type: GrantFiled: May 15, 2002Date of Patent: August 24, 2004Assignee: BASF CorporationInventors: Duane A. Heyman, Mao-Yao Huang
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Patent number: 6777478Abstract: The adhesive material contains a radical-polymerizable compound, a curing agent, and a thermoplastic resin; gives a negative result of the Ames test; and has a PII, or skin irritation, value of 2 or less. In particular, all the starting ingredients should preferably give a negative result of the Ames test and have a PII, or skin irritation, value of 2 or less.Type: GrantFiled: March 7, 2001Date of Patent: August 17, 2004Assignee: Sony Chemicals CorporationInventor: Tomoyuki Ishimatsu
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Patent number: 6770716Abstract: It has been discovered that certain compounds serve as polymerization accelerators when employed together with peroxide initiators for the polymerization of vinylaromatic monomers. Suitable accelerators that increase the rate of decomposition of the peroxide initiator include, but are not necessarily limited to, hydroperoxides and/or metallic salts. Representative examples of suitable hydroperoxide accelerators include t-butyl hydroperoxide (TBH), cumyl hydroperoxide, and p-isopropyl cumyl hydroperoxide, whereas suitable metallic salt accelerators include cobalt naphthenate and cobalt acetoacetonate. Use of these accelerators when vinylaromatic monomers are polymerized in the presence of polybutadienes and peroxide initiators results in an increase in grafting as compared with similar copolymers made without the accelerator.Type: GrantFiled: March 4, 2003Date of Patent: August 3, 2004Assignee: Fina Technology, Inc.Inventors: Jose M. Sosa, Cyril Chevillard
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Patent number: 6767965Abstract: The present invention provides a method of preparing a monomer-grafted syndiotactic polystyrene with polarity, which comprises (a) forming swollen syndiotactic polystyrene by mixing with a syndiotactic polystyrene in powder state and a radical initiator in a solvent at the temperature of 40-80° C. using a batch reactor, and (b) grafting a monomer selected from the group consisting of maleic anhydride, maleic imide and derivatives thereof onto the swollen syndiotactic polystyrene.Type: GrantFiled: January 10, 2003Date of Patent: July 27, 2004Assignee: Samsung Atofina Co. Ltd.Inventors: Xuequan Zhang, Jae Gon Lim, Jung Hyun Baik, Hyun Joon Kim
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Publication number: 20040132620Abstract: There is provided a process for producing a modified ethylene-vinylcyclohexane copolymer resin, which comprises the steps of:Type: ApplicationFiled: July 23, 2003Publication date: July 8, 2004Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Shinichi Kondo, Takashi Sanada
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Publication number: 20040110904Abstract: The present invention relates to a shaped article containing at least one peroxide curable compound containing a butyl-like polymer(s) without any conjugated aliphatic diene in its composition, said polymer containing less than 15 wt. % of solid matter insoluble in boiling cyclohexane under reflux for 60 min. The present invention also relates to a sealing material and a medical device containing at least one peroxide-curable compound containing a butyl-like polymer containing less than 15 wt. % of solid matter insoluble in boiling cyclohexane under reflux for 60 min. Further, the present invention relates to a process for producing a butyl-like polymer having no conjugated aliphatic diene in its composition and containing less than 15 wt. % of solid matter insoluble in boiling cyclohexane under reflux for 60 min.Type: ApplicationFiled: October 1, 2003Publication date: June 10, 2004Inventors: Adam Gronowski, Akhtar Osman, Stephan Glander
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Publication number: 20040110856Abstract: A method of forming features on substrates by imprinting is provided. The method comprises: (a) forming a polymer solution comprising at least one polymer dissolved in at least one polymerizable monomer; and (b) depositing the polymer solution on a substrate to form a liquid film thereon; and then either: (c) curing the liquid film by causing the monomer(s) to polymerize and optionally cross-linking the polymer(s) to thereby form a polymer film, the polymer film having a glass transition temperature (Tg); and imprinting the polymer film with a mold having a desired pattern to form a corresponding negative pattern in the polymer film, or (d) imprinting the liquid film with the mold and curing it to form the polymer film. The temperature of imprinting is as little as 10° C. above the Tg, or even less if the film is in the liquid state. The pressure of the imprinting can be within the range of 100 to 500 psi.Type: ApplicationFiled: December 4, 2002Publication date: June 10, 2004Inventors: Jung Gun Young, Sivapackia Ganapathiappan, Yong Chen, Richard Stanley Williams
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Patent number: 6743860Abstract: The present invention relates to a thermoplastic resin composition comprising (a) 100 parts by weight of a block copolymer comprising at least two polymeric blocks A composed mainly of a vinyl aromatic compound and at least one polymeric block B composed mainly of a conjugated diene compound, or a hydrogenated block copolymer thereof, (d) 5 to 50 parts by weight of an organic peroxide, and (e) 10 to 80 parts by weight of one or more substances selected from the group consisting of multifunctional vinyl compounds and multifunctional (meth)acrylate compounds. The present invention provides a master batch of an organic peroxide in which the organic peroxide is so uniformly dispersed in a thermoplastic resin that crosslinking and/or decomposition occur uniformly, a method of preparing the same, a thermoplastic resin composition obtained using the master batch and a method of preparing the same.Type: GrantFiled: August 2, 2002Date of Patent: June 1, 2004Assignee: Riken Technos CorporationInventor: Hiroki Mizuno
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Publication number: 20040087724Abstract: A process for manufacturing block polymer or copolymer from isotactic polypropylene. Polyolefins are introduced into an extruder. Free radical generator is mixed with the polyolefins to form a mixture at room temperature for free radical formation. The mixture is brought up to a temperature of between 175° C. to 220° C. Chain degradation of the polyolefins is induced by the free radical formation to form degraded polymer. Alkenically unsaturated monomers or polymer segments are mixed with the degraded polymer to form a second mixture. The temperature of the second mixture may be lowered to a temperature of between 90° C. to 150° C. The temperature of the second mixture is then adjusted to a temperature between 100° C. to 250° C. to form a novel block polymer or copolymer.Type: ApplicationFiled: October 31, 2002Publication date: May 6, 2004Inventors: Grant Doney, Keith Salsman
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Patent number: 6723796Abstract: Methods are disclosed for making graft copolymers. The methods comprise the steps of: (a) providing (i) an ethylene/propylene (EP) copolymer or other graftable polymer, (ii) an ethylenically unsaturated sulfur-, nitrogen- and/or oxygen-containing monomer, and (iii) an amount of an initiator sufficient to graft said monomer and EP copolymer or other graftable polymer, (b) introducing said EP copolymer or other graftable polymer into an extruder; (c) introducing said monomer into the extruder; (d) introducing said initiator into the extruder, wherein at least one of the above-identified reactants in (a) is introduced in the presence of a polar solvent; and (e) reacting said EP copolymer or other graftable polymer, monomer and initiator by operating said extruder, thereby forming the graft copolymer. This invention also relates to methods of making a dispersant viscosity index improver and methods for making a lubricating oil.Type: GrantFiled: March 11, 2002Date of Patent: April 20, 2004Assignee: Castrol LimitedInventors: Irwin L. Goldblatt, Richard P Sauer
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Patent number: 6716926Abstract: A process for obtaining a polyolefin composition endowed with improved adhesion performance, especially paintability, comprising premixing a high-flow polyolefin resin with one or more grafting monomers and initiator, possibly also one or more comonomers, feeding the obtained premix and a low-flow polyolefin resin into a mixing device, and gradually heating the components to above their melting points while being subjected to mixing forces. The process may be carried out in an extruder, and polyether amine may optionally be introduced into the extruding mass downstream of the feeding point.Type: GrantFiled: April 26, 2002Date of Patent: April 6, 2004Assignee: Borealis Technology OyInventor: Kjetil L. Børve
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Patent number: 6713563Abstract: A process for making a vinylidene fluoride-co-trifluoroethylene networked polymer comprising the steps of: providing a poly(vinylidene fluoride-co-trifluoroethylene) copolymer; mixing the copolymer with a peroxide and a coagent to form a curing mixture; and processing the curing mixture such that the peroxide, in combination with the coagent, crosslinks the copolymer to form a networked polymer.Type: GrantFiled: March 29, 2002Date of Patent: March 30, 2004Assignee: The United States of America as represented by the Secretary of the NavyInventors: Charles M. Roland, Riccardo Casalini
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Patent number: 6706391Abstract: An anisotropically electroconductive film, which has a high reliability in its capacity for conducting electricity and also a good adhesion under such an adhesive condition that the film is heated at a temperature of 130° C. or less for a short period of time, has a layer of an adhesive within which electroconductive particles are distributed. The adhesive is composed of a thermosetting resin composition including a base resin, a reactive compound, an organic peroxide and a reaction accelerating compound, and also the electroconductive particles incorporated into the thermosetting resin composition. The base resin is a polyacetalized resin which is obtained by acetalizing a polyvinyl alcohol. The reactive compound is at least one selected from a group consisting of acryloxy group-bearing compounds, methacryloxy group-bearing compounds and epoxy group-bearing compounds. The reaction accelerating compound is a compound which has a radically reactive group and alkali-reactive group as its end groups.Type: GrantFiled: July 26, 2001Date of Patent: March 16, 2004Assignee: Bridgestone CorporationInventors: Ryo Sakurai, Hidetoshi Hiraoka, Tokuo Okada, Teruo Miura, Yasuhiro Morimura
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Patent number: 6703460Abstract: It has been discovered that sequential polyperoxides can be beneficially used as initiators for vinylaromatic/diene copolymers to give high grafting values and reasonable molecular weights. A new cyclic diperoxide did not give these same results. The sequential polyperoxide initiators can be used as the only initiators or together with other conventional peroxide initiators to advantage. The polymerization rate can also be increased using these sequential polyperoxide initiators.Type: GrantFiled: March 4, 2003Date of Patent: March 9, 2004Assignee: Fina Technology, Inc.Inventors: Kenneth Paul Blackmon, Lu Ann Kelly
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Patent number: 6699949Abstract: An in situ controlled oxidation reaction of trialkylborane (BR3) in the presence of polyolefin and maleic anhydride produces mono-oxidized trialkylborane adducts, i.e., peroxyldialkylborane (R—O—O—BR2), that can undergo homolytic cleavage to form (R—O* *O—BR2) and activate the polyolefin chain by alkoxyl radical (R—O*) hydrogen-abstraction at ambient temperature. The formed polymeric radical (C*), associated with the oxidized borane moiety (*O—BR2), then reacts with maleic anhydride by addition reaction, without side reactions, to form functional polyolefins that contain incorporated maleic anhydride side groups.Type: GrantFiled: May 30, 2002Date of Patent: March 2, 2004Assignee: Penn State Research FoundationInventor: Tze-Chiang Chung
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Patent number: 6670427Abstract: Template-textured materials in the form of template-textured polymers (TGP) on various surfaces including membranes (i.e, template-textured membranes). Such materials are created by modifying the surface of solid carriers, which, by cross-linking polymerization of functional monomers initiated on the surface of said solid carriers in the presence of a template, leads to stable template prints that subsequently bind template molecules or template derivatives in a specific manner. The invention also relates to methods for the production of TGPs and to the use thereof for substance-specific separation of materials.Type: GrantFiled: March 26, 2001Date of Patent: December 30, 2003Assignee: Poly-Am GmbHInventors: Mathias Ulbricht, Sergiy Piletski, Uwe Schedler, Heike Matuschewski
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Patent number: 6620883Abstract: The invention relates to a process for the preparation of graft rubber polymers of the ABS type by emulsion polymerization according to the so-called fed batch process, in which latexes having markedly reduced residual monomer contents are obtained, and to compositions containing the mentioned graft rubber polymers.Type: GrantFiled: September 26, 2001Date of Patent: September 16, 2003Assignee: Bayer AktiengesellschaftInventors: Hans-Erich Gasche, Herbert Eichenauer, Pierre Vanhoorne, Ulrich Jansen, Eckhard Wenz, Stefan Moss
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Patent number: 6620876Abstract: A storage stable monomer/polymer composition comprises a component A and a component B. Component A comprises an emulsion polymer formed by the polymerization of 1-99% by weight of a C1-C10 alkyl acrylate, 99-1% by weight of C1-C10 alkyl methacrylate, and 0-0.5% by weight of a first graft component, which is then swollen by a mixture of at least one ethylenically unsaturated monomer and a polymerization initiator. Component B also comprises an emulsion polymer formed by the polymerization of 1-99% by weight of C1-C10 alkyl acrylate, 99-1% by weight of C1-C10 alkyl methacrylate, and 0-0.5% by weight of a second graft component, swollen with at least one ethylenically unsaturated monomer and a polymerization activator. Curing of the monomer/polymer composition begins only after the water has evaporated from the dispersion. The aqueous monomer/polymer compositions are used as binders for road marking paints, floor coating compositions, coating materials and sealing compositions.Type: GrantFiled: October 18, 2001Date of Patent: September 16, 2003Assignee: Roehm GmbH & Co., KGInventors: Peter Quis, Monika Rohrer
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Patent number: 6608143Abstract: Acrylic copolymers are provided which have polymeric portions having different polarities or glass transition temperatures, which permit easy selection of combinations of such polymeric portions having different polarities or glass transition temperatures, which increase a design freedom and which are applicable for diverse uses. Acrylic copolymers including a polymeric backbone portion prepared via copolymerization of (a) an alkyl (meth)acrylate ester containing 1-14 carbon atoms in the alkyl, (b) an olefinic polymer or copolymer terminally modified by a free-radically polymerizable unsaturated double bond and (c) a polymer terminally modified by a free-radically polymerizable unsaturated double bond and having a number average molecular weight of 2,000-30,000 and a glass transition temperature of at least 30° C.Type: GrantFiled: November 6, 2001Date of Patent: August 19, 2003Assignee: Sekisui Chemical Co., Ld.Inventors: Masateru Fukuoka, Akira Nakasuga, Hiraku Miyashita, Hajime Nosetani
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Patent number: 6605671Abstract: The invention discloses an improved process for the production of cross-linked rubber particles. The cross-linking agents are added to the aqueous rubber dispersions and converted at relatively high temperatures without inertization of the reaction mix and without pressurizing of an inert gas. The cross-linked rubber particles are suitable, for example, for the production of technical rubber products and for various tire components.Type: GrantFiled: July 17, 2001Date of Patent: August 12, 2003Assignee: Bayer AktiengesellschaftInventor: Werner Obrecht
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Publication number: 20030149184Abstract: A curing composition of a fluororubber comprising a fluororubber which is curable with an organic peroxide, for example, an iodine-containing fluororubber, a polyfunctional unsaturated compound, and an organic peroxide, for example, dicumyl peroxide, in which the total amount of acetone and tert.-butanol contained in the decomposed products of the organic peroxide, which are generated at a curing temperature, is 2 moles or less per one mole of the decomposed products.Type: ApplicationFiled: October 15, 1999Publication date: August 7, 2003Inventors: KOJI MATSUMOTO, YOSHIHIRO SHIRAI
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Patent number: 6602959Abstract: The invention relates to a method for manufacturing a sealable and peelable polymer blend, in which method polystyrene and an ethylene copolymer are first melt blended and the obtained blend is further mixed with the same ethylene copolymer either by melt blending or dry blending so that the final polymer blend contains 1-50% by weight polystyrene and 99-50% by weight ethylene copolymer. Ethylene copolymer is preferably ethylene/methyl(meth)acrylate, ethylene/ethyl(meth)acrylate, ethylene/butyl(meth)acrylate or ethylene/vinylacetate copolymer.Type: GrantFiled: October 23, 2001Date of Patent: August 5, 2003Assignee: Optatech CorporationInventors: Torvald Vestberg, Ismo Lehtiniemi, Tarja Mäkelä
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Patent number: 6579947Abstract: The invention relates to a hydraulic fracturing fluid comprising an aqueous liquid, and a block copolymer containing at least one water-soluble block and one hydrophobic block and being particularly suited for use in high temperature ranges, greater than 180° C.Type: GrantFiled: February 20, 2001Date of Patent: June 17, 2003Assignee: Rhodia ChimieInventors: Caroline Heitz, Mathieu Joanicot, Robert J. Tillotson
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Patent number: 6569951Abstract: An elastic-thermoplastic graft polymer prepared by a multi-stage free radical polymerization is described. The elastic-thermoplastic graft polymer is prepared by polymerizing (i) one or more monomers containing vinyl groups, and (ii) at least one molecular weight regulating compound, in the presence of (iii) at least one rubber in latex form. The ratio of monomers (M) to the molecular weight regulating compound (MWR) is altered throughout the various stages of the polymerization method. The M:MWR ratio is: from 50:1 to 400:1 in the first stage; from 100:1 to 800:1 in the second stage; and from 200:1 to 2000:1 in the third stage of the polymerization. In at least one further reaction stage of the polymerization, the monomers, in the absence of the molecular weight regulating compound, are polymerized in the presence of the rubber. This further reaction stage occurs before the first stage and/or after the third stage of the polymerization.Type: GrantFiled: September 28, 2001Date of Patent: May 27, 2003Assignee: Bayer AktiengesellschaftInventors: Herbert Eichenauer, Hans-Erich Gasche, Ulrich Jansen
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Patent number: 6569950Abstract: There is provided a process for producing an acid modified polypropylene resin, which comprises the step of kneading: (1) 100 parts by weight of a polypropylene resin (A), (2) 0.1 to 20 parts by weight of an unsaturated carboxylic acid or a derivative thereof (B), (3) 0.01 to 20 parts by weight of an organic peroxide (C) having a decomposition temperature of from 50 to 120° C., at which a half-life of the organic peroxide is 1 minute, and (4) optionally, 0.01 to 20 parts by weight of an organic peroxide (D) having a decomposition temperature of from 150 to 200° C., at which a half-life of the organic peroxide is 1 minute.Type: GrantFiled: January 14, 2002Date of Patent: May 27, 2003Assignee: Sumitomo Chemical Company, LimitedInventors: Katsuhisa Kitano, Takashi Sanada
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Patent number: 6562901Abstract: Present invention is a resin composition obtained by reacting polyolefin (A) with a (co)polymer (B) prepared from a copolymerizable monomer mixture (C) comprising an &agr;,&bgr;-monoethylenically unsaturated monomer and other copolymerizable monomers in a weight ratio (A)/(B)=1/9-9/1 under radical generation in an organic solvent, or by polymerizing a copolymerizable monomer mixture (C) comprising an &agr;,&bgr;-monoethylenically unsaturated monomer and other copolymerizable monomers in the presence of polyolefin (A) in a weight ratio (A)/(C)=1/9-9/1 in an organic solvent and successively by reacting the obtained reaction mass under radical generation; and the resin composition has good solution stability, does not cause liquid phase separation or solid precipitation, can be used as intact, is excellent in sprayability at high concentration, and, specifically, has novel function and effect that adhesion to polyolefin molded articles is excellent; and the resin composition can be favorably used fType: GrantFiled: February 23, 2001Date of Patent: May 13, 2003Assignee: Mitsui Chemicals, Inc.Inventors: Keiichi Asami, Taisaku Kano, Koichi Machida, Tsukasa Murakami
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Publication number: 20030087982Abstract: A method of modifying a polymeric material which comprises the steps of activation-treatment and a hydrophilic polymer-treatment, or comprises the steps of activation-treatment, a hydrophilic polymer-treatment, and monomer grafting in this order, or comprises the step of a solvent-treatment followed by these steps. Thus, the polymeric material, e.g., polyolefin, is improved in hydrophilicity, adhesion, etc. without lowering the practical strength thereof The polymeric material thus improved in adhesion and other properties can be used in many applications where water absorption and adhesion are required, such as an absorption material, e.g., a wiping/cleansing material, a water retention material, a material for microorganism culture media, a separator for batteries (or cells), a synthetic paper, a filter medium, a textile product for clothing, a medical/sanitary/cosmetic supply, and reinforcing fibers for composite materials.Type: ApplicationFiled: August 27, 2001Publication date: May 8, 2003Inventor: Hitoshi Kanazawa
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Patent number: 6559230Abstract: Safety glass interlayers are prepared from a composition comprising: A. A homogeneously linear or substantially linear ethylene/&agr;-olefin interpolymer, e.g., ethylene/1-octene; B. A coagent containing at least two vinyl groups, e.g., trimethyol propane tri(meth)acrylate; and C. A peroxide, e.g., Luperox™ 101. The interlayer films exhibit an excellent combination of tear strength and clarity.Type: GrantFiled: September 21, 2001Date of Patent: May 6, 2003Assignee: DuPont Dow Elastomers L.L.C.Inventors: Henry G. Heck, Douglas P. Waszeciak
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Patent number: 6552130Abstract: A resin composition comprising (A) a (meth)acrylic acid ester (B) and an acrylic polymer soluble in the component (A) and further (C) a compound having a mercapto group (—SH) and a carboxyl group (—COOH) in the molecule or an component (C) and (F) an organic amine or an component (F) and (G) a radical trapping agent. The composition is suitably used as a covering material for civil engineering and construction applications.Type: GrantFiled: July 18, 2001Date of Patent: April 22, 2003Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Takayuki Makino, Toshio Takemoto