Ethylenic Reactant Contains Nitrogen Heterocycle, E.g., Pyridine, Diazines, Etc. Patents (Class 525/279)
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Patent number: 5451453Abstract: Supports having azlactone-functional surfaces, adduct supports prepared from such azlactone-functional supports, and methods of preparing both are disclosed. Azlactone functionality is introduced to surfaces of a pre-existing support in a manner which retains useful physical and chemical characteristics of the pre-existing support. One method involves exposing surfaces with high energy radiation to generate free radical reaction sites on the surfaces and causing azlactone-functional moieties to react with the free radical reaction sites. Another method involves coating surfaces with azlactone monomers, crosslinking monomers, and optionally co-monomers and polymerizing the monomers to form a polymerized coating of azlactone-functionality on the surfaces. Another method involves dispersion polymerization of azlactone-functional moieties to produce azlactone-functional particles within pores and interstices of a pre-existing support.Type: GrantFiled: June 20, 1994Date of Patent: September 19, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: David R. Gagnon, Patrick L. Coleman, Gary J. Drtina, Oh-Seung Kwon, Christopher S. Lyons, Dean S. Milbrath, Jerald K. Rasmussen, Julie B. Stahl
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Patent number: 5439983Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.Type: GrantFiled: July 27, 1994Date of Patent: August 8, 1995Assignee: Phillips Petroleum CompanyInventors: Iqbal Ahmed, Henry L. Hsieh
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Patent number: 5438099Abstract: Abstract of the disclosure: A particulate graft copolymer comprises 30 to 90% by weight of at least one elastomeric grafting base A having a weight average particle size of from 30 to 1,000 nm comprising, based on A, 85 to 99.8% by weight of at least one alkyl acrylate A11 having 1 to 8 carbon atoms in the alkyl radical, 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A12, and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or hydroxyalkyl methacrylate A13 or at least 50% by weight of one or more dienes A111, up to 50% by weight of one or more ethylenically unsaturated monomers A112, and 0.1 to 10% by weight of at least one hydroxyalkyl acrylate or hydroxyalkyl methacrylate A113 and10 to 70% by weight of a graft sheath B comprising, based on B, up to 99.9% by weight of at least one aromatic vinyl monomer B1, up to 99.9% by weight of at least one polar, copolymerizable, ethylenically unsaturated monomer B2, and 0.Type: GrantFiled: December 13, 1993Date of Patent: August 1, 1995Assignee: BASF AktiengesellschaftInventors: Wolfgang Fischer, Norbert Guentherberg
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Patent number: 5436297Abstract: A modified polyolefin comprising: (A) 100 parts by weight of a polyolefin; (B) 0.01 to 20 parts by weight of a monomer mixture consisting of: (b-1) 5 to 50% by mole of glycidyl acrylate, glycidyl methacrylate or an unsaturated glycidyl compound represented by general formula (I) below ##STR1## wherein R is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; Ar is an aromatic hydrocarbon group having 6 to 20 carbon atoms and having at least one glycidyl group; and n is an integer of 1 to 4, and (b-2) 95 to 50% by mole of at least one monomer selected from the group consisting of acrylamide monomers, vinylpyrrolidones, acrylic acid esters and methacrylic acid esters, the monomer mixture being graft-copolymerized with the polyolefin.Type: GrantFiled: October 27, 1993Date of Patent: July 25, 1995Assignee: Tonen CorporationInventors: Tatsuo Teraya, Shintaro Kikuchi, Kouichi Yokoyama, Yuji Fujita
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Patent number: 5432237Abstract: Disclosed is a radical polymerizable composition comprised of a polymer having a .pi.-electron conjugated structure having repeating units of a mono-substituted or di-substituted isothianaphthene structure, which is represented by the formula [Ia] and/or [Ib]: ##STR1## wherein R.sup.1 and R.sup.2 represent hydrogen, C1-C18 alkoxy group, or --O(CH.sub.2 CH.sub.2 O).sub.n CH.sub.3 [n: 1 to 4] with the proviso that the case where both R.sup.1 and R.sup.2 represent hydrogen is excluded, X is an anion, y is from 0.01 to 1, and m is from 5 to 5,000,and a radical polymerizable compound. The radical polymerizable composition has a very stable electroconductivity in air and can be molded into an optional shape.Type: GrantFiled: January 24, 1994Date of Patent: July 11, 1995Assignee: Showa Denko K.K.Inventors: Reiko Otsuka, Yoshiaki Ikenoue, Yoshihiro Saida, Masao Kobayashi
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Patent number: 5430073Abstract: The invention relates to a process for preparing a polymer in which in situ polymerization of monomers takes place in the presence of a catalyst, in which the monomers are obtained by in situ activation of precursor monomers.According to the invention a premature polymerization is avoided, but polymerization only starts at the desired moment.Type: GrantFiled: July 15, 1993Date of Patent: July 4, 1995Assignee: DSM, N.V.Inventors: Hans K. Van Dijk, Ronald M. A. M. Schellekens, Markus J. H. Bulters, Olav M. Aagaard, Gerard P. De Vries, Matthias J. G. Brouns
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Patent number: 5426133Abstract: 1. A water-absorptive contact lens obtained by saponification of a copolymer composed essentially of:(A) from 1 to 30% by weight of a (meth)acrylate polymer having at least one polymerizable group per molecule on an average obtained by copolymerizing (a) an alkyl (meth)acrylate and (b) a monomer having at least two polymerizable groups per molecule, as the main components;(B) from 1 to 10% by weight of a vinyl monomer selected from the group consisting of maleic acid esters and N-vinyl lactams;(C) from 50 to 98% by weight of a fatty acid vinyl ester; and(D) from 0.02 to 10% by weight of a cross linking monomer.Type: GrantFiled: September 10, 1993Date of Patent: June 20, 1995Assignee: Menicon Co., Ltd.Inventors: Yasuhito Hishida, Masanori Kadoya, Keiji Sugimoto, Tsuyoshi Watanabe, Noriko Iwata
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Patent number: 5426009Abstract: The invention relates to a polymeric composite material which:is based on a liquid crystal polymer component,exhibits a high glass transition temperature of at least 60.degree. C. and a scattering texture when deposited as a thin film,can be rendered transparent by being heated above the glass transition temperature and/or clearing temperature, andis obtained by mixing a liquid crystal polymer component, a reactive liquid crystalline component, optionally a polymerization initiator component, and/or further additive components, with subsequent polymerization.Type: GrantFiled: September 17, 1993Date of Patent: June 20, 1995Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: David Coates, Mark Verrall, Emma J. Brown
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Patent number: 5424366Abstract: Multi-functional viscosity index improvers for lubricating oils containing an EPM or EPDM polymer onto which has been grafted an unsaturated functional monomer containing phenothiazine.Type: GrantFiled: June 1, 1994Date of Patent: June 13, 1995Assignee: Texaco Inc.Inventors: Maria M. Kapuscinski, Theodore E. Nalesnik, Robert T. Biggs, Benjamin J. Kaufman
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Patent number: 5408009Abstract: A high polymer which is a precursor capable of forming a hydrogen bond at a temperature of 40.degree. C. or more and a high polymer capable of forming a hydrogen bond, and a nonlinear optical material comprising a thin polymer film containing the high polymer and a method for forming the nonlinear optical material are disclosed. The thin polymer film containing the high polymer may be oriented in the electric field at a low temperature to give a nonlinear optical material.Type: GrantFiled: November 2, 1993Date of Patent: April 18, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Masaki Okazaki
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Patent number: 5408005Abstract: A process for preparing a rubber modified thermoplastic resin, in which a latex in aqueous emulsion is prepared in the presence of an ionic surfactant; a vinyl monomer insoluble or substantially insoluble in water is added, and the particles of the latex are transferred to the monomer to form an organic phase using a transfer agent of opposite charge to the surfactant; and a polymerization of the organic phase is performed.Type: GrantFiled: June 21, 1993Date of Patent: April 18, 1995Assignee: NorsolorInventors: Philippe Heim, Gerard Riess
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Patent number: 5408002Abstract: An azlactone-functional thermoplastic composition is disclosed. The composition is a blend of an azlactone-functional composition and a thermoplastic polymer. A method of making azlactone-functional homopolymers by bulk homopolymerization is disclosed, optionally also concurrent or sequential blending of a thermoplastic polymer. A method of blending azlactone-functional compositions and thermoplastic polymers is disclosed. Molded articles and adduct molded articles formed from the thermoplastic composition are disclosed.Type: GrantFiled: September 9, 1993Date of Patent: April 18, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Patrick L. Coleman, Steven M. Heilmann, Steven L. Kangas, Robert H. Menzies, Jerald K. Rasmussen, Richard J. Rolando, Jennifer J. Sahlin, Julie B. Stahl
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Patent number: 5401805Abstract: Graft copolymers are disclosed which comprise an olefin borane-containing homopolymer or copolymer backbone polymer having radically polymerized polymeric segments chemically bonded as side chains or as a chain end. A borane-containing diene homopolymer or a copolymer of a diene and/or at least one alpha-olefin having from about 2 to 22 carbon atoms copolymerized with another monomer containing organoborane functional groups can be used as a backbone polymer to prepare the graft copolymers of the present invention. Under oxidation conditions, the borane group becomes the reaction site for the radical polymerization and copolymerization. Radical polymerizable monomers, such as methyl methacrylate, styrene, alpha-methylstyrene, acrylonitrile and the like, can be polymerized to yield high molecular weight graft copolymer. By this synthetic route, high graft efficiency is observed with only a very low concentration of homopolymer being produced.Type: GrantFiled: November 3, 1993Date of Patent: March 28, 1995Assignee: The Penn State Research FoundationInventors: T. C. Chung, G. J. Jiang, D. Rhubright
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Patent number: 5397842Abstract: A blend of a polyolefin, such as polypropylene, with a segmented copolymer containing both polyolefin segments and segments derived from greater than 20 to about 100% of a vinyl aromatic monomer is useful in applications where high melt strength is desired.Type: GrantFiled: November 25, 1992Date of Patent: March 14, 1995Assignee: Rohm and Haas CompanyInventors: Raymond G. Hamilton, Mark T. McCarty
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Patent number: 5385956Abstract: The method concerns preparing a polymer composition containing an electrically conductive polymer which is formed, in the presence of a catalyst, from polymerizable monomer units that are converted from non-polymerizable precursor monomers with the aid of a sufficiently energy-intense light source. In this method according to the invention is that the precursor monomers have a structure according to formula (I). The method according to the invention makes it possible to very easily and rapidly, and thus economically, prepare a polymer composition containing an electrically conductive polymer. Furthermore, the method according to the invention permits a polymer composition to be produced that contains an electrically conductive polymer in specifically pre-selected areas.Type: GrantFiled: July 15, 1993Date of Patent: January 31, 1995Assignee: DSM N.V.Inventors: Ronald M. A. M. Schellekens, Hans K. Van Dijk
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Patent number: 5382633Abstract: A modified polymer is described comprising a thermoplastic polymer composition comprising a graft copolymer between (1) a preformed thermoplastic polymer and (2) a monomer composition comprising (a) at least one polymerisable monomer containing a polymerisable group and at least one functional polymer-modifying group and (b) at least one comonomer containing at least two polymerisable groups, said copolymer being substantially free of unbound monomer. Such polymers can be produced by reacting together, in a melt and in the presence of free radicals whilst applying shear to the melt, the preformed thermoplastic polymer to be modified, the polymerisable monomer, and the comonomer, thereby to graft said monomer to said preformed polymer leaving substantially no unbound monomer, the reaction being continued for a period of time sufficient to produce a graft copolymer that is thermoplastic and can be blended with an unmodified polymer. A free radical generator can be added, if desired.Type: GrantFiled: April 8, 1991Date of Patent: January 17, 1995Assignee: 3i Research Exploitation LimitedInventors: Gerald Scott, Sahar Al-Malaika
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Patent number: 5378402Abstract: Electrically conductive polymers, especially polypyrroles, are formed with a charged polymeric dopant supplying the necessary counter-ions to stabilise the charged conductive form of the conductive polymer. The physical properties of the conductive polymer can thus be usefully modified in ways different from those achieved by non-polymeric dopants or by forming the conductive polymers in pre-existing bodies of non dopant (i.e. uncharged) polymers.Type: GrantFiled: July 21, 1983Date of Patent: January 3, 1995Assignee: Raychem LimitedInventors: Malcolm G. Cross, Robert Lines
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Patent number: 5374364Abstract: Multifunctional viscosity index improvers for lubricating oils containing an EPM or EPDM polymer with pendant thiazoline units.Type: GrantFiled: September 3, 1993Date of Patent: December 20, 1994Assignee: Texaco Inc.Inventors: Maria M. Kapuscinski, Nicholas Benfaremo, Robert T. Biggs
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Patent number: 5373060Abstract: A particulate graft polymer A ofA1: a grafting base based on a polydiene rubber A1 of, based on A1,A11: 70 to 100% by weight of a polymerizable diene, andA12: up to 30% by weight of a copolymerizable, ethylenically unsaturated monomer having a first graft sheath A2 of, based on A2,A21: 75 to 99.8% of at least one C.sub.1 -C.sub.8 alkyl acrylate A21,A22: 0.1 to 5% by weight of at least one polyfunctional, crosslinking monomer A22,A23: 0.1 to 20% by weight of at least one monomer A23 containing one or more acidic or basic groups, and a second graft sheath A3 comprising, based on A3,A31: 40 to 89.9% by weight of at least one aromatic vinyl monomer A31,A32: 10 to 49.9% by weight of at least one polar, ethylenically unsaturated monomer A32,A33: 0.1 to 20% by weight of at least one monomer A33 containing one or more basic or acidic groups, andA34: up to 5% by weight of at least one polyfunctional, crosslinking monomer A34,A23 and A33 in each case being different groups.Type: GrantFiled: July 6, 1993Date of Patent: December 13, 1994Assignee: BASF AktiengesellschaftInventors: Norbert Guentherberg, Wolfgang Fischer, Norbert Niessner
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Patent number: 5367029Abstract: Particulate graft copolymers for matt thermoplastic molding materials contain a base and a graft sheath. The base contains 75 to 99.8% of at least one alkyl acrylate, from 0.1 to 5% of at least one polyfunctional, crosslinking monomer having at least two ethylenic double bonds which are not conjugated in the 1,3-position, and from 0.1 to 20% of at least one ethylenically unsaturated monomer having one or more acidic groups. Alternatively, the base may contain at least 50% of one or more dienes, up to 50% of at least one further ethylenically unsaturated monomer, and up to 15% of at least one ethylenically unsaturated monomer having one or more acidic groups. The sheath contains from 0 to 99.8% of at least one aromatic vinyl monomer, from 0 to 99.8% of at least one polar, copolymerizable, ethylenically unsaturated monomer, from 0.1 to 20% of at least one ethylenically unsaturated monomer having one or more basic groups, and from 0.1 to 10% of at least one hydroxyalkyl (meth)acrylate.Type: GrantFiled: October 18, 1993Date of Patent: November 22, 1994Assignee: BASF AktiengesellschaftInventors: Wolfgang Fischer, Norbert Guentherberg, Norbert Niessner
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Patent number: 5364891Abstract: Process for making a polymer with desired groups Y comprising reacting a precursor polymer having carbon- or nitrogen-bound --NH.sub.2 and/or --NH-- groups with at least one compound having a single enolic carbonyl group and at least one group Y. Also the polymer itself and a composition containing it.Type: GrantFiled: February 14, 1991Date of Patent: November 15, 1994Assignees: Imperial Chemical Industries PLC, ICI Resins BVInventors: David A. Pears, John G. Carey, Paul H. Stenson, Gerardus C. Overbeek
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Patent number: 5362812Abstract: Reactive polymeric dyes are provided comprising a chromophoric moiety derived from at least one free radically polymerizable dye and an azlactone moiety derived from 2-alkenylazlactone such that the free radically polymerizable dye is incorporated into the backbone of the polymer. Alternatively, 2-alkenylazlactone is polymerized and then derivatized with a nucleophilic dye or dyes, such that the chromophoric portion of the dye is pendent to the polymer backbone. Both types of reactive polymeric dyes may also contain additional polymerized monomeric units. The reactive polymeric dyes of the present invention can be used in a photoresist system and in particular in a color proofing construction.Type: GrantFiled: April 23, 1993Date of Patent: November 8, 1994Assignee: Minnesota Mining and Manufacturing CompanyInventors: Gary L. Holmes, Terrance P. Smith, Mahfuza B. Ali, David W. Macomber
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Patent number: 5359008Abstract: The present invention provides a second-order nonlinear optical polymer including a polymer backbone and side groups bonded to the polymer backbone, wherein the side groups include one or more of a first nonlinear optical group represented by the following formula (C-1) and one or more of a second nonlinear optical group represented by the following formula (C-2) or (C-2)': ##STR1## wherein .pi..sub.1 to .pi..sub.n, .pi.'.sub.1, .pi.'.sub.2, and .pi.".sub.1 each represent independently a .pi.-conjugated cyclic compound group; X.sub.1 to X.sub.n-1, X'.sub.1, Y.sub.1 to Y.sub.n-1, and Y'.sub.1 each represent independently CH, N, or N.fwdarw.O; A.sub.1, A.sub.2, and A.sub.3 each represent independently an electron attracting group; D.sub.1, D.sub.2, and D.sub.3 each represent independently an electron donating group; and n represents an integer of 3 or greater.Type: GrantFiled: May 17, 1993Date of Patent: October 25, 1994Assignee: Nippon Telegraph and Telephone CorporationInventors: Michiyuki Amano, Makoto Hikita, Satoru Tomaru, Toshikuni Kaino, Yoshito Shuto
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Patent number: 5357000Abstract: The present invention provides graft copolymers that are highly absorbent to aqueous electrolyte solutions.Type: GrantFiled: April 26, 1993Date of Patent: October 18, 1994Assignee: Phillips Petroleum CompanyInventors: Iqbal Ahmed, Henry L. Hsieh
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Patent number: 5346964Abstract: A hydrogenated diene block copolymer having a polystyrene-reduced number-average molecular weight of 50,000-600,000 which is a hydrogenation product of an (A)-(B) block copolymer in which (A) means an alkenyl aromatic compound polymer block and (B) means a conjugated diene homopolymer block wherein the vinyl content of the conjugated diene portion is more than 60%, or an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15% or more, an (A)-(B)-(C) block copolymer in which (A) and (B) are as defined above and (C) means an alkenyl aromatic compound-conjugated diene copolymer tapered block wherein the proportion of the alkenyl aromatic compound increases gradually, or an (A)-(B)-(A) block copolymer in which (A) and (B) are as defined above. Said hydrogenated diene block copolymer is useful as a modifier for polar resins, non-polar resins or both of them.Type: GrantFiled: June 23, 1993Date of Patent: September 13, 1994Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Tooru Shibata, Toshio Teramoto, Yoshiharu Hashiguchi, Kunio Goshima
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Patent number: 5334485Abstract: Photosensitive, photocurable, compositions contain a polymeric backbone which are basic in an aqueous environment having a pendant photosensitive group. The pendant groups are styryl-amine or nitrogen heterocyclic groups which contain an ethylenically unsaturated photocross-linking group. The pendant styryl-amine or nitrogen heterocyclic groups can cross-link two polymer chains by photo addition through ethylenically unsaturated groups in the styryl moiety forming a cyclobutane crosslinked site. The cross-linking is accomplished by irradiating the material with visible light or ultraviolet radiation of appropriate wave length, depending on the absorbitivity of the system. The photocurable polymer can be formulated into useful systems including in liquid resists, pre-coated film resists, etc. and can be used in both negative or positive imaging systems.Type: GrantFiled: November 5, 1991Date of Patent: August 2, 1994Assignee: The Chromaline CorporationInventors: Lawrence C. Van Iseghem, Alexander S. Gybin
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Patent number: 5331056Abstract: Polymer compositions, typically thermoplastic polymer compositions, readily converted into electroconductive polymers and articles shaped therefrom, e.g., films, comprise at least one convertible polymer support substrate (A) and at least one amphiphilic heterocyclic monomer (B) having the formula (I): ##STR1## in which R.sub.1 and R.sub.2, which may be identical or different, are each a linear or branched alkyl, aryl, alkylaryl, arylalkyl, hydroxycarbonyl, alkoxycarbonyl or amide radical; X is an oxygen or sulfur atom or the divalent radical ##STR2## wherein R.sub.3 is a hydrogen atom or an alkyl, aryl, alkylaryl or arylalkyl radical; at least one of the substituents R.sub.1, R.sub.2 and R.sub.3 having an amphiphilicity-imparting number of carbon atoms.Type: GrantFiled: December 18, 1992Date of Patent: July 19, 1994Assignee: Rhone-Poulenc FilmsInventors: Nicole Pecate, Joel Richard
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Patent number: 5314977Abstract: This invention relates to a two stage aqueous emulsion polymerization process for making graft copolymers. In the first stage, at least one first ethylenically unsaturated monomer is polymerized in the presence of at least one mercapto-olefin compound to form a macromonomer with terminal functional groups. In the second stage, at least one second ethylenically unsaturated monomer is polymerized in the presence of the macromonomer such that a copolymer is formed with a backbone of polymerized units of the at least one second ethylenically unsaturated monomer and side chains of the macromonomer.Type: GrantFiled: June 3, 1993Date of Patent: May 24, 1994Assignee: Rohm and Haas CompanyInventors: David R. Amick, William D. Emmons, Dennis P. Lorah
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Patent number: 5310812Abstract: A toner for developing electrostatic latent images with a good combination of fixability, anti-offset characteristic, anti-sticking characteristic and pulverizability contains a composition comprising a colorant or magnetic material and a binder resin. The binder resin has 0.1 to 60 wt. % of a chloroform-insoluble or a THF (tetrahydrofuran)-insoluble component and a THF-soluble component, the THF-soluble providing a molecular weight distribution in the chromatogram of GPC (gel permeation chromatography) thereof such that there is a main peak in the molecular weight range of 1,000 to 25,000 and a sub-peak or shoulder in the molecular weight range of 2,000 to 150,000. The binder resin may suitably be obtained through two polymerization steps including a solution polymerization step and a suspension polymerization step.Type: GrantFiled: December 7, 1992Date of Patent: May 10, 1994Assignee: Canon Kabushiki KaishaInventors: Satoshi Yasuda, Kiichiro Sakashita, Yasuo Mitsuhashi, Seiichi Takagi, Shuichi Aita, Yoshinobu Nagai, Toshiaki Nakahara
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Patent number: 5308749Abstract: Biologically active reagents are prepared from particles of copolymers having highly active succinimid groups. The reagents are prepared by covalently attaching biologically active substances, for example antibodies, to the particles, directly or indirectly through amide groups by displacement of highly active succinimid groups on the particle surface. These reagents are used to advantage in analytical elements, methods for the detection of specific binding ligands (such as immunological species) and immunoassays, and in purification methods such as affinity chromatography.Type: GrantFiled: January 25, 1991Date of Patent: May 3, 1994Assignee: Eastman Kodak CompanyInventors: Richard C. Sutton, Ignazio S. Ponticello, Susan J. Danielson, Marsha D. B. Oenick
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Patent number: 5306779Abstract: A hydrogenated diene block copolymer having a polystyrene-reduced number-average molecular weight of 50,000-600,000 which is a hydrogenation product of an (A)-(B) block copolymer in which (A) means an alkenyl aromatic compound polymer block and (B) means a conjugated diene homopolymer block wherein the vinyl content of the conjugated diene portion is more than 60%, or an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15% or more, an (A)-(B)-(C) block copolymer in which (A) and (B) are as defined above and (C) means an alkenyl aromatic compound-conjugated diene copolymer tapered block wherein the proportion of the alkenyl aromatic compound increases gradually, or an (A)-(B)-(A) block copolymer in which (A) and (B) are as defined above and in which hydrogenation product at least 80% of the double bonds of the conjugated diene portion is saturated by the hydrogenation.Type: GrantFiled: September 1, 1992Date of Patent: April 26, 1994Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Tooru Shibata, Toshio Teramoto, Yoshiharu Hashiguchi, Kunio Goshima
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Patent number: 5298565Abstract: A graft polymer is prepared by grafting, onto a polymeric substantially saturated hydrocarbon backbone, a free-radical polymerizable vinyl nitrogen monomer, which grafting takes place with improved efficiency in the presence of minor amounts of a volatile aliphatic hydrocarbon substituted aromatic solvent capable of free-radical hydrogen atom chain transfer. The modified hydrocarbon based polymer finds utility as an additive for lubricating oils, particularly as dispersant-viscosity improvers for engine oils.Type: GrantFiled: June 1, 1993Date of Patent: March 29, 1994Assignee: The Lubrizol CorporationInventors: Richard M. Lange, Carmen V. Luciani
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Patent number: 5298560Abstract: A partially crosslinked thermoplastic resin composition is prepared by dynamically heat-treating a thermoplastic resin (A) in the presence of a carbon radical inducing agent (B) comprising a charge transfer complex or a combination of a hydrogen donating compound and a hydrogen accepting compound.Type: GrantFiled: May 14, 1991Date of Patent: March 29, 1994Assignee: Nippon Petrochemicals Company, LimitedInventors: Fuyuki Aida, Masaaki Miyazaki, Mamoru Nagai
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Patent number: 5288777Abstract: ABS copolymers and similar styrene or .alpha.-methylstyrene copolymers which contain an elastomer phase are stabilized against light-induced degradation by a) incorporation of a copolymerizable sterically hindered amine in, and b) addition of a non-copolymerizable sterically hindered amine to, the copolymer. Preferred sterically hindered amines are polyalkylpiperidines.Type: GrantFiled: November 9, 1992Date of Patent: February 22, 1994Assignee: Ciba-Geigy CorporationInventors: Bernard Gilg, Gerhard Rytz, Werner Stauffer, Margot Clauss
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Patent number: 5288807Abstract: This invention relates to vinyl monomer compositions having accelerated surface cure characteristics. These compositions are prepared from a vinyl monomer or monomer mixtures such as blend of isobornyl methacrylate and hydroxypropyl methacrylate, a bulk phase polymerization catalyst system, a polyvalent metal oxidative surface phase catalyst, and a diolefin rubber dispersed in the vinyl monomer as a surface cure accelerator. These compositions are useful as sealers, healers and for polymer concrete.Type: GrantFiled: July 2, 1991Date of Patent: February 22, 1994Assignee: Rohm and Haas CompanyInventor: Frederick P. Hinz
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Patent number: 5288808Abstract: Polymers containing repeating units of: ##STR1## and optionally random distribution of other units derived from at least one vinyl monomer, R.sub.1 is H; alkyl, cycloalkyl or aryl each of which is unsubstituted or substituted by at least one halogen; ##STR2## (R.sub.7 is H, alkyl, cycloalkyl or aryl); A is a single bond; alkylene, cycloalkylene or arylene; or ##STR3## (B is alkylene, cycloalkylene or arylene); R.sub.2, R.sub.3 and R.sub.4 are alkyl, cycloalkyl or aryl; it being possible for at least one of R.sub.3 and R.sub.4 to contain at least one hydroxyl or carboxylic acid groups or to represent a polyoxyethylene or polyester sequence.These polymers are useful for the preparation of graft copolymers containing the units of the formula: ##STR4## where Po is a vinyl or a diene polymer sequence, and other vinyl units. These graft copolymers are useful especially as compatibility agents.Type: GrantFiled: November 20, 1992Date of Patent: February 22, 1994Assignee: ATOCHEMInventor: Gilbert Clouet
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Patent number: 5286800Abstract: Polyolefin graft copolymers are disclosed which comprise a polyolefin homopolymer or copolymer backbone polymer having a plurality of free radically polymerized polymeric segments chemically bonded as side chains. It has been found that the use of a borane-containing polyolefin comprising a copolymer of at least one alpha-olefin having from about 2 to 22 carbon atoms copolymerized with another monomer containing organoborane functional groups can be used as a backbone polymer to prepare the graft copolymers of the present invention. Under oxidation conditions, the borane group becomes the reaction site for the free radical polymerization and copolymerization. Numerous free radical polymerizable monomers, such as methyl methacrylate, styrene, alpha-methylstyrene, acrylonitrile and the like, can be polymerized to yield high molecular weight graft copolymers. By this synthetic route, high graft efficiency is observed with only a very low concentration of homopolymer being produced.Type: GrantFiled: April 6, 1992Date of Patent: February 15, 1994Assignee: The Pennsylvania Research CorporationInventors: T. C. Chung, G. J. Jiang, D. Rhubright
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Patent number: 5262486Abstract: Modified polymers in acid form or in the form of their salts consist ofA) a carboxyl-containing copolymer prepared by emulsion polymerization andB) side radicals introduced therein by partial grafting onto the carboxyl groups and of the general formula I ##STR1## where R.sup.1 and R.sup.2 are each hydrogen or C.sub.1 -C.sub.5 -alkyl, X is oxygen, sulfur or imino, Y is an ester, amide, ether or C.sub.1 -C.sub.10 -alkylene group and 1<n.ltoreq.100 for the average number n of the monomer units undergoing addition per reacted acid function.Type: GrantFiled: July 16, 1991Date of Patent: November 16, 1993Assignee: BASF AktiengesellschaftInventors: Thomas Telser, Martin Meister, Horst Koch
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Patent number: 5262484Abstract: Graft copolymers and processes for the preparation thereof are provided. The copolymers comprise a base polymer having grafted thereto a monomeric 2-alkenyl azlactone. The surface properties of the graft copolymers can be modified by binding thereto nucleophilic reagents comprising further functional groups with desired properties. Further, the amount of azlactone available at the surface of a graft copolymer for binding to such nucleophilic reagents can be controlled by selecting a surface against which the graft copolymer is formed. The graft copolymers exhibit desirable thermoplastic, melt flow, and adhesion properties and are particularly useful for immobilizing proteins. Methods of immunoassay based on the immobilization of proteins are also disclosed. Another utility of the graft copolymers involves the compatibilizing of immiscible polymer blends.Type: GrantFiled: September 9, 1992Date of Patent: November 16, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Patrick L. Coleman, Thomas A. Kotnour, Richard J. Rolando
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Patent number: 5247040Abstract: This invention relates to a two stage aqueous emulsion polymerization process for making graft copolymers. In the first stage, at least one first ethylenically unsaturated monomer is polymerized in the presence of at least one mercapto-olefin compound to form a macromonomer with terminal functional groups. In the second stage, at least one second ethylenically unsaturated monomer is polymerized in the presence of the macromonomer such that a copolymer is formed with a backbone of polymerized units of the at least one second ethylenically unsaturated monomer and side chains of the macromonomer.Type: GrantFiled: June 27, 1991Date of Patent: September 21, 1993Assignee: Rohm and Haas CompanyInventors: David R. Amick, William D. Emmons, Dennis P. Lorah
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Patent number: 5239013Abstract: Organic groups covalently bound to a polymer backbone provide second or third order nonlinear susceptibilities to the polymer. In another aspect, a method is disclosed for providing the novel polymers of the invention. Polymers of the invention can be directionally oriented to provide useful optically nonlinear media for use in nonlinear optical devices such as optical switches or light modulation devices.Type: GrantFiled: September 29, 1992Date of Patent: August 24, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Cecil V. Francis, Steven M. Heilmann, Larry R. Krepski, Jerald K. Rasmussen
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Patent number: 5231140Abstract: The invention relates to a process for the preparation of (meth)acrylate polymers with side-chain, non-linear optical chromophores and molecular weights of from 5000 to 5000000, which comprises reacting polymers of (meth)acryloyl chloride in solution with D-.omega.-hydroxyalkyl chromophores of the formula (I) or the alcoholates thereof ##STR1## where D is an electron donor,A is an electron acceptor,X is CH and/or N, and m is from 2 to 11.The polymers can be used in optical components.Type: GrantFiled: May 22, 1992Date of Patent: July 27, 1993Assignee: BASF AktiengesellschaftInventors: Heike Kilburg, Karl-Heinz Etzbach, Karin H. Beck, Peter Strohriegl, Harry Mueller, Oskar Nuyken
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Patent number: 5219947Abstract: A toner for developing electrostatic latent images with a good combination of fixability, anti-offset characteristic, anti-sticking characteristic and pulverizability is provided as a composition comprising a colorant or magnetic material and a binder resin. The binder resin has 0.1 to 60 wt. % of a chloroform-insoluble or a THF (tetrahydrofuran)insoluble and a THF-soluble, the THF-soluble providing a molecular weight distribution in the chromatogram of GPC (gel permeation chromatography) thereof such that there are a main peak in the molecular weight range of 1,000 to 25,000 and a sub-peak or shoulder in the molecular weight range of 2,000 to 150,000. The binder resin may suitably be obtained through two polymerization steps including a solution polymerization step and a suspension polymerization step.Type: GrantFiled: April 23, 1990Date of Patent: June 15, 1993Assignee: Canon Kabushiki KaishaInventors: Satoshi Yasuda, Kiichiro Sakashita, Yasuo Mitsuhashi, Seiichi Takagi, Shuichi Aita, Yoshinobu Nagai, Toshiaki Nakahara
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Patent number: 5218026Abstract: A fluorine-containing elastomer composition comprising a specific fluorine-containing elastomer having iodine bonded thereto and having a multimodel molecular weight distribution, a specific vulcanizing agent, an organic peroxide, and a polyfunctional unsaturated compound. The fluorine-containing elastomer composition has not only excellent processability, mold release properties and burr-removal performance in molding but also capability of providing a vulcanization product which is not only improved with respect to mechanical properties, but also has extremely excellent resistance to chemicals and solvents, particularly methanol, and good metal-adhesion properties.Type: GrantFiled: December 20, 1990Date of Patent: June 8, 1993Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Keiichi Toda, Kenichi Hayashi, Hiroshi Saito
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Patent number: 5216084Abstract: Organic groups covalently bound to a polymer backbone provide second or third order nonlinear susceptibilities to the polymer. In another aspect, a method is disclosed for providing the novel polymers of the invention. Polymers of the invention can be directionally oriented to provide useful optically nonlinear media for use in nonlinear optical devices such as optical switches or light modulation devices.Type: GrantFiled: May 11, 1990Date of Patent: June 1, 1993Assignee: Minnesota Mining and Manufacturing CompanyInventors: Cecil V. Francis, Steven M. Heilmann, Larry R. Krepski, Jerald K. Rasmussen
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Patent number: 5212251Abstract: Alkali-resistant core-shell polymers having an acid-insoluble core and an acid-soluble shell are prepared by sequential emulsion polymerization of a monomer mixture having acid-ionizable functionality such that the resulting polymer has an acid-insoluble core and an acid-soluble shell. Films from these alkali-resistant, core-shell polymers are resistant to high pH environments where alkali-resistance is required. The alkali-resistant, core-shell polymers are useful in applications such as inks, clear overprint varnishes, coatings, metal adhesion, fiber treatment, paper treatment, cathodic deposition coatings, stain blocking, coagulants and flocculants.Type: GrantFiled: September 24, 1990Date of Patent: May 18, 1993Assignee: Rohm and Haas CompanyInventors: Dennis P. Lorah, Mark S. Frazza
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Patent number: 5206297Abstract: Moulding composition in the form of particles of a) at least one polyheteroaromatic compound or an aniline in the oxidised, polycationic form, especially polypyrrole, and b) at least one polyanion of a thermoplastic polymer having sulfated alcohol groups ##STR1## in recurring structural units. Mouldings obtained from the moulding compositions have a high electrical conductivity and good mechanical strength properties. The mouldings can be used as electrodes, electrically conductive fibers or components for electromagnetic screening. The pulverulent moulding compounds are also suitable as electrically conductive fillers for plastics.Type: GrantFiled: March 6, 1991Date of Patent: April 27, 1993Assignee: Ciba-Geiby CorporationInventors: Wolfgang Wernet, Friedrich Lohse, Jurgen Finter, Hartmut Bleier, Bruno Rotzinger, Thomas Vogel
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Patent number: 5194465Abstract: ABS copolymers and similar styrene or .alpha.-methylstyrene copolymers with contain an elastomer phase are stabilized against light-induced degradation by a) incorporation of a copolymerizable sterically hindered amine in, and b) addition of a non-copolymerizable sterically hindered amine to, the copolymer. Preferred sterically hindered amines are polyalkylpiperidines.Type: GrantFiled: September 30, 1991Date of Patent: March 16, 1993Assignee: Ciba-Geigy CorporationInventors: Bernard Gilg, Gerhard Rytz, Werner Stauffer, Margot Clauss
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Patent number: 5191024Abstract: A hydrogenated diene block copolymer having a polystyrene-reduced number-average molecular weight of 50,000-600,000 which is a hydrogenation product of an (A)--(B) block copolymer in which (A) means an alkenyl aromatic compound polymer block and (B) means a conjugated diene homopolymer block wherein the vinyl content of the conjugated diene portion is more than 60%, or an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15% or more, an (A)--(B)--(C) block copolymer in which (A) and (B) are as defined above and (C) means an alkenyl aromatic compound-conjugated diene copolymer tapered block wherein the proportion of the alkenyl aromatic compound increases gradually, or an (A)--(B)--(A) block copolymer in which (A) and (B) are as defined above, in which block copolymer(1) the weight proportion of theh alkenyl aromatic compound/the conjugated diene is 5/95 to 60/40, and(2) the content of the bound alkenyl aromatic compound in at least oType: GrantFiled: May 18, 1990Date of Patent: March 2, 1993Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Tooru Shibata, Toshio Teramoto, Yoshiharu Hashiguchi, Kunio Goshima
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Patent number: RE34740Abstract: The present invention relates to absorption resins comprising vinyl copolymers which do not dissolve in water and are capable of absorbing microorganisms without inactivating the microorganisms and also adsorbents with a large contact area which are capable of absorbing microorganisms efficiently as well as methods of making the resins and the adsorbents.Type: GrantFiled: December 6, 1993Date of Patent: September 27, 1994Assignee: Japane Vilkene Company, Ltd.Inventors: Nariyoshi Kawabata, Akinori Minami, Tadahira Yo