Ethylenic Reactant Contains A Chalcogen Heterocycle Patents (Class 525/284)
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Patent number: 9790307Abstract: A process for producing a silane-crosslinked polyolefin which comprises exposing a polyolefin containing at least one [1,3,2]-dioxasilinane ring structure to moisture in the presence of an organic carboxylic acid, which is used as a hydrolysis and condensation catalyst and does not contain tin, thereby producing the silane-crosslinked polyolefin, wherein the polyolefin containing at least one [1,3,2]-dioxasilinane ring structure is made by the process of grafting an olefinically unsaturated [1,3,2]-dioxasilinane to a polyolefin in the presence of a free radical initiator. There is also provided the resulting silane-crosslinked polyolefin and the graftable silane composition used in the process.Type: GrantFiled: December 12, 2014Date of Patent: October 17, 2017Assignee: Momentive Performance Materials Inc.Inventors: Samim Alam, Roy U. Rojas Wahl
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Patent number: 9018311Abstract: An object of the present invention is to provide a novel copolymer useful as a pigment dispersing agent in the field of color liquid crystal displays and the like.Type: GrantFiled: November 2, 2011Date of Patent: April 28, 2015Assignee: Nippon Soda Co., Ltd.Inventors: Takeshi Niitani, Toshiaki Okado, Hidenori Naruse, Tooru Kajita
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Patent number: 8980392Abstract: The use of a functionalized organosilicon compound as a coupling agent between an inorganic filler and an elastomer in an elastomer composition including an isoprene elastomer and a reinforcing inorganic filler is disclosed. The compound is selected among functionalized organosilicon compounds including at least one double bond C?C or C?N, and not including any C?C—C?O bonds or N?N bonds, and reacting with the isoprene units according to an electrocyclic reaction, in particular according to a standard cycloaddition reaction [2+1], [2+2], [3+2] or a Diels-Alder reaction [4+2] or an ene-synthesis reaction other than an ene-synthesis reaction between an isoprene unit and a C?C—C?O or N?N function. Also described, are elastomer composition(s) obtained and items manufactured using such compositions.Type: GrantFiled: June 2, 2010Date of Patent: March 17, 2015Assignee: Rhodia OperationsInventors: Laurent Guy, Virginie Pevere, Thierry Vidal
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Publication number: 20150018486Abstract: The present invention comprises compositions and methods for delivery systems of agents, including therapeutic compounds, pharmaceutical agents, drugs, detection agents, nucleic acid sequences and biological factors. In general, the nanotherapeutic compositions of the present invention comprise a platform comprising a colloidal metal, a targeting ligand such a tumor necrosis factor, a stealth agent such as polyethylene glycol, and one or more diagnostic or therapeutic agents for delivery. The invention also comprises methods and compositions for making such nanotherapeutic compositions and for the treatment of cancer.Type: ApplicationFiled: February 14, 2014Publication date: January 15, 2015Applicant: Cytlmmune Sciences, Inc.Inventors: Lawrence Tamarkin, Giulio F. Paciotti, Marja S. Huhta
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Patent number: 8835533Abstract: The present invention relates to anaerobically curable compositions demonstrating resistance to elevated temperature conditions.Type: GrantFiled: October 14, 2009Date of Patent: September 16, 2014Assignee: Henkel US IP LLCInventors: Qinyan Zhu, Shabbir Attarwala
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Publication number: 20140256884Abstract: A novel copolymer having excellent pigment dispersion performance, and more particularly, a novel copolymer usable as a pigment dispersing agent that can attain high luminance and high contrast of a green picture element in a color filter. The novel copolymer contains: a block chain (A) including a repeating unit having a tertiary amino group; and a block chain (B) including a repeating unit represented by the following formula (I) (wherein R1 represents a hydrogen atom or a C1-C3 alkyl group, R2 and R3 each independently represent a hydrogen atom or a C1-C6 alkyl group, Q represents an oxygen-containing saturated hetero ring group optionally having an alkyl group as a substituent or a C2-C20 alkenyl group, and n represents an integer of 0 to 6), and has an amine value of 80 mgKOH/g or more and 250 mgKOH/g or less.Type: ApplicationFiled: October 15, 2012Publication date: September 11, 2014Applicant: NIPPON SODA CO., LTD.Inventors: Takeshi Niitani, Toshiaki Okado, Izumi Tando, Hidenori Naruse, Tooru Kajita
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Publication number: 20140206821Abstract: A ?-conjugated aromatic/heteroaromatic oligomer-containing vinyl monomer is generally provided, which can include a polymerizable group, a linker group, and a ?-conjugated aromatic/heteroaromatic side chain. The ?-conjugated aromatic/heteroaromatic side chain includes a first cyclopentadiene ring covalently attached to the linder group, a set of second cyclopentadiene rings covalently attached to the first cyclopentadiene ring, and a third cyclopentadiene ring positioned at a terminal end of the ?-conjugated aromatic/heteroaromatic side chain such that the set of second cyclopentadiene rings is positioned between the first cyclopentadiene ring and the third cyclopentadiene ring. Methods are also provided for forming a polymer via polymerizing the ?-conjugated aromatic/heteroaromatic oligomer-containing vinyl monomer, and for grafting a ?-conjugated aromatic/heteroaromatic oligomer-containing polymer onto a surface of a nanomaterial.Type: ApplicationFiled: January 22, 2014Publication date: July 24, 2014Inventors: Chuanbing Tang, Yali Qiao, Harry J. Ploehn, MD. Sayful Islam
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Publication number: 20140166942Abstract: Provide are: a conjugated block copolymer capable of increasing the amount of optical absorption by a photoelectric conversion active layer and controlling the morphology thereof and capable of achieving excellent photoelectric conversion efficiency; and a photoelectric conversion element comprising a composition including an electron accepting material and this kind of conjugated block polymer. A ?-electron conjugated block copolymer comprising: a polymer block (A) which involving a monomer unit having at least one heteroaryl skeleton selected from the group consisting of a fused ?-conjugated skeleton, a fluorene, a carbazole, a dibenzosilole and a dibenzogermole containing at least one thiophene ring in a part of a chemical structure thereof; and a polymer block (B) involving a monomer unit of a thiophene-2,5-diyl group having a substituent at least at a 3-position thereof.Type: ApplicationFiled: March 30, 2012Publication date: June 19, 2014Inventors: Takafumi Izawa, Hiromasa Shibuya, Takashi Sugioka, Takuya Inagaki, Yasushi Morihara, Atsuhiro Nakahara, Akio Fujita, Hiroyuki Ogi
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Publication number: 20140124710Abstract: Provided are: a conjugated block copolymer capable of increasing the amount of optical absorption by a photoelectric conversion active layer and controlling the morphology thereof and capable of achieving excellent photoelectric conversion efficiency; and a photoelectric conversion element comprising a composition including an electron accepting material using this kind of conjugated block polymer. A ?-electron conjugated block copolymer comprises: a polymer block (A) and a polymer block (B), each of which involves a monomer unit having at least one fused ?-conjugated skeleton including at least one thiophene ring in one part of the chemical structure thereof, the polymer block (A) and the polymer block (B) have different monomer units from each other.Type: ApplicationFiled: March 30, 2012Publication date: May 8, 2014Applicant: KURARAY CO., LTD.Inventors: Takafumi Izawa, Hiromasa Shibuya, Takashi Sugioka, Takuya Inagaki, Yasushi Morihara, Atsuhiro Nakahara, Akio Fujita, Hiroyuki Ogi
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Publication number: 20140121326Abstract: A method for forming a conjugated heteroaromatic polymer is described, wherein at least one compound of formula (1) is polymerized using an acid as a catalyst, wherein X is selected from S, O, Se, Te, PR2 and NR2, Y is hydrogen (H) or a precursor of a good leaving group Y? whose conjugate acid (HY) has a pKa of less than 30, Z is hydrogen (H), silyl, or a good leaving group whose conjugate acid (HY) has a pKa of less than 30, b is 0, 1 or 2, each R1 is a substituent, and the at least one compound of formula (1) being polymerized includes at least one compound of formula (1) with Z?H and Y?H.Type: ApplicationFiled: October 28, 2012Publication date: May 1, 2014Inventors: Chien-Chung Han, Balasubramanian Arumugam
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Publication number: 20140084220Abstract: Provided is a conjugated block copolymer that is capable of morphology control and that can achieve superior conversion efficiency.Type: ApplicationFiled: March 9, 2012Publication date: March 27, 2014Applicant: KURARAY CO., LTD.Inventors: Takuya Inagaki, Hiromasa Shibuya, Takashi Sugioka, Takafumi Izawa, Yasushi Morihara, Atsuhiro Nakahara, Akio Fujita, Hiroyuki Ogi
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Publication number: 20140073742Abstract: The present invention relates to unsaturated polyester resin compositions comprising (a) an unsaturated polyester, (b) a vinyl group containing organic compound as reactive diluent and (c) a tertiary aromatic amine, wherein the resin composition further comprises (d) a compound according to formula (1) as reactive diluent whereby n=0-3; R1 and R2 each individually represent H, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkylaryl or C7-C20 arylalkyl; X=O, S or NR3 whereby R3=H, C1-C20 alkyl, C3-C20 cycloalkyl, C6-C20 aryl, C7-C20 alkylaryl, C7-C20 arylalkyl, part of a polymer chain or attached to a polymer chain, and the resin composition comprises, as vinyl group containing organic compound (b), styrene, a styrene derivative, a vinyl ether, a vinyl amine or vinyl amide or a mixture of at least two of these compounds.Type: ApplicationFiled: March 29, 2012Publication date: March 13, 2014Applicant: DSM IP ASSETS B.V.Inventors: Johan Franz Gradus Antonius Jansen, Iris Hilker, Nanning Joerg Arfsten
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Publication number: 20140072905Abstract: A positive resist composition contains: (A) a polymer compound having a structure where a hydrogen atom of a phenolic hydroxyl group is replaced by an acid labile group represented by the following formula (I): wherein R represents a monovalent organic group; A represents a group having a polycyclic hydrocarbon ring structure or a group having a polycyclic heterocyclic structure; and * represents a bonding position to an oxygen atom of the phenolic hydroxyl group.Type: ApplicationFiled: November 6, 2013Publication date: March 13, 2014Applicant: FUJIFILM CorporationInventors: Tomotaka TSUCHIMURA, Takeshi INASAKI
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Publication number: 20140051808Abstract: A highly branched polyolefin having olefin derived units; wherein the highly branched polyolefin has: (i) a branching index, g?(vis), of less than about 0.9; (ii) a phase angle, ?, of less than about 55 degrees at a complex modulus of 10 kPa, measured at 190° C.; (iii) a gel content of less than or equal to about 10%; and (iv) a melting point of less than about 135° C.; wherein the highly branched polyolefin is obtained by contacting one or more polyolefins with a free radical generator. The highly branched polyolefin may also comprise a modifying polymer, wherein the modifying polymer may be the similar or dissimilar to the polyolefin. Methods of producing these highly branched polyolefins and blends of these highly branched polyolefins are also disclosed.Type: ApplicationFiled: July 30, 2013Publication date: February 20, 2014Inventor: Mun F. Tse
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Publication number: 20140051809Abstract: Highly branched compositions including: (i) from about 96 wt % to about 99.9 wt % metallocene catalyzed ethylene propylene diene derived units; and (ii) from about 0.1 wt % to about 4 wt % multifunctional monomer derived units, wherein the highly branched composition has: (a) a Mooney viscosity ML (1+4) at 125° C. of about 30 to 100 MU, (b) a Mooney relaxation area MLRA of about 100 to about 1000, (c) a branching index, g?(vis) of less than about 0.9, (d) a phase angle, ?, of less than about 55 degrees at a complex modulus of 10 kPa, measured at 190° C., and (e) a degree of shear thinning greater than about 0.95, measured at 190° C., are disclosed herein. Homogeneous blends including this composition are also described. Processes to make the highly branched composition and the homogeneous blend are also described herein.Type: ApplicationFiled: July 30, 2013Publication date: February 20, 2014Inventor: Mun F. Tse
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Patent number: 8623962Abstract: This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)?83), when 70 to 90 mol % ethylene is present in the co-oligomer.Type: GrantFiled: September 21, 2012Date of Patent: January 7, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: John R. Hagadorn, Matthew W. Holtcamp, Andrew G. Narvaez, Jr., Donna J. Crowther, Patrick Brant
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Publication number: 20130217832Abstract: An object of the present invention is to provide a novel copolymer useful as a pigment dispersing agent in the field of color liquid crystal displays and the like.Type: ApplicationFiled: November 2, 2011Publication date: August 22, 2013Applicant: NIPPON SODA CO., LTD.Inventors: Takeshi Niitani, Toshiaki Okado, Hidenori Naruse, Tooru Kajita
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Publication number: 20130033975Abstract: A reversible recording medium based on optical storage of at least one item of information within a support material, includes at least one layer of support material having: base molecules able to take, in a local zone, a first collective state of molecules able to generate a first signal of second harmonic characteristic of this first collective state of molecules when excited by electromagnetic reading radiation; the base molecules having the first collective state of molecules able to transform, at least in part, into transformed molecules so as to pass to a second collective state of molecules when excited by electromagnetic writing radiation, the molecules having the second collective state of molecules able to generate a second signal of second harmonic characteristic of this second collective state of molecules when excited by the electromagnetic reading radiation. The molecules exhibit a molecular structure based on a coumarin skeleton of Formula (I).Type: ApplicationFiled: April 5, 2011Publication date: February 7, 2013Applicant: UNIVERSITE DAMGERSInventors: Denis Gindre, Marc Salle, Oksana Krupka, Konstantinos Iliopoulos
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Publication number: 20120259267Abstract: Compositions are provided in which dendrimers and/or nanoparticles are synthesized with multi-photon responsive elements and self-immolative oligomers. The compositions may be utilized to selectively deliver Payloads within tissue by irradiating the compositions. The compositions may also be used to amplify sensitivity to irradiation.Type: ApplicationFiled: September 23, 2010Publication date: October 11, 2012Applicant: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: Adah Almutairi, Nadezda Fomina, Jagadis Sankaranarayanan
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Patent number: 8283419Abstract: This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)?83), when 70 to 90 mol % ethylene is present in the co-oligomer.Type: GrantFiled: June 19, 2009Date of Patent: October 9, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: John R. Hagadorn, Matthew W. Holtcamp, Andrew G. Narvaez, Jr., Donna J. Crowther, Patrick Brant
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Patent number: 8273431Abstract: A polyamide resin composition contains a resin component containing at least a polyamide (X) and a fatty acid metallic salt having from 10 to 50 carbon atoms, and contains arbitrarily an additive (A) and/or an additive (B). The polyamide (X) is obtained through melt polycondensation of a diamine component containing 70% by mol or more of m-xylylenediamine and a dicarboxylic acid component containing 70% by mol or more of an ?,?-linear aliphatic dicarboxylic acid. The additive (A) is at least one compound selected from the group consisting of a diamide compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diamine having from 2 to 10 carbon atoms, a diester compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diol having from 2 to 10 carbon atoms, and a surfactant, and the additive (B) is at least one compound selected from the group consisting of a metallic hydroxide, a metallic acetate salt, a metallic alkoxide, a metallic carbonate salt and a fatty acid.Type: GrantFiled: May 31, 2007Date of Patent: September 25, 2012Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Ryoji Otaki, Jun Mitadera, Tomonori Kato, Tomomichi Kanda
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Publication number: 20120225233Abstract: The use of a functionalized organosilicon compound as a coupling agent between an inorganic filler and an elastomer in an elastomer composition including an isoprene elastomer and a reinforcing inorganic filler is disclosed. The compound is selected among functionalized organosilicon compounds including at least one double bond C?C or C?N, and not including any C?C—C?O bonds or N?N bonds, and reacting with the isoprene units according to an electrocyclic reaction, in particular according to a standard cycloaddition reaction [2+1], [2+2], [3+2] or a Diels-Alder reaction [4+2] or an ene-synthesis reaction other than an ene-synthesis reaction between an isoprene unit and a C?C—C?O or N?N function. Also described, are elastomer composition(s) obtained and items manufactured using such compositions.Type: ApplicationFiled: June 2, 2010Publication date: September 6, 2012Applicant: RHODIA OPERATIONSInventors: Laurent Guy, Virginie Pevere, Thierry Vidal
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Publication number: 20120118832Abstract: An ionic polymer of formula VI wherein each b=0 or 1; X is hydrogen, 1/z of a metal ion of charge z, a protonated nitrogen base, or a tetrasubstituted organic ammonium compound; the molar ratio of q:r:s:t=(100-0.1):(0-99.9):(0-50):(0-30); R1, R2 and R3 are hydrogen or C1-4 alkyl; R4, R5, R6 and R7 are hydrogen, C1-4 alkyl or F, wherein F is a functional group that imparts a property to polymer VI, at least one and no more than two of R4, R5, R6 and R7 are F and F is the same or different; G is a single bond or a C1-30 hydrocarbyl group; and for each instance of t when t is not zero, c=0-5 and d=0-5, provided that c+d=1-5, and wherein q, r and s as present in c are independent of any other value of q, r and s.Type: ApplicationFiled: November 11, 2011Publication date: May 17, 2012Applicant: SEGETIS, INC.Inventors: Dorie J. Yontz, Brian D. Mullen, Cora M. Leibig, Marc D. Rodwogin, Vivek Badarinarayana, Feng Jing, Friederike T. Stollmaier
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Publication number: 20120123058Abstract: The present invention provides a novel methanofullerene derivative applicable as an organic semiconductor material in electronics devices such as organic FETs and electroluminescence devices and solar cells, represented by formula (I) wherein the average value of 13C-NMR chemical shift values of carbons C2 and C2? on FL, bonded to C1 is 80.10 ppm or greater, wherein FL represents fullerenes, X1 and X2 are each an aromatic hydrocarbon, an alkyl group or the like, C2 and C2? are carbon atoms on FL, bonded to C1, and n is an integer of 1 to 10.Type: ApplicationFiled: June 25, 2010Publication date: May 17, 2012Applicants: JX NIPPON OIL & ENERGY CORPORATION, OSAKA MUNICIPAL TECHNICAL RESEARCH INSTITUTEInventors: Toshinobu Ohno, Yuko Takao, Kazuyuki Moriwaki, Fukashi Matsumoto, Souichi Uchida, Satoru Ikeda
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Publication number: 20120027342Abstract: Provided is a cationically polymerizable resin composition which has a low viscosity, is easy to work, and is extremely rapidly cured upon irradiation with light to give a cured product excellent in optical transparency, flexibility, thermal stability, and post-heating bendability. The cationically polymerizable resin composition includes an oxetane-ring-containing vinyl ether compound (A) and/or an alicyclic-epoxy-group-containing vinyl ether compound (B); an oligomer or polymer (C) containing, in the molecule, at least one selected from oxetane group, epoxy group, hydroxyl group, vinyl ether group, and an aliphatic or alicyclic unsaturated hydrocarbon group and having a molecular weight of 500 or more; and an oxetane compound (D) containing no vinyl ether group and having 6 or more carbon atoms.Type: ApplicationFiled: March 30, 2010Publication date: February 2, 2012Inventors: Tsukasa Yoshida, Yoshinori Funaki, Yo Yamato
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Patent number: 8030415Abstract: A moisture crosslinkable thermoplastic composition is produced by a process of grafting an unsaturated silane of the formula: G1R1SiZ where G1 is vinyl, R1 is methyl and Z is a divalent hydrolyzable group under reactive mechanical working conditions and in the presence of at least two peroxides and subsequently is converted into a crosslinked thermoplastic composition by exposure to moisture in the presence of a crosslinking catalyst.Type: GrantFiled: March 16, 2010Date of Patent: October 4, 2011Assignee: Momentive Performance Materials, Inc.Inventor: Eric R. Pohl
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Publication number: 20110160404Abstract: The invention relates to copolymers that can be obtained by the polymerization of monomers (A), (B), (C) and (D), where (A) is a monomer of formula (I) wherein A is C2-C4 alkylene and B is a C2-C4 alkylene different from A, R is hydrogen or methyl, m is a number between 1 and 500, and n is a number between 1 and 500, the sum of m+n being equal to between 2 and 1000; (B) is a monomer of formula (II) wherein D is C3 alkylene, R is hydrogen or methyl, and o is a number between 2 and 500; (C) is an ethylenically unsaturated monomer containing an aromatic group; and (D) is an ethylenically unsaturated monomer containing an alkyl radical.Type: ApplicationFiled: July 17, 2009Publication date: June 30, 2011Applicant: CLARIANT FINANCE (BVI) LIMITEDInventors: Bjoern Fechner, Carsten Schaefer, Alexander Woerndle
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Patent number: 7956131Abstract: Lactam polymers has been modified with sodium borohydride (NaBH4) to yield lactam polymers bearing hydroxyl functional groups. These functional groups are useful for the covalent attachment of reactive groups, fluorescent probes, antimicrobial agents, bioactive factors, and drugs. The resulting as components for medical devices, specifically ophthalmic devices and more specifically contact lenses. Hydrogels based on these polymers are also useful for biomedical applications in the areas of drug delivery, tissue engineering, and implantable devices.Type: GrantFiled: March 17, 2010Date of Patent: June 7, 2011Assignee: Johnson & Johnson Vision Care, Inc.Inventors: Stephen C Arnold, Walter R Laredo
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Publication number: 20110040042Abstract: Described herein are compositions including heterocyclic organic compounds such as fused thiophene compounds, methods for making them, and uses thereof.Type: ApplicationFiled: October 19, 2010Publication date: February 17, 2011Inventor: Mingqian He
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Publication number: 20100317805Abstract: The invention relates to novel compounds of formula (I): in which R1, R2 and R3, identical or different, independently represent: hydrogen a halogen a C1 to C15 hydroxy or hydroxyalkyl group a C1 to C15 linear or branched alkyl group a, b and c independently lying between 0 and 5. R4 is linked to the naphthalene unit at position 1, 2 or 3 via a —CH2—O— bond and represents: either a divalent group which is (co)polymerisable with a monomer; in which case d lies between 1 and 3 or a monovalent group which is (co)polymerisable with a monomer; in which case d is equal to 2 or 3 and R5 is linked to the naphthalene unit at position 1, 2 or 3 and represents: hydrogen, a halogen, a C1 to C15 hydroxyalkyl group, a C1 to C15 linear or branched alkyl group, and e is an integer lying between 0 and 2 and such that d+e=3. It also relates to the method for synthesising these compounds and to their use for the manufacture of photochromic or photosensitive polymers.Type: ApplicationFiled: August 25, 2010Publication date: December 16, 2010Applicant: POLYMEREXPERTInventors: Sébastien GIBANEL, Jean-Luc POZZO, Anne PAGNOUX, Marc DOLATKHANI
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Patent number: 7825188Abstract: The present invention provides curatives for thermosetting adhesive compositions, methods of preparation and uses thereof. In particular, the present invention relates to elastomeric epoxy curative compounds that can be used in thermosetting compounds, methods for preparing the curative compounds and epoxy compositions containing the curative compounds.Type: GrantFiled: December 19, 2007Date of Patent: November 2, 2010Assignee: Designer Molecules, Inc.Inventor: Stephen M Dershem
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Publication number: 20100249332Abstract: In accordance with embodiments provided herein, biodegradable filament suitable for use as fishing line and/or fishing net prepared from a polyester copolymer is provided. Embodiments of biodegradable filament is prepared from a polymer blend comprising from about 60% by weight to about 99.9% by weight of polybutylene succinate (PBS) and from about 0.1% by weight to about 40% by weight of a second polymer selected from the group consisting of polycaprolatone (PCL), polyglycolic acid (PGA), and polylactic acid (PLA).Type: ApplicationFiled: July 16, 2009Publication date: September 30, 2010Applicant: WRIGHT & MCGILL CO.Inventor: Patrick J. Ferguson
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Patent number: 7795347Abstract: A group of polymers comprising a plurality of polyolefin chains and polar polymer chains and having a multi-branched structure such as a block structure, a graft structure and a star-shaped structure is produced efficiently by polymerizing or reacting a combination of various polar monomers and their polymers i.e. polar polymer chains by using a functional group-containing polyolefin as a macroinitiator, a macromonomer or a reactive polymer. The resulting multi-branched polymer has a specific shape such as a block structure, a graft structure or a star-shaped structure, and has properties of both the polyolefin and polar polymer, thus exhibiting useful performance in various uses in films and compatibilizing agents as a novel polyolefin-based polymer.Type: GrantFiled: March 11, 2004Date of Patent: September 14, 2010Assignee: Mitsui Chemicals, Inc.Inventors: Hideyuki Kaneko, Tomoaki Matsugi, Shin-Ichi Kojoh, Shingo Matsuo, Nobuo Kawahara, Norio Kashiwa
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Publication number: 20100218892Abstract: A maleimide terminated polyimide incorporated into a two-part acrylic structural adhesive system. The maleimide terminated polyimide of the various embodiments of the present invention provide improving thermal stability, strength, and toughness.Type: ApplicationFiled: February 2, 2010Publication date: September 2, 2010Inventors: JIAN-PING HUANG, Eric N. Wyman
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Patent number: 7683134Abstract: A process for the manufacture of maleated polypropylenes having an acid number greater than 6, a yellowness index color of no greater than 76, and a number average molecular weight of at least 20,000. The process for making the maleated polypropylenes includes forming a mixture of molten polypropylene and molten maleic anhydride in a reactor, introducing a free radical initiator into the molten mixture to produce a product having maleic anhydride grafted onto the polypropylene, and recovering a high acid number, high molecular weight maleated polypropylene of low color from the reactor.Type: GrantFiled: July 21, 2008Date of Patent: March 23, 2010Assignee: Eastman Chemical CompanyInventors: Thomas David Roberts, Stephen Wayne Coe
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Publication number: 20100036491Abstract: A method for manufacturing of ultrahigh molecular weight polyethylene (UHMWPE) for implants, where the implants have been machined out of UHMWPE blocks or extruded rods, has anthocyanin dispersely imbedded in the polyethylene. The implant is then exposed to ? ray or electron beam irradiation in an amount of at least 2.5 Mrad followed by a heat treatment to prevent the implant from becoming brittle in the long term as well as to improve strength and wear. The method includes mixing a powder or granulate resin of UHMWPE with an aqueous liquid that contains anthocyanin in a predetermined amount. The water is then evaporated in order to deposit the anthocyanin in a predetermined concentration on the polyethylene particles. The doped UHMWPE particles are compressed into blocks at temperatures in a range of approximately 135° C.-250° C. and pressures in a range of approximately 2-70 MPa. Medical implants are made from the blocks.Type: ApplicationFiled: August 5, 2008Publication date: February 11, 2010Applicant: Howmedica Osteonics Corp.Inventors: Shulin He, Shi-Shen Yau, Aiguo Wang
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Patent number: 7625967Abstract: The present invention relates to oil gel compositions that include at least one non-aromatic ester oil and an anionic block copolymer of a mono alkenyl arene and a conjugated diene. The block copolymer is selectively hydrogenated and has mono alkenyl arene end blocks and a controlled distribution block of a mono alkenyl arene and a conjugated diene midblock. The ester oil is a non-aromatic, ester compound such as soybean oil, rapeseed oil, and other like compounds.Type: GrantFiled: March 7, 2006Date of Patent: December 1, 2009Assignee: Kraton Polymers U.S. LLCInventor: David John St. Clair
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Patent number: 7511100Abstract: A process for crosslinking polymers employs a silane crosslinker which, upon hydrolysis, produces a reduced quantity of volatile organic compound.Type: GrantFiled: October 19, 2007Date of Patent: March 31, 2009Assignee: Momentive Performance Materials Inc.Inventor: Keith J. Weller
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Patent number: 7459499Abstract: Pressure-sensitive adhesive comprising an acrylate block copolymer having at least two chemically distinguishable, covalently interlinked acrylate polymer blocks P in microphase-separated regions and each having a softening temperature of between ?125 and +20° C.Type: GrantFiled: December 15, 2004Date of Patent: December 2, 2008Assignee: tesa AGInventors: Marc Husemann, Thilo Dollase, Bernd Luhmann
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Publication number: 20080249252Abstract: The invention relates to novel compounds of the formula I, II; III or IV wherein the general symbols are as defined in claim 1. These compounds are useful as surface modifiers for polymers in order to improve resistance to fog formation or water and oil repellency.Type: ApplicationFiled: June 5, 2008Publication date: October 9, 2008Inventors: Piero Piccinelli, Manuele Vitali, Andrea Landuzzi, Giovanni Da Roit, Primo Carrozza, Markus Grob, Nicola Lelli
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Patent number: 7417092Abstract: Methods are described herein for converting carbocationically terminated polymers to anionically terminated polymers. These methods comprise: (a) providing a carbocationically terminated polymeric moiety; (b) reacting the carbocationically terminated polymeric moiety with a heterocyclic compound of the formula where —X— is selected from —S—, —O—, —NH— and —NR—, and where R is an alkyl group or an aryl group, thereby providing an end-capped polymeric moiety; and (c) reacting the end-capped polymeric moiety with an organolithium compound to yield an anionically terminated polymeric moiety. Also described are block copolymers in which a first polymer block comprising cationically polymerized monomers is linked to a second polymer block comprising anionically polymerized monomers by a group, as well as a polymer in which a polymer block comprising cationically polymerized monomers is linked to a halogenated silane residue or a carbosilane residue by a group.Type: GrantFiled: June 18, 2004Date of Patent: August 26, 2008Assignee: University of Massachusetts LowellInventors: Rudolf Faust, Axel H. E. Mueller
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Patent number: 7408007Abstract: A process for the manufacture of maleated polypropylenes having an acid number greater than 4.5, a yellowness index color of no greater than 76, and a number average molecular weight of at least 20,000. The process for making the maleated polypropylenes includes forming a mixture of molten polypropylene and molten maleic anhydride in a reactor, introducing a free radical initiator into the molten mixture to produce a product having maleic anhydride grafted onto the polypropylene, and recovering a high acid number, high molecular weight maleated polypropylene of low color from the reactor.Type: GrantFiled: February 4, 2005Date of Patent: August 5, 2008Assignee: Eastman Chemical CompanyInventors: Thomas David Roberts, Stephen Wayne Coe
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Patent number: 7358307Abstract: A graft polymer containing a cyclic structure comprised of a polymer containing a cyclic structure graft-modified with an unsaturated compound containing a polar group, having a graft ratio of 10 to 150 mol %, having a weight average molecular weight of 1,000 to 1,000,000, and having a gel content of not more than 0.1 wt % or having a ratio (Ha/La) of high molecular weight side area (Ha) and low molecular weight side area (La) divided by a vertical line suspended from a peak top of a differentiated elution profile measured by gel permeation chromatography to a baseline of not more than 1.6, a method of production of the same, and a curable composition containing that graft polymer containing a cyclic structure and a curing agent.Type: GrantFiled: April 27, 2001Date of Patent: April 15, 2008Assignee: Zeon CorporationInventors: Junji Kodemura, Kazuaki Kondo
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Patent number: 7326753Abstract: A process for crosslinking polymers employs a silane crosslinker which, upon hydrolysis, produces a reduced quantity of volatile organic compound.Type: GrantFiled: November 16, 2005Date of Patent: February 5, 2008Assignee: Momentive Performance Materials Inc.Inventor: Keith J. Weller
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Patent number: 7285327Abstract: A white film for a reflecting structure for surface light sources, which contains voids inside it and has a light stabilizer-containing coating film formed on at least one surface of it, is aged little with time and its brightness lowers little even when used for a long time. The white film ensures good image quality of display screens for a long time, and it is favorable to reflecting sheets and reflectors in edge light-type and direct back light-type surface light sources for liquid crystal display screens.Type: GrantFiled: July 10, 2001Date of Patent: October 23, 2007Assignee: Toray Industries, Inc.Inventors: Takashi Mimura, Yoshio Tanaka, Hisashi Oowatari
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Patent number: 7112368Abstract: The present invention is directed to poly(dioxythiophene)/poly(acrylamidoalkylsulfonic acid) complexes and the oxidative polymerization process for making them. Aqueous dispersions of these poly(dioxythiophene)/poly(acrylamidoalkylsulfonic acid) complexes are useful for forming transparent electrically conductive organic layers comprised of such complexes.Type: GrantFiled: October 29, 2002Date of Patent: September 26, 2006Assignee: E. I. du Pont de Nemours and CompanyInventor: Che-Hsiung Hsu
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Patent number: 6946524Abstract: Processes for producing polyester amides, by reacting a polyisobutylene with a first reagent selected from the group consisting of at least monounsaturated acids having from 3 to 21 carbon atoms and derivatives thereof; and a second reagent selected from the group consisting of monoethanolamine and alkylamines of the general formula R—NH2, wherein R represents an alkyl group having from 1 to 4 carbon atoms; are described. The polyester amides thus produced and their uses in stabilizing asphaltenes in crude oil and crude oil derivatives are also described.Type: GrantFiled: August 29, 2001Date of Patent: September 20, 2005Assignee: Cognis Deutschland GmbH & Co. KGInventors: Wolfgang Breuer, Paul Birnbrich, Claus-Peter Herold, Stephan Von Tapavicza, Didier Groffe, Matthias Hof
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Patent number: 6913043Abstract: A composition comprising by weight: 70 to 96% of at least one polyamide chosen from PA-11, PA-12, aliphatic polyamides resulting from the condensation of an aliphatic diamine having from 6 to 12 carbon atoms and an aliphatic diacid having from 9 to 12 carbon atoms, and 11/12 copolyamides having either more than 90% of nylon-11 units or more than 90% of nylon-12 units; 4 to 10% of a plasticizer; 0 to 25% of an NBR or H-NBR elastomer; and the sum of the amount of plasticizer and the amount of elastomer is between 4 and 30%; can be manufactured by melt-blending the various constituents using standard techniques for thermoplastics. The composition is particularly useful for pipes used in the operation of offshore oil and gas fields. They exhibit very good ageing resistance. They are also useful for simpler pipes in motor vehicles, these compositions withstanding the ageing caused by the temperature under the bonnet of motor vehicles and the nature of the fluids transported.Type: GrantFiled: March 4, 2003Date of Patent: July 5, 2005Assignee: ARKEMAInventors: Bernard Jacques, Bernard Pees, Michael Werth
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Patent number: 6875823Abstract: There is provided a process for producing a modified polyolefin resin, which comprises the steps of: (1) blending at least the following components (A) to (D) to produce a blend: (A) 100 parts by weight of a polyolefin resin, (B) from 0.1 to 20 parts by weight of a compound having an epoxy group and an unsaturated bond, (C) from 0.01 to 20 parts by weight of an organic peroxide having a decomposition temperature of from 50 to 115° C., at which temperature a half-life thereof is 1 minute, and (D) from 0 to 20 parts by weight of an organic peroxide having a decomposition temperature of from 150 to 200° C., at which temperature a half-life thereof is 1 minute, and (2) melt-kneading said blend to produce a modified polyolefin resin.Type: GrantFiled: August 7, 2003Date of Patent: April 5, 2005Assignee: Sumitomo Chemical Company, LimitedInventors: Shinichi Kondo, Takashi Sanada
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Patent number: 6861502Abstract: An organic polymer having a plurality of regions along the length of the polymer backbone and comprising two or more of the following a first region for transporting negative charge carriers and having a first bandgap defined by a first LUMO level and a first HOMO level; and a second region for transporting positive charge carriers and having a second bandgap defined by a second LUMO level and a second HOMO level; and a third region for accepting and combining positive and negative charge carriers to generate light and having a third bandgap defined by a third LUMO level and a third HOMO level, wherein each region comprises one or more monomers and the quantity arrangement of the monomers in the organic polymer is selected so that the first, second and third bandgaps are distinct from one another in the polymer.Type: GrantFiled: March 13, 2000Date of Patent: March 1, 2005Assignee: Dow Global Technologies Inc.Inventors: Carl Robert Towns, Richard O'Dell, Stephen John Martin O'Connor