Cyclic Anhydride Patents (Class 525/285)
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Patent number: 11421064Abstract: The present invention relates to a process for the production of modified polyethylene comprising adding a free radical initiator composition and a polar monomer in extrusion of polyethylene materials with a melt mass flow rate (MFR) as determined in accordance with ISO 1133-1 (2011) at 190° C. under a load of 2.16 kg of between 0.5 and 75 g/10 min characterized in that the free radical initiator composition is added in quantities between 0.01 wt % to 5 wt % compared to the total weight of the polyethylene material wherein the extrusion is performed at a temperature between 230° C. and 350° C. Such process allows for the production of modified polyethylenes, such as having an amount of grafted polar monomer, such as maleic anhydride, of >3 wt %, with low amount of free, unreacted monomer whilst maintaining or not significantly modifying melt properties such as melt mass flow rate.Type: GrantFiled: April 29, 2019Date of Patent: August 23, 2022Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Franciscus Petrus Hermanus Schreurs, Jan Nicolaas Eddy Duchateau
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Patent number: 11383886Abstract: The disclosure provides a functionalized polymer for use in coating compositions and a method for making the functionalized polymer. In some embodiments, the functionalized polymer is a water-dispersible polymer, more preferably a water-dispersible polyester polymer, having one or more side groups including one or more salt groups. Packaging containers (e.g., food or beverage cans) comprising the functionalized polymer and methods of making such containers are also provided.Type: GrantFiled: July 2, 2020Date of Patent: July 12, 2022Assignee: The Sherwin-Williams CompanyInventors: Carl Cavallin, Charles Skillman, Richard H. Evans, Larry B. Brandenburger, T. Howard Killilea, George W. O'Dell
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Patent number: 11219973Abstract: There is provided a method for soldering a first non-metallic component to one or more metallic or non-metallic component, the method comprising the step of removably securing the first non-metallic component to the one or more metallic component by using a conductive polymeric composite or removably securing the first non-metallic component to the one or more non-metallic component by using the conductive polymeric composite, wherein the conductive polymeric composite used in the method comprises a blend of at least one filler material and at least one thermoplastic polymer.Type: GrantFiled: April 20, 2016Date of Patent: January 11, 2022Assignee: AGENCY FOR SCIENCE, TECHNOLOGY AND RESEARCHInventors: Kuan Eng Johnson Goh, Siew Ting Melissa Tan, Sen Wai Kwok, Kok Hin Henry Goh
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Patent number: 11186741Abstract: The present invention relates to a composition comprising an aqueous dispersion of multistage polymer particles comprising a first and a second phase, wherein the first phase comprises structural units of a carboxylic acid monomer or a salt thereof, and a nonionic ethylenically unsaturated monomer; and wherein the second phase comprises a first and second polymer, wherein the first phase or the second phase first polymer or both comprise structural units of a high Tg hydrophobic monomer; and wherein the second phase second polymer comprises at least 80 percent structural units of styrene. The high Tg hydrophobic monomer is defined as being one or more of the following monomers: cyclohexyl methacrylate, isobornyl methacrylate, 4-t-butyl methacrylate, t-butylstyrene, or n-butyl methacrylate. The multistage polymer particles are useful as opaque polymers, which are used in pigmented coating formulations to reduce the load of TiO2.Type: GrantFiled: August 30, 2019Date of Patent: November 30, 2021Assignee: Rohm and Haas CompanyInventors: James K. Bardman, David G. Kelly, Michael W. Leonard
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Patent number: 11136427Abstract: A process to form a first composition comprising a functionalized olefin-based polymer comprises: a) polymerizing a composition comprising an olefin to form a reaction product comprising an olefin-based polymer; b) subjecting at least a portion of the reaction product to at least one devolatilization to form a polymer-rich melt, wherein step b) occurs downstream from and in-line with step a); and c) reacting at least a portion of the polymer-rich melt with at least one functionalization agent and, optionally, at least one free-radical initiator to form the first composition, wherein step c) occurs downstream from and in-line with step b), wherein “the viscosity of the functionalized olefin-based polymer (177° C./350° F.)” to “the viscosity of the olefin-based polymer (177° C./350° F.)” is from 0.1 to 5.0.Type: GrantFiled: September 22, 2016Date of Patent: October 5, 2021Assignee: Dow Global Technologies LLCInventors: Shrikant Dhodapkar, Gregory E. Johnson, Rennisha R. Wickham, Santosh S. Bawiskar, Guang Ming Li, Harold W. Boone
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Patent number: 10844308Abstract: The present invention relates to novel uses of corrosion inhibitors in fuels and lubricants.Type: GrantFiled: June 27, 2017Date of Patent: November 24, 2020Assignee: BASF SEInventors: Jochen Mezger, Szilard Csihony
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Patent number: 10703868Abstract: A composition for flooring containing coconut fibers according to the present invention comprises: (A) 100 parts by weight of acrylonitrile-butadiene latex consisting of 20 to 60 parts by weight of acrylonitrile, 40 to 80 parts by weight of butadiene, 1 to 3 parts by weight of a first emulsifier, and 4 to 7 parts by weight of an acrylic monomer; (B) 3 to 6 parts by weight of a vulcanizing agent obtained by mixing sulfur, EZ, MZ, and a second emulsifier in a ratio of 3:1:1:0.1; (C) 2 to 3 parts by weight of a zinc oxide; (D) 2 to 5 parts by weight of an antioxidant; and (E) 20 to 40 parts by weight of calcium carbonate.Type: GrantFiled: July 13, 2017Date of Patent: July 7, 2020Inventor: Dae Ho Jeong
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Patent number: 10703848Abstract: The present invention provides a hydrogenated block copolymer containing, in the molecule thereof, a polymer block (C) having a conjugated diene compound as a main component, a polymer block (B) having a conjugated diene compound as a main component, and a polymer block (S) having a vinyl aromatic compound as a main component.Type: GrantFiled: September 7, 2016Date of Patent: July 7, 2020Assignee: Asahi Kasei Kabushiki KaishaInventors: Yasuhiro Kusanose, Hiroyuki Ichino, Masashi Yamamoto, Masahiro Fujiwara, Toshikazu Hoshina
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Patent number: 10407539Abstract: The present invention relates to specific deoxybenzoin containing flame retardant polyesters and flame retardant thermoplastic polymer molding compositions comprising deoxybenzoin containing flame retardant polyesters as well as their preparation and use for producing moldings, fibers or foils.Type: GrantFiled: October 9, 2015Date of Patent: September 10, 2019Assignees: BASF SE, University of MassachusettsInventors: Roland Helmut Krämer, Sebastian Wagner, Peter Deglmann, Motonori Yamamoto, Todd Emrick, Aabid Mir
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Patent number: 10392460Abstract: The present invention provides a process of producing a modified polymer composition, which composition comprises a free-radical polymeriseable monomer grafted to a polyolefin backbone. The process comprises contacting, in an extruder, an olefin polymer and the free-radical polymeriseable monomer in the presence of a stable radical in an extruder and extruding the composition.Type: GrantFiled: September 11, 2015Date of Patent: August 27, 2019Assignee: BOREALIS AGInventors: Ricardo Godoy-Lopez, Floran Prades, Anh Tuan Tran
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Patent number: 10202478Abstract: Multigraft copolymers having various structures, e.g., comb and centipede structures, can be prepared from emulsion copolymerization of monomers and macromonomers. The emulsion copolymerization can be initiated by a thermally activated radical initiator or a redox initiation system. The multigraft copolymers can have high molecular weight and/or a large number of branch points. Elastomer or adhesive compositions of the copolymers can be prepared. Also described are poly(n-alkyl acrylate-graft-styrene) multigraft copolymers.Type: GrantFiled: June 19, 2015Date of Patent: February 12, 2019Assignee: University of Tennessee Research FoundationInventors: Jimmy W. Mays, Nam-Goo Kang, Qiuyu Zhang, Wenwen Wang
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Patent number: 10189933Abstract: A method for producing functionalized thermoplastic elastomers on the basis of grafting substrates, selected from olefine-block copolymers of composition 80 to 98 mass-% ethylene-/2 to 20 mass-% C3- to C12-olefine units or partially crystalline propylene/ethylene and/or C4- to C12-olefine and/or C4- to C12-diene-copolymers of composition 50 to 98 mass-% propylene-/2 to 50 mass-% C2- and/or C4- to C12-olefine and/or C4- to C12-diene units or cross-linked styrene/olefine/styrene or styrene/olefine-block copolymers, wherein, in a liquid mixing reactor per 100 mass parts of particular grafting substrate—0.1 to 15 mass parts of at least one functional monomer from the series of functional groups comprising ?,?-ethylenic unsaturated compounds or 0.1 to 15 mass parts of a monomer mixture comprising at least one of said functional monomers and—0.01 to 10 mass parts of at least one initiator forming free radicals having a 1-hour half-life temperature (THwz/1h) between 50 and 200° C.Type: GrantFiled: March 14, 2014Date of Patent: January 29, 2019Assignee: BYK-CHEMIE GMBHInventors: Klaus Dieter Besser, Jochen Gerecke, Bianka Leitner, Inno Rapthel
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Patent number: 10174162Abstract: The present invention relates to a copolyester having intrinsic viscosity greater than 0.50 dL/gm, comprises: terephthalate polyester composition; and a modified transparent polybutylene naphthalate, wherein the modified polybutylene naphthalate comprises naphthalene dicarboxylic acid, 1,4-butane diol, and isophthalic acid or monoethylene glycol or diethylene glycol or cyclohexane dimethanol or polyethylene naphthalate, nucleating agent, and a modified nanoclay.Type: GrantFiled: August 5, 2015Date of Patent: January 8, 2019Assignee: Ester Industries LimitedInventors: Sanjay Tammaji Kulkarni, Balasundaram Dillyraj, Chandrakant Omkar Vyas
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Patent number: 10005947Abstract: Methods for treating oil-based drilling fluids with a fluid loss additive that includes one or more hydrocarbon resins. An oil-based drilling fluid and a hydrocarbon resin can be combined to produce a treated oil-based drilling fluid. The hydrocarbon resin can include a polymerized product of a reaction mixture that can include a dicyclopentadiene; at least one member selected from the group consisting of: a dimer of an aliphatic cyclic diene having five carbon atoms, a dimer of an aliphatic non-cyclic diene having five carbon atoms, a monoolefin, a diolefin, or a polyene, each having more than five carbon atoms and no aromatic rings, a C5-olefin, a debutanized aromatic concentrate, and any mixture thereof; and at least one member selected from the group consisting of: a fatty acid-containing material, a rosin acid-containing material, and a mixture thereof.Type: GrantFiled: November 18, 2014Date of Patent: June 26, 2018Assignee: INGEVITY SOUTH CAROLINA, LLCInventors: Phillip W. Hurd, Nathan P. Rife
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Patent number: 9932458Abstract: Disclosed is a rubber composition for flexible coupling. In particular, the rubber composition for flexible coupling is prepared by mixing a filler including an HNBR alloy and carbon blacks having different average particle diameters with a hydrogenated acrylonitrile-butadiene rubber such that performance deterioration due to hydrolysis can be prevented even in hot and humid environments and the rubber composition has superior heat resistance and improved mechanical strength.Type: GrantFiled: December 31, 2015Date of Patent: April 3, 2018Assignees: Hyundai Motor Company, Kia Motors Company, PCK Co., Ltd., TSR Co., Ltd., Hyundai Mobis Co., Ltd.Inventors: Jae Wook Kang, Kyung Mo Yang, Byung Sub Park, Kang Won Seo, Sung Chul Kim, Dong Won Lee
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Patent number: 9688802Abstract: The present invention relates to a poly(ethylene-aliphatic diene)-g-polystyrene-based copolymer having an improved mechanical property and heat resistance, and a method for preparing the same. More particularly, the present invention relates to a poly(ethylene-aliphatic diene)-g-polystyrene-based copolymer, which includes an ethylene-aliphatic diene copolymer as a soft segment and a polystyrene-based polymer grafted to the soft segment as a hard segment, and a method for preparing the same. The poly(ethylene-aliphatic diene)-g-polystyrene-based copolymer has elasticity equivalent to that of SBS or SEBS, and improved mechanical properties such as tensile strength and heat resistance, thereby being used as a substituent for SBS or SEBS.Type: GrantFiled: May 23, 2014Date of Patent: June 27, 2017Assignee: KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGYInventors: Dong Hyun Kim, No Hyung Park, Jung Soo Kim, Dong Gyu Jeon
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Patent number: 9593269Abstract: A polyolefin-based composition made from or containing (A) a first polymer composition made from or containing a polyolefin grafted with an unsaturated monomer, (B) a second polymer composition made from or containing a polyethylene, and (C) a third polymer composition made from or containing (i) a first polyisobutylene and (ii) a second polyisobutylene. The first polyisobutylene has a Viscosity Average Molecular Weight (VAMW1), and the second polyisobutylene has a Viscosity Average Molecular Weight (VAMW2), wherein VAMW1?VAMW2. The polyolefin-based composition is useful as an adhesives or a tie-layer adhesive composition for multi-layered structures. In particular, the composition is useful as an adhesive to bind a metal layer to a dissimilar substrate.Type: GrantFiled: September 22, 2015Date of Patent: March 14, 2017Assignee: Equistar Chemicals, LPInventor: Maged G. Botros
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Patent number: 9458342Abstract: The present invention provides a laminated polyester film which can be suitably used for extrusion lamination with polyolefins and comprises a coating layer having an excellent adhesion property to the polyolefins, in particular, a coating layer having a remarkably excellent adhesion property to polypropylene. The laminated polyester film of the present invention comprises a polyester film and a coating layer formed on a surface of the polyester film which is formed by applying a coating composition comprising (A) a modified polyolefin having two melting points, and at least one crosslinking agent, and then drying the coating composition applied.Type: GrantFiled: April 4, 2011Date of Patent: October 4, 2016Assignee: MITSUBISHI PLASTICS, INC.Inventors: Aiko Kodama, Toshihiro Koda, Masato Fujita
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Patent number: 9403923Abstract: A process for preparing a polyethylene wax by polymerization of ethylene in the presence of a Ziegler-Natta catalyst system composed of titanium tetrachloride and dialkylaluminium halide, wherein the polymerization temperature is in the range from 170 to 200° C., the polymerization is carried out essentially in the absence of solvents and the Al/Ti molar ratio is less than 1.6, gives a wax having the following property profile: dropping point of from 115 to 125° C.; penetration number of not more than 1 mm·10?1; viscosity at 150° C. of less than 60 mPas; density of from 0.945 to 0.960 g/cm3 at 23° C.; molar mass of less than 1500 g/mol and crystallinity of more than 70%.Type: GrantFiled: September 13, 2007Date of Patent: August 2, 2016Assignee: HONEYWELL INTERNATIONAL INC.Inventors: Volker Schrenk, Udo Spitzer, Hans-Dieter Zagefka
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Patent number: 9382354Abstract: This invention relates to a polymer product of an anhydride functionalized polymer with a cyclic epoxide, and processes for the production thereof.Type: GrantFiled: October 20, 2014Date of Patent: July 5, 2016Assignee: ExxonMobil Chemical Patents Inc.Inventor: Matthew W. Holtcamp
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Patent number: 9340670Abstract: The present invention relates to an environmentally friendly flame-retardant polycarbonate resin composition having scratch resistance, which includes a specific (meth)acrylic flame-retardant copolymer to improve flame retardancy and scratch resistance.Type: GrantFiled: June 11, 2013Date of Patent: May 17, 2016Assignee: Cheil Industries Inc.Inventors: Jin Hwa Chung, Ja Kwan Koo, Joo Hyun Jang, Yong Hee Kang, Kee Hae Kwon, Kwang Soo Park, Man Suk Kim, Jin Seong Lee
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Patent number: 9156983Abstract: A process for producing a solution blend of a polybenzimidazole (PBI) and a polyetherketoneketone (PEKK). The PBI is mixed with sulfuric acid at a temperature between 40° C. and 80° C. for 30 minutes to 2 hours to produce a PBI solution then cooled to room temperature to form a cooled PBI solution. Then PEKK is added to the cooled PBI solution to form a mixture and that mixture is stirred from 30 minutes to 2 hours at room temperature to form a stirred mixture. The stirred mixture is poured into an excess of water being stirred swiftly to form an aqueous mixture. The aqueous mixture is filtered to produce a blend. The blend is washed with water and dried. The resulting blend can yield a blend in all proportion from 1/99 PBI/PEKK to 99/1 PBI/PEKK.Type: GrantFiled: June 27, 2014Date of Patent: October 13, 2015Assignee: PBI Performance Products, Inc.Inventors: Bobby G. Dawkins, Michael Gruender, Gregory S. Copeland, Tim Hsu
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Patent number: 9120888Abstract: The invention provides compositions containing at least one functionalized polyolefin, and in particular, to compositions containing at least one functionalized ethylene interpolymer, which has a melt viscosity less than 50,000 cP at 350° F. (177° C.) and a molecular weight distribution (Mw/Mn) from about 1 to 5. The invention also provides adhesive formulations containing the same. The invention also relates to the preparation of the functionalized interpolymers, by reacting, for example, such an ethylene interpolymer with the following: a) at least one unsaturated compound, containing at least one heteroatom, and b) at least one initiator.Type: GrantFiled: June 11, 2007Date of Patent: September 1, 2015Assignee: Dow Global Technologies LLCInventors: Teresa P. Karjala, Selim Yalvac, Benjamin R. Rozenblat, Cynthia L. Rickey, Steven A. Wells
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Patent number: 8981013Abstract: The invention provides polyolefin blend compositions of polar and/or non-polar polymers, with at least one functionalized polyolefin polymer selected from the group consisting of: amine functionalized, hydroxyl functionalized, imide functionalized, anhydride functionalized, or carboxylic acid functionalized polyolefin polymers. The invention also provides methods for making the functionalized polyolefin polymer. The invention also provides for materials and articles containing at least one component prepared from such compositions.Type: GrantFiled: December 17, 2007Date of Patent: March 17, 2015Assignee: Dow Global Technologies LLCInventors: H. Craig Silvis, Stephen F. Hahn, David F. Pawlowski, Patricia Ansems, Laura K. Mergenhagen, Hamed Lakrout, Ashish Batra, Laura Bauerle Weaver, Lawrence J. Effler, Katja Oswald
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Publication number: 20150024227Abstract: There is described a block copolymer comprising at least a block [A] and a block [B], where: (a) (i) block [A] comprises from 5 to 95 mole-% per mole-% of the block [A] of itaconate functional moieties; (b) (i) block [B] is substantially free of itaconate functional moieties. Preferably the block copolymer is made by a controlled radical polymerisation (CRP) such as reversible addition-fragmentation chain transfer (RAFT).Type: ApplicationFiled: February 4, 2013Publication date: January 22, 2015Inventors: Tijs Nabuurs, Michael Arnoldus Jacobus Schellekens, Gerardus Cornelis Overbeek
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Publication number: 20150005453Abstract: Disclosed are reactive functionalized, PIB grafted polymers having an architecture of one or more pendent polyisobutylene moieties grafted on to an organic backbone, wherein the backbone is not polyisobutylene and contains at least one telechelic, reactive functionality. Also a process for making the reactive functionalized, PIB grafted polymer s and curable compositions comprising the reactive functionalized, PIB grafted polymers.Type: ApplicationFiled: September 17, 2014Publication date: January 1, 2015Inventors: Laxmisha Sridhar, Smita Shah, Andrew D. Messana, Anthony F. Jacobine
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Publication number: 20140255713Abstract: A method for manufacturing a propylene polymer, including: a) fermenting and optionally purifying first renewable materials to produce an alcohol or an alcohol mixture, the alcohol or alcohol mixture including at least isopropanol and/or at least a mixture of ethanol and 1-butanol; b) dehydrating the resulting alcohol or the alcohol mixture to produce an alkene or alkene mixture in a first series of reactors, the alkene or alkene mixture containing at least propylene; c) polymerizing the propylene in a second reactor, optionally in the presence of a comonomer, so as to produce a propylene polymer; d) isolating the propylene polymer obtained in step c); and e) grafting the propylene polymer obtained from step d). A grafted propylene polymer capable of being obtained by the method, to the compositions containing the polymer, as well as to the uses of the polymer.Type: ApplicationFiled: May 21, 2014Publication date: September 11, 2014Applicant: ARKEMA FRANCEInventors: Samuel DEVISME, Fabrice CHOPINEZ, Jean-Laurent PRADEL, Guillaume LE, Thomas ROUSSEL, Jean-Luc DUBOIS
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Patent number: 8778854Abstract: The disclosed invention relates to a composition comprising a grafted polymer. The polymer comprises a backbone with at least one olefin block and at least one vinyl aromatic block. The polymer is grafted with a pendant carbonyl containing group, the grafting being conducted by halogenating the vinyl aromatic carbon of the vinyl aromatic block and then grafting a carboxylic acid or derivative thereof on the halogenated vinyl aromatic carbon in the presence of an activating agent. The carbonyl containing-group is optionally substituted to provide ester, imide and/or amide functionality. The grafted polymer is useful as a dispersant viscosity modifier in lubricating compositions such as engine oils.Type: GrantFiled: July 6, 2010Date of Patent: July 15, 2014Assignee: The Lubrizol CorporationInventors: David Price, William R. S. Barton, Michael R. Sutton, Mark C. Davies
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Publication number: 20140182883Abstract: A crosslinked resin compound includes a resin compound including 0.1 to 20 parts by mass of one material selected from the group consisting of monomer having an epoxy group, acid anhydride and silane coupling agent with respect to 100 parts by mass of ethylene-based copolymer, and the resin compound is crosslinked.Type: ApplicationFiled: December 24, 2013Publication date: July 3, 2014Applicant: Hitachi Metals, Ltd.Inventors: Keisuke SUGITA, Akinari NAKAYAMA
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Publication number: 20140163174Abstract: Methods for forming rosin-derived cationic compounds are provided. The method can include attaching a cationic group to a conjugated diene on a hydrophenathrene-based ring of a resin acid (e.g., levopimaric acid, abietic acid, dehydroabietic acid, or a mixture thereof) to form a rosin-derived cationic compound. Attaching the cationic group to the conjugated diene on the hydrophenathrene-based ring of the resin acid can be achieved via a Diels-Alder reaction of a dienophile with the hydrophenathrene-based ring of the resin acid. Rosin-derived cationic compounds are also provided. The rosin-derived cationic compound can include a cationic group attached to a conjugated diene on a hydrophenathrene-based ring of a resin acid, wherein the rosin-derived cationic compound further comprises a carboxylic acid group.Type: ApplicationFiled: December 10, 2013Publication date: June 12, 2014Inventors: Chuanbing Tang, Jifu Wang, Alan W. Decho, Yung Pin Chen
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Publication number: 20140087987Abstract: This invention relates to processes to produce polyethylene involving contacting ethylene with a metallocene catalyst system; wherein the catalyst system comprises: a stoichiometric activator; and a metallocene compound. The metallocene catalyst system is also disclosed.Type: ApplicationFiled: September 23, 2013Publication date: March 27, 2014Inventors: Donna J. Crowther, Patrick Brant, John R. Hagadorn, Jacqueline A. Lovell
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Publication number: 20140031203Abstract: The present invention provides a novel water-absorbent resin desirable for use as a hygienic material and the like, and an absorbent material and absorbent article using the water-absorbent resin; the water-absorbent resin having a high gel strength that prevents a reduction in liquid permeation rate by suppressing gel blocking during absorption, and an excellent water-retention capacity at the same time. The water-absorbent resin satisfies the following criteria (1) and (2): (1) having a water-retention capacity of saline solution of 40 g/g or more, and (2) having a total gel strength of 5,500 Pa or greater, the total gel strength being the sum of 30 times swollen gel strength a, 40 times swollen gel strength b, and 50 times swollen gel strength c.Type: ApplicationFiled: April 19, 2012Publication date: January 30, 2014Applicant: SUMITOMO SEIKA CHEMICALS CO., LTD.Inventors: Kimihiko Kondo, Ryusuke Umeza, Kazuyoshi Takamatsu, Junichi Takatori
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Publication number: 20140024567Abstract: Disclosed is an oil-soluble lubricating oil additive composition, suitable for use as a dispersant viscosity index improver in lubricating oils; prepared by the process which comprises reacting a hydrocarbon polymer having a number average molecular weight (Mn) between about 7,000 and about 500,000 wherein the polymer backbone has been functionalized with an ethylenically unsaturated acylating agent and an aryloxy-alkylene amine.Type: ApplicationFiled: July 18, 2012Publication date: January 23, 2014Applicant: Chevron Oronite Company LLCInventors: Patrick J. McDougall, Pritesh A. Patel
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Patent number: 8623962Abstract: This invention relates to a process to functionalize propylene co-oligomer comprising contacting an alkene metathesis catalyst with a heteroatom containing alkene, and a propylene a co-oligomer having an Mn of 300 to 30,000 g/mol comprising 10 to 90 mol % propylene and 10 to 90 mol % of ethylene, wherein the oligomer has at least X % allyl chain ends, where: 1) X=(?0.94 (mol % ethylene incorporated)+100), when 10 to 60 mol % ethylene is present in the co-oligomer, and 2) X=45, when greater than 60 and less than 70 mol % ethylene is present in the co-oligomer, and 3) X=(1.83*(mol % ethylene incorporated)?83), when 70 to 90 mol % ethylene is present in the co-oligomer.Type: GrantFiled: September 21, 2012Date of Patent: January 7, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: John R. Hagadorn, Matthew W. Holtcamp, Andrew G. Narvaez, Jr., Donna J. Crowther, Patrick Brant
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Publication number: 20130324665Abstract: A PIB derivative suitable for use as a fuel additive or lubricant additive prepared from a reactive low molecular weight polyisobutylene composition comprising at least 50 mol percent alpha vinylidene terminated polyisobutylene molecules, the composition having a polydispersity of no more than 1.5 and a number average molecular weight of at least 500 Daltons and no more than 1000 Daltons. The derivative is selected from the group consisting of: alkyl hydroxyaromatic compounds; alkyl alkoxy aromatic compounds; polyisobutenylsuccinic anhydrides; polyisobutenylsuccinimides; PIB-amine compounds; sulfurized PIB compounds; and Mannich condensation products of an alkylated hydroxyaromatic compound.Type: ApplicationFiled: May 28, 2013Publication date: December 5, 2013Applicant: TPC Group LLCInventors: Sohel K. Shaikh, Jennifer Leigh Sengstock
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Publication number: 20130316234Abstract: A modifier for polyvinylidene fluoride (PVDF), which improves the adhesion of PVDF to a metal, a binder resin composition for battery and a battery using the PVDF modifier are provided. The modifier for polyvinylidene fluoride herein is a modifier in which the peeling strength of a specific cured film to an aluminium foil is 20 g/cm or more, and the specific cured film is obtained from a mixture of 6 parts by mass of the modifier for polyvinylidene fluoride and 14 parts by mass of a polyvinylidene fluoride composition. The modifier preferably contains a macromonomer copolymer (X), obtained by polymerizing both a macromonomer (A) having unsaturated double bonds and a vinyl monomer (B) having polar groups. The macromonomer (A) is preferably a methacrylic acid ester-based macromonomer (A-1). The vinyl monomer (B) is preferably a methacrylate, and a fluoroalkyl methacrylate.Type: ApplicationFiled: January 5, 2012Publication date: November 28, 2013Applicant: MITSUBISHI RAYON CO., LTD.Inventors: Fumino Momose, Mitsufumi Nodono
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Patent number: 8575275Abstract: The invention provides a composition comprising the reaction product of a mixture comprising the following: A) at least one functionalized ethylene-based polymer formed by reacting an ethylene-based polymer with at least one anhydride-containing compound and/or at least one carboxylic acid-containing compound; B) at least one ethylene-based polymer; C) at least one anhydride-containing compound and/or at least one carboxylic acid-containing compound; and wherein the composition comprises from 0.05 to 1.0 weight percent, based on the total weight of the composition, of one or more grafted anhydride-containing compounds and/or one or more grafted carboxylic acid-containing compounds.Type: GrantFiled: September 3, 2008Date of Patent: November 5, 2013Assignee: Dow Global Technologies LLCInventors: Olaf Henschke, Gabriele Goethel
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Publication number: 20130289216Abstract: A process for producing a water-soluble, hydrolysis-stable, polymerizable polymer, comprising a) a step of copolymerizing a mixture comprising (i) a first copolymerizable monomer comprising at least one optionally protected carboxylic acid group and a first polymerizable organic moiety, and (ii) a second copolymerizable monomer comprising one or more optionally protected primary and/or secondary amino groups and a second polymerizable organic moiety, for obtaining an amino group containing copolymer; b) a step of coupling to the amino group containing copolymer a compound having a polymerizable moiety and a functional group reactive with an amino group of repeating units derived from the second copolymerizable monomer in the amino group containing copolymer obtained in the first step wherein the optionally protected amino group is deprotected, so that polymerizable pendant groups are linked to the backbone by hydrolysis-stable linking groups, and, optionally, a step of deprotecting the protected carboxylic acType: ApplicationFiled: December 20, 2011Publication date: October 31, 2013Applicant: DENTSPLI International Inc.Inventors: Joachim E. Klee, Helmut Ritter, Maximilliam Maier, Julia Gansel, Andreas Facher, Oliver Eelsner, Sven Pohle
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Patent number: 8557920Abstract: The present invention relates to a polymer composition, comprising (i) a polypropylene homopolymer, (ii) a polypropylene random copolymer, prepared by copolymerization of propylene with an olefin comonomer and having an amount of olefin comonomer units of 0.2 to 5 wt %, and (iii) an elastomeric copolymer of propylene and at least one olefin comonomer, the polymer composition having a tensile modulus, determined according to ISO 527-2/1 B at 1 mm/min. and 230 C, of at least 1200 MPa.Type: GrantFiled: May 11, 2006Date of Patent: October 15, 2013Assignee: Borealis Technology OyInventors: Kauno Alastalo, Carl-Gustaf Ek, Bo Malm, Ulf Torgersen, Olli Tuominen
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Publication number: 20130244010Abstract: Provided are a modifier for polyolefin resin which imparts excellent wettability for water, etc. to a polyolefin resin substrate without decreasing the resin property of the polyolefin resin substrate composed of polyolefin resin, and a polyolefin resin composition containing the modifier and a polyolefin resin. The present invention relates to a modifier for polyolefin resin (K) containing a copolymer (X) having a polyolefin (A) and an unsaturated dicarboxylic acid (anhydride) (B) as a constitutional unit and having an acid value of 50 to 250 mg KOH/g.Type: ApplicationFiled: November 26, 2011Publication date: September 19, 2013Applicant: SANYO CHEMICAL INDUSTRIES, LTD.Inventors: Tatsuhiko Hasegawa, Yosuke Nakata
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Publication number: 20130216750Abstract: A method of producing a silane cross-linked polyethylene is disclosed which includes maleating a polyethylene polymer to form a maleated polyethylene and reacting the maleated polyethylene with a primary or secondary amino silane to form a silane-grafted polyethylene. The method further includes treating the silane-grafted polyethylene in a moisture curing process to form the silane cross-linked polyethylene.Type: ApplicationFiled: February 21, 2012Publication date: August 22, 2013Applicant: FINA TECHNOLOGY, INC.Inventors: Fengkui Li, John Ashbaugh, Jason Clark
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Patent number: 8513362Abstract: To provide a polyolefin polymer having a polar group represented by Formula (i) produced by modifying, with a high modification ratio, a double bond in a polymer having the double bond at one terminal, both terminals, or at the inside of a polymer chain thereof that is obtained by a known method; a method for producing the polyolefin polymer; and a water dispersion material and a mold release agent composition each containing the polyolefin polymer, wherein, PO, A, B, D, E, d, e, M, i, j, and n are defined as in the application.Type: GrantFiled: June 17, 2008Date of Patent: August 20, 2013Assignee: Mitsui Chemicals, Inc.Inventors: Makoto Suzuki, Naoshi Nagai
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Patent number: 8461261Abstract: Provided is a resin composition containing a resin component prepared by blending a graft copolymer with an engineering plastic, wherein the above graft copolymer is a graft copolymer satisfying (a) to (e) shown below: (a) a graft rate is 1 to 150% by mass, (b) a weight average molecular weight measured by GPC is 500 to 400000, (c) a molecular weight distribution (Mw/Mn) is 1.5 to 4, (d) a main chain is a polymerization chain containing 1 to 100% by mass of a monomer unit having a functional group interacting with the engineering plastic and (e) a side chain is a homopolymerization chain of a single kind selected from ?-olefins having 3 to 28 carbon atoms or a copolymerization chain of two or more kinds selected therefrom or a copolymerization chain comprising an ?-olefin unit having 3 to 28 carbon atoms and an ethylene unit which accounts for 50% by mass or less, and a mesopentad ratio [mmmm] of the polymerization chain is 30 to 80 mole %.Type: GrantFiled: January 14, 2009Date of Patent: June 11, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventors: Manabu Nomura, Susumu Kanno, Ryo Aburatani, Shuji Machida
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Patent number: 8461271Abstract: Provided is a production process for a graft copolymer or a thermoplastic resin composition containing the above graft copolymer, which comprises graft-polymerizing 100 parts by mass of a combination of 20 to 100% by mass of a reactive polyolefin and 0 to 80% by mass of a polyolefin other than the reactive polyolefin with 0.2 to 300 parts by mass of at least one specific monomer under the presence of a radical initiator and which is useful as a sealant, a modifier for polyolefins, a surface treating agent, a primer treating agent, a coating agent component and the like.Type: GrantFiled: November 30, 2007Date of Patent: June 11, 2013Assignee: Idemitsu Kosan Co., Ltd.Inventors: Shuji Machida, Ryo Aburatani, Takenori Fujimura, Harumi Nakashima
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Publication number: 20130137829Abstract: This invention relates to a polymer of a cyclic olefin and a vinyl terminated macromonomer, and processes for the production thereof.Type: ApplicationFiled: November 29, 2011Publication date: May 30, 2013Inventors: Matthew W. Holtcamp, Donna J. Crowther, Caol P. Huff, Patrick Brant, Jacqueline A. Lovell
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Patent number: 8378034Abstract: Adducts of an unsaturated metathesis polymer or interpolymer and an unsaturated diacid anhydride. A process for producing adducts of an unsaturated metathesis polymer or interpolymer and unsaturated diacid anhydride.Type: GrantFiled: August 4, 2009Date of Patent: February 19, 2013Assignee: Firestone Polymers, LLCInventors: James H. Pawlow, William L. Hergenrother, Mark N. Dedecker, Daniel F. Graves
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Publication number: 20130030071Abstract: This invention relates to end-functionalized living polymers or copolymers having a structure represented by the general formula 1 or 2, wherein R1 is a hydrogen atom, a methyl group, or a radically non-polymerizable organic group containing 1 to 20 carbon atoms.Type: ApplicationFiled: March 29, 2011Publication date: January 31, 2013Applicant: BASF SEInventors: Huiguang Kou, Andreas Moeck, Clemens Auschra, Peter Nesvadba, Frank Oliver Heinrich Pirrung, Andreas Gernandt
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Publication number: 20130018149Abstract: Provided is a multi-arm (greater than 3 arms) star ethylene polymer (sEP). The multi-arm star ethylene polymer is a polymer of an ethylene/maleic anhydride copolymer (EMAC) grafted with vinyl-terminated polyethylene. There are also provided a process for making the sEP and blend of a matrix ethylene polymer and the sEP.Type: ApplicationFiled: July 14, 2011Publication date: January 17, 2013Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Andy H. Tsou, Shuji Luo, Johannes M. Soulages
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Publication number: 20130005912Abstract: A method of making a styrenic composition having a high melt strength including combining a styrenic monomer and a second monomer to form a combined mixture and subjecting the combined mixture to polymerization to obtain a styrenic co-polymer, wherein the second monomer comprises a hydroxyl functional group and wherein the styrenic composition has a greater melt strength than that of general purpose polystyrene.Type: ApplicationFiled: June 29, 2011Publication date: January 3, 2013Applicant: FINA TECHNOLOGY, Inc.Inventors: Wei Wang, David W. Knoeppel
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Patent number: 8338343Abstract: The invention relates to a process for an additive composition comprising an amidized or imidized polymer. The invention further relates to a highly grafted, multi-functional lubricant additive useful to improve the viscosity index and dispersancy properties of a lubricating oil composition. The present invention also relates to a method of extending lubricant drain intervals and improving fuel economy and fuel economy durability. The additive composition is prepared by: (A) reacting an olefin copolymer of ethylene and at least one C3 to C23 &agr; -olefin comprising from about 15 to 80 mole percent of ethylene, from about 20 to 85 mole percent of said C3 to C23 &agr; -olefin and from about 0 to 15 wt percent of a polyene, said copolymer having a number average molecular weight ranging from 1,000 to 500,000, with an olefinic carboxylic acid acylating agent, said process comprising heating said polymer to a molten condition at a temperature in the range of 60° C. to 240° C.Type: GrantFiled: June 8, 2006Date of Patent: December 25, 2012Assignee: Lanxess Elastomers B.V.Inventors: Patric Meessen, Gerhard Van Vliet, Gerardus Arnoldus Rademakers, Johannes Hendrik Geesink, Zhaoyao Joe Qiu, Franciscus Victoire Paulus Houtvast