Three-membered Ring Containing Two Carbon And One Chalcogen Atom Patents (Class 525/286)
  • Patent number: 6001488
    Abstract: A resin composition comprising an epoxy group-containing cycloolefin resin and a crosslinking agent is provided. More specifically, a resin composition comprising an epoxy group-containing thermoplastic norbornene resin obtained by introducing epoxy groups into a thermoplastic norbornene resin, and as the crosslinking agent, a curing agent for epoxy resins or a photoreactive substance is provided. The resin composition is suitable for use as an insulating material.
    Type: Grant
    Filed: June 29, 1998
    Date of Patent: December 14, 1999
    Assignees: Nippon Zeon Co., Ltd., Fujitsu Limited
    Inventors: Hideaki Kataoka, Eiko Yuda, Shigemitsu Kamiya, Masahide Yamamoto, Yoshikatsu Ishizuki, Yasuhiro Yoneda, Daisuke Mizutani, Kishio Yokouchi
  • Patent number: 5981665
    Abstract: A thermoplastic elastomer is achieved by absorbing an acrylate monomer, an initiator and eventually a diacrylate into polyolefin particles, after which the temperature is raised and the acrylate polymerises into the polyolefin and forms a dispersed phase, which has been functionalized by copolymerising a functional monomer together with the acrylate. As a compatibiliser a grafter polyolefin is used, which is melt-blended after the polymerisation into the thermoplastic elastomer or before the polymerisation into the polyolefin.
    Type: Grant
    Filed: August 20, 1997
    Date of Patent: November 9, 1999
    Assignee: Optatech Corporation
    Inventors: Torvald Vestberg, Viveca Lonnberg, Tommi Vainio, Kalle Hanhi, Harri Jukarainen
  • Patent number: 5912301
    Abstract: A graft-modified polyolefin resin is provided, which is obtained by preparing a aqueous suspension containing (a1) 100 parts by weight of a polyolefin resin, (a2) 0.1 to 30 parts by weight of a mixture of 1 to 1000 parts by weight of an unsaturated glycidyl ester to 100 parts by weight of a compound having a glycidyl group as represented by a general formula (I): ##STR1## wherein Ar is an aromatic hydrocarbon group of C.sub.6 -C.sub.23 having at least one glycidyloxy group, and R is a hydrogen atom or a methyl group, (a3) 0.1 to 500 parts by weight of a vinyl monomer, and (a4) 0.001 to 10 parts by weight of a radical initiator to 100 parts by weight in total of (a2) and (a3), to thus impregnate (a1) with (a2) and (a3), and polymerizing (a2) and (a3) onto (a1). Resin compositions containig the graft-modified polyolefin resin have not only well-balanced mechanical properties, but excellent moldability.
    Type: Grant
    Filed: August 22, 1997
    Date of Patent: June 15, 1999
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kazuhiko Tamai, Shinji Ozawa, Kenji Kurimoto, Haruo Tomita
  • Patent number: 5895800
    Abstract: A resin composition comprising an epoxy group-containing cycloolefin resin and a crosslinking agent is provided. More specifically, a resin composition comprising an epoxy group-containing thermoplastic norbornene resin obtained by introducing epoxy groups into a thermoplastic norbornene resin, and as the crosslinking agent, a curing agent for epoxy resins or a photoreactive substance is provided. The resin composition is suitable for use as an insulating material.
    Type: Grant
    Filed: June 29, 1998
    Date of Patent: April 20, 1999
    Assignees: Nippon Zeon Co., Ltd., Fujitsu Limited
    Inventors: Hideaki Kataoka, Eiko Yuda, Shigemitsu Kamiya, Masahide Yamamoto, Yoshikatsu Ishizuki, Yasuhiro Yoneda, Daisuke Mizutani, Kishio Yokouchi
  • Patent number: 5886101
    Abstract: A novel class of interpenetrating polymer networks which are dispersible in conventional coating solvents is disclosed. Such dispersions are useful in preparing protective and/or decorative film coatings and are particularly useful in photosensitive or imaging formulations such as photoresists, solder masks and the like. These polymer networks are comprised of at least two interpenetrating crosslinked polymers. At least one of the polymer networks is formed by polymerization in a solvent. In one embodiment of this invention, at least one polymer network is prepared from macromers to produce a polymer system having functionalized branch or graft linear segments. The solvent dispersible interpenetrating networks of this invention are particularly useful as binders in addition polymerizable photosensitive compositions containing crosslinking monomers such as solder masks. Upon exposure to actinic radiation and suitable thermal curing, solder mask coatings of such photosensitive compositions form multiple, e.g.
    Type: Grant
    Filed: April 7, 1993
    Date of Patent: March 23, 1999
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Eugene G. Sommerfeld, Frank L Schadt, III
  • Patent number: 5783639
    Abstract: A resin composition comprising an epoxy group-containing cycloolefin resin and a crosslinking agent is provided. More specifically, a resin composition comprising an epoxy group-containing thermoplastic norbornene resin obtained by introducing epoxy groups into a thermoplastic norbornene resin, and as the crosslinking agent, a curing agent for epoxy resins or a photoreactive substance is provided. The resin composition is suitable for use as an insulating material.
    Type: Grant
    Filed: January 13, 1997
    Date of Patent: July 21, 1998
    Assignees: Nipon Zeon Co., Ltd., Fujitsu Limited
    Inventors: Hideaki Kataoka, Eiko Yuda, Shigemitsu Kamiya, Masahide Yamamoto, Yoshikatsu Ishizuki, Yasuhiro Yoneda, Daisuke Mizutani, Kishio Yokouchi
  • Patent number: 5783608
    Abstract: Separation functional fibers are produced by exposing fibers with a core/sheath structure to an ionizing radiation and then grafting a polymerizable monomer to the fibers. Ion-exchange fibers are produced by introducing, through radiation-initiated graft polymerization, ion-exchange groups into the sheath of each of composite fibers the core and the sheath of which are composed of different kinds of high-polymer components. The separation functional fibers and the ion-exchange fibers are useful in various applications such as the production of pure water in electric power, nuclear, electronic and pharmaceutical industries and the demineralization of high-salt content solutions in the production of foods and chemicals. The fibers are also useful in removing harmful components from gases, as well as odorous components such as ammonia.
    Type: Grant
    Filed: February 21, 1997
    Date of Patent: July 21, 1998
    Assignees: Ebara Corporation, Japan Atomic Energy Research Institute
    Inventors: Takanobu Sugo, Toshihiko Yamada, Hiroyuki Shima, Kunio Fujiwara
  • Patent number: 5747597
    Abstract: The present invention provides a curable resin composition comprising: a polymer (A) containing a polymerizable unsaturated bonding group; and a polymerizable unsaturated monomer (B). Polymerizable unsaturated monomer (B) comprises as an essential component an oligoalkyl(C.sub.2 -C.sub.4)ether(n=2-15)-monoalkoxy(C.sub.1 -C.sub.18)-(meth)acrylate. This curable resin composition according to the present invention displays superior adherence, air-drying, water resistance, and storage stability properties in addition to a reduced odor.
    Type: Grant
    Filed: August 12, 1996
    Date of Patent: May 5, 1998
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Yukiko Fujita, Shinya Ueno, Yoko Kawasaki, Kumiko Fukakusa, Hidefumi Matsuya, Tomomasa Mitani, Akira Komori, Mika Matsumura
  • Patent number: 5728791
    Abstract: The present invention provides a polyvinyl graft-polymer having one structural unit having a glycidyloxy group represented by the following general formula (I) at side chains of the polyvinyl polymer per 2-1,000 repeating units of vinyl: ##STR1## wherein Ar represents an aromatic hydrocarbon group 6-23 in carbon number having at least one glycidyloxy group, and R represents hydrogen atom or methyl group, and its manufacturing method. The polyvinyl graft-polymer of the present invention is excellent not only in mechanical properties and heat resistance, but also in adhesiveness, paintability dyeability and antistatic property.
    Type: Grant
    Filed: November 14, 1995
    Date of Patent: March 17, 1998
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Kazuhiko Tamai, Kazuya Yonezawa
  • Patent number: 5726249
    Abstract: In coating compositions based on a low molecular weight anhydride resin having pendant non-cyclic anhydride moieties, epoxy resin containing glycidyl methacrylate and catalyst, the use of branched epoxy resin provides an improved balance of performance characteristics.
    Type: Grant
    Filed: January 3, 1997
    Date of Patent: March 10, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Robert John Barsotti, Christopher Scopazzi
  • Patent number: 5714296
    Abstract: A graft copolymer of recurring units of (C.sub.6 -C.sub.18)alkyl (meth)acrylate (A), vinylpyridine (B), glycidyl (meth) acrylate (C), and glycidyl (meth) acrylate units esterified with (meth)acrylic acid (D) onto which polymeric side chains of units of vinylpyridine, (C.sub.1 -C.sub.3)alkyl acrylate, and optionally (C.sub.1 -C.sub.3)alkyl methacrylate are grafted. The polymer is suitable as a binder for colorless, positively chargeable liquid toners, in particular in combination with a copolymer of (C.sub.6 -C.sub.18)alkyl (meth) acrylate and hydroxyalkyl (meth)acrylate as charge control agents. After fixing of the electrophotographically produced toner image, the toners give colorless resist masks or printing screens with a high resistance toward etching agents and solvents.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: February 3, 1998
    Assignee: Agfa-Gevaert AG
    Inventors: Raimund Josef Faust, Danuta Eva Allen
  • Patent number: 5710211
    Abstract: According to the present invention, there are provided a process for producing a vinyl alcohol polymer comprising reaction of a vinyl ester polymer (A) having an epoxy group with a compound (B) having a thiol or thioester group and hydrolysis thereof, said hydrolysis being conducted during or after said reaction; and a process for producing a vinyl alcohol polymer comprising reaction of a vinyl ester polymer (C) having a thiol or thioester group with a compound (D) having an epoxy group and hydrolysis thereof, said hydrolysis being conducted during or after said reaction. According to the present invention, it is possible to efficiently introduce into PVA various functional groups having excellent reactivity, crosslinkability, ionic interactivity, water-solubility, interfacial physical properties, low-temperature flexibility, etc., under relatively mild reaction conditions.
    Type: Grant
    Filed: July 19, 1996
    Date of Patent: January 20, 1998
    Assignee: Kuraray Co., Ltd.
    Inventors: Toshiaki Sato, Naoki Fujiwara, Atsushi Jikihara
  • Patent number: 5705559
    Abstract: Disclosed is a process for preparing crosslinked resin particles which comprises dispersing a resin having both a water-dispersible function and a self-crosslinkable function in one molecule in an aqueous medium and then three-dimensionally crosslinking.
    Type: Grant
    Filed: February 21, 1995
    Date of Patent: January 6, 1998
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Hiroyuki Sakamoto, Kenshiro Tobinaga, Yasuyuki Tsuchiya, Hisaichi Muramoto, Yusuke Ninomiya, Keizou Ishii, Shinichi Ishikura
  • Patent number: 5693716
    Abstract: The present invention provides amphipathic graft copolymers which comprises a hydrophobic polymer portion to which is grafted at least one amphipathic polymer portion containing pH independent ionic groups. The amphipathic graft copolymers can be prepared employing a procedure which comprises polymerizing at least two hydrophobic monomers, wherein at least one of the monomers is a graftable monomer, and at least one hydrophilic monomer, including at least one anionic and/or cationic pH independent ionic monomer, or a post reactive non-ionic monomer that can be converted to a pH independent ionic derivative, in a reaction medium and recovering the thus prepared amphipathic graft copolymer. Stable, substantially non-aqueous solution compositions of said amphipathic graft copolymer containing less than 15 percent by weight water are also provided.
    Type: Grant
    Filed: November 21, 1995
    Date of Patent: December 2, 1997
    Assignee: The Dow Chemical Company
    Inventors: Craig J. Bott, Dale M. Pickelman, Thomas E. Fisk
  • Patent number: 5677385
    Abstract: Disclosed are a photo-setting colored filter composition, a color filter, a process for the preparation thereof, a curable resin, and a curable resin composition. The photo-setting colored filter composition of the present invention has an excellent photo-curability, miscibility in the composition, and developability.The curable resin composition is excellent in stability of the composition, tackiness, developability, sensitivity, anti-strippability, and hydrolysis resistance compared to conventional curable resin compositions.
    Type: Grant
    Filed: January 14, 1997
    Date of Patent: October 14, 1997
    Assignee: Daicel Chemical Industries, Ltd.
    Inventors: Hiroto Miyake, Koichi Okumura, Toshio Endo
  • Patent number: 5674946
    Abstract: The invention relates to activated support materials which comprise epoxy-substituted poly(meth)acrylamides, characterized in that:a) the base support contains aliphatic hydroxyl groups,b) the covalently bonded polymers are bonded to the support via a terminal monomer unit,c) the polymers contain monomer units of the formula I,d) the monomer units are linearly linked, ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 independently of one another are H or CH.sub.3,R.sup.4 is H or alkyl having 1-5 carbon atomsandn is an integer between 1 and 5 and to the use thereof.
    Type: Grant
    Filed: April 3, 1996
    Date of Patent: October 7, 1997
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventor: Egbert Muller
  • Patent number: 5665827
    Abstract: The invention is a practical process for anionically synthesizing multiblock polymers containing a plurality of blocks formed from polar and/or non-polar monomers by using a cyclic organometallic compound initiator that comprises a divalent metal atom and an organic moiety contained in a ring, preferably a cycloorganomagnesium initiator. Activation of the ring metallic atom results in anionic polymerization of the monomers by addition into the initiator ring at the bonds between the metallic atom and its two adjacent carbon atoms, the metallic atom acting as a bridge between the two living ends of the propagating chain. The active chain ends can be coupled or terminated.
    Type: Grant
    Filed: November 7, 1996
    Date of Patent: September 9, 1997
    Assignee: Bridgestone Corporation
    Inventor: James E. Hall
  • Patent number: 5635565
    Abstract: A rubber-modified thermoplastic resin is obtained by polymerizing (b) an aromatic vinyl compound and (c) a vinyl cyanide compound in the presence of (a) a rubbery polymer, and in which the content of the component (a) is 50 to 85% by weight, the content of the component (b) is 5 to 48% by weight and the content of the component (c) is 2 to 45% by weight, and which resin has a Q value of 30.times.10.sup.-4 to 50.times.10.sup.-3 and a grafting degree of 5% by weight or more. A thermoplastic resin composition comprising the above rubber-modified thermoplastic resin and at least one other thermoplastic resin is prepared.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: June 3, 1997
    Assignee: Japan Synthetic Rubber Co., Ltd.
    Inventors: Hajime Miyajima, Tsugio Asakawa, Noriaki Ijuin, Hiroo Nakamura, Toshihiro Ogawa, Shinichi Kimura
  • Patent number: 5589541
    Abstract: A process for producing a modified propylene polymer comprising the steps of premixing a propylene polymer with a vinyl monomer and polymerizing the vinyl monomer by kneading the premix at a temperature of a melting point thereof or higher is described, wherein the propylene polymer is a particulate propylene polymer having a specific surface area of 0.1 m.sup.2 /g or more. A modified propylene polymer composition is also described, obtained by mixing (a) a particulate propylene polymer having a specific surface area of 0.1 m.sup.2 /g or more, (b) 5% by weight or more of a vinyl monomer mainly comprising an aromatic vinyl monomer based on the total weight of the vinyl monomer and the propylene polymer, and (c) a radical polymerization initiator, substantially impregnating the vinyl monomer and the radical polymerization initiator into the propylene polymer, and then polymerizing the vinyl monomer by melt-kneading.
    Type: Grant
    Filed: March 28, 1995
    Date of Patent: December 31, 1996
    Assignee: Dainippon Ink and Chemicals Inc.
    Inventors: Masafumi Kinoshita, Toshio Niwa, O. Shibata
  • Patent number: 5587433
    Abstract: A method for producing esters of hydroxy terminated polybutadiene, including the steps of: (a) providing an anhydride; (b) reacting a hydroxy terminated polybutadiene with the anhydride to form a carboxyl terminated polybutadiene derivative; (c) reacting the derivative with an epoxide. Also a curable composition, including: (a) an ester of hydroxy terminated polybutadiene; (b) a copolymerizable ethylenically unsaturated monomer; and (c) a drier.
    Type: Grant
    Filed: August 17, 1995
    Date of Patent: December 24, 1996
    Assignee: Sartomer Company, Inc.
    Inventor: Rudolph H. Boeckeler
  • Patent number: 5578683
    Abstract: There is provided a pressure-sensitive adhesive graft copolymer formed of an acrylic backbone comprising at least one alkyl acrylate ester containing from about 4 to about 8 carbon atoms in the alkyl group having pendant therefrom side chains having a molecular weight of from about 1,000 to about 25,000, a glass transition temperature of greater than about 25.degree. C. and having crosslinkable reactive moieties.
    Type: Grant
    Filed: June 27, 1994
    Date of Patent: November 26, 1996
    Assignee: Avery Dennison Corporation
    Inventors: Carol A. Koch, Prakash Mallya, Colin C. Smith
  • Patent number: 5576394
    Abstract: The present invention provides a functional group-containing alkyl acrylate-butadiene-aromatic vinyl compound copolymer which is obtained from the following layers by emulsion graftlinking polymerization: an inner layer comprising polybutadiene or an aromatic vinyl compound-butadiene copolymer; a middle layer comprising an aromatic vinyl compound--an alkyl acrylate copolymer; and an outer layer comprising an alkyl acrylate--a functional group-containing vinyl compound copolymer. The functional group-containing alkyl acrylate-butadiene-aromatic vinyl compound copolymer can be incorporated into a PC/PBT alloy as an impact modifier, thus the impact strength of the modified alloy composition at room temperature and low temperatures can be increased effectively.
    Type: Grant
    Filed: June 27, 1995
    Date of Patent: November 19, 1996
    Assignee: Industrial Technology Research Institute
    Inventors: Cheng-Lung Chao, Juh-Shyong Lee, Feng-Chih Chang
  • Patent number: 5574111
    Abstract: Crystalline propylene (co)polymers modified by grafting with a vinylpolybutadiene having 1,2-structure content of at least 10%.Said (co)polymers are reacted with a liquid vinylpolybutadiene in the presence of a non-peroxidic radical initiator at a temperature in the range 200.degree. to 350.degree. C., the liquid vinylpolybutadiene having a 1.2-structure content of at least 10% and being generally used in amounts within the range 0,5 to 20% by weight.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: November 12, 1996
    Assignee: Centro Sviluppo Settori Impiego S.r.l.
    Inventors: Corrado Brichta, Francesco Mascia, Amodio Di Somma, Gabriele Torregiani, Antonio Addeo
  • Patent number: 5561196
    Abstract: This invention relates to grafted polypropylene compositions and a process for their production. More particularly, the invention relates to polypropylene compositions based on polypropylene homopolymers, and copolymers of propylene with ethylene and/or butadiene, grafted with certain epoxy-alkyl acrylate compounds, and a process for their production. The grafted polypropylene compositions are useful especially as compatibilizers for addition to other polymer compositions.
    Type: Grant
    Filed: July 13, 1995
    Date of Patent: October 1, 1996
    Assignee: Den norske stats oljeselskap a.s.
    Inventors: Hans K. Kotlar, Per M. Hansen
  • Patent number: 5547999
    Abstract: A reactive microgel suitable for a photosensitive resin composition for a water-developable flexographic printing plate, which has an average particle diameter to 10 .mu.m, and is formed ofmicrogel particles, as a core, synthesized from an acrylic monomer in an aqueous medium in the presence of an oil-soluble initiator and in the presence of a reactive polymer emulsifier which is an adduct of a neutralized product of an acrylic copolymer having a tertiary amino group with a compound having an epoxy group and an .alpha., .beta.-unsaturated double bond, and a nonionic emulsifier having an HLB of 12 to 16, anda compound having an epoxy group and an .alpha., .beta.-unsaturated double bond, attached to surfaces of the microgel particles.
    Type: Grant
    Filed: May 9, 1995
    Date of Patent: August 20, 1996
    Assignee: Toyolink Manufacturing Co., Ltd.
    Inventors: Sunao Satake, Yoshimi Yatsuyanagi, Masahiro Fujii, Ippei Imagawa
  • Patent number: 5545694
    Abstract: A reactive microgel suitable for a photosensitive resin composition for a water-developable flexographic printing plate, which has an average particle diameter of 1 to 10 .mu.m, and is formed ofmicrogel particles, as a core, synthesized from an acrylic monomer in an aqueous medium in the presence of an oil-soluble initiator and in the presence of a reactive polymer emulsifier which is an adduct of a neutralized product of an acrylic copolymer having a tertiary amino group with a compound having an epoxy group and an .alpha.,.beta.-unsaturated double bond, and a nonionic emulsifier having an HLB of 12 to 16, anda compound having an epoxy group and an .alpha.,.beta.-unsaturated double bond, attached to surfaces of the microgel particles.
    Type: Grant
    Filed: February 9, 1995
    Date of Patent: August 13, 1996
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Sunao Satake, Yoshimi Yatsuyanagi, Masahiro Fujii, Ippei Imagawa
  • Patent number: 5541262
    Abstract: Crystalline propylene (co)polymers modified by grafting with a vinylpolybutadiene having 1,2-structure content of at least l0%.The (co)polymers are reacted with a liquid vinylpolybutadiene in the presence of a non-peroxidic radical initiator at a temperature in the range 200.degree. to 350.degree. C., the liquid vinylpolybutadiene having a 1,2-structure content of at least 10% and being generally used in amounts within the range 0.5 to 20% by weight.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: July 30, 1996
    Assignee: Centro Sviluppo Settori Impiego S.r.l.
    Inventors: Corrado Brichta, Francesco Mascia, Amodio Di Somma, Gabriele Torregiani, Antonio Addeo
  • Patent number: 5536775
    Abstract: Amine curable compositions containing a partially acrylated epoxy resin useful for forming protective and/or decorative coatings on a variety of substrates, particularly flooring substrates.
    Type: Grant
    Filed: November 4, 1994
    Date of Patent: July 16, 1996
    Assignee: Sandoz Ltd.
    Inventors: Benedict S. Curatolo, Frank V. Apicella, Jr., Thomas W. Richardson, Sr.
  • Patent number: 5527859
    Abstract: Copolymers crosslinkable by a free radical method are prepared by polymer-analogous reaction ofA) a copolymer (A) which is composed ofa1) from 20 to 85 mol % of a monomer (a1) having the structural element of methacrylic acid anda2) from 15 to 80 mol % of another monomer (a2) which undergoes free radical polymerization,a3) from 5 to 50 mol % of the total amount of the monomers (a1) and (a2) being monomers (a3) which carry functional groups and whose functional groups are capable of undergoing a condensation or addition reaction,withB) an olefinically unsaturated monomer (B) which carries a functional group which is complementary to that of the monomers (a3),by a process in which the polymer-analogous reaction is carried out at from 90.degree. to 150.degree. C. in an average residence time of from 3 to 20 minutes in highly concentrated solution or in the absence of a solvent. Said copolymers are used as binders for powder coatings.
    Type: Grant
    Filed: August 2, 1995
    Date of Patent: June 18, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Fritz E. Kempter, Wolfgang Reich, Jurgen Hofmann
  • Patent number: 5514754
    Abstract: A method of enhancing the water absorbance of and increasing the particle size of fine water absorbent cross-linked polyacrylic polymer particles includes impregnating the polymer particles with an impregnating monomer solution containing an acrylic monomer, with or without a cross-linking agent for the acrylic monomer. The solution is impregnated into the resin in a weight ratio of cross-linked polyacrylic polymer, dry basis, to impregnating monomer solution in the range of about 1:1 to about 1:10; and subjecting the impregnated polymer to conditions, such as increased temperature, e.g., 100.degree. C.-150.degree. C. to polymerize the impregnated monomer, within the cross-linked polymer particles, to form a cross-linked polyacrylic polymer having enhanced water absorbance and increased particle size.
    Type: Grant
    Filed: September 28, 1994
    Date of Patent: May 7, 1996
    Assignee: American Colloid Company
    Inventors: John A. Henderson, Anthony S. Tomlin, David M. Lucas
  • Patent number: 5502113
    Abstract: A pigment dispersion useful for forming aqueous coating compositions containing metallic flake pigment, an aqueous carrier and a graft copolymer dispersant (binder);wherein the graft copolymer has a weight average molecular weight of about 5,000-100,000 and comprises a polymeric backbone and macromonomer side chains attached to the backbone wherein(1) the polymeric backbone is formed of polymerized ethylenically unsaturated monomers and(2) the side chains are macromonomers that are attached to the backbone at a single terminal point and formed from polymerized ethylenically unsaturated monomers that are polymerized in the presence of a cobalt chain transfer agent have a weight average molecular weight of about 1,000-30,000;wherein the graft copolymer contains about 2 to 70% by weight, based on the weight of the graft copolymer, of polymerized constituents having a phosphate moiety and phosphoric acid moieties that are polymerized into the backbone, the side chains or both and the polymer is neutralized with a
    Type: Grant
    Filed: August 22, 1994
    Date of Patent: March 26, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Joseph A. Antonelli, Lee A. E. Becton, Brian P. Devlin, Christopher Scopazzi
  • Patent number: 5496896
    Abstract: The invention relates to a curable composition containing as component A) compounds with at least two activated double bonds (I), these being .alpha.,.beta.-unsaturated carbonyl compounds, .alpha.,.beta.-unsaturated carboxylic acid esters or .alpha.,.beta.-unsaturated nitriles, and compounds B) which contain at least two active hydrogen atoms or at least two groups with active hydrogen atoms or at least one active hydrogen atom and at least one group with an active hydrogen atom, and customary additives, catalysts, if appropriate pigments and an organic solvent. Either component A) or B) or components A) and B) are based on a branched soluble acrylate copolymer (P) which is obtainable by copolymerization ofa) 3 to 30% by weight of monomers with at least two ethylenically unsaturated polymerizable double bonds,b) 5 to 60% by weight of monomers with a functional group andc) 5 to 92% by weight of other ethylenically unsaturated monomers,the sum of a), b) and c) being 100% by weight.
    Type: Grant
    Filed: April 1, 1993
    Date of Patent: March 5, 1996
    Assignee: BASF Lacke & Farben Aktiengesellschaft
    Inventor: Jung W. Alfons
  • Patent number: 5484850
    Abstract: Copolymers crosslinkable by a free radical method and having a number average molecular weight of from 1500 to 6000 and a molecular weight distribution corresponding to a polydispersity of from 1 to 4.0 are obtainable by polymer-analogous reaction ofA) a copolymer (A) which is composed ofa1) from 50 to 85 mol % of a monomer (a1) containing the structural element of methacrylic acid anda2) from 15 to 50 mol % of another monomer (a2) undergoing free radical polymerization,a3) from 5 to 50 mol % of the total amount of the monomers (a1) and (a2) being monomers (a3) which carry functional groups and whose functional groups are capable of undergoing a condensation or addition reaction,and is obtainable by free radical mass or solution polymerization at from 140.degree. to 210.degree. C. and with an average residence time of from 2 to 90 minuteswithB) an olefinically unsaturated monomer (B) which carries a functional group which is complementary to the functional groups of the monomers (a3).
    Type: Grant
    Filed: October 28, 1994
    Date of Patent: January 16, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Fritz E. Kempter, Wolfgang Reich, Ulrich Jager, Eckhard Korona
  • Patent number: 5483005
    Abstract: A process for preparing (meth)acrylate polymers with lateral non-linear optical chromophores and molecular weights of from 5000 to 500,000, comprises reacting polymers of (meth)acryloyl isocyanate in solution with D-.omega.-hydroxyalkyl chromophores of the formula (I) ##STR1## where D is an electron donor,A is an electron acceptor,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 can be identical or different and are each H, alkyl, cycloalkyl, alkoxy or R.sup.3 and R.sup.4 are each CN, NO.sub.2 or CHO or R.sup.1 and R.sup.2, or R.sup.3 and R.sup.4, together form a fused-on ring,X is CH and/or Nandm is an integer from 2 to 11.The products are suitable for optical components in communications technology.
    Type: Grant
    Filed: November 4, 1993
    Date of Patent: January 9, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Stefan Beckmann
  • Patent number: 5457158
    Abstract: A process is described for preparing blends of fluorocarbon plastomers such as vinylidene fluoride polymers with fluorosilicone elastomers to obtain materials having a unique combination of flexibility at low temperature and high mechanical strength. Vinylidene fluoride polymer is first exposed to radiation and then mixed with the fluorosilicone. Coagents such as diallylphtalate and triallylisocyanurate are also used to assist in grafting and compatibilizing the two polymers.
    Type: Grant
    Filed: July 11, 1994
    Date of Patent: October 10, 1995
    Assignee: Dow Corning Corporation
    Inventors: Gerardo Caporiccio, Liberato Mascia
  • Patent number: 5436297
    Abstract: A modified polyolefin comprising: (A) 100 parts by weight of a polyolefin; (B) 0.01 to 20 parts by weight of a monomer mixture consisting of: (b-1) 5 to 50% by mole of glycidyl acrylate, glycidyl methacrylate or an unsaturated glycidyl compound represented by general formula (I) below ##STR1## wherein R is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; Ar is an aromatic hydrocarbon group having 6 to 20 carbon atoms and having at least one glycidyl group; and n is an integer of 1 to 4, and (b-2) 95 to 50% by mole of at least one monomer selected from the group consisting of acrylamide monomers, vinylpyrrolidones, acrylic acid esters and methacrylic acid esters, the monomer mixture being graft-copolymerized with the polyolefin.
    Type: Grant
    Filed: October 27, 1993
    Date of Patent: July 25, 1995
    Assignee: Tonen Corporation
    Inventors: Tatsuo Teraya, Shintaro Kikuchi, Kouichi Yokoyama, Yuji Fujita
  • Patent number: 5426009
    Abstract: The invention relates to a polymeric composite material which:is based on a liquid crystal polymer component,exhibits a high glass transition temperature of at least 60.degree. C. and a scattering texture when deposited as a thin film,can be rendered transparent by being heated above the glass transition temperature and/or clearing temperature, andis obtained by mixing a liquid crystal polymer component, a reactive liquid crystalline component, optionally a polymerization initiator component, and/or further additive components, with subsequent polymerization.
    Type: Grant
    Filed: September 17, 1993
    Date of Patent: June 20, 1995
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: David Coates, Mark Verrall, Emma J. Brown
  • Patent number: 5424369
    Abstract: A self-crosslinking resin comprising a resin containing a blocked isocyanate group, and a resin containing a hydroxyl group, and a tertiary amino group and/or a quaternary ammonium group and attached to the resin by a urethane bond.The self-crosslinking resins are useful for adhesive compositions and coating compositions of the aqueous type.
    Type: Grant
    Filed: June 17, 1992
    Date of Patent: June 13, 1995
    Assignee: Kansai Paint Company, Limited
    Inventors: Yoshiyuki Yukawa, Motoshi Yabuta, Yasushi Nakao
  • Patent number: 5424366
    Abstract: Multi-functional viscosity index improvers for lubricating oils containing an EPM or EPDM polymer onto which has been grafted an unsaturated functional monomer containing phenothiazine.
    Type: Grant
    Filed: June 1, 1994
    Date of Patent: June 13, 1995
    Assignee: Texaco Inc.
    Inventors: Maria M. Kapuscinski, Theodore E. Nalesnik, Robert T. Biggs, Benjamin J. Kaufman
  • Patent number: 5422394
    Abstract: A water-based autoxidizable coating composition for application to architectural surfaces, fittings or furnishings at ambient temperatures which contains water, a drier to promote autoxidation and a water-soluble autoxidizable film-forming copolymer which contains 0.5 to 7 wt % of acrylic acid, 50 to 50 wt % of either a hydroxy acrylate chosen from hydroxy ethyl or hydroxyisopropyl acrylate or alternatively a polyethoxylate (meth)acrylate and 30 to 50 wt % of an autoxidizable ester of copolymerized acrylic acid in which the esterifying moieties are 3-allyloxy-2-hydroxypropyl or the methallyl analogue. Also an autoxidizable copolymer of the above composition. The coating composition laps well yet is water-soluble and resistant to both long term and short term damage by water. Also the copolymer for use in the compositions.
    Type: Grant
    Filed: November 29, 1993
    Date of Patent: June 6, 1995
    Assignee: Imperial Chemical Industries PLC
    Inventors: Philip L. Taylor, Peter G. Osborn
  • Patent number: 5420199
    Abstract: A thermoplastic resin composition consisting essentially of (a) 50 to 90 % by weight of polybutylene terephthalate (component A), (b) 5 to 40 % by weight of modified polyolefin modified by an unsaturated monomer having a glycidyloxy group and an unsaturated monomer having a carboxyl group or an acid anhydride group (component B), (c) 5 to 40 % by weight of polycarbonate (component C); and molded articles prepared from the above thermoplastic resin composition.The thermoplastic resin composition of the invention can give molded articles having excellent toughness, rigidity, strength and dimensional stability.
    Type: Grant
    Filed: February 28, 1994
    Date of Patent: May 30, 1995
    Assignee: Teijin Limited
    Inventor: Hiroki Fujie
  • Patent number: 5409776
    Abstract: A multi-shell emulsion particle of dry state structure having one or more of penetrating pore(s) connecting the surface layer of the particle with the interior of the particle and having a particle diameter of from 0.1 to 5.0.mu. preferably from 0.1 to 1.2.mu..
    Type: Grant
    Filed: February 1, 1994
    Date of Patent: April 25, 1995
    Assignee: Mitsui Tomatsu Chemicals, Incorporated
    Inventors: Kousuke Someya, Akihiro Yamazaki, Futoshi Hoshino, Takeshi Yanagihara
  • Patent number: 5391631
    Abstract: A vinyl polymer is obtainable by polymerizing vinyl monomers in at least two stages by a procedure in which, in a first stage, from 5 to 95% by weight of vinyl monomers are polymerized in an organic solvent or in the absence of a solvent and, in the second stage, from 5 to 95% by weight of the vinyl monomers are polymerized in the presence of the vinyl polymer obtained in the first stage, likewise in an organic solvent or in the absence of a solvent, with the proviso that the polymerization in the second stage is carried out under conditions under which an average molecular weight M.sub.n, which is at least 1,000 higher compared with that of the vinyl polymer, the first stage of results for the vinyl monomers of the second stage in the absence of the vinyl polymer obtained in the first stage.
    Type: Grant
    Filed: May 27, 1993
    Date of Patent: February 21, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Bettina Porsch, Hans Renz
  • Patent number: 5385974
    Abstract: A novel graft copolymer having a number-average molecular weight of about 1,500 to about 1,000,000, produced by graft-copolymerizing an alkylene oxide and a cyclic ester to a saponified ethylene-saturated carboxylic acid vinyl ester copolymer; a process for production thereof; and a plasticizer comprising said graft copolymer as the active component.
    Type: Grant
    Filed: July 15, 1993
    Date of Patent: January 31, 1995
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Tadayuki Ohmae, Hisao Tanaka, Sumio Hara
  • Patent number: 5382634
    Abstract: The object of the present invention is to provide such a polyolefin that only the terminal of polypropylene or ethylene-propylene random copolymer is modified with a (meth)acrylic derivative unit to give a substantially monodipersed system. The feature thereof consists in such a polyolefin that the terminal of polypropylene or ethylene-propylene random copolymer obtained by living polymerization is modified with a (meth)acrylic derivative unit. As the (meth)acrylic derivative, there are used vinyl methacrylate, allyl methacrylate, trimethylsiloxyethyl methacrylate, 2-trimethylsiloxypropyl methacrylate, N, N-dimethylaminoethyl methacrylate, N,N-diethylaminoethyl methacrylate, glycidyl methacrylate, acrylic acid chloride and like.
    Type: Grant
    Filed: April 25, 1994
    Date of Patent: January 17, 1995
    Assignee: Tonen Corporation
    Inventors: Naomi Koyama, Miyuki Usui, Hiroyuki Furuhashi, Satoshi Ueki
  • Patent number: 5374364
    Abstract: Multifunctional viscosity index improvers for lubricating oils containing an EPM or EPDM polymer with pendant thiazoline units.
    Type: Grant
    Filed: September 3, 1993
    Date of Patent: December 20, 1994
    Assignee: Texaco Inc.
    Inventors: Maria M. Kapuscinski, Nicholas Benfaremo, Robert T. Biggs
  • Patent number: 5362804
    Abstract: An unsaturated polyester resin composition for the production of cured molded article which comprises:an unsaturated polyester resin; anda core-shell polymer as a low shrinking agent which comprises:(a) a cross-linked core layer polymerized from a first monomer comprising an aromatic vinyl monomer in an amount of not less 50% by weight, the core layer being contained in the core-shell polymer in an amount of 50-90% by weight; and(b) a shell layer polymerized from a monomer comprising methyl methacrylate in an amount of not less 50% by weight;and the core-shell polymer having a refractive index in the range of 1.52-1.58 and within .+-.0.02 from the refractive index of the cured material of the unsaturated polyester resin.
    Type: Grant
    Filed: February 24, 1993
    Date of Patent: November 8, 1994
    Assignee: Takeda Chemical Industries, Ltd.
    Inventors: Junji Oshima, Susumu Okatani, Koichi Akiyama, Masato Sakurai
  • Patent number: 5362813
    Abstract: A polymer dispersion of a star polymer dispersed in an organic liquid; wherein the star polymer has a crosslinked core having attached thereto at least three macrononomer arms; where(1) the core is formed of monomers having at least two ethylenically unsaturated double bonds which are crosslinked with each other and the core has at least 3 free radical polymerizable sites each of which are reacted with the macromonomer; and(2) the macromonomer that forms the arms of the star polymer is formed of ethylenically unsaturated monomers that have been polymerized by free radical polymerization in the presence of a free radical polymerization initiator and a catalytic chain transfer agent containing CO.sup.+2 to provide the macromonomer with a terminal ethylenically unsaturated group that is polymerized with the free radical polymerizable site on the core to form the star polymer. The process for making the star polymer and coating compositions that utilize the star polymer are also part of this invention.
    Type: Grant
    Filed: December 22, 1993
    Date of Patent: November 8, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Joseph A. Antonelli, Christopher Scopazzi
  • Patent number: 5356999
    Abstract: Multifunctional viscosity index improvers for lubricating oils containing an EPM or EPDM polymer onto which has been grafted an unsaturated reactive monomer and thereafter reacted with amines containing sulfonamide units.
    Type: Grant
    Filed: October 29, 1990
    Date of Patent: October 18, 1994
    Assignee: Texaco Inc.
    Inventors: Maria M. Kapuscinski, Benjamin J. Kaufman, Robert T. Biggs
  • Patent number: 5346953
    Abstract: Core-shell ABS copolymers having an SAN shell completely surrounding the diene core are provided by melt blending an aliphatic diene polymer with an SAN copolymer, said copolymer containing functional groups capable of reacting with the diene polymer. For example, the SAN copolymer may contain azide groups capable of reacting with the olefinic groups in the diene polymer, or both the SAN copolymer and the diene polymer may contain other functional groups capable of interreaction, such as acidic (e.g., maleic anhydride) groups in the diene and epoxy (e.g., glycidyl methacrylate) groups in the SAN copolymer.
    Type: Grant
    Filed: October 7, 1993
    Date of Patent: September 13, 1994
    Assignee: General Electric Company
    Inventors: James J. Scobbo, Jr., Gregory J. Stoddard