Three-membered Ring Containing Two Carbon And One Chalcogen Atom Patents (Class 525/286)
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Patent number: 6001488Abstract: A resin composition comprising an epoxy group-containing cycloolefin resin and a crosslinking agent is provided. More specifically, a resin composition comprising an epoxy group-containing thermoplastic norbornene resin obtained by introducing epoxy groups into a thermoplastic norbornene resin, and as the crosslinking agent, a curing agent for epoxy resins or a photoreactive substance is provided. The resin composition is suitable for use as an insulating material.Type: GrantFiled: June 29, 1998Date of Patent: December 14, 1999Assignees: Nippon Zeon Co., Ltd., Fujitsu LimitedInventors: Hideaki Kataoka, Eiko Yuda, Shigemitsu Kamiya, Masahide Yamamoto, Yoshikatsu Ishizuki, Yasuhiro Yoneda, Daisuke Mizutani, Kishio Yokouchi
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Patent number: 5981665Abstract: A thermoplastic elastomer is achieved by absorbing an acrylate monomer, an initiator and eventually a diacrylate into polyolefin particles, after which the temperature is raised and the acrylate polymerises into the polyolefin and forms a dispersed phase, which has been functionalized by copolymerising a functional monomer together with the acrylate. As a compatibiliser a grafter polyolefin is used, which is melt-blended after the polymerisation into the thermoplastic elastomer or before the polymerisation into the polyolefin.Type: GrantFiled: August 20, 1997Date of Patent: November 9, 1999Assignee: Optatech CorporationInventors: Torvald Vestberg, Viveca Lonnberg, Tommi Vainio, Kalle Hanhi, Harri Jukarainen
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Patent number: 5912301Abstract: A graft-modified polyolefin resin is provided, which is obtained by preparing a aqueous suspension containing (a1) 100 parts by weight of a polyolefin resin, (a2) 0.1 to 30 parts by weight of a mixture of 1 to 1000 parts by weight of an unsaturated glycidyl ester to 100 parts by weight of a compound having a glycidyl group as represented by a general formula (I): ##STR1## wherein Ar is an aromatic hydrocarbon group of C.sub.6 -C.sub.23 having at least one glycidyloxy group, and R is a hydrogen atom or a methyl group, (a3) 0.1 to 500 parts by weight of a vinyl monomer, and (a4) 0.001 to 10 parts by weight of a radical initiator to 100 parts by weight in total of (a2) and (a3), to thus impregnate (a1) with (a2) and (a3), and polymerizing (a2) and (a3) onto (a1). Resin compositions containig the graft-modified polyolefin resin have not only well-balanced mechanical properties, but excellent moldability.Type: GrantFiled: August 22, 1997Date of Patent: June 15, 1999Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Kazuhiko Tamai, Shinji Ozawa, Kenji Kurimoto, Haruo Tomita
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Patent number: 5895800Abstract: A resin composition comprising an epoxy group-containing cycloolefin resin and a crosslinking agent is provided. More specifically, a resin composition comprising an epoxy group-containing thermoplastic norbornene resin obtained by introducing epoxy groups into a thermoplastic norbornene resin, and as the crosslinking agent, a curing agent for epoxy resins or a photoreactive substance is provided. The resin composition is suitable for use as an insulating material.Type: GrantFiled: June 29, 1998Date of Patent: April 20, 1999Assignees: Nippon Zeon Co., Ltd., Fujitsu LimitedInventors: Hideaki Kataoka, Eiko Yuda, Shigemitsu Kamiya, Masahide Yamamoto, Yoshikatsu Ishizuki, Yasuhiro Yoneda, Daisuke Mizutani, Kishio Yokouchi
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Patent number: 5886101Abstract: A novel class of interpenetrating polymer networks which are dispersible in conventional coating solvents is disclosed. Such dispersions are useful in preparing protective and/or decorative film coatings and are particularly useful in photosensitive or imaging formulations such as photoresists, solder masks and the like. These polymer networks are comprised of at least two interpenetrating crosslinked polymers. At least one of the polymer networks is formed by polymerization in a solvent. In one embodiment of this invention, at least one polymer network is prepared from macromers to produce a polymer system having functionalized branch or graft linear segments. The solvent dispersible interpenetrating networks of this invention are particularly useful as binders in addition polymerizable photosensitive compositions containing crosslinking monomers such as solder masks. Upon exposure to actinic radiation and suitable thermal curing, solder mask coatings of such photosensitive compositions form multiple, e.g.Type: GrantFiled: April 7, 1993Date of Patent: March 23, 1999Assignee: E. I. du Pont de Nemours and CompanyInventors: Eugene G. Sommerfeld, Frank L Schadt, III
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Patent number: 5783639Abstract: A resin composition comprising an epoxy group-containing cycloolefin resin and a crosslinking agent is provided. More specifically, a resin composition comprising an epoxy group-containing thermoplastic norbornene resin obtained by introducing epoxy groups into a thermoplastic norbornene resin, and as the crosslinking agent, a curing agent for epoxy resins or a photoreactive substance is provided. The resin composition is suitable for use as an insulating material.Type: GrantFiled: January 13, 1997Date of Patent: July 21, 1998Assignees: Nipon Zeon Co., Ltd., Fujitsu LimitedInventors: Hideaki Kataoka, Eiko Yuda, Shigemitsu Kamiya, Masahide Yamamoto, Yoshikatsu Ishizuki, Yasuhiro Yoneda, Daisuke Mizutani, Kishio Yokouchi
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Patent number: 5783608Abstract: Separation functional fibers are produced by exposing fibers with a core/sheath structure to an ionizing radiation and then grafting a polymerizable monomer to the fibers. Ion-exchange fibers are produced by introducing, through radiation-initiated graft polymerization, ion-exchange groups into the sheath of each of composite fibers the core and the sheath of which are composed of different kinds of high-polymer components. The separation functional fibers and the ion-exchange fibers are useful in various applications such as the production of pure water in electric power, nuclear, electronic and pharmaceutical industries and the demineralization of high-salt content solutions in the production of foods and chemicals. The fibers are also useful in removing harmful components from gases, as well as odorous components such as ammonia.Type: GrantFiled: February 21, 1997Date of Patent: July 21, 1998Assignees: Ebara Corporation, Japan Atomic Energy Research InstituteInventors: Takanobu Sugo, Toshihiko Yamada, Hiroyuki Shima, Kunio Fujiwara
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Patent number: 5747597Abstract: The present invention provides a curable resin composition comprising: a polymer (A) containing a polymerizable unsaturated bonding group; and a polymerizable unsaturated monomer (B). Polymerizable unsaturated monomer (B) comprises as an essential component an oligoalkyl(C.sub.2 -C.sub.4)ether(n=2-15)-monoalkoxy(C.sub.1 -C.sub.18)-(meth)acrylate. This curable resin composition according to the present invention displays superior adherence, air-drying, water resistance, and storage stability properties in addition to a reduced odor.Type: GrantFiled: August 12, 1996Date of Patent: May 5, 1998Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Yukiko Fujita, Shinya Ueno, Yoko Kawasaki, Kumiko Fukakusa, Hidefumi Matsuya, Tomomasa Mitani, Akira Komori, Mika Matsumura
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Patent number: 5728791Abstract: The present invention provides a polyvinyl graft-polymer having one structural unit having a glycidyloxy group represented by the following general formula (I) at side chains of the polyvinyl polymer per 2-1,000 repeating units of vinyl: ##STR1## wherein Ar represents an aromatic hydrocarbon group 6-23 in carbon number having at least one glycidyloxy group, and R represents hydrogen atom or methyl group, and its manufacturing method. The polyvinyl graft-polymer of the present invention is excellent not only in mechanical properties and heat resistance, but also in adhesiveness, paintability dyeability and antistatic property.Type: GrantFiled: November 14, 1995Date of Patent: March 17, 1998Assignee: Kanegafuchi Kagaku Kogyo Kabushiki KaishaInventors: Kazuhiko Tamai, Kazuya Yonezawa
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Patent number: 5726249Abstract: In coating compositions based on a low molecular weight anhydride resin having pendant non-cyclic anhydride moieties, epoxy resin containing glycidyl methacrylate and catalyst, the use of branched epoxy resin provides an improved balance of performance characteristics.Type: GrantFiled: January 3, 1997Date of Patent: March 10, 1998Assignee: E. I. du Pont de Nemours and CompanyInventors: Robert John Barsotti, Christopher Scopazzi
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Patent number: 5714296Abstract: A graft copolymer of recurring units of (C.sub.6 -C.sub.18)alkyl (meth)acrylate (A), vinylpyridine (B), glycidyl (meth) acrylate (C), and glycidyl (meth) acrylate units esterified with (meth)acrylic acid (D) onto which polymeric side chains of units of vinylpyridine, (C.sub.1 -C.sub.3)alkyl acrylate, and optionally (C.sub.1 -C.sub.3)alkyl methacrylate are grafted. The polymer is suitable as a binder for colorless, positively chargeable liquid toners, in particular in combination with a copolymer of (C.sub.6 -C.sub.18)alkyl (meth) acrylate and hydroxyalkyl (meth)acrylate as charge control agents. After fixing of the electrophotographically produced toner image, the toners give colorless resist masks or printing screens with a high resistance toward etching agents and solvents.Type: GrantFiled: December 27, 1995Date of Patent: February 3, 1998Assignee: Agfa-Gevaert AGInventors: Raimund Josef Faust, Danuta Eva Allen
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Patent number: 5710211Abstract: According to the present invention, there are provided a process for producing a vinyl alcohol polymer comprising reaction of a vinyl ester polymer (A) having an epoxy group with a compound (B) having a thiol or thioester group and hydrolysis thereof, said hydrolysis being conducted during or after said reaction; and a process for producing a vinyl alcohol polymer comprising reaction of a vinyl ester polymer (C) having a thiol or thioester group with a compound (D) having an epoxy group and hydrolysis thereof, said hydrolysis being conducted during or after said reaction. According to the present invention, it is possible to efficiently introduce into PVA various functional groups having excellent reactivity, crosslinkability, ionic interactivity, water-solubility, interfacial physical properties, low-temperature flexibility, etc., under relatively mild reaction conditions.Type: GrantFiled: July 19, 1996Date of Patent: January 20, 1998Assignee: Kuraray Co., Ltd.Inventors: Toshiaki Sato, Naoki Fujiwara, Atsushi Jikihara
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Patent number: 5705559Abstract: Disclosed is a process for preparing crosslinked resin particles which comprises dispersing a resin having both a water-dispersible function and a self-crosslinkable function in one molecule in an aqueous medium and then three-dimensionally crosslinking.Type: GrantFiled: February 21, 1995Date of Patent: January 6, 1998Assignee: Nippon Paint Co., Ltd.Inventors: Hiroyuki Sakamoto, Kenshiro Tobinaga, Yasuyuki Tsuchiya, Hisaichi Muramoto, Yusuke Ninomiya, Keizou Ishii, Shinichi Ishikura
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Patent number: 5693716Abstract: The present invention provides amphipathic graft copolymers which comprises a hydrophobic polymer portion to which is grafted at least one amphipathic polymer portion containing pH independent ionic groups. The amphipathic graft copolymers can be prepared employing a procedure which comprises polymerizing at least two hydrophobic monomers, wherein at least one of the monomers is a graftable monomer, and at least one hydrophilic monomer, including at least one anionic and/or cationic pH independent ionic monomer, or a post reactive non-ionic monomer that can be converted to a pH independent ionic derivative, in a reaction medium and recovering the thus prepared amphipathic graft copolymer. Stable, substantially non-aqueous solution compositions of said amphipathic graft copolymer containing less than 15 percent by weight water are also provided.Type: GrantFiled: November 21, 1995Date of Patent: December 2, 1997Assignee: The Dow Chemical CompanyInventors: Craig J. Bott, Dale M. Pickelman, Thomas E. Fisk
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Patent number: 5677385Abstract: Disclosed are a photo-setting colored filter composition, a color filter, a process for the preparation thereof, a curable resin, and a curable resin composition. The photo-setting colored filter composition of the present invention has an excellent photo-curability, miscibility in the composition, and developability.The curable resin composition is excellent in stability of the composition, tackiness, developability, sensitivity, anti-strippability, and hydrolysis resistance compared to conventional curable resin compositions.Type: GrantFiled: January 14, 1997Date of Patent: October 14, 1997Assignee: Daicel Chemical Industries, Ltd.Inventors: Hiroto Miyake, Koichi Okumura, Toshio Endo
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Patent number: 5674946Abstract: The invention relates to activated support materials which comprise epoxy-substituted poly(meth)acrylamides, characterized in that:a) the base support contains aliphatic hydroxyl groups,b) the covalently bonded polymers are bonded to the support via a terminal monomer unit,c) the polymers contain monomer units of the formula I,d) the monomer units are linearly linked, ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 independently of one another are H or CH.sub.3,R.sup.4 is H or alkyl having 1-5 carbon atomsandn is an integer between 1 and 5 and to the use thereof.Type: GrantFiled: April 3, 1996Date of Patent: October 7, 1997Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventor: Egbert Muller
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Patent number: 5665827Abstract: The invention is a practical process for anionically synthesizing multiblock polymers containing a plurality of blocks formed from polar and/or non-polar monomers by using a cyclic organometallic compound initiator that comprises a divalent metal atom and an organic moiety contained in a ring, preferably a cycloorganomagnesium initiator. Activation of the ring metallic atom results in anionic polymerization of the monomers by addition into the initiator ring at the bonds between the metallic atom and its two adjacent carbon atoms, the metallic atom acting as a bridge between the two living ends of the propagating chain. The active chain ends can be coupled or terminated.Type: GrantFiled: November 7, 1996Date of Patent: September 9, 1997Assignee: Bridgestone CorporationInventor: James E. Hall
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Patent number: 5635565Abstract: A rubber-modified thermoplastic resin is obtained by polymerizing (b) an aromatic vinyl compound and (c) a vinyl cyanide compound in the presence of (a) a rubbery polymer, and in which the content of the component (a) is 50 to 85% by weight, the content of the component (b) is 5 to 48% by weight and the content of the component (c) is 2 to 45% by weight, and which resin has a Q value of 30.times.10.sup.-4 to 50.times.10.sup.-3 and a grafting degree of 5% by weight or more. A thermoplastic resin composition comprising the above rubber-modified thermoplastic resin and at least one other thermoplastic resin is prepared.Type: GrantFiled: December 18, 1995Date of Patent: June 3, 1997Assignee: Japan Synthetic Rubber Co., Ltd.Inventors: Hajime Miyajima, Tsugio Asakawa, Noriaki Ijuin, Hiroo Nakamura, Toshihiro Ogawa, Shinichi Kimura
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Patent number: 5589541Abstract: A process for producing a modified propylene polymer comprising the steps of premixing a propylene polymer with a vinyl monomer and polymerizing the vinyl monomer by kneading the premix at a temperature of a melting point thereof or higher is described, wherein the propylene polymer is a particulate propylene polymer having a specific surface area of 0.1 m.sup.2 /g or more. A modified propylene polymer composition is also described, obtained by mixing (a) a particulate propylene polymer having a specific surface area of 0.1 m.sup.2 /g or more, (b) 5% by weight or more of a vinyl monomer mainly comprising an aromatic vinyl monomer based on the total weight of the vinyl monomer and the propylene polymer, and (c) a radical polymerization initiator, substantially impregnating the vinyl monomer and the radical polymerization initiator into the propylene polymer, and then polymerizing the vinyl monomer by melt-kneading.Type: GrantFiled: March 28, 1995Date of Patent: December 31, 1996Assignee: Dainippon Ink and Chemicals Inc.Inventors: Masafumi Kinoshita, Toshio Niwa, O. Shibata
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Patent number: 5587433Abstract: A method for producing esters of hydroxy terminated polybutadiene, including the steps of: (a) providing an anhydride; (b) reacting a hydroxy terminated polybutadiene with the anhydride to form a carboxyl terminated polybutadiene derivative; (c) reacting the derivative with an epoxide. Also a curable composition, including: (a) an ester of hydroxy terminated polybutadiene; (b) a copolymerizable ethylenically unsaturated monomer; and (c) a drier.Type: GrantFiled: August 17, 1995Date of Patent: December 24, 1996Assignee: Sartomer Company, Inc.Inventor: Rudolph H. Boeckeler
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Patent number: 5578683Abstract: There is provided a pressure-sensitive adhesive graft copolymer formed of an acrylic backbone comprising at least one alkyl acrylate ester containing from about 4 to about 8 carbon atoms in the alkyl group having pendant therefrom side chains having a molecular weight of from about 1,000 to about 25,000, a glass transition temperature of greater than about 25.degree. C. and having crosslinkable reactive moieties.Type: GrantFiled: June 27, 1994Date of Patent: November 26, 1996Assignee: Avery Dennison CorporationInventors: Carol A. Koch, Prakash Mallya, Colin C. Smith
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Patent number: 5576394Abstract: The present invention provides a functional group-containing alkyl acrylate-butadiene-aromatic vinyl compound copolymer which is obtained from the following layers by emulsion graftlinking polymerization: an inner layer comprising polybutadiene or an aromatic vinyl compound-butadiene copolymer; a middle layer comprising an aromatic vinyl compound--an alkyl acrylate copolymer; and an outer layer comprising an alkyl acrylate--a functional group-containing vinyl compound copolymer. The functional group-containing alkyl acrylate-butadiene-aromatic vinyl compound copolymer can be incorporated into a PC/PBT alloy as an impact modifier, thus the impact strength of the modified alloy composition at room temperature and low temperatures can be increased effectively.Type: GrantFiled: June 27, 1995Date of Patent: November 19, 1996Assignee: Industrial Technology Research InstituteInventors: Cheng-Lung Chao, Juh-Shyong Lee, Feng-Chih Chang
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Patent number: 5574111Abstract: Crystalline propylene (co)polymers modified by grafting with a vinylpolybutadiene having 1,2-structure content of at least 10%.Said (co)polymers are reacted with a liquid vinylpolybutadiene in the presence of a non-peroxidic radical initiator at a temperature in the range 200.degree. to 350.degree. C., the liquid vinylpolybutadiene having a 1.2-structure content of at least 10% and being generally used in amounts within the range 0,5 to 20% by weight.Type: GrantFiled: June 6, 1995Date of Patent: November 12, 1996Assignee: Centro Sviluppo Settori Impiego S.r.l.Inventors: Corrado Brichta, Francesco Mascia, Amodio Di Somma, Gabriele Torregiani, Antonio Addeo
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Patent number: 5561196Abstract: This invention relates to grafted polypropylene compositions and a process for their production. More particularly, the invention relates to polypropylene compositions based on polypropylene homopolymers, and copolymers of propylene with ethylene and/or butadiene, grafted with certain epoxy-alkyl acrylate compounds, and a process for their production. The grafted polypropylene compositions are useful especially as compatibilizers for addition to other polymer compositions.Type: GrantFiled: July 13, 1995Date of Patent: October 1, 1996Assignee: Den norske stats oljeselskap a.s.Inventors: Hans K. Kotlar, Per M. Hansen
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Patent number: 5547999Abstract: A reactive microgel suitable for a photosensitive resin composition for a water-developable flexographic printing plate, which has an average particle diameter to 10 .mu.m, and is formed ofmicrogel particles, as a core, synthesized from an acrylic monomer in an aqueous medium in the presence of an oil-soluble initiator and in the presence of a reactive polymer emulsifier which is an adduct of a neutralized product of an acrylic copolymer having a tertiary amino group with a compound having an epoxy group and an .alpha., .beta.-unsaturated double bond, and a nonionic emulsifier having an HLB of 12 to 16, anda compound having an epoxy group and an .alpha., .beta.-unsaturated double bond, attached to surfaces of the microgel particles.Type: GrantFiled: May 9, 1995Date of Patent: August 20, 1996Assignee: Toyolink Manufacturing Co., Ltd.Inventors: Sunao Satake, Yoshimi Yatsuyanagi, Masahiro Fujii, Ippei Imagawa
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Patent number: 5545694Abstract: A reactive microgel suitable for a photosensitive resin composition for a water-developable flexographic printing plate, which has an average particle diameter of 1 to 10 .mu.m, and is formed ofmicrogel particles, as a core, synthesized from an acrylic monomer in an aqueous medium in the presence of an oil-soluble initiator and in the presence of a reactive polymer emulsifier which is an adduct of a neutralized product of an acrylic copolymer having a tertiary amino group with a compound having an epoxy group and an .alpha.,.beta.-unsaturated double bond, and a nonionic emulsifier having an HLB of 12 to 16, anda compound having an epoxy group and an .alpha.,.beta.-unsaturated double bond, attached to surfaces of the microgel particles.Type: GrantFiled: February 9, 1995Date of Patent: August 13, 1996Assignee: Toyo Ink Manufacturing Co., Ltd.Inventors: Sunao Satake, Yoshimi Yatsuyanagi, Masahiro Fujii, Ippei Imagawa
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Patent number: 5541262Abstract: Crystalline propylene (co)polymers modified by grafting with a vinylpolybutadiene having 1,2-structure content of at least l0%.The (co)polymers are reacted with a liquid vinylpolybutadiene in the presence of a non-peroxidic radical initiator at a temperature in the range 200.degree. to 350.degree. C., the liquid vinylpolybutadiene having a 1,2-structure content of at least 10% and being generally used in amounts within the range 0.5 to 20% by weight.Type: GrantFiled: June 6, 1995Date of Patent: July 30, 1996Assignee: Centro Sviluppo Settori Impiego S.r.l.Inventors: Corrado Brichta, Francesco Mascia, Amodio Di Somma, Gabriele Torregiani, Antonio Addeo
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Patent number: 5536775Abstract: Amine curable compositions containing a partially acrylated epoxy resin useful for forming protective and/or decorative coatings on a variety of substrates, particularly flooring substrates.Type: GrantFiled: November 4, 1994Date of Patent: July 16, 1996Assignee: Sandoz Ltd.Inventors: Benedict S. Curatolo, Frank V. Apicella, Jr., Thomas W. Richardson, Sr.
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Patent number: 5527859Abstract: Copolymers crosslinkable by a free radical method are prepared by polymer-analogous reaction ofA) a copolymer (A) which is composed ofa1) from 20 to 85 mol % of a monomer (a1) having the structural element of methacrylic acid anda2) from 15 to 80 mol % of another monomer (a2) which undergoes free radical polymerization,a3) from 5 to 50 mol % of the total amount of the monomers (a1) and (a2) being monomers (a3) which carry functional groups and whose functional groups are capable of undergoing a condensation or addition reaction,withB) an olefinically unsaturated monomer (B) which carries a functional group which is complementary to that of the monomers (a3),by a process in which the polymer-analogous reaction is carried out at from 90.degree. to 150.degree. C. in an average residence time of from 3 to 20 minutes in highly concentrated solution or in the absence of a solvent. Said copolymers are used as binders for powder coatings.Type: GrantFiled: August 2, 1995Date of Patent: June 18, 1996Assignee: BASF AktiengesellschaftInventors: Fritz E. Kempter, Wolfgang Reich, Jurgen Hofmann
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Patent number: 5514754Abstract: A method of enhancing the water absorbance of and increasing the particle size of fine water absorbent cross-linked polyacrylic polymer particles includes impregnating the polymer particles with an impregnating monomer solution containing an acrylic monomer, with or without a cross-linking agent for the acrylic monomer. The solution is impregnated into the resin in a weight ratio of cross-linked polyacrylic polymer, dry basis, to impregnating monomer solution in the range of about 1:1 to about 1:10; and subjecting the impregnated polymer to conditions, such as increased temperature, e.g., 100.degree. C.-150.degree. C. to polymerize the impregnated monomer, within the cross-linked polymer particles, to form a cross-linked polyacrylic polymer having enhanced water absorbance and increased particle size.Type: GrantFiled: September 28, 1994Date of Patent: May 7, 1996Assignee: American Colloid CompanyInventors: John A. Henderson, Anthony S. Tomlin, David M. Lucas
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Patent number: 5502113Abstract: A pigment dispersion useful for forming aqueous coating compositions containing metallic flake pigment, an aqueous carrier and a graft copolymer dispersant (binder);wherein the graft copolymer has a weight average molecular weight of about 5,000-100,000 and comprises a polymeric backbone and macromonomer side chains attached to the backbone wherein(1) the polymeric backbone is formed of polymerized ethylenically unsaturated monomers and(2) the side chains are macromonomers that are attached to the backbone at a single terminal point and formed from polymerized ethylenically unsaturated monomers that are polymerized in the presence of a cobalt chain transfer agent have a weight average molecular weight of about 1,000-30,000;wherein the graft copolymer contains about 2 to 70% by weight, based on the weight of the graft copolymer, of polymerized constituents having a phosphate moiety and phosphoric acid moieties that are polymerized into the backbone, the side chains or both and the polymer is neutralized with aType: GrantFiled: August 22, 1994Date of Patent: March 26, 1996Assignee: E. I. Du Pont de Nemours and CompanyInventors: Joseph A. Antonelli, Lee A. E. Becton, Brian P. Devlin, Christopher Scopazzi
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Patent number: 5496896Abstract: The invention relates to a curable composition containing as component A) compounds with at least two activated double bonds (I), these being .alpha.,.beta.-unsaturated carbonyl compounds, .alpha.,.beta.-unsaturated carboxylic acid esters or .alpha.,.beta.-unsaturated nitriles, and compounds B) which contain at least two active hydrogen atoms or at least two groups with active hydrogen atoms or at least one active hydrogen atom and at least one group with an active hydrogen atom, and customary additives, catalysts, if appropriate pigments and an organic solvent. Either component A) or B) or components A) and B) are based on a branched soluble acrylate copolymer (P) which is obtainable by copolymerization ofa) 3 to 30% by weight of monomers with at least two ethylenically unsaturated polymerizable double bonds,b) 5 to 60% by weight of monomers with a functional group andc) 5 to 92% by weight of other ethylenically unsaturated monomers,the sum of a), b) and c) being 100% by weight.Type: GrantFiled: April 1, 1993Date of Patent: March 5, 1996Assignee: BASF Lacke & Farben AktiengesellschaftInventor: Jung W. Alfons
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Patent number: 5484850Abstract: Copolymers crosslinkable by a free radical method and having a number average molecular weight of from 1500 to 6000 and a molecular weight distribution corresponding to a polydispersity of from 1 to 4.0 are obtainable by polymer-analogous reaction ofA) a copolymer (A) which is composed ofa1) from 50 to 85 mol % of a monomer (a1) containing the structural element of methacrylic acid anda2) from 15 to 50 mol % of another monomer (a2) undergoing free radical polymerization,a3) from 5 to 50 mol % of the total amount of the monomers (a1) and (a2) being monomers (a3) which carry functional groups and whose functional groups are capable of undergoing a condensation or addition reaction,and is obtainable by free radical mass or solution polymerization at from 140.degree. to 210.degree. C. and with an average residence time of from 2 to 90 minuteswithB) an olefinically unsaturated monomer (B) which carries a functional group which is complementary to the functional groups of the monomers (a3).Type: GrantFiled: October 28, 1994Date of Patent: January 16, 1996Assignee: BASF AktiengesellschaftInventors: Fritz E. Kempter, Wolfgang Reich, Ulrich Jager, Eckhard Korona
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Patent number: 5483005Abstract: A process for preparing (meth)acrylate polymers with lateral non-linear optical chromophores and molecular weights of from 5000 to 500,000, comprises reacting polymers of (meth)acryloyl isocyanate in solution with D-.omega.-hydroxyalkyl chromophores of the formula (I) ##STR1## where D is an electron donor,A is an electron acceptor,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 can be identical or different and are each H, alkyl, cycloalkyl, alkoxy or R.sup.3 and R.sup.4 are each CN, NO.sub.2 or CHO or R.sup.1 and R.sup.2, or R.sup.3 and R.sup.4, together form a fused-on ring,X is CH and/or Nandm is an integer from 2 to 11.The products are suitable for optical components in communications technology.Type: GrantFiled: November 4, 1993Date of Patent: January 9, 1996Assignee: BASF AktiengesellschaftInventors: Karl-Heinz Etzbach, Stefan Beckmann
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Patent number: 5457158Abstract: A process is described for preparing blends of fluorocarbon plastomers such as vinylidene fluoride polymers with fluorosilicone elastomers to obtain materials having a unique combination of flexibility at low temperature and high mechanical strength. Vinylidene fluoride polymer is first exposed to radiation and then mixed with the fluorosilicone. Coagents such as diallylphtalate and triallylisocyanurate are also used to assist in grafting and compatibilizing the two polymers.Type: GrantFiled: July 11, 1994Date of Patent: October 10, 1995Assignee: Dow Corning CorporationInventors: Gerardo Caporiccio, Liberato Mascia
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Patent number: 5436297Abstract: A modified polyolefin comprising: (A) 100 parts by weight of a polyolefin; (B) 0.01 to 20 parts by weight of a monomer mixture consisting of: (b-1) 5 to 50% by mole of glycidyl acrylate, glycidyl methacrylate or an unsaturated glycidyl compound represented by general formula (I) below ##STR1## wherein R is a hydrogen atom or an alkyl group having 1 to 6 carbon atoms; Ar is an aromatic hydrocarbon group having 6 to 20 carbon atoms and having at least one glycidyl group; and n is an integer of 1 to 4, and (b-2) 95 to 50% by mole of at least one monomer selected from the group consisting of acrylamide monomers, vinylpyrrolidones, acrylic acid esters and methacrylic acid esters, the monomer mixture being graft-copolymerized with the polyolefin.Type: GrantFiled: October 27, 1993Date of Patent: July 25, 1995Assignee: Tonen CorporationInventors: Tatsuo Teraya, Shintaro Kikuchi, Kouichi Yokoyama, Yuji Fujita
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Patent number: 5426009Abstract: The invention relates to a polymeric composite material which:is based on a liquid crystal polymer component,exhibits a high glass transition temperature of at least 60.degree. C. and a scattering texture when deposited as a thin film,can be rendered transparent by being heated above the glass transition temperature and/or clearing temperature, andis obtained by mixing a liquid crystal polymer component, a reactive liquid crystalline component, optionally a polymerization initiator component, and/or further additive components, with subsequent polymerization.Type: GrantFiled: September 17, 1993Date of Patent: June 20, 1995Assignee: Merck Patent Gesellschaft mit beschrankter HaftungInventors: David Coates, Mark Verrall, Emma J. Brown
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Patent number: 5424369Abstract: A self-crosslinking resin comprising a resin containing a blocked isocyanate group, and a resin containing a hydroxyl group, and a tertiary amino group and/or a quaternary ammonium group and attached to the resin by a urethane bond.The self-crosslinking resins are useful for adhesive compositions and coating compositions of the aqueous type.Type: GrantFiled: June 17, 1992Date of Patent: June 13, 1995Assignee: Kansai Paint Company, LimitedInventors: Yoshiyuki Yukawa, Motoshi Yabuta, Yasushi Nakao
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Patent number: 5424366Abstract: Multi-functional viscosity index improvers for lubricating oils containing an EPM or EPDM polymer onto which has been grafted an unsaturated functional monomer containing phenothiazine.Type: GrantFiled: June 1, 1994Date of Patent: June 13, 1995Assignee: Texaco Inc.Inventors: Maria M. Kapuscinski, Theodore E. Nalesnik, Robert T. Biggs, Benjamin J. Kaufman
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Patent number: 5422394Abstract: A water-based autoxidizable coating composition for application to architectural surfaces, fittings or furnishings at ambient temperatures which contains water, a drier to promote autoxidation and a water-soluble autoxidizable film-forming copolymer which contains 0.5 to 7 wt % of acrylic acid, 50 to 50 wt % of either a hydroxy acrylate chosen from hydroxy ethyl or hydroxyisopropyl acrylate or alternatively a polyethoxylate (meth)acrylate and 30 to 50 wt % of an autoxidizable ester of copolymerized acrylic acid in which the esterifying moieties are 3-allyloxy-2-hydroxypropyl or the methallyl analogue. Also an autoxidizable copolymer of the above composition. The coating composition laps well yet is water-soluble and resistant to both long term and short term damage by water. Also the copolymer for use in the compositions.Type: GrantFiled: November 29, 1993Date of Patent: June 6, 1995Assignee: Imperial Chemical Industries PLCInventors: Philip L. Taylor, Peter G. Osborn
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Patent number: 5420199Abstract: A thermoplastic resin composition consisting essentially of (a) 50 to 90 % by weight of polybutylene terephthalate (component A), (b) 5 to 40 % by weight of modified polyolefin modified by an unsaturated monomer having a glycidyloxy group and an unsaturated monomer having a carboxyl group or an acid anhydride group (component B), (c) 5 to 40 % by weight of polycarbonate (component C); and molded articles prepared from the above thermoplastic resin composition.The thermoplastic resin composition of the invention can give molded articles having excellent toughness, rigidity, strength and dimensional stability.Type: GrantFiled: February 28, 1994Date of Patent: May 30, 1995Assignee: Teijin LimitedInventor: Hiroki Fujie
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Patent number: 5409776Abstract: A multi-shell emulsion particle of dry state structure having one or more of penetrating pore(s) connecting the surface layer of the particle with the interior of the particle and having a particle diameter of from 0.1 to 5.0.mu. preferably from 0.1 to 1.2.mu..Type: GrantFiled: February 1, 1994Date of Patent: April 25, 1995Assignee: Mitsui Tomatsu Chemicals, IncorporatedInventors: Kousuke Someya, Akihiro Yamazaki, Futoshi Hoshino, Takeshi Yanagihara
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Patent number: 5391631Abstract: A vinyl polymer is obtainable by polymerizing vinyl monomers in at least two stages by a procedure in which, in a first stage, from 5 to 95% by weight of vinyl monomers are polymerized in an organic solvent or in the absence of a solvent and, in the second stage, from 5 to 95% by weight of the vinyl monomers are polymerized in the presence of the vinyl polymer obtained in the first stage, likewise in an organic solvent or in the absence of a solvent, with the proviso that the polymerization in the second stage is carried out under conditions under which an average molecular weight M.sub.n, which is at least 1,000 higher compared with that of the vinyl polymer, the first stage of results for the vinyl monomers of the second stage in the absence of the vinyl polymer obtained in the first stage.Type: GrantFiled: May 27, 1993Date of Patent: February 21, 1995Assignee: BASF AktiengesellschaftInventors: Bettina Porsch, Hans Renz
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Patent number: 5385974Abstract: A novel graft copolymer having a number-average molecular weight of about 1,500 to about 1,000,000, produced by graft-copolymerizing an alkylene oxide and a cyclic ester to a saponified ethylene-saturated carboxylic acid vinyl ester copolymer; a process for production thereof; and a plasticizer comprising said graft copolymer as the active component.Type: GrantFiled: July 15, 1993Date of Patent: January 31, 1995Assignee: Sumitomo Chemical Company, LimitedInventors: Tadayuki Ohmae, Hisao Tanaka, Sumio Hara
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Patent number: 5382634Abstract: The object of the present invention is to provide such a polyolefin that only the terminal of polypropylene or ethylene-propylene random copolymer is modified with a (meth)acrylic derivative unit to give a substantially monodipersed system. The feature thereof consists in such a polyolefin that the terminal of polypropylene or ethylene-propylene random copolymer obtained by living polymerization is modified with a (meth)acrylic derivative unit. As the (meth)acrylic derivative, there are used vinyl methacrylate, allyl methacrylate, trimethylsiloxyethyl methacrylate, 2-trimethylsiloxypropyl methacrylate, N, N-dimethylaminoethyl methacrylate, N,N-diethylaminoethyl methacrylate, glycidyl methacrylate, acrylic acid chloride and like.Type: GrantFiled: April 25, 1994Date of Patent: January 17, 1995Assignee: Tonen CorporationInventors: Naomi Koyama, Miyuki Usui, Hiroyuki Furuhashi, Satoshi Ueki
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Patent number: 5374364Abstract: Multifunctional viscosity index improvers for lubricating oils containing an EPM or EPDM polymer with pendant thiazoline units.Type: GrantFiled: September 3, 1993Date of Patent: December 20, 1994Assignee: Texaco Inc.Inventors: Maria M. Kapuscinski, Nicholas Benfaremo, Robert T. Biggs
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Patent number: 5362804Abstract: An unsaturated polyester resin composition for the production of cured molded article which comprises:an unsaturated polyester resin; anda core-shell polymer as a low shrinking agent which comprises:(a) a cross-linked core layer polymerized from a first monomer comprising an aromatic vinyl monomer in an amount of not less 50% by weight, the core layer being contained in the core-shell polymer in an amount of 50-90% by weight; and(b) a shell layer polymerized from a monomer comprising methyl methacrylate in an amount of not less 50% by weight;and the core-shell polymer having a refractive index in the range of 1.52-1.58 and within .+-.0.02 from the refractive index of the cured material of the unsaturated polyester resin.Type: GrantFiled: February 24, 1993Date of Patent: November 8, 1994Assignee: Takeda Chemical Industries, Ltd.Inventors: Junji Oshima, Susumu Okatani, Koichi Akiyama, Masato Sakurai
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Patent number: 5362813Abstract: A polymer dispersion of a star polymer dispersed in an organic liquid; wherein the star polymer has a crosslinked core having attached thereto at least three macrononomer arms; where(1) the core is formed of monomers having at least two ethylenically unsaturated double bonds which are crosslinked with each other and the core has at least 3 free radical polymerizable sites each of which are reacted with the macromonomer; and(2) the macromonomer that forms the arms of the star polymer is formed of ethylenically unsaturated monomers that have been polymerized by free radical polymerization in the presence of a free radical polymerization initiator and a catalytic chain transfer agent containing CO.sup.+2 to provide the macromonomer with a terminal ethylenically unsaturated group that is polymerized with the free radical polymerizable site on the core to form the star polymer. The process for making the star polymer and coating compositions that utilize the star polymer are also part of this invention.Type: GrantFiled: December 22, 1993Date of Patent: November 8, 1994Assignee: E. I. Du Pont de Nemours and CompanyInventors: Joseph A. Antonelli, Christopher Scopazzi
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Patent number: 5356999Abstract: Multifunctional viscosity index improvers for lubricating oils containing an EPM or EPDM polymer onto which has been grafted an unsaturated reactive monomer and thereafter reacted with amines containing sulfonamide units.Type: GrantFiled: October 29, 1990Date of Patent: October 18, 1994Assignee: Texaco Inc.Inventors: Maria M. Kapuscinski, Benjamin J. Kaufman, Robert T. Biggs
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Patent number: 5346953Abstract: Core-shell ABS copolymers having an SAN shell completely surrounding the diene core are provided by melt blending an aliphatic diene polymer with an SAN copolymer, said copolymer containing functional groups capable of reacting with the diene polymer. For example, the SAN copolymer may contain azide groups capable of reacting with the olefinic groups in the diene polymer, or both the SAN copolymer and the diene polymer may contain other functional groups capable of interreaction, such as acidic (e.g., maleic anhydride) groups in the diene and epoxy (e.g., glycidyl methacrylate) groups in the SAN copolymer.Type: GrantFiled: October 7, 1993Date of Patent: September 13, 1994Assignee: General Electric CompanyInventors: James J. Scobbo, Jr., Gregory J. Stoddard