Nitrogen Atom Is Part Of A Carboxylic Acid Amide Group Patents (Class 525/296)
  • Patent number: 4302558
    Abstract: A graft copolymer is obtained by graft-polymerizing a vinyl or vinylidene monomer onto a rubber trunk polymer which comprises a polyalkylene oxide monomer comprising 4 to 500 alkylene oxide groups together with an ethylenic unsaturation, and a conjugated diene and/or an alkyl acrylate. This graft copolymer alone or in a mixture thereof with another thermoplastic resin, because of the presence of the polyalkylene oxide monomer unit incorporated in the rubber trunk polymer, provides a resin composition possessing excellent antistatic property, which, practically, is not lowered by washing.
    Type: Grant
    Filed: September 6, 1979
    Date of Patent: November 24, 1981
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Masaki Ohya, Akio Kobayashi, Takeo Ogiwara, Yoshikatsu Satake
  • Patent number: 4293667
    Abstract: Disclosed are novel organic pigments adapted particularly for use as fillers for paper. The organic pigments are finely divided particles obtained by graft copolymerizing an ethylenically unsaturated monomer, such as styrene, onto a water-soluble cationic prepolymer in an aqueous solution and in the presence of a free-radical polymerization initiator.
    Type: Grant
    Filed: June 23, 1980
    Date of Patent: October 6, 1981
    Assignee: Hercules Incorporated
    Inventors: William W. Maslanka, Gavin G. Spence
  • Patent number: 4293666
    Abstract: Disclosed are novel organic pigments adapted particularly for use as fillers for paper. The organic pigments are finely divided particles obtained by graft copolymerizing an ethylenically unsaturated monomer, such as styrene, onto a water-soluble cationic prepolymer in an aqueous solution and in the presence of a free-radical polymerization initiator.
    Type: Grant
    Filed: June 23, 1980
    Date of Patent: October 6, 1981
    Assignee: Hercules Incorporated
    Inventors: William W. Maslanka, Gavin G. Spence
  • Patent number: 4292220
    Abstract: The specification discloses a polymer of ethylenically unsaturated monomers wherein the polymer comprises diamide mer units having pendant unsaturated, air-curable alkyl groups. Methods of making and using the polymers and articles made therefrom are taught. The polymer may be used in coating, bonding or adhering to substrates. Of particular importance are uses in paint compositions and in caulk compositions. The air-curable alkyl diamide mer unit is derived from an unsaturated drying oil. Aqueous coating compositions are disclosed in which the polymer is an ammonia or amine salt, in solution, and is either the sole polymeric vehicle or is combined with a water insoluble polymer latex.
    Type: Grant
    Filed: December 20, 1979
    Date of Patent: September 29, 1981
    Assignee: Rohm and Haas Company
    Inventors: Ronald W. Novak, Leslie R. Wolf
  • Patent number: 4289823
    Abstract: There is disclosed a calenderable, soft, three-stage acrylic heteropolymer having a calculated T.sub.g of about (-) 40.degree. to (=) 20.degree. C. which is suitable for producing films and sheets useful to coat textile materials and other substrates to form composites. The heteropolymer can be coagulated and then introduced into a calendering apparatus to produce films and sheets at substantially lower temperatures than are required for calendering vinyl halide polymers.
    Type: Grant
    Filed: September 30, 1980
    Date of Patent: September 15, 1981
    Assignee: Rohm and Haas Company
    Inventor: Charles T. Arkens
  • Patent number: 4289675
    Abstract: An air drying latex coating composition, curable under ambient conditions, is described having copolymer particles consisting essentially of copolymerized monoethylenically unsaturated monomers dispersed in an aqueous emulsion. The copolymer particles have 0.5-30% by weight of ethylenically unsaturated monomers bonded thereto through reacted C.sub.1 -C.sub.6 N-alkylol functionalities. Curing agents or curing catalysts are also present to cure the deposited composition. The coating compositions are provided by forming an aqueous dispersion of the copolymer particles, bonding an ethylenically unsaturated monomer thereto through a C.sub.1 -C.sub.6 N-alkylol functionality, and admixing therein a curing catalyst or curing agent.
    Type: Grant
    Filed: December 3, 1979
    Date of Patent: September 15, 1981
    Assignee: DeSoto, Inc.
    Inventor: John J. Krajewski
  • Patent number: 4287316
    Abstract: A transparent resin composition comprising (1) 6 to 100% by weight of a nitrile graft copolymer comprising a rubber trunk polymer and a branch polymer grafted thereon, which has been obtained by graft-polymerizing onto the rubber trunk polymer a monomer mixture containing an unsaturated nitrile and a monomer copolymerizable therewith, and (2) 0 to 94% by weight of a random copolymer of an unsaturated nitrile and a monomer copolymerizable therewith, the resin components of the resin composition other than the rubber trunk polymer constituting a matrix resin, wherein(a) said rubber trunk polymer has a glass transition temperature of not higher than 0.degree. C. and constitutes 4 to 25% by weight of the resin composition,(b) the unsaturated nitrile constitutes 25 to 90% by weight of the matrix resin in the resin composition,(c) the difference in the refractive indexes between the rubber trunk polymer and the matrix resin is not more than 0.
    Type: Grant
    Filed: April 19, 1979
    Date of Patent: September 1, 1981
    Assignee: Kureha Kagaku Kogyo Kabushiki Kaisha
    Inventors: Akira Kaneko, Masaki Ohya, Masayasu Suzuki, Akio Kobayashi
  • Patent number: 4287106
    Abstract: The adhesive or adhesive component according to the invention, which contains a vinyl monomer, a vinyl polymer, a compound producing free radicals, and, as an adhesion promoter, an acid amide or imide which is substituted on the nitrogen atom by a chlorosulfonated alkyl, aryl or aralkyl group, forms, together with an amine accelerator, an adhesive with which heat-, oil- and water-resistant bonds, for example of metals, polymeric materials, glass and ceramics, having very high tensile shearing strength can be obtained. The adhesive can also be converted into the form of a dried sheet, with or without carrier, and in this form can be used for bonding.
    Type: Grant
    Filed: August 13, 1979
    Date of Patent: September 1, 1981
    Assignee: Ciba-Geigy Corporation
    Inventors: Imre Forgo, Abdul-Cader Zahir, Jacques Francois
  • Patent number: 4282338
    Abstract: A method is disclosed for preparing graft polymers of alpha-substituted-beta-propiolactones, comprising the step of providing anionic sites in an amorphous base polymer and reacting the anionic compound with an alpha-substituted-beta-propiolactone. Critical concentrations of unsaturation in the base polymer and critical quantities of the beta-propiolactone concerned are indicated.
    Type: Grant
    Filed: March 26, 1980
    Date of Patent: August 4, 1981
    Assignee: Anic S.p.A.
    Inventors: Arnaldo Roggero, Luciano Zotteri
  • Patent number: 4281082
    Abstract: Disclosed are novel organic pigments adapted particularly for use as fillers for paper. The organic pigments are finely divided particles obtained by graft copolymerizing an ethylenically unsaturated monomer, such as styrene, onto a water-soluble cationic prepolymer in an aqueous solution and in the presence of a free-radical polymerization initiator.
    Type: Grant
    Filed: December 26, 1979
    Date of Patent: July 28, 1981
    Assignee: Hercules Incorporated
    Inventors: William W. Maslanka, Gavin G. Spence
  • Patent number: 4279795
    Abstract: Materials for forming a hydrogel when contacted with water having improved anti-thrombogenic properties and a highly improved mechanical strength are obtained by the copolymerization of a free radical-polymerizable vinyl monomer capable of forming a hydrophilic polymer and a hydrophobic macromolecular compound having a chain-terminated polymerizable double bond and a molecular weight of 1,000 to 100,000.
    Type: Grant
    Filed: December 28, 1973
    Date of Patent: July 21, 1981
    Assignee: Kuraray Co., Ltd.
    Inventors: Shuzo Yamashita, Kyoichiro Shibatani, Kiochi Takakura, Kiyokazu Imai
  • Patent number: 4235982
    Abstract: Disclosed are novel organic pigments adapted particularly for use as fillers for paper. The organic pigments are finely divided particles obtained by graft copolymerizing an ethylenically unsaturated monomer, such as styrene, onto a watersoluble cationic prepolymer in an aqueous solution and in the presence of a free-radical polymerization initiator.
    Type: Grant
    Filed: May 25, 1978
    Date of Patent: November 25, 1980
    Assignee: Hercules, Incorporated
    Inventors: William W. Maslanka, Gavin G. Spence
  • Patent number: 4214064
    Abstract: In a process for producing a casting plate of polymethyl methacrylate by continuously subjecting a methyl methacrylate monomer or a syrup containing soluble polymeric resins in the methyl methacrylate monomer to casting polymerization, an improvement which comprises adding a sulfur-containing compound represented by the formula:A--S-R).sub.n S-Bwherein n is an integer of 0 to 10, R is an alkylene group having 1 to 6 carbon atoms and A and B are the same or different and are each a --(CH.sub.2).sub.m --CH(XY) group in which m is an integer of 0 to 23, X is a hydrogen atom, a halogen atom or a methyl group and Y is a hydrogen atom, a cyano group, a --OCOCH.sub.3 group, a --COOR' group or a --COSR" group, R' and R" being each an alkyl group having 1 to 24 carbon atoms, and a surfactant to the starting monomer or syrup to obtain the casting plate having an improved thermal stability.
    Type: Grant
    Filed: November 30, 1977
    Date of Patent: July 22, 1980
    Assignee: Sumitomo Chemical Company, Limited
    Inventor: Hiroyuki Kanazawa
  • Patent number: 4206294
    Abstract: A graft copolymer having a polymeric backbone with pendant hydroxyl groups; wherein the hydrogen atom of at least the one the hydroxyl groups is replaced by the formula ##STR1## where R is an aliphatic group, a cycloaliphatic group or an aromatic group; R.sup.1 is an alkylene group having 2-6 carbon atoms; R.sup.2 is a polymer segment of a vinyl addition polymer, such as butyl acrylate/hydroxyethyl acrylate; coating compositions of this copolymer can be cross-linked with conventional cross-linking agents such as an alkylated melamine formaldehyde resin or an organic polyisocyanate and coating compositions useful for flexible elastomeric substrates can be prepared from this copolymer.
    Type: Grant
    Filed: December 22, 1978
    Date of Patent: June 3, 1980
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: John A. Simms
  • Patent number: 4177221
    Abstract: This invention relates to a thermosetting, substrate-free, storage-resistant synthetic resin foil which is hard, scratch- and abrasion-proof in the hardened state, comprising: (a) about 60 to 95% by weight of a hardenable polyester resin, (b) about 1 to 15% by weight of a cross-linking agent for the polyester resin, (c) about 5 to 40% by weight of a thermoplastic containing predominantly linear, high-molecular weight reactive groups, (d) about 1 to 15% by weight of a monomer with at least one polymerizable double bond and at least one group reactable with the reactive group of the thermoplastic under the conditions of reaction, (e) and at least one hardening catalyst, and optionally dyestuffs, pigments and/or fillers. The invention also relates to a process for preparing the novel foil of the invention.
    Type: Grant
    Filed: November 2, 1977
    Date of Patent: December 4, 1979
    Assignee: Th. Goldschmidt AG
    Inventors: Eckehard Schamberg, Jurgen Fock, Otto Klocker, Eberhard Esselborn
  • Patent number: 4165418
    Abstract: A pigment dispersant suitable for use in making a series of paints, the dispersant being a copolymer of defined proportions of ethylenically unsaturated monomers containing hydroxy and/or amide groups, straight or branched chain alkyl groups of from 7 to 22 carbon atoms and optionally also groupings which can promote association of the copolymer with a pigment surface. A millbase made with the aid of such a dispersant can be combined in either loading or tinting operations with a wide range of different film-forming polymers.
    Type: Grant
    Filed: February 8, 1977
    Date of Patent: August 21, 1979
    Assignee: Imperial Chemical Industries Limited
    Inventor: Derek N. A. Speakman