Abstract: A method for preparing a functionalized polymer includes the steps of (i) polymerizing monomer to form a reactive polymer; and (ii) reacting the reactive polymer with a [poly(hydrocarbylene glycol) hydrocarbyl ether] (meth)acrylate.

Abstract: The invention relates to fluoropolymers that have been modified with low molecular weight, polymeric chain transfer agents, and uses of the modified fluoropolymers. The modified fluoropolymers provide enhanced properties to the fluoropolymer, such as increased adhesion, and hydrophilic characteristics. The modified functional fluoropolymers are useful in many applications, including as binders in electrode-forming compositions and separator compositions, for hydrophilic membranes and hollow fiber membranes, as an aqueous and a solvent cast coating for baked decorative and protective coatings, and as a tie layer between a fluoropolymer layer and an incompatible polymer layer.

Abstract: The present invention relates to a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye. In particular the present invention relates to a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye, its process of preparation and use. The present invention concerns also objects or articles comprising a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye. The present invention concerns as well a photovoltaic module comprising a polymeric composition comprising a polymeric elastomeric phase and a fluorescent dye.

Abstract: Described herein are alkoxylated polymers suitable for use in primers, inks or coating compositions. The alkoxylated polymers derive from a polyalkylene glycol polymer or copolymer backbone having one or more alkoxylated sites in a non-reactive form and at least one reactive terminal end, and one or more polyfunctional monomers or oligomers having two or more functional polar groups with an active hydrogen, or mixtures thereof, wherein the alkoxylated polymer is polymerized in a one step process. Primers, inks or coating compositions are further described.

Abstract: The present invention relates to multi-arm surfactant-system thickening star macromolecules, and methods of preparing and using the same. In one aspect of the invention, a surfactant-system thickening star macromolecule is capable of providing surfactant-compatibility, increase the viscosity of a surfactant-containing system, and/or temperature-stability to an aqueous composition.

Abstract: The present invention relates to multi-arm surfactant-system thickening star macromolecules, and methods of preparing and using the same. In one aspect of the invention, a surfactant-system thickening star macromolecule is capable of providing surfactant-compatibility, increase the viscosity of a surfactant-containing system, and/or temperature-stability to an aqueous composition.

Abstract: The invention provides a composition comprising: (a) a star polymer comprising: (i) a core portion comprising a polyvalent (meth)acrylic monomer, oligomer or polymer thereof or a polyvalent divinyl non-acrylic monomer, oligomer or polymer thereof; and (ii) at least two arms of polymerized alkyl(meth)acrylate ester; and (b) an oil of lubricating viscosity, wherein the core portion further comprises a functional group of formula (I): —CH2—C(R1)(C(?O)A)-Y—??(I) wherein R1 is hydrogen, a linear or branched alkyl group containing 1 to 5 carbon atoms; A is nitrogen or oxygen; and Y is a free radical leaving group selected from the group consisting of one or more atoms or groups of atoms which may be transferred by a radical mechanism under the polymerization conditions, a halogen, an —O—N? group and an —S—C(?S)— group. The invention further provides the use of the composition in an oil of lubricating viscosity as a dispersant, a viscosity modifier or a precursor to a dispersant viscosity modifier.

Abstract: The present invention provides a polymerizable composition that is suitably used as a temporary cement for implant use and a mobile tooth-fixing material. The present invention is a polymerizable composition that includes an acrylic block copolymer (a) having at least one polymer block A that mainly contains a (meth)acrylic acid ester unit and that functions as a hard segment and at least one polymer block B that mainly contains an acrylic acid ester unit and that functions as a soft segment, a polymerizable monomer (b), and a polymerization initiator (c).

Abstract: An object of the present invention is to provide a novel copolymer useful as a pigment dispersing agent in the field of color liquid crystal displays and the like.

Abstract: The invention provides compositions comprising at least one propylene-based polymer, at least one peroxide and at least one coagent.

Abstract: Provided are a pressure-sensitive adhesive composition, an optical laminate, a pressure-sensitive adhesive polarizing plate and a display device. When a particular block copolymer forming a micro phase separation region in a crosslinking structure is used, and a cohesive strength of the block copolymer is controlled, a pressure-sensitive adhesive composition having excellent physical properties required for an optical member, and particularly having excellent bending preventability, cuttability and pressure-sensitive adhesive durability may be provided. Such a pressure-sensitive adhesive composition may be used for optical uses, for example, to laminate various optical members, or apply an optical member to a display device.

Abstract: The present invention relates to branched polymer comprising a support moiety and at least three block co-polymer chains covalently coupled to and extending from the moiety, wherein: (i) each of the at least three block co-polymer chains comprise (a) a cationic polymer block that is covalently coupled to a hydrophilic polymer block, or (b) a cationic polymer block that is covalently coupled to a hydrophobic polymer block, said hydrophobic polymer block being covalently coupled to a hydrophilic polymer block; and (ii) at least one of said covalent couplings associated with each of said block co-polymer chains is biodegradable.

Abstract: This invention relates to a composition comprising a multiblock polyolefin represented by the formula: PO—C(R11)(R12)—C(R13)?C(R14)—C(R15)(R16)—PO*, or isomers thereof, wherein R11, R12, R13, R14, R15, and R16, are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; PO and PO* are polyolefins; PO and PO* are each independently a substituted or unsubstituted hydrocarbyl group having 9 to 4000 carbon atoms, provided that at least one of PO and PO* are C20 or greater, said polyolefin having: 1) an internal unsaturation as shown by the 13C NMR peak at between about 128 and about 132 ppm; 2) an Mn ratio “Z”=0.1 to 10 where Z is the Mn (as determined by 13C NMR) divided by Mn (as determined according to Gel Permeation Chromotography using polystyrene standards); and 3) optionally, from 0.3(J) and 0.

Abstract: This invention relates to rapid drying lacquers that are particularly useful for automotive OEM refinish applications. The lacquer includes a novel acrylic triblock copolymer as a replacement material for all or part of the cellulose acetate butyrate binder component. This invention is also directed to a process for producing coatings from the rapid drying lacquers. These lacquers are especially useful in providing chip and humidity resistant coatings, especially metallic effect coatings, having excellent adhesion and down flop or metallic effect.

Abstract: Disclosed herein is a block copolymer comprising a first block derived from a cyclo-alkyl vinyl monomer, a hydrogenated vinyl aromatic polymer or a hydrogenated vinyl pyridine polymers; and a second block derived from an acrylate monomer. Disclosed herein too is a method comprising reacting a first block derived from a cyclo-alkyl vinyl monomer, a hydrogenated vinyl aromatic polymer or a hydrogenated vinyl pyridine polymers with an initiator to form a macroinitiator; and polymerizing a second block onto the first block to form a block copolymer; where the second block is derived by polymerizing an acrylate monomer; and where the block copolymer has a chi parameter of greater than or equal to about 0.05, when measured at a temperature of 200° C. to 210° C.; where the chi parameter is a measure of interactions between the first block and the second block of the copolymer.

Abstract: Process for the preparation of a vinylidene chloride polymer comprising polymerizing vinylidene chloride and optionally at least one ethylenically unsaturated monomer copolymerizable therewith under the control of a RAFT agent of formula (II).

Abstract: This invention relates to rapid drying lacquers that are particularly useful for automotive OEM refinish applications. The lacquer includes a novel acrylic triblock copolymer as a replacement material for all or part of the cellulose acetate butyrate binder component. This invention is also directed to a process for producing coatings from the rapid drying lacquers. These lacquers are especially useful in providing chip and humidity resistant coatings, especially metallic effect coatings, having excellent adhesion and down flop or metallic effect.

Abstract: In accordance with various aspects of the invention, implantable and insertable medical devices are provided, which contain one or more polymeric regions. In one aspect, the polymeric regions comprise (a) a block copolymer that comprises a polyaromatic block and a polyalkene block admixed with (b) a sulfonated high Tg polymer. In another aspect, the polymeric regions comprise a block copolymer that comprises (a) a sulfonated polymer block and (b) fluorinated polymer block.

Abstract: The invention relates to a controlled polymerization method for producing ABA-triblock copolymers on the basis of (meth)acrylate with A-blocks which have a narrow, monomodal molecular weight distribution and a B-block which has a bimodal molecular weight distribution, and to the use thereof as binders in glues and sealing materials.

Abstract: The invention relates to compositions comprising two structured linear copolymers selected from the group consisting of block copolymers and gradient copolymers, these copolymers being prepared by different controlled polymerization techniques and the difference in the polydispersities of these copolymers, ?(Mw/Mn), being ?0.25. The invention further relates to the production of such blends and to their use as wetting agents and dispersants.

Abstract: A macromolecular emulsifier with switchable surface activity, and use thereof for preparation of polymer latex is disclosed. By using the macromolecular emulsifier with switchable surface activity as an emulsifier, a reversibly coagulable and re-dispersible polymer latex can be prepared by emulsion polymerization. The polymer latex can achieve the coagulation of latex particles by heating and aerating with nitrogen, air, inert gas and/or adding a small amount of alkali solution; the coagulated latex particles can be restored and re-dispersed into stable latex by aerating with carbon dioxide and/or adding a small amount of acid solution. The coagulation and re-dispersion process is reversible and is easy to control.

Abstract: A process for making a block copolymer compatibilizer, comprising reacting an acrylic monomer that has functional groups with one or more vinyl monomers in the presence of a free radical initiator and a stable free radical to form a reaction product that includes residual unreacted acrylic monomer, and reacting one or more vinyl monomers with the reaction product to form a second block that incorporates the residual unreacted acrylic monomer. A blend composition comprising a first thermoplastic polymer, which has functional groups, a reactive block copolymer that has functional groups in two or more blocks, and a second thermoplastic polymer that is compatible with one block of the block copolymer, where the functional groups in the first thermoplastic react with the functional groups in the block copolymer.

Abstract: Acrylic block copolymers are described which are inherently tacky. Also described are compositions of the copolymers which exhibit properties enabling their use as pressure sensitive adhesives, without addition of tackifiers and/or subsequent processing.

Abstract: A BCP having first block of first monomer and second block of second monomer, adapted to undergo a transition from disordered state to ordered state at a temperature less than TOD, further including a bridging moiety having a functional group to provide hydrogen bonding between bridging moieties of adjacent first and second BCP molecules when in the ordered state and at a temperature in excess of a glass transition temperature Tg for the BCP. Composition including BCP comprising first block of first monomer and second block of second monomer, and a crosslinking compound having first and second terminal groups joined by a central moiety and arranged to crosslink second blocks of adjacent first and second BCP molecules by providing non-covalent bonding between the terminal groups and a functional group of the second monomer of the second blocks when the BCP is in the ordered state.

Abstract: The present invention relates to a photovoltaic module comprising as an encapsulant a composition comprising at least one polyacrylate- or polymethacrylate-type block copolymer with the general formula B-(A)n, n being a natural integer no lower than one, preferably 1 to 8, the block A being selected from among methacrylates having a Tg higher than 0° C., the block B being a polyacrylate or a polymethacrylate having a Tg lower than 0° C., the block B being at least 50 wt % of the total weight of the block copolymer.

Abstract: A method for producing an AB block copolymer with PDI is provided. The method comprises steps of: 1) reaction, in the presence of at least one free radical initiator, of a reaction mixture comprising a compound of formula (I), and 2) reaction, at a temperature of 45° C. or above, of a reaction mixture comprising an ethylenically unsaturated monomer B and, independent from that of step 1), a compound of formula (I) and the macroinitiator of step 1) in solvent(s) to obtain the AB block copolymer; wherein the weight ratio of the compound of formula (I) to the macroinitiator in step 2) is at least 1:1000.

Abstract: The invention relates to a controlled polymerization method for producing ABA-triblock copolymers on the basis of (meth)acrylate with A-blocks having a narrow, monomodal molecular weight distribution, and a B-block having a wide, monomodal molecular weight distribution. The invention further relates to the use thereof as binders in glues or sealing compounds.

Abstract: The present application is relates to a pressure-sensitive adhesive composition. The pressure-sensitive adhesive composition of the present application may form a pressure-sensitive adhesive having excellent durability and reliability, stress relaxation and reworkability. In addition, when the pressure-sensitive adhesive composition is used collaterally, for example, a coating process may be efficiently performed even when a coating solid content is high, thereby maintaining excellent productivity and forming a pressure-sensitive adhesive having excellent uniformity in thickness. The pressure-sensitive adhesive composition may be used for an optical film such as a polarizing plate.

Abstract: A directed self-assembling composition for pattern formation includes a block copolymer. The block copolymer includes a polystyrene block having a styrene unit, and a polyalkyl (meth)acrylate block having an alkyl (meth)acrylate unit. The block copolymer has a group that is bound to at least one end of a main chain of the block copolymer and that includes a hetero atom.

Abstract: The invention relates to a controlled polymerization process for preparing (meth)acrylate-based AB diblock copolymers with a B block which has a narrow monomodal molecular weight distribution, and an A block which has a broad monomodal molecular weight distribution, and to the use thereof, for example, as a binder in adhesives or sealants.

Abstract: Disclosed herein are copolymers comprising functional groups attached to the backbone of the polymer and methods of making these polymers.

Abstract: The invention relates to a controlled polymerization process for preparing (meth)acrylate-based AB diblock copolymers with a B block which has a narrow monomodal molecular weight distribution, and an A block which has a broad bimodal molecular weight distribution, and to the use thereof, for example, as a binder in adhesives or sealants.

Abstract: The invention relates to a multiblock polyolefin, and methods to make a multiblock polyolefin, represented by the formula (X) or (XII): PO—C(R11)(R12)—C(R13)?C(R14)—C(O)—O—((CR15R16)z—(CR17R18)m—O)n—R19??(X) or PO—C(R11)(R12)—C(R13)?C(R14)—C(O)—O—((CR15R16)z—(CR17R18)mO)n—C(O)—C(R14)?C(R13)—C(R12)(R11)—PO??(XX) wherein R11, R12, R13, and R14 are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; R15, R16, R17, and R18 are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; R19 is a C1 to a C20 substituted or unsubstituted hydrocarbyl group or a hydrogen; z is ?1 to about 5; m is ?1 to about 5; PO is a polyolefin hydrocarbyl group comprising 10 to 4000 carbon atoms; and n is from 1 to about 10,000.

Abstract: Provided is an alternating block copolymer. The alternating block copolymer has an olefin polymer block and an poly(alkyl methacrylate) block. The olefin polymer block has monomeric units of one or more alpha olefins of 2 to 12 carbon atoms that make up 90 wt % or more of the total weight of the olefin polymer block. The olefin polymer block exhibits a number average molecular weight of the olefin polymer block is 1000 to 500,000. The poly(alkyl methacrylate) block has monomeric units of one or more alkyl methacrylates with alkyl side chains of 1 to 100 carbon atoms that make up 90 wt % or more of the total weight of the poly(alkyl methacrylate) block. The poly(alkyl methacrylate) block exhibits a number average molecular weight of 1000 to 500,000. There is also provided a lubricant composition containing the alternating block copolymer and a process for making the alternating block copolymer.

Abstract: The invention relates to a multiblock polyolefin, and methods to make a multiblock polyolefin, represented by the formula (X) or (XII): PO—C(R11)(R12)—C(R13)?C(R14)—C(O)—O—((CR15R16)z—(CR17R18)m—O)n—R19??(X) or PO—C(R11)(R12)—C(R13)?C(R14)—C(O)—O—((CR15R16)z—(CR17R18)mO)n—C(O)—C(R14)?C(R13)—C(R12)(R11)—PO??(XX), wherein R11, R12, R13, and R14 are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; R15, R16, R17, and R18 are each independently a substituted or unsubstituted C1 through C4 hydrocarbyl group or a hydrogen; R19 is a C1 to a C20 substituted or unsubstituted hydrocarbyl group or a hydrogen; z is ?1 to about 5; m is ?1 to about 5; PO is a polyolefin hydrocarbyl group comprising 10 to 4000 carbon atoms; and n is from 1 to about 10,000.

Abstract: Described herein are block copolymers having hydrophobic blocks and hydrophilic blocks which are effective in binding to the surface of hard tissue; compositions comprising the same, as well as methods of making and using the same are also described.

Abstract: A block copolymer composition containing a diblock copolymer blend including a first poly(methyl methacrylate)-b-poly((trimethylsilyl)methyl methacrylate) diblock copolymer; and, a second poly(methyl methacrylate)-b-poly((trimethylsilyl)methyl methacrylate) diblock copolymer. Also provided are substrates treated with the block copolymer composition.

Abstract: Disclosed herein are novel block polymers comprising at least one first block and at least one second block, wherein the at least one first block comprises at least one acrylate monomer of formula CH2?CH—COOR2 wherein R2 is chosen from C4 to C12 cycloalkyl groups and at least one methacrylate monomer of formula CH2?C(CH3)—COOR?2 wherein R?2 is chosen from C4 to C12 cycloalkyl groups, and the second block comprises at least one acrylic acid monomer and at least one monomer with a glass transition temperature of less than or equal to 20° C. Also disclosed herein is a process for the preparation of such polymers which may be carried out continuously in a single reactor. Finally, further disclosed herein are compositions comprising the novel polymers and processes using the composition for making up and/or caring for keratinous substances or for improving the hold of a cosmetic composition while maintaining its gloss.

Abstract: Methods for fabricating sub-lithographic, nanoscale microstructures utilizing self-assembling block copolymers, and films and devices formed from these methods are provided.

Abstract: A curable resin composition, which contains, with respect to 100 parts of an epoxy resin, 1 to 70 parts of an epoxy resin curing agent and 1 to 50 parts of an acrylic block copolymer, and the acrylic block copolymer contains (?) at least one polymer block A composed of a structural unit derived from an alkyl methacrylate and at least one polymer block B composed of a structural unit derived from an alkyl acrylate, has a weight average molecular weight (Mw) of 30,000 to 300,000 and a molecular weight distribution (Mw/Mn) of 1.5 or less, and contains 3 to 60 percent by mass of the polymer block A. In addition, a cured resin is formed from the above curable resin composition.

Abstract: A copolymer composition including a block copolymer having a poly(methyl methacrylate) block and a poly((trimethylsilyl)methyl methacrylate) block is provided; wherein the block copolymer exhibits a number average molecular weight, MN, of 1 to 1,000 kg/mol; and, wherein the block copolymer exhibits a polydispersity, PD, of 1 to 2. Also provided are substrates treated with the copolymer composition.

Abstract: It is an object of the present invention to provide a copolymer for a cured product that is satisfactory in properties, such as adhesion properties, as a chip stacking adhesive or the like. The present invention is a star polymer comprising, as an arm portion, a polymer chain containing repeating units represented by formula (I) and formula (II), and comprising a core portion derived from a monomer represented by formula (III), wherein a molar ratio of the repeating unit represented by formula (I) to the repeating unit represented by formula (II) ((I)/(II)) in the arm portion is in the range of 60/40 to 95/5.

Abstract: A polymer composition comprising star macromolecules is provided. Each star macromolecule has a core and five or more arms, wherein the number of arms within a star macromolecule varies across the composition of star molecules. The arms on a star are covalently attached to the core of the star; each arm comprises one or more (co)polymer segments; and at least one arm and/or at least one segment exhibits a different solubility from at least one other arm or one other segment, respectively, in a reference liquid of interest.

Abstract: The present invention relates to an impact modifier and a device and a method for the production thereof, as well as to a method for preparing a thermoset material, or a thermoset material precursor, from the impact modifier. The impact modifier comprises at least one copolymer selected from A-B-A, A-B, and A-B-C block copolymers in which: each block is linked to the other by means of a covalent bond or an intermediate molecule that is connected to one of the blocks by a covalent bond and to the other block by another covalent bond; A is a PMMA homopolymer or a copolymer of methyl methacrylate, A preferably being compatible with the resin; C is either (i) a PMMA homopolymer or a copolymer of methyl methacrylate, or (ii) a polymer based on monomers or a mixture of vinyl monomers, and blocks A and C are identical; and B is incompatible or partially compatible with the thermoset resin and incompatible with block A and optional block C.

Abstract: Disclosed are a resin composition for laser engraving, including an acrylic block copolymer; a relief printing plate precursor for laser engraving comprising a relief-forming layer formed from the resin composition on a support; a process for producing the relief printing plate precursor; a process of making a relief printing plate using the relief printing plate precursor; and a relief printing plate having a relief layer which is manufactured by the process.

Abstract: Disclosed is an emulsion binder containing an A-B block copolymer. The A-B block copolymer has a number average molecular weight of 5,000 to 100,000, and a polydispersity index (weight average molecular weight/number average molecular weight) of not greater than 1.7. The polymer block A has an acid value of 0 to 30 mgKOH/g and a glass transition point of not higher than 60° C. The polymer block B has an acid value of 75 to 250 mgKOH/g. The A-B block copolymer has been neutralized with an alkaline material, and has been allowed to self-emulsify in an aqueous medium to form emulsion particles having an average particle size of 30 to 300 nm.

Abstract: The invention relates to polymer particles in the form of filaments formed by block copolymers, as well as to the method for preparing same by means of controlled radical polymerization in emulsion in the presence of a specific living macroinitiator derived from a nitroxide. The invention is characterized in that the filamentous particles are obtained in a dispersed aqueous medium by means of the synthesis of said block copolymers, performed by heating the reaction medium at a temperature of 60 to 120° C., the final block copolymer containing between 10 and 50 mol. % of the macroinitiator which is water soluble and the hydrophobic monomer conversion rate being at least 50%. According to the invention, the weight ratio of hydrophilic fraction of the filamentous particles is less than 25 wt %.

Abstract: A modifier for polyvinylidene fluoride (PVDF), which improves the adhesion of PVDF to a metal, a binder resin composition for battery and a battery using the PVDF modifier are provided. The modifier for polyvinylidene fluoride herein is a modifier in which the peeling strength of a specific cured film to an aluminium foil is 20 g/cm or more, and the specific cured film is obtained from a mixture of 6 parts by mass of the modifier for polyvinylidene fluoride and 14 parts by mass of a polyvinylidene fluoride composition. The modifier preferably contains a macromonomer copolymer (X), obtained by polymerizing both a macromonomer (A) having unsaturated double bonds and a vinyl monomer (B) having polar groups. The macromonomer (A) is preferably a methacrylic acid ester-based macromonomer (A-1). The vinyl monomer (B) is preferably a methacrylate, and a fluoroalkyl methacrylate.

Abstract: Disclosed herein is a block copolymer comprising a first block derived from a vinyl aromatic monomer; and a second block derived from an acrylate monomer; where a chi parameter that measures interactions between the first block and the second block is greater than or equal to about 0.05, when measured at 240° C. Disclosed herein too is a method comprising polymerizing a vinyl aromatic monomer to form a first block; and polymerizing a second block onto the first block to form a block copolymer; where the second block is derived by polymerizing an acrylate monomer; and where the block copolymer has a chi parameter of greater than or equal to about 0.05, when measured at 240° C.; where the chi parameter is a measure of interactions between the first block and the second block.

Abstract: Disclosed is an interfacial polymer for a network used as a coupling agent in mixing of rubber-silica. More particularly, the interfacial polymer for a rubber-silica network is a block copolymer containing a copolymer of conjugated diene and vinyl aromatic monomers, in which when used as a coupling agent in the mixing of synthetic rubber and silica (an inorganic material), the polymer enhances silica dispersibility within the rubber, and improves compatibility and processability, resulting in considerable improvement in the dynamic property as well as the mechanical property of the rubber, and when used in a tire, etc., it enhances automobile braking performance and reduces rolling resistance.