Abstract: A composite for moldings having the high bending elastic modulus and the high bending strength, comprising a thermoplastic resin and a polymerizable monomer which is a multifunctional polymerizable monomer having an alicyclic strucure unit or a mixture consisting of a multifunctional polymerizable monomer having an alicyclic strucure unit and a monofunctional polymerizable monomer having at least two alicyclic structure units, is prepared by compounding them. Also, a composite for moldings having the high bending elastic modulus and the high bending strength, comprising a vinyl chloride resin, a (meth)acrylate monomer which is a multifunctional (meth)acrylate or a mixture consisting of a multifunctional (meth)acrylate and a monofunctional (meth)acrylate, and a polymerization initiator. The composite has good workability. Further, an unfluid precursor for moldings is prepared by heating the composite.

Abstract: Environmentally friendly, disposable, degradable and/or recyclable plastic articles are made from water soluble, miscible, high molecular weight, thermoplastic, polymeric resin blends that are comprised by weight of about 65% to 95% high molecular weight water soluble thermoplastic resin having an inverse solubility characteristic and about 35% to 5% of at least one of certain high molecular weight thermoplastic polymers that are functionally compatible (miscible) with the inversely soluble resin. The articles are insoluble when used for their intended purposes, but become soluble when exposed to tepid or cool water and degradable when buried in a land fill or compost. The inversely soluble resin comprises high molecular weight poly(ethylene oxide). The compatible polymer is selected from the group consisting of Nylon 11, Nylon 12, polycaprolactone, polycaprolactone, polyethylene-co-acrylic acid, polyethylene-co-methacrylic acid, polyethylene-co-vinylacetate and polyethylene-co-vinylalcohol.

Abstract: Thermosetting composition is excellent in storage stability, useful as one component thermosetting composition, gives cured products having excellent chemical properties, physical properties and weathering resistance and is favorably utilized in coating compositions, ink, adhesive and molded plastics.The thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating and optionally a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.

Abstract: Disclosed are fibers comprising a graft copolymer consisting of a propylene polymer material backbone having graft polymerized thereto an ethylenically unsaturated monomer(s) or a blend of at least two of said graft copolymers.

Abstract: A hydrogenated diene block copolymer having a polystyrene-reduced number-average molecular weight of 50,000-600,000 which is a hydrogenation product of an (A)-(B) block copolymer in which (A) means an alkenyl aromatic compound polymer block and (B) means a conjugated diene homopolymer block wherein the vinyl content of the conjugated diene portion is more than 60%, or an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15% or more, an (A)-(B)-(C) block copolymer in which (A) and (B) are as defined above and (C) means an alkenyl aromatic compound-conjugated diene copolymer tapered block wherein the proportion of the alkenyl aromatic compound increases gradually, or an (A)-(B)-(A) block copolymer in which (A) and (B) are as defined above. Said hydrogenated diene block copolymer is useful as a modifier for polar resins, non-polar resins or both of them.

Abstract: Multi-stage polymer process and composition having an alkali-insoluble emulsion polymer and an alkali-soluble polymer are produced by a two-stage sequential emulsion polymerization process. When the multi-stage polymers of this invention are utilized as cement modifiers, improvements in cement mortar physical properties are realized.

Abstract: A fluorochemical graft copolymer comprising: a base polymer comprising polymerized units derived from monomers having terminal olefinic double bonds, having grafted thereto a plurality of polyfluoropolyether groups, Also disclosed is a process for preparing such a graft copolymer, and a method for reducing the surface energy of a polymer comprising polymerized units derived from monomers having terminal olefinic double bonds.

Abstract: A hydrogenated diene block copolymer having a polystyrene-reduced number-average molecular weight of 50,000-600,000 which is a hydrogenation product of an (A)-(B) block copolymer in which (A) means an alkenyl aromatic compound polymer block and (B) means a conjugated diene homopolymer block wherein the vinyl content of the conjugated diene portion is more than 60%, or an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15% or more, an (A)-(B)-(C) block copolymer in which (A) and (B) are as defined above and (C) means an alkenyl aromatic compound-conjugated diene copolymer tapered block wherein the proportion of the alkenyl aromatic compound increases gradually, or an (A)-(B)-(A) block copolymer in which (A) and (B) are as defined above and in which hydrogenation product at least 80% of the double bonds of the conjugated diene portion is saturated by the hydrogenation.

Abstract: The subject invention relates to segmented fluoropolymers of the A-B-A type where A is a crystallizable fluoropolymer segment, and B is a base-resistant elastomeric fluoropolymer segment, the segmented fluoropolymers being useful as thermoplastic fluoroelastomers which are highly resistant to attack by bases. The fluoroelastomers are useful, for example, in O-rings and shaft seals in internal combustion engines using aggressive oils and in oil well applications.

Abstract: A crosslinkable resin composition containing:(A) from 10% to 90% by weight of a thermoplastic resin component,(B) from 90% to 10% by weight of a curable resin component, comprising, expressed by reference to the curable resin (100%),(i) 50% to 95% of a (meth)acryloyl derivative, and(ii) 50% to 5% of a (meth)allyloxy derivative, and(C) from 0% to 30% by weight of a plasticiser for the thermoplastic resin component, is disclosed.Also a new crosslinked resin layer and a process for the manufacture of the new crosslinked resin layer on a substrate are described.The crosslinked resin layer herein exhibits a desirable balance between flexibility, resistance to stain and resistance to scuff properties, in combination with outstanding mechanical and chemical properties.The crosslinkable resin composition is particularly suitable for coating application of various substrates such as flooring materials, wall covering materials, coils, wires, and various shaped articles e.g. cars, containers and metallic profiles.

Abstract: Graft copolymers obtained byA) emulsion polymerization of from 5 to 35% by weight of a monomer mixture ofa.sub.1) 60-80% by weight of one or more vinylaromatic monomers,a.sub.2) 20-40% by weight of one or more ethylenically unsaturated nitriles,B) subsequent emulsion polymerization, in the presence of the emulsion polymer obtained in stage A), of 20-45% by weight of a monomer mixture ofb.sub.1) 50-75% by weight of one or more vinylaromatic monomers,b.sub.2) 25-50% by weight of one or more C.sub.1 -C.sub.18 -alkyl acrylates,C) subsequent emulsion polymerization, in the presence of the emulsion polymer obtained in stage B), of 5-35% by weight of a monomer mixture ofc.sub.1) 60-80% by weight of one or more vinylaromatic monomers,c.sub.2) 20-40% by weight of one or more ethylenically unsaturated nitriles,D) subsequent emulsion polymerization, in the presence of the emulsion polymer obtained in stage C), of 15-45% by weight of a monomer mixture ofd.sub.1) 80-99.9% by weight of one or more C.sub.1 -C.sub.

Abstract: A pigment dispersing agent for paints is constituted with a particular acrylic polymer component having a tertiary amino group and/or a nitrogen-containing heterocyclic ring and a particular polyester component, and has particular number average molecular weight and amine value. This pigment dispersing agent is applicable to both acrylic resin series and polyester resin series paints as well as thermosetting type paints.

Abstract: This application discloses linear methacrylic ABC triblock polymers in which the composition of each of the three blocks is different and wherein at least one of the blocks is hydrophobic and at least one of the blocks is hydrophilic.

Abstract: Novel styrene derivatives are disclosed of the formula: ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and each represents a saturated aliphatic hydrocarbon group or an aromatic hydrocarbon group, and R.sub.3 is --OH, Cl, or a group of the formula --OR.sub.4 or ##STR2## wherein R.sub.4 represents a saturated aliphatic hydrocarbon group or an aromatic hydrocarbon groups. The functionalized styrene monomers I as well as polymers and copolymers incorporating such monomer units are useful as initiators, or precursors thereof, for the polymerization of isobutylene under cationic conditions to give graft copolymers containing both styrenic and isobutylenic units. These copolymers have commercial applications such as rubbers, coatings, and luricants.

Abstract: A hydrogenated diene block copolymer having a polystyrene-reduced number-average molecular weight of 50,000-600,000 which is a hydrogenation product of an (A)--(B) block copolymer in which (A) means an alkenyl aromatic compound polymer block and (B) means a conjugated diene homopolymer block wherein the vinyl content of the conjugated diene portion is more than 60%, or an alkenyl aromatic compound-conjugated diene random copolymer block wherein the vinyl content of the conjugated diene portion is 15% or more, an (A)--(B)--(C) block copolymer in which (A) and (B) are as defined above and (C) means an alkenyl aromatic compound-conjugated diene copolymer tapered block wherein the proportion of the alkenyl aromatic compound increases gradually, or an (A)--(B)--(A) block copolymer in which (A) and (B) are as defined above, in which block copolymer(1) the weight proportion of theh alkenyl aromatic compound/the conjugated diene is 5/95 to 60/40, and(2) the content of the bound alkenyl aromatic compound in at least o

Abstract: A modified polymer rubber is obtained by(1) graft-polymerizing at least one grafting monomer to a shreaded rubbery polymer (A) in an aqueous suspension at a temperature of 30.degree.-130.degree. C. to obtain a graft polymer, and(2) kneading the graft polymer with at least one polymerizable monomer in the presence of a free radical initiator at a temperature of 180.degree.-280.degree. C. This process does not cause gel formation and is advantageous in manufacturing cost.The modified polymer rubber thus obtained is excellent in processability and storage stability, and highly useful as a compatibilizer for various resins.

Abstract: There is here provided a thermoplastic resin composition which comprises (I) 50 to 99% by weight of a polyamide resin, and (II) 50 to 1% by weight of a multi-phase structure thermoplastic resin which is composed of 5 to 95% by weight of at least one ethylene copolymer selected from the group consisting of epoxy group-containing ethylene copolymers, ethylene-unsaturated carboxylic acids, alkyl ester copolymers and metallic salts of the ethylene-unsaturated carboxylic acids, and ethylene-vinyl ester copolymers, and 95 to 5% by weight of a vinyl polymer or copolymer obtained from at least one vinyl monomer, either of both the components possessing a dispersion phase where each particle has a diameter of 0.001 to 10 .mu.m. A method for preparing the above-mentioned thermoplastic resin composition is also provided here.

Abstract: Disclosed is a methacrylic resin cast plate which is comprised of 100 parts by weight of [I] polymethyl methacrylate or a methyl methacrylate copolymer containing at least 90% by weight of methyl methacrylate units and, dispersed therein, a graft copolymer [IV] obtained by graft-polymerizing a hard resin component [III] containing at least 90% by weight of methyl methacrylate units onto a crosslinked rubbery copolymer [II] containing at least 45% by weight of butyl acrylate units and having an average particle diameter of 0.1 to 1 .mu.m, the amount of the graft copolymer [IV] being 2 to 30 parts by weight as the amount of the crosslinked rubbery copolymer.

Abstract: Radiation curable compositions useful as coatings for wood, metal, glass, fabric, paper, fiber and plastics are made from copolymers of 4-hydroxystyrene and an alkadiene or an allyl ester of an ethylenically unsaturated acid blended wit ethylenically unsaturated compounds.

Abstract: Vinyl ether copolymers and a method of preparing the same. The vinyl ether is copolymerized with styrene, alkyl-substituted styrenes, alkoxy-substituted styrenes and mixtures thereof. In the process, a cadmium halide is used with hydrogen iodide or a suitable iodine containing electrophile, as the coinitiator.

Abstract: A graft copolymer produced by polymerizing an ethylenically unsaturated monomer in the presence of a fluorine-containing resin having reactive double bonds via a urethane linkage is excellent in transparency and pigment dispersibility and can provide a coating composition excellent in weather resistance.

Abstract: A method of producing a modified polypropylene comprising the step of graft-polymerizing a propylene random copolymer containing an unconjugated diene comonomer represented by the general formula: ##STR1## wherein R.sub.1 -R.sub.4 are H or an alkyl group having 1-6 carbon atoms, and n is an integer of 1-20, with a monomer having an unsaturated bond by a radical method.

Abstract: A self-curing aqueous resin dispersion obtained by neutralizing a resin having at least one alicyclic epoxy group and at least two carboxyl groups in the molecule, with a base and dispersing the neutralized resin in water.

Abstract: Vinyl ether copolymers and a method of preparing the same. The vinyl ether is copolymerized with styrene, alkyl-substituted styrenes, alkoxy-substituted styrenes and mixtures thereof. In the process, a cadmium halide is used with hydrogen iodide or a suitable iodine containing electrophile, as the coinitiator.

Abstract: Cationically polymerizable styryloxy resins having urethane linkages, represented by the formula III ##STR1## wherein R.sup.1 and R.sup.2 are H, or one of R.sup.1 and R.sup.2 is H and the other is methyl;R.sup.3 and R.sup.4 (which may be the same or different) are H, lower alkyl, or alkoxy if R.sup.2 is not methyl;R.sup.5 is a divalent hydrocarbon radical;G.sup.1 is an n-valent hydrocarbon radical free of amino, aliphatic thiol, aliphatic hydroxyl or other groups which interfere with cationic polymerization;and n is an integer of 2 or more.G.sup.1 is a hydrocarbon backbone which is not interrupted by a hetero atom. Preferably G.sup.1 is a residue of a diene homopolymer or copolymer, in which case the resins produce flexible polymers. The resins are polymerized with a cationic polymerization initiator or latent acid catalyst. The resins have utility in the field of electronics.

Abstract: Radiation curable compositions useful as coatings for wood, metal, glass, fabric, paper, fiber and plastics are made from homopolymers of 4-acetoxystyrene or homopolymers of 4-hydroxystyrene blended with ethylenically unsaturated compounds.

Abstract: Resin compositions obtained by causing copolymerization of particular radical (co-and/or) polymerizable organic peroxide and vinyl monomer in particular propylene polymers and that it is a best way to use an aqueous suspension in the manufacture.

Abstract: A thermosetting resin composition comprising a special poly(p-hydroxystyrene) derivative resin and a radical polymerization initiator, and if necessary an epoxy modified polybutadiene, can provide prepregs and laminates having a low dielectric constant, a shorter signalling delay time, good heat resistance and flame retardancy and thus being suitable for producing multilayer printed circuit boards.

Abstract: Improved core-shell polymers having an alkali-insoluble core and an alkali-soluble shell are prepared by emulsion polymerization of the core-shell polymers utilizing compounds which chemically graft the core and shell together. The core-shell polymers exhibit improved solvent stability, water resistance, heat resistance and rheology. The polymers are useful in application such as inks, coatings and varnishes, floor polishes, leather treatment, cement formulations, and as a seed for further emulsion polymerization.

Abstract: A graft precursor is formed by preparing a propylene polymer suspension having a propylene polymer suspended in water and a solution having a specific radically (co)polymerizable organic peroxide and a specific radical polymerization initiator dissolved in specific amounts in a vinyl monomer, mixing the propylene suspension and the solution in a specific ratio, heating and stirring the resultant mixture under conditions incapable of inducing substantial decomposition of the polymerization initiator, and further elevating the temperature of the mixture after the total amount of the vinyl monomer, the radically (co)polymerizable organic peroxide, and the radical polymerization initiator has decreased to less than 50% by weight of the initial total amount. Then a graft resin composition is produced by melting and kneading the graft precursor, either by itself or in combination with a propylene polymer and a vinyl polymer, at a temperature in the range of 100.degree. to 300.degree. C.

Abstract: Graft polymers are prepared by reacting an ethylenically unsaturated polymerizable monomer with a polymer of an olefin of 2 to about 8 carbon atoms in a process wherein the olefin polymer is substantially insoluble in the monomer but is capable of absorbing the monomer. In a preferred aspect, a vinyl halide polyolefin graft polymer is produced by reacting a solid polyolefin particle with a vinyl halide monomer in which the polyolefin is substantially insoluble, but is capable of absorbing the monomer. The solid particles can be contacted with the monomer in one step or in stages. When the stage-wise reaction is continued until the proportion of polyolefin in the polymer product is about 2 to about 20 weight percent, the resulting product can be formed to a transparent or translucent article.

Abstract: Homogeneous thermoset copolymers which may be used in the preparation of laminates for circuitry boards will comprise a poly(vinyl benzyl ether) of a polyphenol and a polyalkadiene in which the alkadiene monomer will contain from 3 to about 8 carbon atoms. The polymers are prepared by admixing a solution of the poly(vinyl benzyl ether) of a polyphenol dissolved in an organic solvent with a solution of the polyalkadiene also dissolved in an organic solvent. The admixing is done at an elevated temperature to form the desired composite. The resulting copolymer will possess desirable characteristics such as high glass transition temperature and low dielectric constant.

Abstract: A therapeutic composition comprising a therapeutic macromolecular agent incorporated in cross-linked polyacetal.

Abstract: A process is provided for metallating ethylene polymers which have polymerized therein a minor amount of nonconjugated diene. Metallation is accomplished with a blend of three metallating reagents: (a) an alkyllithium compound; (b) a potassium alkoxide; and (c) a chelating tertiary diamine. The metallated polymers so prepared may be reacted with one or more anionically polymerizable monomers to form graft polymers or with a reagent such as carbon dioxide to form a functionalized polymer. When the anionically polymerizable monomer has two or more polymerizable sites, the metallated polymer is reacted with a modifying compound such as alpha-methylstyrene before it is reacted with the monomer(s). Certain of the graft polymers behave as thermoplastic elastomers whereas others are thermoplastic. The blend of metallating reagents may be used with any polymer having partial or complete unsaturation.

Abstract: Adhesive compositions with thermoreversible crosslinking resulting from the reaction of a divinyl ether having the formula CH.sub.2 .dbd.CH--O--R--O--CH.dbd.CH.sub.2, R being aliphatic, armomatic or cycloaliphatic, with a copolymer resulting from the copolymerization of an olefin with an ethylenically unsaturated monocarboxylic acid and, optionally, an ester of an ethylenically unsaturated monocarboxylic acid, the proportion being 0.1 to 5 percent by weight of the divinyl ether to 99.9 to 95 percent by weight of the copolymer.

Abstract: A process for producing a novel photosensitive resin having cinnamic groups, comprising reacting a polyallylamine represented by the general formula (I) ##STR1## (wherein n is at least 10) or an inorganic acid salt thereof with a compound having a cinnamic group in the presence of a solvent. The process is free from drawbacks as experienced in the production of a conventional photosensitive resin (e.g. polyvinyl cinnamate), such as formation of by-products during the polymerization of a monomer (e.g. vinyl cinnamate).

Abstract: A process for producing a resin composition which comprises suspension-polymerizing at least one vinyl monomer in an aqueous medium in the presence of a dispersing agent, said suspension polymerization being carried out using a nonionic dispersant as said dispersing agent in the presence of a high-molecular-weight vinyl polymer having a weight average molecular weight of at least 500,000 obtained by emulsion polymerization.

Abstract: A thermoplastic, melt-processible, elastomeric composition based on partially crosslinked compatible blends of an ethylene copolymer and a vinyl or vinylidene halide polymer.

Abstract: Polymeric dyes having pendent chromophore groups which are selected from azo, tricyanovinyl, anthraquinone, methine, and indoaniline groups fall into two classes, [A] condensation polymers, and [B] polymers derived from copolymerized ethylenically-unsaturated monomers, the dyes being capable of undergoing thermoplastic deformation by a focused laser beam when in a layer of thickness in the range of 0.1 to 100 micrometers and having an absorptivity in the range of 10 to 250 Lg.sup.-1 cm.sup.-1. They are film-forming, thermally- and light-stable, and solvent-coatable. These compounds are useful as coloring and light-absorbing agents, particularly as the light-absorbing agents in thin optical recording layers.

Abstract: Adhesive compositions with thermoreversible crosslinking resulting from the reaction of a divinyl ether having the formula CH.sub.2 .dbd.CH--O--R--O--CH.dbd.CH.sub.2, R being aliphatic, aromatic or cycloaliphatic, with a copolymer resulting from the copolymerization of an olefin with an ethylenically unsaturated monocarboxylic acid and, optionally, an ester of an ethylenically unsaturated monocarboxylic acid, the proportion being 0.1 to 5 percent by weight of the divinyl ether to 99.9 to 95 percent by weight of the copolymer.

Abstract: A thermoplastic, melt-processible, elastomeric composition based on partially crosslinked compatible blends of an ethylene copolymer and a vinyl or vinylidene halide polymer.

Abstract: Acrylic films having superior properties are produced by casting a solution comprising an organic solvent and a polymer system of one or more completely polymerized acrylic polymers onto a carrier, removing the solvent thereby forming the film on the carrier, and stripping the film from the carrier.The polymer system comprises at least one polymer prepared by polymerizing monomers of the general formula (I): ##STR1## wherein: R.sub.1 is hydrogen or methyl; and R.sub.2 is straight branched alkyl of about 1-20 carbon atoms, preferably about 1-8 carbon atoms, more preferably 1-4 carbon atoms, and most preferably 1-2 carbon atoms.The polymers are homopolymers, mixed copolymers, and graft copolymers. They may be cross-linked.

Abstract: An antistatic resinours composition comprising (A) graft copolymers prepared by emulsion polymerization of (a) monomer mixture consisting of (i) from 50 to 100 percents by weight of monomers having polyalkylene oxide chains and (ii) from 50 to 0 percents by weight of vinyl monomers in the presence of rubbers and (B) thermoplastic resins compatible with the graft copolymers, has permanent antistatic performances, superior mechanical properties and high flowability.

Abstract: Graft polymers are prepared by reacting an ethylenically unsaturated polymerizable monomer with a polymer of an olefin of 2 to about 8 carbon atoms in a process wherein the olefin polymer is substantially insoluble in the monomer but is capable of absorbing the monomer. In a preferred aspect, a vinyl halide polyolefin graft polymer is produced by reacting a solid polyolefin particle with a vinyl halide monomer in which the polyolefin is substantially insoluble, but is capable of absorbing the monomer. The solid particles can be contacted with the monomer in one step or in stages. When the stage-wise reaction is contined until the proportion of polyolefin in the polymer product is about 2 to about 20 weight percent, the resulting product can be formed to a transparent or translucent article.

Abstract: The method and production of macromolecular monomers from cationically polymerizable monomers and vinyl-substituted hydrocarbon halides is disclosed. These cationically polymerizable monomers may react in the presence of a catalyst with the hydrocarbon halide to produce a macromer retaining a polymerizable headgroup. This compound may be used in a variety of copolymerization processes with a variety of copolymerizable monomers to form graft copolymers.

Abstract: A diffusion control layer comprising a polymerization product of a monomer capable of undergoing .beta.-elimination in an alkaline environment is disclosed for use in diffusion transfer film units, as an interlayer or overcoat in photosensitive elements, or as a timing layer or overcoat in image-receiving elements.

Abstract: Provided is an antithrombogenic biomedical material comprising a copolymer of (A) not less than 5% by weight of one or more polymerizable monomers having a polyethylene oxide unit with a degree of polymerization not less than 5 and a polymerizable carbon-carbon double bond and (B) not more than 95% by weight of one or more monomers copolymerizable with said monomer (A).

Abstract: A process for the impact modification of a plastic with a rubbery polymer to form a thermoplastic resin in a reactor extruder is provided. The process includes the steps of dissolving a rubbery polymer in at least one ethylenically unsaturated monomer to form a feed solution, introducing the feed solution into the feed section of a twin screw reactor extruder, heating the feed solution under pressure to a temperature sufficient for polymerization to begin, shearing the feed solution until the solids content formed is equal to at least about twice the rubber content in the feed solution so as to produce a phase inversion product wherein discrete particles of rubber become encapsulated in a continuous phase of plastic polymer formed from the ethylenically unsaturated monomer, thereafter reacting the phase inversion product until at least about 70 weight percent of the feed solution has been converted to a thermoplastic resin, and extruding the said thermoplastic resin through a die.

Abstract: The use of alkyl acrylate in the preparation of the soft component of impact-resistant polystyrene based on polystyrene-grafted butadiene mixed with polyphenylene ether reduces the dust attraction of moldings prepared from this type of mixture.

Abstract: The char-forming characteristics of vinyl aromatic polymers are improved by the incorporation therein of (1) active allyl and/or benzyl carbon moieties and (2) an arylsulfonate ester. In an example, a styrenic polymer comprising polyvinylbenzylacetate is given increased char-forming ability by the presence of pentaerythritol parabromobenzenesulfonate.