Acyclic Hydrocarbon Is Ethylene Patents (Class 525/324)
  • Patent number: 7858707
    Abstract: A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.
    Type: Grant
    Filed: September 14, 2006
    Date of Patent: December 28, 2010
    Assignee: Dow Global Technologies Inc.
    Inventors: Daniel J. Arriola, Edmund M. Carnahan, David D. Devore, Phillip D. Hustad, Brian A. Jazdzewski, Roger L. Kuhlman, Francis J. Timmers, Timothy T. Wenzel
  • Patent number: 7858706
    Abstract: A composition for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first metal complex olefin polymerization catalyst, (B) a second metal complex olefin polymerization catalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by catalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.
    Type: Grant
    Filed: March 17, 2005
    Date of Patent: December 28, 2010
    Assignee: Dow Global Technologies Inc.
    Inventors: Daniel J. Arriola, Edmund M. Carnahan, Yunwa Wilson Cheung, David D. Devore, David D. Graf, Phillip D. Hustad, Roger L. Kuhlman, Colin Li Pi Shan, Benjamin C. Poon, Gordon R. Roof, James C. Stevens, Pamela J. Stirn, Timothy T. Wenzel
  • Publication number: 20090233063
    Abstract: There are provided a liquid composition for making pigment fixed having a high resistance to rubbing and a good dry-cleanability; an ink set including the liquid composition for making pigment fixed and an ink composition excellent in terms of color intensity, discharge stability, and adhesiveness; and a method for producing ink-jet-recorded matter on a fabric having a high resistance to rubbing and good dry-cleanability using the liquid composition for making pigment fixed and the ink composition. The liquid composition for making pigment fixed according to the present invention contains at least polymer fine particles synthesized using an alkyl (meth)acrylate and/or cyclic alkyl (meth)acrylate and a reactive compound having an ethylene-based unsaturated compound and a reactive group, the glass transition temperature and the acid value of the liquid composition being equal to or lower than ?10° C. and equal to or lower than 100 mg KOH/g, respectively.
    Type: Application
    Filed: March 5, 2009
    Publication date: September 17, 2009
    Inventors: Masahiro YATAKE, Yoshimasa TAMURA
  • Publication number: 20090156729
    Abstract: An adhesive blend is described that can include a semi-crystalline copolymer of propylene and at least one comonomer selected from the group consisting of ethylene and at least one C4 to C20 ?-olefin, the copolymer having a weight average molecular weight (Mw) from about 15,000 to about 200,000; an melt index (MI) from about 7 dg/min to about 3000 dg/min as measured by ASTM D 1238(B), and a (Mw/Mn) of approximately 2. Various production processes are also described. Also described are adhesive compositions and methods for making adhesive compositions having polymers or polymer blends with melt flow rates (MFRs) equal to and above 250 dg/min. at 230 NC. Certain specific embodiments of the invention involve the use of a free radical initiator, e.g., a peroxide.
    Type: Application
    Filed: February 24, 2009
    Publication date: June 18, 2009
    Inventors: Anthony G. Karandinos, Keith A. Nelson, Jean M. Tancrede, Kenneth Lewtas, Sudhin Datta, Charles Cozewith, Bruce A. Harrington, David J. Lohse, Olivier J.F. Georjon
  • Publication number: 20090105407
    Abstract: An adhesive composition comprising a copolymer of propylene and at least one comonomer selected from the group consisting of ethylene and C4-20?-olefins, the copolymer having (i) a content of units derived from propylene of greater than about 50 mole percent, (ii) a Brookfield viscosity at 190 C from about 50 to about 100,000 cP, (iii) an MWD from about 1.5 to about 15, and (iv) containing less than about 50 ppm residual catalyst metal.
    Type: Application
    Filed: December 21, 2005
    Publication date: April 23, 2009
    Inventors: Teresa P. Karjala, Patricia Ansems, Charles F. Diehl, Selim Yalvac, Cynthia L. Rickey, Seema V. Karande, Angela N. Taha
  • Publication number: 20080293890
    Abstract: This invention relates to polyolefin compositions. In particular, the invention pertains to elastic polymer compositions that can be more easily processed on cast film lines, extrusion lamination or coating lines due to improved resistance to draw resonance. The compositions of the present invention comprise an elastomeric polyolefin resin and a high pressure low density type resin. The preferred compositions of the present invention comprise from 88 to 99 percent elastomer or plastomer and from 1 to 12 percent by weight of a high pressure low density type resin.
    Type: Application
    Filed: December 23, 2005
    Publication date: November 27, 2008
    Applicant: DOW GLOBAL TECHNOLOGIES INC.
    Inventors: Thomas I. Butler, Andy C. Chang, Jozef J. I. Van Dun, Ronald J. Weeks, Jeffrey D. Weinhold, Rajen M. Patel, David T. Gillespie
  • Publication number: 20080125521
    Abstract: The present invention relates to select elastomeric blends including at least one halogenated random copolymer. In particular, the present invention relates to compositions including at least one halogenated random copolymer of isobutylene and methylstyrene, preferably para-methylstyrene; wherein the at least one halogenated random copolymer includes at least 9.0 wt % methylstyrene, preferably para-methylstyrene, based upon the weight of the at least one halogenated random copolymer; and at least one general purpose rubber. The invention also relates to articles made from these compositions and processes for making the same.
    Type: Application
    Filed: September 30, 2005
    Publication date: May 29, 2008
    Inventors: Walter H. Waddell, Donald S. Tracey, Stuart W. Botfeld
  • Patent number: 7256240
    Abstract: In a process for producing a polymer blend, at least one first monomer is polymerized in a first slurry phase reaction zone in the presence of a supported first catalyst to produce a thermoplastic first polymer having a crystallinity of at least 30%. At least part of said first polymer is then contacted with at least one second monomer different from said first monomer in a second solution phase reaction zone in the presence of a second catalyst and in the absence of polyenes under conditions to produce a second polymer having a crystallinity of less than 20%.
    Type: Grant
    Filed: December 22, 2006
    Date of Patent: August 14, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Peijun Jiang
  • Patent number: 7019082
    Abstract: Embodiments of the present invention include a material comprising a polymer having a modulus of elasticity less than 105 Pa and a material comprising a polymer having a modulus of elasticity of less than 5×104 Pa. Embodiments also include a material comprising a polymeric network and a multiplicity of side chains attached to the polymeric network. The multiplicity of side chains may have an average molecular weight below the critical molecular weight for entanglements. In certain embodiments it may be advantageous for the side branches to have a glass transition temperature below the use temperature of the material. The polymer network may comprise at least two monomers so that the polymer network is a copolymer. Embodiments of the present invention also include methods of forming a polymer network. Such as, for example, a method of preparing a polymer network comprising cross-linking a polymer, wherein the polymer comprises a multiplicity of side chains.
    Type: Grant
    Filed: August 11, 2003
    Date of Patent: March 28, 2006
    Assignee: Carnegie Mellon University
    Inventors: Krzysztof Matyjaszewski, Tadeusz Pakula
  • Patent number: 6822051
    Abstract: The invention provides a polyethylene composition comprising a melt blend of (i) a bimodal high molecular weight high density polyethylene resin having a NCTL stress crack resistance of about 200 hours or greater, and (ii) a high density polyethylene resin selected from the group consisting of a homopolymer high density polyethylene resin, a copolymer high density polyethylene resin, and mixtures thereof, wherein the composition has a minimum NCTL stress crack resistance of 24 hours. In another embodiment, a polyethylene composition comprises a melt blend of the bimodal high molecular weight high density polyethylene resin and a linear low density polyethylene resin. The bimodal high molecular weight high density polyethylene resin can be a commodity film grade resin, the homopolymer and copolymer resins can be milk bottle grade and detergent bottle grade, respectively, and the linear low density polyethylene resin can be a film grade.
    Type: Grant
    Filed: March 29, 2002
    Date of Patent: November 23, 2004
    Assignee: Media Plus, Inc.
    Inventor: Michael G. Harris
  • Patent number: 6800688
    Abstract: A resin which has excellent adhesion to nonpolar substrates, is nontacky, and has satisfactory solubility in aromatic or nonaromatic solvents and satisfactory compatibility with other resins. The resin is a modified polyolefin resin having a weight-average molecular weight of 15,000 to 150,000 obtained by modifying a polyolefin resin by grafting thereto (A) an unsaturated polycarboxylic acid or a derivative thereof and (B) a (meth)acrylic ester represented by a specific general formula, the contents of (A) and (B) in the modified polyolefin resin being 0.1 to 20 wt. % and 0.1 to 30 wt. %, respectively.
    Type: Grant
    Filed: August 6, 2002
    Date of Patent: October 5, 2004
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Kazuhiro Usui, Kenichi Fujino, Terumasa Fujitaka, Tadashi Matsui, Hidetoshi Yoshioka, Shunji Sekiguchi
  • Patent number: 6797784
    Abstract: The invention relates to homopolymers and/or copolymers containing <100 ppm coarse particles with a particle diameter of between 200 and 500 &mgr;m, to thermoplastic moulding materials containing said homopolymtrs and/or copolymers, to the use of the homopolymers and/or copolymers and moulding materials for the production of moulded parts and to the moulded parts themselves.
    Type: Grant
    Filed: May 3, 2001
    Date of Patent: September 28, 2004
    Assignee: Bayer Aktiengesellschaft
    Inventors: Michael Zobel, Dieter Wittmann, Herbert Eichenauer, Alfred Eitel, Thomas Eckel, Bernd Keller, Hans-Bernhard Hauertmann, Dorothy Rose
  • Publication number: 20040147684
    Abstract: The present invention provides a coating composition for polyolefin resins, comprising a resin obtained by graft-copolymerizing at least one member selected from the group consisting of an &agr;,&bgr;-unsaturated carboxylic acid and an acid anhydride thereof with at least one member selected from the group consisting of polypropylene and a propylene-&agr;-olefin copolymer, chlorinating the graft copolymer to give an acid-modified chlorinated polyolefin, linking a (meth)acrylic ester having one hydroxyl group to the polyolefin via an ester linkage, and then graft-copolymerizing (meth)acrylic acid monomers with the polyolefin; and a process for producing the composition.
    Type: Application
    Filed: October 7, 2003
    Publication date: July 29, 2004
    Inventors: Takafumi Masuda, Shoji Maekawa, Shigeru Sugiyama, Shin-ichi Akiyama
  • Publication number: 20040121922
    Abstract: The present invention provides an olefin block copolymer for a viscosity index improver capable of preparing a lubricating oil composition having excellent low temperature properties and excellent balance between viscosity and shear stability, a viscosity index improver and a lubricating oil composition comprising the viscosity index improver.
    Type: Application
    Filed: November 26, 2003
    Publication date: June 24, 2004
    Inventors: Keiji Okada, Shigenobu Ikenaga, Ryousuke Kaneshige, Tomoaki Matsugi, Shinichi Kojoh, Terunori Fujita
  • Patent number: 6750289
    Abstract: A thermoplastic elastomer produced without a hydrogenation step is functionalized utilizing a free radical initiator and a functionalizing monomer having at least one point of unsaturation. The base polymers can be produced by copolymerizing an &agr;-olefin capable of producing an amorphous backbone with a comonomer which provides a “hook” for grafting to with a living polystyrene chain. Another method is to copolymerize an &agr;-olefin monomer system capable of producing an amorphous backbone with a comonomer containing a functional group from which an anionically polymerizable monomer is grown from the backbone. A third method involves copolymerizing an &agr;-olefin monomer system capable of giving an amorphous backbone with an olefin-terminated polystyrene comonomer. In a less preferred embodiment, a conventional EPDM polymer can be metallated and a monoalkenyl aromatic compound anionically polymerizable monomer grown from the backbone.
    Type: Grant
    Filed: January 23, 2003
    Date of Patent: June 15, 2004
    Assignee: Shell Oil Company
    Inventors: Bridget Ann Spence, Ronald James Hoxmeier, Robert Charles Job
  • Patent number: 6579922
    Abstract: Provided is a high density multimodal polyethylene, having a shear ratio (SR) of 18 or more and comprising at least 20% by weight of a high molecular weight fraction, which high molecular weight fraction has: (a) a density (p) of 0.930 g/cm3 or less; and (b) a high load melt index (HLMI) of 0.30 g/10 mins or less.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: June 17, 2003
    Assignee: Fina Research, S.A.
    Inventor: Etienne Laurent
  • Patent number: 6569948
    Abstract: Provided is a high density multimodal polyethylene, having a shear ratio (SR) of 18 or more and comprising at least 20% by weight of a high molecular weight fraction, which high molecular weight fraction has: (a) a density (p) of 0.930 g/cm3 or less; and (b) a high load melt index (HLMI) of 0.30 g/10 mins or less.
    Type: Grant
    Filed: April 10, 2002
    Date of Patent: May 27, 2003
    Assignee: Fina Research, S.A.
    Inventor: Etienne Laurent
  • Patent number: 6566446
    Abstract: A new process of interpolymerizing ethylene interpolymer products having improved properties, such as increased onset of crystallization temperature, is disclosed. Preferably, the process comprises interpolymerizing a first homogeneous ethylene/alpha-olefin interpolymer and at least one second homogeneous ethylene/alpha-olefin interpolymer using at least two constrained geometry catalysts having different reactivities such that the first ethylene/alpha-olefin interpolymer has a narrow molecular weight distribution (NMWD) with a very high comonomer content and relatively high molecular weight and the second ethylene/alpha-olefin interpolymer has a NMWD with a low comonomer content and a molecular weight lower than that of the first interpolymer. The resultant first homogeneous interpolymer is combined with the resultant second homogeneous interpolymer in appropriate weight ratios resulting in the desired finished polymer structure.
    Type: Grant
    Filed: September 18, 1997
    Date of Patent: May 20, 2003
    Assignee: Dow Global Technologies Inc.
    Inventors: Deepak R. Parikh, Robert S. Cardwell, Brian W. S. Kolthammer
  • Publication number: 20030088021
    Abstract: Blend compositions containing a novel homopolymer, the use of which allows the incorporation of more comonomer in the additional components of the blend (for the same overall density) resulting in increased tie molecule formation and improvement in properties such as ESCR, toughness and impact strength are disclosed. The homopolymers are important for applications where a high density is needed to ensure certain mechanical properties like abrasion resistance, indentation resistance, pressure resistance, topload resistance, modulus of elasticity, or morphology (for the chlorination of PE to CPE) and additional advantages such as melt processability. The blend can be obtained by dry or melt mixing the already produced components, or through in-situ production by in parallel and/or in series arranged reactors. These resins can be used in applications such as films, blow molded, injection molded, and rotomolded articles, fibres, and cable and wire coatings and jacketings and, various forms of pipe.
    Type: Application
    Filed: June 13, 2002
    Publication date: May 8, 2003
    Applicant: The Dow Chemical Company
    Inventors: Jozef J. Van Dun, Akira Miyamoto, Grant B. Jacobsen, Fumio Matsushita, Schouterden J. Patrick, Spencer Lee, Pak-Wing S. Chum, Larry A. Meiske, Wauteraerts L. Peter
  • Publication number: 20030073785
    Abstract: The present invention provides an olefin block copolymer for a viscosity index improver capable of preparing a lubricating oil composition having excellent low temperature properties and excellent balance between viscosity and shear stability, a viscosity index improver and a lubricating oil composition comprising the viscosity index improver.
    Type: Application
    Filed: May 31, 2002
    Publication date: April 17, 2003
    Inventors: Keiji Okada, Shigenobu Ikenaga, Ryousuke Kaneshige, Tomoaki Matsugi, Shinichi Kojoh, Terunori Fujita
  • Patent number: 6545088
    Abstract: Ethylene, an &agr;-olefin and, optionally, a diene monomer are polymerized in a process comprising the step of contacting (1) ethylene, (2) at least one C3-C20 aliphatic &agr;-olefin, (3) optionally, at least one C4-C20 diene, (4) a catalyst comprising (a) a metallocene complex, and (b) an activator, and (5) a solvent. The process is conducted in either a single reactor or in multiple reactors, the latter configured either in series or parallel. Solvent is removed from the polymer stream in an anhydrous, first stage solvent recovery operation such that the solids concentration of the product stream is increased by at least 100 percent. Additional solvent is removed in an anhydrous, second stage solvent recovery operation from the product of the first stage solvent recovery operation such that the solids concentration of the product stream is in excess of 65 weight percent.
    Type: Grant
    Filed: July 12, 1996
    Date of Patent: April 8, 2003
    Assignee: Dow Global Technologies Inc.
    Inventors: Brian W. S. Kolthammer, Robert S. Cardwell, Deepak R. Parikh, Morris S. Edmondson, Stanley W. Smith
  • Patent number: 6500535
    Abstract: The invention provides a heat-resistant, low-dielectric polymeric material that is preferably a copolymer in which a non-polar &agr;-olefin base polymer segment and a vinyl aromatic copolymer segment are chemically combined with each other, and that is a thermoplastic resin showing a multi-phase structure in which a dispersion phase formed by one segment is finely dispersed in a continuous phase formed by another segment. It is thus possible to achieve a polymeric material that is excellent in heat resistance, has high strength, and has a low dielectric constant and a reduced dielectric loss, and so is suitable for an electrical insulating material for high-frequency purposes.
    Type: Grant
    Filed: August 26, 1998
    Date of Patent: December 31, 2002
    Assignees: TDK Corporation, NOF Corporation
    Inventors: Toshiaki Yamada, Takeshi Takahashi, Yoshiyuki Yasukawa, Kenji Endou, Shigeru Asami, Michihisa Yamada, Yasuo Moriya
  • Patent number: 6495629
    Abstract: A novel chlorine-free modified polyolefin resin composition with excellent adherence to nonpolar substrates, excellent solubility in solvents, excellent compatibility with other resins, and without tack after painting and drying is obtainable by graft modifying a mixed resin having 40 to 99 parts by weight of polyolefin resin (A) and 1 to 60 parts by weight of ethylenic compound-unsaturated carboxylic acid copolymer (B) that contains 0.1 to 50% by weight of unsaturated carboxylic acid derivative, with unsaturated carboxylic acid derivative and/or its anhydride (C), the modified polyolefin resin composition having weight average molecular weight of 20,000 to 150 000 and the grafting weight of (C) being 0.1 to 20% by weight.
    Type: Grant
    Filed: March 15, 2001
    Date of Patent: December 17, 2002
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Kazuhiro Usui, Kenichi Fujino, Terumasa Fujitaka, Koji Masumoto, Hidetoshi Yoshioka
  • Patent number: 6433095
    Abstract: Provided is a high density multimodal polyethylene, having a shear ratio (SR) of 18 or more and a HLMI of 15 g/10 mins or less comprising at least 20% by weight of a high molecular weight fraction, which high molecular weight fraction has: (a) a density (&rgr;) of 0.930 g/cm3 or less; and (b) a high load melt index (HLMI) of 0.30 g/10 mins or less.
    Type: Grant
    Filed: March 30, 2000
    Date of Patent: August 13, 2002
    Assignee: Fina Research, S.A.
    Inventor: Etienne Laurent
  • Patent number: 6426388
    Abstract: Disclosed is a novel chlorine-free modified polyolefin composition with excellent adherence to polyolefin substrates, with excellent solventresistance, oil resistance and weather resistance, with no tack, and also with excellentcohesion, obtainable by using 0.5 to 15% (by weight) of maleic anhydride and 0.1 to 7.5% (by weight) of styrenic monomer to polypropylene, eyhylene-propylene copolymer or ethylene-propylene-buten copolymer, and by graft polymerizing so as the weight ratio of maleic anhydride to styrenic monomer to become not less than 2 to not more than 5.
    Type: Grant
    Filed: November 13, 2000
    Date of Patent: July 30, 2002
    Assignee: Nippon Paper Industries Co., Ltd.
    Inventors: Kenichi Fujino, Terumasa Fujitaka, Kazuhiro Usui, Kouji Masumoto, Hidetoshi Yoshioka
  • Patent number: 6414102
    Abstract: The invention relates to polyolefin copolymers (I) and to graft copolymers (II) which are prepared from the copolymers (I), wherein the copolymers (I) are linear copolymers containing divinylbenzene comonomer units selected from the group consisting of 1,4-divinylbenzene units, mixtures of 1,4- and 1,3-divinylbenzene units and mixtures of 1,4-, 1,3- and 1,2-divinylbenzene units, wherein R, in formulas I and II, is a C1 to C10 linear or branched alkyl group or a C6 to C10 substituted or unsubstituted aromatic group; and wherein G and G′, independently, are selected from —H, —OH, epoxy, —NH2, —COOH, anhydride, —Cl, —Br, —M, —COOM (M=metal) or a polymer chain having the molecular weight of at least about 500, which can be derived from both step and chain polymerization reactions. In the graft copolymer (II), the combined alpha-olefin mole % (x+y) is from about 50 and 99.
    Type: Grant
    Filed: March 19, 2001
    Date of Patent: July 2, 2002
    Assignee: The Penn State Research Foundation
    Inventors: Tze-Chiang Chung, Jin Yong Dong
  • Patent number: 6407185
    Abstract: Process for the preparation of a composition containing ethylene polymers comprising a polymer of melt index MI2 of 5 to 1000 g/10 min and a polymer of melt index MI5 of 0.01 to 2 g/10 min, the ratio of these indices being from 500 to 50,000 and the weight ratio of the two polymers being equal to (30 to 70):(70 to 30), according to which part of the ethylene, a catalyst derived from a transition metal having an intrinsic molecular weight distribution defined by an intrinsic Mw/Mn ratio less than or equal to 10 and a deactivation constant less than or equal to 0.5 h−1, and a cocatalyst are introduced into a first reactor, polymerization of the ethylene is carried out therein, a mixture comprising one of the polymers, the catalyst and the cocatalyst is drawn off from this reactor and the mixture and another part of the ethylene are introduced into a second reactor, which ethylene is polymerized to form the other polymer.
    Type: Grant
    Filed: April 14, 2000
    Date of Patent: June 18, 2002
    Assignee: Solvay (Societe Anonyme)
    Inventor: Michel Promel
  • Patent number: 6399708
    Abstract: A bulk polymerized grafted and crosslinkable thermoplastic polyolefin powder composition having elasticity and flexibility properties, which is in the form of a powder intended for the production of flexible coatings by free flow over a hot mold, characterized in that it contains: a) from 100 to 5% by weight and preferably from 80 to 20% by weight of at least one homopolymer of ethylene and/or at least one copolymer containing at least 50 molar % of ethylene; b) from 0 to 95% by weight and preferably from 20 to 80% by weight of at least one thermoplastic elastomer; c) from 0.1 to 15 parts by weight and preferably from 0.5 to 10 parts by weight of a grafting agent, per 100 parts by weight of the accumulated components “a” and “b”. This powder composition is suitable for the production of flexible coatings by its free flow over a hot mold.
    Type: Grant
    Filed: June 2, 1997
    Date of Patent: June 4, 2002
    Assignee: Visteon Systemes Interieurs S.A.S.
    Inventors: Dominique Valligny, Tony Marciniak
  • Patent number: 6399683
    Abstract: A resin composition for extruded forms that has improved workability, and excellent properties with respect to transparency, heat resistance, low-temperature resistance, etc. The composition contains 50 to 99% by weight of component A, which is a copolymer of ethylene and &agr;-olefin, and 1 to 50% by weight of component B, which is an ethylene-containing polymer. The component A has: (a) a melt flow rate (MFR) of 0.1 to 5 g/10 min.; (b) a density D of 0.88 to 0.
    Type: Grant
    Filed: November 10, 1997
    Date of Patent: June 4, 2002
    Assignee: Mitsubishi Chemical Corporation
    Inventors: Koji Yamamoto, Hajime Ikeno, Keiko Shichijo
  • Patent number: 6395839
    Abstract: A bulk polymerized grafted and crosslinkable thermoplastic polyolefin powder composition having elasticity and flexibility properties, which is in the form of a powder intended for the production of flexible coatings by free flow over a hot mold, characterized in that it contains: a) from 100 to 5% by weight and preferably from 80 to 20% by weight of at least one homopolymer of ethylene and/or at least one copolymer containing at least 50 molar % of ethylene; b) from 0 to 95% by weight and preferably from 20 to 80% by weight of at least one thermoplastic elastomer; c) from 0.1 to 15 parts by weight and preferably from 0.5 to 10 parts by weight of a grafting agent, per 100 parts by weight of the accumulated components “a” and “b”. This powder composition is suitable for the production of flexible coatings by its free flow over a hot mold.
    Type: Grant
    Filed: March 26, 2001
    Date of Patent: May 28, 2002
    Assignee: Visteon Systemes Interieurs S.A.S.
    Inventors: Dominique Valligny, Tony Marciniak
  • Publication number: 20020042472
    Abstract: A class of relatively high molecular weight, high density ethylene polymers (HMW-HDPE) is disclosed capable of being formed into thin films of high strength, such polymers having a density of at least about 0.935 g/cc, a flow index (I21) no higher than about 15 g/10 min., a melt flow ratio (MFR) of at least about 65, and a dynamic elasticity at 0.1 rad./sec. of no higher than about 0.7 at a corresponding complex viscosity at 0.1 rad./sec. no higher than about 14E5, i.e., about 14×105 poises.
    Type: Application
    Filed: October 2, 2001
    Publication date: April 11, 2002
    Inventors: S. Christine Ong, Sandra D. Schregenberger, Pradeep P. Shirodkar
  • Patent number: 6365682
    Abstract: A process for producing terpolymers of propylene, comprising a) feeding into a slurry reactor a reaction mixture containing 50-85 w-% of propylene, 1-10 w-% of ethylene, 15-40 w-% of another C4-C8 alpha-olefin, a catalyst system maintaining olefin polymerization at said temperature conditions, and optionally hydrogen, b) polymerizing said reaction mixture at a temperature of lower than 70° C. a sufficient time to obtain a propylene terpolymer amounting to 50-99 w-% of the end product, c) transferring said reaction mixture into a gas phase reactor operating at a pressure of higher than 5 bars, preferably higher than 10 bars, optionally adding 0-30 w-% of ethylene, 0-10 w-% of another C4-C8 alpha-olefin, 0-40 w-% of propylene and optionally hydrogen, and d) continuing polymerization in said gas phase reactor for obtaining a propylene terpolymer amounting to 1-50 wt-% of the end product. The terpolymer has a melting temperature a less than 135° C., preferably less than 132° C.
    Type: Grant
    Filed: February 22, 2000
    Date of Patent: April 2, 2002
    Assignee: Borealis Technology Oy
    Inventors: Kauno Alastalo, Bo Malm, Päivi Pitkänen, Mika Meller, Anne Britt Bjåland, Nina Ackermans, Kshama Motha
  • Patent number: 6359081
    Abstract: A functional block copolymer useful as a compatibilizing agent for a blend of a condensation polymer and vinyl polymer comprises segments of a condensation polymer and a vinyl polymer derived from a reactive functional group-containing monomer or a functions-imparting monomer such as ultraviolet absorption or flame retardant functions. The block copolymer can further include a segment of a lower cohesive energy polymer. The condensation or vinyl polymer segment, or the lower cohesive energy polymer segment contains azo or peroxide groups which act as a polymerization initiator for the copolymerization of the vinyl monomer forming the vinyl polymer segment.
    Type: Grant
    Filed: April 19, 2000
    Date of Patent: March 19, 2002
    Assignees: Takiron Co., Ltd., Osaka Municipal Government
    Inventors: Masayuki Shimada, Yasuyuki Agari, Yoichiro Makimura
  • Patent number: 6355735
    Abstract: A semi-interpenetrating polymer network including at least one epoxy monomer, at least one olefin monomer forming a co-monomer mixture with the epoxy monomer and a catalytic amount of at least one palladium compound uniformly distributed in said co-monomer mixture to promote formation of the semi-interpenetrating polymer network under ambient conditions.
    Type: Grant
    Filed: August 17, 1999
    Date of Patent: March 12, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Mark I. Wagner, Stephen D. Meyer
  • Publication number: 20020019487
    Abstract: A bulk polymerized grafted and crosslinkable thermoplastic polyolefin powder composition having elasticity and flexibility properties, which is in the form of a powder intended for the production of flexible coatings by free flow over a hot mold, characterized in that it contains:
    Type: Application
    Filed: June 2, 1997
    Publication date: February 14, 2002
    Inventors: DOMINIQUE VALLIGY, TONY MARCINIAK
  • Patent number: 6344522
    Abstract: Process for the preparation of a composition containing ethylene polymers comprising a polymer of melt index MI2 of 5 to 1000 g/10 min and a polymer of melt index MI5 of 0.01 to 2 g/10 min, the ratio of these indices being from 500 to 50,000 and the weight ratio of the two polymers being equal to (30 to 70):(70 to 30), according to which part of the ethylene, a catalyst derived from a transition metal having an intrinsic molecular weight distribution defined by an intrinsic Mw/Mn ratio less than or equal to 10 and a deactivation constant less than or equal to 0.5 h−1, and a cocatalyst are introduced into a first reactor, polymerization of the ethylene is carried out therein, a mixture comprising one of the polymers, the catalyst and the cocatalyst is drawn off from this reactor and the mixture and another part of the ethylene are introduced into a second reactor, which ethylene is polymerized to form the other polymer.
    Type: Grant
    Filed: April 14, 2000
    Date of Patent: February 5, 2002
    Assignee: Solvay Polyolefins - Europe Belgium
    Inventor: Michel Promel
  • Patent number: 6316546
    Abstract: A class of relatively high molecular weight, high density ethylene polymers (HMW-HDPE) is disclosed capable of being formed into thin films of high strength, such polymers having a density of at least about 0.925 g/cc, a flow index (I21) no highier than about 15 g/10 min., a melt flow ratio (MFR) of at least about 65, and a dynamic elasticity at 0.1 rad./sec. of no higher than about 0.7 at a corresponding complex viscosity at 0.1 rad./sec. no highier than about 14E5, i.e., about 14×105 poises. The ethylene polymer is a bimodal blend of relatively high molecular weight (HMW) and low molecular weight (LMW) ethylene polymers.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: November 13, 2001
    Assignee: ExxonMobil Oil Corporation
    Inventors: S. Christine Ong, Sandra D. Schregenberger, Pradeep P. Shirodkar
  • Publication number: 20010025085
    Abstract: The present invention provides resin materials for producing molded products endowed with excellent heat resistance, solvent resistance, toughness, tensile elongation, and transparency. Specifically, there are provided aromatic vinyl resin materials which have the following properties: Storage elasticity values G′(1.0) and G′(0.1) as measured at 300° C., a strain &ggr; of 20%, and a frequency of 1.0 Hz or 0.1 Hz satisfy the expression, log[G′(1.0)/G′(0.1)]≦0.6, the heat of fusion &Dgr;H as measured over the range 200-295° C. is 8 to 50 (J/g), and the 1H-NMR peak integrated values for the fraction corresponding to the temperature range of not lower than 50° C., as collected from temperature rising election fraction on the Soxhlet extraction residue by use of cyclohexane or o-dichlorobenzene, satisfy the relation [1.8-2.1 (ppm)]/[1.0-1.7(ppm))<0.49.
    Type: Application
    Filed: February 2, 2001
    Publication date: September 27, 2001
    Applicant: IDEMITSU PETROCHEMICAL CO., LTD.
    Inventors: Hideo Teshima, Tomoaki Takebe, Masanori Sera
  • Patent number: 6265493
    Abstract: The invention relates to a process for preparing polyolefin graft copolymers (II) from linear and well defined polyolefin copolymers (I) containing divinylbenzene comonomer units, wherein R, in formulas I and II, is a C1 to C10 linear or branched alkyl group or a C6 to C10 substituted or unsubstituted aromatic group; and wherein G and G′, independantly, are selected from —H, —OH, epoxy, —NH2, —COOH, anhydride, —Cl, —Br, —M, —COOM (M=metal, e.g., Li, Na, K and Ca) or a polymer chain having the molecular weight of at least about 500, which can be derived from both step and chain polymerization reactions. G and G′ can be selected singly or in a combination of two or more thereof. In the graft copolymer composition, the combined alpha-olefin mole .% (x+y) is from about 50 to 99.9 mole %. Preferably, x+y is from 85 to 99.9 mole %, and most preferably x+y is from 95 to 99.9 mole %.
    Type: Grant
    Filed: May 18, 2000
    Date of Patent: July 24, 2001
    Assignee: The Penn State Research Foundation
    Inventors: Tze-Chiang Chung, Jinyong Dong
  • Patent number: 6239242
    Abstract: There are a number of recent developments relating to co- and homo-polymers of vinyl aromatic monomers. There are syndiotactic polymers of styrene, there are pseudo random polymers of styrene and ethylene. The present invention seeks to provide novel pseudoblock polymers of styrene and ethylene in which at least 10 weight % of the vinyl aromatic monomer is incorporated in the form of one or more atactic pseudoblocks.
    Type: Grant
    Filed: August 21, 1999
    Date of Patent: May 29, 2001
    Assignee: Nova Chemicals Corporation
    Inventors: Qinyan Wang, Patrick Lam
  • Patent number: 6221974
    Abstract: The invention relates to a process for the preparation of a creep-resistant polypropylene by means of the following steps: (a) copolymerizing propylene and ethylene into a random copolymer at 40 to 110° C. using: a catalyst system of the above-mentioned type; a portion of ethylene or C4-C10-&agr;-olefin leading to 1.0 to 10.0% by weight of ethylene repeating units in said random copolymer; and no or a minimal amount of hydrogen leading to a MFR10 value of between 0.01 and 5.0 g/10 min for said random copolymer, if this step is performed first, or to a MFR2 value for said polypropylene of between 0.05 and 0.40 g/10 min, if this step is performed after step (b); the proportion of random copolymer of this step being from 20 to 80% by weight of said polypropylene, (b) polymerizing propylene at 40 to 110° C. using: a catalyst system of the above-mentioned type; no or a minimal portion of ethylene leading to 0.0 to 1.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: April 24, 2001
    Assignee: Borealis Technology Oy
    Inventors: Mika Härkönen, Bo Malm, Anders Nymark
  • Patent number: 6194520
    Abstract: A class of relatively high molecular weight, high density ethylene polymer blends is disclosed capable of being blow molded with excellent processability into articles, e.g., bottles, of superior mechanical and other properties, such blends having a density of at least about 0.930 g/cc, a flow index (I21) of at least about 2 g/10 min., a melt flow ratio (MFR) of at least about 60, and a polydispersity index of at least about 8, the polymers of said blend consisting essentially of at least about 0.3 weight fraction of a relatively high molecular weight (HMW) component having a density of at least about 0.900 g/cc, a flow index or high load melt index (I21) of at least about 0.2 g/10 min., and a flow ratio (FR) at least about 10, and a relatively low molecular weight (LMW) component having a density of at least about 0.930 g/cc and a melt index (I2) no greater than about 1000 g/10 min.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: February 27, 2001
    Assignee: Mobil Oil Corporation
    Inventors: Subrahmanyam Cheruvu, Thomas E. Nowlin, S. Christine Ong, Giyarpuram N. Prasad, Paul P. Tong
  • Patent number: 6191227
    Abstract: A polyethylene resin superior in both moldability and long-term physical properties and suitable for both pipe and pipe joint, the polyethylene resin having a density of 0.915 to 0.955 g·cm−3, a melt flow rate of not more than 0.20 dg·min as measured at 190° C. and at a load of 2.16 kgf, a melt flow rate of 17.0 to 70.0 dg·min−1 as measured at 190° C. and at a load of 21.6 kgf, a zero shear viscosity (&eegr;0) of 200,000 to 2,000,000 Pa·s, a characteristic time constant (&tgr;0) of 50 to 500 sec., and a ratio (&tgr;0/&eegr;0) of 1.0×10−4 to 4.0×10−4 Pa−1, the zero shear viscosity (&eegr;0) being obtained by approximating a dynamic melt viscosity (&eegr;*, unit: Pa·s) with equation [1], the dynamic melt viscosity (&eegr;*) being obtained by measurement using a rheometer at 190° C., at a parallel plate spacing of 1.5 mm, at a distortion of 10% to 15% and in the frequency (&ohgr;) range of 100 to 0.
    Type: Grant
    Filed: August 6, 1997
    Date of Patent: February 20, 2001
    Assignee: Japan Polyolefins Co., Ltd.
    Inventors: Tohru Matsuoka, Kiyofumi Matsuoka, Fumiaki Naka, Kiyonobu Sato
  • Patent number: 6160039
    Abstract: This invention relates to a process for the production of masterbatches which contain short fibres or pulps and which may be used for the production of polymer compositions or rubber compositions.
    Type: Grant
    Filed: March 1, 1999
    Date of Patent: December 12, 2000
    Assignee: Rhein Chemie Rheinau GmbH
    Inventors: Harald Kleinknecht, Andreas Schuch, Iris Degen
  • Patent number: 6156845
    Abstract: An olefin (co-)polymer composition including 0.01 to 5.0 weight parts of high molecular weight polyethylene which is an ethylene homopolymer or an ethylene-olefin copolymer containing 50 weight % or more of an ethylene polymerization unit; and 100 weight parts of an olefin (co-)polymer other than the high molecular weight polyethylene, wherein said high molecular weight polyethylene has an intrinsic viscosity [.eta..sub.E ] of 15 to 100 dl/g measured in tetralin at 135.degree. C. or more, and said high molecular weight polyethylene exists as dispersed fine particles having a numerical average particle size of 1 to 5000 nm.
    Type: Grant
    Filed: April 2, 1997
    Date of Patent: December 5, 2000
    Assignee: Chisso Corporation
    Inventors: Jun Saito, Hideo Nobuhara, Shingo Kikukawa, Hitoshi Sato, Akira Yamauchi
  • Patent number: 6156836
    Abstract: This invention provides polypropylene resin compositions which have sharply improved balance of physical properties in comparison with the related polypropylene materials, are materials that can be used in both interior and exterior parts of automobiles, have excellent thin-wall moldability and can sharply reduce generation of flow marks. Particularly, it provides a polypropylene resin composition which comprises specified amounts of (A) a specified ethylene-propylene block copolymer, (B) a specified thermoplastic elastomer and (C) talc, wherein it has specified values of physical properties measured by ASTM and has a degree of b-axis orientation of 720 or more which is calculated from the ratio of differential peak intensities measured by wide-angle X-ray diffraction of the central area of an ASTM No. 1 dumbbell prepared by injection molding.
    Type: Grant
    Filed: December 24, 1998
    Date of Patent: December 5, 2000
    Assignees: Japan Polychem Corporation, Toyota Jidosha Kabushiki Kaisha
    Inventors: Kunio Iwanami, Akira Kobayashi, Mitsuhiro Murayama, Yuji Fujita, Takayuki Nagai, Takao Nomura, Masatoshi Matsuda, Osamu Kito, Hisayuki Iwai
  • Patent number: 6136924
    Abstract: Process for the preparation of a composition containing ethylene polymers comprising a polymer of melt index MI.sub.2 of 5 to 1000 g/10 min and a polymer of melt index MI.sub.5 of 0.01 to 2 g/10 min, the ratio of these indices being from 500 to 50,000 and the weight ratio of the two polymers being equal to (30 to 70):(70 to 30), according to which part of the ethylene, a catalyst derived from a transition metal having an intrinsic molecular weight distribution defined by an intrinsic M.sub.w /M.sub.n ratio less than or equal to 10 and a deactivation constant less than or equal to 0.5 h.sup.-1, and a cocatalyst are introduced into a first reactor, polymerization of the ethylene is carried out therein, a mixture comprising one of the polymers, the catalyst and the cocatalyst is drawn off from this reactor and the mixture and another part of the ethylene are introduced into a second reactor, which ethylene is polymerized to form the other polymer.
    Type: Grant
    Filed: December 13, 1995
    Date of Patent: October 24, 2000
    Assignee: Solvay (Societe Anonyme)
    Inventor: Michel Promel
  • Patent number: 6090893
    Abstract: The invention relates to polyethylene compositions containing 85-99.5 weight % of component A, which is a linear (co)polymer of ethylene having a bimodal weight distribution, and 0.5-15 weight % of component B having a unimodal molecular weight distribution. Component A is 40-60% by weight of a low molecular weight component (A1) having a weight average molecular weight between 5,000 and 50,000 g/mol, and a molecular weight distribution Mw/Mn between 2.5 and 9 and 60-40% by weight of a high molecular weight component (A2) having a weight average molecular weight between 300,000 and 900,000 g/mol, and a molecular weight distribution M/w/Mn between 4.5 and 12. Component B is a linear ethylene polymer having a molecular weight between 150,000-600,O00 g/mol and an average molecular weight which is higher than the average molecular weight of component (A1) but lower than the average molecular weight of component (A2) and a density controlled within the range of 910-960 kg/m.sup.3.
    Type: Grant
    Filed: June 16, 1997
    Date of Patent: July 18, 2000
    Assignee: Borealis Polymers Oy
    Inventors: Ali Harlin, Aimo Sahila, Veli Kilpelainen, Anders Nymark
  • Patent number: 6075116
    Abstract: The present invention provides a highly impact resistant polyamide composition which comprises a polyamide resin and an acid modification product of a metallocene catalyzed polyolefin elastomer. The invention also provides a less hygroscopic and highly impact resistant polyamide composition which comprises a polyamide resin, novolak phenol and an acid modification product of a metallocene catalyzed polyolefin elastomer. Used as the polyamide resin is less expensive nylon 6.
    Type: Grant
    Filed: June 30, 1998
    Date of Patent: June 13, 2000
    Assignee: Kishimoto Sangyo Co., Ltd.
    Inventors: Takeshi Moriwaki, Toshiharu Sakaguchi
  • Patent number: 6015854
    Abstract: The present invention teaches propylene-ethylene copolymers of about 5 to about 100 dg/min melt flow that have a homopolymer phase combined with a copolymer rubber phase in which the ethylene content of the rubber is between about 75 to about 95% w and a clarity of greater than 25%. The rubber content of the copolymer ranges between about 3% w to about 60% w. In addition to improved clarity, these copolymers have high stiffness (flexural modulus) and good falling weight impact toughness at low temperatures.
    Type: Grant
    Filed: October 24, 1997
    Date of Patent: January 18, 2000
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventor: James Douglas McCullough, Jr.