Polymer Derived From Fluorine Monomer Patents (Class 525/326.2)
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Publication number: 20140104674Abstract: A display medium adapted for an electrophoretic display is provided. The display medium includes at least one particle and a random copolymer bonded with the particle, wherein the random copolymer has a structural unit originated from a first monomer and a second monomer. The first monomer is selected from at least one or a combination of a group of specific compounds consisting of 2-ethylhexyl acrylate, lauryl methacrylate and octadecyl acrylate etc. and the second monomer is selected from at least one kind of a group of specific compounds composed of 2,2,2 trifluoroethyl acrylate, 2,2,3,3 tetrafluoropropyl methacrylate and 1,1,1,3,3,3-hexafluoroisopropyl acrylate. A method of manufacturing the display medium and an electrophoretic display with the display medium are also provided.Type: ApplicationFiled: October 15, 2012Publication date: April 17, 2014Applicant: SIPIX TECHNOLOGY INC.Inventors: Wei-Ho Ting, Ning-Wei Jan, Hui Du, Hong-Mei Zang, Tyau-Jeen Lin, Chun-Hsien Chen
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Publication number: 20140106979Abstract: Polymers having orthogonal reactive groups and solid supports comprising polymers immobilized thereto are provided. The polymers find utility in any number of applications including immobilizing analyte molecules to solid supports for high throughput assays.Type: ApplicationFiled: October 11, 2013Publication date: April 17, 2014Applicant: NVS Technologies, Inc.Inventors: Aldrich N. K. Lau, Robert G. Eason
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Publication number: 20140093728Abstract: A carbon nanostructure that is free of a growth substrate can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. The carbon nanostructure can be released from a growth substrate in the form of a flake material. Optionally, the carbon nanotubes of the carbon nanostructure can be coated, such as with a polymer, or a filler material can be present within the porosity of the carbon nanostructure. Methods for forming a carbon nanostructure that is free of a growth substrate can include providing a carbon nanostructure adhered to a growth substrate, and removing the carbon nanostructure from the growth substrate to form a carbon nanostructure that is free of the growth substrate. Various techniques can be used to affect removal of the carbon nanostructure from the growth substrate. Isolation of the carbon nanostructure can further employ various wet and/or dry separation techniques.Type: ApplicationFiled: September 24, 2013Publication date: April 3, 2014Applicant: Applied Nanostructured Solutions, LLCInventors: Tushar K. SHAH, Harry Charles Malecki, Rajneeta Rachel Basantkumar, Han Liu, Corey Adam Fleischer, Joseph J. Sedlak, Jigar M. Patel, William Patrick Burgess, Jess Michael Goldfinger
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Patent number: 8680209Abstract: The present invention provides a method for producing a stabilized fluoropolymer which comprises producing the stabilized fluoropolymer by subjecting a treatment target substance containing a sulfonic-acid-derived-group-containing fluoropolymer to a fluorination treatment, wherein the sulfonic-acid-derived-group-containing fluoropolymer is a fluoropolymer containing —SO3M (in which M represents H, NR1R2R3R4 or M11/L; R1, R2, R3 and R4 are the same or different and each represents H or an alkyl group containing 1 to 4 carbon atoms; and M1 represents an L-valent metal), and the treatment target substance has a moisture content of not higher than 500 ppm by mass.Type: GrantFiled: October 18, 2012Date of Patent: March 25, 2014Assignees: Daikin Industries, Ltd., Asahi Kasei E-Materials CorporationInventors: Eiji Honda, Hideki Iijima, Yasuhiro Hashimoto, Tadashi Ino, Tadaharu Isaka, Masahiro Kondo
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Patent number: 8674031Abstract: The present invention provides a water- and oil-repellent soil-resistant composition comprising (A) a fluorine-containing polymer having repeating units derived from a monomer comprising a fluorine-containing monomer and (B) a silane compound. The water- and oil-repellent soil-resistant composition comprising the fluorine-containing acrylate polymer can impart the excellent water- and oil-repellency and soil resistance to the porous substrate and is free from an organic solvent.Type: GrantFiled: November 10, 2009Date of Patent: March 18, 2014Assignees: Daikin Industries, Ltd., Dow Corning CorporationInventors: Akihiko Ueda, Yasuo Itami, Tetsuya Masutani, Peter Cheshire Hupfield, Janet Smith, Jean-Paul Lecomte
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Patent number: 8648149Abstract: The invention relates to the field of chemistry and relates to radically coupled PTFE polymer compounds that can be used, for example, as tribo materials, and a method for the production thereof. The object of the invention is to disclose radically coupled PTFE polymer compounds which exhibit improved wear resistances with comparable gliding properties, and furthermore a simple and efficient method for the production of such compounds. The object is attained through radically coupled PTFE polymer compounds comprising radiation-chemically and/or plasma-chemically modified PTFE powders, on the particle surface of which olefinically unsaturated polymers are chemically radically coupled by a reactive conversion into a melt.Type: GrantFiled: June 7, 2010Date of Patent: February 11, 2014Assignee: Leibniz-Institut fuer Polymerforschung Dresden E.V.Inventors: Dieter Lehmann, Bernd Kluepfel
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Patent number: 8641919Abstract: Piezoelectric compositions are provided wherein mechanical and piezoelectric properties can be separately modulated. Preferred compositions include resin blends that comprise: (a) a piezoelectrically active polymer and (b) a matrix polymer, methods of making, and use of such resin blends. Advantages of preferred resin blends of the invention can include high piezoelectricity, mechanical strength and flexibility, convenient fabrication process, and high sensitivity at high temperatures.Type: GrantFiled: August 8, 2007Date of Patent: February 4, 2014Assignee: The Johns Hopkins UniversityInventors: Michael Yu, James E. West, Ilene J. Busch-Vishniac, Dawnielle Farrar
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Publication number: 20140013858Abstract: A measuring tube for a lining of a measuring tube of a flow measuring device, wherein a nanoparticle is chemically bound to a polymer.Type: ApplicationFiled: February 15, 2012Publication date: January 16, 2014Applicant: Endress + Hauser FLowtec AGInventors: Johannes Ruchel, Wolfgang Brobeil
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Patent number: 8618222Abstract: Fluoroelastomer compositions comprising fluoroelastomers having copolymerized units of a nitrile group-containing cure site monomer are cured with certain hydroxylamine derivatives. The hydroxylamine derivative is of formula R1(C(O))nNHOR2 wherein n is 0 or 1; R1 is H, C(O)R3, C(O)R4, C(O)OR3, or C(O)SR3; R2 is H, C(O)R3, or C(O)OR3; R3 is C1-C20 alkyl group, aryl, heterocycle, benzyl, 9-fluorenylmethyl, or CH2R4; and R4 is a fluoroalkyl group, with the proviso that R1 and R2 cannot simultaneously be H.Type: GrantFiled: March 12, 2012Date of Patent: December 31, 2013Assignee: E I du Pont de Nemours and CompanyInventors: Christopher J Bish, Peter A Morken
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Patent number: 8609739Abstract: A polymer for ion conductor applications includes a polymer segment having a perfluorocyclobutyl moiety and a phosphonated aryl group and a polymer segment a perfluorocyclobutyl moiety without phosphonated aryl group. The polymer is formed into an ion conducting membrane for fuel cell applications.Type: GrantFiled: February 17, 2011Date of Patent: December 17, 2013Assignee: GM Global Technology Operations LLCInventors: Lijun Zou, Timothy J. Fuller, Michael R. Schoeneweiss
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Publication number: 20130317178Abstract: A polymer includes at least one pendant dioxirane moiety represented by Formula III or IV: In Formulas III and IV, R1 is absent or is alkylene, perhaloalkylene, cycloalkylene, arylene, heteroarylene, heterocyclylene, amino, carbonyl, carboxyl, alkylcarboxy, carboxyalkyl or alkylcarboxyalkyl; R2 is an electron withdrawing group; R8 is —N+R4R5 or alkylene; R9 is —N+R4R5 or alkylene; each R4 is independently H, alkyl, or cycloalkyl; and each R5 is independently H, alkyl, or cycloalkyl.Type: ApplicationFiled: August 1, 2013Publication date: November 28, 2013Applicant: Empire Technology Development LLCInventors: Angele Sjong, Kraig K. Anderson
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Publication number: 20130310464Abstract: The invention relates to a copolymer which can be obtained by free-radical copolymerization of one or more urethane-based, polysiloxane-containing macromonomers and one or more further free-radically polymerizable comonomers. Processes for preparing the copolymer and its use as additive in coating compositions and plastics and as wetting agent and dispersant in homogeneous dispersions are also described.Type: ApplicationFiled: November 17, 2011Publication date: November 21, 2013Applicant: BYK-Dhemie GmbHInventor: Heike Bubat
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Publication number: 20130310522Abstract: A composite resin material particle is produced by a method including the steps of: forming a mixed slurry containing a resin material particle and carbon nanotubes; supplying the mixed slurry to a pressure vessel, followed by supplying carbon dioxide with stirring an inside of the pressure vessel; holding the inside of the pressure vessel at a temperature and at a pressure which allow the carbon dioxide to be maintained in a subcritical or supercritical state; and transferring the carbon dioxide to the outside of the pressure vessel.Type: ApplicationFiled: February 7, 2011Publication date: November 21, 2013Applicant: Taiyo Nippon Sanso CorporationInventors: Takeru Yajima, Toshiyuki Abe, Toru Sakai, Kentaro Miyoshi
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Patent number: 8580897Abstract: Disclosed herein is a crosslinked fluoropolymer network formed by the free radical initiated crosslinking of a diacrylate fluoropolymer. The diacrylate copolymer is of formula CH2?CR?COO—(CH2)n—R—(CH2)n—OOCR??CH2, wherein R is selected from the group consisting of i) an oligomer comprising copolymerized units of vinylidene fluoride and perfluoro(methyl vinyl ether), ii) an oligomer comprising copolymerized units of vinylidene fluoride and hexafluoropropylene, iii) an oligomer comprising copolymerized units of tetrafluoroethylene and perfluoro(methyl vinyl ether), and iv) an oligomer comprising copolymerized units of tetrafluoroethylene and a hydrocarbon olefin, R? is H or —CH3, n is 1-4 and wherein said oligomer has a number average molecular weight of 1000 to 25,000 daltons. The source of the free radicals may be a photoinitiator or an organic peroxide.Type: GrantFiled: November 14, 2012Date of Patent: November 12, 2013Assignees: E I du Pont de Nemours and Company, Le Centre National de la Recherche ScienInventors: Ming-Hong Hung, Bruno Ameduri, Georgi Kostov
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Publication number: 20130281631Abstract: A phosphoric acid polymer containing a repeating unit represented by the following formula (1): (wherein, R1 represents a hydrogen atom or methyl, group).Type: ApplicationFiled: October 13, 2011Publication date: October 24, 2013Applicant: TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Satoshi Nakazawa, Mitsuru Ueda, Tomoya Higashihara, Namiko Fukuzaki
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Patent number: 8563657Abstract: The present invention relates to (i) novel fluoroionic compounds capable of dispersing particulate filler compositions into a fluoropolymer; (ii) novel particulate compositions in which particulates are surface-functionalized with a fluoroionic compound; (iii) fluoropolymer composite materials containing the surface-functionalized particulates of (ii) incorporated into a fluoropolymer; (iv) crosslinked versions of (iii); v) methods for producing the crosslinked material of (iv); and (vi) articles of manufacture containing the compositions (iii) and (iv).Type: GrantFiled: April 6, 2009Date of Patent: October 22, 2013Assignee: The Research Foundation of State University of New YorkInventors: Benjamin S. Hsiao, Benjamin Chu, Jie Wei, Hongyang Ma, Feng Zuo
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Patent number: 8563660Abstract: [Object] To provide a fluororubber-based sealing material which is excellent in sealing properties under high/low temperature load and is capable of sealing at a temperature of not higher than ?40° C. even when gas oil (diesel fuel) is used. [Means for Solving] A fluororubber-based sealing material obtained by crosslinking a composition for a fluororubber-based sealing material, said composition comprising 100 parts by weight of a fluorine-containing copolymer which contains 64 to 69% by weight of fluorine, has a crosslinking site derived from a bromine-containing compound and/or an iodine-containing compound and is capable of being crosslinked by a peroxide, 0.Type: GrantFiled: April 7, 2009Date of Patent: October 22, 2013Assignee: Nok CorporationInventor: Hiroyuki Sano
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Publication number: 20130274420Abstract: A noncrystalline fluoroelastomer which is a copolymer consisting essentially of vinylidene fluoride and a fluoromonomer represented by the general formula (1): CH2?CFRf??(1) wherein Rf is a straight or branched fluoroalkyl group containing 1 to 12 carbon atoms, and has a vinylidene fluoride units/fluoromonomer units mol ratio of 78/22 to 22/78 and a glass transition temperature of not higher than 25° C.Type: ApplicationFiled: June 7, 2013Publication date: October 17, 2013Inventors: Shigeru MORITA, Masanori KITAICHI, Shouji FUKUOKA, Daisuke OTA
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Publication number: 20130224592Abstract: Provided is a lithium ion battery having a long service life by improving an adhesion strength between a binder resin and a metal foil. A binder resin, which is a compound having a chemical structure that contains a polyvinylidene fluoride molecular chain, a six-membered ring such as a cyclohexane ring, and an end group selected from the group consisting of SiX3, S, N, GeX3, and TiX3 (wherein X is a functional group that undergoes a condensation reaction), wherein the six-membered ring is disposed in a region between the polyvinylidene fluoride molecular chain and the end group, is mixed with an active material and applied to a metal foil, and the binder resin is chemically bonded to metal atoms such as copper atoms on the surface of the metal foil.Type: ApplicationFiled: November 18, 2010Publication date: August 29, 2013Applicant: Hitachi, Ltd.Inventor: Tomio Iwasaki
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Patent number: 8513351Abstract: Fluoroelastomeric gel having the following properties: appearance: transparent gelatinous solid; water content between 10% and 90% by weight; a density between 1.1 and 2.1 g/cm3; said gel satisfies the following test: dried in a stove at 90° C. until a constant weight gives curable fluoroelastomers.Type: GrantFiled: June 22, 2005Date of Patent: August 20, 2013Assignee: Solvay Solexis S.p.A.Inventors: Marco Apostolo, Stefano Arrigoni, Margherita Albano
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Publication number: 20130197628Abstract: Copolymer-modified nanoparticles produced by a process in which nanoparticles are ablated by laser radiation from a surface of a substrate in a liquid include an amphiphilic copolymer.Type: ApplicationFiled: April 19, 2011Publication date: August 1, 2013Applicants: AESCULAP AG, Max Planck Gesellschaft zur Foerderung der Wissenschaften e.V., LASER ZENTRUM HANNOVER E.V.Inventors: Stephan Barcikowski, Christin Menneking, Markus Klapper, Klaus Müllen, Michael Hoffmann, Simon Stelzig, Dennis Langanke, Helmut Goldmann
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Publication number: 20130197163Abstract: The invention pertains to peroxide-curable fluoroelastomers for the oil and gas industry, including explosive decompression, and which can be easily processed to yield cured parts in standard machineries at reasonable throughput rates, said fluoroelastomers comprising: recurring units derived from vinylidene fluoride (VDF); recurring units derived from hexafluoropropylene (HFP); recurring units derived from at least one bis-olefin [bis-olefin (OF)] having general formula: wherein R1, R2, R3, R4, R5 and R6, equal or different from each other, are H, a halogen, or a C1-C5 optionally halogenated group, possibly comprising one or more oxygen group; Z is a linear or branched C1-C18 optionally halogenated alkylene or cycloalkylene radical, optionally containing oxygen atoms, or a (per)fluoropolyoxyalkylene radical; and iodine or bromine cure-sites; said fluoroelastomers further possessing a Mooney viscosity (ML) of at least 85 MU (1+10@121° C.), when measured according to ASTM D1646.Type: ApplicationFiled: October 7, 2011Publication date: August 1, 2013Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.Inventors: Marco Apostolo, Liubov Chernysheva
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Publication number: 20130190456Abstract: The present invention aims to provide a curable composition excellent in storage stability and scorch resistance. The present invention provides a curable composition including a fluoroelastomer (A) that contains a cyano group in a main chain and/or a side chain thereof, and a compound (B) that is at least one compound selected from the group consisting of an amide compound and a hydrazide compound, the compound (B) having at least one structure selected from the group consisting of azo structure, hydrazine structure, and imine structure, and producing NH3 when decomposed.Type: ApplicationFiled: November 25, 2011Publication date: July 25, 2013Applicant: DAIKIN INDUSTRIES, LTD.Inventor: Seiichi Hirano
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Publication number: 20130184400Abstract: A process for coating flexible substrates applying a curable fluorinated copolymer A which is the reaction product of FC and M1) at least one polycarboxylic anhydride and/or M2) at least a monofunctional isocyanate, wherein FC is a curable fluorinated copolymer on the basis of FC1) at least one fluorinated olefin having 2 to 10 carbon atoms, FC2) at least one non-fluorinated olefin having OH-groups and optionally carboxyl groups and FC3) at least one non-fluorinated, hydroxyl group free olefin having optionally carboxyl groups.Type: ApplicationFiled: March 4, 2013Publication date: July 18, 2013Applicants: DAIKIN INDUSTRIES, LTD., LANXESS DEUTSCHLAND GMBHInventors: LANXESS DEUTSCHLAND GMBH, DAIKIN INDUSTRIES, LTD.
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Patent number: 8487018Abstract: Heavy metal-free compostable polymers, composites and articles anaerobically biodegrade in landfills in a relatively short time. Heavy metal-free composite polymeric articles and sheets such as indoor or outdoor signs, billboards, banners, images, protective barriers, backdrops and wall coverings have very useful service durations and yet are landfill biodegradable.Type: GrantFiled: February 21, 2011Date of Patent: July 16, 2013Assignee: Biotech Products, LLCInventor: Richard F. Grossman
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Publication number: 20130171066Abstract: The present invention relates to the preparation and use of polymer complements to ?-amyloid peptides (A?) for detecting soluble or aggregated A? in fluid samples or for treating a subject having a neurodegenerative disease.Type: ApplicationFiled: July 25, 2011Publication date: July 4, 2013Inventors: Boerje Sellergren, Carla Sofia Antunes Aureliano, Javier Urraca Ruiz, Eric Schillinger
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Patent number: 8476356Abstract: A (per)fluoroelastomeric composition curable by peroxidic way comprising for 100 phr of (per)fluoroelastomer: as filler, from 2 to 70 phr of carbon black having a surface area between 25 and 35 m2/g; as crosslinking agent, from 0.5 to 10 phr of a bis-olefin having general formula: wherein: R1, R2, R3, R4, R5, R6, equal to or different from each other, are H or C1-C5 alkyls; Z is selected between a linear or branched C1-C18 alkylene or cycloalkylene radical, optionally containing oxygen atoms, preferably at least partially fluorinated, or a (per)fluoropolyoxyalkylene radical.Type: GrantFiled: June 28, 2007Date of Patent: July 2, 2013Assignee: Solvay Solexis S.p.A.Inventors: Milena Stanga, Giovanni Comino, Stefano Arrigoni, Margherita Albano
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Patent number: 8466231Abstract: A process of reducing the amount of fluorinated emulsifiers in fluoropolymer dispersions by contacting the fluoropolymer dispersion with an anion exchange resin in the presence of a pH-dependent surfactant, and fluoropolymer dispersion containing the pH-dependent surfactant and uses thereof.Type: GrantFiled: April 8, 2009Date of Patent: June 18, 2013Assignee: 3M Innovative Properties CompanyInventors: Michael C. Dadalas, Klaus Hintzer, Ludwig Mayer, Tilman C. Zipplies, James Arthur McDonell
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Patent number: 8454738Abstract: Disclosed is a mold-releasing agent comprising, as active ingredients, a graft copolymer (A) in which a polyalkylene glycol or an alkyl ether thereof is graft-copolymerized with a polyfluoro-1-alkene represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)bCH?CH2 (wherein n is an integer of 1 to 6, a is an integer of 1 to 4, and b is an integer of 1 to 3), and a polyfluoroalkylphosphonic acid represented by the general formula: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cP(O)(OH)2 (wherein n is an integer of 1 to 6, a is an integer of 1 to 4, and b is an integer of 1 to 3, and c is an integer of 1 to 3) or a salt thereof (B). The mold-releasing agent comprises, as an active ingredient, a compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and having mold release performance equivalent to or more than that of a mold-releasing agent comprising a compound having a perfluoroalkyl group containing 8 or more carbon atoms as an active ingredient.Type: GrantFiled: June 3, 2010Date of Patent: June 4, 2013Assignee: Unimatec Co., Ltd.Inventors: Yoshiyama Kaneumi, Seiichiro Murata, Katsuyuki Sato
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Patent number: 8455557Abstract: There are provided herein selective membranes, such as composite membranes, and/or films and processes for their preparation. The membranes and/or films have a given morphology which may be stabilized, for example against swelling and chemical degradation, by covalent crosslinking and optionally, in addition, by hydrophobization. There is provided a membrane and/or film and a process for the preparation thereof, the membrane and/or film include an ionomer and/or polyelectrolyte crosslinked through aryl-aryl (—Ar—Ar—), aryl-ether-aryl (—Ar—O—Ar—) and/or aryl-sulfide-aryl (—Ar—S—Ar—) bonds.Type: GrantFiled: May 24, 2007Date of Patent: June 4, 2013Assignee: Ben Gurion University of the Negev R&D AuthorityInventors: Charles Linder, Ora Kedem, Yoram Oren
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Publication number: 20130112618Abstract: Filtration membrane comprising polymeric nanofibers and/or microfibers attaching dendrimer component presenting reactive sites selective for chemicals to be filtered, and related nanofibers and microfibers, composite materials, compositions, methods and system.Type: ApplicationFiled: August 8, 2012Publication date: May 9, 2013Inventors: Mamadou S. DIALLO, William A. GODDARD, III, Seong-Jik PARK, Manki CHO
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Patent number: 8426527Abstract: Obtaining a crosslinked rubber with high flexibility at low temperature includes crosslinking a fluororubber composition. The fluororubber composition includes a fluororubber and a compound of formula (X—)x(Z—)zY. In the formula, X is U—(CF2)aO(CF2CF2O)b—; Z is RFO(CF2CF2O)c—; Y is a (x+z) valent perfluoro saturated hydrocarbon group, optionally interrupted by an etheric oxygen atom; x is an integer of at least 3; z is an integer of at least 0; U is a monovalent group with an unsaturated hydrocarbon, a bromine atom, an iodine atom, or a combination thereof; RF is a C1-20 linear perfluoroalkyl group, optionally interrupted by an etheric oxygen atom; a is an integer of from 0 to 20; b is an integer of from 1 to 200; and c is an integer of from 3 to 200.Type: GrantFiled: March 22, 2012Date of Patent: April 23, 2013Assignee: Asahi Glass Company, LimitedInventors: Makoto Honda, Tomoyuki Fujita, Kunio Watanabe, Daisuke Shirakawa
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Patent number: 8404756Abstract: A foamable fluoropolymer composition containing foam cell nucleating agent is provided, wherein the fluoropolymer comprises melt-fabricable tetrafluoroethylene-/hexafluoropropylene copolymer and tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, wherein the alkyl contains 1 to 4 carbon atoms, wherein the melting temperature of said tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer is no more than 35° C. greater than the melting temperature of said tetrafluoroethylene/hexafluoropropylene copolymer, and/or wherein said tetrafluoroethylene/hexafluoropropylene copolymer and said tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer each have a melt flow rate (MFR) within the range of 1 to 40 g/10 min and the MFR of one of said copolymers is at least twice that of the other of said copolymers.Type: GrantFiled: April 13, 2012Date of Patent: March 26, 2013Assignee: E. I. du Pont de Nemours and CompanyInventors: Heidi Elizabeth Burch, Sundar Kilnagar Venkataraman, Robert Thomas Young
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Patent number: 8404782Abstract: A stabilized fluorine-containing polymer powder having an average particle size of 5 to 100 ?m is prepared by contacting a fluorine-containing polymer powder, which is prepared by milling the fluorine-containing polymer and removing fine particles, fibrous particles and coarse particles by classification, with a fluorinating agent so that the total number of unstable terminal groups is decreased to 7 to 50 per 106 carbon atoms. This is a fluorine-containing polymer powder achieved a high coating efficiency in an electrostatic coating method and provides a film having good properties such as heat resistance, non-tackiness, low frictional property, chemical resistance, etc.Type: GrantFiled: July 9, 2010Date of Patent: March 26, 2013Assignee: Daikin Industries, Ltd.Inventors: Yasukazu Nakatani, Toshio Miyatani, Koichiro Ogita
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Publication number: 20130072636Abstract: Fluoroelastomer compositions comprising fluoroelastomers having copolymerized units of a nitrile-containing cure site monomer are cured with certain hydrazide curatives. The hydrazide is of the general formula R1C(O)NHNHR2, wherein R1 is alkyl, aryl, benzyl, heterocycle, fluoroalkyl, or H; R2 is H, alkyl, aryl, heterocycle, CO2R3, C(O)H, or CH2R4; R3 is alkyl, CH2R4, aryl, benzyl, or heterocycle; and R4 is a fluoroalkyl group.Type: ApplicationFiled: March 15, 2012Publication date: March 21, 2013Applicant: E.I. DU PONT DE NEMOURS AND COMPANYInventors: CHRISTOPHER J. BISH, Peter A. Morken
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Publication number: 20130066018Abstract: Fluoroelastomer compositions comprising fluoroelastomers having copolymerized units of a nitrile group-containing cure site monomer are cured with certain hydroxylamine derivatives. The hydroxylamine derivative is of formula R1(C(O))nNHOR2 wherein n is 0 or 1; R1 is H, C(O)R3, C(O)R4, C(O)OR3, or C(O)SR3; R2 is H, C(O)R3, or C(O)OR3; R3 is C1-C20 alkyl group, aryl, heterocycle, benzyl, 9-fluorenylmethyl, or CH2R4; and R4 is a fluoroalkyl group, with the proviso that R1 and R2 cannot simultaneously be H.Type: ApplicationFiled: March 12, 2012Publication date: March 14, 2013Applicant: E I DU PONT DE NEMOURS AND COMPANYInventors: CHRISTOPHER J. BISH, Peter A. Morken
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Publication number: 20130046062Abstract: Provided is a method for efficiently and homogeneously reacting an ETFE having a functional group and a compound having a reactive functional group which can react with the functional group. A method for reacting an ethylene/tetrafluoroethylene copolymer having a functional group, which comprises reacting, in the presence of a solvent which can dissolve the ethylene/tetrafluoroethylene copolymer having a functional group, the ethylene/tetrafluoroethylene copolymer having a functional group and a compound (A) having a reactive functional group which can react with the functional group, in a dissolved state.Type: ApplicationFiled: October 16, 2012Publication date: February 21, 2013Applicant: Asahi Glass Company, LimitedInventor: Asahi Glass Company, Limited
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Patent number: 8377187Abstract: Disclosed is a graft copolymer in which a polyalkylene glycol or an alkyl ether thereof is graft-copolymerized with a polyfluoro-1-alkene represented by the general formula: CnF2n+(CH2CF2)a(CF2CF2)bCH?CH2 (wherein n is an integer of 1 to 6, a is an integer of 1 to 4, and b is an integer of 1 to 3). The graft copolymer is an oligomer compound having a perfluoroalkyl group containing 6 or less carbon atoms, which is said to have low bioaccumulation potential, and having, when used as an active ingredient of a mold-releasing agent, mold release performance equivalent to that of a compound having a perfluoroalkyl group containing 8 or more carbon atoms.Type: GrantFiled: June 3, 2010Date of Patent: February 19, 2013Assignee: Unimatec Co., Ltd.Inventors: Yoshiyama Kaneumi, Seiichiro Murata, Katsuyuki Sato
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Patent number: 8362167Abstract: The invention provides a compound and tautomeric forms thereof having the formula: wherein Rf1 is selected from the group consisting of hydrogen, a straight chain, branched secondary or branched tertiary C1-C20 perfluoroalkyl group optionally containing ether or thioether linkages and C1-C10 perfluoroalicyclic group optionally containing ether or thioether groups; Rf2 is a straight or branched C1-C20 perfluoroalkylene group optionally substituted with ether and thiother linkages; and X is selected from the group consisting of fluorine and The invention also provides perfluoroelastomeric compositions cured with the perfluoroimidoylamidines of the invention as well as combinations of perfluoroimidoylamidines and other curing agents.Type: GrantFiled: July 10, 2007Date of Patent: January 29, 2013Assignee: LODESTAR Inc.Inventors: Gubanov Viktor Andreevich, Kollar Alexander Nikolaevich, Volkova Margarita Alekseevna, Tsipkina Irina Mikhailovna
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Patent number: 8361368Abstract: Certain polymer materials, including perfluorosulfonic acid ionomers, have been found to be capable of being deformed from an initial permanent shape into three or more temporary shapes. An article thus formed from such a polymer material may be used initially in a final temporary shape. As the article is progressively heated, the polymer composition reverts successively from its final temporary shape through its intermediate temporary shapes. If a suitable temperature is reached, the original permanent shape is recovered. The article may be devised to serve successive functions in each of its several shapes.Type: GrantFiled: September 23, 2009Date of Patent: January 29, 2013Assignee: GM Global Technology Operations LLCInventors: Tao Xie, Paul E. Krajewski
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Publication number: 20130023620Abstract: A process for manufacturing a fluoropolymer hybrid organic/inorganic composite comprising: (i) mixing at least one fluoropolymer comprising recurring units derived from at least one (meth)acrylic monomer [monomer (MA)] of formula: at least one metal compound [compound (M)] of formula: X4-mAYm, wherein each of R1, R2, R3, equal or different from each other, is independently a hydrogen atom or a C1-C3 hydrocarbon group, and ROH is a hydrogen atom or a C1-C5 hydrocarbon moiety comprising at least one hydroxyl group [polymer (F)]; wherein m is an integer from 1 to 4, A is a metal selected from the group consisting of Si, Ti and Zr, Y is a hydrolysable group, X is a hydrocarbon group comprising one or more functional groups; (ii) reacting at least a fraction of hydroxyl groups of the ROH groups of said monomer (MA) of said polymer (F) with at least a fraction of said compound (M), to obtain a grafted polymer comprising pendant —Ym-1AX4-m groups, with m, Y, A and X having same meaning as above; and (iii) hyType: ApplicationFiled: March 31, 2011Publication date: January 24, 2013Applicant: SOLVAY SPECIALTY POLYMERS ITALY S.P.A.Inventors: Julio A. Abusleme, Riccardo Pieri, Ivan Pagin
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Patent number: 8357725Abstract: The invention pertains to a semi-crystalline fluoropolymer having ion exchange groups comprising recurring units derived from at least one ethylenicalty unsaturated monomer comprising at least one fluorine atom (fluorinated monomer); and a substantial amount of recurring units derived from at least one ethylenically unsaturated monomer comprising at least one ion exchange group (functional monomer), wherein the amount of unstable end groups of —COF type is of less than 0.05 mmol/kg, and the use of the stabilized fluoropolymer in fuel cells devices, a membrane and a membrane-electrode assembly.Type: GrantFiled: May 17, 2012Date of Patent: January 22, 2013Assignee: Solvay Solexis S.p.A.Inventors: Vincenzo Arcella, Luca Cirillo, Alessandro Ghielmi, Luca Merlo, Stefano Millefanti
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Patent number: 8354201Abstract: A fuel cell includes a first flow field plate defining at least one flow field channel. A cathode catalyst layer is disposed over at least a portion of the first flow field plate. A polymeric ion conducting membrane is disposed over cathode catalyst layer. An anode catalyst layer is disposed over the polymeric ion conducting membrane. Finally, a second flow field plate defining at least one flow field channel is disposed over the anode catalyst layer. The polymeric ion conducting membrane extends beyond the cathode catalyst layer and the anode catalyst layer such that the fuel cell has at least one peripheral region with the polymeric catalyst layer interposed between first flow field plate and the second flow field plate without the cathode catalyst layer and the anode catalyst layer.Type: GrantFiled: August 28, 2009Date of Patent: January 15, 2013Assignee: GM Global Technology Operations LLCInventors: Sean M MacKinnon, Timothy J. Fuller, Annette M. Brenner
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Patent number: 8349965Abstract: A fluororubber composition according to the present invention contains 0.1 to 3 parts by weight of a polyol compound, 0.1 to 4 parts by weight of a peroxide crosslinking agent, and 1 to 9 parts by weight of a co-crosslinking agent per 100 parts by weight of a peroxide-crosslinkable fluoropolymer. A crack-resistant seal according to the present invention contains a crosslinked fluoropolymer and a polyol compound. The crack-resistant seal according to the present invention can be formed by crosslinking the fluororubber composition, and the resultant crack-resistant seal has particularly high crack resistance. With the fluororubber composition according to the present invention, a durable crack-resistant seal having high plasma resistance, crack resistance, and compression set and that produces few particles can be formed at low cost.Type: GrantFiled: March 12, 2009Date of Patent: January 8, 2013Assignee: Nippon Valqua Industries, Ltd.Inventors: Masanori Okazaki, Naoki Ohsumi
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Patent number: 8344071Abstract: Disclosed is a two-pack fluorine coating composition which comprises a combination of: a base component comprising a fluorinated copolymer having a hydroxyl group which can be dissolved in a low-polar weak solvent even at a low temperature and; a curing agent comprising a polyisocyanate compound.Type: GrantFiled: October 15, 2007Date of Patent: January 1, 2013Assignees: Asahi Kasei Chemicals Corporation, Asahi Glass Company, LimitedInventors: Shinichiro Watanabe, Isao Kimura
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Publication number: 20120296002Abstract: A surface treatment method for a fluororesin molded body, which is a method for treating a surface of an ETFE molded body by using a glow discharge generated by a pulsed electric field having a voltage-rising time of at most 10 ?sec in a nitrogen atmosphere under a pressure in the vicinity of atmospheric pressure; which comprises carrying out a plurality of glow discharge treatments at intervals of at least 0.01 sec so that the discharge density of each of the glow discharges is from 40 to 200 W·min/m2, and that the total discharge density of the glow discharges is from 220 to 800 W·min/m2. Further, an ETFE molded body subjected to a surface treatment by the surface treatment method.Type: ApplicationFiled: July 26, 2012Publication date: November 22, 2012Applicant: Asahi Glass Company, LimitedInventors: Hiroshi Aruga, Koichi Oda
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Patent number: 8313536Abstract: Provided is a functional member 4 comprising a fluororesin containing a carbon material 2 and having surface cleanliness, wherein the content of the carbon material 2 in a surface portion 4a of the functional member 4 is significantly less than the content of the carbon material 2 in an inner portion 4b of the functional member 4.Type: GrantFiled: February 23, 2009Date of Patent: November 20, 2012Assignee: Tokyo Electron LimitedInventors: Jiro Higashijima, Satoshi Kaneko
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Patent number: 8309660Abstract: The present invention provides a perfluoroelastomer seal material in which adhesive strength, contamination, corrosion and color change of a contacted surface with a seal material are improved, and an amount of an uncrosslinked polymer component is at most 1% by weight, measured under specific conditions, and a process for preparing the same. The present invention relates to a perfluoroelastomer seal material, wherein a rate of weight decrease is at most 1% by weight when the seal material is immersed into perfluoro(tri-n-butyl) amine at 60° C. for 70 hours and is dried at 90° C. for 5 hours, 125° C. for 5 hours and 200° C. for 10 hours after taken out of the emersion. And, the present invention also relates to a process for preparing a perfluoroelastomer seal material comprising a step of treating with a solvent having at least 50% of a swelling rate based on said molded article, when said molded article is immersed at 60° C. for 70 hours.Type: GrantFiled: October 13, 2010Date of Patent: November 13, 2012Assignee: Daikin Industries, Ltd.Inventors: Hiroyuki Tanaka, Tsuyoshi Noguchi
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Patent number: 8258230Abstract: The present invention relates to arborescent polymers and to a process for making same. In one embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with a polymer or copolymer having a low glass transition temperature (Tg), and to a process for making such arborescent polymers. In another embodiment, the present invention relates to arborescent polymers formed from at least one inimer and at least one isoolefin that have been end-functionalized with less than about 5 weight percent end blocks derived from a polymer or copolymer having a high glass transition temperature (Tg), and to a process for making such arborescent polymers.Type: GrantFiled: August 31, 2007Date of Patent: September 4, 2012Assignees: The University of Akron, Lanxess, Inc.Inventors: Gabor Kaszas, Judit Puskas, Kevin Kulbaba, Robert Lloyd Nelson
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Patent number: RE44096Abstract: There is provided a material which is free from fading into white due to surface scattering and is useful as a laminated article having excellent adhesion and practical low reflection.Type: GrantFiled: August 25, 2005Date of Patent: March 19, 2013Assignee: Daikin Industries, Ltd.Inventors: Kazuyuki Sato, Tsuyoshi Itagaki, Yasuo Itami