Abstract: Described herein are articles for separating gases. The article includes a selective layer consisting of a crosslinked amorphous fluorinated copolymer containing one or more types of fluorinated ring monomers, with crosslinking between the fluorinated copolymer chains. The crosslinking improves the mechanical properties of the fluoropolymer, thereby permitting use of polymer types which would otherwise be excessively brittle. The resulting crosslinked polymer membranes have superior selectivity and reliability performance compared with previous compositions known to the art. Methods for making and using the article described are also provided.

Abstract: A redox-active compound is disclosed that is the reaction product of an electron-withdrawing monomer, a cross-linker, and a redox-active moiety. The cross-linker may be connected to the redox-active moiety through the electron-withdrawing functional group. The redox-active compound has a reduced form and an oxidized form and neither the reduced form nor the oxidized form is decomposed by oxygen. The redox-active compound may be used to create a pH gradient in a fluid stream. A redox-active composition may include the redox-active compound, a binder, and a current collector. The redox-active composition may be part of a membraneless electrochemical cell.

Abstract: An electrophotographic photoreceptor includes a conductive substrate and a photosensitive layer on the conductive substrate. The outermost surface layer of the electrophotographic photoreceptor contains fluorine-containing resin particles, a fluorine graft polymer, and an acidic compound having an acid dissociation constant (pKa) of 3 or less in water at 25° C. The amount of the acidic compound relative to the outermost surface layer is 100 ppm or more and 10000 ppm or less.

Abstract: Microporous membrane composites that are non-dewetting are disclosed. These microporous membrane composites are wet with solutions of methanol and water and are non-dewetting following autoclave treatment in water. The microporous membrane composites comprise a microporous membrane support that is coated with a crosslinked ionomer comprising hydrophilic groups. Compared to the microporous membrane support, the microporous membrane composite has a flow loss on average in isopropyl alcohol of less than 82%.

Abstract: The present invention is aimed to provide a highly-productive method for producing a stabilized fluoropolymer. The present invention relates to a method for producing a stabilized fluoropolymer, comprising the step of bringing a fluoropolymer to be treated into contact with a fluorinating agent to produce a stabilized fluoropolymer, while maintaining the concentration of hydrogen fluoride present in a reaction vessel at not higher than 1.0% by volume.

Abstract: Provided is a treatment method for fluororesin pellets to remove hydrofluoric acid released from fluororesin pellets obtained by melt-molding a melt-moldable fluororesin. The treatment method comprises bringing a hydrofluoric acid-removing medium selected from warm water of from 30 to 200° C., steam of from 100 to 200° C. and warm wind of from 40 to 200° C. into contact with fluororesin pellets obtained by melt-molding a melt-moldable fluororesin, and thereby treating the fluororesin pellets so that the amount of hydrofluoric acid released per kg of the resulting fluororesin pellets would be at most 5 ?g as determined after the storage of the resulting fluororesin pellets at 35° C. for 15 days.

Abstract: The invention concerns a method for preparing block copolymers, comprising a step of controlled free-radical copolymerisation of trifluoroethylene with at least one additional monomer, different from trifluoroethylene, in the presence of a chain transfer agent, said chain transfer agent being a xanthate compound, a trithiocarbonate compound or a monoiodide compound. The invention also concerns the block copolymers likely to be obtained by this method.

Abstract: A method of producing a polymeric compound containing a structural unit that decomposes upon exposure to generate an acid, the method including: synthesizing a precursor polymer by polymerizing a water-soluble monomer having an anionic group, washing the precursor polymer with water, and subsequently subjecting the precursor polymer to a salt exchange with an organic cation. Also, a polymeric compound produced using the method of producing a polymeric compound, and a method of forming a resist pattern using the resist composition.

Abstract: An electrochromic device including a first substantially transparent substrate having an electrically conductive material associated therewith; a second substrate having an electrically conductive material associated therewith; and an electrochromic medium contained within a chamber positioned between the first and second substrates which includes: at least one solvent; at least one anodic electroactive material; at least one cathodic electroactive material; wherein at least one of the anodic and cathodic electroactive materials is electrochromic; and a creep resistant crosslinked polyelectrolyte gel matrix.

Abstract: The present invention provides a TFE/Pr type elastomer being excellent in not only amine resistance but also heat resistance and chemical resistance and having a small gel content, and a crosslinkable composition comprising the elastomer. The above-mentioned fluorine-containing elastomer is a fluorine-containing elastomer being crosslinkable with the compound (A), comprising 40 to 70% by mole of tetrafluoroethylene unit, 30 to 60% by mole of propylene unit and 0.1 to 2.5% by mole of a carboxyl group-containing vinyl monomer unit and having a Mooney viscosity at 121° C. of 5 to 100.

Abstract: A sulfonic acid anion-containing polymer having a triarylsulfonium cation is prepared by (1) preparing a sulfonic acid anion-containing polymer having an ammonium or metal cation not bound thereto, (2) purifying the polymer by water washing or crystallization, and (3) then reacting the polymer with a triarylsulfonium salt. A resist composition comprising the inventive polymer is effective for controlling acid diffusion since the sulfonium salt is bound to the polymer backbone.

Abstract: It has been discovered by in present invention that, compared with a fluorosurfactant having only one betaine group per molecule, a fluorosurfactant having a plurality of betaine groups per molecule is superior in its ability to undergo electrostatic interaction with other components of a fire fighting composition thereby improving the performance of the fire fighting composition. Previously known fluorosurfactants comprise only one betaine group per molecule. In contrast, the present invention provides for a fluorobetaine copolymer containing a plurality of betaine groups.

Abstract: A fluorinated elastic copolymer which has iodine atoms, bromine atoms, or both iodine and bromine atoms, at its molecular terminals and which includes repeating units (a) based on tetrafluoroethylene, repeating units (b) based on a fluorinated monomer having one polymerizable unsaturated bond (provided that tetrafluoroethylene is excluded), and repeating units (c) based on a fluorinated monomer having at least two polymerizable unsaturated bonds, wherein the ratio (molar ratio) of the repeating units (a) to the repeating units (b) is (a)/(b)=40/60 to 90/10, and the proportion of the repeating units (c) based on the total amount of the repeating units (a) and the repeating units (b) is from 0.01 to 1 mol %.

Abstract: The invention relates to a method of preparing a fluorinated copolymer, comprising a step of copolymerization of a fluorinated monomer (of the vinylidene fluoride type) with an ?-trifluoromethacrylic acid monomer or derivative of ?-trifluoromethacrylic acid, in the presence of a xanthate or trithiocarbonate compound. The invention also relates to copolymers obtained by this method as well as block copolymers comprising a copolymer block prepared according to this method.

Abstract: The present invention provides a preparation process for converting to a vinylidene fluoride elastomer having a group having sulfinic acid, sulfinic acid derivative, sulfonic acid or sulfonic acid derivative at one end or both ends of its trunk chain, and the preparation process provides a vinylidene fluoride elastomer having, at one end or both ends of its trunk chain, end groups represented by the formula: —CR1R2—CR3R4—SO2H, wherein R1 to R4 may be the same or different and each is hydrogen atom or fluorine atom, by allowing a vinylidene fluoride elastomer having, at one end or both ends of its trunk chain, end groups represented by the formula: —CR1R2—CR3R4—X1, wherein R1 to R4 are as defined above, X1 is bromine atom or iodine atom, to react with a sulfur compound represented by the formula: (M1)nH2-nS2O4, wherein M1 is a monovalent or divalent metal ion or ammonium ion, n is an integer of 0 to 2.

Abstract: There is provided herein a membrane or film comprising one or more aromatic ionomers covalently crosslinked through aryl-aryl (—Ar—Ar—), aryl-ether-aryl (—Ar—O—Ar—), aryl-sulfide-aryl (—Ar—S—Ar—), aryl-sulfone-aryl bonds, or any combination thereof, wherein said one or more aromatic ionomers further comprises at least one electron withdrawing group adapted to improve oxidant resistance of said membrane or film.

Abstract: The present invention provides a method for producing a stabilized fluoropolymer which comprises producing the stabilized fluoropolymer by subjecting a treatment target substance containing a sulfonic-acid-derived-group-containing fluoropolymer to a fluorination treatment, wherein the sulfonic-acid-derived-group-containing fluoropolymer is a fluoropolymer containing —SO3M (in which M represents H, NR1R2R3R4 or M11/L; R1, R2, R3 and R4 are the same or different and each represents H or an alkyl group containing 1 to 4 carbon atoms; and M1 represents an L-valent metal), and the treatment target substance has a moisture content of not higher than 500 ppm by mass.

Abstract: A solid electrolyte polymer including a cross-linked polyvinylidene fluoride (PVDF)-based polymer, and a polymer actuator including the cross-linked PVDF-based polymer and an electrolytic material.

Abstract: There are provided herein selective membranes, such as composite membranes, and/or films and processes for their preparation. The membranes and/or films have a given morphology which may be stabilized, for example against swelling and chemical degradation, by covalent crosslinking and optionally, in addition, by hydrophobization. There is provided a membrane and/or film and a process for the preparation thereof, the membrane and/or film include an ionomer and/or polyelectrolyte crosslinked through aryl-aryl (—Ar—Ar—), aryl-ether-aryl (—Ar—O—Ar—) and/or aryl-sulfide-aryl (—Ar—S—Ar—) bonds.

Abstract: A resist composition containing a base component (A) which generates an acid upon exposure and exhibits changed solubility in a developing solution by the action of acid, wherein the base component (A) contains a copolymer (A1) having a structural unit (a0) containing a group represented by the following general formula (a0-1) or (a0-2), a structural unit (a11) containing an acid-decomposable group which exhibits increased polarity by the action of acid and contains a polycyclic group, and a structural unit (a12) containing an acid-decomposable group which exhibits increased polarity by the action of acid and contains a monocyclic group. Each of the groups —R3—S+(R4)(R5) and Mm+ in the formula has only one aromatic ring as a whole or has no aromatic ring.

Abstract: Obtaining a crosslinked rubber with high flexibility at low temperature includes crosslinking a fluororubber composition. The fluororubber composition includes a fluororubber and a compound of formula (X—)x(Z—)zY. In the formula, X is U—(CF2)aO(CF2CF2O)b—; Z is RFO(CF2CF2O)c—; Y is a (x+z) valent perfluoro saturated hydrocarbon group, optionally interrupted by an etheric oxygen atom; x is an integer of at least 3; z is an integer of at least 0; U is a monovalent group with an unsaturated hydrocarbon, a bromine atom, an iodine atom, or a combination thereof; RF is a C1-20 linear perfluoroalkyl group, optionally interrupted by an etheric oxygen atom; a is an integer of from 0 to 20; b is an integer of from 1 to 200; and c is an integer of from 3 to 200.

Abstract: A stabilized fluorine-containing polymer powder having an average particle size of 5 to 100 ?m is prepared by contacting a fluorine-containing polymer powder, which is prepared by milling the fluorine-containing polymer and removing fine particles, fibrous particles and coarse particles by classification, with a fluorinating agent so that the total number of unstable terminal groups is decreased to 7 to 50 per 106 carbon atoms. This is a fluorine-containing polymer powder achieved a high coating efficiency in an electrostatic coating method and provides a film having good properties such as heat resistance, non-tackiness, low frictional property, chemical resistance, etc.

Abstract: The present invention provides a method for producing a stabilized fluoropolymer which comprises producing the stabilized fluoropolymer by subjecting a treatment target substance containing a sulfonic-acid-derived-group-containing fluoropolymer to a fluorination treatment, wherein the sulfonic-acid-derived-group-containing fluoropolymer is a fluoropolymer containing —SO3M (in which M represents H, NR1R2R3R4 or M11/L; R1, R2, R3 and R4 are the same or different and each represents H or an alkyl group containing 1 to 4 carbon atoms; and M1 represents an L-valent metal), and the treatment target substance has a moisture content of not higher than 500 ppm by mass.

Abstract: The invention provides a compound and tautomeric forms thereof having the formula: wherein Rf1 is selected from the group consisting of hydrogen, a straight chain, branched secondary or branched tertiary C1-C20 perfluoroalkyl group optionally containing ether or thioether linkages and C1-C10 perfluoroalicyclic group optionally containing ether or thioether groups; Rf2 is a straight or branched C1-C20 perfluoroalkylene group optionally substituted with ether and thiother linkages; and X is selected from the group consisting of fluorine and The invention also provides perfluoroelastomeric compositions cured with the perfluoroimidoylamidines of the invention as well as combinations of perfluoroimidoylamidines and other curing agents.

Abstract: A fluororubber composition according to the present invention contains 0.1 to 3 parts by weight of a polyol compound, 0.1 to 4 parts by weight of a peroxide crosslinking agent, and 1 to 9 parts by weight of a co-crosslinking agent per 100 parts by weight of a peroxide-crosslinkable fluoropolymer. A crack-resistant seal according to the present invention contains a crosslinked fluoropolymer and a polyol compound. The crack-resistant seal according to the present invention can be formed by crosslinking the fluororubber composition, and the resultant crack-resistant seal has particularly high crack resistance. With the fluororubber composition according to the present invention, a durable crack-resistant seal having high plasma resistance, crack resistance, and compression set and that produces few particles can be formed at low cost.

Abstract: A method of producing a polymeric compound containing a structural unit that decomposes upon exposure to generate an acid, the method including: synthesizing a precursor polymer by polymerizing a water-soluble monomer having an anionic group, washing the precursor polymer with water, and subsequently subjecting the precursor polymer to a salt exchange with an organic cation. Also, a polymeric compound produced using the method of producing a polymeric compound, and a method of forming a resist pattern using the resist composition.

Abstract: A fluororubber composition which (1) is clean, (2) achieves a higher specific gravity, (3) achieves a better physical property in terms of breaking elongation, (4) is free of halogen substance (chlorine), and (5) provides a rubber surface which is non-tacky to metal(s); and a method for producing a crosslinked fluororubber product. The fluororubber composition includes a peroxide-crosslinkable fluororubber comprising a terfluoropolymer; barium sulfate; a peroxide crosslinking agent; and a salt having BF4? as a counter ion; wherein the barium sulfate is included in an amount of 50 to 180 parts by weight based on 100 parts by weight of the fluoropolymer; and wherein the salt having BF4? as a counter ion is included in an amount of 0.7 to 1.5 parts by weight based on 100 parts by weight of the fluoropolymer.

Abstract: To provide a fluorinated curable resin composition which is excellent in thermal stability and thermal adhesive property. A fluorinated curable resin composition comprising a fluoropolymer (P) having a polymerizable double bond and a thiol compound (S), wherein the fluoropolymer (P) is a copolymer having repeating units derived from a fluoromonoene (a) and a fluorodiene (b) having a residual unsaturated side chain, and the content of the thiol compound (S) is from 0.01 to 1 part by mass per 100 parts by mass of the fluoropolymer (P).

Abstract: Materials are provided that may be useful as ionomers or polymer ionomers, including compounds including bis sulfonyl imide groups which may be highly fluorinated and may be polymers.

Abstract: The present invention discloses a method for making blended polymers by utilizing fluorophilic inter-polymer associative interactions between perfluorocarbon functional groups attached on the constituent polymers. The method of the present invention is capable of forming blended polymers from otherwise incompatible polymers. Also disclosed are blended polymers obtained by the method thereof. Methods and devices utilizing novel blended polymer of the present invention including chromatography, catalysis, photonic and sensor applications are also provided.

Abstract: A foamable fluoropolymer composition containing foam cell nucleating agent is provided, wherein the fluoropolymer comprises melt-fabricable tetrafluoroethylene-/hexafluoropropylene copolymer and tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer, wherein the alkyl contains 1 to 4 carbon atoms, wherein the melting temperature of said tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer is no more than 35° C. greater than the melting temperature of said tetrafluoroethylene/hexafluoropropylene copolymer, and/or wherein said tetrafluoroethylene/hexafluoropropylene copolymer and said tetrafluoroethylene/perfluoro(alkyl vinyl ether) copolymer each have a melt flow rate (MFR) within the range of 1 to 40 g/10 min and the MFR of one of said copolymers is at least twice that of the other of said copolymers.

Abstract: The present invention provides a crosslinkable composition being capable of providing a molded article and a sealing material for an oxygen sensor which have excellent long-term heat resistance and satisfactory compression set. Also there is provided a molded article and a sealing material for an oxygen sensor which have excellent long-term heat resistance and satisfactory compression set. The crosslinkable composition comprises (A) a compound having at least one specific crosslinkable reaction group and (B) a nonperfluoro fluorine-containing elastomer being crosslinkable with the compound (A).

Abstract: Described herein are polymers useful for forming or coating implantable medical devices and such medical devices. The polymers are biocompatible and hemocompatible and comprise PTFE surfaces modified by covalently linking a nitric oxide releasing polymer to the PTFE surface through a linking group. Further described are precursor polymers and processes for preparing such polymers and precursor polymers.

Abstract: The present invention provides a novel production process by which unstable terminal groups can be sufficiently stabilized under mild conditions. The present invention is related to a method for producing an —SO3H group-containing fluoropolymer wherein a fluoropolymer to be treated having a —SO2X group-containing monomer unit (X representing F or Cl) is subjected to a procedure comprising at least the steps A, B and C defined below in that order: A: Step of reacting with a halogenating agent; B: Step of reacting with a decomposition treatment agent; C: Step of reacting with a fluorinating agent.

Abstract: To provide a process for efficiently producing a perfluoropolymer having unstable terminal groups reduced. A process for producing a fluorination-treated perfluoropolymer, which comprises melting a thermoplastic perfluoropolymer to form strands and contacting the polymer strands with a fluorine gas. For fluorination-treatment of the perfluoropolymer, an apparatus 10 is used, which comprises a melt extruder 11 for melting and extruding the perfluoropolymer, a die 12 for forming the melt extruded polymer into continuous strands 1 and a fluorination tank 13 for contacting the continuous strands 1 with a fluorine gas.

Abstract: To provide an amorphous fluorinated polymer which is soluble in a fluorinated solvent having a boiling point of at most 70° C., and a fluorinated polymer composition containing it. An amorphous fluorinated polymer characterized by having a fluorine content of at least 50 mass % and an intrinsic viscosity of at least 0.03 g/dL and less than 0.05 dL/g as measured in perfluoro(2-butyltetrahydrofuran) at 30° C.

Abstract: The present invention provides a method for producing a stabilized fluoropolymer which comprises producing the stabilized fluoropolymer by subjecting a treatment target substance containing a sulfonic-acid-derived-group-containing fluoropolymer to a fluorination treatment, wherein the sulfonic-acid-derived-group-containing fluoropolymer is a fluoropolymer containing —SO3M (in which M represents H, NR1R2R3R4 or M11/L; R1, R2, R3 and R4 are the same or different and each represents H or an alkyl group containing 1 to 4 carbon atoms; and M1 represents an L-valent metal), and the treatment target substance has a moisture content of not higher than 500 ppm by mass.

Abstract: Fluoropolymers having a —CF adjacent to a —CH which are subsequently dehydrofluorinated to create a —C?C— can be used as controlled release carriers for therapeutic agent(s) by covalently conjugating the therapeutic agent(s) to the fluoropolymer at the —C?C—.

Abstract: A stabilized fluorine-containing polymer powder having an average particle size of 5 to 100 ?m is prepared by contacting a fluorine-containing polymer powder, which is prepared by milling the fluorine-containing polymer and removing fine particles, fibrous particles and coarse particles by classification, with a fluorinating agent so that the total number of unstable terminal groups is decreased to 7 to 50 per 106 carbon atoms. This is a fluorine-containing polymer powder achieved a high coating efficiency in an electrostatic coating method and provides a film having good properties such as heat resistance, non-tackiness, low frictional property, chemical resistance, etc.

Abstract: An ink composition for a color filter includes about 100 parts by weight of a pigment dispersion, about 7 parts by weight to about 65 parts by weight of a thermosetting resin having hydroxyl group at a side chain of the thermosetting resin, about 0.015 part by weight to about 1.5 parts by weight of a thermal initiator, about 0.8 part by weight to about 15 parts by weight of an epoxy-based resin containing fluorine, and about 15 parts by weight to about 165 parts by weight of a solvent. A color filter substrate is manufactured using the ink composition for color filter. The ink composition for the color filter improves straightness of ink jetting through an ink-jetting nozzle and prevents the ink composition from spreading to neighboring pixels.

Abstract: A stabilized fluorine-containing polymer powder having an average particle size of 5 to 100 ?m is prepared by contacting a fluorine-containing polymer powder, which is prepared by milling the fluorine-containing polymer and removing fine particles, fibrous particles and coarse particles by classification, with a fluorinating agent so that the total number of unstable terminal groups is decreased to 7 to 50 per 106 carbon atoms. This is a fluorine-containing polymer powder achieved a high coating efficiency in an electrostatic coating method and provides a film having good properties such as heat resistance, non-tackiness, low frictional property, chemical resistance, etc.

Abstract: The present invention provides a novel production process by which unstable terminal groups can be sufficiently stabilized under mild conditions. The present invention is related to a method for producing an —SO3H group-containing fluoropolymer wherein a fluoropolymer to be treated having a —SO2X group-containing monomer unit (X representing F or Cl) is subjected to a procedure comprising at least the steps A, B and C defined below in that order: A: Step of reacting with a halogenating agent; B: Step of reacting with a decomposition treatment agent; C: Step of reacting with a fluorinating agent.

Abstract: It is an object of the present invention to provide a novel method for producing a fluoropolymer according to which unstable terminal groups can be sufficiently stabilized under mild conditions. This invention is related to a method for producing a stabilized fluoropolymer comprising subjecting a fluoropolymer to be treated containing no —SO2X (X representing F or Cl) group-containing monomer units to the following step A, step B and step C in that order: A: Step of reacting with a halogenating agent; B: Step of reacting with a degradation treatment agent; C: Step of reacting with a fluorinating agent.

Abstract: To provide a process for efficiently producing a perfluoropolymer having unstable terminal groups reduced. A process for producing a fluorination-treated perfluoropolymer, which comprises melting a thermoplastic perfluoropolymer to form strands and contacting the polymer strands with a fluorine gas. For fluorination-treatment of the perfluoropolymer, an apparatus 10 is used, which comprises a melt extruder 11 for melting and extruding the perfluoropolymer, a die 12 for forming the melt extruded polymer into continuous strands 1 and a fluorination tank 13 for contacting the continuous strands 1 with a fluorine gas.

Abstract: A curative composition comprising a cation and an anion of the formula Anq?Qpm+, wherein m, n, p, and q are positive integers, wherein m*p=n*q, wherein Qm+ is an organo onium, and Aq? is an anion, provided that at least one Aq? is selected from the formula: wherein each R independently is H, halo, alkyl, aryl, aralkyl, or cycloalkyl, and which also may be halogenated, fluorinated, or perfluorinated, wherein two or more of R and R? groups may together form a ring, wherein each R group independently may contain one or more heteroatom(s), wherein R? can be the same as R, with the proviso that R? cannot be halo. Also provided are a fluoropolymer composition including this curative, a method of making a fluoropolymer, and fluoropolymer articles containing curable or cured fluoropolymer compositions.

Abstract: The present invention relates to a powder paint composition comprising at least (a) a thermosetting polymer having functional groups capable of reacting with ?-hydroxyalkylamide units (b) a compound comprising ?-hydroxyalkylamide units and (c) a deceleration agent, capable of reversibly blocking the functional groups of polymer (a). The deceleration agent is present in an amount sufficient to block at least 9% of the total amount of functional groups of polymer (a). The present invention relates also to the use of a specific amine compound as a deceleration agent in a powder paint composition.

Abstract: Non-coherent UV-treated porous halopolymer membranes are disclosed.

Abstract: Disclosed herein is an ion conductive polymer comprising a unit represented by Formula (1) below: —SO2[N?SO2(M+)]X1-??(1) wherein X1 is an integer greater than 1, and M+ is H+ or Li+. Further disclosed is an imide monomer represented by Formula (A) below: Z1-SO2[N?SO2M+]Y-Z2 ??(A) wherein Y is an integer of 2 or greater, Z1 is OH, F, Cl, Br, I or NZ3Z4 (in which Z3 and Z4 are each independently H, M or SiMe3, and M is a metal element), Z2 is OH, F, Cl, Br, I or NZ3Z4 (in which Z3 and Z4 are each independently H, M or SiMe3, and M is a metal element), and M+ is H+ or Li+.

Abstract: It is an object of the present invention to provide a novel method for producing a fluoropolymer according to which unstable terminal groups can be sufficiently stabilized under mild conditions. This invention is related to a method for producing a stabilized fluoropolymer comprising subjecting a fluoropolymer to be treated containing no —SO2X (X representing F or Cl) group-containing monomer units to the following step A, step B and step C in that order: A: Step of reacting with a halogenating agent; B: Step of reacting with a degradation treatment agent; C: Step of reacting with a fluorinating agent.

Abstract: An object of the present invention is to provide a novel solid reagent capable of solving the problems of conventional solid reagents based on resin beads. The present invention relates to a solid reagent comprising an organic polymer base in which a polymer side chain is introduced onto the backbone of the organic polymer base via graft polymerization and a reactive functional group is introduced onto the polymer side chain. The organic polymer base is preferably in the form of a fiber, a woven or nonwoven fabric consisting of an assembly of fibers, a porous membrane or a hollow fiber membrane. The graft polymerization is preferably a radiation-induced graft polymerization. Solid reagents according to the present invention can be used in various organic synthetic reactions.