Abstract: The present invention relates to a process for producing PEG acrylate-HNBR copolymer which exhibits excellent processability by latex hydrogenation of PEG acrylate-NBR latex to afford PEG acrylate-HNBR latex and subsequent coagulation.

Abstract: This invention relates to a novel process for selectively and efficiently hydrogenating nitrile rubber in the presence of specific complex catalysts system comprising an NHC-ligand comprising Ru-complex catalyst and a specific hydrogenation enhancer.

Abstract: Provided are an adhesive resin composition that can be uniformly applied, has high adhesiveness, and further has high strength in acid resistance, and a laminate including the same. Provided is an adhesive resin composition including an acid-modified polyolefin resin component having a melting point of higher than 80° C. and 140° C. or lower, a crosslinking agent component, and a solvent component, in which the solvent component contains an aromatic solvent, an aliphatic solvent, and a ketone-based solvent, the aromatic solvent has a highest boiling point, and the solvent component contains the aromatic solvent in an amount of 50 parts by mass or more and 80 parts by mass or less, the aliphatic solvent in an amount of 10 parts by mass or more and 30 parts by mass or less, and the ketone-based solvent in an amount of 5 parts by mass or more and 20 parts by mass or less, based on 100 parts by mass of a total amount of the solvent component.

Abstract: The present invention provides a compound of the formula (I): wherein, A is R6(R7)s, N, O, S, or —NR5—; R6 is an s-valent organic group; R7 is each independently, —O—, —S—, —NR5— or —O—P(?O)OR4?—; R2 and R3 are each independently a hydrogen atom or a hydrocarbon group; R4? is each independently, a hydrocarbon group; R5 is each independently, a hydrogen atom or a hydrocarbon group; and s is an integer of 1-10.

Abstract: The present invention is directed to an air spring sleeve comprising: an outer layer, at least one reinforcing layer, and an inner layer that form the sleeve; the outer layer and the inner layer are formed of an elastomeric composition, with the proviso that the elastomeric composition does not comprise epichlorohydrin; and the at least one reinforcing layer comprises a plurality of reinforcing elements disposed between a layer of the elastomeric composition, wherein the elastomeric composition of the at least one reinforcing layer is identical to the elastomeric composition of the outer layer and the inner layer.

Abstract: The present invention is related to a process for the preparation of polymers containing amino groups by hydrogenation of nitrile groups containing polymers by heterogeneous catalysis.

Abstract: A cross-linkable nitrile rubber composition including a highly saturated nitrile rubber (A) containing ?,?-ethylenically unsaturated nitrile monomer units in a ratio of 5 to 50 wt % and having an iodine value of 120 or less, a polysaccharide polymer staple fiber (B) having an average fiber diameter of 1 ?m or less, and a cross-linking agent (C), wherein a ratio of content of the polysaccharide polymer staple fiber (B) is 0.5 to 30 parts by weight with respect to 100 parts by weight of the highly saturated nitrile rubber (A).

Abstract: This invention relates to a novel process for selectively hydrogenating nitrile rubbers in the presence of specific Ruthenium based complex catalysts without simultaneous molecular weight degradation by a metathetic reaction.

Abstract: Elastomer compositions comprising uncured elastomer and reclaimed elastomer are described. In one embodiment, the compositions comprise reclaimed elastomer material (micronized rubber powder) of broad particle size distribution, which is less expensive than traditional reclaimed elastomer material with narrow particle size distribution. Further, compositions comprising reclaimed elastomer materials with broad particle size distribution perform comparably to those comprising reclaimed elastomer materials with narrow particle size distribution. In other embodiments, the compositions comprise both vulcanized, and devulcanized elastomer materials. Advantageously, by using a combination of vulcanized and devulcanized material, it is possible to incorporate a greater percentage by weight of reclaimed material in to an elastomer composition, thus providing additional cost savings while maintaining high levels of mechanical properties.

Abstract: The present invention provides processes for making 2-((3R,5R,6S)-5-(3-chlorophenyl)-6-(4-chlorophenyl)-1-((S)-1-(isopropylsulfonyl)-3-methylbutan-2-yl)-3-methyl-2-oxopiperidin-3-yl)acetic acid as well as intermediates and processes for making the intermediates. Also provided are crystalline forms of the compound and the intermediates.

Abstract: The invention provides a composition comprising at least the following: A) interpolymer comprising, in polymerized form, ethylene, an ?-olefin and a nonconjugated polyene; B) sulfur; C) at least one phase transfer catalyst (PTC) selected from the group consisting of the following: as described herein; as described herein; as described herein; and D) at least one primary accelerator selected from the group consisting of the following: as described herein; as described herein; as described herein; as described herein; and combinations thereof.

Abstract: The present invention provides a compound of the formula (I): wherein: R2 and R3 represent each independently a hydrogen atom or a hydrocarbon group; A represents an s-valent organic group; and s is an integer of 2-10. This nitrileoxide compound has stable and can be easily produced.

Abstract: A cross-linkable nitrile rubber composition obtained by mixing a master batch (B) which contains a nitrile copolymer rubber (b1) having an iodine value of 120 or less and an aromatic polyvalent amine cross-linking agent (b2) into a carboxyl group-containing nitrile copolymer rubber (A) having an iodine value of 120 or less and a cross-linked product obtained by cross-linking the same are provided.

Abstract: This invention relates to a process for the hydrogenation of diene-based copolymers in the presence of catalysts on specific carrier materials containing at least one hyper-branched polymer.

Abstract: Provided is a method of producing a rubber molded article, including crosslinking a rubber compound at a temperature lower than a usual crosslinking temperature (150° C. or more). The method includes a crosslinking step of crosslinking a rubber compound at a temperature of 100° C. or less, the rubber compound having a nitrile structure represented by the following formula (I) and an olefin structure represented by the following formula (II), in a rubber composition containing the rubber compound and a thiol compound having at least two thiol groups in a molecule thereof: provided that R in the formula (II) represents a divalent organic group having 4 or more carbon atoms and having an unsaturated bond represented by —C?C— in a structure thereof.

Abstract: An improved polymerization and process method allows the production of special nitrile rubbers which are characterized by a specific anion content and an excellent storage stability and allow a particularly good vulcanization rate and moreover result in vulcanized materials that have advantageous properties, especially with regard to the contact with metal components of molded parts based on said vulcanized materials.

Abstract: This invention relates to a novel process for selectively hydrogenating nitrile rubbers in the presence of specific Ruthenium based complex catalysts without simultaneous molecular weight degradation by a metathetic reaction.

Abstract: A novel vulcanizable polymer composition is provided which is characterized by a specific combination of a polyamine crosslinking agent and a particular crosslinking accelerator. Furtheron polymer vulcanizates on the basis of such polymer compositions as well as method for preparing such polymer vulcanizate is provided, in particular in the form of mouldings or shaped parts.

Abstract: A non-carboxylated styrene-butadiene copolymer, preparation method and use thereof are provided. The non-carboxylated styrene-butadiene copolymer is prepared by hot polymerization in the absence of acid monomers and is used in asphalt-based systems such as asphalt emulsions.

Abstract: A nitrile rubber coupled via bisdihydropyrazole groups is produced by reacting a nitrile rubber which is based on conjugated dienes, ?,?-unsaturated nitriles and optionally further copolymerizable monomers as monomers, may have been hydrogenated and has covalently bonded tetrazole groups with a bifunctional ene compound in which the ene groups can each be reacted with the tetrazole groups to give dihydropyrazole groups.

Abstract: An epoxy thermoset that includes a reaction product of a toughening agent prepared from a reaction of a first epoxy resin and a polyether polyamine, a second epoxy resin and a liquid amine hardener for the toughening agent and the second epoxy resin. The toughening agent is an adduct of the second epoxy resin and the polyether polyamine. The polyether polyamine phase of the toughening agent separates to form particles in the epoxy thermoset, where the particles have a volume average diameter in a range from 20 nanometers to 200 nanometers.

Abstract: A method for making an electrode active material of a lithium ion battery is disclosed. In the method, elemental sulfur is mixed with a polyacrylonitrile to form a mixture. The mixture is heated in vacuum or a protective gas at a heating temperature of about 250° C. to about 500° C., to form a sulfur containing composite. The sulfur containing composite is reacted with a reducing agent for elemental sulfur in a liquid phase medium to remove part of the elemental sulfur from the sulfur containing composite.

Abstract: The present application relates to a modified rubber masterbatch and preparation method thereof, rubber composition prepared therewith and vulcanized rubber and preparation method thereof. The modified rubber component comprises uncrosslinked rubber and rubber particles having crosslinked structure dispersed therein, wherein the rubber particles having crosslinked structure are synthetic rubber particles and/or natural rubber particles, have an average particle size of 20-500 nm and a gel content of 60% by weight or higher, and wherein the uncrosslinked rubber is styrene-butadiene rubber. The weight ratio of the rubber particles having crosslinked structure to the uncrosslinked rubber is greater than 20:80 and less than or equal to 80:20. The rubber composition comprises a blend of modified rubber component and base rubber, in which the modified rubber masterbatch is present in an amount of 1 to 70 parts by weight, relative to per 100 parts by weight of the base rubber.

Abstract: This invention relates to novel catalyst compositions based on Ruthenium- or Osmium-based complex catalysts and to a process for selectively hydrogenating nitrile rubbers in the presence of such catalyst compositions.

Abstract: There are provided novel vulcanizable compositions based on optionally fully or partly hydrogenated nitrile rubbers containing epoxy groups, and specific crosslinkers, which no longer require use of conventional crosslinkers, more particularly sulphur. The vulcanizates producible therefrom possess very good compression sets at room temperature, 100° C. and 150° C., and additionally exhibit high tensile stress combined with good elongation at break.

Abstract: A carbon nanostructure that is free of a growth substrate can include a plurality of carbon nanotubes that are branched, crosslinked, and share common walls with one another. The carbon nanostructure can be released from a growth substrate in the form of a flake material. Optionally, the carbon nanotubes of the carbon nanostructure can be coated, such as with a polymer, or a filler material can be present within the porosity of the carbon nanostructure. Methods for forming a carbon nanostructure that is free of a growth substrate can include providing a carbon nanostructure adhered to a growth substrate, and removing the carbon nanostructure from the growth substrate to form a carbon nanostructure that is free of the growth substrate. Various techniques can be used to affect removal of the carbon nanostructure from the growth substrate. Isolation of the carbon nanostructure can further employ various wet and/or dry separation techniques.

Abstract: This disclosure relates to composition for grafting fragrance substances, as well as related articles, consumer products, and methods.

Abstract: An improved polymerization and work-up process makes it possible to produce specific nitrile rubbers which have a particular ion index which is responsible for an excellent vulcanization rate and leads to vulcanizates having an advantageous property profile.

Abstract: One embodiment of the present invention relates to ionic liquids and ionic viscoelastics formed between [1] a small molecule or macromolecule containing two or more cations; and [2] a small molecule or macromolecule containing two or more anions. Another embodiment of the invention is the use of the inventive ionic liquids and ionic viscoelastics, formed between a small molecule or macromolecule containing two or more cations and a small molecule or macromolecule containing two or more anions, to form a crosslinked network. In certain embodiments, the ionic liquids formed can be viscous liquids, viscous liquid formed networks, or viscoelastic networks/gels. In certain embodiments, the ionic material of the invention may be used for a variety of applications including, but not limited to, lubricants, additives, gas separation, liquid separation, membranes, fuel cells, sensors, batteries, coatings, heat storage, liquid crystals, biocompatible fluids, solvents, and electronic materials.

Abstract: The invention is based on the discovery that a remarkable improvement in the performance of maleimide thermosets can be achieved by incorporating amide-extended maleimides into an adhesive formulation. Amide-extended maleimides described herein can be used to toughen bismaleimide thermosetting materials without sacrificing any thermal stability. Amide-extended maleimides are readily prepared by reacting a bismaleimide with an appropriate amine via the well-known Michael addition reaction. Acylation of the resulting secondary amines provides the amide-extended maleimide. The acylating agent can also be used to introduce polymerizable functional groups into the backbones of these thermoset monomers. Amide-extended acrylate and methacrylate monomers can also be prepared.

Abstract: The present invention relates to a process for the production of water and solvent-free hydrogenated nitrile rubber polymers, to the hydrogenated nitrile rubbers and the use thereof.

Abstract: The present invention provides methods of depolymerizing and hydrogenating polymers using a transition metal catalyst represented by formula Ia or Ib: where the structural variables are defined herein.

Abstract: An improved polymerization and process method allows the production of special nitrile rubbers which are characterized by a specific anion content and an excellent storage stability and allow a particularly good vulcanization rate and moreover result in vulcanized materials that have advantageous properties, especially with regard to the contact with metal components of molded parts based on said vulcanized materials.

Abstract: Provided are new partially hydrogenated nitrile rubbers which are distinguished by a specific ratio of viscosity to molecular weight, and also vulcanizable mixtures and vulcanizates based on said rubbers, and also the associated preparation processes. The partially hydrogenated nitrile rubbers lead to compounded formulations having advantageous processing properties in conjunction with excellent vulcanizate properties.

Abstract: A process of degrading nitrile rubbers comprises subjecting them to a metathesis reaction in the presence of specific catalysts with increased activity.

Abstract: A non-carboxylated styrene-butadiene copolymer, preparation method and use thereof are provided. The non-carboxylated styrene-butadiene copolymer is prepared by hot polymerization in the absence of acid monomers and is used in asphalt-based systems such as asphalt emulsions.

Abstract: An improved polymerization and work-up process makes it possible to produce specific nitrile rubbers which have a particular ion index which is responsible for an excellent vulcanization rate and leads to vulcanizates having an advantageous property profile.

Abstract: A flame retardant resin composition in which an acrylonitrile-styrene based polymer, into which sulfonic acid groups and/or sulfonate groups have been introduced by sulfonating processing with a sulfonating agent containing less than 3 wt % of moisture, is contained in a resin to be made flame retardant, so that flame retardant properties will be conferred on the resin flame resistant.

Abstract: An adduct of (a) at least one divinylarene dioxide, and (b) at least one end-functionalized polymer. For example, the adduct may be beneficially used as a toughening agent for toughening thermoset resins such as epoxy resins.

Abstract: Catalysts for metathesis reactions, in particular for the metathesis of nitrile rubber, are provided.

Abstract: The present invention provides a production method of a crosslinkable polymer material which includes adding 2 -(glycidyloxy)-1-naphthonitrile oxide or 2-[5 -(ethoxycarbonyl)pentyloxy]-1-naphthonitrile oxide by an addition reaction to a polymer material having a multiple bond to which a nitrile oxide is added by an addition reaction so as to introduce a glycidyl group or an ethoxycarbonyl group into the polymer material.

Abstract: The present invention provides a production method of a modified polymer material produced by modifying a polymer material having in a molecule thereof a multiple bond that reacts with a nitrile oxide, includes reacting the polymer material with an aromatic nitrile oxide derivative having a substituent at an ortho-position of a nitrile oxide group of an aromatic nitrile oxide in which the nitrile oxide group is bonded to an aromatic ring.

Abstract: Biocidal compositions containing organoselenium compounds are disclosed, as well as methods of producing and using same.

Abstract: Through the use of an improved iron-based redox system it is possible to prepare special new, optionally hydrogenated, nitrile rubbers which feature a more uniform monomer distribution and a lower fraction of long-chain branches and hence are distinguished by enhanced flow properties at the same time as very good properties on processing.

Abstract: A nitrile group-containing highly saturated copolymer rubber having an iodine value of 80 or less and containing a caprate in 0.01 to 0.4 wt %. Preferably, the caprate is an alkaline earth metal caprate or Group XIII metal caprate. According to present invention, it is possible to provide a nitrile group-containing highly saturated copolymer rubber improved in mold fouling resistance while maintaining good normal state physical properties and heat resistance when being made into a cross-linked product.

Abstract: The present invention relates to a novel multi functional additive grafted rubber. More particularly the present invention relates to novel grades of rubber and in particular to chemically grafted with cardanol (meta-penta decenyl phenol) and/or its derivatives. Importantly the rubber grades of the invention involve chemically anchored/grafted selective meta alkenyl phenol and/or its derivatives in the backbone of natural or synthetic rubber. Importantly, such rubber variant of the invention have high plasticity, lower Mooney and melt viscosities, better cure properties as compared to conventional virgin natural rubber or natural rubber plasticized with aromatic process oils.

Abstract: In a method for making sulfurized polyacrylonitrile, polyacrylonitrile, a first solvent, a catalyst, and sulfur or sodium thiosulfate are provided. The polyacrylonitrile is dissolved in the first solvent to form a polyacrylonitrile solution. The catalyst is uniformly dispersed in the polyacrylonitrile solution. The polyacrylonitrile solution with the catalyst is heated to induce a cyclizing reaction of the polyacrylonitrile, thereby forming a first conjugated polymer solution with a conjugated polymer. The sulfur or sodium thiosulfate is uniformly mixed with the conjugated polymer to form a mixture. The mixture is heated to form sulfurized polyacrylonitrile.

Abstract: Using nano-particles to topographically enhance the reacting surface of an inorganic fiber used as a reinforcement medium in an embedding matrix is described.

Abstract: A novel process for the metathetic degradation of nitrile rubbers is provided which uses specific transition metal complex catalysts showing an increased activity.

Abstract: The present invention relates to a low molecular weight optionally hydrogenated nitrile rubber and a process for preparing a low molecular weight optionally hydrogenated nitrile rubber by molecular weight degradation of nitrile rubbers via a metathesis process in the presence of a transition metal complex catalyst in a specific reaction mixture, a polymer composite comprising at least one optionally hydrogenated nitrile rubber, at least one cross-linking agent and/or curing system, optionally at least one filler and optionally further auxiliary products for rubbers and a shaped article comprising the optionally hydrogenated nitrile rubber or the composite.