Hydrolyzed; Neutralized; Or Metal Containing Chemical Treating Agent Patents (Class 525/330.2)
  • Patent number: 11815658
    Abstract: Films having high light transmission values, low haze and high glass transition temperatures and useful, for example, as optical protection films and zero-zero optical retardation films, are prepared using one or more copolymers of methyl methacrylate having certain characteristics.
    Type: Grant
    Filed: February 20, 2018
    Date of Patent: November 14, 2023
    Assignee: Trinseo Europe GmbH
    Inventors: Jiaxin Jason Ge, Florence Mehlmann, Estelle Meurice Pierrat
  • Patent number: 10821418
    Abstract: The present invention relates to a super absorbent polymer exhibiting more improved liquid permeability and/or absorption rate while maintaining excellent absorption performance. Such super absorbent polymer comprises a base polymer powder including a first cross-linked polymer of a water-soluble ethylenically unsaturated monomer having at least partially neutralized acidic groups; and a surface cross-linked layer formed on the base polymer powder and including a second cross-linked polymer in which the first cross-linked polymer is further cross-linked through an alkylene carbonate having 2 to 5 carbon atoms, and satisfies predetermined physical properties.
    Type: Grant
    Filed: January 10, 2017
    Date of Patent: November 3, 2020
    Assignee: LG Chem, Ltd.
    Inventors: Dae Woo Nam, Chang Sun Han, Hyemin Lee, Hwayoon Jung, Hyung Ki Yoon
  • Patent number: 10451990
    Abstract: A toner comprising a toner particle including a resin component, wherein the resin component includes an olefin copolymer including ester group having specific structures Y1 and Y2 and an olefin copolymer including acid group having an acid value of from 50 mg KOH/g to 300 mg KOH/g, the amount of the olefin copolymer including ester group is 50% by mass or more, the toner particle has a surface layer including the olefin copolymer including acid group which has formed a salt with a metal, the metal is at least one metal selected from the group consisting of Mg, Ca, Sr, Al, and Zn, and the total amount of the metal in the toner is from 25 ppm to 500 ppm.
    Type: Grant
    Filed: September 20, 2018
    Date of Patent: October 22, 2019
    Assignee: CANON KABUSHIKI KAISHA
    Inventors: Kentaro Kamae, Ryuji Murayama, Junichi Tamura, Hayato Ida, Takashi Hirasa
  • Patent number: 9232786
    Abstract: An agrochemical formulation and its method of manufacture comprising an agrochemical active and a dispersant polymer comprising a copolymer of benzylmethacrylate, acrylic acid and 2-acrylamido-2-methyl propane sulfonic acid.
    Type: Grant
    Filed: April 19, 2010
    Date of Patent: January 12, 2016
    Assignee: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Klin A. Rodrigues, Mark Alexander
  • Patent number: 9095748
    Abstract: Multi-piece golf balls having a solid core of at least one layer and cover of at least one layer are provided. At least one of the core layers comprises a thermoplastic ionomer composition, preferably a highly neutralized ethylene acid copolymer. And, at least one of the core layers comprises a thermoplastic polyamide composition. The ionomer composition is preferably used to form the inner core and the polyamide composition is preferably used to form the outer core layer. More preferably, the ionomer composition has a flex modulus of 80,000 psi or less and the polyamide composition has a flex modulus of 90,000 psi or greater. The resulting ball has high resiliency and rebounding properties.
    Type: Grant
    Filed: June 30, 2011
    Date of Patent: August 4, 2015
    Assignee: Acushnet Company
    Inventors: Michael J. Sullivan, Mark L. Binette
  • Patent number: 9006346
    Abstract: The present invention provides a resin composition for a golf ball and a golf ball which have high resilience while maintaining soft compression and also have low spin on driver shots, and therefore can achieve a long flight distance. The present invention relates to a resin composition for a golf ball, including an ionomer resin consisting of a metal ion-neutralized copolymer of (A) a C3-8 ?,?-unsaturated carboxylic acid and (B) a C3-8 ?,?-unsaturated carboxylic acid ester, the ionomer resin having a mass ratio of (A)/(B) of 10/90 to 25/75, and a degree of neutralization of 30 to 105 mol %.
    Type: Grant
    Filed: December 26, 2012
    Date of Patent: April 14, 2015
    Assignee: Dunlop Sports Co., Ltd.
    Inventors: Kazuki Shiga, Ryo Murakami, Yoshiyuki Ikeda
  • Patent number: 8975339
    Abstract: Provided is a surface treatment method for a water-absorbent resin having excellent production efficiency, absorption capacity against pressure, fluid permeability or the like. Provided is a method for the surface treatment of a water-absorbent resin which comprises a) a step for mixing 0.1 to 20 parts by weight of an acid group-containing radically polymerizable compound and 5 to 20 parts by weight of water, relative to 100 parts by weight of a water-absorbent resin; and b) a step for polymerizing the acid group-containing radically polymerizable compound, wherein neutralization ratio of the acid group-containing radically polymerizable compound is 0 to 60% by mol, and is lower than neutralization ratio of the water-absorbent resin.
    Type: Grant
    Filed: October 8, 2008
    Date of Patent: March 10, 2015
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Yoshiro Mitsukami, Taku Iwamura, Makoto Matsumoto
  • Patent number: 8907022
    Abstract: Disclosed is a method for forming an aqueous dispersion of an ionomer composition comprising mixing a solid ionomer composition with water heated to a temperature from about 80 to about 90° C., the solid ionomer composition comprising an ethylene acid copolymer comprising about 18 to about 30 weight % of copolymerized units of acrylic acid or methacrylic acid, based on the total weight of the parent acid copolymer, the acid copolymer having a melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the total carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts comprising sodium cations.
    Type: Grant
    Filed: August 20, 2012
    Date of Patent: December 9, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventors: Richard Allen Hayes, Elliott Echt
  • Publication number: 20140350191
    Abstract: The present invention relates to a process for the preparation of water-absorbing polymer structures, comprising the following process steps: i) providing an untreated, water-absorbing polymer structure; and ii) bringing the untreated, water-absorbing polymer structure into contact with a salt comprising a divalent or higher-valent cation of a metal and at least one organic base as anion. The invention relates also to the water-absorbing polymer structures obtainable by that process, to water-absorbing polymer structures, to a composite comprising a water-absorbing polymer structure and a substrate, to a process for the preparation of a composite, to the composite obtainable by that process, to chemical products, such as foams, molded articles and fibers comprising water-absorbing polymer structures or a composite, to the use of water-absorbing polymer structures or of a composite in chemical products and to the use of a salt in the treatment of the surface of water-absorbing polymer structures.
    Type: Application
    Filed: August 13, 2014
    Publication date: November 27, 2014
    Inventors: Mirko Walden, Harald Schmidt, Rainer Teni, Armin Reimann, Franck Furno, Jorg Issberner, Peter Herbe, Ursula Nielinger, Michael Keup
  • Publication number: 20140336335
    Abstract: The present invention is concerned with an emulsion copolymer latex comprising an acrylic/methacrylic copolymer obtainable by the emulsion copolymerisation of the following monomer components: A: from 75% weight to 97.5% by weight, based on the total weight of monomer components A+B+C+D, of methyl acrylate; B: from 0.1% to 15% by weight, based on the total weight of monomer components A+B+C+D, of at least one ethylenically unsaturated carboxylic acid monomer containing one C?C double bond capable of free radical copolymerisation with component A and at least one carboxylic acid (CO2H) group; C: from 1% to 20% by weight based on the total weight of monomer components A+B+C+D of at least one associative monomer being a (meth)acrylate ester of an alkoxylated alcohol; and D: from 0% to 15% by weight of one or more non-ionic ethylenically unsaturated monomers other than those defined above as A, B or C; wherein the total monomer components A+B+C+D together add up to 100%.
    Type: Application
    Filed: November 16, 2012
    Publication date: November 13, 2014
    Inventors: Mark Thomas Stanion, Paul Edward Hunt
  • Patent number: 8859685
    Abstract: A process for producing a water absorbent resin is provided with which it is possible to efficiently and inexpensively obtain a surface-crosslinked water-absorbing resin having excellent material properties, while ensuring high productivity. In continuous production scaled up to a large scale (in particular, 1 t/hr or more), the physical properties are improved and stabilized (for example, a reduction in standard deviation of the physical properties) by a surface crosslinking treatment to further improve absorption against pressure (AAP) and saline flow conductivity (SFC).
    Type: Grant
    Filed: August 27, 2010
    Date of Patent: October 14, 2014
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Kozo Nogi, Kunihiko Ishizaki, Kazumasa Konishi
  • Publication number: 20140249278
    Abstract: An ionomer has an ABA-type triblock structure, wherein an A-block is an ionic polymer block including a structural unit having a general formula (i) expressed as follows: —(CH2—CR1(COOM1/y)- where R1 is one of a methyl group and hydrogen, M is one of metal, NH4, organic ammonium and imidazolium, and y is a valence of an M ion, and a B-block is a nonionic polymer block selected from a group consisting of an olefin (co) polymer block, a vinyl (co) polymer block, a diene (co) polymer block, a polyester resin block and a polycarbonate resin block.
    Type: Application
    Filed: May 16, 2014
    Publication date: September 4, 2014
    Inventors: Takashi SAWAGUCHI, Daisuke SASAKI
  • Patent number: 8808816
    Abstract: Gas-barrier multilayer structures and gas-barrier shaped articles are sufficiently prevented from clouding even when exposed to cold water at 30° C. or below and have excellent gas barrier properties. Processes for producing such gas-barrier multilayer structures, and coating liquids (A) of excellent coating properties that are used to produce the multilayer structures are also provided. A coating liquid (A) includes a solvent mixture of water and an organic solvent and a polycarboxylic acid polymer partially neutralized with a polyvalent metal wherein the polymer is both dissolved and dispersed as particles in the solvent mixture and wherein the particles dispersed account for 5 to 80 wt% of 100 wt% of the polycarboxylic acid polymer partially neutralized with a polyvalent metal.
    Type: Grant
    Filed: September 28, 2007
    Date of Patent: August 19, 2014
    Assignee: Toppan Printing Co., Ltd.
    Inventors: Masahiro Yamazaki, Chisato Fujimura, Katsumi Kawaguchi
  • Patent number: 8802786
    Abstract: The present invention relates to a particulate superabsorbent polymer composition which absorbs water, aqueous liquids, and blood, and a process to make the superabsorbent polymers, wherein a superabsorbent polymer is surface treated with a neutralized multivalent metal salt solution having a pH value similar as that of human skin. The present invention also relates to particulate superabsorbent polymer composition having high Gel Bed Permeability and high Absorbency Under Load.
    Type: Grant
    Filed: April 21, 2011
    Date of Patent: August 12, 2014
    Assignee: Evonik Corporation
    Inventors: Yaru Shi, Gonglu Tian, Mark Joy, Geoff Blake, Scott Smith, Bernfried Messner
  • Publication number: 20140206822
    Abstract: The present invention relates to a surface treatment method for magnetic particles, a magnetic composite prepared thereby, and a magnetic composite for labeling target materials. More specifically, the invention relates to a surface treatment method for magnetic particles and a magnetic composite having excellent dispersibility prepared thereby, wherein the surface treatment method comprises the steps of: performing the acid-treatment of magnetic particles and mixing the acid-treated magnetic particles with a water-soluble solvent in order to form a hydroxyl group (—OH) on the surface of the magnetic particles; and mixing the magnetic particles, in which the hydroxyl group is formed, with a surface treatment agent containing an organic ligand, which can be bonded to the hydroxyl group, so that the organic ligand is treated on the surface of the magnetic particles.
    Type: Application
    Filed: June 22, 2012
    Publication date: July 24, 2014
    Applicant: NANOBRICK CO., LTD.
    Inventors: Jae Hyun Joo, Sung-Bok Wee, Youn-Jung Park, Sung-Wan Hong, Hyong-Ku Chang
  • Patent number: 8742026
    Abstract: The invention relates to a process for producing water-absorbing polymer particles with improved permeability, comprising the steps of polymerization, drying, grinding, classification and thermal surface postcrosslinking, with pneumatic conveying between grinding and classification.
    Type: Grant
    Filed: March 2, 2012
    Date of Patent: June 3, 2014
    Assignee: BASF SE
    Inventors: Matthias Weismantel, Markus Braun
  • Patent number: 8729191
    Abstract: An embodiment of the present invention allows for production, with a high productivity, of a water-absorbent resin including an improved relationship between absorption capacity and water-soluble polymer which are conflicting properties of the water-absorbent resin, being easily controlled for polymerization reaction, being of no odor, being less colored, and being of high absorption properties. In one embodiment of the present invention, acrylic acid composition is neutralized with a basic composition including an iron content of 0.2 to 5 ppm by weight (relative to a basic compound exclusive of a solvent); and then polymerizing a resultant neutralized product, the acrylic acid composition including: (i) a methoxyphenol content of 10 to 200 ppm by weight relative to the weight of acrylic acid; and (ii) at least one compound content of which is 0 to 10 ppm by weight relative to the weight of acrylic acid, the compound being selected from the group consisting of protoanemonin and furfural.
    Type: Grant
    Filed: April 6, 2006
    Date of Patent: May 20, 2014
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Takaaki Kawano, Hirotama Fujimaru, Kunihiko Ishizaki, Katsuyuki Wada
  • Patent number: 8729190
    Abstract: A particulate water-absorbent agent containing a polyacrylate salt-type water-absorbent resin. The agent has an absorption capacity without load of 28 g/g or higher and has a diffusion absorption index of 1.40 to 10.0 g/g min. The amount of water-soluble components in the agent, with stirring, is 15-60% by mass. The difference between this amount and the amount of water-soluble components, without stirring, is 15-50% by mass. Also disclosed is a method of making the above-identified agent.
    Type: Grant
    Filed: February 28, 2008
    Date of Patent: May 20, 2014
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Takahiro Kitano, Takaaki Kawano, Katsuyuki Wada
  • Patent number: 8674025
    Abstract: An object of the present invention is to provide a golf ball resin composition with an excellent resilience and fluidity. Another object of the present invention is to provide a golf ball resin composition with a high hardness and durability. Yet another object of the present invention is to provide a golf ball traveling a great distance with an ionomer cover. The present invention provides a golf ball resin composition comprising, (A) an ionomer resin consisting of a metal ion-neutralized product of a binary copolymer composed of an olefin and an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms; (B) a binary copolymer composed of an olefin and an ?,?-unsaturated carboxylic acid having 3 to 8 carbon atoms, and (C) a zinc compound, wherein a content ratio ((A)/(B)) of (A) component to (B) component ranges from 50/50 to 80/20 in a mass ratio and a content of (C) component ranges from 0.
    Type: Grant
    Filed: April 11, 2011
    Date of Patent: March 18, 2014
    Assignee: SRI Sports Limited
    Inventor: Takahiro Shigemitsu
  • Patent number: 8669313
    Abstract: The invention provides a golf ball material which is a resin mixture composed of (a) an olefin-methacrylic acid copolymer and/or an olefin-methacrylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 120,000 to 200,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 4.0 to 7.0, or a metal neutralization product thereof, (b) an olefin-acrylic acid copolymer and/or an olefin-acrylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 150,000 to 220,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 5.5 to 8.5, or a metal neutralization product thereof, (c) an organic acid or a metal salt thereof, and (d) a basic inorganic metal compound for neutralizing at least 70 mol % of acid groups in components (a) to (c), which resin mixture has a Shore D hardness of from 30 to 60.
    Type: Grant
    Filed: November 30, 2010
    Date of Patent: March 11, 2014
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Kae Iizuka, Eiji Takehana
  • Patent number: 8669312
    Abstract: The invention provides a golf ball material which is a resin mixture composed of (a) an olefin-unsaturated carboxylic acid copolymer and/or an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 120,000 to 200,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 4.3 to 6.6, or a metal neutralization product thereof, (b) an olefin-unsaturated carboxylic acid copolymer and/or an olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester copolymer having a weight-average molecular weight (Mw) of from 120,000 to 200,000 and a weight-average molecular weight (Mw) to number-average molecular weight (Mn) ratio of from 6.8 to 9.
    Type: Grant
    Filed: November 30, 2010
    Date of Patent: March 11, 2014
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Kae Iizuka, Eiji Takehana
  • Publication number: 20140065288
    Abstract: Anticaking agents for inhibiting or preventing caking of inorganic salt granules are provided. The anticaking agents comprise a coordination complex of iron and a salt anion of an organic acid, wherein the salt anion is selected from the group consisting of malate, polyacrylate, diphosphonate, and mixtures thereof. Free-flowing, solid salt compositions resistant to caking are also described herein, along with methods of melting ice and/or snow on a surface or inhibiting the accumulation or formation of ice and/or snow on a surface, and methods of preventing or inhibiting caking of solid inorganic salt granules.
    Type: Application
    Filed: September 4, 2013
    Publication date: March 6, 2014
    Applicant: North American Salt Company
    Inventors: Geoffrey A. Brown, Joshua M. Shipman
  • Patent number: 8534465
    Abstract: A process for removing metallic impurities from a product mass flow comprising water-absorbing polymer particles, wherein the product mass flow has a temperature of 35 to 90° C.
    Type: Grant
    Filed: December 7, 2009
    Date of Patent: September 17, 2013
    Assignee: BASF SE
    Inventors: Rüdiger Funk, Jürgen Schröder, Matthias Weismantel
  • Patent number: 8492470
    Abstract: Disclosed are golf balls comprising cores or intermediate layers prepared from thermoplastic compositions having coefficients of restitution equal to or greater than 0.83 and PGA compressions greater than 100. Also disclosed is a composition comprising or prepared from (a) at least one aliphatic, mono-functional organic acid having from 16 to 20 carbon atoms, wherein the organic acid is unsaturated and linear; (b) an ethylene acid copolymer consisting essentially of copolymerized comonomers of ethylene and from 18 to 24 weight % of copolymerized comonomers of at least one C3 to C8 ?,? ethylenically unsaturated carboxylic acid, based on the total weight of the ethylene acid copolymer, having a melt index from about 200 to about 600 g/10 minutes; wherein the combined acid moieties of (a) and (b) are nominally neutralized to a level from about 120% to about 200%; and optionally (c) filler.
    Type: Grant
    Filed: September 22, 2011
    Date of Patent: July 23, 2013
    Assignee: E.I. du Pont de Nemours and Company
    Inventor: James R. De Garavilla
  • Patent number: 8487048
    Abstract: Objects of the present invention are: to provide a water-absorbent resin which exhibits excellent balances between water absorption performances; and further to provide a process by which a water-absorbent resin having excellent absorption properties can be produced even if no hydrophilic organic solvent is used, or even if its amount is extremely reduced, when carrying out the surface-crosslinking treatment; and further to provide a water-absorbent resin optimum to absorbent articles such as diapers.
    Type: Grant
    Filed: May 7, 2004
    Date of Patent: July 16, 2013
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Katsuyuki Wada, Masatoshi Nakamura, Kazuki Kimura, Kunihiko Ishizaki
  • Patent number: 8461268
    Abstract: A golf ball material composed of (A) an oxygen-containing inorganic metal compound in the form of a particulate or a master batch capable of neutralizing at least some of the acid groups in an acid-containing polymer blend, (B) one or more polymer selected from among diene polymers, thermoplastic polymers and thermoset polymers, and (C) an acid-containing polymer is prepared by mixing component A in a blend of components B and C. The golf ball material has a good heat resistance, flowability and processability, and can be used to produce high-performance golf balls having durability, scuff resistance and optimal hardness without a loss of rebound.
    Type: Grant
    Filed: November 15, 2011
    Date of Patent: June 11, 2013
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 8450419
    Abstract: The invention provides a golf ball material comprising components (A), (B) and (C): (A) a mixture of different masterbatches prepared by separately masterbatching two or more different metal ions (A1) or a masterbatch prepared by simultaneously masterbatching two or more different metal ions in itself (A2), (B) one or more polymer selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) one or more polymer having an acid content of from about 0.5 to about 30 wt % and selected from the group consisting of olefin-unsaturated carboxylic acid copolymers, olefin-unsaturated carboxylic acid-unsaturated carboxylic acid ester terpolymers, unsaturated carboxylic anhydride-containing polymers, unsaturated dicarboxylic acid-containing polymers and unsaturated dicarboxylic acid half ester-containing polymers. The invention also provides a method for preparing such a golf ball material, and a golf ball made of the material.
    Type: Grant
    Filed: August 24, 2010
    Date of Patent: May 28, 2013
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 8410223
    Abstract: There is provided a production method for a water-absorbing resin for stably and continuously producing the water-absorbing resin with industrially high property, in particular, the water-absorbing resin with high liquid permeation. A method of the present invention relates to a production method for a water-absorbing resin including: a polymerization step of an aqueous solution of an unsaturated monomer; a drying step of the resultant hydrogel polymer; and a surface cross-linking step after drying; characterized by including a pneumatic transportation step for pneumatic transporting the water-absorbing resin powder substance in a pipeline with a surface roughness (Rz) of the inner surface of equal to or smaller than 800 nm, by using gas with a dew point of ?5° C. to ?100° C.
    Type: Grant
    Filed: March 26, 2009
    Date of Patent: April 2, 2013
    Assignee: Nippon Shokubai Co., Ltd.
    Inventors: Koji Matsumoto, Kozo Nogi, Kunihiko Ishizaki
  • Patent number: 8410219
    Abstract: Provided is a method for increasing the melt flow of a composition comprising a mixture of high molecular weight carboxylate functionalized ethylene copolymers (Mw between 80,000 and 500,000 Da) with low molecular weight carboxylate functionalized ethylene copolymers (Mw between 2,000 and 30,000 Da), wherein the carboxylic acid groups are at least partially neutralized to form salts containing zinc cations. The method comprises melt mixing the composition with ionomers containing cations other than zinc. Also disclosed are trimodal compositions comprising high molecular weight terpolymers, high molecular weight dipolymers and low molecular weight dipolymers wherein the carboxylic acid groups are at least partially neutralized to salts containing zinc cations and non-zinc cations. The compositions are used in films, multilayer structures and other articles of manufacture.
    Type: Grant
    Filed: December 22, 2009
    Date of Patent: April 2, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventor: John Chu Chen
  • Patent number: 8410222
    Abstract: A process for producing water-absorbing polymer particles, comprising polymerization, drying, comminution, classification and recycling of the undersize obtained in the classification, wherein the recycled undersize is coated with a reducing agent and/or inorganic particles.
    Type: Grant
    Filed: July 3, 2009
    Date of Patent: April 2, 2013
    Assignee: BASF SE
    Inventors: Rüdiger Funk, Matthias Weismantel, Sylvia Bertha
  • Patent number: 8399549
    Abstract: Described are golf balls comprising cores or intermediate layers prepared from thermoplastic compositions having coefficients of restitution equal to or greater than 0.83 and PGA compression greater than 100. Also described is a composition comprising or prepared from (a) at least one aliphatic, mono-functional organic acid having from 16 to 20 carbon atoms, wherein the organic acid is unsaturated and linear; (b) an ethylene acid copolymer consisting essentially of copolymerized comonomers of ethylene and from 18 to 24 weight % of copolymerized comonomers of at least one C3 to C8 ?,? ethylenically unsaturated carboxylic acid, based on the total weight of the ethylene acid copolymer, having a melt index from about 200 to about 600 g/10 minutes; wherein the combined acid moieties of (a) and (b) are nominally neutralized to a level from about 120% to about 200%; and optionally (c) filler.
    Type: Grant
    Filed: April 10, 2012
    Date of Patent: March 19, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventor: James R. De Garavilla
  • Patent number: 8394895
    Abstract: A process for continuous thermal postcrosslinking of water-absorbing polymer particles, wherein the postcrosslinker is applied to the water-absorbing polymer particles by means of suitable nozzles and the nozzles are exchanged or cleaned via the interior of a glovebox adjoining the plant section comprising the nozzle.
    Type: Grant
    Filed: June 10, 2009
    Date of Patent: March 12, 2013
    Assignee: BASF SE
    Inventors: Oskar Stephan, Karl J. Possemiers, Ann Becker, Leo Van Miert, Ronny De Kaey
  • Publication number: 20130046063
    Abstract: A method for increasing the efficacy of hydrophobically modified (meth)acrylic based polymers to increase the critical micelle concentration of a surfactant composition by attenuating the degree of neutralization (DN) of the polymer is disclosed.
    Type: Application
    Filed: October 22, 2012
    Publication date: February 21, 2013
    Applicant: Lubrizol Advanced Materials, Inc.
    Inventor: Lubrizol Advanced Materials, Inc.
  • Patent number: 8372920
    Abstract: The present invention relates to a water-absorbing polymer structure comprising about 10 to about 100,000 ppm, based on the solids content of the water-absorbing polymer structure, of a non-polymerized sulphonate, a non-polymerized salt of a sulphonate or a mixture of a non-polymerized sulphonate and a non-polymerized salt of a sulphonate, and less than 1,000 ppm, based on the solids content of the water-absorbing polymer structure, of non-polymerized sulphites, non-polymerized bisulfites, non-polymerized sulphinates or non-polymerized salts of these compounds.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: February 12, 2013
    Assignee: Evonik Stockhausen GmbH
    Inventor: Mirko Walden
  • Patent number: 8362139
    Abstract: The present disclosure relates to a coating composition that can be applied to a conductive substrate via an anodic electrodeposition process, a substrate coated with the coating composition and a process for applying the coating to a substrate. The coating composition comprises an aqueous dispersion of at least partially neutralized copolymer comprising ?-olefin and unsaturated carboxylic acid. After a layer of the coating has been applied to the substrate, it can be heated to cure the coating and form a crosslinked network that provides a durable chip and corrosion resistant finish.
    Type: Grant
    Filed: October 3, 2008
    Date of Patent: January 29, 2013
    Assignee: E I du Pont de Nemours and Company
    Inventor: Allisa Gam
  • Patent number: 8349621
    Abstract: A ligand molecule-immobilized polymer has a structure represented by the following general formula (1). In the general formula (1), R1 represents a ligand molecule-containing group, R2 represents a hydrophobic group, R3 represents a spacer site, R4 represents a hydrophilic group, R5 represents a group having charge, a to d specify a composition ratio and each represent an integer of 1 or more, and n and m specify chain lengths and represent integers satisfying the relationships of 1?n(a+b+c+d)?10,000 and 1?m?350.
    Type: Grant
    Filed: November 24, 2008
    Date of Patent: January 8, 2013
    Assignee: Canon Kabushiki Kaisha
    Inventor: Kousuke Mukumoto
  • Publication number: 20120296034
    Abstract: An acid-functional polymer is reacted with a transition metal compound having an average particle size small enough to react with the polymer at a temperature below the glass transition temperature of the polymer, e.g., at room temperature, to produce cross-linked polymer. The process produces a liquid polymer product that dries to a cross-linked film without the required presence of volatile ligands. Improved coatings such as floor polishes that can be formed from these cross-linked polymers are also disclosed.
    Type: Application
    Filed: July 27, 2012
    Publication date: November 22, 2012
    Inventors: Jay M. Shaffer, Tracy L. Eifolla
  • Patent number: 8293845
    Abstract: A method for increasing the efficacy of hydrophobically modified (meth)acrylic based polymers to increase the critical micelle concentration of a surfactant composition by attenuating the degree of neutralization (DN) of the polymer is disclosed.
    Type: Grant
    Filed: November 9, 2007
    Date of Patent: October 23, 2012
    Inventors: Krishnan Tamareselvy, William F. Masler, III, Deborah S. Filla, Gary Gray
  • Patent number: 8258223
    Abstract: The invention concerns a process for producing water-absorbing polymer, which comprises a base polymer A being mixed with a first aqueous solution B of at least one surface postcrosslinker and a second aqueous solution C of at least one polyvalent cation and thermally treated, wherein said base polymer A is based on at least 50% neutralized acid-functional monomer and said solutions B and C are metered wholly or partly concurrently through separate nozzles whereby a water-absorbing polymer having a high saline flow conductivity value is obtained.
    Type: Grant
    Filed: June 28, 2011
    Date of Patent: September 4, 2012
    Assignee: BASF SE
    Inventors: Ulrich Riegel, Thomas Daniel, Matthias Weismantel, Mark Elliott, Dieter Hermeling
  • Patent number: 8247499
    Abstract: A water-absorbing polymer structure is disclosed, whose surface has been brought into contact with a combination of a metal salt and an oxide of a metal. The invention also relates to a process for treating the surface of water-absorbing polymer structures whereby the surface of water-absorbing polymer structures is brought into contact with a combination of a metal salt and an oxide of a metal at a temperature of from about 50 to about 300° C. The present invention further relates to the water-absorbing polymer structures obtainable by this process, a composite comprising a water-absorbing polymer structure and a substrate, chemical products such as foams and fibers comprising water-absorbing polymer structures or a composite, and the use of a combination of an oxide of a metal and of a metal salt for treatment of the surface of super-absorbing polymer structures.
    Type: Grant
    Filed: April 21, 2006
    Date of Patent: August 21, 2012
    Assignee: Evonik Stockhausen GmbH
    Inventors: Mirko Walden, Franck Furno, Harald Schmidt
  • Patent number: 8236903
    Abstract: An acid-functional polymer is reacted with a transition metal compound having an average particle size small enough to react with the polymer at a temperature below the glass transition temperature of the polymer, e.g., at room temperature, to produce cross-linked polymer. The process produces a liquid polymer product that dries to a cross-linked film without the required presence of volatile ligands. Improved coatings such as floor polishes that can be formed from these cross-linked polymers are also disclosed.
    Type: Grant
    Filed: August 6, 2008
    Date of Patent: August 7, 2012
    Inventors: Jay M. Shaffer, Tracy L. Eifolla
  • Publication number: 20120165121
    Abstract: An object of the present invention is to provide a golf ball resin composition excellent in resilience. Another object of the present invention is to provide a golf ball excellent in a shot feeling and resilience. The golf ball resin composition of the present invention is characterized in that a storage modulus E? (Pa) and a loss modulus E? (Pa) satisfy a following expression; log(E?/E?2)??6.08 when measured at the conditions of the temperature of 12° C., the oscillation frequency of 10 Hz, and a strain of 0.05% in a tensile mode using a dynamic viscoelasticity measuring apparatus.
    Type: Application
    Filed: November 23, 2011
    Publication date: June 28, 2012
    Inventors: Kazuyoshi SHIGA, Ryo MURAKAMI, Takahiro SHIGEMITSU
  • Publication number: 20120165120
    Abstract: An object of the present invention is to provide a golf ball resin composition excellent in resilience. Another object of the present invention is to provide a golf ball excellent in a shot feeling and resilience. The present invention provides a golf ball resin composition having the spin-lattice relaxation time (T1) of 13C nucleus measured by a High resolution solid state carbon nuclear magnetic resonance (NMR) method of 7.3 seconds or shorter.
    Type: Application
    Filed: November 23, 2011
    Publication date: June 28, 2012
    Inventors: Kazuyoshi SHIGA, Ryo Murakami, Hideaki Kimura, Tomoka Kitago, Takahiro Shigemitsu
  • Patent number: 8202925
    Abstract: Described are golf balls comprising cores or intermediate layers prepared from thermoplastic compositions having coefficients of restitution equal to or greater than 0.83 and PGA compression greater than 100. Also described is a composition comprising or prepared from (a) at least one aliphatic, mono-functional organic acid having from 16 to 20 carbon atoms, wherein the organic acid is unsaturated and linear; (b) an ethylene acid copolymer consisting essentially of copolymerized comonomers of ethylene and from 18 to 24 weight % of copolymerized comonomers of at least one C3 to C8 ?,? ethylenically unsaturated carboxylic acid, based on the total weight of the ethylene acid copolymer, having a melt index from about 200 to about 600 g/10 minutes; wherein the combined acid moieties of (a) and (b) are nominally neutralized to a level from about 120% to about 200%; and optionally (c) filler.
    Type: Grant
    Filed: May 26, 2009
    Date of Patent: June 19, 2012
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: James R. De Garavilla
  • Patent number: 8188193
    Abstract: A process for thermally surface postcrosslinking water-absorbing polymer particles in a fluidized bed generated by means of a carrier gas, wherein the surface postcrosslinker is supplied to the fluidized bed in gaseous form.
    Type: Grant
    Filed: July 3, 2009
    Date of Patent: May 29, 2012
    Assignee: BASF SE
    Inventors: Stefan Blei, Marco Krüger, Wilfried Heide, Matthias Weismantel, Uwe Stueven
  • Patent number: 8106115
    Abstract: A golf ball material composed of (A) an oxygen-containing inorganic metal compound in the form of a particulate or a master batch capable of neutralizing at least some of the acid groups in an acid-containing polymer blend, (B) one or more polymer selected from among diene polymers, thermoplastic polymers and thermoset polymers, and (C) an acid-containing polymer is prepared by mixing component A in a blend of components B and C. The golf ball material has a good heat resistance, flowability and processability, and can be used to produce high-performance golf balls having durability, scuff resistance and optimal hardness without a loss of rebound.
    Type: Grant
    Filed: February 20, 2009
    Date of Patent: January 31, 2012
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Publication number: 20120014874
    Abstract: Provided are a photosensitizer-metal nanoparticle charge complex and a composition for photodynamic therapy or diagnosis containing the same. The complex includes a metal nanoparticle, a photosensitizer charged with a first charge, and a linker bound to the metal nanoparticle and charged with a second charge having an opposite polarity to the first charge. During circulation in blood, the photosensitizer-metal nanoparticle charge complex is maintained in a complex type, and thus duration of a side effect of photosensitivity can be reduced. In a tumor tissue, the complex is specifically accumulated, but in a normal tissue, it is difficult for the complex to penetrate. Thus, the complex can selectively destroy the tumor tissue. Moreover, selective fluorescence in the tumor tissue can provide further improvement in accuracy of diagnosing a tumor using the complex.
    Type: Application
    Filed: October 28, 2009
    Publication date: January 19, 2012
    Inventors: Yong-Doo Choi, Bo-seung Jang, JIn-Young Park, Jung-Im Lee, In-Hoo Kim
  • Patent number: 8053524
    Abstract: A golf ball material composed of (A) an olefin-containing thermoplastic polymer having an acid content of at least 0.5 wt % but less than 5.0 wt %, (B) a resin composition which includes one or more selected from the group consisting of diene polymers, thermoplastic polymers and thermoset polymers, and (C) an oxygen-containing inorganic metal compound has a good thermal stability, flow and processability, making it suitable for injection molding. The golf ball material is ideal for the production of high-performance golf balls endowed with durability, scuff resistance and optimal hardness without a loss of rebound in the molded article.
    Type: Grant
    Filed: July 15, 2009
    Date of Patent: November 8, 2011
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Yoshinori Egashira, Eiji Takehana
  • Patent number: 8026315
    Abstract: The present invention relates to a process for producing water-absorbing polymeric particles by polymerizing a monomer solution, which comprises removing the polymer gel from the reactor when the gel temperature is at least 50° C. and the monomer conversion is not more than 90 mol %, and also to a process for producing hygiene articles.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: September 27, 2011
    Assignee: Basf Aktiengesellschaft
    Inventors: Ulrich Riegel, Thomas Daniel, Dieter Hermeling, Mark Elliott
  • Patent number: 8017679
    Abstract: The invention concerns the use of hydrosoluble homopolymers and/or copolymers of acrylic/or methacrylic acid with one or more acrylic, vinyl or ally monomers as an aid to the grinding of mineral particles in aqueous suspension, providing them by their use particular optical properties. The invention also concerns the said aqueous suspensions and their uses in the fields of paper and paint.
    Type: Grant
    Filed: March 6, 2006
    Date of Patent: September 13, 2011
    Assignee: Coatex S.A.S.
    Inventors: Xueping Qiu, Jacques Mongoin, Christian Jacquemet