Polymer Derived From Acrylic Or Methacrylic Acids, Acid Halides Or Salt Monomers Patents (Class 525/329.7)
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Patent number: 12071495Abstract: Provided are polymers obtained by radical copolymerization of a mixture of (1) acrylic acid; (2) methacrylic acid; and (3) at least one allylcatechol selected from 4-allylbenzene-1,2-diol, 3-allylbenzene-1,2-diol and mixtures thereof. The polymers are especially useful for treating a metallic surface intended to be coated by a paint, a varnish or an adhesive. Also provided are methods of coatings making use of this polymer P, compositions comprising the polymer P and useful for these methods, and the obtained coated materials.Type: GrantFiled: November 27, 2019Date of Patent: August 27, 2024Assignee: SPECIALTY OPERATIONS FRANCEInventors: Marie-Pierre Labeau, Guillaume Gody
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Patent number: 12030967Abstract: The present disclosure relates to a preparation method of a super absorbent polymer capable of preparing a super absorbent polymer exhibiting an improved absorption rate while reducing an amount of a blowing agent used. The preparation method of a super absorbent polymer includes: preparing a monomer mixture including a water-soluble ethylene-based unsaturated monomer having at least partially neutralized acidic groups and an internal cross-linking agent; adjusting a dynamic pressure applied to the monomer mixture being transferred to 140 Pa or more by controlling a transfer rate while transferring the monomer mixture to a polymerization reactor; cross-linking and polymerizing the monomer mixture transferred to the polymerization reactor to form a hydrogel polymer; drying, pulverizing and classifying the hydrogel polymer to form a base resin powder; and further cross-linking a surface of the base resin powder in the presence of a surface cross-linking agent to form a surface cross-linked layer.Type: GrantFiled: October 1, 2019Date of Patent: July 9, 2024Assignee: LG Chem, Ltd.Inventors: Tae Young Won, Jungmin Sohn, Hyemin Lee, Junwye Lee, Seongbeom Heo, Kwangin Shin, Chang Hun Han
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Patent number: 12030997Abstract: A production method includes a surface-crosslinking step of heating a mixture of a surface-crosslinking agent and a particulate dried polymer obtained with an acid group-containing unsaturated monomer as a main component. A moisture content of the particulate dried polymer is not greater than 15% by mass. A heating device including a rotary container and a plurality of heating tubes that are located within the rotary container, extend in an axial direction of the rotary container, and rotate together with the rotary container, is used in the surface-crosslinking step. The heating device includes a means for introducing and discharging a gas into and from the rotary container.Type: GrantFiled: May 15, 2019Date of Patent: July 9, 2024Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Ryota Wakabayashi, Shin-ichi Fujino, Mai Sato, Yoshihiro Shobo, Shin-ya Katsube, Kunihiko Ishizaki
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Patent number: 11814549Abstract: An environmentally friendly, bio-based binder system that is useful for the formation of fiberglass insulation, the system includes: A) an aqueous curable binder composition, which includes a carbohydrate and a crosslinking agent; and B) a dedust composition, which includes a blown, stripped plant-based oil and optionally at least one emulsifying agent. The bio-based binder system is typically heated to form a cured binder system.Type: GrantFiled: January 13, 2020Date of Patent: November 14, 2023Assignee: CARGILL, INCORPORATEDInventors: Frank P. Lochel, Jr., John Carl Tolfa
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Patent number: 11773300Abstract: Adhesive compositions are disclosed comprising acrylic copolymers formed from a monomer mixture comprising, based on the total weight of monomers in the monomer mixture, from 59 to 97.9 weight percent 2-ethylhexyl acrylate, from 0.1 to 10 weight percent styrene, from 0 to 25 weight percent methyl methacrylate, and from 2 to 30 weight percent ethyl acrylate, wherein the ratio of ethyl acrylate to styrene (by weight) is greater than 4.5 to 1. Methods for preparing adhesive compositions are disclosed comprising feeding an aqueous initial charge to a reactor, heating the aqueous initial charge to from about 30 to 110° C., gradually feeding a monomer mixture into the reactor over a period of time (less than 3 hours), in the presence of a free-radical polymerization initiator, thereby forming the acrylic adhesive composition, wherein the amount of free monomer in the reactor does not exceed 17 percent by weight, based on the total weight of the reactor contents, during gradual feeding.Type: GrantFiled: July 17, 2018Date of Patent: October 3, 2023Assignees: Dow Global Technologies LLC, Rohm and Hass CompanyInventors: Joseph B. Binder, Hany Necola
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Patent number: 11766695Abstract: A gas barrier laminate including a resin substrate, a first coating layer containing a carboxylic acid polymer; and a second coating layer containing a polyvalent metal compound and a resin, laminated in this order; a ratio of a thickness of the second coating layer to the first coating layer in the range of 1.0 or more and 4.0 or less; and the second coating layer satisfies at least one of the following: (condition 1) a haze of the second coating layer is 8% or less; (condition 2) a surface roughness Ra of the second coating layer is ½ or less of the thickness of the second coating layer; and (condition 3) the number of concave portions having a diameter of 1.5 ?m or more per unit area on a surface of the second coating layer opposite to the first coating layer is 2/0.01 mm2 or less.Type: GrantFiled: July 7, 2020Date of Patent: September 26, 2023Assignee: TOPPAN PRINTING CO., LTD.Inventors: Kengo Okamura, Miki Fukugami
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Patent number: 11384208Abstract: A super absorbent polymer according to the present invention has an excellent discoloration resistance property even under high temperature/high humidity conditions, while maintaining excellent absorption performance, and is preferably used for hygienic materials such as diapers, and thus can exhibit excellent performance.Type: GrantFiled: May 10, 2017Date of Patent: July 12, 2022Inventors: Sang Gi Lee, Hye Mi Nam, Soo Jin Lee, Chang Sun Han, Moo Kon Kim
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Patent number: 11358122Abstract: A moisture absorbent for a vehicle lamp includes a first inorganic material, a second inorganic material, alkali metal phosphate, and a polymer wax are included. A composite moisture absorbent structure includes a first moisture absorbent pack including a powder type moisture absorbent and a second moisture absorbent pack including a capsule type moisture absorbent are embedded.Type: GrantFiled: May 31, 2019Date of Patent: June 14, 2022Assignee: DesiKhan Co., Ltd.Inventors: Sin Jong Hyung, Nak Cheon Choi, You Jin Lee, Jong Hyup Kim
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Patent number: 11325101Abstract: The present invention relates to a super absorbent polymer having not only excellent absorption rate and absorbency under load but also excellent rewetting properties, and a method for preparing the same.Type: GrantFiled: November 17, 2016Date of Patent: May 10, 2022Inventors: Sang Gi Lee, Hye Mi Nam, Min Ho Hwang, Soo Jin Lee, Tae Hwan Jang
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Patent number: 11234909Abstract: The present invention provides a water-in-oil polymeric emulsion composition, including: (a) 25 to 65 wt % of a cross-linked polymer, (b) 15 to 40 wt % of an oil; (c) 1 to 12 wt % of a surfactant; and (d) 1 to 40 wt % of water, wherein (a) the cross-linked polymer is polymerized by using 35 to 85 mol % of a 2-arylamido-2-methylpropane-sulfonic acid totally or partially salified by an alkali metal or ammonium, 15 to 65 mol % of acryloyl morpholine, and 0.005 to 1 mol % of a polyethylenic monomer used as a cross-linking agent.Type: GrantFiled: February 24, 2016Date of Patent: February 1, 2022Assignees: KCI LIMITED, KER CHEMISTRY, SARLInventors: Gwang Ho Yoon, Mae In Lee, Seong Gi Oh, Mallo Paul
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Patent number: 10988415Abstract: The present invention relates to the use of a copolymer as a dispersant for binder compositions based on calcium sulfate, the copolymer having a polymer backbone and sidechains bound thereto, and at least one ionizable monomeric unit M1 and at least one sidechain-carrying monomeric unit M2, characterized in that the copolymer has, in a direction along the polymer backbone, a non-random distribution of the monomeric units M1 and/or of the monomeric units M2.Type: GrantFiled: September 22, 2016Date of Patent: April 27, 2021Assignee: SIKA TECHNOLOGY AGInventors: Jürg Weidmann, Christina Hampel, Jörg Zimmermann
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Patent number: 10928291Abstract: A method for the classification of superabsorber particles is disclosed, in which the superabsorber particles are put onto a top screen deck of a screening machine having at least two screen decks with a different hole size, the superabsorber particles which are smaller than the holes of the respective screen deck respectively falling through the holes and the superabsorber particles remaining on the screen deck being removed via an extraction point. Balls are positioned on each perforated plate, which balls are propelled upward by the movement of the perforated plate and strike from below the screen deck respectively lying above, wherein the balls have a stiffness in the range from 40 to 100 N/mm and a damping in the range from 1 to 4%. A machine for carrying out the method also is disclosed.Type: GrantFiled: June 29, 2016Date of Patent: February 23, 2021Assignee: BASF SEInventors: Oskar Stephan, Norbert Eugen Voll, Rüdiger Funk
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Patent number: 10881191Abstract: The present invention is directed to a debridement and/or implant cleaning tool 1 in which the means for cleaning 4 is made of a biodegradable material. Thus, if parts of the means for cleaning 4 come loose during use, these will be degraded by natural processes in the body and will not remain in the body and cause negative body reactions.Type: GrantFiled: October 28, 2019Date of Patent: January 5, 2021Assignee: LABRIDA ASInventors: S. Petter Lyngstadaas, Johan Wohlfahrt
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Patent number: 10717803Abstract: A block copolymer, in particular for use as a dispersant for mineral binder compositions, including at least one first block A and at least one second block B, wherein the first block A has a monomer unit M1 and the second block B has a monomer unit M2. To this end a proportion of monomer units M2 which is in any case present in the first block A is less than 25 mol %, in particular less than or equal to 10 mol %, based on all the monomer units M1 in the first block A and a proportion of monomer units M1 which is in any case present in the second block B is less than 25 mol %, in particular less than or equal to 10 mol %, based on all the monomer units M2 in the second block B.Type: GrantFiled: March 27, 2015Date of Patent: July 21, 2020Assignee: SIKA TECHNOLOGY AGInventors: Jürg Weidmann, Lukas Frunz, Jörg Zimmermann
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Patent number: 10562999Abstract: A copolymer, in particular a dispersant for solid particles, in particular a dispersant for mineral binder compositions, including a polymer backbone and sidechains bound thereto. Said copolymer includes at least one phosphorus group-carrying monomeric unit M1 and at least one sidechain-carrying monomeric unit M2, the copolymer having, in a direction along the polymer backbone, a non-random distribution of the monomeric units M1 and/or of the monomeric units M2.Type: GrantFiled: September 22, 2016Date of Patent: February 18, 2020Assignee: SIKA TECHNOLOGY AGInventors: Jürg Weidmann, Lukas Frunz, Joachim Glaus, Jürgen Gresser
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Patent number: 10472522Abstract: The invention relates to a process for manufacturing aqueous mineral material suspensions or dried mineral materials using at least one lithium ion neutralised water-soluble organic polymer, the ground mineral materials obtained by this process, the use of the mineral materials in paper, paints and plastics, as well as the use of the lithium ion neutralised water-soluble organic polymer in the manufacturing process as a dispersing and/or grinding enhancer.Type: GrantFiled: April 12, 2018Date of Patent: November 12, 2019Inventors: Patrick A. C. Gane, Matthias Buri, Beat Karth, Samuel Rentsch
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Patent number: 10293555Abstract: Provided is a liquid material for forming a three-dimensional object. The liquid material is adapted to harden a powder material for forming a three-dimensional object containing an organic material. The liquid material contains a solvent and a cross-linking agent. A dynamic contact angle of the liquid material over a film made of the organic material is from 20° to 80°.Type: GrantFiled: November 11, 2015Date of Patent: May 21, 2019Assignee: Ricoh Company, Ltd.Inventors: Mariko Kojima, Yoshihiro Norikane, Keiko Osaka, Hiroshi Iwata, Mitsuru Naruse, Nozomu Tamoto
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Patent number: 10189009Abstract: A water absorbent resin (water absorbing agent) and method for producing it are provided which improve, in a water absorbent article (in particular, a diaper) including a water absorbent resin as a water absorbing agent, the absolute absorption amount (g), liquid absorbing times (in particular, liquid absorbing times at the second instance and later), re-wet (g), and diffusion distance (%) of the water absorbent article. A particulate water absorbing agent of the present invention has a CRC, a proportion of particles with sizes of 600 ?m to 150 ?m as defined through a standard-sieve classification, an SST, and the value of the difference between an FST and the SST each within a predetermined range.Type: GrantFiled: August 30, 2013Date of Patent: January 29, 2019Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Manabu Ueda, Takahiro Kitano, Yoshitaka Ikeuchi, Hiroyuki Ikeuchi, Katsuyuki Wada
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Patent number: 10059817Abstract: The present invention relates to an absorbent suitable for use in a thin sanitary material/absorbent article having a high absorbent content and not prone to gel blocking, the absorbent having excellent liquid diffusibility (e.g. SFC) and minimal decrease in absorption ratio under pressure (e.g., AAP or PUP) even when a liquid permeation enhancer is added, and to a method for manufacturing the high-performance absorbent stably during actual production. The method is a method for manufacturing a polyacrylic acid (salt)-based absorbent, having a surface-crosslinking agent addition step for adding a solution of a surface-crosslinking agent, and a liquid permeation enhancer addition step for adding a liquid permeation enhancer, the liquid permeation enhancer addition step being performed after and/or at the same time as the surface-crosslinking agent addition step, the method characterized in that a surface crosslinking step for performing heat treatment in an atmosphere having a dew point of 45° C. to 100° C.Type: GrantFiled: October 19, 2016Date of Patent: August 28, 2018Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Kazuki Kimura, Yusuke Watanabe, Sayaka Machida, Taku Fujimoto, Kenji Kadonaga
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Patent number: 10029229Abstract: The present invention is directed to adjustable chromophore compounds and materials (e.g., ophthalmic lens materials) incorporating those compounds. The adjustable chromophore compounds include a chemical moiety that structurally changes upon exposure to predetermined electromagnetic radiation (e.g., two photon radiation) as well as lens materials, particularly intraocular lens materials that incorporate those compounds.Type: GrantFiled: July 7, 2015Date of Patent: July 24, 2018Assignee: Novartis AGInventor: Joseph I. Weinschenk, III
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Patent number: 10014525Abstract: This binder for battery electrodes is characterized by containing a polymer including: (A) a structural unit represented by general formula (1) and derived from a monomer having a hydroxyl group (in the formula, R1 is a hydrogen or a C1-C4 straight-chain or branched alkyl group, R2 and R3 are each a hydrogen or a C1-C4 straight-chained or branched alkyl group, and n is an integer of 2-30); (B) a structural unit derived from an ethylenically unsaturated monomer having at least one functional group selected from the group consisting of a difunctional carboxylic acid group, a nitrile group and a ketone group; and (C) a structural unit derived from a polyfunctional (meth)acrylate monomer having at most five functional groups.Type: GrantFiled: January 24, 2014Date of Patent: July 3, 2018Assignee: OSAKA SODA CO., LTD.Inventors: Takashi Matsuo, Tomoyuki Yano, Yasushi Miki, Katsuhito Miura
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Patent number: 9969910Abstract: In conventional moisture curable compositions, it has been difficult to control changes in the physical characteristics of the cured products to a low level when the cured products are left in a high temperature atmosphere of 80° C. or more as a reliability test. The present invention is characterized by being able to control changes to a low level and having a slight change in elongation rate required to follow the expansion of an adherend under a high temperature atmosphere. The moisture curable composition contains components (A) to (D); component (A): an oligomer, in which a main skeleton is a (meth)acrylic polymer, having a hydrolyzable silyl group in the molecule component (B): a polydialkylsiloxane; component (C): a titanium catalyst; and component (D): a silane-based coupling agent having an isocyanurate skeleton.Type: GrantFiled: November 6, 2014Date of Patent: May 15, 2018Assignee: Three Bond Co., Ltd.Inventors: Yosuke Watanabe, Hiroki Sadanaga
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Patent number: 9868800Abstract: A method for producing polyacrylic acid (salt)-based water-absorbing resin includes a step of polymerizing an acrylic acid (salt)-based aqueous monomer solution, the polymerization step involving use of a polymerization reaction apparatus including a polymerization reaction unit covered with a casing, the polymerization step involving a polymerization reaction under internal pressure of the polymerization reaction unit, the internal pressure being slightly reduced and having a pressure reduction level of more than 0 kPa and not more than 10 kPa relative to the ambient pressure at the periphery of the polymerization reaction unit.Type: GrantFiled: April 24, 2015Date of Patent: January 16, 2018Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Shinichi Fujino, Kunihiko Ishizaki, Satoshi Matsumoto
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Patent number: 9824792Abstract: A wiring harness has a waterproof structure in which a waterproof agent covers a conductor exposed portion-and outer peripheral surfaces of end portions of wire covering members of a plurality of insulated wires in succession, the portion including a splice portion where portions of the members of the insulated wires are removed and the exposed conductors are spliced together and a bundle of the exposed conductors of the insulated wires, the end portions being adjacent to the portion, whereby the portion is sealed with the waterproof agent, wherein the waterproof agent is a cured product of an ultraviolet curable adhesive agent that contains (A) an ester acrylate having a linear or branched C2-C12 alkyl group, (B) a (meth)acrylate compound comprising at least two urethane bonds in one molecule, and (C) a photopolymerization initiator.Type: GrantFiled: October 9, 2015Date of Patent: November 21, 2017Assignees: AutoNetworks Technologies, Ltd., Sumitomo Wiring Systems, Ltd., Sumitomo Electric Industries, Ltd., Kyushu UniversityInventors: Kazuo Nakashima, Takehiro Hosokawa, Tatsuya Hase, Kenji Ito, Makoto Mizoguchi
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Patent number: 9771500Abstract: The present invention provides a sealant composition for electronic device, in which the curing does not proceed when heated, which does not cause the problem of use in the mounting process of electronic device. The present invention relates to a sealant composition for electronic device comprising (a) a compound having two or more (meth)acryloyl groups and (c) a nitroxide compound and/or a thiocarbonylthio compound.Type: GrantFiled: February 3, 2016Date of Patent: September 26, 2017Assignee: HENKEL AG & CO. KGAAInventors: Yusuke Horiguchi, Kenichiro Sato, Mieko Sano
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Patent number: 9605128Abstract: A gas barrier material comprising a polycarboxylic acid polymer, and containing 0.10 to 1.4% by weight of a monovalent metal element, at least not less than 5.0% by weight of a polyvalent metal element, and 0.01 to 3.0% by weight of a nitrogen element per the total weight of nitrogen and carbon. The gas barrier material exhibits excellent gas barrier property, excellent waterproof property after the bend working and excellent appearance on the surface of the coating.Type: GrantFiled: March 14, 2013Date of Patent: March 28, 2017Assignee: TOYO SEIKAN GROUP HOLDINGS, LTD.Inventors: Shunya Nangou, Yusuke Obu, Kashiko Kawai, Tomohiro Miyai, Nan Zhang
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Patent number: 9528006Abstract: To provide a coating composition for undercoating which, in forming a gas-barrier layer having a crosslinked structure between a polycarboxylic acid type polymer and polyvalent metal ions by the heating at a low temperature for a short period of time, permits polyvalent metal ions to be easily and quickly fed into the polycarboxylic acid type polymer and, besides, into the whole gas-barrier layer. A coating composition containing, as chief components, a nonaqueous polyester polyol, an isocyanate compound, and an alkaline compound of a polyvalent metal that serves as an ion source for forming the crosslinked structure, wherein the nonaqueous polyester polyol contains a nonaqueous polyester polyol which contains a metal element in the resin skeleton thereof as an essential component, and the alkaline compound of the polyvalent metal has an average primary particle size in a range of 0.005 to 0.5 ?m.Type: GrantFiled: December 24, 2010Date of Patent: December 27, 2016Assignees: TOYO SEIKAN KAISYA, LTD., KANSAI PAINT CO., LTD.Inventors: Yusuke Obu, Kashiko Kawai, Tomohiro Miyai, Shunya Nangou, Takahiro Hidaka, Hideki Masuda
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Patent number: 9517446Abstract: The present invention relates to a super absorbent polymer (SAP) and a preparation method thereof. More specifically, the present invention provides a SAP satisfying the overall properties required to a SAP and especially the superior initial absorbency and absorbing rate under load at the same time, and a preparation method thereof, by treating the surface of the SAP with a surface treatment solution including water and a diol-based or glycol-based surface crosslinking agent.Type: GrantFiled: April 23, 2013Date of Patent: December 13, 2016Assignee: LG Chem, Ltd.Inventors: Tae-Young Won, Chang-Sun Han, Gi-Cheul Kim, Yong-Hun Lee, Sang-Gi Lee, Kyu-Pal Kim, Sung-Soo Park, Gyu Leem
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Patent number: 9505861Abstract: Comb polymers having carboxyl/carboxylate and ester groups, containing a) 0.1-0.9 mol fractions of a partial structural unit S1, which is derived from an acrylic/methacrylic or maleic acid unit, b) 0-0.4 mol fractions of a partial structural unit S2, which is derived, for example, from an acrylic/methacrylic or maleic acid unit, which is esterified by means of a C1 to C20-alkanol or a polyalkylene glycol, alkyl-capped on one end, preferably a polyethylene glycol, and c) 0.1-0.4 mol fractions of a partial structural unit S3, which is derived from an acrylic/methacrylic or maleic acid unit, which is esterified by means of a polyalkylene glycol monoalkyl ether, which has a terminal, secondary hydroxyl group of the form-CH(R3)OH, wherein R3 is bulky alkyl group, preferably a methyl group.Type: GrantFiled: August 31, 2012Date of Patent: November 29, 2016Assignee: SIKA TECHNOLOGY AGInventors: Ueli Sulser, Jörg Zimmermann, Lukas Frunz
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Patent number: 9447203Abstract: An object of the present invention is to provide a method for producing water absorbent resin powder in which permeability potential (SFC) is improved while a water absorbing rate (FSR) is being kept. The method is a method for producing water absorbent polyacrylic acid (salt) resin powder including the steps of: (i) polymerizing an acrylic acid (salt) monomer aqueous solution; (ii) during or after the step of (i), performing gel grinding of a hydrogel crosslinked polymer obtained by the polymerization, wherein the hydrogel crosslinked polymer has resin solid content of 10 wt % to 80 wt %, and the gel grinding is carried out with gel grinding energy (GGE) of 18 [J/g] to 60 [J/g]; (iii) drying a particulate hydrogel crosslinked polymer obtained by the gel grinding, wherein the drying is performed at 150° C. to 250° C.; and (iv) carrying out a surface treatment to the particulate hydrogel crosslinked polymer thus dried.Type: GrantFiled: April 7, 2011Date of Patent: September 20, 2016Assignee: NIPPOM SHOKUBAI CO., LTD.Inventors: Sayaka Machida, Kazushi Torii, Yoko Shirai, Hiroyuki Ikeuchi, Shigeru Sakamoto, Koji Tachi, Reiko Nakatsuru
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Patent number: 9320822Abstract: The present invention provides a method for manufacturing a water-absorbing resin which (i) is made of acrylic acid that is suitable for mass production of water-absorbing resin and (ii) has an excellent water-absorbing property. In the method, a polyacrylic acid (salt)-based water-absorbing resin is manufactured by sequentially carrying out predetermined monomer preparing step, polymerization step, drying step, and surface crosslinking step. An acetic acid concentration in acrylic acid or the like supplied in the monomer preparing step is in a range of 300 ppm to 10000 ppm on the acrylic acid basis, and an acetic acid concentration lowering rate defined by a predetermined formula is 35% or higher.Type: GrantFiled: February 18, 2013Date of Patent: April 26, 2016Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Satoshi Matsumoto, Takashi Miyamoto, Toyofumi Sakai, Yoshitake Ishii, Kunihiko Ishizaki
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Patent number: 9315640Abstract: Provided is a method for producing a water absorbent resin, which promotes the formation of interconnected voids (continuous gas bubbles) in a foamed polymer (foam-like water absorbent resin) by a more convenient method, and produces with high efficiency a water absorbent resin which exhibits a high water absorption rate even when stepped into a sheet form or a powder form in hygiene articles and the like.Type: GrantFiled: May 27, 2015Date of Patent: April 19, 2016Assignee: Nippon Shokubai Co., Ltd.Inventors: Toshihiro Takaai, Hidenori Wada, Sinichi Fujino
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Patent number: 9303361Abstract: The present invention relates to a method for producing a cationic surface sizing agent, and contains a first step of obtaining a copolymer (A) by solution-polymerizing a monomer mixture which contains a monomer having a tertiary amino group (a) in the amount of 15 to 45% by weight, a (meth)acrylic acid ester (b) in the amount of 15 to 85% by weight, and styrenes (c) in the amount of 0 to 70% by weight in the presence of a chain transfer agent; a second step of obtaining a copolymer (B) by polymerizing the copolymer (A) and a nonionic hydrophilic monomer (d); a third step of obtaining a copolymer (C) by polymerizing the copolymer (B) and a hydrophobic monomer (e) in the absence of a surfactant; and a fourth step of obtaining a quaternary ammonium salt of the copolymer (C) by quaternizing a tertiary amino group present in the copolymer (C).Type: GrantFiled: August 18, 2011Date of Patent: April 5, 2016Assignee: HARIMA CHEMICALS, INC.Inventors: Takuji Sodeyama, Yoko Hayashi, Kazushige Inaoka
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Patent number: 9266309Abstract: A method of producing a gas-barrier laminated member having a gas-barrier layer formed by crosslinking the carboxyl groups of a polycarboxylic acid polymer with multivalent metal ions. The method comprises forming a layer (A) containing an alkaline compound of a multivalent metal on at least one surface of a plastic base material, applying a solution (b) obtained by dissolving a polycarboxylic acid polymer in a solvent containing at least water onto the layer (A) that contains the alkaline compound of the multivalent metal, and removing the solvent by a heat treatment so that a metal-ionically crosslinked structure is formed with the multivalent metal ions among the carboxyl groups in the solution (b). The gas-barrier laminated member has excellent adhesion to the base material, gas-barrier property, retort resistance and flexibility, and is efficiently produced by only being heated at a low temperature for a short period of time through a decreased number of simplified steps.Type: GrantFiled: June 26, 2009Date of Patent: February 23, 2016Assignees: TOYO SEIKAN KAISHA, LTD., KANSAI PAINT CO., LTD.Inventors: Yusuke Obu, Kashiko Kawai, Tomohiro Miyai, Takahiro Hidaka, Hideki Masuda
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Patent number: 9260611Abstract: Provided is a synthesis method for a self-dispersible pigment, including performing ring-opening addition of a lactone-based compound to an acidic group bonded to a surface of a pigment particle directly or via another atomic group to bond a functional group including an ester group to the surface of the pigment particle.Type: GrantFiled: November 1, 2011Date of Patent: February 16, 2016Assignee: Canon Kabushiki KaishaInventors: Katsuhiro Hayashi, Junichi Sakai, Kenji Nishiguchi
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Patent number: 9186313Abstract: A hair treatment composition comprising: i) an oligosaccharide comprising 3 to 7 sugar units in which the linkage group between the sugar units is an a 1-4 link; and ii) an acrylic pressure sensitive adhesive comprising: i) an acrylic group having a side-chain with at least 4 carbons (eg n-butyl acrylate or 2-ethylhexyl acrylate) and; ii) a short side-chain acrylic such as methyl acrylate. the weight ratio of short side chain acrylic group ii) to the acrylic group i).Type: GrantFiled: February 3, 2012Date of Patent: November 17, 2015Assignee: Conopco, Inc.Inventors: Lalitesh Chandra, Deryn Lorraine Nicholls, Prem Kumar Cheyalazhagan Paul
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Patent number: 9169369Abstract: An adsorption-desorption material, in particular, crosslinked vinylepoxide-amine polymeric materials having an Mw from about 500 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material, and linear vinylepoxide-amine polymeric materials having an Mw from about 140 to about 1×106, a total pore volume from about 0.2 cc/g to about 2.0 cc/g, and an adsorption capacity of at least about 0.2 millimoles adsorbed CO2 per gram of adsorption-desorption material. This disclosure also relates to processes for preparing the crosslinked and linear vinylepoxide-amine materials, as well as to selective removal of CO2 and/or other acid gases from a gaseous stream using the vinylepoxide materials.Type: GrantFiled: December 21, 2011Date of Patent: October 27, 2015Assignee: ExxonMobil Research and Engineered CompanyInventors: Dennis G. Peiffer, David C. Calabro, Quanchang Li, Mobae Afeworki
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Patent number: 9138505Abstract: Disclosed is a method for producing a water absorbent resin, by which a surface-crosslinked water absorbent resin having excellent physical properties can be efficiently obtained at low cost, while assuring high productivity. When the production scale is increased to a continuous production on a huge scale (for example, 1 t/hr or more), the physical properties are improved and stabilized (for example, standard deviation of the physical properties is reduced) by a surface-crosslinking treatment, and the absorption against pressure (AAP) and liquid permeability (SFC) are further improved.Type: GrantFiled: August 27, 2010Date of Patent: September 22, 2015Assignee: NIPPON SHOKUBAI CO., LTD.Inventors: Kozo Nogi, Kunihiko Ishizaki, Katsuyuki Wada
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Patent number: 9127092Abstract: A method for preparing a coupled polymer, the method comprising the steps of: (i) polymerizing monomer to form a reactive polymer, and (ii) reacting the reactive polymer with coumarin or a substituted coumarin compound.Type: GrantFiled: December 27, 2013Date of Patent: September 8, 2015Assignee: Bridgestone CorporationInventor: Steven Luo
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Patent number: 9102804Abstract: A method for producing a water-absorbing resin comprises circulation of the water-absorbing resin in a predetermined amount in a pulverization step before a surface cross-linking step. At least a part of a classified polymer is supplied again to the same or a different pulverization step before the surface cross-linking step, wherein the circulation pulverization ratio in the pulverization step, represented by the following equation, is 1.10 to 1.50: (Circulation pulverization ratio)=(total supply amount of the water-absorbing resin to the pulverization step)/(total discharge amount of the water-absorbing resin at the drying step) wherein (total supply amount of the water-absorbing resin to the pulverization step)=(total discharge amount of the water-absorbing resin at the drying step)+(amount of the classified polymer supplied again to the same or a different pulverization step).Type: GrantFiled: September 16, 2010Date of Patent: August 11, 2015Assignee: Nippon Shokubai Co., LtdInventors: Sayaka Machida, Kazushi Torii, Yoko Shirai, Hiroyuki Ikeuchi, Kunihiki Ishizaki
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Patent number: 9074030Abstract: Provided is a method for producing a water absorbent resin, which promotes the formation of interconnected voids (continuous gas bubbles) in a foamed polymer (foam-like water absorbent resin) by a more convenient method, and produces with high efficiency a water absorbent resin which exhibits a high water absorption rate even when stepped into a sheet form or a powder form in hygiene articles and the like.Type: GrantFiled: June 29, 2011Date of Patent: July 7, 2015Assignee: Nippon Shokubai Co., Ltd.Inventors: Toshihiro Takaai, Hidenori Wada, Shinichi Fujino
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Patent number: 9029480Abstract: The present invention relates to a preparation method of a superabsorbent polymer, and specifically to a method of preparing a superabsorbent polymer including the steps of: preparing a hydrous gel phase polymer by thermal polymerizing or photo-polymerizing a monomer composition including a water-soluble ethylene-based unsaturated monomer and a polymerization initiator; drying the hydrous gel phase polymer; milling the dried polymer; classifying the milled hydrous gel phase polymer into two or more grades by particle size; adding a surface cross-linking agent to each hydrous gel phase polymer classified into two or more grades; and carrying out a surface cross-linking reaction of the hydrous gel phase polymer to which the surface cross-linking agent is added.Type: GrantFiled: November 28, 2011Date of Patent: May 12, 2015Assignee: LG Chem, Ltd.Inventors: Tae-Young Won, Chang-Sun Han, Gi-Cheul Kim, Sang-Gi Lee, Kyu-Pal Kim, Sung-Soo Park, Gyu Leem
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Patent number: 9023951Abstract: Disclosed is a method for producing a water absorbent resin, by which a surface-crosslinked water absorbent resin having excellent physical properties can be efficiently obtained at low cost, while assuring high productivity. When the production scale is increased to a continuous production on a huge scale (for example, 1 t/hr or more), the physical properties are improved and stabilized (for example, standard deviation of the physical properties is reduced) by a surface-crosslinking treatment, and the absorption against pressure (AAP) and liquid permeability (SFC) are further improved.Type: GrantFiled: August 27, 2010Date of Patent: May 5, 2015Assignee: Nippon Shokubai Co., Ltd.Inventors: Kozo Nogi, Kunihiko Ishizaki, Syuji Kanzaki
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Patent number: 9018326Abstract: A two-part acrylic adhesive composition comprising at least one organoborane-amine complex initiator and at least one multifunctional maleimide crosslinker.Type: GrantFiled: March 12, 2013Date of Patent: April 28, 2015Assignee: IPS CorporationInventor: Xiaoyi Xie
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Publication number: 20150087742Abstract: The present invention relates to a super absorbent polymer (SAP) and a preparation method thereof. More specifically, the present invention provides a SAP satisfying the overall properties required to a SAP and especially the superior initial absorbency and absorbing rate under load at the same time, and a preparation method thereof, by treating the surface of the SAP with a surface treatment solution including water and a diol-based or glycol-based surface crosslinking agent.Type: ApplicationFiled: April 23, 2013Publication date: March 26, 2015Inventors: Tae-Young Won, Chang-Sun Han, Gi-Cheul Kim, Yong-Hun Lee, Sang-Gi Lee, Kyu-Pal Kim, Sung-Soo Park, Gyu Leem
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Publication number: 20150080151Abstract: A golf ball comprises a dynamically crosslinked thermoplastic material prepared by a method including: (a) partially crosslinking a rubber composition of a rubber polymer and two free radical initiators at a first crosslinking temperature to form a thermoplastic, partially crosslinked elastomer composition; (b) mixing a thermoplastic polymer composition with the thermoplastic, partially crosslinked rubber composition and heating the mixture to a second crosslinking temperature higher than the first crosslinking temperature and at which the thermoplastic polymer composition is liquid; and (c) continuously mixing the mixture while further crosslinking the rubber composition to form a thermoplastic material having a dispersed phase of crosslinked rubber composition in the thermoplastic polymer composition.Type: ApplicationFiled: September 17, 2013Publication date: March 19, 2015Applicant: NIKE, INC.Inventor: John C. Chen
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Patent number: 8981011Abstract: The present application relates to an olefin-based ionomer resin composition, to an encapsulant, and to an optoelectronic device. The resin composition according to the present application may be used as an encapsulant for a variety of optoelectronic devices, and may exhibit superior adhesion to the substrates of the optoelectronic devices. In addition, according to the present application, an olefin-based ionomer resin composition, which can provide good workability and economic advantages in the manufacture of devices without negatively affecting components such as encapsulated optoelectronic elements or the wired electrodes of optoelectronic devices, may be provided.Type: GrantFiled: October 18, 2013Date of Patent: March 17, 2015Assignee: LG Chem, Ltd.Inventors: Hoon Chae, Beom Doo Seo, Choong Hoon Lee, Sung Ho Choi
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Patent number: 8975342Abstract: Compositions are described that are blends of a grafted copolymer and a polyamide. Methods of making the blended compositions are also described. The grafted copolymers are the reaction product of (1) a first compound having both an aziridinyl group and a polymeric group with (2) a second polymeric material having an acidic group. Blending the grafted copolymer with the polyamide can be used, for example, to increase the cohesive strength of the grafted copolymer.Type: GrantFiled: November 16, 2011Date of Patent: March 10, 2015Assignee: 3M Innovative Properties CompanyInventors: Jason D. Clapper, Kevin M. Lewandowski, Craig E. Hamer
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Patent number: 8975339Abstract: Provided is a surface treatment method for a water-absorbent resin having excellent production efficiency, absorption capacity against pressure, fluid permeability or the like. Provided is a method for the surface treatment of a water-absorbent resin which comprises a) a step for mixing 0.1 to 20 parts by weight of an acid group-containing radically polymerizable compound and 5 to 20 parts by weight of water, relative to 100 parts by weight of a water-absorbent resin; and b) a step for polymerizing the acid group-containing radically polymerizable compound, wherein neutralization ratio of the acid group-containing radically polymerizable compound is 0 to 60% by mol, and is lower than neutralization ratio of the water-absorbent resin.Type: GrantFiled: October 8, 2008Date of Patent: March 10, 2015Assignee: Nippon Shokubai Co., Ltd.Inventors: Yoshiro Mitsukami, Taku Iwamura, Makoto Matsumoto
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Patent number: 8969497Abstract: A method for producing a water-absorbent resin including the step of subjecting a water-soluble ethylenically unsaturated monomer to a reversed phase suspension polymerization in a petroleum hydrocarbon dispersion medium in the presence of a radical polymerization initiator and a dispersion stabilizer, wherein the method is characterized by the use of an ether-ester type nonionic surfactant as the dispersion stabilizer, and a water-absorbent resin obtained by the method, wherein the water-absorbent resin has a water-retention capacity of saline solution of 25 g/g or more, a water-absorption rate of saline solution of 50 seconds or less, and a flow index under moisture absorption of 70% or more. According to the method of the present invention, a water-absorbent resin having high water-retention capacity, excellent water-absorption rate, and further having excellent flowability under moisture absorption can be produced.Type: GrantFiled: August 23, 2012Date of Patent: March 3, 2015Assignee: Sumitomo Seika Chemicals Co., Ltd.Inventors: Masayoshi Handa, Junichi Takatori