Abstract: Crosslinking coagents based on aromatic diimides having N-substituted allyl groups are employed in place of triallyl isocyanurate (TAIC) for the free radical curing of fluoroelastomers. The diimide coagents mix more easily with fluoroelastomers and are less likely to homopolymerize than TAIC. Thus mold fouling and sticking due to low molecular weight polymers of coagent is greatly reduced.

Abstract: An aromatic ether oligomer or polyaromatic ether comprising the formula: wherein Ar is an independently selected divalent aromatic radical; formed by reacting a dihydroxyaromatic with a dihaloaromatic; and wherein the reaction is performed in the presence of a copper compound and cesium carbonate. The polyaromatic ether is formed when neither the dihydroxyaromatic nor the dihaloaromatic is present in an excess amount. The aromatic ether oligomer is formed by using an excess of either dihydroxyaromatic or dihaloaromatic. A phthalonitrile monomer comprising the formula: formed by reacting a 3- or 4-nitrophthalonitrile with a hydroxy-terminated aromatic ether oligomer. A thermoset formed by curing the phthalonitrile monomer. Processes for forming all the above.

Abstract: Crosslinking coagents based on aromatic diimides having N-substituted allyl groups are employed in place of triallyl isocyanurate (TAIC) for the free radical curing of fluoroelastomers. The diimide coagents mix more easily with fluoroelastomers and are less likely to homopolymerize than TAIC. Thus mold fouling and sticking due to low molecular weight polymers of coagent is greatly reduced.

Abstract: Compositions are disclosed which comprise mixtures of at least one compound selected from silicone elastomers, bis-, tri- or higher polymaleimides and/or bis-, tri- or higher polycitraconimides, and at least one compound selected from p-phenylene-diamine based antiozonants, sulfur compounds capable of accelerating sulfur vulcanization of polymers capable of being crosslinked by sulfur and polysulfide polymers which when compounded into polymers curable by free radical initiators in the presence of free radical initiators permit substantially tack free surface cure of the polymers by decomposition of the free radical initiator in the presence of molecular oxygen. Compositions containing the above ingredients and at least one free radical initiator, curable compositions containing the combination and processes for making and using the compositions are also disclosed.

Abstract: A polythioether comprising: wherein R1 is a C1-10 alkyl, —(R3Q)pR3— or C6-C20 aryl where Q is O or S, each R3 is independently C1-6 alkyl, and p is an integer between 0 and 6; R2 is C1-6 alkyloxy or C5-12 cycloalkyloxy, R4 is H, C1-6 alkyl, C1-6 alkyl alcohol and C0-6 alkyl substituted with where X is a halogen, m is an integer between 1 and 4, and n is an integer selected to yield a molecular weight for said polythioether of between 1000 and 10,000 Daltons.

Abstract: A structure of signal transmission line comprising a core portion, a middle material layer and a coating layer, it is characterized by that: the core portion includes at least one transmission medium enveloped with an insulation layer; the coating layer includes at least one layer; the middle material layer is provided between the core portion and the coating layer, and is comprised of at least a metallic-wire knitting layer and a paper wrapping layer. By separated transmitting of signals of high and low frequencies with the core portion with plural cores, the skin effect is lowered; and by providing more than one obscuring layers, the degree of mutual interference among a magnetic field, radio frequencies and static electricity can be lowered, and thereby, transmission with lower attenuation rate, smaller distortion and superior quality can be obtained.

Abstract: Curable compositions comprise a benzoxazine compound or resin in combination with at least one additional curable compound or resin. Optionally, the composition will further comprise a curing agent and/or a filler. These compositions have utility as adhesives, coatings and encapsulants, especially for use within the semiconductor fabrication industry, with particular utility as die attach adhesives, films, and underfill materials, such as no-flow underfills, capillary flow underfills, wafer level underfills, and as lead free solders.

Abstract: A three dimensional copolymer network of polyphenylene ether segments and styrenic resins such as styrene/acrylonitrile copolymers provide articles of high heat reesistance and dielectric properties suitable for use in electronic components. Methods for preparing the copolymers employ polyphenylene ether polymers with end caps having at least one pair of unsaturated aliphatic carbon atoms, i.e. carbon-carbon double bond, and polymerize styrene monomers and acrylonitrile monomers or styrene/acrylonitrile copolymers or both in the presence of these polyphenylene ether polymers.

Abstract: The present invention relates to a method for evaluating the crosslink degree of a vulcanized sample in real time during a vulcanization process or diagnosing the electrical properties of the sample after the completion of the vulcanization process, and then determining an optimal vulcanization time and an optimal content of each constituent gradient of a composition for vulcanization that optimize the properties of the composition according to the vulcanization conditions, for the sake of improving the properties of the vulcanized sample prepared from a polymer by vulcanization at a high temperature.

Abstract: A liner is the product of reaction of (a) a hydrophilic prepolymer bearing isocyanate groups; and (b) a water-borne polymer dispersion, the polymer bearing groups that are reactive to isocyanate groups; wherein the dispersion has a sufficiently high solids content, and the polymer has a sufficiently high modulus and glass transition or crystalline melting temperature, that the product of reaction exhibits a 24-hour Tensile Strength of at least about 2.5 MPa.

Abstract: The present invention provides a curable polyphenylene ether (PPE) resin, a composition made therefrom, and a process for preparing the resin. The process involves introducing a vinyl group-containing functional group to the terminal end of PPE by modifying the hydroxy and ester groups on the terminal end. Thus, a curable thermosetting PPE resin including a vinyl group on the terminal end can be obtained. Since the dehydrogenation of side chain methyl using n-BuLi is not conducted in the process of the present invention, the process is much easier, and the cost can be decreased.

Abstract: The invention provides a liner which is the product of reaction of a (a) hydrophilic prepolymer bearing isocyanate groups; and (b) a water-borne polyurethane dispersion, the polyurethane bearing groups that are reactive to isocyanate groups.

Abstract: A one-step, in-situ, process for producing a high solids content emulsion or dispersion of partially or totally crosslinked urea formaldehyde (UF), melamine formaldehyde (MF), or melamine urea formaldehyde (MUF) resin droplets or particles, by forming a reaction mixture of (i) aqueous formaldehyde (formalin), (ii) at least one water-soluble protective colloid, (iii) water and (iv) optionally a surfactant, and mixing the reaction mixture in a reaction vessel; optionally adjusting the initial pH of the reaction mixture according to a desired value as needed; adding (i) urea or substituted urea, (ii) melamine or substituted melamine, or (iii) a mixture thereof, to the reaction mixture; and heating the reaction mixture to a temperature at which condensation takes place between the (i) urea or substituted urea, (ii) the melamine or substituted melamine, or (iii) the mixture thereof, and the formaldehyde to form a urea formaldehyde, melamine formaldehyde or melamine urea formaldehyde resin, and holding the reaction

Abstract: A polythioether comprising: R4—S&Brketopenst;R1—S—CH2CH2—(R2)m—S&Brketclosest;nR1SR4 wherein R1 is a C1-10 alkyl, —(R3Q)pR3— or C6-C20 aryl where Q is O or S, each R3 is independently C1-6 alkyl, and p is an integer between 0 and 6; R2 is C1-6 alkyloxy or C5-12 cycloalkyloxy, R4 is H, C1-6 alkyl, C1-6 alkyl alcohol and C0-6 alkyl substituted with &Brketopenst;CH2CH2(R2)m&Brketclosest;X, where X is a halogen, m is an integer between 1 and 4, and n is an integer selected to yield a molecular weight for said polythioether of between 1000 and 10,000 Daltons.

Abstract: A polythioether is provided of the formula wherein R1 is H, C1-6 alkyl, C1-6 alkyl alcohol, C1-6 alkyl substituted with at least one of: —NHR5 wherein R5 is a C1-6 alkyl, R2 is C2-6 alkyl, C6-8 cycloalkyl, C6-10 alkylcycloalkyl, —[—(CH2)r—Q—]s—(CH2)t—, or C1-2 alkyl substituted forms thereof, wherein r is an integer value from 2 to 8, Q is a heteroatom selected from the group consisting of: O, S, —NH— and —NCH3—, s is an integer value from 1 to 5, and t is an integer value from 2 to 10, R3 is H or C1-4 alkyl, R4 is —CH2— or R2, M is a C1-10 alkyl, C6-20 aryl, C6-20 aryl substituted with at least one C1-8 alkyl group, or a N or O heteroatom, Y is C2-20 alkyl, C6-20 cycloalkyl, C6-10 alkylcycloalkyl, or —[—(CH2)r—Q—]s(—CH2—)t—, n is an integer value from 1 to 60, m is an integer value from 1 to 60, and p is an integer value from 1 to 10,

Abstract: A catayltic process for the hydrogenation of aromatic polymers is disclosed. The catalyst used in the process is a metal or mixture of metals of sub-group VIII of the periodic table together with a support of silicon dioxide, aluminum oxide or a mixture thereof. The catalyst, having pores is characaterized in that the pores having diameters of 100 to 1,000 Å constitute less than 15 percent of the total volume of pores. The hydrogenation, that is carried out in the presence of at least one oxygen-containing hydrocarbon is characterized in that it is essentially complete and without significant degradation of molecular weights.

Abstract: The present invention provides a crosslinking agent which may have reactive benzoxazine groups prepared from (a) at least one aromatic compound, (b) at least one aminotriazine compound, and (c) at least one other compound having active hydrogen groups reactive with aminoplast compound (b). The crosslinking agent is essentially free of hydroxyl functionality and has a glass transition temperature of at least 25° C. The present invention is further directed to a method for preparing the above-described crosslinking agent, and a curable powder coating composition comprising a mixture of (A) a polymer having functional groups reactive with aminotriazine and/or benzoxazine groups having a glass transition temperature of at least 30° C.; and (B) the above crosslinking agent. Multilayer composite coating compositions are also provided including a basecoat deposited from a film-forming composition and a topcoat over the basecoat, deposited from the curable powder coating composition described above.

Abstract: A rubber composition is disclosed containing an ethylene-propylene-nonconjugated diene copolymer rubber (or a blend of an ethylene-propylene-nonconjugated diene copolymer rubber and a diene rubber), a specific alkoxysilane compound, and amorphous silica powder having a specific surface area of 50 to 100 m2/g (BET adsorption). The vulcanized rubber is prepared by vulcanizing such a rubber composition. The rubber composition is excellent in dynamic characteristics and also in mechanical characteristics, dynamic fatigue resistance and thermal aging resistance. It also can provide a vulcanized rubber having the above-mentioned effects.

Abstract: Membranes for use in polymer electrolyte fuel cells or electrolyzers comprise a sulfonated aromatic polyether ether ketone of the formula (I) wherein the ion exchange equivalent (I.E.C.) of the sulfonated polyether ether ketone is in the range from 1.35 to 1.95 mmol (—SO3H)/g (polymer) and the membrane has a long-term stability of at least 1000 hours at an operating voltage of from 0.4 to 1.1 V.

Abstract: This invention involves a composition composed of a homopolymer of vinyl ethylene carbonate or a copolymer of vinyl ethylene carbonate, which is further reacted with ammonia, a primary alkyl amine, or an amino alcohol. The resulting compound, which is a polymer containing both carbamate and hydroxyl groups is then mixed with an aminoplast, coated on a substrate and cured to form a crosslinked coating. In addition, the polymer containing both hydroxyl and carbamate functional groups can be further reacted with either an anhydride or a monofunctional isocyanate, resulting in a copolymer containing only carbamate functional groups. This copolymer is mixed with an aminoplast, coated on a substrate and cured to form a crosslinked coating.

Abstract: The present invention relates to titanate compounds of the formula wherein R is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms and x is an integer of from 2 to 8.

Abstract: The specification discloses a method for vulcanizing an elastomer using as the cure promoter the monomeric distillate by-product from the clay-based dimerization of an unsaturated fatty acid mixture, preferably a tall oil fatty acid mixture. The distillate provides a cost-effective alternative to conventional fatty acid promoters.

Abstract: A one-step, in-situ, process for producing a high solids content emulsion or dispersion of partially or totally crosslinked urea formaldehyde or melamine formaldehyde resin droplets or particles, by forming a reaction mixture of (i) aqueous formaldehyde (formalin), (ii) at least one water-soluble protective colloid, (iii) water and (iv) optionally a surfactant, and mixing the reaction mixture in a reaction vessel; optionally adjusting the initial pH of the reaction mixture according to a desired value as needed; adding (a) urea, substituted urea, or a mixture thereof, or (b) melamine, substituted melamine, or a mixture thereof, to the reaction mixture; and heating the reaction mixture to a temperature at which condensation takes place between the (a) urea, substituted urea, or the mixture thereof, or (b) melamine substituted melamine, or the mixture thereof, and the formaldehyde to form a urea formaldehyde or melamine formaldehyde resin, and holding the reaction mixture at that temperature or a higher tempera