Monomer Contains Non-conjugated Diene Group Or At Least One Fused Or Bridged Ring Or At Least One Cycloaliphatic Structure Patents (Class 525/332.1)
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Patent number: 12178894Abstract: The invention relates to a thickening composition intended for topical application on the skin, lips or skin appendages, said thickening composition comprising at least one oil derived from a biological source and at least one poly(farnesene) polymer having a number average molar mass ranging from 10,000 to 120,000 g/mol. The invention also relates to a cosmetic composition comprising the thickening composition according to the invention and the use of the thickening composition according to the invention in a cosmetic composition.Type: GrantFiled: January 10, 2020Date of Patent: December 31, 2024Assignee: TOTALENERGIES ONETECHInventor: Benjamin Swoboda
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Patent number: 11573359Abstract: A method for producing a polarizing plate including a polarizer and a substrate film is provided. The method comprises: stretching a primary film to obtain a polarizer material film; providing an unstretched substrate film on the polarizer material film to obtain a layered body; and stretching the layered body to obtain the polarizing plate. The polarizer includes a dichroic material and has a thickness T of 20 ?m or less. A phase difference Re in an in-plane direction of the substrate film in the polarizing plate is 20 nm or less.Type: GrantFiled: May 25, 2021Date of Patent: February 7, 2023Assignee: ZEON CORPORATIONInventors: Hiromu Mashima, Takamichi Inomata
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Patent number: 11331390Abstract: The first aspect of the present invention relates to an ophthalmic composition comprising (A) one or more kinds selected from the group consisting of terpenoid, a tocopherol, and a benzyl ammonium compound and a salt thereof, wherein the ophthalmic composition is contained in a container in which a portion or the whole of a part coming into contact with the ophthalmic composition is formed from a resin containing a cyclic olefin. The second aspect of the present invention relates to an ophthalmic composition comprising (A2) a surface active component and (B2) a buffer, wherein the ophthalmic composition is contained in a container in which a portion or the whole of a part coming into contact with the ophthalmic composition is formed from a resin containing a cyclic olefin.Type: GrantFiled: April 21, 2017Date of Patent: May 17, 2022Assignee: ROHTO PHARMACEUTICAL CO., LTD.Inventor: Yasuko Matsumura
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Patent number: 11220563Abstract: To provide a novel production method for a hydrogenated petroleum resin that does not cause filter clogging and is also capable of suppressing a significant decrease in catalytic activity in hydrogenation in a production method for a dicyclopentadiene/vinyl aromatic compound-based hydrogenated resin to be used as a tackifier. A production method for a dicyclopentadiene/vinyl aromatic compound-based hydrogenated petroleum resin, in which a reaction product obtained by reacting a dicyclopentadiene with a vinyl aromatic compound is subjected to thermal polymerization, thereby obtaining a thermal polymerization reaction product, followed by hydrogenation thereof, characterized in that as the thermal polymerization reaction product, an oligomer-removed thermal polymerization reaction product obtained by removing a dicyclopentadiene oligomer from the thermal polymerization reaction product is used as a hydrogenation raw material.Type: GrantFiled: March 8, 2018Date of Patent: January 11, 2022Assignee: Maruzen Petrochemical Co., Ltd.Inventors: Keisuke Matsushita, Yoshikazu Iizima, Tomoki Hayashi
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Patent number: 10815407Abstract: A rubber composition is, in particular, suitable for producing a sealing part for a high pressure hydrogen apparatus having excellent low temperature sealing properties and blister resistance, and the sealing part for a high pressure hydrogen apparatus is obtained by using the rubber composition. A rubber composition includes an ethylene/butene/ethylidene norbornene terpolymer (EBENB), and the rubber composition is for use in producing a sealing part for a high pressure hydrogen apparatus.Type: GrantFiled: August 21, 2018Date of Patent: October 27, 2020Assignee: NOK CORPORATIONInventor: Atsushi Koga
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Patent number: 10669398Abstract: The present invention is a flame-retardant resin composition comprising a cycloolefin-based polymer and a halogen-containing flame retardant selected from a group consisting of a halogenated bisimide compound and a halogen-containing styrene-based resin, and may be comprising a halogen-active species scavenger, wherein a content of the halogen-containing flame retardant is 10 to 80 parts by weight based on 100 parts by weight of the cycloolefin-based polymer, and a content of the halogen-active species scavenger is less than 25 parts by weight based on 100 parts by weight of the halogen-containing flame retardant, and a resin formed article. One aspect of the invention provides a flame-retardant resin composition having excellent flame retardance, low dielectric constant and low dielectric loss tangent, and a resin formed article produced by forming this flame-retardant resin composition.Type: GrantFiled: March 8, 2016Date of Patent: June 2, 2020Assignee: ZEON CORPORATIONInventors: Ayako Kato, Shinsuke Miyazawa
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Patent number: 10597340Abstract: Provided herein are methods and compositions for the electrochemical selective radiofluorination of aromatic molecules. The resulting fluorine-18 labeled compounds are ideal radionuclides for use in Positron Emission Tomography (PET); they are also difficult to radiolabel efficiently and with high specific activity using existing approaches. For example, radiopharmaceuticals such as [F18]L-DOPA, which is indispensable in PET brain disease imaging, may be made electrochemically with high radiochemical yield and high specific activity using 18F-. The invention process described herein opens new possibilities and provides wider access to PET tracers such as 18F-L-Dopa, since 18F- is much more widely available than the 18F2, currently used for synthesis of electron rich substrates.Type: GrantFiled: November 10, 2015Date of Patent: March 24, 2020Assignee: THE REGENTS OF THE UNIVERSITY OF CALIFORNIAInventors: Saman Sadeghi, Qinggang He, Artem Lebedev
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Patent number: 10590233Abstract: The present invention provides a hydrogenated syndiotactic crystalline dicyclopentadiene ring-opening polymer having a melting point of lower than 280° C., an initial melting temperature of 260° C. or higher and a syndiotacticity of higher than 90%, and a syndiotactic dicyclopentadiene ring-opening polymer, and a method for producing the syndiotactic dicyclopentadiene ring-opening polymer, and a method for producing the hydrogenated syndiotactic crystalline dicyclopentadiene ring-opening polymer. The hydrogenated syndiotactic crystalline dicyclopentadiene ring-opening polymer has a sufficiently high initial melting temperature, excellent heat resistance and advantageous industrial producibility. The syndiotactic dicyclopentadiene ring-opening polymer is excellent in solution stability after polymerization reaction and can be converted into the hydrogenated product by hydrogenation reaction.Type: GrantFiled: February 4, 2016Date of Patent: March 17, 2020Assignee: ZEON CORPORATIONInventor: Shigetaka Hayano
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Patent number: 10351664Abstract: The present invention is a resin formed article comprising a hydrogenated syndiotactic crystalline dicyclopentadiene ring-opening polymer with an initial melting temperature of 260° C. or higher, a melting point of lower than 280° C. and a syndiotacticity of higher than 90%, and a resin film, and an injection formed article. One aspect of the invention provides a resin formed article, a resin film and an injection formed article which sufficiently reflect the properties of the hydrogenated crystalline dicyclopentadiene ring-opening polymer.Type: GrantFiled: March 8, 2016Date of Patent: July 16, 2019Assignee: ZEON CORPORATIONInventors: Masatsugu Kato, Shigetaka Hayano
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Patent number: 10179833Abstract: An oligomer, composition, and composite material employing the same are provided. The oligomer can be a reaction product of a reactant (a) and a reactant (b). The reactant (a) is a reaction product of a reactant (c) and a reactant (d). The reactant (b) can be or a combination thereof, wherein a is 0 or 1, and R1 is independently hydrogen or and wherein b is 0-6; c is 0 or 1; and, d is 0-6. The reactant (c) is wherein R2 is C5-10 alkyl group. The reactant (d) is wherein e is 0-10.Type: GrantFiled: December 30, 2016Date of Patent: January 15, 2019Assignee: INDUSTRIAL TECHNOLOGY RESEARCH INSTITUTEInventors: Ming-Tsung Hong, Yun-Ching Lee, Wei-Ta Yang, Meng-Song Yin
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Patent number: 9809720Abstract: A novel ferroelectric ink comprising multiphase Barium Strontium Titanate (BST) in a polymer composite is described. The ink can be employed using direct-ink writing techniques to print high dielectric constant, low loss, and electrostatically-tunable dielectrics on substrates. The substrates can be flexible such as plastics or rigid, such as substrates comprising semiconductor materials or ceramics and the like. The dielectric ink is made by suspending pre-sintered nano/submicron-sized particles of BST in a thermoplastic polymer with a solvent. After printing with the ink, a low temperature curing process is performed at temperatures below 200° C., a temperature too low to sinter BST. Fully printed devices, such as a varactor and a phase shifter using direct ink writing methodologies are described.Type: GrantFiled: July 6, 2016Date of Patent: November 7, 2017Assignee: University of MassachusettsInventors: Mahdi Haghzadeh, Alkim Akyurtlu, Craig Armiento
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Patent number: 9156969Abstract: The present invention relates to a conjugated diene based polymer comprising a monomer unit derived from at least one conjugated diene selected from 1,3-butadiene and isoprene and a monomer unit derived from a compound represented by Formula (1): wherein n represents an integer of 0 to 5; R11, R12 and R13 each independently represent an alkyl group having 1 to 10 carbon atoms.Type: GrantFiled: April 7, 2014Date of Patent: October 13, 2015Assignee: Sumitomo Chemical Company, LimitedInventor: Mana Fujii
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Patent number: 8981026Abstract: This invention relates to a cycloolefin copolymer, which is prepared via ring-opening metathesis polymerization using, as monomers, dicyclopentadiene obtained by chemically bonding two cyclopentadiene molecules using a Diels-Alder reaction and tricyclopentadiene obtained by chemically bonding three cyclopentadiene molecules using a Diels-Alder reaction, in which the cyclopentadiene is a C5-fraction of naphtha cracking, and to a method of preparing the same. This copolymer is a non-crystalline transparent resin and is useful for a variety of end uses.Type: GrantFiled: August 6, 2012Date of Patent: March 17, 2015Assignee: Kolon Industries, Inc.Inventors: Woon Sung Hwang, Jong Un Sung, Woon Jin Park, Sung Rak Joo, Bun Yeoul Lee, Eun Seok Park
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Patent number: 8981012Abstract: The present invention provides novel, modified polydicyclopentadienes and methods to prepare modified polydicyclopentadienes. The modified polydicyclopentadienes prepared by the methods of the invention are useful in many applications including new and useful solid phases for chromatography.Type: GrantFiled: July 8, 2009Date of Patent: March 17, 2015Assignee: University of Iowa Research FoundationInventors: Ned B. Bowden, Mathew Perring
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Publication number: 20150065660Abstract: The invention provides methods and membranes for separating mixtures of two or more compounds such as fatty acids or fatty acid esters.Type: ApplicationFiled: September 4, 2014Publication date: March 5, 2015Inventors: Ned B. Bowden, Abhinaba Gupta
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Patent number: 8946366Abstract: Disclosed herein are a cyclic olefin compound, a photoreactive polymer, and an alignment layer comprising the photoreactive polymer, where the cyclic olefin compound can be used to provide the photoreactive polymer having not only excellences in liquid crystal alignment and alignment rate but also readiness for change in the alignment direction depending on the polarization direction.Type: GrantFiled: September 23, 2011Date of Patent: February 3, 2015Assignee: LG Chem, Ltd.Inventors: Dong-Woo Yoo, Sung-Ho Chun, Dai-Seung Choi, Sung-Kyoung Lee
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Patent number: 8940848Abstract: The present invention relates to a branched conjugated diene copolymer which is useful for preparing a rubber composition, having high uniformity of a temperature dependence curve of a viscoelasticity tan ?, for a tire, a rubber composition comprising the copolymer, and a pneumatic tire produced using the rubber composition for a tire. The branched conjugated diene copolymer is composed of monomer components comprising a branched conjugated diene compound represented by a general formula (1): wherein R1 represents an aliphatic hydrocarbon group having 6 to 11 carbon atoms, and an aromatic vinyl compound represented by a general formula (2): wherein R2 represents an aromatic hydrocarbon group having 6 to 10 carbon atoms, and R5 represents a hydrogen atom or the like, and a copolymerization ratio (m) of the aromatic vinyl compound (2) is 45% by mass or more.Type: GrantFiled: September 4, 2013Date of Patent: January 27, 2015Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Kensuke Washizu
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Patent number: 8912284Abstract: The present invention relates to a crosslinkable polymer composition, comprising (i) an unsaturated polyolefin having a total amount of carbon-carbon double bonds/1000 carbon atoms of more than 0.37, and (ii) a polar copolymer.Type: GrantFiled: June 1, 2006Date of Patent: December 16, 2014Assignee: Borealis Technology OyInventors: Jan-Ove Boström, Annika Smedberg
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Patent number: 8912301Abstract: The present invention relates to a branched conjugated diene copolymer which is useful for preparing a rubber composition, having high uniformity of a temperature dependence curve of a viscoelasticity tan ?, for a tire, a rubber composition comprising the copolymer, and a pneumatic tire produced using the rubber composition for a tire. The branched conjugated diene copolymer is composed of monomer components comprising a branched conjugated diene compound represented by a general formula (1): wherein R1 represents an aliphatic hydrocarbon group having 6 to 11 carbon atoms, and an aromatic vinyl compound represented by a general formula (2): wherein R2 represents an aromatic hydrocarbon group having 6 to 10 carbon atoms, and R5 represents a hydrogen atom or the like, and a copolymerization ratio (m) of the aromatic vinyl compound (2) is 45% by mass or more.Type: GrantFiled: March 18, 2014Date of Patent: December 16, 2014Assignee: Sumitomo Rubber Industries, Ltd.Inventor: Kensuke Washizu
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Patent number: 8865829Abstract: There is disclosed a functionalized elastomer comprising the reaction product of a living anionic elastomeric polymer; and a polymerization terminator of formula I where R1, R2 and R3 are independently C1 to C8 alkyl or C1 to C8 alkoxy, with the proviso that at least two of R1, R2 and R3 are C1 to C8 alkoxy; R4 is C1 to C8 alkyl; Si is silicon; S is sulfur; and Z is R5 or of formula II where R5 is alkyl, aryl, alkylaryl or arylalkyl. There is further disclosed a rubber composition comprising the functionalized elastomer, and a pneumatic tire comprising the rubber composition.Type: GrantFiled: November 22, 2011Date of Patent: October 21, 2014Assignee: The Goodyear Tire & Rubber CompanyInventors: Leena Nebhani, Michael Joseph Rachita
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Publication number: 20140221575Abstract: In accordance with one aspect a temperature regulating article comprises a substrate and a polymeric phase change material bound to the substrate, wherein the polymeric phase change material is characterized by including a precisely branched polymer with substantially equally spaced repeating sidechains. In other embodiments the polymeric phase change material includes between 20 and 200 branches per 1000 carbon units, has a latent heat of at least 5 Joules per gram, and a transition temperature between 0° C. and 40° C.Type: ApplicationFiled: February 7, 2014Publication date: August 7, 2014Applicant: Outlast Technologies, LLCInventors: Mark Hartmann, David E. Henton
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Patent number: 8791209Abstract: A modified natural rubber particle having carbon-carbon double bands assigned to multifunctional vinyl monomers graft-copolymerized onto the surface of the modified natural rubber particle, which is prepared by graft-copolymerization of multifunctional vinyl monomers having two or more carbon-carbon double bonds onto natural rubber particles or deproteinized natural rubber particles. One of the methods for producing a modified natural rubber particle includes the steps of: forming inclusion complex of the multifunctional vinyl monomers having two or more carbon-carbon double bonds with a guest-protecting agent to protect at least one of the double bonds of the multifunctional vinyl monomers; graft-copolymerizing the resulting inclusion complex onto natural rubber particles or deproteinized natural rubber particles; and deprotecting the protected double bonds by removing the guest-protecting agent from the obtained graft-copolymer.Type: GrantFiled: November 26, 2012Date of Patent: July 29, 2014Assignees: Tokai Rubber Industries, Ltd., National University Corporation Nagaoka University of TechnologyInventors: Osamu Wakisaka, Akihiro Shibahara, Seiichi Kawahara, Yoshimasa Yamamoto, Nanthaporn Pukkate
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Publication number: 20140163175Abstract: Conventional cross-linked cyclic olefin polymers do not have a sufficiently low linear expansion coefficient. A compound having a structure represented by the following formula (a).Type: ApplicationFiled: July 25, 2012Publication date: June 12, 2014Applicant: CANON KABUSHIKI KAISHAInventors: Seiji Okada, Ryo Ogawa
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Publication number: 20140144573Abstract: An elastomeric composition and method incorporating a hydrocarbon polymer modifier with improved permanence. The composition comprises elastomer, filler and silane-functionalized hydrocarbon polymer modifier (Si-HPM) adapted to couple the Si-HPM to the elastomer, filler or both, wherein the Si-HPM comprises an interpolymer of monomers chosen from piperylenes, cyclic pentadienes, aromatics, limonenes, pinenes, amylenes, and combinations thereof. The method comprises melt processing a mixture to form the elastomeric composition in the shape of an article, wherein the mixture comprises elastomer, Si-HPM, silica, bifunctional organosilane crosslinking agent; and curing the elastomeric composition to form the article. Also disclosed are a silylated hydrocarbon polymer modifier coupled with a bifunctional organosilane crosslinking agent, and a silica-coupled hydrocarbon polymer modifier coupled to the silica via the bifunctional organosilane crosslinking agent.Type: ApplicationFiled: August 25, 2011Publication date: May 29, 2014Applicant: ExxonMobil Chemical Patents Inc.Inventors: Edward J. Blok, Anthony J. Dias, Robert J. Claassen, II, Eugene Ronald Uhl
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Publication number: 20140088260Abstract: The invention discloses an adhesion agent composition comprising at least one C3-C200 olefin compound having at least one metathesis active double bond, wherein the olefin is substituted or unsubstituted; and at least one compatibilizing functionality for interacting with a substrate surface. The substrate surface can be any surface, for example, silicate glasses, silicate minerals, metals, metal alloys, ceramics, natural stones, plastics, carbon, silicon, and semiconductors. The invention also discloses articles of manufacture utilizing these adhesion agents as well as methods for adhering a polyolefin to a substrate surface.Type: ApplicationFiled: March 15, 2013Publication date: March 27, 2014Applicant: MATERIA, INC.Inventor: MATERIA, INC.
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Publication number: 20140080978Abstract: The invention provides dispersing agents for inorganic fillers capable of uniformly dispersing inorganic fillers in a substrate such as made of a rubber or resin material such that molded products with improved mechanical strength and abrasion resistance can be produced from such a substrate material and more specifically that rubber compositions with improved abrasion resistance and workability can be obtained and that automobile tires with improved low fuel consumption and handling stability can be produced from such rubber compositions, as well as a method of producing such dispersing agents characterized as using a modified conjugated diene polymer obtained by introducing specified structural units with improved mutual reaction with inorganic fillers into a conjugated diene polymer having affinity with rubber and resin materials.Type: ApplicationFiled: November 15, 2013Publication date: March 20, 2014Inventors: Yuji Ohi, Makoto Hattori, Ippei Noda, Akira Miyano, Hironari Matsumoto
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Patent number: 8653197Abstract: The disclosure is directed to a thermoplastic vulcanizate composition comprising a dynamically-cured rubber; from about 20 to about 300 parts by weight of a thermoplastic resin per 100 parts by weight rubber and from about 30 to about 250 parts by weight additional oil per 100 parts by weight rubber; wherein the rubber comprises a multimodal polymer composition cured with a curing agent, the multimodal polymer composition comprising 45 to 75 wt % of a first polymer fraction and 25 to 55 wt % of a second polymer fraction, each comprising ethylene, a C3-C10 alpha-olefin, and a non-conjugated diene. A method of producing the thermoplastic vulcanizate is also disclosed.Type: GrantFiled: April 13, 2012Date of Patent: February 18, 2014Assignee: ExxonMobil Chemical Patents Inc.Inventors: Maria D. Ellul, Periagaram S. Ravishankar, Jianya Cheng, Paul E. McDaniel
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Patent number: 8633280Abstract: The present invention provides methods of depolymerizing and hydrogenating polymers using a transition metal catalyst represented by formula Ia or Ib: where the structural variables are defined herein.Type: GrantFiled: March 30, 2011Date of Patent: January 21, 2014Assignee: Zannan Scitech Co., LtdInventor: Zheng-Yun James Zhan
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Publication number: 20140005338Abstract: A polymerizable composition which contains a cycloolefin monomer and a ruthenium carbene complex which is expressed by the following general formula (I): (in which general formula (I), R1 and R2 respectively independently represent a hydrogen atom, halogen atom, or cyclic or chain C1 to C20 hydrocarbon group which may contain a halogen atom, oxygen atom, nitrogen atom, sulfur atom, phosphorus atom, or silicon atom; X1 and X2 respectively independently represent an anionic ligand; L1 and L2 respectively independently represent a neutral electron donor ligand; L2 is a group with a higher three-dimensionally bulk than L1, where L1 and L2 are at cis positions with each other; R1 and R2 may bond with each other to form an aliphatic ring or aromatic ring which may contain a hetero atom; and R1, R2, X1, X2, L1, and L2 may bond with each other in any combination to form a multidentate chelating ligand).Type: ApplicationFiled: March 8, 2012Publication date: January 2, 2014Applicant: ZEON CORPORATIONInventors: Akihiko Yoshiwara, Yasuo Tsunogae
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Publication number: 20130310523Abstract: Disclosed is the preparation of compositions which are blends of certain types of hydrogenated ethylene-dicyclopentadiene (E/DCPD) copolymers in combination with elastomeric polymers. An E/DCPD copolymer and an elastomeric polymer are co-dissolved in a common liquid reaction medium which is then subjected to hydrogenation conditions. These hydrogenation conditions serve to hydrogenate in-situ at least a portion of the residual double bonds of the E/DCPD copolymer component and possibly also eliminate any residual unsaturation which might be present in the elastomeric polymers. This combination of materials which has been hydrogenated in-situ can then be co-precipitated to form a polymer composition which can be molded into polyolefin materials of improved structural, thermal and mechanical properties with desirable impact resistance.Type: ApplicationFiled: July 19, 2013Publication date: November 21, 2013Inventors: Lisa S. Baugh, Enock Berluchie
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Patent number: 8541527Abstract: Elastomeric interpolymers comprising at least two, or more, cyclic olefin monomers that are prepared by ring opening metathesis polymerization, and that are characterized by having no crystallinity, a glass transition temperature (Tg) of less than ?80° C., and a number average molecular weight (Mn) of at least 40 kg/mole, and functionalized products thereof. A ring opening metathesis polymerization process for producing the elastomeric interpolymers having no crystallinity. Uses of the elastomeric interpolymers in applications such as rubber compounds, tires, and the like. Cores of golf balls that are prepared by using metathesis polymerization produced elastomeric interpolymers having 0 to about 30% crystallinity.Type: GrantFiled: June 6, 2012Date of Patent: September 24, 2013Assignee: Firestone Polymers, LLCInventors: James Pawlow, Christopher Robertson, Daniel Graves, Mitch Barry
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Publication number: 20130172493Abstract: A process for making dendritic hydrocarbon polymers by reacting an amount of one or more telechelic hydrocarbon polymers with an amount of one or more multifunctional coupling agents under conditions sufficient to produce the dendritic hydrocarbon polymer. The telechelic hydrocarbon polymer is made by ring opening metathesis polymerization (ROMP) in the presence of bi-functional alkene chain terminating agents (CTAs). The dendritic hydrocarbon polymer can be hydrogenated to produce a substantially saturated dendritic hydrocarbon polymer. The dendritic polyethylenes (dPE) can be used as processability additives to provide extensional hardening in low concentrations in various conventional polyethylenes (PEs) such as HDPE, LLDPE and mLLDPE.Type: ApplicationFiled: December 30, 2011Publication date: July 4, 2013Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Shuji Luo, Andy Haishung Tsou
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Patent number: 8470946Abstract: Carbon nanotube (CNT) yarns and sheets having enhanced mechanical strength using infused and bonded nano-resins. A CNT yarn or sheet is surface-activated to produce open bonds in the CNT walls prior to resin infusion. The CNT yarn or sheet is infused with a low viscosity nano-resin that penetrates spaces between individual CNTs and is cured to cross-link and chemically bond to the CNT walls, either directly or through a functional molecule, to bond the individual CNTs or ropes to each other. The nano-resin can comprise dicyclopentadiene having an uncured viscosity near that of water. The cross-linking process involves ring-opening metathesis polymerization and catalysis of the nano-resin in combination with a functionalizing material such as norbornene, to enhance bonding between the carbon and nano-resin. The process increases load capability, tensile strength, and elastic modulus of the yarns and sheets, for use as a structural component in composite materials.Type: GrantFiled: August 20, 2012Date of Patent: June 25, 2013Assignee: The Regents of the University of CaliforniaInventor: Lawrence E. Carlson
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Publication number: 20130123379Abstract: Provided herein are graft copolymers of polyfarnesenes with condensation polymers; and methods of making and using the graft copolymers disclosed herein. The graft copolymers are obtained from the reaction of a polycondensation polymer with a modified polyfarnesene obtained from reaction of a polyfarnesene with a modifier in the presence of a grafting initiator. In certain embodiments, the condensation polymers include polyesters, polycarbonates, polyamides, polyethers, phenol-formaldehyde resins, urea-formaldehyde resins, melamine-formaldehyde resins and combinations thereof. In some embodiments, the polyfarnesenes include farnesene homopolymers derived from a farnesene, and farnesene interpolymers derived from a farnesene and at least a vinyl monomer. In certain embodiments, the farnesene is prepared from a sugar by using a microorganism.Type: ApplicationFiled: July 29, 2011Publication date: May 16, 2013Applicant: AMYRIS, INC.Inventor: Derek James Mcphee
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Patent number: 8426529Abstract: Disclosed is a selected type of copolymer composition comprising copolymers having units derived from ethylene and dicyclopentadiene (DCPD) co-monomers. Such copolymer compositions: a) have a DCPD-derived comonomer unit content of from about 25 mole % to about 45 mole %; b) have a Weight Average Molecular Weight, Mw, of greater than about 170,000; c) comprise amorphous material and have glass transition temperatures, Tg, of from about 8° C. to about 129° C., which also fit the equation Tg (in ° C.)?[(mole % DCPD×3.142)?4.67]; and d) comprise no significant amount of crystalline polyethylene homopolymer or crystallizable polyethylene segments within the ethylene-dicyclopentadiene copolymers. Such copolymers can be readily derivatized by hydrogenation and/or epoxidation to provide polymeric materials suitable for use as engineering thermoplastics.Type: GrantFiled: May 10, 2007Date of Patent: April 23, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Lisa Saunders Baugh, Abhimanyu Onkar Patil, Christian Peter Mehnert, Kevin R. Squire, Kenneth A. Cook, Caiguo Gong, Enock Berluche, Karla Schall Colle, Alan J. Oshinski, Stephen Zushma, Beverly J. Poole
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Patent number: 8420738Abstract: A thermoplastic elastomer composition which has excellent cleanability and is suitable for use as a medical rubber supply. It is characterized by comprising a rubber ingredient dynamically crosslinked with a crosslinking agent and a matrix which comprises a thermoplastic resin and in which the crosslinked rubber ingredient has been dispersed, the crosslinking agent comprising a triazine derivative.Type: GrantFiled: October 2, 2008Date of Patent: April 16, 2013Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Hiroaki Nakano, Hideyuki Okuyama
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Patent number: 8389639Abstract: A proton exchange membrane comprising modified hyper-branched polymer is disclosed. The proton exchange membrane includes 85-90 wt % of sulfonated tetrafluorethylene copolymer and 15-10 wt % of modified hyper-branched polymer. The modified hyper-branched polymer comprises the bismaleimide (BMI)-based hyper-branched polymer, and parts of the chain ends of the hyper-branched polymer are sulfonated by the sulfonic compound. Also, the modified hyper-branched polymer and sulfonated tetrafluorethylene copolymer are interpenetrated to form an interpenetrating polymer. Furthermore, the modification step could be performed before or after forming the interpenetrating polymer. For example, the sulfonation is proceeded after forming the interpenetrating polymer. Alternatively, the sulfonation of the hyper-branched polymer could be proceeded before the formation of the interpenetrating polymer.Type: GrantFiled: November 23, 2009Date of Patent: March 5, 2013Assignee: Industrial Technology Research InstituteInventors: Chung-Liang Chang, Ya-Ting Hsu, Jing-Pin Pan
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Patent number: 8334353Abstract: Provided herein are polyfarnesenes such as farnesene homopolymers derived from a farnesene and farnesene interpolymers derived from a farnesene and at least a vinyl monomer; and the processes of making and using the polyfarnesenes. The farnesene homopolymer can be prepared by polymerizing the farnesene in the presence of a catalyst such as a Ziegler-Natta catalyst, a Kaminsky catalyst, a metallocene catalyst, an organolithium reagent or a combination thereof. In some embodiments, the farnesene is prepared from a sugar by using a microorganism.Type: GrantFiled: February 2, 2012Date of Patent: December 18, 2012Assignee: Amyris, Inc.Inventor: Derek James McPhee
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Patent number: 8314196Abstract: Provided herein are polyfarnesenes such as farnesene homopolymers derived from a farnesene and farnesene interpolymers derived from a farnesene and at least a vinyl monomer; and the processes of making and using the polyfarnesenes. The farnesene homopolymer can be prepared by polymerizing the farnesene in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism.Type: GrantFiled: September 19, 2011Date of Patent: November 20, 2012Assignee: Amyris, Inc.Inventor: Derek James McPhee
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Publication number: 20120225290Abstract: In accordance with one aspect a temperature regulating article comprises a substrate and a polymeric phase change material bound to the substrate, wherein the polymeric phase change material is characterized by including a precisely branched polymer with substantially equally spaced repeating sidechains. In other embodiments the polymeric phase change material includes between 20 and 200 branches per 1000 carbon units, has a latent heat of at least 5 Joules per gram, and a transition temperature between 0° C. and 40° C.Type: ApplicationFiled: March 4, 2011Publication date: September 6, 2012Applicant: Outlast Technologies, Inc.Inventors: Mark Hartmann, David E. Henton
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Patent number: 8217128Abstract: Farnesene interpolymer comprises units derived from a farnesene (e.g., ?-farnesene or ?-farnesene) and units derived from at least one vinyl monomer. The farnesene interpolymer can be prepared by copolymerizing the farnesene and at least one vinyl monomer in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism. In other embodiments, the at least one vinyl monomer is ethylene, an ?-olefin, or a substituted or unsubstituted vinyl halide, vinyl ether, acrylonitrile, acrylic ester, methacrylic ester, acrylamide or methacrylamide, or a combination thereof.Type: GrantFiled: September 1, 2009Date of Patent: July 10, 2012Assignee: Amyris, Inc.Inventor: Derek James McPhee
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Patent number: 8210967Abstract: Elastomeric interpolymers comprising at least two, or more, cyclic olefin monomers that are prepared by ring opening metathesis polymerization, and that are characterized by having no crystallinity, a glass transition temperature (Tg) of less than ?80° C., and a number average molecular weight (Mn) of at least 40 kg/mole, and functionalized products thereof. A ring opening metathesis polymerization process for producing the elastomeric interpolymers having no crystallinity. Uses of the elastomeric interpolymers in applications such as rubber compounds, tires, and the like. Cores of golf balls that are prepared by using metathesis polymerization produced elastomeric interpolymers having 0 to about 30% crystallinity.Type: GrantFiled: October 15, 2007Date of Patent: July 3, 2012Assignee: Firestone Polymers, LLCInventors: James Pawlow, Christopher Robertson, Daniel Graves, Mitch Barry
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Patent number: 8202945Abstract: Butadiene copolymers are brominated using certain quaternary ammonium tribromides as the brominating agent. The bromination process proceeds easily under mild conditions, and produces a brominated product that has excellent thermal stability.Type: GrantFiled: August 14, 2007Date of Patent: June 19, 2012Assignee: Dow Global Technologies LLCInventors: Bruce A. King, David B. Gorman, John W. Hull, Jr., Daniel J. Murray, Terry L. Gehrman
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Patent number: 8178625Abstract: The instant disclosure is directed to a thermoplastic vulcanizate composition comprising a dynamically-cured rubber; from about 20 to about 300 parts by weight of a thermoplastic resin per 100 parts by weight rubber and from about 30 to about 250 parts by weight additional oil per 100 parts by weight rubber; wherein the rubber comprises a multimodal polymer composition cured with a curing agent, the multimodal polymer composition comprising 45 to 75 wt % of a first polymer fraction and 25 to 55 wt % of a second polymer fraction, each comprising ethylene, a C3-C10 alpha-olefin, and a non-conjugated diene, wherein the polymer fractions have been polymerized using a Ziegler-Natta catalyst system, wherein the first polymer fraction has a Mooney viscosity of greater than or equal to about 150 ML(1+4@125° C.), and the second polymer fraction has a Mooney viscosity of about 20 ML to about 120 ML; and about 10 phr to about 50 phr of an extender oil.Type: GrantFiled: August 1, 2006Date of Patent: May 15, 2012Assignee: ExxonMobil Chemical Patents Inc.Inventors: Maria D. Ellul, Periagaram S. Ravishankar, Jianya Cheng, Paul E. McDaniel
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Publication number: 20120010370Abstract: Provided herein are polyfarnesenes such as farnesene homopolymers derived from a farnesene and farnesene interpolymers derived from a farnesene and at least a vinyl monomer; and the processes of making and using the polyfarnesenes. The farnesene homopolymer can be prepared by polymerizing the farnesene in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism.Type: ApplicationFiled: September 19, 2011Publication date: January 12, 2012Applicant: Amyris, Inc.Inventor: Derek James MCPHEE
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Patent number: 8053531Abstract: A hydrogenated crystalline norbornene ring-opening polymer is obtained by hydrogenating 80% or more of carbon-carbon double bonds of a ring-opening polymer that is obtained by ring-opening polymerization of norbornene monomers including 90 to 100 wt % of 2-norbornene and 0 to 10 wt % of a 2-norbornene derivative having a substituent which does not include an aliphatic carbon-carbon double bond in the presence of a branching agent, the hydrogenated crystalline norbornene ring-opening polymer having a melting point of 110 to 145° C. and a branching index of 0.3 to 0.98, and a molded article is obtained by molding the hydrogenated crystalline norbornene ring-opening polymer. The hydrogenated crystalline norbornene ring-opening polymer has excellent industrial productivity, and the molded article has excellent productivity and moisture resistance.Type: GrantFiled: February 27, 2009Date of Patent: November 8, 2011Assignee: Zeon CorporationInventors: Takeshi Hirata, Takashi Houkawa, Hiroaki Matsuda, Yosuke Naka
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Patent number: 8044149Abstract: Provision of, in a process of producing a hydrogenated polymer, which comprises steps of sequentially performing, in the presence of a ruthenium carbene complex, a ring-opening metathesis polymerization reaction of a cyclic olefin and a hydrogenation reaction of a ring-opening metathesis polymer produced by the polymerization reaction to give a hydrogenated polymer, a simple and economic process of obtaining a hydrogenated polymer having an extremely small content of residual ruthenium derived from the ruthenium carbene complex. A process of producing a hydrogenated polymer, which comprises, in the presence of a ruthenium carbene complex, subjecting a cyclic monoolefin and/or a cyclic diolefin to a ring-opening metathesis polymerization, hydrogenating the resulting ring-opening metathesis polymer to give a hydrogenated polymer, and bringing the hydrogenated polymer in contact with a poor solvent of the hydrogenated polymer in the presence of dissolved hydrogen to allow precipitation.Type: GrantFiled: September 20, 2007Date of Patent: October 25, 2011Assignee: Kuraray Co., Ltd.Inventors: Hideharu Iwasaki, Yasutaka Inubushi
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Patent number: 8030411Abstract: Embodiments of the disclosed polymer composition comprise a first unsaturated polymer or polymer precursor, and an effective amount of a peptizer. The peptizer typically comprises a heteroaryl or a heterocyclic compound, other than morpholine as disclosed in assignee's prior applications. Disclosed polymer compositions are useful for making sports equipment, such as at least one layer of a golf ball, often a core. Because the compositions are useful for making golf balls, materials commonly known for making such golf balls can be used in combination with the polymer composition. A method for forming a golf ball also is disclosed. The method comprises providing disclosed compositions and then forming at least one component of a golf using the composition.Type: GrantFiled: December 15, 2006Date of Patent: October 4, 2011Assignee: Taylor Made Golf Company, Inc.Inventors: Hyun J. Kim, Hong G. Jeon
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Patent number: 7932316Abstract: A composition that includes functionalized polymers and one or more types of particulate filler exhibits both an increased gum Mooney viscosity and a decreased compound Mooney viscosity relative to a comparable composition that includes only one such functionalized polymer. The functionalized polymers include first and second types of functionalities which exhibit a non-covalent interaction that has a bond energy of from about 0.1 to about 20 kJ/mol.Type: GrantFiled: December 17, 2007Date of Patent: April 26, 2011Assignee: Bridgestone CorporationInventors: Yuan-Yong Yan, Steven Luo
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Patent number: 7868115Abstract: Provided herein are farnesene interpolymers derived from a farnesene and at least one vinyl monomer. In certain embodiments, the farnesene is ?-farnesene, ?-farnesene or a combination thereof. In some embodiments, the at least one vinyl monomer is ethylene, an ?-olefin such as styrene, or a substituted or unsubstituted vinyl halide, vinyl ether, acrylonitrile, acrylic ester, methacrylic ester, acrylamide or methacrylamide, or a combination thereof.Type: GrantFiled: June 29, 2010Date of Patent: January 11, 2011Assignee: Amyris Biotechnologies, Inc.Inventor: Derek James McPhee