Sulfur Compound Contains Sulfur Atom Bonded To At Least Two Oxygen Atoms, E.g., Sulfonate, Etc. Patents (Class 525/353)
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Patent number: 11925918Abstract: A silica aggregate includes primary silica particles aggregated, the primary silica particles having an average particle size of 1 nm or more and less than 10 nm, the primary silica particles being crosslinked to each other by a bond containing a siloxane bond.Type: GrantFiled: March 26, 2020Date of Patent: March 12, 2024Assignee: CANON KABUSHIKI KAISHAInventors: Kengo Kanazaki, Fumio Yamauchi, Teigo Sakakibara, Yoshinori Kotani, Ryoko Ueyama
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Patent number: 11912069Abstract: Provided is a 5-rib tire that can have improved steering stability and noise performance A tread portion 2 includes four circumferential grooves 3 and five land portions 4. Two tread ends are ends of a 50%-load ground-contact surface. Each of the five land portions 4 is provided with no groove having a groove width greater than 2.0 mm, and is provided with only sipes 9. The five land portions 4 include a shoulder land portion 11. The shoulder land portion 11 is provided with a plurality of shoulder sipes 20. At least one of the shoulder sipes 20 includes an inclined portion 21 and an axial portion 22. The axial portion 22 cross the tread end.Type: GrantFiled: September 1, 2022Date of Patent: February 27, 2024Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Kohei Miyoshi, Ryota Ikeda, Yuto Ohte
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Patent number: 11891463Abstract: An ethylene-based polymer formed from reacting at least the following: ethylene and at least one asymmetrical polyene, of Structure 1, as described herein.Type: GrantFiled: June 26, 2019Date of Patent: February 6, 2024Assignee: Dow Global Technologies LLCInventors: John O. Osby, Hayley A. Brown, Mehmet Demirors, Carmelo Declet Perez
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Patent number: 11682793Abstract: A single-ion polymer electrolyte has formula (I): R—[SO2N(M)SO2—X—]m—SO3Li (I). In formula (I), X may be an electron withdrawing group such as an aromatic group, substituted aromatic group, —(CF2)n—, —(CCl2)n—, —C6H4—, or —C6H3(NO2)—. R may be a fluorinated alkyl, LiSO3(CF2)3—, or an aromatic group, and M may be a metal cation. For the single-ion polymer electrolyte with formula (I), m may be an integer from 2 to 2000, and n may be an integer from 1 to 4.Type: GrantFiled: October 27, 2020Date of Patent: June 20, 2023Assignee: FORD GLOBAL TECHNOLOGIES. LLCInventors: Zijie Lu, Andrew Robert Drews, Xiaojiang Wang
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Patent number: 10323107Abstract: Unsaturated compounds of formula (I): wherein: R1, R2, and R3 are each independently H or CH3; R4 is a linear or branched C1-C30-alkylene; R5 and R6 are each independently H, C1-C20-alkyl, C3-C15-cycloalkyl, aryl, —CH2—O—C1-C20-alkyl, or —CH2—O—C2-C20-alkenyl, where R5 and R6 may together form a C3-C6-alkylene; R7 is independently H,C1-C4-alkyl, or where R8 is C1-C22-alkyl or C2-C22-alkenyl; and n is an integer from 2 to 200. Mixtures and polymers including the unsaturated compounds of formula (I). A method for preparing polymers by free-radical polymerization of monomers including the unsaturated compounds of formula (I). A process for preparing polymers including polymer-analogous reactions. And polymers including compounds (I) as cement additives, grinding aids, hydraulic binder additives, concrete plasticizers, reactive plasticizers for preparing plastics, rubber, or latex, associative thickeners and antioxidants, or for preparing polyether siloxanes.Type: GrantFiled: October 30, 2014Date of Patent: June 18, 2019Assignee: BASF SEInventors: Sophie Maitro-Vogel, Martin Ernst, Christian Schade, Pavel Tuzina, Hoang Trang Tran-Thien, Eva-Maria Reis-Walther, Natalia Shabelina, Nina Susanne Hillesheim, Christian Scholz
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Patent number: 8993682Abstract: The present invention provides an electrolyte having high conductivity even under high-temperature low-humidification conditions (e.g. at a temperature of 100 to 120° C. and a humidity of 20 to 50% RH) and thereby makes it possible to realize a higher performance fuel cell. The present invention is a fluoropolymer electrolyte having an equivalent weight (EW) of not less than 250 but not more than 700 and a proton conductivity of not lower than 0.10 S/cm as measured at a temperature of 110° C. and a relative humidity of 50% RH and comprising a COOZ group- or SO3Z group-containing monomer unit, wherein Z represents an alkali metal, an alkaline earth metal, hydrogen atom or NR1R2R3R4 in which R1, R2, R3 and R4 each independently represents an alkyl group containing 1 to 3 carbon atoms or hydrogen atom.Type: GrantFiled: March 12, 2009Date of Patent: March 31, 2015Assignees: Asahi Kasei E-Materials Corporation, Daikin Industries, Ltd.Inventors: Kohei Kita, Takahiko Murai, Naoki Sakamoto, Naoto Miyake, Tadashi Ino, Noriyuki Shinoki, Masaharu Nakazawa, Masahiro Kondo, Takashi Yoshimura
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Patent number: 8936659Abstract: A substance includes diamond particles having a maximum linear dimension of less than about 1 ?m and an organic compound attached to surfaces of the diamond particles. The organic compound may include a surfactant or a polymer. A method of forming a substance includes exposing diamond particles to an organic compound, and exposing the diamond particles in the presence of the organic compound to ultrasonic energy. The diamond particles may have a maximum linear dimension of less than about 1 ?m. A composition includes a liquid, a plurality of diamond nanoparticles dispersed within the liquid, and an organic compound attached to surfaces of the diamond nanoparticles. A method includes mixing a plurality of diamond particles with a solution comprising a liquid solvent and an organic compound, and exposing the mixture including the plurality of diamond nanoparticles and the solution to ultrasonic energy.Type: GrantFiled: October 18, 2011Date of Patent: January 20, 2015Assignee: Baker Hughes IncorporatedInventors: Soma Chakraborty, Gaurav Agrawal, Anthony A. DiGiovanni
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Patent number: 8835562Abstract: Improved methods for preparing sulfonated block polymers with acyl sulfates in non-halogenated aliphatic solvents are provided. The methods include the sulfonation of a precursor block polymer with an acyl sulfate in a reaction mixture further comprising at least one non-halogenated aliphatic solvent to form a sulfonated block polymer, wherein the initial concentration of the precursor block polymer is in the range of from about 0.1 wt % to a concentration that is below the limiting concentration of the precursor block polymer based on the total weight of the reaction mixture. A sulfonation degree of greater than about 1.0 milliequivalent sulfonic acid per gram sulfonated block polymer can be achieved substantially free of polymer precipitation and free of disabling gelation.Type: GrantFiled: July 7, 2009Date of Patent: September 16, 2014Assignee: Stepan CompanyInventors: Gregory Paul Dado, Dale Lee Handlin, Jr., Carl Lesley Willis
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Patent number: 8835352Abstract: There is disclosed an indicator composition, the application thereof to substrates, and related products. The indicator composition comprises an organic solvent soluble polymer and a redox sensitive material which displays different visible properties in the oxidized and reduced forms. The organic solvent soluble polymer can be at least partially sulfonated polystyrene. The indicator composition can be dissolved in organic solvents such as acetone, ethanol and ethyl acetate to form inks which can be used in a variety of printing processes. The indicator composition can be used to detect oxidizing agents, oxygen, water, reducing agents, UV light, temperature and the passage of time.Type: GrantFiled: June 17, 2010Date of Patent: September 16, 2014Assignee: Insignia Technologies LimitedInventors: Erik Smyth, Andrew Mills, David Hazafy
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Patent number: 8802893Abstract: According to a method for producing acetic acid by carbonylation of methanol characterized in that an acid having an acid dissociation constant (pKa) smaller than the constant of acetic acid is allowed to be present in the reaction system, acetic acid can be produced by the reaction of methanol and carbon monoxide in a reaction liquid in the presence of a solid catalyst containing rhodium and alkyl iodide, to achieve an enhanced reaction rate of carbonylation of methanol in producing acetic acid in the region at a high carbonylation degree (Ca>0.8 mol/mol) for more efficient production of acetic acid.Type: GrantFiled: February 8, 2011Date of Patent: August 12, 2014Assignee: Chiyoda CorporationInventors: Zhixiong You, Takeshi Minami, Chunji Yin, Yoichi Umehara, Tetsuro Matsumura, Chikako Hashimoto, Yasuo Hosono
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Patent number: 8722811Abstract: The invention comprises an adhesion promoter for a printing ink and a printing ink comprising the adhesion promoter. The adhesion promoter comprises the product of reacting together (a) a solution of a polymer or synthetic resin (b) a sulphonic acid or a derivative of a sulphonic acid, and (c) a metal compound selected from one or more of the group consisting of a metal halide, metal alkoxide, metal halo-alkoxide or a condensed metal alkoxide, wherein the metal is selected from titanium or zirconium.Type: GrantFiled: April 4, 2007Date of Patent: May 13, 2014Assignee: Dorf Ketal Chemicals (India) Pvt. LtdInventors: Robert Hume Duncan, Arran Alexander Dickon Tulloch
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Patent number: 8722809Abstract: The present invention provides a preparation process for converting to a vinylidene fluoride elastomer having a group having sulfinic acid, sulfinic acid derivative, sulfonic acid or sulfonic acid derivative at one end or both ends of its trunk chain, and the preparation process provides a vinylidene fluoride elastomer having, at one end or both ends of its trunk chain, end groups represented by the formula: —CR1R2—CR3R4—SO2H, wherein R1 to R4 may be the same or different and each is hydrogen atom or fluorine atom, by allowing a vinylidene fluoride elastomer having, at one end or both ends of its trunk chain, end groups represented by the formula: —CR1R2—CR3R4—X1, wherein R1 to R4 are as defined above, X1 is bromine atom or iodine atom, to react with a sulfur compound represented by the formula: (M1)nH2-nS2O4, wherein M1 is a monovalent or divalent metal ion or ammonium ion, n is an integer of 0 to 2.Type: GrantFiled: January 20, 2009Date of Patent: May 13, 2014Assignees: The University of Tokyo, Daikin Industries, Ltd.Inventors: Yuzo Komatsu, Haruhiko Mohri, Hirokazu Aoyama, Takanori Fukushima, Takuzo Aida
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Patent number: 8642705Abstract: A process for producing a conjugated diene-based polymer which comprises, in the first modification, modifying a conjugated diene-based polymer having active chain ends, which is obtained by polymerizing a diene-based monomer singly or with other monomers and has a content of a cis-1,4 unit of 75% by mole or greater in the conjugated diene portion of the main chain, by reacting the active chain ends with a hydrocarbyloxysilane compound and reacting the modified polymer with a specific compound such as a hydrocarbyloxysilane compound, and a rubber composition containing the polymer modified in accordance with the above process and, preferably, 10 to 100 parts by weight of silica and/or carbon black per 100 parts by weight of the rubber component containing the modified polymer, are provided. The rubber composition containing silica and/or carbon black exhibits improved fracture properties, abrasion resistance, low heat buildup property and excellent workability.Type: GrantFiled: July 2, 2010Date of Patent: February 4, 2014Assignee: Bridgestone CorporationInventors: Youichi Ozawa, Hajime Kondou, Noriko Endou
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Patent number: 8623965Abstract: The present disclosure relates to a sulfurized polyacrylonitrile and a lithium-ion battery cathode active material. The sulfurized polyacrylonitrile includes a structural unit. A general molecular formula of the structural unit is C3HNSn, in which n is a positive integer. The lithium-ion battery cathode active material includes sulfurized polyacrylonitrile and a sulfurized polyacrylonitrile with inserted ions.Type: GrantFiled: March 18, 2011Date of Patent: January 7, 2014Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Xiang-Ming He, Li Wang, Wei-Hua Pu, Wen-Ting Sun, Jian-Jun Li
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Patent number: 8575278Abstract: Certain disclosed embodiments of the present invention concern a golf ball including a core having a center, an outer cover layer, and optionally one or more intermediate layers. At least one or more of the core, outer cover layer or one or more intermediate layers includes a sulfonated polyisoprene ionomer having the general formula: where A is an isoprene repeating unit having the formula —(CH2—C(CH3)?CH—CH2)—, B is an isoprene repeating unit or other monomer repeating unit, m is greater than 10, and n is greater than 2, and X is selected from one or both of the following groups; i) Li+, Na+, K+, Zn2+, Ca2+, Co2+, Ni2+, Cu2+, Pb2+, and Mg2+ or ii) an ammonium cation having the general formula [NR1R2R3R4]+. R1, R2, R3 and R4 are selected from one or both of the following hydrogen, a C1-C20 aliphatic, cycloaliphatic or aromatic moiety.Type: GrantFiled: December 21, 2010Date of Patent: November 5, 2013Assignee: Taylor Made Golf Company, Inc.Inventors: Hyun J. Kim, Hong G. Jeon
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Patent number: 8524853Abstract: The present invention relates to polyarylene ether block copolymers according to the general formula A-K—X—K-A, where —X— is a polyarylene ether segment with number-average molar mass of at least 5000 g/mol, and A- is a segment of the general structure R2NH—(R1—NH—CO—Ar—CO—NH)n—R1—NH—, in which R1 is a linear or branched alkylene group having from 2 to 12 carbon atoms and Ar is an arylene group having from 6 to 18 carbon atoms, and R2 is selected from aryloyl, alkyloyl, and H, and in which the number average of n is from 1 to 3, and there is a coupling group K of the structure —CO—Ar3—CO— linking each A to X, in which Ar13 is an aromatic group having from 6 to 18 carbon atoms. The present invention also relates to a process for the production of the polyarylene ether block copolymers of the invention, to polymer compositions comprising the polyarylene ether block copolymers of the invention, and also to the use thereof for the production of moldings, of films, of fibers, or of foams.Type: GrantFiled: May 31, 2010Date of Patent: September 3, 2013Assignee: BASF SEInventors: Cecile Gibon, Martin Weber, Reinoud J. Gaymans, Ranimol Stephen
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Patent number: 8470955Abstract: The present invention relates to a poly(arylene ether) copolymer having a cation exchange group, a method for manufacturing the same, and use thereof. The poly(arylene ether) copolymer having the cation exchange group according to the present invention has excellent physical characteristics, ion exchanging capacity, metal ion adsorption capacity and a processability, and thus can be molded in various shapes and can be extensively applied to various fields such as recovering of organic metal, air purification, catalysts, water treatment, medical fields and separating of proteins.Type: GrantFiled: November 30, 2011Date of Patent: June 25, 2013Assignee: Hyundai Motor CompanyInventors: Inchul Hwang, Nak Hyun Kwon, Young Taek Kim, Dong Il Kim, Ju Ho Lee
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Patent number: 8431730Abstract: The present invention is directed towards novel sulfonic acid esters as catalysts for crosslinking of polymers having hydroxyl, carboxyl, and amide functional groups with a crosslinking agent and resin compositions containing the same. The present invention provides polymeric film coatings which have superior hardness, impact resistance, adhesion, improved blister resistance, salt spray characteristics and flexibility. These catalysts are especially effective in coil primer formulations containing calcium ion exchange anticorrosive pigments, where traditional blocked acid catalysts are ineffective.Type: GrantFiled: October 2, 2008Date of Patent: April 30, 2013Assignee: King IndustriesInventors: Farouk Abi-Karam, Ramanathan Ravichandran, Raman Subrayan, Richard A. Abramshe
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Patent number: 8378054Abstract: A process for preparing polyaryl ethers in which a polycondensation of the monomer building blocks is carried out using microwave irradiation leads to thermoplastic molding compositions having improved color properties.Type: GrantFiled: November 11, 2008Date of Patent: February 19, 2013Assignee: BASF SEInventors: Martin Weber, Volker Warzelhan, Faissal-Ali El-Toufaili, Andreas Greiner, Heiner Stange, Seema Agrarwal
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Patent number: 8372919Abstract: In a method for making sulfurized polyacrylonitrile, polyacrylonitrile, a first solvent, a catalyst, and sulfur or sodium thiosulfate are provided. The polyacrylonitrile is dissolved in the first solvent to form a polyacrylonitrile solution. The catalyst is uniformly dispersed in the polyacrylonitrile solution. The polyacrylonitrile solution with the catalyst is heated to induce a cyclizing reaction of the polyacrylonitrile, thereby forming a first conjugated polymer solution with a conjugated polymer. The sulfur or sodium thiosulfate is uniformly mixed with the conjugated polymer to form a mixture. The mixture is heated to form sulfurized polyacrylonitrile.Type: GrantFiled: March 18, 2011Date of Patent: February 12, 2013Assignees: Tsinghua University, Hon Hai Precision Industry Co., Ltd.Inventors: Xiang-Ming He, Li Wang, Wei-Hua Pu, Wen-Ting Sun, Jian-Jun Li
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Patent number: 8372558Abstract: A vinyl monomer is graft polymerized on an aromatic hydrocarbon-based polymer film substrate to introduce graft chains into the substrate and thereafter a functional monomer represented by the following formula and having sulfonic acid groups or functional groups capable of conversion to sulfonic acid groups is graft polymerized to introduce the sulfonic acid groups or the functional groups capable of conversion to sulfonic acid groups: where R is an aromatic ring or an aliphatic chain; X is (1) —OH, (2) —OLi, —ONa or —OK, (3) —F or —Cl, or (4) —OCnH2n+1 where n is an integer of 1 to 7. Since the graft chains obtained by graft polymerization of the vinyl monomer can also be utilized as scaffold polymers, the graft polymerizability of the functional monomer to the aromatic hydrocarbon-based polymer film substrate is sufficiently improved to enable the preparation of a polymer electrolyte membrane that excels not only in proton conductivity and mechanical strength but also in dimensional stability.Type: GrantFiled: August 22, 2008Date of Patent: February 12, 2013Assignee: Japan Atomic Energy AgencyInventors: Jinhua Chen, Yasunari Maekawa, Masaharu Asano, Masaru Yoshida
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Patent number: 8362153Abstract: The present invention provides for polyisobutenyl sulfonates, methods for preparing them, and composition employing them; wherein said polyisobutenyl sulfonates have improved low temperature and high temperature viscometric properties. The polyisobutenyl sulfonates are prepared by sulfonating polyisobutene and reacting the polyisobutenyl sulfonate with an alkali metal or alkaline earth metal, wherein the polyisobutene is characterized by having at least 90 mole percent methyl-vinylidene, a number average molecular weight of about 350 to 5,000, and a ratio of weight average molecular weight to number average molecular weight Mw/Mn of from about 1.01 to about 1.4.Type: GrantFiled: December 15, 2006Date of Patent: January 29, 2013Assignee: Chevron Oronite Company LLCInventor: James J. Harrison
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Patent number: 8362155Abstract: [Problem] To provide a conjugated diene polymer cyclized product free from coloring, a conjugated diene polymer cyclized product that has a narrow molecular weight distribution and is free from coloring, and a method for producing these conjugated diene polymer cyclized products. [Means for Resolution] A conjugated diene polymer cyclized product having a Gardner color scale of not more than 3.0. A conjugated diene polymer cyclized product having a Gardner color scale of not more than 3.0 and a ratio of weight average molecular weight/number average molecular weight of not more than 1.5. A method for producing a conjugated diene polymer cyclized product includes adding water to a conjugated diene polymer solution obtained by polymerizing a conjugated diene in a solvent by using an organoalkali metal compound as an initiator, thereby terminating the polymerization and then subjecting the subject conjugated diene polymer to a cyclization reaction.Type: GrantFiled: June 13, 2005Date of Patent: January 29, 2013Assignee: Zeon CorporationInventor: Toshio Kase
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Patent number: 8334340Abstract: A sulfur-containing cycloaliphatic compound, useful as a crosslinker for filled sulfur-vulcanizable elastomer compositions, is represented by the general formula: G[—CaH2a—S—S(?O)b—R]n wherein G is a saturated, monocyclic aliphatic group of valence n containing from 5 to 12 carbon atoms and optionally containing at least one halogen or a saturated monocyclic silicone [RSiO—]n[R2SiO—]p group of valence n; each R independently is a monovalent hydrocarbon of up to 20 carbon atoms; each occurrence of subscripts a and b independently is an integer wherein a is 2 to 6 and b is 1 or 2; n is an integer of from 3 to 6; and p is an integer of from 0 to 3.Type: GrantFiled: October 30, 2008Date of Patent: December 18, 2012Assignee: Momentive Performance Materials, Inc.Inventors: Michael Joseph O'Brien, Robert James Perry, Richard W. Cruse, William Michael York, Carla Recker, Thomas Kramer, Katharina Herzog
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Patent number: 8299166Abstract: The present invention relates to a composition comprising (i) a crosslinkable polyolefin with hydrolysable silane groups (A), and (ii) a silanol condensation catalyst comprising an organic sulphonic acid (B) which comprises the structural element Ar—R1 (I) wherein Ar is an aromatic group, which may e.g. be a benzene, naphthalene, phenantrene or anthracene group, and R1 is an organic residue comprising at least 21 C-atoms, the organic sulphonic acid (B) further comprising one, two or more sulphonic acid groups, to an article, in particular a wire or cable, comprising such a composition, and to the use of such a composition for the production of an article.Type: GrantFiled: April 16, 2007Date of Patent: October 30, 2012Assignee: Borealis Technology OyInventor: Roger Carlsson
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Patent number: 8288483Abstract: Disclosed is a diurethane compound R2(SO2)m(CH2)nOCONH—R1—NHCOO(CH2)n(SO2)mR2 produced by a method allowing a diamine compound H2NR1NH2 to react with a chloroformate compound ClCOO(CH2)n(SO2)mR2 or a method allowing a diisocyanate compound OCNR1NCO to react with a hydroxyl-containing compound R2(SO2)m(CH2)nOH. The diurethane compound is compounded with multivalent amine crosslinkable group-containing acrylic rubber together with a basic vulcanization accelerator to form an acrylic rubber composition. The acrylic rubber composition including the diurethane compound as a vulcanizing agent decreases a delay in the vulcanization rate due to prevention of scorching and also allows a vulcanized article to satisfy the compression set characteristics.Type: GrantFiled: January 30, 2009Date of Patent: October 16, 2012Assignee: Unimatec Co., Ltd.Inventors: Daisuke Ito, Haruyoshi Tatsu, Keisuke Kokin, Hideyuki Ono
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Publication number: 20120196988Abstract: The present invention relates to a process for the preparation of cross-linked polyallylamines or pharmaceutically acceptable salts thereof. The invention further relates to a process for the preparation of Sevelamer or pharmaceutically acceptable salts thereof, preferably hydrochloride or carbonate salts, used in the treatment of hyperphosphatemia, and having good flowability, low porosity and/or a swelling index of between 7 and 9.Type: ApplicationFiled: January 31, 2012Publication date: August 2, 2012Applicant: CHEMI SPAInventors: Mauro GABOARDI, Erminio OLDANI
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Patent number: 8222346Abstract: The present invention is a novel block copolymer containing a controlled distribution copolymer block of a conjugated diene and a mono alkenyl arene, where the controlled distribution copolymer block has terminal regions that are rich in conjugated diene units and a center region that is rich in mono alkenyl arene units. Also disclosed is a method for manufacture of the block copolymer.Type: GrantFiled: September 22, 2004Date of Patent: July 17, 2012Assignee: Dais-Analytic Corp.Inventors: Liwei Cao, Scott G. Ehrenberg, Joseph M Serpico
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Patent number: 8216766Abstract: A polymer having a rate of dissolution in an alkaline developer that increases under the action of acid is provided. The polymer is prepared by reacting a hydrogenated ROMP polymer with an O-alkylating agent in the presence of a base.Type: GrantFiled: March 25, 2009Date of Patent: July 10, 2012Assignees: Shin-Etsu Chemical Co., Ltd., Mitsui Chemicals, Inc.Inventors: Takeru Watanabe, Takeshi Kinsho, Tomohiro Kobayashi, Tadahiro Sunaga, Yuichi Okawa, Hirofumi Io
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Publication number: 20120142527Abstract: There is disclosed an indicator composition, the application thereof to substrates, and related products. The indicator composition comprises an organic solvent soluble polymer and a redox sensitive material which displays different visible properties in the oxidised and reduced forms. The organic solvent soluble polymer can be at least partially sulfonated polystyrene. The indicator composition can be dissolved in organic solvents such as acetone, ethanol and ethyl acetate to form inks which can be used in a variety of printing processes. The indicator composition can be used to detect oxidising agents, oxygen, water, reducing agents, UV light, temperature and the passage of time.Type: ApplicationFiled: June 17, 2010Publication date: June 7, 2012Inventors: Erik Smyth, Andrew Mills, David Hazafy
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Publication number: 20120142868Abstract: A process for preparing isobutene homo- or copolymer derivatives by (i) polymerizing isobutene or an isobutene-comprising monomer mixture in the presence of an iron halide-donor complex, an aluminum trihalide-donor complex, or an alkylaluminum halide-donor complex, (ii) reacting a resulting high-reactivity isobutene polymer with a compound which introduces a low molecular weight polar group or a substructure thereof, and (iii) in the case of reaction with a substructure, further reacting to complete the formation of the low molecular weight polar group. The homo- or copolymer derivatives include a radical of a hydrophobic polyisobutene polymer having a number-average molecular weight of 110 to 250 000 and low molecular weight polar groups including amino functions, nitro groups, hydroxyl groups, mercaptan groups, carboxylic acid or carboxylic acid derivative functions, sulfonic acid or sulfonic acid derivative functions, aldehyde functions and/or silyl groups.Type: ApplicationFiled: November 28, 2011Publication date: June 7, 2012Applicant: BASF SEInventors: Hannah Maria König, Klaus Mühlbach, Helmut Mach, Ulrich Eichenauer
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Publication number: 20120071607Abstract: The present invention relates to a polyolefin composition comprising (A) a crosslinkable polyolefin with hydrolysable silane groups which upon hydrolysation form an acid or a base, characterised in that the acid or base generates a gel content of at least 40% after 40 hours in the 90° C. cross-linking test, wherein the acid or base is added in an amount of 4.5 mmol/kg to an ethylene/vinyltrimethoxysilane copolymer with a MFR2=2 g/10 min, a density of 923 g/cm3, and 2 wt. % of vinyltrimethoxysilane and then is cross-linked in a waterbath at 90° C., and to a polyolefin composition comprising (i) a crosslinkable polyolefin with hydrolysable silane groups, and (ii) a non-polymeric compound with hydrolysable silane groups which upon hydrolysation form an acid or a base, characterised in that the acid or base generates a gel content of at least 40% after 40 hours in the 90° C. cross-linking test, wherein the acid or base is added in an amount of 4.Type: ApplicationFiled: May 14, 2010Publication date: March 22, 2012Inventors: Kristian Dahlen, Roger Carlsson
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Publication number: 20120049125Abstract: The present invention is directed to methods for the preparation of pigment particles suitable for use in an electrophoretic dispersion, particularly an electrophoretic dispersion in a fluorinated solvent. The method comprises: a) treating pigment particles to incorporate reactive groups onto the surface of the pigment particles; and b) reacting said reactive group with a functional group in a fluorinated monomer, oligomer or polymer to form a polymer layer over the surface of the pigment particles.Type: ApplicationFiled: August 23, 2011Publication date: March 1, 2012Inventors: Hui Du, Yu Li, Wie-Ho Ting, Yayong Liu, Haiyan Gu, HongMei Zang
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Publication number: 20120034464Abstract: A substance includes diamond particles having a maximum linear dimension of less than about 1 ?m and an organic compound attached to surfaces of the diamond particles. The organic compound may include a surfactant or a polymer. A method of forming a substance includes exposing diamond particles to an organic compound, and exposing the diamond particles in the presence of the organic compound to ultrasonic energy. The diamond particles may have a maximum linear dimension of less than about 1 ?m. A composition includes a liquid, a plurality of diamond nanoparticles dispersed within the liquid, and an organic compound attached to surfaces of the diamond nanoparticles. A method includes mixing a plurality of diamond particles with a solution comprising a liquid solvent and an organic compound, and exposing the mixture including the plurality of diamond nanoparticles and the solution to ultrasonic energy.Type: ApplicationFiled: October 18, 2011Publication date: February 9, 2012Applicant: BAKER HUGHES INCORPORATEDInventors: Soma Chakraborty, Gaurav Agrawal, Anthony A. DiGiovanni
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Publication number: 20110313110Abstract: A flame retardant with which fire retardancy is improved and the fire retardancy is able to be secured stably for a long time is provided. An internal layer 11 containing a polymer and a flame retardant factor layer 12 that is formed outside of the internal layer 11 and that contains a polymer to which at least one of a sulfonate group and a sulfonate base is bonded are included. Thereby, compared to a case that the flame retardant factor layer 12 is not included, moisture is hardly absorbed, and respective particles of the flame retardant are inhibited from being adhered to each other. Accordingly, blocking is inhibited.Type: ApplicationFiled: August 12, 2008Publication date: December 22, 2011Applicant: SONY CORPORATIONInventor: Yasuhito Inagaki
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Patent number: 8026339Abstract: A polysulfone is provided with a nitrogen-containing functional group having an affinity to an acid, an electrolyte membrane using the polysulfone, and a fuel cell including the electrolyte membrane. In particular, the polysulfone includes a nitrogen-containing functional group that has an affinity to an acid, such as a phosphoric acid, thereby having an excellent acid retaining ability. In an electrolyte membrane including the polysulfone and an acid, the amount of the retained acid can be controlled. Therefore, the electrolyte membrane has a high ionic conductivity and a high mechanical strength. A polysulfone blend of polysulfone and a thermoplastic resin prevents the dissolution of polysulfone by phosphoric acid, so that an electrolyte membrane using the polysulfone blend has an improved durability. A cross-linked reaction product of polysulfone, a cross-linking agent and a polymerization product of polysulfone, a thermoplastic resin, and a cross-linking agent strongly resist a phosphoric acid.Type: GrantFiled: June 1, 2007Date of Patent: September 27, 2011Assignee: Samsung SDI Co., Ltd.Inventors: Chung-kun Cho, Myung-jin Lee, Myeong-soon Kang
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Patent number: 8013072Abstract: At least partially hydrolyzed chlorosulfonated polyolefin elastomers containing 0.5-10 weight percent chlorine and 0.25 to 5 weight percent sulfur are prepared from low density polyethylene or from linear ethylene/alpha-olefin copolymer base resins having a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn) less than 3.5.Type: GrantFiled: May 13, 2009Date of Patent: September 6, 2011Assignee: DuPont Performance Elastomers L.L.C.Inventor: Royce E. Ennis
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Patent number: 7972757Abstract: A resin for an electrostatic-image-developing toner includes a graft polymer, wherein the graft polymer has a polyester structure in the main chain thereof; the graft polymer includes monomer units derived from vinyl monomers in the side chains thereof; and at least a part of the monomer units have a residue of surfactant.Type: GrantFiled: March 3, 2008Date of Patent: July 5, 2011Assignee: Fuji Xerox Co., Ltd.Inventors: Hideo Maehata, Hirotaka Matsuoka, Fumiaki Mera
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Publication number: 20100256308Abstract: A method for producing a water-absorbent resin, characterized by adding an oxetane compound represented by the following general formula (1): wherein R1 is an alkyl group having 1 to 6 carbon atoms; R2 is an alkanediyl group having 1 to 6 carbon atoms; and X is an atomic group containing at least one group selected from the group consisting of carbonyl group, phosphoryl group, and sulfonyl group, to a water-absorbent resin precursor obtainable by polymerizing water-soluble ethylenically unsaturated monomers, and subjecting the components to a post-crosslinking reaction while heating; and a water-absorbent resin obtainable by the method as defined above, characterized in that the water-absorbent resin has a water-retention capacity of physiological saline of 30 g/g or more, a water-absorption capacity of physiological saline under load of 2.07 kPa of 28 mL/g or more, and a water-soluble substance of 20% by mass or less.Type: ApplicationFiled: September 9, 2008Publication date: October 7, 2010Applicant: SUMITOMO SEIKA CHEMICALS CO., LTD.Inventors: Junichi Takatori, Masayoshi Handa, Yasuhiro Nawata
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Patent number: 7781535Abstract: An acidic group-containing polymer which has an acidic group such as sulfonic acid group, phosphoric acid group, and phosphonic acid group, and a proton acceptor which has a boiling point at 1 atmosphere higher than 100° C. and which functions as a medium for conducting proton dissociated from the acidic group are retained in pores of a porous member. Preferred examples of the proton acceptor include a salt structure composed of an anion and a cation derived from a basic organic compound, a basic organic compound, and a dissociation-facilitating polymer which facilitates dissociation of proton. Any one of the acidic group-containing polymer and the proton acceptor may be retained first, or both may be retained simultaneously.Type: GrantFiled: March 3, 2005Date of Patent: August 24, 2010Assignee: Honda Motor Co., Ltd.Inventors: Teruaki Komiya, Tadahiro Shiba
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Publication number: 20100160571Abstract: A curable composition has an olefin polymer including hydrolysable silane groups on its main chain; and to a latent compound suitable for releasing a curing catalyst under the action of a rise in temperature and/or actinic radiation.Type: ApplicationFiled: December 9, 2009Publication date: June 24, 2010Inventors: Jérôme Alric, Olivier Pinto, Jean-Michel Marty, Mikael Abeguile
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Patent number: 7732535Abstract: A coating for an implantable medical device comprising modified poly(ethylene-co-vinyl alcohol).Type: GrantFiled: March 23, 2005Date of Patent: June 8, 2010Assignee: Advanced Cardiovascular Systems, Inc.Inventor: Stephen D. Pacetti
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Patent number: 7674854Abstract: It is an object of the present invention to provide a method of producing a polyvinyl acetal resin by which a polyvinyl acetal resin having a high acetalization degree can be produced even in a solid catalyst system, a polyvinyl butyral resin produced by the above-mentioned production method of a polyvinyl acetal resin, and a method of producing an esterified polyvinyl alcohol resin by which the esterification can be performed at high efficiency even in a solid catalyst system. The present invention is a method of producing a polyvinyl acetal resin, wherein a solution or a suspension containing a polyvinyl alcohol resin and a carbonyl compound is pressurized in the presence of a solid catalyst.Type: GrantFiled: August 4, 2004Date of Patent: March 9, 2010Assignee: Sekisui Chemical Co., Ltd.Inventors: Toshio Tada, Yohei Nishimura, Katsunori Toyoshima
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Patent number: 7671137Abstract: To provide a rubber composition for a tire increasing the interaction between rubber fillers, low in heat buildup, and able to raise the vulcanization speed. A rubber composition for a tire containing 100 parts by weight of (A) a sulfur-vulcanizable diene-based rubber, (B) 0.1 to 1 part by weight of a 4,4?-oxybis(benzenesulfonylazide) and (C) a vulcanization type compounding agent, wherein the ingredients (A) and (B) are mixed at the time of a first mixing step before the compounding of the ingredient (C).Type: GrantFiled: October 3, 2008Date of Patent: March 2, 2010Assignee: The Yokohama Rubber Co., Ltd.Inventor: Naoki Kushida
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Patent number: 7659026Abstract: A fluorinated sulfonamide small molecule having the general structure wherein m, n and p are 0 to 3, with the proviso that m+n+p is equal to 1 to 4; A1 is an aromatic heterocyclic group, with the proviso that carbon atoms of the heterocyclic ring are fully substituted by fluorinated sulfonamide groups; and R1, R2, and R3 are linear or branched perfluoroalkylene groups, optionally containing oxygen, chlorine, bromine, or iodine atoms. Polymers and small molecules useful in making polymer electrode membranes, membrane electrode assemblies, and electrochemical cells, such as fuel cells, are also described.Type: GrantFiled: June 25, 2004Date of Patent: February 9, 2010Assignee: E.I. du Pont de Nemours and CompanyInventor: Mark F. Teasley
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Publication number: 20090304622Abstract: The present invention refers to a method of infiltrating enamel for the prevention and/or treatment of carious lesions comprising (a) exposing an enamel area to a conditioner comprising hydrochloric acid; (b) exposing the conditioned enamel area to an infiltrant; and (c) curing the infiltrant. The present invention further refers to a kit for carrying out the method of infiltrating enamel, which comprises a conditioner comprising hydrochloric acid and an infiltrant comprising at least one low viscous dental resin. Alternatively, the kit comprises ready-to-use means for carrying out the method of infiltrating enamel, e.g. application strips with delivery pads soaked with conditioner or infiltrant. The present invention also refers to a method for identifying an infiltrant by calculation of the penetration coefficient, and to an infiltrant identified by the method having a penetration coefficient of >50 cm/s or comprising a low viscous light curing resin having a penetration coefficient of >50 cm/s.Type: ApplicationFiled: May 11, 2007Publication date: December 10, 2009Applicants: CHARITE-UNIVERSITATSMEDIZIN BERLIN, ERNST MUHLBAUER GMBH & CO. KGInventors: Hendrik Meyer-Lueckel, Sebastian Paris, Jan Mueller, Andrij M. Kielbassa, Bernd Detje
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Publication number: 20090286937Abstract: The present invention provides a chemically amplified positive composition comprising a resin which comprises a structural unit having an acid-labile group in a side chain and a structural unit represented by the formula (I): wherein R1 represents a hydrogen atom etc., R? and R? are independently a hydrogen atom etc., k represents an integer of 1 to 12, R is independently a C1-C6 alkyl group etc. and x represents an integer of 0 to 7, and an acid generator represented by the formula (V): wherein Y1 and Y2 each independently represent a fluorine atom etc., R12 represents a C1-C30 linear, branched chain or cyclic hydrocarbon group which may be substituted, and A+ represents an organic counter ion.Type: ApplicationFiled: May 14, 2009Publication date: November 19, 2009Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Akira Kamabuchi, Satoshi Yamaguchi
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Patent number: 7598323Abstract: A method of effecting cross-linking of a resin comprises generating vinyl sulfonyl moieties in situ with the resin, said sulfonyl moieties then undergoing a reaction which effects cross-linking of the resin. The vinyl sulfonyl moieties may be generated as a result of a loss of a liquid carrier for the resin to be cross-linked. The cross-linking reaction may result from reaction of the vinyl sulfonyl moieties with nucleophilic groups in the resin composition. The resin may be a co-polymer of a compound of formula (IV) with other olefinically unsaturated monomers.Type: GrantFiled: November 27, 2003Date of Patent: October 6, 2009Assignee: The University of ManchesterInventors: Peter A. Lovell, David J. Berrisford, Andrew Whiting
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Patent number: 7550538Abstract: Chlorosulfonated propylene/olefin elastomers containing 0.5-55 weight percent chlorine and 0.15 to 5 weight percent sulfur are prepared from metallocene catalyzed propylene/olefin copolymer base resins having a ratio of Mw/Mn less than 3.5 and a copolymerized propylene content of 70-98 weight percent.Type: GrantFiled: March 12, 2008Date of Patent: June 23, 2009Assignee: DuPont Performance Elastomers LLCInventor: Avinash C. Gadkari
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Patent number: 7550539Abstract: At least partially neutralized chlorosulfonated ethylene/alpha-olefin elastomers containing 0.5-10 weight percent chlorine and 0.25 to 5 weight percent sulfur are prepared from ethylene/alpha-olefin copolymer base resins having a ratio of weight average molecular weight (Mw) to number average molecular weight (Mn) less than 3.5.Type: GrantFiled: March 13, 2008Date of Patent: June 23, 2009Assignee: Dupont Performance Elastomers LLCInventors: Royce Elton Ennis, Furman Eugene Glenn, Sr.