Metal Oxide Patents (Class 525/368)
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Patent number: 8772379Abstract: Biocomposite compositions and compositions, which include dried distillers solubles, and which can be used in making biocomposite compositions are described. Methods for preparing the compositions are also described.Type: GrantFiled: May 13, 2013Date of Patent: July 8, 2014Assignee: GS Cleantech CorporationInventors: Michael J. Riebel, Jeffrey L. Tate
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Patent number: 8680191Abstract: There is disclosed a composition for producing an elastomeric film comprising: a synthetic polymer, sulphur, and a metal-oxide cross-linking agent. The concentration of the total solids in the composition is between 5-20% by weight of the composition. Also disclosed is a multiple-coating method of manufacturing an elastomeric film comprising the steps of: (i) providing a composition comprising a synthetic polymer, a cross linking agent, wherein the concentration of the total solids in the composition is between 5-20% by weight of the composition, (ii) contacting the composition with a mold to form a layer of composition on the mold, (iii) contacting the layer of composition on the mold with a further amount of the composition to form a further layer, (iv) drying the composition, and (v) curing the composition.Type: GrantFiled: April 29, 2013Date of Patent: March 25, 2014Assignee: Diptech Pte. LimitedInventor: Khon Pu Foo
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Patent number: 8461268Abstract: A golf ball material composed of (A) an oxygen-containing inorganic metal compound in the form of a particulate or a master batch capable of neutralizing at least some of the acid groups in an acid-containing polymer blend, (B) one or more polymer selected from among diene polymers, thermoplastic polymers and thermoset polymers, and (C) an acid-containing polymer is prepared by mixing component A in a blend of components B and C. The golf ball material has a good heat resistance, flowability and processability, and can be used to produce high-performance golf balls having durability, scuff resistance and optimal hardness without a loss of rebound.Type: GrantFiled: November 15, 2011Date of Patent: June 11, 2013Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Patent number: 8436087Abstract: There is disclosed a composition for producing an elastomeric film comprising: a synthetic polymer, sulphur, and a metal-oxide cross-linking agent. The concentration of the total solids in the composition is between 5-20% by weight of the composition. Also disclosed is a multiple-coating method of manufacturing an elastomeric film comprising the steps of: (i) providing a composition comprising a synthetic polymer, a cross linking agent, wherein the concentration of the total solids in the composition is between 5-20% by weight of the composition, (ii) contacting the composition with a mold to form a layer of composition on the mold, (iii) contacting the layer of composition on the mold with a further amount of the composition to form a further layer, (iv) drying the composition, and (v) curing the composition.Type: GrantFiled: March 22, 2010Date of Patent: May 7, 2013Assignee: Diptech Pte. LimitedInventor: Khon Pu Foo
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Patent number: 8048965Abstract: Disclosed is a method for extending a shelf life of vinyl ester resin or unsaturated polyester resin during transportation or general storage. The method includes the step of enhancing an oxygen content of the vinyl ester resin or the unsaturated polyester resin, such that the self-polymerization reaction of reactive functional groups having carbon-carbon unsaturated double bonds of the vinyl ester resin or the unsaturated polyester resin can be minimized, so as to slow down occurrence of a gelation phenomenon of the vinyl ester resin or the unsaturated polyester resin in a long-time transportation or storage, and further to decrease a monetary loss.Type: GrantFiled: July 30, 2009Date of Patent: November 1, 2011Assignee: Swancor Inc. Co., Ltd.Inventors: Feng-Mao Huang, Shih-Wen Yur, Ming-Zhou Chuang
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Patent number: 7923498Abstract: There is disclosed a composition for producing an elastomeric film comprising: a synthetic polymer, sulphur, and a metal-oxide cross-linking agent. The concentration of the total solids in the composition is between 5-20% by weight of the composition. Also disclosed is a multiple-coating method of manufacturing an elastomeric film comprising the steps of: (i) providing a composition comprising a synthetic polymer, a cross linking agent, wherein the concentration of the total solids in the composition is between 5-20% by weight of the composition, (ii) contacting the composition with a mould to form a layer of composition on the mould, (iii) contacting the layer of composition on the mould with a further amount of the composition to form a further layer, (iv) drying the composition, and (v) curing the composition.Type: GrantFiled: January 22, 2008Date of Patent: April 12, 2011Assignee: Diptech Pte. LimitedInventor: Khon Pu Foo
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Patent number: 7906570Abstract: Disclosed is a thermoplastic resin composition contains including a methacrylic resin having a ring structure in a main chain thereof and a glass transition temperature of 110° C. or higher, and at least one kind of metal compound selected from metal salts, metal complexes, and metal oxides, wherein a content of the metal compound in the composition is from 10 to 10,000 ppm in terms of metal atom based on a mass of the methacrylic resin, and a process for producing such a thermoplastic resin composition, the process including carrying out, when preparing a methacrylic resin having a ring structure in a main chain thereof and a glass transition temperature of 110° C. or higher, cyclization condensation reaction using a catalyst to form the ring structure; and then adding a deactivator of the catalyst.Type: GrantFiled: March 1, 2007Date of Patent: March 15, 2011Assignee: Nippon Shokubai Co., Ltd.Inventors: Ken-ichi Ueda, Shigeo Otome, Shoji Ito, Yow-hei Sohgawa, Hideo Asano
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Publication number: 20110028659Abstract: Disclosed is a method for extending a shelf life of vinyl ester resin or unsaturated polyester resin during transportation or general storage. The method includes the step of enhancing an oxygen content of the vinyl ester resin or the unsaturated polyester resin, such that the self-polymerization reaction of reactive functional groups having carbon-carbon unsaturated double bonds of the vinyl ester resin or the unsaturated polyester resin can be minimized, so as to slow down occurrence of a gelation phenomenon of the vinyl ester resin or the unsaturated polyester resin in a long-time transportation or storage, and further to decrease a monetary loss.Type: ApplicationFiled: July 30, 2009Publication date: February 3, 2011Inventors: Feng-Mao HUANG, Shih-Wen YUR, Ming-Zhou CHUANG
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Patent number: 7737225Abstract: An elastomer composition includes a polymer system made up of a majority of HNBR polymer and an optional polymer additive such as carboxylated nitrile, ethylene-propylene-diene rubber, isoprene rubber, chloroprene rubber, acrylonitrile-butadiene rubber, butyl rubber, isoprene rubber, natural rubber and hydrogenated carboxylated butadiene acrylonitrile terpolymer, and combinations thereof. The polymer system totals 100 parts by weight. A cure system for the elastomer composition includes 1.5 to 30 parts by weight of zinc, magnesium or calcium oxide, 15 to 50 parts by weight of an ?,?-ethylenically unsaturated carboxylic acid and an organoperoxide. Under vulcanization conditions, the elastomer composition cures through the in situ formation of a metal carboxylate. A degradation inhibitor for an elastomer composition that includes an amine and an imidazole along with an optional polymerized quinoline is noted to be particularly effective.Type: GrantFiled: December 14, 2005Date of Patent: June 15, 2010Assignee: The United States of America as represented by the Secretary of the ArmyInventors: Paul Touchet, Alan R. Teets, David P. Flanagan, Charles G. Pergantis
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Publication number: 20100056303Abstract: The invention provides a golf ball material composed of an ionomeric resin composition obtained by melt-blending under applied heat one or more compounds selected from among UV/EB-curable materials with, in the presence of a peroxide, a non-ionomeric thermoplastic resin and an ionomeric resin; or of an ionomeric resin composition obtained by using, instead of the ionomeric resin, an acid-containing polymer base of the ionomeric resin and subjecting the acid-containing polymer composition similarly prepared by melt-blending under applied heat to an acid-neutralizing reaction with a metal ionic species. Methods for preparing such a material, and golf balls which include as a component therein a molding made of the golf ball material are also provided. The golf ball material has a good thermal stability, flow and processability, and can thus be used to obtain high-performance golf balls endowed with an excellent abrasion resistance, scuff resistance, durability and flexibility without a loss of rebound.Type: ApplicationFiled: August 27, 2008Publication date: March 4, 2010Applicant: Bridgestone Sports Co, Ltd.Inventors: Yoshinori EGASHIRA, Jun Shindo, Eiji Takehana, Hiroyuki Nagasawa
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Patent number: 7514505Abstract: A golf ball material composed of (A) an oxygen-containing inorganic metal compound in the form of a particulate or a master batch capable of neutralizing at least some of the acid groups in an acid-containing polymer blend, (B) one or more polymer selected from among diene polymers, thermoplastic polymers and thermoset polymers, and (C) an acid-containing polymer is prepared by mixing component A in a blend of components B and C. The golf ball material has a good heat resistance, flowability and processability, and can be used to produce high-performance golf balls having durability, scuff resistance and optimal hardness without a loss of rebound.Type: GrantFiled: August 3, 2005Date of Patent: April 7, 2009Assignee: Bridgestone Sports Co., Ltd.Inventors: Yoshinori Egashira, Eiji Takehana
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Patent number: 7476712Abstract: The invention is directed to a film which comprises a poly(carboxylic acid) polymer and a polyvalent metal compound, which is endowed with excellent gas barrier property against, for example oxygen, which has such resistance that the appearance, shape, and gas-barrier properties are not impaired by neutral water, high-temperature water vapor, or hot water; a laminate produced by use of the film; and a process for producing the film or laminate industrially conveniently at low cost. The film or laminate of the present invention is suitable for use as a package, packaging container, or vacuum insulation material for articles which are apt to be deteriorated by oxygen, etc., such as foods, beverages, chemicals, medicines, and metallic precision parts; e.g., electronic parts.Type: GrantFiled: April 23, 2003Date of Patent: January 13, 2009Assignee: Kureha CorporationInventors: Hideaki Tanaka, Hiroyuki Oba, Masahiro Yamazaki, Tomohisa Hasegawa
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Publication number: 20080139723Abstract: There is disclosed a composition for producing an elastomeric film comprising: a synthetic polymer, sulphur, and a metal-oxide cross-linking agent. The concentration of the total solids in the composition is between 5-20% by weight of the composition. Also disclosed is a multiple-coating method of manufacturing an elastomeric film comprising the steps of: (i) providing a composition comprising a synthetic polymer, a cross linking agent, wherein the concentration of the total solids in the composition is between 5-20% by weight of the composition, (ii) contacting the composition with a mould to form a layer of composition on the mould, (iii) contacting the layer of composition on the mould with a further amount of the composition to form a further layer, (iv) drying the composition, and (v) curing the composition.Type: ApplicationFiled: January 22, 2008Publication date: June 12, 2008Inventor: Khon Pu Foo
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Patent number: 7151141Abstract: To a fluorine-containing polymer, 0.1 to 10% of a compound having an alkali metal or an alkaline earth metal in terms of the number of atoms of the alkali metal or the alkaline earth metal based on the total number of the above terminal groups, 0.1 to 10% of ammonia in terms of the number of ammonia molecules based on the total number of the above terminal groups, or 0.1 to 10% of a compound having an ammonium group in terms of the number of the ammonium groups based on the total number of the above terminal groups is added, and heated at a temperature of at least 200° C. in an atmosphere containing moisture. By this process, unstable terminal groups such as terminal carboxylic acid groups and coloration caused by such terminal groups are effectively removed from the fluorine-containing polymer, and furthermore unstable bonds in the backbones can be removed. The obtained fluorine-containing polymer contains 1.Type: GrantFiled: July 1, 2004Date of Patent: December 19, 2006Assignee: Daikin Industries Ltd.Inventors: Yoshiyuki Hiraga, Satoshi Komatsu, Tomohisa Noda, Masayuki Namimatsu, Hiroyuki Imanishi
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Patent number: 7138461Abstract: A molding material consisting of a fluorine-containing copolymer, which has a metal elution index ? of at most 10 as the total amount in ng of metals of Na, Mg, Cu, Cr, Ni, K, Ca and Fe per 1 g of the molding material, as obtained by elution analysis of the molding material with nitric acid.Type: GrantFiled: December 27, 2004Date of Patent: November 21, 2006Assignee: Asahi Glass Company, LimitedInventors: Atushi Funaki, Naoko Sumi, Teruo Takakura
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Patent number: 7037949Abstract: A reactive liquid is coated on an ion exchange resin precursor membrane for the hydrolysis treatment. Preferably, a reactive liquid having a viscosity of not lower than 50 mPa·s or a small surface tension is used. Said precursor membrane is also subjected to the hydrolysis treatment under constraint, while the precursor membrane is maintained in a widened or a stretched state.Type: GrantFiled: February 7, 2002Date of Patent: May 2, 2006Assignee: Asahi Kasei Chemicals CorporationInventors: Naoto Miyake, Takuya Hasegawa
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Patent number: 7030193Abstract: The present invention relates to a polymer composite containing at least one carboxylated nitrile rubber polymer, that is optionally hydrogenated, at least one basic compound, at least one polyhalogenated hydrocarbon, optionally at least one filler and optionally at least one cross-linking agent, a process for preparing said polymer composite wherein at least one carboxylated nitrile rubber polymer, that is optionally hydrogenated, at least one basic compound, at least one polyhalogenated hydrocarbon, optionally at least one filler and optionally at least one cross-linking agent are mixed and a shaped article containing diester bridges formed by reaction of at least one carboxylated nitrile rubber polymer, that is optionally hydrogenated, at least one basic compound and at least one polyhalogenated hydrocarbon.Type: GrantFiled: June 22, 2004Date of Patent: April 18, 2006Assignee: Bayer Inc.Inventors: Frederic Guerin, Carl Walter Von Hellens, Sharon X. Guo
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Patent number: 6911512Abstract: Provided is a composition comprising an aromatic material selected from a polythiol aromatic compound or resin, a hydroxythiophenol compound or resin, a catechol novolak resin, a catechol cresol novolak resin, a polyhydroxy aromatic resin or compound comprising at least one aromatic ring having at least one hydroxyl group attached directly to the aromatic ring wherein at least one hydroxyl group is a phenolate salt, or a combination thereof, and a salt former compound capable of forming a salt with the aromatic material, a fluoropolymer, and optionally a phase transfer catalyst. Also provided are articles comprising powder-coated fluoropolymers with aromatic compounds, and methods for making the compositions and articles.Type: GrantFiled: October 10, 2003Date of Patent: June 28, 2005Assignee: 3M Innovative Properties CompanyInventors: Naiyong Jing, Lisa P. Chen, Jeffrey T. Anderson, Thomas J. Blong, Justin A. Riddle, Blake E. Chandler
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Publication number: 20040242793Abstract: To a fluorine-containing polymer, 0.1 to 10% of a compound having an alkali metal or an alkaline earth metal in terms of the number of atoms of the alkali metal or the alkaline earth metal based on the total number of the above terminal groups, 0.1 to 10% of ammonia in terms of the number of ammonia molecules based on the total number of the above terminal groups, or 0.1 to 10% of a compound having an ammonium group in terms of the number of the ammonium groups based on the total number of the above terminal groups is added, and heated at a temperature of at least 200° C. in an atmosphere containing moisture. By this process, unstable terminal groups such as terminal carboxylic acid groups and coloration caused by such terminal groups are effectively removed from the fluorine-containing polymer, and furthermore unstable bonds in the backbones can be removed. The obtained fluorine-containing polymer contains 1.Type: ApplicationFiled: July 1, 2004Publication date: December 2, 2004Applicant: Daikin Industries, Ltd.Inventors: Yoshiyuki Hiraga, Satoshi Komatsu, Tomohisa Noda, Masayuki Namimatsu, Hiroyuki Imanishi
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Patent number: 6777501Abstract: To a fluorine-containing polymer, 0.1 to 10% of a compound comprising an alkali metal or an alkaline earth metal in terms of the number of atoms of the alkali metal or the alkaline earth metal based on the total number of the above terminal groups, 0.1 to 10% of ammonia in terms of the number of ammonia molecules based on the total number of the above terminal groups, or 0.1 to 10% of a compound having an ammonium group in terms of the number of the ammonium groups based on the total number of the above terminal groups is added, and heated at a temperature of at least 2000C in an atmosphere containing moisture. By this process, unstable terminal groups such as terminal carboxylic acid groups and coloration caused by such terminal groups are effectively removed from the fluorine-containing polymer, and furthermore unstable bonds in the backbones can be removed. The obtained fluorine-containing polymer contains 1.Type: GrantFiled: September 8, 2000Date of Patent: August 17, 2004Assignee: Daikin Industries Ltd.Inventors: Yoshiyuki Hiraga, Satoshi Komatsu, Tomohisa Noda, Masayuki Namimatsu, Hiroyuki Imanishi
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Patent number: 6680082Abstract: The present invention relates to neutralized copolymer resins having at least two different metals with one of the metals being zinc. These mixed metal resins are transformed into particulate or powder form for application to metal objects. The powder composition has a good balance of properties including all the advantages associated with neutralized ethylene acid copolymers while also having good powder coating behavior for coatings applied to metal objects. The invention also relates to coated metal objects containing the powder composition and metal.Type: GrantFiled: October 3, 2002Date of Patent: January 20, 2004Assignee: E. I. du Pont de Nemours and CompanyInventors: Richard Tien-Hua Chou, Mark Bernard Kelly
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Patent number: 6673871Abstract: Elastomeric articles, such as gloves and condoms, are disclosed including a process for making the articles. The elastomeric articles produced according to the present invention are made from a synthetic polymer. During production of the articles, the polymer is cross-linked using a metal oxide as a cross-linking agent. In one embodiment, the polymer is cross-linked without using conventional sulfur-containing cross-linking agents or accelerators.Type: GrantFiled: December 21, 2000Date of Patent: January 6, 2004Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Derek Warneke, Jali Williams
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Patent number: 6670426Abstract: An olefin thermoplastic elastomer containing an olefin random copolymer formed by copolymerizing ethylene, an &agr;-olefin having 3 to 10 carbon atoms and an unsaturated monomer having a functional group, and optionally a non-conjugated diene, and metal ions crosslinking the olefin random copolymer, has the same or similar rubber elasticity, flexibility and molding and processability as the conventional olefin thermoplastic elastomers, and has good mechanical properties, wear resistance, in particular scratch resistance.Type: GrantFiled: February 10, 2003Date of Patent: December 30, 2003Assignee: JSR CorporationInventors: Kentarou Kanae, Akihiko Morikawa, Hideo Nakanishi, Shoei Tsuji
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Patent number: 6667377Abstract: This invention concerns ionomers comprising monomer units of vinylidene fluoride and monomer units of perfluorovinyl ethers having pendant groups containing fluoroalkyl sulfonyl methide or fluoroalkyl sulfonyl imide derivatives and univalent metal salts thereof, and with the uses of said ionomers in eledrochemical applications, electrochemical capacitors and modified electrodes.Type: GrantFiled: May 10, 2001Date of Patent: December 23, 2003Assignee: E. I. du Pont de Nemours and CompanyInventors: Andrew Edward Feiring, Christopher Marc Doyle, Mark Gerrit Roelofs, William Brown Farnham, Paul Gregory Bekiarian, Hanne A. K. Blau
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Patent number: 6664339Abstract: A base resistant, substantially amorphous fluoroelastomer comprising (1) 10-40 mole percent ethylene units, (2) 32-60 mole percent tetrafluoroethylene units, (3) 20-40 mole percent perfluoro ether units selected from the group consisting of perfluoro(alkyl vinyl ethers), perfluoro(alkyl alkenyl ethers) and perfluoro(alkoxy alkenyl ethers), and (4) 0.1 to 15 mole percent of a cure site monomer selected from the group consisting of i) 3,3,3-trifluoropropene-1, ii) trifluoroethylene, iii) 1,2,3,3,3-pentafluoropropylene, iv) 1,1,3,3,3-pentafluoropropylene, and v) 2,3,3,3-tetrafluoropropene. Such fluoroelastomers may be vulcanized with polyhydroxy curatives. The resulting vulcanized fluoroelastomer compositions are resistant to attack by amines, strong bases and hydrogen sulfide and possess a combination of good low temperature and high temperature properties and they are resistant to oil swell.Type: GrantFiled: May 2, 2002Date of Patent: December 16, 2003Assignee: DuPont Dow Elastomers LLCInventors: Walter Werner Schmiegel, Phan Linh Tang
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Patent number: 6642331Abstract: Perfluoroelastomers, curable by peroxidic route, obtainable by polymerizing the following monomers: a) tetrafluoroethylene (TFE); b) fluorovinylethers of general formula: CFX═CXOCF2OR (I) c) bis-olefins having general formula: RI1RI2C═CRI3—Z—CRI4═CRI5RI6 (IA) d) optionally, one or more fluorinated olefinic comonomers selected from C2-C8 perfluoroolefins, perfluoroalkylvinylethers (PAVE) CF2═CFOR2f, perfluoro-oxyalkylvinylethers CF2═CFOXa, said perfluoroelastomers comprising iodine and/or bromine atoms in the chain and/or in end position, said halogen atoms deriving from “cure site” comonomers and/or from chain transfer agents used in polymerization.Type: GrantFiled: October 16, 2002Date of Patent: November 4, 2003Assignee: Ausimont S.p.A.Inventors: Marco Apostolo, Stefano Arrigoni
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Publication number: 20030065103Abstract: The present invention relates to neutralized copolymer resins having at least two different metals with one of the metals being zinc. These mixed metal resins are transformed into particulate or powder form for application to metal objects. The powder composition has a good balance of properties including all the advantages associated with neutralized ethylene acid copolymers while also having good powder coating behavior for coatings applied to metal objects. The invention also relates to coated metal objects containing the powder composition and metal.Type: ApplicationFiled: October 3, 2002Publication date: April 3, 2003Inventors: Richard Tien-Hua Chou, Mark Bernard Kelly
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Publication number: 20020156170Abstract: An optical nanocomposite material has a nanoparticulate filler dispersed in a host plastic material. According to the method of making the nanocomposite material, a predetermined temperature sensitive optical vector, such as refractive index, of the plastic host material and nanoparticulate filler are directionally opposed resulting in a nanocomposite material having significantly improved stability of the refractive index with respect to temperature.Type: ApplicationFiled: April 5, 2002Publication date: October 24, 2002Inventors: John Border, Michael R. McGovern
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Publication number: 20020114943Abstract: Elastomeric articles, such as gloves and condoms, are disclosed including a process for making the articles. The elastomeric articles produced according to the present invention are made from a synthetic polymer. During production of the articles, the polymer is cross-linked using a metal oxide as a cross-linking agent. In one embodiment, the polymer is cross-linked without using conventional sulfur-containing cross-linking agents or accelerators.Type: ApplicationFiled: December 21, 2000Publication date: August 22, 2002Inventors: Derek Warneke, Jali Williams
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Patent number: 6359102Abstract: Improvements are disclosed for biphasic polymerization processes in which an aqueous solution of a first monomer that is hydrolytically unstable below a pH of about six or above a pH of about eight is admixed with a water-immiscible organic solvent and there is added to the admixture a catalyst selected from tertiary amine, quaternary amine and phosphonium catalysts, an acid-forming co-monomer for the first monomer, an acid scavenger, after which the resulting polymer is recovered, wherein the improvement includes providing the aqueous solution at a pH between about si and about eight, and adding to the admixture the acid-forming co-monomer and the acid scavenger at relative rates effective to maintain the pH of the admixture between about six and about eight. The catalyst may be added in a molar ratio to the first monomer effective to provide a predetermined weight-average or number-average molecular weight for the resulting polymer.Type: GrantFiled: June 29, 1998Date of Patent: March 19, 2002Assignee: Integra LifeSciences I, Ltd.Inventors: John E. Kemnitzer, George L. Brode, Joachim B. Kohn
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Patent number: 6221971Abstract: Elastomeric vinylidene fluoride-containing copolymers are cured by a sequential process. In a first step, gum fluoroelastomer is mixed at a temperature of 150° C.-250° C. in the presence of an organic base and metal oxide or metal hydroxide to generate an unsaturated product. The unsaturated product is mixed with a polyhydroxy compound, polyamine, or organic peroxide and the resultant compounded fluoroelastomer is crosslinked.Type: GrantFiled: November 18, 1999Date of Patent: April 24, 2001Assignee: DuPont Dow Elastomers, L.L.C.Inventor: David L. Tabb
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Patent number: 6020440Abstract: Elastomeric vinylidene fluoride-containing copolymers are cured by a sequential process. In a first step, gum fluoroelastomer is mixed at a temperature of 150.degree. C.-250.degree. C. in the presence of an organic base and metal oxide or metal hydroxide to generate an unsaturated product. The unsaturated product is mixed with a polyhydroxy compound, polyamine, or organic peroxide and the resultant compounded fluoroelastomer is crosslinked.Type: GrantFiled: September 29, 1997Date of Patent: February 1, 2000Assignee: Dupont Dow Elastomers, L.L.C.Inventor: David L. Tabb
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Patent number: 5869578Abstract: A process for forming a golf ball cover composition, which process comprises: a) forming a polymer comprising (1) a first monomeric component comprising an olefinic monomer having from 2 to 8 carbon atoms; (2) a second monomeric component comprising an unsaturated carboxylic acid based acrylate class ester having from 4 to 22 carbon atoms; and (3) an optional third monomeric component comprising at least one monomer selected from the group consisting of carbon monoxide, sulfur dioxide, an anhydride monomer, an unsaturated monocarboxylic acid, an olefin having from 2 to 8 carbon atoms, and a vinyl ester or vinyl ether of an alkyl acid having from 4 to 21 carbon atoms; b) applying a sufficient amount of heat to the polymer to convert it to a substantially molten state; c) adding an inorganic metal base to the molten polymer to form a mixture; and d) saponifying the mixture to form a polymer salt particularly adapted for forming improved golf ball covers.Type: GrantFiled: November 25, 1997Date of Patent: February 9, 1999Assignee: Acushnet CompanyInventor: Murali Rajagopalan
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Patent number: 5866670Abstract: A process for producing a polyacetal copolymer, which is extremely heat-stable and is extremely reduced in the quantity of unstable terminals even in a high polymerization yield in which trioxane as the principal monomer, comprises copolymerization of trioxane as the principal monomer with a cyclic ether or cyclic formal having at least one carbon-to-carbon bond as the comonomer by using a specific heteropoly-acid or acid salt thereof as a polymerization catalyst until the content of the remaining monomers is lowered to at most 10% by weight based on all the monomers fed, adding 0.01 to 10% by weight, based on the resulting crude polymer, of a solution containing a catalyst deactivator, or contacting a basic gas as the deactivator to deactivate the catalyst, and subjecting the crude polymer as such to heat melting treatment without washing thereof.Type: GrantFiled: August 15, 1996Date of Patent: February 2, 1999Assignee: Polyplastics Co., Ltd.Inventors: Akira Nakai, Kaoru Yamamoto, Eiji Masuda, Hiroyuki Kanai
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Patent number: 5837779Abstract: A process for the production of an ionomers containing ethylenically-unsaturated structural units comprising contacting:(a) a terpolymer containing structural units produced from (i) at least one .alpha.-olefin having from 2 to 8 carbon atoms; (ii) at least one ester of alpha, beta-ethylenically-unsaturated carboxylic acids; and (iii) at least one carboxylic acid with;(b) an inorganic metal-containing base under conditions effective to convert at least a portion of acid functionalities to inorganic metal salts thereof.Type: GrantFiled: May 13, 1996Date of Patent: November 17, 1998Assignee: Chevron Chemical CompanyInventors: Steven P. Current, Leslie P. Theard
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Patent number: 5830933Abstract: A denture adhesive composition contains a denture adhesive and a pharmacologically acceptable carrier in which the denture adhesive is a salt of a copolymer of maleic acid or anhydride and a 1 to 5 carbon atom alkyl vinyl ether having a specific viscosity of at least 4.0. The denture adhesive composition is used to adhere a denture to the oral mucosa.Type: GrantFiled: April 22, 1996Date of Patent: November 3, 1998Assignee: Block Drug Company, Inc.Inventors: Joseph Synodis, Alfred J. Smetana, Robert C. Gasman, Eddie Wong, Hal C. Clarke
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Patent number: 5804668Abstract: The polymer compounds according to the invention prepared from specific amidines, zinc mercapto compounds and elastomers are ideally suitable for the production of thermally stable rubber vulcanisates containing halogen. The vulcanisates of rubbers containing halogen obtained by means of the polymer compounds are distinguished by a reduced tendency towards unwanted post-vulcanization and, at elevated storage temperatures, are resistant to thermal and oxidative degradation.Type: GrantFiled: May 1, 1997Date of Patent: September 8, 1998Assignee: Bayer AGInventors: Rudiger Schubart, Rudiger Musch
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Patent number: 5728774Abstract: A process for the continuous production of superabsorbent polymers, characterised in that aqueous emulsions of uncross-linked and cross-linked polyacrylonitrile homopolymers and/or copolymers, the polyacrylonitrile concentrations in the reaction mixture being from 10 to 45 w.t. %, are hydrolysed with aqueous alkali hydroxide solutions at 50.degree. to 100.degree. C. in a continuously operating reactor suitable for carrying out highly viscous reactions, and that from the highly viscous gels formed the products in the form of superabsorbent powders are continuously precipitated by means of continuous precipitation using low-boiling monoalcohols, and the use thereof in sanitary articles, as water-storing materials in agriculture or for sheathing electrical cables.Type: GrantFiled: December 20, 1996Date of Patent: March 17, 1998Assignee: Bayer AktiengesellschaftInventors: Gunter Sackmann, Sergej Schapowalow, Martin Ullrich, Helmut Brod
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Patent number: 5631326Abstract: Crosslinked, nitrogen-containing vinyl copolymers having units of the formula I ##STR1## and physiologically tolerated salts thereof, in which, in formula I, A1, A2, R, w, x, y and z have the meanings given, a process for their preparation and the use of the compounds as medicaments, active compound carriers and foodstuff auxiliaries are described.Type: GrantFiled: May 30, 1995Date of Patent: May 20, 1997Assignee: Hoechst AktiengesellschaftInventors: Michael Ahlers, Heiner Glombik, Stefan M ullner, Axel Walch
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Patent number: 5583186Abstract: The present invention provides a new and improved process for preparing a polybutene amine composition comprising the steps of reacting a chlorinated polybutene with an excess of at least one mole of at least one type of an amine compound per mole of the chlorinated polybutene at a reaction temperature of at least about 100.degree. C.; neutralizing the reaction mixture with calcium oxide; and recovering the polybutene amine composition, the recovery process including the steps of removing the formed water and the neutralized and excess of the amine compound and removing inorganic solids using a non-aqueous separation technique such as filtration. During the neutralization step, water formation is kept to a minimum and no water is intentionally added to the process thereby minimizing resultant waste streams and/or undesirable by-products.Type: GrantFiled: June 1, 1995Date of Patent: December 10, 1996Assignee: Ferro CorporationInventor: Michael P. Duncan
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Patent number: 5569722Abstract: Ionomer compositions which have improved optical properties are disclosed. These compositions comprise ionomers which can be represented as the polymerization product of alpha-olefins having from two to eight carbon atoms, esters of alpha, beta-ethylenically-unsaturated carboxylic acids, metal salts of acrylic and methacrylic acid, and optional alpha, beta-ethylenically-unsaturated comonomers which impart some desired polymer property or properties, such as acidity and/or solvent resistivity. Also disclosed are methods of making these ionomer compositions in a reactive extruder and treating the compositions with acid to impart acidity to the compositions or to only the surface of the compositions.Type: GrantFiled: June 5, 1995Date of Patent: October 29, 1996Assignee: Chevron Chemical CompanyInventors: James H. Wang, David Rosendale, Victor P. Kurkov, Leslie P. Theard, Ta Y. Ching, Lewis R. Compton, Tor H. G. Palmgren, Mitchell P. Eichelberger
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Patent number: 5567779Abstract: A process for the production of super-absorbent polymers with a swelling capacity in water-containing liquids of up to 1,000 g/g in which aqueous emulsions of particularly high molecular weight polymers of acrylonitrile are partly hydrolyzed by reaction with aqueous solutions of alkali metal and/or alkaline earth metal hydroxides, the polymers are precipitated in powder form by addition of water-miscible organic solvents, separated off, dried and then optionally heated for a short time. The super-absorbent polymers are used as water-storing materials, for example in sanitary articles, in agriculture or in the sheathing of electrical cables.Type: GrantFiled: October 20, 1995Date of Patent: October 22, 1996Assignee: Bayer AktiengesellschaftInventors: G unter Sackmann, Rolf-Volker Meyer, Siegfried Korte, Sergej Schapowalow
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Patent number: 5554698Abstract: Ionomer compositions which have improved optical properties are disclosed. These compositions comprise ionomers which can be represented as the polymerization product of alpha-olefins having from two to eight carbon atoms, esters of alpha, beta-ethylenically-unsaturated carboxylic acids, metal salts of acrylic and methacrylic acid, and optional alpha, beta-ethylenically-unsaturated comonomers which impart some desired polymer property or properties, such as acidity and/or solvent resistivity. Also disclosed are methods of making these ionomer compositions in a reactive extruder and treating the compositions with acid to impart acidity to the compositions or to only the surface of the compositions.Type: GrantFiled: June 5, 1995Date of Patent: September 10, 1996Assignee: Chevron Chemical CompanyInventors: James H. Wang, David Rosendale, Victor P. Kurkov, Leslie P. Theard, Ta Yen Ching, Lewis R. Compton, Tor H. G. Palmgren, Mitchell P. Eichelberger
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Patent number: 5541265Abstract: A process for preparing a coating composition characterized in that the process comprises the step of reacting 0.05 to 0.9 chemical equivalents of a calcium compound based on an acid value of a polymer with a polymer emulsion containing the polymer having the acid value of 20 to 200 prepared by a polymerization of unsaturated ethylenic monomers is provided. Calcium oxide, calcium hydroxide, calcium carbonate and the like may be used as the calcium compound, and the reaction of the calcium compound with the polymer may be carried out after the pH of the emulsion is adjusted within a range of from 4.5 to 9 by adding a base. The coating compositions of the present invention are stable for long period of time and free from environmental pollution since they contain no heavy metal. They are characterized to not generate uncomfortable odor of ammonia during application and drying-up since no metal complex is used.Type: GrantFiled: June 2, 1994Date of Patent: July 30, 1996Assignee: Yuho Chemicals, Inc.Inventors: Tadashi Gomi, Atsushi Wada
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Patent number: 5525652Abstract: A novel denture adhesive composition contains an adhesive mixture comprising sodium carboxymethyl cellulose and, either a partially neutralized sodium, magnesium, zinc mixed salt or a partially neutralized magnesium, zinc mixed salt of an alkyl vinyl ether maleic acid copolymer.Type: GrantFiled: August 10, 1994Date of Patent: June 11, 1996Assignee: Block Drug Company, Inc.Inventors: Hal C. Clarke, Hyung-Kook Ahn, Eddie Wong, Robert C. Gasman, Alfred J. Smetana, Joseph Synodis
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Patent number: 5521267Abstract: Emulsifier-free synthetic resins and mixtures of synthetic resins with water are used as binders for water-borne printing inks and printing varnishes. The resins contain: (a) a polymer resin A containing acid groups which may have been neutralized or partially neutralized and can be prepared by in-situ polymerization of ethylenically unsaturated compounds containing acid groups with further ethylenically unsaturated compounds and condensation with monohydroxy compounds and, if desired, neutralization or partial neutralization, and (b) if desired, a water-insoluble polymer resin B in the form of latex particles which can be prepared by emulsion polymerization of ethylenically unsaturated compounds in the presence of the polymer resin A.Type: GrantFiled: September 6, 1994Date of Patent: May 28, 1996Assignee: Hoechst AktiengesellschaftInventors: Astrid Giencke, Petra Ulrich, Gerd Walz, Bernd Mergardt
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Patent number: 5519093Abstract: Amine functional polymers are prepared by polymerization of vinylamides with vinyl ester monomers. The resultant polymers are hydrolyzed under acid conditions and subsequently at least partially basified to the free-base amine. Byproduct salts are removed by precipitation or by extraction into an immiscible phase. The polymers made by this method are crosslinkable through reaction of the amine groups and are useful in high performance coatings, adhesives, binders and the like.Type: GrantFiled: May 11, 1994Date of Patent: May 21, 1996Assignee: Air Products and Chemicals, Inc.Inventors: Robert K. Pinschmidt, Jr., Khalil Yacoub
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Patent number: 5516853Abstract: The present invention relates to a process for the production of oxidatively crosslinkable, water-dilutable binders bya) forming a copolymer having intramolecular carboxylic anhydride groups by copolymerizing anhydride-functional compounds, other olefinically unsaturated monomers and 5 to 50% by weight, based on the weight of the olefinically unsaturated monomers used for the production of the copolymers a), of monomers which cannot be homopolymerized under the reaction conditions,b) subsequently reacting by ring-opening esterification at least 50% of the anhydride groups present in the copolymer with one or more unsaturated monohydric alcohols,c) reacting by ring-opening esterification up to 50% of the anhydride groups with monohydric saturated alcohols having a molecular weight of 32 to 200 either before, during or after step b),d) optionally reacting 1 to 70% of the carboxyl groups formed in steps b) and c) with organic epoxide compounds ande) neutralizing at least a portion of the carboxyl groups formed iType: GrantFiled: April 19, 1995Date of Patent: May 14, 1996Assignee: Bayer AktiengesellschaftInventors: Volker Schneider, Eberhard Arning, Harald Blum, Christian Wamprecht
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Patent number: 5504162Abstract: Salts of copolymers of ethylenically unsaturated carboxylic acids and ethylenically unsaturated fatty acid derivatives.Type: GrantFiled: January 4, 1994Date of Patent: April 2, 1996Assignee: Hoechst AktiengesellschaftInventors: Herbert Friedrich, Bernhard Mees, Richard Gruber
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Patent number: RE36657Abstract: A denture adhesive composition contains a denture adhesive and a pharmacologically acceptable carrier in which the denture adhesive is a salt of a copolymer of maleic acid or anhydride and a 1 to 5 carbon atom alkyl vinyl ether having a specific viscosity of at least 4.0. The denture adhesive composition is used to adhere a denture to the oral mucosa.Type: GrantFiled: November 18, 1998Date of Patent: April 11, 2000Assignee: Block Drug Company, Inc.Inventors: Joseph Synodis, Alfred J. Smetana, Robert C. Gasman, Eddie Wong, Hal C. Clarke