Chemical Treating Agent Is A Nitrogen-containing Compound Patents (Class 525/374)
  • Patent number: 6265358
    Abstract: A composition comprising a hydrocarbon polymer having {overscore (M)}n ranging from 20,000 to about 500,000, when the polymer is not a star polymer, and up to about GPC peak molecular weight of 4,000,000 when the polymer is a star polymer having attached thereto pendant groups Aa and Bb wherein each A is independently a member of the group of formula —Q—Kk wherein each Q is independently an aliphatic or aromatic hydrocarbon group, each K is independently a member selected from the group consisting of amide groups, nitrile groups, ester groups and carboxylic acid groups, and each k is independently a number ranging from 1 to about 3, and when k≧2, groups —K on adjacent carbon atoms, taken together, may constitute a succinimide group, and a is 0 or a number ranging from 1 to about 50; and each B is independently a member of the group of formula: wherein each X is independently O, S, or NRb, each Rb is independently H, NH2, hydrocarbyl, hydroxyhydrocarbyl, or aminohydrocarb
    Type: Grant
    Filed: December 3, 1997
    Date of Patent: July 24, 2001
    Assignee: The Lubrizol Corporation
    Inventors: Carmen V. Luciani, Richard M. Lange, Daniel M. Vargo
  • Patent number: 6252006
    Abstract: A coating composition of a fluororubber containing a fluorine-containing elastomeric copolymer which has repeating units of the formula: —CH2— in the backbone, a polyol curing agent, and a salt or a complex compound of a basic compound having a pKa of at least 8 and an organic acid as a curing accelerator. This composition is a one-pack type composition having a long pot life, and can provide a cured coating in a short time at a relatively low temperature. Furthermore, this composition can be applied by dispenser type coating or screen printing, even when the concentration of the fluorine-containing copolymer is high.
    Type: Grant
    Filed: March 25, 1999
    Date of Patent: June 26, 2001
    Assignee: Daikin Industries Ltd.
    Inventors: Nobuyuki Tomihashi, Kiyotaro Terasaka, Toshiyuki Kinoshita
  • Patent number: 6248815
    Abstract: The present invention relates to a water based laminating adhesive composition and a method of using thereof. More particularly, the invention relates to a water-based laminating adhesive comprising: a first component comprising at least one aqueous vinyl polymer dispersion (A) comprising the reaction product of i) at least one ethylenically unsaturated monomer; ii) at least one free radical initiator; and iii) optionally, at least one ethylenically unsaturated oligomer; and b) a second component comprising at least one water dispersible polyfunctional aziridine crosslinking agent (B). The adhesive optionally comprises at least one aqueous polyurethane polymer dispersion (C). Improved bonded properties of dry laminated flexible film substrates such as polyolefin, polyester and polyamide, as well as cellophane, metals or paper are obtained.
    Type: Grant
    Filed: June 4, 1998
    Date of Patent: June 19, 2001
    Assignee: H. B. Fuller Licensing & Financing, Inc.
    Inventors: George A. Papsin, Thomas E. Rolando, Peter A. Voss
  • Patent number: 6239230
    Abstract: Surface-tested superabsorbent polymer particles obtained by mixing 100 parts by weight of superabsorbent polymer particles with 0.001 to 10 parts by weight of a hydroxyalkylamide, and heating the surface-treated superabsorbent polymer particles to crosslink molecular chains existing at least in the vicinity of the surfaces of the superabsorbent polymer particles is disclosed. Surface crosslinking the superabsorbent polymer particles with a hydroxyalkylamide substantially increases both the rate of liquid absorption and the quantity of liquid absorbed and retained by the superabsorbent particles.
    Type: Grant
    Filed: September 7, 1999
    Date of Patent: May 29, 2001
    Assignee: BASK Aktiengesellschaft
    Inventors: David Eckert, Peter W. Carrico, Michael A. Mitchell
  • Patent number: 6228949
    Abstract: The specification describes various polymers having monomer of formula (I): In formula (I), R1 and R2 are, independently, hydrogen, a C1-C24 alkyl group, an aromatic or heteroaromatic group, a C3-C8 cycloalkyl or C2-C7 heterocycloalkyl group, or a —C(O)R3 group in which R3 is a C1-C24 alkyl group, an aromatic or heteroaromatic group, a C3-C8 cycloalkyl or C2-C7 heterocyclic group; or a —CH2—C(O)—R4 group in which R4 is a C1-C6 alkyl group. At least one of R1 and R2 is a —C(O)R3 group. The polymer may be a homopolymer or a copolymer containing other ethylenically unsaturated monomers. The polymer may be used in a variety of coating compositions such as inks, adhesives, paints and films. Unique monomers where both R1 and R2 are acetoacetyl groups and novel monomers where R2 is an acetoacetyl group are also described.
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: May 8, 2001
    Assignee: Eastman Chemical Company
    Inventors: Dean Charles Webster, Allen Lynn Crain, Chadwick Edward Marlow
  • Patent number: 6228953
    Abstract: A method of preparing a carbamate functional polymer or oligomer is provided. The method comprises: (a) preparing a reaction mixture comprising a lower alkyl carbamate, a hydroxyl functional polymer or oligomer, and an alcohol different from and having a higher boiling point than an alcohol from which the lower alkyl carbamate is derived; and (b) heating the reaction mixture to form a carbamate functional polymer or oligomer. Also provided is a method of preparing a carbamate functional acrylic polymer by preparing a similar reaction mixture using acrylic monomers containing hydroxyl groups or groups that can be converted to hydroxyl groups and heating the reaction mixture in the presence of a free radical initiator and an esterification catalyst.
    Type: Grant
    Filed: August 20, 1999
    Date of Patent: May 8, 2001
    Assignee: PPG Industries,Ohio, Inc.
    Inventors: Steven V. Barancyk, Debra L. Singer
  • Patent number: 6228988
    Abstract: The present invention describes processes for preparing desired synthetic products that comprise a covalently bonded hydroxamic acid group —CONHOH by forming a mixture of a liquid reaction medium and a solid phase reaction product that carries a plurality of moieties of formula (A1) or (B1): where X is a residual, non-hydroxamate partial structure of the desired synthetic product, P1 is hydrogen or an amino-protecting group, P2 is hydrogen or a hydroxyl protecting group, and the bond designated (a) covalently links the moieties (A1) or (B1) to the residue of a solid substrate; by cleaving the bond designated (a) in the resultant mixture; and by separating the resultant liquid reaction phase from the resultant reaction solids to recover the desired synthetic product.
    Type: Grant
    Filed: June 9, 1999
    Date of Patent: May 8, 2001
    Assignee: British Biotech Pharmaceuticals, Ltd.
    Inventors: Christopher David Floyd, Christopher Norman Lewis
  • Patent number: 6225408
    Abstract: An adhesive composition including as principal components: (a) about 10-90% by weight of at least one free radical-polymerizable monomer, (b) about 0-20% by weight of an adhesion promoter, (c) about 10-80% by weight of a primary low molecular weight toughener (or toughening agent) with a weight average molecular weight (Mw) less than about 18,000 or a number average molecular number (Mn) less than about 10,000 and; (d) about 1-15% by weight of an auxiliary high molecular weight toughener (or toughening agent) with a Mw greater than about 18,000 or a Mn greater than about 10,000 based on the total weight of components (a)-(d).
    Type: Grant
    Filed: June 1, 1999
    Date of Patent: May 1, 2001
    Assignee: Lord Corporation
    Inventors: Jian-Ping Huang, Robin F. Righettini, Frances G. Dennis
  • Patent number: 6221976
    Abstract: A shelf-stable water-borne dispersion or solution that cures rapidly and at low temperatures when coated onto a substrate can be prepared with an aqueous-based solution or stable aqueous dispersion of a polymer having a backbone containing pendant silanol groups which are sufficiently neutralized to inhibit silanol condensation.
    Type: Grant
    Filed: January 25, 1999
    Date of Patent: April 24, 2001
    Assignee: The Dow Chemical Company
    Inventors: Mladen Ladika, Gene D. Rose
  • Patent number: 6194516
    Abstract: A method for producing a hydroxyl-terminated (meth) acrylic polymer which comprises converting a halogen atom in a terminal structure of the general formula (1) —CH2—C(R1)(CO2R2)(X)  (1) wherein R1 is hydrogen or methyl, R2 is alkyl containing 1 to 20 carbon atoms, aryl containing 6 to 20 carbon atoms or aralkyl containing 7 to 20 carbon atoms, and X is chlorine, bromine or iodine, of a (meth)acrylic polymer obtained by polymerizing a (meth)acrylic monomer using an organic halide or a halogenated sulfonyl compound as an initiator and, as a catalyst, a metal complex with a central metal selected from the elements belonging to the groups 8, 9, 10 and 11 in the periodic table, into a hydroxyl-containing substituent. The present invention can provide, in an easy and simple manner, a (meth)acrylic polymer which is hydroxyl-terminated at both ends in a high proportion and which has been difficult to produce in the prior art. It can give a cured product with good curing characteristics.
    Type: Grant
    Filed: October 1, 1998
    Date of Patent: February 27, 2001
    Assignee: Kaneka Corporation
    Inventors: Masato Kusakabe, Kenichi Kitano, Yoshiki Nakagawa
  • Patent number: 6194522
    Abstract: A method for crosslinking a polymer composition including an aliphatic polycarbodiimide and a polymer containing at least two sulfur- or phosphorous-containing acid groups such as copolymerized 2-(meth)acrylamido-2-methyl-1-propanesulfonic acid, 3-sulfopropyl(meth)acrylate, 2-sulfoethyl(meth)acrylate or 2-phosphoethyl(meth)acrylate is provided. The method provides the benefits of a crosslinked composition such as solvent resistance without materially affecting film formation.
    Type: Grant
    Filed: January 21, 1999
    Date of Patent: February 27, 2001
    Assignee: Rohm and Haas Company
    Inventor: Ward Thomas Brown
  • Patent number: 6184306
    Abstract: The present invention relates to asymmetrical siloxy compounds of the formula wherein R1, R2 and R3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R4 is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms; and n is an integer of from 1 to 8.
    Type: Grant
    Filed: March 22, 2000
    Date of Patent: February 6, 2001
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Thierry Florent Edme Materne, Giorgio Agostini, Friedrich Visel, Martin Paul Cohen
  • Patent number: 6160057
    Abstract: The specification describes various polymers having monomer of formula (I): ##STR1## In formula (I), R1 and R2 are, independently, hydrogen, a C.sub.1 -C.sub.24 alkyl group, an aromatic or heteroaromatic group, a C.sub.3 -C.sub.8 cycloalkyl or C.sub.2 -C.sub.7 heterocycloalkyl group, or a --C(O)R3 group. Preferably R1 and R2 are both a a --C(O)R3 group where R3 which can the same of different is selected from the group consisting of a C.sub.1 -C.sub.24 alkyl group, an aromatic or heteroaromatic group, a C.sub.3 -C.sub.8 cycloalkyl or C.sub.2 -C.sub.7 heterocyclic group; or a --CH.sub.2 --C(O)--R4 group in which R4 is a C.sub.1 -C.sub.6 alkyl group. At lease one of R1 and R2 is a --C(O)R3 group. The polymer may be a homopolymer or a copolymer containing other ethylenically unsaturated monomers. The polymer may be used in a variety of coating compositions such as inks, adhesives, paints and films.
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: December 12, 2000
    Assignee: Eastman Chemical Company
    Inventors: Dean Charles Webster, Allen Lynn Crain, Chadwick Edward Marlow
  • Patent number: 6114452
    Abstract: Perfluoroelastomer compositions are provided which have excellent high temperature properties. The perfluoroelastomer component of the compositions are copolymers having a plurality of carbonyl-containing functional groups and copolymerized monomer units comprising a perfluoroolefin, a perfluoro(vinyl) ether and a nitrile-containing cure site monomer. The curative component is other than an organotin compound and includes peroxides, ammonium salts, aromatic amino compounds, bisamidrazones, and bisamidoximes.
    Type: Grant
    Filed: June 26, 1998
    Date of Patent: September 5, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Walter Werner Schmiegel
  • Patent number: 6114473
    Abstract: A resin composition for powder coating, which comprises the following components (A), (B) and (C): (A) a carboxyl group-containing resin having a number average molecular weight of from 1,000 to 20,000, an acid value of from 5 to 200 and a glass transition temperature of from 30 to 120.degree. C.; (B) tris(.beta.-methylglycidyl) isocyanurate of formula (1); and (C) as a ring opening polymerization inhibitor, at least one compound selected from the group consisting of amines having in their molecules a bond of formula (2); and onium salts.
    Type: Grant
    Filed: May 28, 1997
    Date of Patent: September 5, 2000
    Assignee: Nissan Chemical Industries, Ltd.
    Inventors: Satoru Miyake, Hisao Ikeda, Motohiko Hidaka, Takeo Moro
  • Patent number: 6099602
    Abstract: A fuel or lubricant composition containing polyisobutene amines and which contains at least one secondary polyisobutene amine of the formula I, ##STR1## in which R denotes a polyisobutene radical containing from 6 to 45 isobutylene units, up to 20% of the isobutylene units being replaceable by n-butylene units, provided that the amount of the secondary polyisobutene amine is larger than the amount of any corresponding primary or tertiary polyisobutene amine which may also be present.
    Type: Grant
    Filed: June 2, 1998
    Date of Patent: August 8, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Roper, Bernhard Geissler, Ernst Langguth, Heinz-Josef Kneuper
  • Patent number: 6100343
    Abstract: A method for improving surface adhesion characteristics of a polymeric substrate and/or virgin polymeric material in which the portion of the surface of the polymeric substrate and/or virgin polymeric material to be treated is contacted with a composition containing at least one oxidizing agent. The oxidizing agent in the composition is present in a kinetically degrading state capable of producing at least one chemical intermediate which is reactive with the polymeric substrate/virgin polymeric material. Contact between the composition containing the oxidizing agent and the polymeric substrate/virgin polymeric material is maintained for an interval sufficient to produce or modify functional groups in the polymeric substrate/virgin polymeric material. The oxidizing agent of choice is a halogenated bivalent oxygen compound. The oxidizing agent is activated by an activator agent containing at least one carboxylic acid group or derivative thereof.
    Type: Grant
    Filed: November 3, 1998
    Date of Patent: August 8, 2000
    Assignee: Beholz Technology, L.L.C.
    Inventor: Lars Guenter Beholz
  • Patent number: 6096832
    Abstract: The present invention relates to asymmetrical siloxy compounds of the formula ##STR1## wherein R.sup.1, R.sup.2 and R.sup.3 are independently selected from the group consisting of alkoxy radicals having from 1 to 8 carbon atoms; R.sup.4 is selected from the group consisting of alkylene groups having from 1 to 15 carbon atoms and arylene and alkyl substituted arylene groups having from 6 to 10 carbon atoms; and n is an integer of from 1 to 8.
    Type: Grant
    Filed: February 18, 1999
    Date of Patent: August 1, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Thierry Florent Edme Materne, Giorgio Agostini, Friedrich Visel, Martin Paul Cohen
  • Patent number: 6093496
    Abstract: This invention concerns a composition comprising a blend of polyolefin with the reaction of a functionalized polyolefin and polyetheramine in which the polyetheramine is grafted into the functionalized polyolefin in a customary mixing apparatus. A process for producing the reaction product of functionalized polypropylene and polyetheramine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts. This invention further includes dyeable polyolefin compositions containing the reaction product of functionalized polyolefin and polyetheramine. Dyeable polyolefin fibers, including polypropylene fibers, are disclosed, which may be made by melt spinning, and which may be employed to make woven and non-woven fabric. The polyolefin employed in the practice of this invention may be a flexible polyolefin.
    Type: Grant
    Filed: May 12, 1998
    Date of Patent: July 25, 2000
    Assignee: Huntsman Petrochemical Corporation
    Inventors: Richard Joseph Gilbert Dominguez, Christopher S. Henkee, Kevin J. Hess, Wheeler C. Crawford, Richard J. Clark, Randall K. Evans, Gerald W. Cummings
  • Patent number: 6093798
    Abstract: The present invention describes solid phase reaction products of a solid substrate carrying a plurality of covalently bound hydroxylamine or protected hydroxylamine groups of formula (A) or (B): ##STR1## where P.sub.1 is hydrogen or an amino protecting group, P.sub.2 is hydrogen or a hydroxyl protecting group, and the bond designated (a) covalently links the formula (A) or (B) to the residue of the solid substrate, and is cleavable under acid conditions or by photolysis. The solid phase reaction products can be used for the synthesis of hydroxamic acid derivatives or a combinatorial library of such compounds.
    Type: Grant
    Filed: June 9, 1999
    Date of Patent: July 25, 2000
    Assignee: British Biotech Pharmaceuticals Limited
    Inventors: Christopher David Floyd, Christopher Norman Lewis
  • Patent number: 6090531
    Abstract: A composition for anti-reflective coating material is disclosed, comprising a polymer compound having repeating units having specific structure, and optionally a melamine, guanamine, urea, phenol, naphthol or hydroxyanthracene compound substituted by at least one group selected from the group consisting of a methylol group and an alkoxymethyl group at two or more positions. The composition for anti-reflective coating material of the present invention is effective for the reduction of adverse effects of reflection by the substrate in a lithographic process using various radiations. A resist pattern formation process which comprises the use of the composition for anti-reflective coating material is also disclosed.
    Type: Grant
    Filed: August 7, 1997
    Date of Patent: July 18, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazuyoshi Mizutani, Hiroshi Yoshimoto
  • Patent number: 6084025
    Abstract: A functionalized polymer prepared by a process comprising the steps of preparing a solution of a cyclic amine compound, an organolithium compound, and from 3 to about 300 equivalents, based upon one equivalent of lithium, of a monomer selected from the group including diene monomers, vinyl aromatic monomers, and mixtures thereof, where the cyclic amine compound is defined by the formula where R.sub.2 is selected from the group consisting of an alkylene, substituted alkylene, oxy- or N-alkylamino-alkylene group having from about 3 to about 16 methylene groups, N is a nitrogen atom, and H is a hydrogen atom, thereby forming a polymerization initiator having the formula where Li is a lithium atom, SOL is a divalent hydrocarbon group having from 3 to about 300 polymerized monomeric units, y is from 0.5 to about 3, and A is a cyclic amine radical derived from the cyclic amine, charging the solution containing (A)Li(SOL)y with from about 0.
    Type: Grant
    Filed: March 15, 1999
    Date of Patent: July 4, 2000
    Assignee: Bridgestone Corporation
    Inventors: Takashi Kitamura, David F. Lawson, Koichi Morita, Yoichi Ozawa
  • Patent number: 6077911
    Abstract: Polymers essentially comprising units of the formula I ##STR1## in which R.sup.1 and R.sup.2 are hydrogen or methyl andR.sup.3 is hydrogen, C.sub.1 -C.sub.18 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl, C.sub.6 -C.sub.10 -aryl or C.sub.6 -C.sub.10 -aryl-C.sub.1 -C.sub.4 -alkyl, it being possible for these radicals, with the exception of the C.sub.1 -C.sub.18 -alkyl radicals, to be up to trisubstituted by radicals selected from the group consisting of C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy and halogen, are prepared by reacting a polymer based on C.sub.1 -C.sub.20 -alkyl esters of acrylic acid, methacrylic acid or mixtures thereof with ammonia or a primary amine in an extruder, by mixing the ammonia or the primary amine by mixing intensively with a melt of the polymer to be reacted, at at most 250.degree. C., before the imidation is carried out, and are used for producing thermoplastic moldings, films or fibers.
    Type: Grant
    Filed: July 27, 1993
    Date of Patent: June 20, 2000
    Assignee: BASF Aktiwngesellschaft
    Inventors: Siegmund Besecke, Andreas Deckers, Juergen Hofmann, Harald Kroeger, Hilmar Ohlig
  • Patent number: 6077913
    Abstract: A method for improving surface adhesion characteristics of a polymer substrate in which the portion of the surface of the polymeric substrate to be treated is contacted with a fluid material containing at least one oxidizing agent. The oxidizing agent in the fluid material is present in a kinetically degrading state capable of producing at least one chemical intermediate which is reactive with the polymeric substrate. Contact between the fluid containing the oxidizing agent and the polymeric substrate is maintained for an interval sufficient to produce or modify functional groups in the polymeric substrate proximate to its surface. The oxidizing agent of choice is a bivalent oxygen compound. The oxidizing agent is activated by an activator agent containing at least one carboxylic acid group or derivative thereof. The activator agent may be present in the fluid upon initial contact with the polymeric substrate or may be added to the fluid subsequent to initial contact with the polymeric substrate.
    Type: Grant
    Filed: March 26, 1998
    Date of Patent: June 20, 2000
    Assignee: Beholz Technology, L.L.C.
    Inventor: Lars Guenter Beholz
  • Patent number: 6040387
    Abstract: Molding compositions MC having a reduced tendency to yellow with thermal stress which consist of a polymer PM containing units of formula I: ##STR1## blending from 0.005-1 wt % of at least one reducing inorganic phosphorus compound IP selected from the group consisting of phosphinic and phosphonic acid and its alkali metal, alkaline-earth metal, aluminum and ammonium salts, wherein the ammonium ion can be substituted with up to four C.sub.1 -C.sub.4 alkyl and/or C.sub.5 -C.sub.8 cycloalkyl groups, with the polymer PM after conclusion of the imidation reaction.
    Type: Grant
    Filed: May 12, 1998
    Date of Patent: March 21, 2000
    Assignee: Roehm GmbH Chemische Fabrik
    Inventors: Klaus Albrecht, Werner Hoess, Hartmut Schikowsky
  • Patent number: 6025450
    Abstract: A functionalized polymer includes a polymer chain carrying at least one functional group selected from alkyl, dialkyl and cycloalkyl amine radicals having the general formula ##STR1## and cyclic amine radicals having the general formula ##STR2## where R.sub.1 is an alkyl, cycloalkyl or aralkyl having from 1 to about 12 carbon atoms, and R.sub.2 is an alkylene, substituted alkylene, oxy- or N-alkylamino-alkylene group having from about 3 to about 16 methylene groups. The invention also provides products based upon such polymers.
    Type: Grant
    Filed: July 9, 1998
    Date of Patent: February 15, 2000
    Assignee: Bridgestone Corporation
    Inventors: David F. Lawson, Mark L. Stayer, Jr., David Saffles, Koichi Morita, Yoichi Ozawa, Ryota Fujio, Thomas A. Antkowiak
  • Patent number: 6020418
    Abstract: Stable, gel-free, water-in-oil microdispersions comprising a continuous phase of an oil and an emulsifier and a discontinuous phase of an aqueous solution of a hydroxamated vinyl polymer are disclosed. Also disclosed is a method for the production of the above-described microdispersions wherein neutralized hydroxylamide and excess base are reacted with a microdispersion of the vinyl polymer.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: February 1, 2000
    Assignee: Cytech Technology Corp.
    Inventors: Howard Ivan Heitner, Roderick Glyn Ryles
  • Patent number: 6013737
    Abstract: A rubber composition comprising 100 parts by weight of a diene rubber ingredient containing an amino group-containing diene rubber, 10 to 120 parts by weight of silica, 0.1 to 15 parts by weight a vulcanizer and 0.1 to 15 parts by weight of a sulfenamide vulcanization accelerator.This rubber composition exhibits excellent heat build-up, tensile property and abrasion resistance, and is suitable for tires and others.
    Type: Grant
    Filed: March 5, 1998
    Date of Patent: January 11, 2000
    Assignee: Nippon Zeon Co., Ltd.
    Inventors: Yukio Takagishi, Masao Nakamura
  • Patent number: 5990238
    Abstract: A polymer includes an ethylene-containing backbone having substituents attached thereto, wherein the substituents include a urethane linked nitrogen-bonded hydrocarbon side chain having about 5 carbon atoms or more in length and a terminal methyl group; and an oxygen linked water solubilizing group. The polymer is particularly useful in a release coating composition and is suitable for forming films from aqueous dispersions thereof, organic solvent dispersions thereof, or mixtures thereof.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: November 23, 1999
    Assignee: 3M Innovative Properties Company
    Inventors: James P. DiZio, Roy Wong, Hildegard M. Schneider
  • Patent number: 5985999
    Abstract: This invention concerns a composition comprising a blend of polyolefin with the reaction of a functionalized polyolefin and polyetheramine in which the polyetheramine is grafted into the functionalized polyolefin in a customary mixing apparatus. A process for producing the reaction product of functionalized polypropylene and polyetheramine by melting with polypropylene in a customary mixing apparatus is also disclosed. Blends of the present invention are advantageously useful to prepare paintable automotive body parts. This invention further includes dyeable polyolefin compositions containing the reaction product of functionalized polyolefin and polyetheramine. Dyeable polyolefin fibers, including polypropylene fibers, are disclosed, which may be made by melt spinning, and which may be employed to make woven and non-woven fabric.
    Type: Grant
    Filed: April 23, 1997
    Date of Patent: November 16, 1999
    Assignee: Huntsman, Petrochemical Corporation
    Inventors: Richard Joseph Gilbert Dominguez, Christopher S. Henkee, Wheeler C. Crawford, Gerald W. Cummings, Kevin John Hess, Richard James Clark, Randall Keith Evans
  • Patent number: 5981660
    Abstract: An isocyanate-curing coating material is disclosed which essentially consists of (A) an agent formed of a hydroxyl group-containing polymer having a weight average molecular weight in the range of 1000-20000 and (B) a polyisocyanate compound as a curing agent containing at least three isocyanate groups in the molecular unit thereof and having a weight average molecular weight in the range of 400-3000 and incorporating (A) the agent and (B) the curing agent in such amounts that the isocyanate groups in (B) the curing agent amounts to 0.5-2 equivalent weights per equivalent weight of the hydroxyl group in (A) the agent. A method for spray coating the isocyanate-curing coating material is also disclosed which comprises the steps of mixing (A) the agent with (B) the curing agent in a coating device, heating the resultant mixture therein to a temperature in the range of 35-80.degree. C., and spraying the hot mixture directly on a given object with the coating device.
    Type: Grant
    Filed: July 16, 1997
    Date of Patent: November 9, 1999
    Assignees: NOF Corporation, Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Shinji Mitsumune, Taichi Okayama, Shinsuke Mochizuki, Akihito Kobayashi
  • Patent number: 5977265
    Abstract: High flow brominated polycarbonates, useful as flame retardant additives for other polymers such as polyesters, are obtained by equilibration of a brominated aromatic polycarbonate such as a tetrabromobisphenol A homo- or copolycarbonate with a di- or polyhydroxy aromatic compound such as bisphenol A, or a diaryl carbonate, and an equilibration catalyst, under conditions such that the weight average molecular weight of the brominated polycarbonate is reduced by at least 35%. Preferred equilibration catalysts are Group I metal carboxylates, such as sodium stearate, and hexaalkylguanidinium salts.
    Type: Grant
    Filed: September 2, 1997
    Date of Patent: November 2, 1999
    Assignee: General Electric Company
    Inventors: Patrick Joseph McCloskey, Gary Charles Davis, David Michel Dardaris, Daniel Joseph Brunelle, Robert Russell Gallucci, Mahari Tjahjadi, David Whalen, Kevin Mitchell Snow
  • Patent number: 5977271
    Abstract: The subject invention provides a thermoset elastomer comprising a crosslinked pseudorandom or substantially random interpolymer of: (a) from 15 to 70 weight percent of at least one .alpha.-olefin, (b) from 30 to 70 weight percent of at least one vinylidene aromatic compound, and (c) from 0 to 15 weight percent of at least one diene. The subject invention further provides a thermoplastic vulcanizate comprising the thermoset elastomers of the invention as provided in a thermoplastic polyolefin matrix. The subject invention further provides processes for preparing the inventive thermoset elastomers and thermoplastic vulcanizates, as well as parts fabricated therefrom. The inventive materials have a superior balance of properties, as compared to EPM and EPDM based materials. The subject invention also pertains to foams and methods for their preparation.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: November 2, 1999
    Assignee: The Dow Chemical Company
    Inventors: Kevin W. McKay, Francis J. Timmers, Edwin R. Feig, Thoi H. Ho, Seema V. Karande
  • Patent number: 5976615
    Abstract: A curable coating composition is described comprising a carbamate functional material and a crosslinking agent, reactive with the carbamate group. The composition further comprises a third component that is a mixture of catalysts including a phosphorus containing acid or acid derivative and other acid catalysts. Coatings prepared with this coating composition can be cured and coated with additional coating(s), providing good intercoat adhesion to the subsequent coating.
    Type: Grant
    Filed: July 9, 1997
    Date of Patent: November 2, 1999
    Assignee: BASF Corporation
    Inventors: Gregory G. Menovcik, John G. Partyka, Aimee R. Barach, Sanjay Mehta
  • Patent number: 5973076
    Abstract: Disclosed are a polybutene-1 resin composition comprising a polybutene-1 resin and a Form-II to Form-I crystal transformation accelerator, and a method of accelerating the Form-II to Form-I crystal transformation comprising molding the polybutene-1 resin composition and allowing the molded product to stand at about 0 to 50.degree. C., the crystal transformation accelerator being an amide compound.
    Type: Grant
    Filed: November 29, 1995
    Date of Patent: October 26, 1999
    Assignee: New Japan Chemical Co., Ltd.
    Inventors: Masafumi Yoshimura, Naoki Ikeda, Kazuaki Mizoguchi, Hiroshi Kitagawa
  • Patent number: 5955548
    Abstract: Substituted cyanoenamines of the formula I ##STR1## wherein Z, R.sup.1, R.sup.2 and R.sup.3 are defined in the description, compositions thereof and methods for preparing the compounds are disclosed. The compounds are useful in the treatment of diseases of the central nervous system, the cardiovascular system, the pulmonary system, the gastrointestinal system and the endocrinologic system.
    Type: Grant
    Filed: May 4, 1998
    Date of Patent: September 21, 1999
    Assignee: Novo Nordisk A/S
    Inventors: Florenzio Zaragonza Dorwald, John Bondo Hansen
  • Patent number: 5936043
    Abstract: A crosslinkable composition including an aliphatic polycarbodliimide and a polymer containing copolymerized 2-(meth)acrylamido-2-methyl-1-propanesulfonic acid, 3-sulfopropyl (meth)acrylate, 2-sulfoethyl(meth)acrylate, or 2-phosphoethyl (meth)acrylate and having an acid number of from 5 to 100 is provided. The composition provides the benefits of a crosslinked composition such as solvent resistance without materially affecting film formation.
    Type: Grant
    Filed: November 25, 1996
    Date of Patent: August 10, 1999
    Assignee: Rohm and Haas Company
    Inventor: Ward Thomas Brown
  • Patent number: 5936029
    Abstract: The present invention provides a method of anionic synthesis of stable macrocyclic polymers that are compounded to form vulcanizable elastomeric compounds exhibiting reduced hysteresis properties. Cyclic organometallic compounds containing divalent metal atoms of Groups IIA and IIB of the Periodic System are employed as initiators of anionic polymerization of conjugated diene, vinyl aromatic and/or triene monomers. Coupling of the living ends of the resulting macrocyclic polymers or copolymers with a coupling agent or a coupling agent that is also a functionalizing agent results in stable macrocyclic polymers with improved hysteresis properties.
    Type: Grant
    Filed: September 29, 1997
    Date of Patent: August 10, 1999
    Assignee: Bridgestone Corporation
    Inventor: James E. Hall
  • Patent number: 5936042
    Abstract: A process for producing an aqueous dispersion of a water-soluble cationic polymer which process comprises modifying a polymer obtained by homopolymerization of an N-vinylcarboxylic acid amide or copolymerization of an N-vinylcarboxylic acid amide and a vinyl monomer copolymerizable with the N-vinyl carboxylic acid amide with an acid in an aqueous medium in the presence of a nitrate ion. The process can produce an aqueous dispersion of a water-soluble cationic polymer having a high molecular weight from the above water-insoluble polymer easily in a single step without causing adverse effects on the handling property while the fluidity is maintained.
    Type: Grant
    Filed: June 9, 1997
    Date of Patent: August 10, 1999
    Assignees: Kurita Water Industries Ltd., Mitsubishi Chemical Corporation
    Inventors: Shouji Matsushima, Katsutoshi Kubo, Masayuki Murano, Satoko Shimada
  • Patent number: 5932695
    Abstract: This invention is direct to a solid phase reaction product of a solid substrate carrying a plurality of covalently bound hydroxylamine or protected hydroxylamine groups. The solid solid phase reaction product may be used for the synthesis of hydroxamic acid derivatives or a combinatorial library of such compounds.
    Type: Grant
    Filed: March 24, 1997
    Date of Patent: August 3, 1999
    Assignee: British Biotech Pharmaceuticals Ltd.
    Inventors: Christopher David Floyd, Christopher Norman Lewis
  • Patent number: 5925409
    Abstract: A method of lining a surface of a substrate comprises providing a reactive mixture which comprises (1) a resin containing active hydrogens; (2) a polycarbodiimide; and (3) an organic diluent; reacting the resin containing active hydrogens and the polycarbodiimide to chemically bind the resin and the polycarbodiimide; applying the chemically bound resin and polycarbodiimide to the surface of the substrate; and curing the chemically bound resin and polycarbodiimide in the presence of an initiator to form a cured resin material which lines the surface of the substrate.
    Type: Grant
    Filed: August 27, 1997
    Date of Patent: July 20, 1999
    Assignee: Reichhold, Inc.
    Inventor: Hildeberto Nava
  • Patent number: 5925715
    Abstract: A dental cement system containing a photocurable ionomer, reactive powder and water undergoes both a conventional setting reaction and a photocuring reaction.The cement system can provide a long working time and can be cured on demand by exposure to an appropriate source of radiant energy. The surface of the cement cured in this manner is then hard enough to allow subsequent clinical procedures to be performed, while the ongoing chemical-cure "setting" reaction hardens the remainder of the cement.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: July 20, 1999
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Sumita B. Mitra
  • Patent number: 5916961
    Abstract: The reduction of hysteresis in a silica-filled, vulcanized elastomeric compound is produced by mixing diene monomer and optionally monovinyl aromatic monomer with a lithium amine initiator and, optionally, a modifier; effecting polymerization conditions; terminating polymerization with an amino group producing terminator to form an amine functionalized diene elastomer; compounding the amine functionalized diene elastomer with an amorphous silica filler and a vulcanization agent; and, effecting vulcanization. A pneumatic tire tread stock incorporating the vulcanized elastomer compound exhibits decreased rolling resistance in the tire.
    Type: Grant
    Filed: July 11, 1997
    Date of Patent: June 29, 1999
    Assignee: Bridgestone Corporation
    Inventors: William L. Hergenrother, Thomas J. Lynch
  • Patent number: 5891960
    Abstract: Coating compositions comprised of a film forming polymer which is the reaction product of (a) a compound containing pendant and/or terminal hydroxyl or epoxy functional groups and (b) citric acid or citric acid anhydride. The coating compositions have enhanced adhesion to galvanized and galvanealed steel substrates without the use of a chrome containing wash primer.
    Type: Grant
    Filed: September 12, 1997
    Date of Patent: April 6, 1999
    Assignee: PPG Industries, Inc.
    Inventors: James A. Claar, Karl F. Schimmel, Shanti Swarup, Bruce A. Connelly
  • Patent number: 5891956
    Abstract: Water-soluble polymers including functionalization from the group of amino groups, carboxylic acid groups, phosphonic acid groups, phosphonic ester groups, acylpyrazolone groups, hydroxamic acid groups, aza crown ether groups, oxy crown ethers groups, guanidinium groups, amide groups, ester groups, aminodicarboxylic groups, permethylated polyvinylpyridine groups, permethylated amine groups, mercaptosuccinic acid groups, alkyl thiol groups, and N-alkylthiourea groups are disclosed.
    Type: Grant
    Filed: May 30, 1995
    Date of Patent: April 6, 1999
    Assignee: The Regents of the University of California, Office of Technology Transfer
    Inventors: Barbara F. Smith, Thomas W. Robison, Joel W. Gohdes
  • Patent number: 5886104
    Abstract: A solid support for the solid-phase synthesis of peptides or proteins in high yield and in high purity, suited both to the synthesis of a single peptide or protein and to the parallel and substantially simultaneous synthesis of a plurality thereof, is based on a cross-linked polyolefin, especially polyethylene, substrate, the cross-linking having been obtained by irradiation with high energy electrons or .gamma. radiation or treatment with organic peroxide such as benzoyl peroxide, to which substrate are grafted polymer chains such as polystyrene chains which are functionalized with a chemical functionality facilitating the formation of an anchoring linkage between the polymer moiety and another chemical species. The solid support is also suited for use in solid-phase biosystems, notably bioassays, such as immunoassays, DNA hybridization assays or PCR amplification.
    Type: Grant
    Filed: December 18, 1995
    Date of Patent: March 23, 1999
    Assignee: Forskniingscenter Riso
    Inventors: Walther Batsberg Pedersen, Kristoffer Almdal, Lars Winther, Rolf Henrik Berg
  • Patent number: 5886854
    Abstract: An improved disk drive system using a non-ferrofluid conductive lubricant is disclosed. In the disk drive system, there is a plurality of critically spaced magnetic disks rotated by a disk motor. A spindle shaft, which is retained by the spindle sleeve, couples to the disk motor and to the plurality of magnetic disks for rotation. The spindle shaft and spindle sleeve uses a bearing, which is lubricated by a non-ferrofluid conductive lubricant. The lubricant is used to prevent electrostatic charge build up during operation of the disk drive system. The lubricant may be either a non-polar oil or a ball bearing grease and further having either a metal caged fullerenes compound, STADIS-450, ASA-3, or Polyfloe 130. One particular type of lubricant is an emeraldine salt of polyanilin produced according to the steps of first reacting a solution of HCL and ammonium persulfate into a solution of HCL and analine to form a polymer.
    Type: Grant
    Filed: July 9, 1996
    Date of Patent: March 23, 1999
    Assignee: International Business Machines Corporation
    Inventors: Arthur Fred Diaz, Robert D. Johnson, Thomas Edward Karis, Holavanahally S. Nagaraj, My Thanh Nguyen
  • Patent number: 5880208
    Abstract: The invention provides a physiologically acceptable polymer comprising a backbone to which are attached guanidino groups, the polymer having a minimum molecular weight of 10,000. The invention also extends to foodstuffs and pharmaceutical compositions comprising the physiologically acceptable polymer. Such foodstuffs and compositions are of value in controlling phosphate levels in the body.
    Type: Grant
    Filed: August 28, 1997
    Date of Patent: March 9, 1999
    Assignee: BTG International Limited
    Inventors: Robert Charles Hider, Anthony Canas-Rodriguez
  • Patent number: 5877225
    Abstract: A method of reducing the volume of a mixture of filter fibers and a powder-form ion-exchange resin, produces a waste product that is particularly suitable for ultimate disposal. A solvent which dissolves the filter fibers is added to the mixture and a mixture which is thus formed is first dried and then given an additional heat treatment.
    Type: Grant
    Filed: December 16, 1996
    Date of Patent: March 2, 1999
    Assignee: Siemens Aktiengesellschaft
    Inventors: Klaus Blinn, Karl-Heinz Kleinschroth, Dietmar Bege
  • Patent number: 5877261
    Abstract: The use of isocyanates which are free from blocking agent for the chemical/thermal crosslinking of hot-melt pressure-sensitive acrylate adhesives (hot-melts).
    Type: Grant
    Filed: September 4, 1997
    Date of Patent: March 2, 1999
    Assignee: Beiersdorf AG
    Inventors: Christian Harder, Axel Burmeister, Christiop Nagel, Wolfgang Schacht