Mixed With -o-c(=o)-o-, Hal-c(=o)-o-, Or Hal-c(=o)-hal Containing Reactant Or Polymer Derived Therefrom Patents (Class 525/394)
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Patent number: 11597827Abstract: To provide a resin composition, a pellet, a composite molded article, a method for manufacturing a composite molded article and a tank, all capable of enabling tight joining and integration of the polyacetal resin molded article and the polyethylene resin molded article, and of suppressing formaldehyde emission and occurrence of mold deposit. The resin composition contains a resin ingredient and melamine, the resin ingredient containing a polyacetal resin and a maleic anhydride-modified polyethylene resin, the polyacetal resin and the maleic anhydride-modified polyethylene resin following a mass proportion of (20 to 49):(80 to 51), and molar concentration of the maleic anhydride group capable of reacting with amino group of melamine contained in the resin composition being 5 to 25 ?mol/g.Type: GrantFiled: August 28, 2019Date of Patent: March 7, 2023Assignees: MITSUBISHI ENGINEERING-PLASTICS CORPORATION, JAPAN POLYETHYLENE CORPORATIONInventors: Kunihiko Fujimoto, Kei Takahashi, Ritsuya Matsumoto
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Patent number: 10759904Abstract: The present invention relates to a method for preparing poly(carbonate-etherimide) compound comprising polycarbonate segment as shown in the structure (A) and polyetherimide segment as shown in the structure (B). Said method does not contain a highly toxic phosgene in its operation, can be performed easily, and can be operated at not high temperature. wherein R1 represents aromatic with 6 to 30 carbon atoms or, optionally said aromatic is bonded with heteroatom; R2 represents aromatic with 6 to 30 carbon atoms or, optionally said aromatic is bonded with heteroatom; m is an integer from 1 to 15; and n is an integer from 1 to 10.Type: GrantFiled: November 14, 2016Date of Patent: September 1, 2020Assignee: PTT GLOBAL CHEMICAL PUBLIC COMPANY LIMITEDInventors: Supakanok Thongyai, Papapida Pornsuriyasak, Suchada Tang-Amornsuksan, Sarawut Lunvongsa, Montira Uprijit, Siriwanna Ounkaew
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Patent number: 10358517Abstract: An amphiphilic block copolymer comprises a poly(phenylene ether) block or a poly(phenylene ether) copolymer block and a hydrophilic block or graft. A method of making the amphiphilic block copolymer comprises polymerization of a hydrophilic ethylenically unsaturated monomer in the presence of poly(phenylene ether) or a poly(phenylene ether) copolymer to make the amphiphilic block copolymer. A porous asymmetric membrane comprises a poly(phenylene ether) or poly(phenylene ether) copolymer, and the amphiphilic block copolymer comprising a poly(phenylene ether) block or a poly(phenylene ether) copolymer block, and a hydrophilic block or graft. The porous asymmetric membrane is made by phase-inversion of a dope solution of the poly(phenylene ether) or poly(phenylene ether) copolymer and the amphiphilic block copolymer in a coagulation bath.Type: GrantFiled: April 30, 2015Date of Patent: July 23, 2019Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Albin Peter Berzinis, Pooja Bajaj, Rachel Elizabeth Halbfinger, Matias Bikel
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Patent number: 10241427Abstract: A polycarbonate copolymer includes a repeating unit A represented by a formula (1) below, chain ends of the PC copolymer being terminated by a monovalent aromatic group or a monovalent fluorine-containing aliphatic group. In the above formula (1), R1 is a hydrogen atom or an alkyl group having 1 to 2 carbon atoms; an average repeating number n is in a range from 6 to 40 and L is an integer of 1 to 4; and when an aromatic ring is substituted by two or more of R1 (L?2), the two or more of R1 are the same or different from each other.Type: GrantFiled: May 15, 2015Date of Patent: March 26, 2019Assignee: IDEMITSU KOSAN CO., LTD.Inventor: Kengo Hirata
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Patent number: 9441106Abstract: In an embodiment, a photovoltaic module, comprises a transparent superstrate; a backsheet, wherein the backsheet comprises a core layer comprising a core composition formed from a first polycarbonate comprising dimethyl bisphenol cyclohexane carbonate repeat units and bishpenol-A, wherein the first polycarbonate has the structure wherein the dimethyl bisphenol cyclohexane carbonate repeat units are present in an amount of 10 wt. % to 50 wt. %, based on the total repeat units in the core composition; and a second polycarbonate selected from the group consisting of a bisphenol-A polycarbonate homopolymer, a polyphthalate carbonate copolymer, a polycarbonate copolymer comprising 2-phenyl-3,3-bis(4-hydroxyphenyl) phthalimidine carbonate and bisphenol-A carbonate repeat units, a polycarbonate copolymer comprising bisphenol-A carbonate and tetrabromobisphenol A carbonate repeat units, and combinations comprising at least one of the foregoing; and a photovoltaic cell between the superstrate and the backsheet.Type: GrantFiled: November 11, 2011Date of Patent: September 13, 2016Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Jian Zhou, Andries Jakobus Petrus van Zyl, Vandita Pai-Paranjape, Glen Robert Tryson, Matthew Frank Niemeyer
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Patent number: 9284450Abstract: The polycarbonate resin composition includes: a polycarbonate component, which includes an aromatic polycarbonate resin and a copolymerized polycarbonate resin including a repeat unit represented by Formula 1 and a repeat unit represented by Formula 2; and a flame retardant, and has a scratch width of about 310 ?m or less as measured by Ball-type Scratch Profile (BSP) test; a pencil hardness rating of F or higher; a flame retardancy level of V-0 or higher as measured on a 2.0 mm thick specimen according to UL94; and a transmittance of about 80% or more as measured in accordance with ASTM D1003. The polycarbonate resin composition can exhibit excellent properties in terms of scratch resistance, flame retardancy and transparency. wherein R1 and R2 are the same or different and are each independently substituted or unsubstituted C1 to C6 alkyl, and a and b are the same or different and are each independently an integer from 1 to 4.Type: GrantFiled: October 3, 2013Date of Patent: March 15, 2016Assignee: Cheil Industries Inc.Inventors: Jong Chan Hur, Jun Ho Chi, Dong Geun Lee, Woo Suk Chei
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Patent number: 8962756Abstract: At least two or more components of thermoplastic resins are compounded by chaotic mixing to form a polymer alloy with a sophisticatedly controlled dispersed phase structure. In the polymer alloy, a dispersed phase having a non-periodic structure with a correlation length of 0.001 ?m to 0.5 ?m and having a compactness (C) of 0.05?(C)?0.8, wherein the compactness (C) can form a molded product that also has transparency while maintaining the original good heat resistance or mechanical properties of the resins blended.Type: GrantFiled: July 15, 2010Date of Patent: February 24, 2015Assignee: Toray Industries, Inc.Inventors: Sadayuki Kobayashi, Shinichiro Ochiai
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Patent number: 8648155Abstract: The present description discloses a polymeric composition which is a melt-processed alloy comprised of (a) a polyarylene sulfide resin, (b) a polyaryl-ether-ketone resin, and a reactive compound which results in (c) a graft copolymer of the polyarylene sulfide resin and/or the polyaryl-ether-ketone resin in addition to the starting resins. Exemplary melt-processed polymeric compositions can be made by reacting an alkoxy silane with the polyarylene sulfide resin and/or the polyaryl-ether-ketone resin to produce a graft copolymer of a portion of one or both of the resins, sufficient to render the composition uniform and homogeneous. It is normally preferred for the exemplary organosilane compound, to be an amino silane. The subject invention further reveals an insulated wire comprising (1) an electrical conductor and (2) a layer of the melt-processed alloy composition; and fiber reinforced composites comprising fibers substantially fully impregnated with the alloy polymeric composition.Type: GrantFiled: April 27, 2012Date of Patent: February 11, 2014Assignee: Ticona LLCInventors: Manoj Ajbani, Andrew Auerbach, Ke Feng
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Patent number: 8586183Abstract: A laser composition comprises a combination of: (a) from more than 45 to less than 94 weight percent of a crystalline or semi-crystalline thermoplastic polyester component selected from poly(butylene terephthalate), poly(ethylene terephthalate), poly(butylene terephthalate) copolymers poly(ethylene terephthalate) copolymers, and combinations thereof; (b) from greater than 6 to less than 25 weight percent of an amorphous thermoplastic poly(ester) copolymer, poly(ester-carbonate), or combination thereof; (c) optionally, from 1 to 30 weight percent of a filler; and (d) optionally, from 0.01 to 5 weight percent of an antioxidant, mold release agent, colorant, stabilizer, or a combination thereof; wherein an article having a 2 mm thickness and molded from the composition has (i) a near infrared transmission at 960 nanometers of greater than 30 percent and (ii) a Vicat softening temperature of at least 170° C.Type: GrantFiled: January 13, 2011Date of Patent: November 19, 2013Assignee: Sabic Innovative Plastics IP B.V.Inventors: Tony Farrell, Johannes Hubertus G. M. Lohmeijer
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Publication number: 20130237648Abstract: A poly(phenylene ether)-poly(hydroxy ether) block copolymer is used to compatibilize blends of polar polymers and non-polar polymers. The resulting compatibilized blends exhibit physical property improvements relative to blends without a compatibilizer and blends with a poly(hydroxy ether).Type: ApplicationFiled: March 8, 2012Publication date: September 12, 2013Inventor: Edward Norman Peters
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Publication number: 20130172471Abstract: Disclosed herein is a biphenyl polyphosphonate. The biphenyl polyphosphonate is represented by Formula 1: wherein R is hydrogen, substituted or unsubstituted C1-C5 alkyl, substituted or unsubstituted C2-C5 alkenyl, substituted or unsubstituted C5-C6 cycloalkyl, substituted or unsubstituted C5-C6 cycloalkenyl, substituted or unsubstituted C6-C20 aryl, or substituted or unsubstituted C6-C20 aryloxy, R1 and R2 are the same or different and are each independently substituted or unsubstituted C1-C6 alkyl, substituted or unsubstituted C5-C6 cycloalkyl, substituted or unsubstituted C6-C12 aryl, or halogen, a and b are the same or different and are each independently an integer from about 0 to about 4, and n is an integer from about 4 to about 500.Type: ApplicationFiled: October 16, 2012Publication date: July 4, 2013Applicant: CHEIL INDUSTRIES INC.Inventor: Cheil Industries Inc.
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Patent number: 8470934Abstract: The present invention relates to polycarbonate compositions having improved surface hardness, processes for the preparation thereof and the use thereof for the production of blends, shaped articles and extrudates.Type: GrantFiled: February 28, 2011Date of Patent: June 25, 2013Assignee: Bayer MaterialScience AGInventors: Helmut-Werner Heuer, Rolf Wehrmann
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Publication number: 20130158147Abstract: Disclosed are random copoly(phosphonate carbonate)s with the high molecular weight and narrow molecular weight distribution exhibiting a superior combination of properties compared to prior art.Type: ApplicationFiled: February 11, 2013Publication date: June 20, 2013Applicants: BAYER MATERIAL SCIENCE AG, FRX POLYMERS, INC.Inventors: FRX Polymers, Inc., Bayer Material Science AG
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Publication number: 20130118581Abstract: In an embodiment, a photovoltaic module, comprises a transparent superstrate; a backsheet, wherein the backsheet comprises a core layer comprising a core composition formed from a first polycarbonate comprising dimethyl bisphenol cyclohexane carbonate repeat units and bishpenol-A, wherein the first polycarbonate has the structure wherein the dimethyl bisphenol cyclohexane carbonate repeat units are present in an amount of 10 wt. % to 50 wt. %, based on the total repeat units in the core composition; and a second polycarbonate selected from the group consisting of a bisphenol-A polycarbonate homopolymer, a polyphthalate carbonate copolymer, a polycarbonate copolymer comprising 2-phenyl-3,3-bis(4-hydroxyphenyl) phthalimidine carbonate and bisphenol-A carbonate repeat units, a polycarbonate copolymer comprising bisphenol-A carbonate and tetrabromobisphenol A carbonate repeat units, and combinations comprising at least one of the foregoing; and a photovoltaic cell between the superstrate and the backsheet.Type: ApplicationFiled: November 11, 2011Publication date: May 16, 2013Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: Jian Zhou, Andries Jakobus Petrus van Zyl, Vandita Pai-Paranjape, Glen Robert Tryson, Matthew Frank Niemeyer
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Patent number: 8329852Abstract: The present invention relates to copolycarbonates having improved surface hardness, processes for the preparation thereof and the use thereof for the production of blends, shaped articles and extrudates.Type: GrantFiled: November 14, 2009Date of Patent: December 11, 2012Assignee: Bayer MaterialScience AGInventors: Helmut-Werner Heuer, Rolf Wehrmann, Alexander Karbach
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Patent number: 8273431Abstract: A polyamide resin composition contains a resin component containing at least a polyamide (X) and a fatty acid metallic salt having from 10 to 50 carbon atoms, and contains arbitrarily an additive (A) and/or an additive (B). The polyamide (X) is obtained through melt polycondensation of a diamine component containing 70% by mol or more of m-xylylenediamine and a dicarboxylic acid component containing 70% by mol or more of an ?,?-linear aliphatic dicarboxylic acid. The additive (A) is at least one compound selected from the group consisting of a diamide compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diamine having from 2 to 10 carbon atoms, a diester compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diol having from 2 to 10 carbon atoms, and a surfactant, and the additive (B) is at least one compound selected from the group consisting of a metallic hydroxide, a metallic acetate salt, a metallic alkoxide, a metallic carbonate salt and a fatty acid.Type: GrantFiled: May 31, 2007Date of Patent: September 25, 2012Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Ryoji Otaki, Jun Mitadera, Tomonori Kato, Tomomichi Kanda
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Patent number: 8227556Abstract: A thermoplastic composition comprising recovered poly(arylene ether), less than or equal to 0.1 weight percent based on the total weight of the thermoplastic composition of a second recovered thermoplastic that gives off greater than or equal to 10 percent by mass of volatiles at a processing temperature for the thermoplastic composition; 0.025 to 4.0 weight percent, based on the total weight of the thermoplastic composition, of a third recovered thermoplastic selected from the group consisting of polyolefin, acrylonitrile-butadiene-styrene, polycarbonate, polycarbonate/acrylonitrile-butadiene-styrene blend, polymethyl methacrylate, polyamide, polyester, polycarbonate/polyester blend and combinations of two or more of the foregoing third recovered thermoplastics, wherein combinations of two or more of the foregoing third recovered thermoplastics are present in an amount of less than or equal to 10 weight percent, based on the total weight of the thermoplastic composition; and an optional virgin thermoplastic.Type: GrantFiled: June 21, 2011Date of Patent: July 24, 2012Assignee: Sabic Innovative Plastics IP B.V.Inventors: Allen Wai-Yee Ko, Michael L. Todt
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Publication number: 20120158127Abstract: Absorbable polyurethanes, polyamides and polyester urethanes prepared from at least one compound selected from: or the corresponding diamines or diisocyanates thereof, wherein each X independently represents —CH2COO—, —CH(CH3)COO—, —CH2CH2OCH2COO—, —CH2CH2CH2CH2CH2COO—, —(CH2)yCOO— where y is 2 to 4 or 6 to 24, or —(CH2CH2O)z?CH2COO— where z? is 2 to 24; each Y represents —COCH2O—, —COCH(CH3)O—, —COCH2OCH2CH2O—, —COCH2CH2CH2CH2CH2O—, —CO(CH2)mO— where m is 2 to 4 or 6 to 24, or —COCH2O(CH2CH2O)n— where n is 2 to 24; R? is hydrogen, benzyl or straight-chained or branched alkyl; p is 1 to 4; and Rn represents one or more members selected from H, alkoxy, benzyloxy, aldehyde, halogen, carboxylic acid and —NO2, which is attached directly to an aromatic ring or attached through an aliphatic chain. Absorbable polymers prepared from these compounds are useful for drug delivery, tissue engineering, tissue adhesives, adhesion prevention and other implantable medical devices.Type: ApplicationFiled: February 22, 2012Publication date: June 21, 2012Applicant: BEZWADA BIOMEDICAL, LLCInventor: Rao S. Bezwada
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Patent number: 8168732Abstract: The present description discloses a polymeric composition which is a melt-processed alloy comprised of (a) a polyarylene sulfide resin, (b) a polyaryl-ether-ketone resin, and a reactive compound which results in (c) a graft copolymer of the polyarylene sulfide resin and/or the polyaryl-ether-ketone resin in addition to the starting resins. Exemplary melt-processed polymeric compositions can be made by reacting an alkoxy silane with the polyarylene sulfide resin and/or the polyaryl-ether-ketone resin to produce a graft copolymer of a portion of one or both of the resins, sufficient to render the composition uniform and homogeneous. It is normally preferred for the exemplary organosilane compound, to be an amino silane. The subject invention further reveals an insulated wire comprising (1) an electrical conductor and (2) a layer of the melt-processed alloy composition; and fiber reinforced composites comprising fibers substantially fully impregnated with the alloy polymeric composition.Type: GrantFiled: April 18, 2008Date of Patent: May 1, 2012Assignee: Ticona LLCInventors: Manoj Ajbani, Andrew Auerbach, Ke Feng
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Patent number: 8142899Abstract: To provide a heat-resistant resin composition which has excellent heat resistance, does not show a reduced mechanical strength such as flexural strength even after being passed rough a reflow furnace and heat-treated under high temperature conditions, and also has an excellent flame retardancy; a production method of the heat-resistant resin composition; a heat-resistant resin-molded article; and a surface mount electronic component. The heat-resistant resin composition includes a polyarylene sulfide resin (A) and an aromatic polyamide (B) having terephthalic acid amide as an essential structural unit at a former/latter ratio of 70/30 to 95/5 by mass. In a molded article composed of the heat-resistant resin composition, the average diameter of holes formed by etching a broken-out section of the molded article with an organic solvent is 0.1 to 1.0 ?m, where the broken-out section is observed on a scanning electron microscope (2,500 times).Type: GrantFiled: December 26, 2006Date of Patent: March 27, 2012Assignee: DIC CorporationInventor: Yasuyuki Yoshino
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Patent number: 8119110Abstract: Disclosed herein are a cosmetic composition comprising a cosmetically acceptable organic liquid medium, at least one non-volatile silicone oil and at least one film-forming block ethylenic polymer and use of the composition for making up keratin materials, such as the skin.Type: GrantFiled: September 27, 2004Date of Patent: February 21, 2012Assignee: L'Oreal S.A.Inventors: Xavier Blin, Véronique Ferrari
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Publication number: 20110251325Abstract: A thermoplastic composition comprising recovered poly(arylene ether), less than or equal to 0.1 weight percent based on the total weight of the thermoplastic composition of a second recovered thermoplastic that gives off greater than or equal to 10 percent by mass of volatiles at a processing temperature for the thermoplastic composition; 0.025 to 4.0 weight percent, based on the total weight of the thermoplastic composition, of a third recovered thermoplastic selected from the group consisting of polyolefin, acrylonitrile-butadiene-styrene, polycarbonate, polycarbonate/acrylonitrile-butadiene-styrene blend, polymethyl methacrylate, polyamide, polyester, polycarbonate/polyester blend and combinations of two or more of the foregoing third recovered thermoplastics, wherein combinations of two or more of the foregoing third recovered thermoplastics are present in an amount of less than or equal to 10 weight percent, based on the total weight of the thermoplastic composition; and an optional virgin thermoplastic.Type: ApplicationFiled: June 21, 2011Publication date: October 13, 2011Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: Allen Wai-Yee Ko, Michael L. Todt
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POLYCARBONATE-POLY(ETHER-ESTER) COPOLYMER COMPOSITION, METHOD OF MANUFACTURE, AND ARTICLES THEREFROM
Publication number: 20110155975Abstract: A composition comprising: a polycarbonate comprising units derived from a bisphenol cyclohexylidene of the formula: wherein Rc1 and Rd1 are each independently C1-12 alkyl, Rc2 and Rd2 are each independently hydrogen or C1-12 alkyl, Rg is C1-12 alkyl or halogen, and t is 0 to 10; and a poly(ether-ester) copolymer comprising 40 to 60 wt % of polyester hard block units derived from a C6-C24 aromatic dicarboxylic acid or a C6-C24 alicyclic dicarboxylic acid and at least one glycol component, wherein when the C6-C24 aromatic dicarboxylic acid comprises terephthalic acid, isophthalic acid groups are present in an amount from 0 to 30 mole %, based on the total moles of isophthalic acid groups and terephthalic acid groups in the hard block units, and 40 to 60 wt % of polyether soft block units derived from poly(oxytetramethylene) glycol, wherein the molecular weight of the poly(oxytetramethylene) glycol groups is 300 to 1800 Daltons.Type: ApplicationFiled: December 30, 2009Publication date: June 30, 2011Inventors: Shreyas Chakravarti, Christopher Luke Hein, Peter Hendrikus Theodorus Vollenberg -
Patent number: 7964675Abstract: A thermoplastic composition comprising recovered poly(arylene ether), less than or equal to 0.1 weight percent based on the total weight of the thermoplastic composition of a second recovered thermoplastic that gives off greater than or equal to 10 percent by mass of volatiles at a processing temperature for the thermoplastic composition; 0.025 to 4.0 weight percent, based on the total weight of the thermoplastic composition, of a third recovered thermoplastic selected from the group consisting of polyolefin, acrylonitrile-butadiene-styrene, polycarbonate, polycarbonate/acrylonitrile-butadiene-styrene blend, polymethyl methacrylate, polyamide, polyester, polycarbonate/polyester blend and combinations of two or more of the foregoing third recovered thermoplastics, wherein combinations of two or more of the foregoing third recovered thermoplastics are present in an amount of less than or equal to 10 weight percent, based on the total weight of the thermoplastic composition; and an optional virgin thermoplastic.Type: GrantFiled: January 10, 2005Date of Patent: June 21, 2011Assignee: Sabic Innovative Plastics IP B.V.Inventors: Allen Wai-Yee Ko, Michael L. Todt
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Publication number: 20110139496Abstract: A resin composition which is low in a roughness of an insulating layer surface and capable of forming thereon a plated conductor layer having a sufficient peel strength in a wet roughing step and which is excellent in dielectric characteristics and a coefficient of thermal expansion, is disclosed. The resin composition contains a cyanate ester resin and a specified epoxy resin.Type: ApplicationFiled: December 14, 2010Publication date: June 16, 2011Applicant: AJINOMOTO CO., INC.Inventor: Shigeo NAKAMURA
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Publication number: 20110144284Abstract: The present invention relates to polycarbonate compositions having improved surface hardness, processes for the preparation thereof and the use thereof for the production of blends, shaped articles and extrudates.Type: ApplicationFiled: February 28, 2011Publication date: June 16, 2011Applicant: Bayer MaterialScience AGInventors: Helmut-Werner Heuer, Rolf Wehrmann
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Patent number: 7781535Abstract: An acidic group-containing polymer which has an acidic group such as sulfonic acid group, phosphoric acid group, and phosphonic acid group, and a proton acceptor which has a boiling point at 1 atmosphere higher than 100° C. and which functions as a medium for conducting proton dissociated from the acidic group are retained in pores of a porous member. Preferred examples of the proton acceptor include a salt structure composed of an anion and a cation derived from a basic organic compound, a basic organic compound, and a dissociation-facilitating polymer which facilitates dissociation of proton. Any one of the acidic group-containing polymer and the proton acceptor may be retained first, or both may be retained simultaneously.Type: GrantFiled: March 3, 2005Date of Patent: August 24, 2010Assignee: Honda Motor Co., Ltd.Inventors: Teruaki Komiya, Tadahiro Shiba
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Publication number: 20090171023Abstract: The present invention provides a thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property. The present invention relates to a thermoplastic polymer composition comprising (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer comprising (B) a hard segment block comprising at least one polymer selected from the group consisting of a polyamide, a polyester, a polyolefin and a polyurethane, and (B2) a soft segment block having an ether bond, with the proviso that a total amount of the components (A) and (B) is 100% by mass.Type: ApplicationFiled: January 26, 2009Publication date: July 2, 2009Applicant: TECHNO POLYMER CO., LTD.Inventors: Masaaki Mawatari, Tatsuya Toneri
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Patent number: 7541420Abstract: A method for preparing a molded article includes the steps of (a) obtaining a polycarbonate resin and (b) molding the polycarbonate resin. The polycarbonate resin is made by a transesterification reaction using an activated diaryl carbonate such that the polycarbonate is susceptible to the formation of internal ester linkages (IEL). The method occurs with the proviso that the polycarbonate resin, the molding conditions or both are selected to control the amount of IEL formed during the molding process to a level of less than 0.4 mol %.Type: GrantFiled: March 20, 2007Date of Patent: June 2, 2009Assignee: Sabic Innovative Plastics IP B.V.Inventors: Sjef Berndsen, Hans Peter Brack, Bernd Jansen, Jan Henk Kamps, Edward Kung, Daniel Lowery, Patrick Joseph McCloskey, Paul Michael Smigelski, Jr., Dennis Willemse
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Publication number: 20090137723Abstract: This invention relates to thermoplastic article having one or more decorative materials embedded therein which is obtained by applying heat and pressure to one or more laminates wherein at least one of said laminates comprises, in order, (1) an upper sheet material; (2) one or more decorative materials; and (3) a lower sheet material; wherein the upper and lower sheet materials are formed from a polyester/aromatic polycarbonate blend wherein the thermoplastic article comprises at least one polyester composition comprising at least one polyester which comprises terephthalic acid and 2,2,4,4-tetramethyl-1,3-cyclobutanediol.Type: ApplicationFiled: January 29, 2009Publication date: May 28, 2009Applicant: EASTMAN CHEMICAL COMPANYInventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
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Patent number: 7335705Abstract: Fluoropolymers are disclosed. The fluoropolymers include (i) units derived from a fluoromonomer composition comprising chlorotrifluoroethylene, and (ii) units derived from at least one donor monomer composition. In the disclosed fluoropolymers, units (i) and (ii) are distributed along the fluoropolymer chain in a substantially alternating fashion. Also disclosed are thermosetting compositions containing such fluoropolymers, substrates coated with such compositions, methods for making such compositions, and methods for coating substrates with such compositions.Type: GrantFiled: September 30, 2005Date of Patent: February 26, 2008Assignee: PPG Industries Ohio, Inc.Inventors: Simion Coca, Edward R. Coleridge, James B. O'Dwyer, Brian E. Woodworth
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Patent number: 7332545Abstract: Fluoropolymers are disclosed. The fluoropolymers include (i) units derived from a fluoromonomer having the formula F2C?CXY, where X is CF3 and Y is either F or CF3, and (ii) units derived from at least one donor monomer. In the disclosed fluoropolymers, units (i) and (ii) are distributed along the fluoropolymer chain in a substantially alternating fashion. Also disclosed are thermosetting compositions containing such fluoropolymers, substrates coated with such compositions, methods for making such compositions, and methods for coating substrates with such compositions.Type: GrantFiled: September 30, 2005Date of Patent: February 19, 2008Assignee: PPG Industries Ohio, Inc.Inventors: Simion Coca, Edward R. Coleridge, James B. O'Dwyer, Brian E. Woodworth, Richard J. Winters
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Publication number: 20070208144Abstract: Poly(arylene ether)-polysiloxane block copolymers and methods for their preparation are provided. The block copolymers include structural units derived from a poly(arylene ether), a hydroxyaryl-terminated polysiloxane, and an activated aromatic carbonate.Type: ApplicationFiled: June 15, 2006Publication date: September 6, 2007Applicant: GENERAL ELECTRIC COMPANYInventors: Erik R. Delsman, Amy R. Freshour, Farah Jean-Jacques Toublan, Gary W. Yeager
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Publication number: 20070208145Abstract: Poly(arylene ether)-polyester block copolymers and methods for their preparation are provided. The block copolymers include structural units derived from a poly(arylene ether), a hydroxy-terminated polyester, and an activated aromatic carbonate.Type: ApplicationFiled: June 15, 2006Publication date: September 6, 2007Applicant: GENERAL ELECTRIC COMPANYInventors: Rene de Kok, Erik R. Delsman, Amy R. Freshour, Farah Jean-Jacques Toublan, Edward N. Peters, Gary W. Yeager
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Patent number: 6878782Abstract: A curable composition includes a functionalized poly(arylene ether); an alkenyl aromatic monomer; an acryloyl monomer; and a polymeric additive having a glass transition temperature less than or equal to 100° C. and a Young's modulus less than or equal to 1000 megapascals at 25° C. The polymeric additive is soluble in the combined functionalized poly(arylene ether), alkenyl aromatic monomer, and acryloyl monomer at a temperature less than or equal to 50° C. The composition exhibits low shrinkage on curing and improved surface smoothness. It is useful, for example, in the manufacture of automotive body panels.Type: GrantFiled: April 9, 2002Date of Patent: April 12, 2005Assignee: General ElectricInventors: Glen David Merfeld, Gary William Yeager, Robert Edgar Colborn, Bryan Duffey
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Patent number: 6844287Abstract: The present invention provides a process for preparing supported zinc dicarboxylate catalysts with high activity for the copolymerization of carbon dioxide and epoxides by supporting zinc dicarboxylate on silica support. The zinc dicarboxylate may be synthesized from zinc oxide and dicarboxylic acid such as succinic acid, glutaric acid, adipic acid, pimelic acid and suberic acid. The silica support can be selected from the group consisting of aerosil, silica gel for chromatography or reagent grade silicon dioxide. The supporting process is performed in a planetary ball grinder under vacuum.Type: GrantFiled: December 13, 2002Date of Patent: January 18, 2005Assignee: Guangzhou Institute of Chemistry, Chinese Academy of SciencesInventors: Yuezhong Meng, Quan Zhu, Shizhen Zhang, Xiuhua Li, Longchao Du
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Patent number: 6803426Abstract: A composition that includes a fluorine-containing copolymer containing at least 30 mol % of residues having the following alternating structural unit: —[DM—AM]— where DM represents a residue from a donor monomer having the following structure (I): where R1 is linear or branched C1 to C4 alkyl; R2 is selected from methyl, linear, cyclic or branched C1 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl; and AM represents an acceptor monomer. The copolymer contains at least 5 wt. % fluorine. The composition may include co-reactive functional groups and may be a thermosetting composition, which can be used to coat a substrate. The thermosetting composition may be part of a multi-component composite coating composition that includes a base coat deposited from a pigmented film-forming composition and a substantially pigment free top coat applied over at least a portion of the base coat.Type: GrantFiled: February 4, 2003Date of Patent: October 12, 2004Assignee: PPG Industries Ohio, Inc.Inventors: Edward R. Coleridge, Edward R. Millero, Jr., Robert T. Pogue, Truman F. Wilt, Carole A. Conley, Shawn A. DeSaw, Robert A. Montague
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Publication number: 20040116618Abstract: The polycarbonate resin of the present invention has an improved refractive index, balance of dispersion, photoelastic constant, and so on while still maintaining the characteristics of polycarbonate, such as excellent impact resistance and heat resistance, and is characterized by comprising an aromatic-aliphatic copolymerized polycarbonate resin (A) and an aromatic polycarbonate resin (B) having a structural unit represented by the following formula (1): 1Type: ApplicationFiled: October 9, 2003Publication date: June 17, 2004Inventors: Satoshi Nagai, Makoto Sasaki, Noritaka Murase, Hisashi Yoshida, Tomoyuki Hashimoto
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Patent number: 6569953Abstract: Phenolic resin polyols are disclosed. The polyols, which contain aliphatic or mixed phenolic and aliphatic hydroxyl groups, are the reaction products of aralkylated phenols or phenol aralkylation polymers with an oxyalkylating agent selected from alkylene oxides and alkylene carbonates. The phenolic resin polyols are versatile intermediates for many polymer systems, including urethanes, epoxies, alkyds, acrylates, and polyesters.Type: GrantFiled: May 26, 1999Date of Patent: May 27, 2003Assignee: Georgia-Pacific Resins, Inc.Inventors: David C. Dehm, David A. Hutchings, Alan K. Randall, Mark A. Peters
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Patent number: 6469078Abstract: This invention relates to a process for increasing the molecular weight and/or for the modification of polycondensates during the processing in the melt, which comprises adding to the polycondensate a blend comprising a) at least one polyfunctional anhydride (polyanhydride); b) at least one polyfunctional compound, the functional groups of which can react with the anhydride groups of component a); and c) at least one phosphonate. This invention also relates to the use of an additive blend for increasing the molecular weight and for the modification of polycondensates during the processing in the melt.Type: GrantFiled: May 15, 2000Date of Patent: October 22, 2002Assignee: Ciba Specialty Chemicals CorporationInventors: Dirk Simon, Rudolf Pfaendner, Heinz Herbst
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Patent number: 6417274Abstract: The invention relates to a novel process for preparing functionalized PPE, the process comprising oxidative coupling in a reaction solution at least one monovalent phenol species using an oxygen containing gas and a complex metal catalyst to produce a PPE; and functionalizing the PPE prior to and/or during at least one isolation step for devolatilization of the reaction solvent. The invention also relates to the polyphenylene ether resin made by the process as well as blends and articles containing the polyphenylene ether resin made by the process.Type: GrantFiled: February 5, 1999Date of Patent: July 9, 2002Assignee: General Electric Co.Inventors: Adrianus J. F. M. Braat, Rene de Jongh, Juraj Liska
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Patent number: 6316579Abstract: A thermoplastic resin composition can be obtained by adding about 0.1 to 20 parts by weight of a diene-series block copolymer (2) to 100 parts by weight of a resin composition containing a polycarbonate-series resin (1) as a basic component of which the proportion of terminal hydroxy groups relative to the whole of the terminals is 1 mole % or above (about 5 to 40 mole %). The polycarbonate-series resin base may further comprise a thermoplastic resin composition (3) such as a rubber-modified styrenic resin. The block copolymer component (2) includes an epoxy-modified block copolymer, etc. When added an organophosphorus compound as a flame retardant (4), or a fluorine-containing resin as a flame-retartant auxiliary (5), a halogen-free flame-retardant thermoplastic resin composition can be obtained. A thermoplastic resin with an improved flowability and impact strength can be obtained by modifying a polymer blend of the polycarbonate-series resin and the styrenic-series resin in quality.Type: GrantFiled: June 20, 2000Date of Patent: November 13, 2001Assignee: Daicel Chemical Industries, Ltd.Inventors: Masahiro Katayama, Masaaki Ito, Yoshihiro Otsuka
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Patent number: 6111016Abstract: A thermoplastic resin composition can be obtained by adding about 0.1 to 20 parts by weight of a diene-series block copolymer (2) to 100 parts by weight of a resin composition containing a polycarbonate-series resin (1) as a basic component of which the proportion of terminal hydroxy groups relative to the whole of the terminals is 1 mole % or above (about 5 to 40 mole %). The polycarbonate-series resin base may further comprise a thermoplastic resin composition (3) such as a rubber-modified styrenic resin. The block copolymer component (2) includes an epoxy-modified block copolymer, etc. When added an organophosphorus compound as a flame retardant (4), or a fluorine-containing resin as a flame-retartant auxiliary (5), a halogen-free flame-retardant thermoplastic resin composition can be obtained. A thermoplastic resin with an improved flowability and impact strength can be obtained by modifying a polymer blend of the polycarbonate-series resin and the styrenic-series resin in quality.Type: GrantFiled: July 17, 1998Date of Patent: August 29, 2000Assignee: Daicel Chemical Industries, Ltd.Inventors: Masahiro Katayama, Masaaki Ito, Yoshihiro Otsuka
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Patent number: 6008302Abstract: Oligomeric materials contain ultraviolet light absorbing compounds that are covalently bound to the oligomer backbone through an ester or amide linkage. These ultraviolet light absorbing oligomers may be combined with polymers such as polyolefins to provide protection against the harmful effects of ultraviolet light.Type: GrantFiled: April 29, 1997Date of Patent: December 28, 1999Assignee: 3M Innovative Properties CompanyInventors: David B. Olson, David M. Burns
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Patent number: 5811032Abstract: A water-soluble polymer prepared by melting and reacting a mixture of an oxycarboxylic acid having a melting point of 170.degree. C. or less and maleamic acid, or a mixture of a plurality of oxycarboxylic acids including at least one oxycarboxylic acid having a melting point of 170.degree. C. or less and maleamic acid, at a temperature of 170.degree. C. or less at the start of the reaction to obtain a polymer; and then hydrolyzing the polymer.Type: GrantFiled: September 19, 1996Date of Patent: September 22, 1998Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Ryozo Kawai, Hiroshi Kurata, Yukari Shimizu, Shoichiro Kajiwara
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Patent number: 5789492Abstract: For optical applications, transparent amorphous thermo-plastics, such as polyaryl ether ketones, are of considerable interest. However, polyaryl ether ketones have inadequate UV stability and weathering resistance while amorphous polyaryl esters do not have these negative properties. The properties can be improved by means of polymer alloys, giving weathering-resistant materials from homogeneously mixed polymers which comprise at least one amorphous polyaryl ether ketone and at least one amorphous polyaryl ester.Type: GrantFiled: June 9, 1992Date of Patent: August 4, 1998Assignee: Hoechst AktiengesellschaftInventors: Michael-Joachim Brekner, Hansotto Drotloff, Otto Hermann-Schonherr, Arnold Schneller
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Patent number: 5741865Abstract: The tendency to opacify of a polyol composition comprising one or more zinc fatty acid salts such as zinc stearate, added to form a mold release agent when the polyol is converted to a molded polyurethane article, is retarded by the presence of a small but effective amount of one or more fatty alkyl diethoxylate (e.g. diethanolamine) compounds.Type: GrantFiled: July 18, 1995Date of Patent: April 21, 1998Assignee: Witco CorporationInventors: Charles R. Bunting, Donald G. Zelhart
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Patent number: 5691412Abstract: A polyamide/aliphatic polyester block copolymer (A) comprising a polyamide block and an aliphatic polyester block, (B) satisfying the expression, T.sub.1 -T<100-C (in which T is the melting point (.degree.C.) of the above block copolymer, T.sub.1 is the melting point (.degree.C.) of a polyamide composed of the polyamide block and C is the content (wt. %) of the polyamide block), (C) exhibiting the extraction amount which satisfies the expression, when extracted in tetrahydrofuran, E<(100-C).times.0.4 (in which E is the extraction amount (wt. %) when the block copolymer is refluxed in tetrahydrofuran, and C is the content (wt. %) of the polyamide block) and (D) having an intrinsic viscosity, measured at 35.degree. C., in the range of from 0.5 to 5; a process for the production thereof; a fiber formed therefrom; and an intimate blend comprising a thermoplastic resin having no or poor compatibility with polyamide and the block copolymer.Type: GrantFiled: May 25, 1995Date of Patent: November 25, 1997Assignee: Teijin LimitedInventors: Shunichi Matsumura, Takashi Ito, Takanori Miyoshi
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Patent number: 5639833Abstract: The invention is directed to molding materials containingA) from 1 to 99% by weight of polyarylene ethers having repeating units I ##STR1## where t and q may each be an integer 0, 1, 2 or 3,T, Q and Z may each be a chemical bond or --O--, --S--, --SO.sub.2 --, S.dbd.O, C.dbd.O, --N.dbd.N--, R.sup.a C.dbd.CR.sup.b -- or --CR.sup.c R.sup.d --, with the proviso that at least one of the groups T, Q and Z is --SO.sub.2 -- or C.dbd.O,R.sup.a and R.sup.b,R.sup.c and R.sup.d, andAr and Ar.sup.1 are as defined in the specification,B) from 1 to 99% by weight of copolyamides containingb.sub.1) from 30 to 44 mol % of units which are derived from terephthalic acid,b.sub.2) from 6 to 20 mol % of units which are derived from isophthalic acid,b.sub.3) from 43 to 49.5 mol % of units which are derived from hexamethylenediamine,b.sub.4) from 0.5 to 7 mol % of units which are derived from aliphatic cyclic diamines of 6 to 30 carbon atoms andb.sub.5) from 0 to 4 mol % of further polyamide-forming monomers which differ from b.sub.Type: GrantFiled: August 10, 1995Date of Patent: June 17, 1997Assignee: BASF AktiengesellschaftInventors: Martin Weber, Herbert Fisch, Gunter Pipper, Axel Gottschalk
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Patent number: 5571873Abstract: A new thermoplastic homopolymer of o-cresol which is a poly(2-methylphenylene oxide) having a high molecular weight distribution is described. The polymer is prepared using a 2 and/or 6 substituted pyridine catalyst to the molecular weight distribution. The homopolymer can be blended with other thermoplastic polymers. The homopolymer is rapidly biodegraded, particularly in soil containing soil microorganisms.Type: GrantFiled: June 5, 1995Date of Patent: November 5, 1996Assignee: Board of Trustees operating Michigan State UniversityInventors: Li-Xia Li, Patrick J. Oriel, Eric A. Grulke