Mixed With -n=c=x-containing Reactant Or Polymer Therefrom (x Is Chalcogen) Patents (Class 525/395)
  • Patent number: 8815401
    Abstract: A prepreg for a printed wiring board, comprising a cyanate ester resin having a specific structure, a non-halogen epoxy resin, a silicone rubber powder as a rubber elasticity powder, an inorganic filler and a base material, which prepreg retains heat resistance owing to a stiff resin skeleton structure, has high-degree flame retardancy without the use of a halogen compound or a phosphorus compound as a flame retardant, and has a small thermal expansion coefficient in plane direction without using a large amount of inorganic filler, and a laminate comprising the above prepreg.
    Type: Grant
    Filed: July 11, 2008
    Date of Patent: August 26, 2014
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Yoshihiro Kato, Takeshi Nobukuni, Masayoshi Ueno
  • Patent number: 8785799
    Abstract: This invention is directed to a polymer thick film moisture barrier layer dielectric composition comprising thermoplastic urethane resin, thermoplastic phenoxy resin, diacetone alcohol and fumed silica. Dielectrics made from the composition can be used in various electronic applications to protect electrical elements and particularly to insulate and protect both the conductive thermoformable silver above it and the polycarbonate substrate below it in capacitive switch applications.
    Type: Grant
    Filed: January 8, 2013
    Date of Patent: July 22, 2014
    Assignee: E I du Pont de Nemours and Company
    Inventor: Jay Robert Dorfman
  • Patent number: 8748540
    Abstract: The present invention provides a composition comprising a solvated aromatic amine and a liquid carrier, wherein said solvated aromatic amine is the reaction product of an aromatic amine and at least one of any anhydride, an isocyanate or an acid in the liquid carrier. The present invention also provides a method of preparing a composition comprising a solvated aromatic amine and a liquid carrier, said method comprising the steps of providing a reaction mixture comprising: a) an aromatic amine; b) at least one of an anhydride, an isocyanate or an acid; and c) a liquid carrier; and heating the reaction mixture at an elevated temperature to provide the solvated aromatic amine in the liquid carriers. The present invention further provides the use of the compositions for the preparation of the curable compounds and for gasoline resistant coatings.
    Type: Grant
    Filed: April 16, 2010
    Date of Patent: June 10, 2014
    Assignee: Crosslink Technology, Inc
    Inventors: John Ulcar, Ackah Toffey
  • Publication number: 20140100312
    Abstract: Disclosed herein is a blend comprising: (a) 5 to 50 percent by weight of the micronized poly(phenylene ether), wherein the mean particle size of the poly(phenylene ether) is 9 microns or less; (b) 50 to 95 percent by weight of a thermoplastic polyurethane; wherein the weight percents are based on the total weight of the blend. Also disclosed are processes for preparing such blends as well as articles derived therefrom.
    Type: Application
    Filed: October 9, 2012
    Publication date: April 10, 2014
    Applicant: Sabic Innovative Plastics
    Inventor: Edward Norman Peters
  • Patent number: 8598281
    Abstract: An epoxybenzyl-terminated poly(arylene ether) has the structure R—W—R wherein W is a divalent poly(arylene ether) residue terminated with phenolic oxygen atoms, and R is an epoxybenzyl group, wherein each occurrence of R is the same or different. The epoxybenzyl-terminated poly(arylene ether) is formed by reacting a peroxide-containing reagent with a vinybenzyl-terminated poly(arylene ether). Also disclosed is a curable composition including the epoxybenzyl-terminated poly(arylene ether)s, a curing promoter, and, optionally, an auxiliary epoxy resin. The curable composition is useful for the preparation of composites, and in particular, composites used in manufacturing printed circuit boards.
    Type: Grant
    Filed: September 1, 2011
    Date of Patent: December 3, 2013
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventor: Edward N. Peters
  • Publication number: 20130237648
    Abstract: A poly(phenylene ether)-poly(hydroxy ether) block copolymer is used to compatibilize blends of polar polymers and non-polar polymers. The resulting compatibilized blends exhibit physical property improvements relative to blends without a compatibilizer and blends with a poly(hydroxy ether).
    Type: Application
    Filed: March 8, 2012
    Publication date: September 12, 2013
    Inventor: Edward Norman Peters
  • Patent number: 8501874
    Abstract: The present invention relates to thermosetting resin compositions which are suitably used for manufacturing circuit boards, such as flexible printed circuit boards (FPCs) and build-up circuit boards, and to multilayer bodies and circuit boards manufactured using such thermosetting resin compositions. A thermosetting resin composition contains a polyimide resin component (A), a phenol resin component (B), and an epoxy resin component (C). The mixing ratio by weight (A)/[(B)+(C)] is in a range of 0.4 to 2.0, the mixing ratio by weight being the ratio of the weight of the component (A) to the total weight of the component (B) and the component (C). By using such a thermosetting resin composition, it is possible to manufacture multilayer bodies and circuit boards which are excellent in dielectric characteristics, adhesiveness, processability, heat resistance, flowability, etc. A thermosetting resin composition contains a polyimide resin (A), a phosphazene compound (D), and a cyanate ester compound (E).
    Type: Grant
    Filed: August 8, 2008
    Date of Patent: August 6, 2013
    Assignee: Kaneka Corporation
    Inventors: Shigeru Tanaka, Kanji Shimoohsako, Takashi Itoh, Koji Okada, Mutsuaki Murakami
  • Publication number: 20130158147
    Abstract: Disclosed are random copoly(phosphonate carbonate)s with the high molecular weight and narrow molecular weight distribution exhibiting a superior combination of properties compared to prior art.
    Type: Application
    Filed: February 11, 2013
    Publication date: June 20, 2013
    Applicants: BAYER MATERIAL SCIENCE AG, FRX POLYMERS, INC.
    Inventors: FRX Polymers, Inc., Bayer Material Science AG
  • Publication number: 20130075142
    Abstract: An adhesive composition for connection between a first circuit member having a first connecting terminal on the main surface and a second circuit member having a second connecting terminal on the main surface, wherein the first circuit member and/or second circuit member are made of a base material containing a thermoplastic resin with a glass transition temperature of no higher than 200° C., the first connecting terminal and/or second connecting terminal are made of ITO and/or IZO, and the adhesive composition includes a phosphate group-containing compound, the free phosphate concentration of the cured adhesive composition being no greater than 100 ppm by mass.
    Type: Application
    Filed: March 24, 2011
    Publication date: March 28, 2013
    Applicant: HITACHI CHEMICAL CO., LTD.
    Inventors: Hiroyuki Izawa, Shigeki Katogi
  • Patent number: 8252868
    Abstract: A thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property containing (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer of (B1) a hard segment block with at least one of a polyamide, polyester, polyolefin or polyurethane, and (B2) a soft segment block having an ether bond.
    Type: Grant
    Filed: November 4, 2011
    Date of Patent: August 28, 2012
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Masaaki Mawatari, Tatsuya Toneri
  • Patent number: 8227556
    Abstract: A thermoplastic composition comprising recovered poly(arylene ether), less than or equal to 0.1 weight percent based on the total weight of the thermoplastic composition of a second recovered thermoplastic that gives off greater than or equal to 10 percent by mass of volatiles at a processing temperature for the thermoplastic composition; 0.025 to 4.0 weight percent, based on the total weight of the thermoplastic composition, of a third recovered thermoplastic selected from the group consisting of polyolefin, acrylonitrile-butadiene-styrene, polycarbonate, polycarbonate/acrylonitrile-butadiene-styrene blend, polymethyl methacrylate, polyamide, polyester, polycarbonate/polyester blend and combinations of two or more of the foregoing third recovered thermoplastics, wherein combinations of two or more of the foregoing third recovered thermoplastics are present in an amount of less than or equal to 10 weight percent, based on the total weight of the thermoplastic composition; and an optional virgin thermoplastic.
    Type: Grant
    Filed: June 21, 2011
    Date of Patent: July 24, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Allen Wai-Yee Ko, Michael L. Todt
  • Patent number: 8084538
    Abstract: The present invention provides a thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property. The present invention relates to a thermoplastic polymer composition comprising (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer comprising (B1) a hard segment block comprising at least one polymer selected from the group consisting of a polyamide, a polyester, a polyolefin and a polyurethane, and (B2) a soft segment block having an ether bond, with the proviso that a total amount of the components (A) and (B) is 100% by mass.
    Type: Grant
    Filed: January 26, 2009
    Date of Patent: December 27, 2011
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Masaaki Mawatari, Tatsuya Toneri
  • Publication number: 20110251325
    Abstract: A thermoplastic composition comprising recovered poly(arylene ether), less than or equal to 0.1 weight percent based on the total weight of the thermoplastic composition of a second recovered thermoplastic that gives off greater than or equal to 10 percent by mass of volatiles at a processing temperature for the thermoplastic composition; 0.025 to 4.0 weight percent, based on the total weight of the thermoplastic composition, of a third recovered thermoplastic selected from the group consisting of polyolefin, acrylonitrile-butadiene-styrene, polycarbonate, polycarbonate/acrylonitrile-butadiene-styrene blend, polymethyl methacrylate, polyamide, polyester, polycarbonate/polyester blend and combinations of two or more of the foregoing third recovered thermoplastics, wherein combinations of two or more of the foregoing third recovered thermoplastics are present in an amount of less than or equal to 10 weight percent, based on the total weight of the thermoplastic composition; and an optional virgin thermoplastic.
    Type: Application
    Filed: June 21, 2011
    Publication date: October 13, 2011
    Applicant: SABIC INNOVATIVE PLASTICS IP B.V.
    Inventors: Allen Wai-Yee Ko, Michael L. Todt
  • Patent number: 7964675
    Abstract: A thermoplastic composition comprising recovered poly(arylene ether), less than or equal to 0.1 weight percent based on the total weight of the thermoplastic composition of a second recovered thermoplastic that gives off greater than or equal to 10 percent by mass of volatiles at a processing temperature for the thermoplastic composition; 0.025 to 4.0 weight percent, based on the total weight of the thermoplastic composition, of a third recovered thermoplastic selected from the group consisting of polyolefin, acrylonitrile-butadiene-styrene, polycarbonate, polycarbonate/acrylonitrile-butadiene-styrene blend, polymethyl methacrylate, polyamide, polyester, polycarbonate/polyester blend and combinations of two or more of the foregoing third recovered thermoplastics, wherein combinations of two or more of the foregoing third recovered thermoplastics are present in an amount of less than or equal to 10 weight percent, based on the total weight of the thermoplastic composition; and an optional virgin thermoplastic.
    Type: Grant
    Filed: January 10, 2005
    Date of Patent: June 21, 2011
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Allen Wai-Yee Ko, Michael L. Todt
  • Publication number: 20110139496
    Abstract: A resin composition which is low in a roughness of an insulating layer surface and capable of forming thereon a plated conductor layer having a sufficient peel strength in a wet roughing step and which is excellent in dielectric characteristics and a coefficient of thermal expansion, is disclosed. The resin composition contains a cyanate ester resin and a specified epoxy resin.
    Type: Application
    Filed: December 14, 2010
    Publication date: June 16, 2011
    Applicant: AJINOMOTO CO., INC.
    Inventor: Shigeo NAKAMURA
  • Patent number: 7897697
    Abstract: A process for preparing derivatized poly(4-hydroxystryrene) having a novolak type structure which comprises the steps of (i) supplying a solution of methanol containing 4-hydroxyphenylmethylcarbinol, (ii) subjecting said solution to an acid catalyzed displacement reaction for a sufficient period of time and under suitable conditions of temperature and pressure to convert substantially all of said carbinol to 4-hydroxyphenylmethylcarbinol methyl ether in solution, (iii) polymerizing said ether containing solution in the presence of a suitable acid catalyst for a sufficient period of time and under suitable conditions of temperature and pressure to form a novolak type polymer.
    Type: Grant
    Filed: June 24, 2009
    Date of Patent: March 1, 2011
    Assignee: DuPont Electronic Polymers L.P.
    Inventors: Michael T. Sheehan, Edward G. Zey
  • Publication number: 20100204410
    Abstract: The present invention is one liquid type cyanate-epoxy composite resin composition comprised of cyanate ester resin (A), epoxy resin (B), and potential curing agent (C), characterized in that the above potential curing agent is the potential curing agent containing phenol resin (b) as well as modified amine (a) which has one or more amino groups having an active hydrogen within a molecule obtained by reacting polyamine compound (a-1) with epoxy compound (a-2). The one liquid type cyanate-epoxy composite resin composition having storage stability, curing properties and high heat resistance properties at the same time can be realized by this composition.
    Type: Application
    Filed: June 6, 2008
    Publication date: August 12, 2010
    Applicant: ADEKA CORPORATION
    Inventors: Ryo Ogawa, Yoko Masamune, Shinsuke Yamada
  • Patent number: 7767308
    Abstract: A moisture-curable adhesive composition that may be formulated to be free of volatile organic compounds, or substantially free of volatile organic compounds which is safe for chronic exposure, resistant to combustion, and provides a high peel strength useful for securing a rubber membrane material to a rigid roof deck includes a polymer having silicon-containing hydrolyzable terminal groups, a phenolic resin, and a non-polymeric silicon-containing hydrolyzable compound, wherein the ratio of the amount of polymer having silicon-containing hydrolyzable terminal groups by weight to the amount of phenolic resin by weight is greater than 2:1.
    Type: Grant
    Filed: October 16, 2006
    Date of Patent: August 3, 2010
    Assignee: Chem Link, Inc.
    Inventors: Philip C. Georgeau, Jonathan H. Ballema
  • Patent number: 7569628
    Abstract: The present invention relates to a styrenic thermoplastic resin composition, and more particularly to a styrenic thermoplastic resin composition comprising a non-halogen flame-retardant having superior flame-retarding properties and impact strength. The present invention provides a flame-retarding styrenic thermoplastic resin composition comprising a) 100 weight parts of a base resin comprising i) 10 to 50 weight parts of a rubber-modified styrene-containing graft copolymer, ii) 5 to 20 weight parts of phenol novolac resin, and iii) 20 to 70 weight parts of a styrene-containing copolymer; and b) 5 to 20 weight parts of an aromatic phosphate. In addition, the a) base resin may further comprise iv) 10 to 40 weight parts of a thermoplastic polyurethane resin.
    Type: Grant
    Filed: June 25, 2007
    Date of Patent: August 4, 2009
    Assignee: LG Chem, Ltd.
    Inventors: Sung-Ho Lee, Chan-Hong Lee, Yong-Yeon Hwang, Ki-Young Nam, Tae-Hak Kim
  • Patent number: 7544741
    Abstract: A polyphenylene ether resin composition comprising a polyphenylene ether, wherein the polyphenylene ether has a polymer chain comprising recurring units each represented by the following formula (1): and has the following characteristics (a), (b) and (c): (a) when the polyphenylene ether is analyzed by 1H-NMR, the polyphenylene ether exhibits a triplet signal (S1) at 3.55 ppm, wherein the triplet signal (S1) has a relative intensity of 0.05 to 0.25 in terms of the percentage of the integrated intensity of the triplet signal (S1), based on the integrated intensity of a signal (S2) observed at 6.47 ppm; (b) the polyphenylene ether exhibits an absorbance of from 0.01 to 0.40 at a wavelength of 480 nm; and (c) the polyphenylene ether has a weight average molecular weight of from 30,000 to 100,000.
    Type: Grant
    Filed: November 28, 2002
    Date of Patent: June 9, 2009
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Akira Mitsui, Mutsumi Maeda
  • Patent number: 7521511
    Abstract: Thermosetting resin compositions for manufacturing circuit boards and build-up circuit boards, and build-up boards, and multilayer bodies and circuit boards manufactured using these compositions are provided. A composition contains polyimide resin (A), phenol resin (B), and epoxy resin (C) components. The mixing ratio by weight (A)/[(B)+(C)] is 0.4 to 2.0, the ratio being the ratio of the weight of (A) to the total weight of (B) and (C). By using such a composition, multilayer bodies and circuit boards, excellent in dielectric characteristics, adhesiveness, processability, heat resistance, flowability, etc. can be manufactured. A composition contains a polyimide resin (A), a phosphazene (D), and a cyanate ester (E). D includes a phenolic hydroxyl group-containing phenoxyphosphazene (D-1) and/or a crosslinked phenoxyphosphazene (D-2) prepared by crosslinking (D-1), (D-2) having at least one phenolic hydroxyl group.
    Type: Grant
    Filed: April 12, 2004
    Date of Patent: April 21, 2009
    Assignee: Kaneka Corporation
    Inventors: Shigeru Tanaka, Kanji Shimoohsako, Takashi Itoh, Koji Okada, Mutsuaki Murakami
  • Patent number: 7371800
    Abstract: A process for preparing derivatized poly(4-hydroxystryrene) having a novolak type structure which comprises the steps of (i) supplying a solution of methanol containing 4-hydroxyphenylmethylcarbinol, (ii) subjecting said solution to an acid catalyzed displacement reaction for a sufficient period of time and under suitable conditions of temperature and pressure to convert substantially all of said carbinol to 4-hydroxyphenylmethylcarbinol methyl ether in solution, (iii) polymerizing said ether containing solution in the presence of a suitable acid catalyst for a sufficient period of time and under suitable conditions of temperature and pressure to form a novolak type polymer.
    Type: Grant
    Filed: April 22, 2005
    Date of Patent: May 13, 2008
    Assignee: DuPont Electronic Polymers L.P.
    Inventors: Michael T. Sheehan, Edward G. Zey
  • Patent number: 7235597
    Abstract: The present invention relates to a styrenic thermoplastic resin composition, and more particularly to a styrenic thermoplastic resin composition comprising a non-halogen flame-retardant having superior flame-retarding properties and impact strength. The present invention provides a flame-retarding styrenic thermoplastic resin composition comprising a) 100 weight parts of a base resin comprising i) 10 to 50 weight parts of a rubber-modified styrenic-containing graft copolymer, ii) 5 to 20 weight parts of phenol novolac resin, and iii) 20 to 70 weight parts of a styrene-containing copolymer; and b) 5 to 20 weight parts of an aromatic phosphate. In addition, the a) base resin may further comprise iv) 10 to 40 weight parts of a thermoplastic polyurethane resin.
    Type: Grant
    Filed: September 5, 2002
    Date of Patent: June 26, 2007
    Assignee: LG Chem, Ltd.
    Inventors: Sung-Ho Lee, Chan-Hong Lee, Yong-Yeon Hwang, Ki-Young Nam, Tae-Hak Kim
  • Patent number: 7084213
    Abstract: A polymer composition comprising chains of at least one aromatic polymer or a mixture thereof together with at least one chain linking component wherein the at least one aromatic polymer comprises polymer chains of number average molecular weight (Mn) in a first range and characterised by a polymer flow temperature, and having at least one reactive end group, and wherein the at least one chain linking component comprises at least two linking sites, characterised in that a plurality of the polymer chain end groups are adapted to react with the linking sites at chain linking temperature in excess of the polymer flow temperature to form linked polymer chains of number average molecular weight (Mn) in a second range which is in excess of the first range, substantially thermoplastic in nature; process for the preparation thereof; prepreg, composite or shaped product obtained therewith and the use thereof.
    Type: Grant
    Filed: August 20, 2001
    Date of Patent: August 1, 2006
    Assignee: Cytec Technology Crop.
    Inventors: Patrick Terence McGrail, Jeffrey Thomas Carter
  • Patent number: 6962965
    Abstract: A functionalized poly(arylene ether) having a pendant carbon—carbon double bond is prepared by reacting the hydroxy end group of a poly(arylene ether) with a polyisocyanate compound to produce a urethane-capped poly(arylene ether) having pendant isocyanate functionality, which is then reacted with a polyfunctional compound having a carbon—carbon double bond and a hydroxy, thiol, or amino group. The functionalized poly(arylene ether) is useful as a component of a curable composition in which its carbon—carbon double bond copolymerizes with one or more olefinically unsaturated comonomers.
    Type: Grant
    Filed: February 20, 2004
    Date of Patent: November 8, 2005
    Assignee: General Electric Company
    Inventor: Gary William Yeager
  • Patent number: 6696528
    Abstract: A low molecular weight engineering thermoplastic polyurethane (ETPU) can be homogeneously melt blended with a polyarylene ether (PAE) to give a low viscosity melt processable blend, and subsequently cooled to form a heterogeneous dispersion of the ETPU in the PAE that has two Tgs, one that is close to the Tg of the pure ETPU, and one that is close to the Tg of the pure PAE. As such, the composite blend retains the properties of the polyarylene ether.
    Type: Grant
    Filed: August 7, 2001
    Date of Patent: February 24, 2004
    Assignee: The Dow Chemical Company
    Inventors: Paul J. Moses, Edward Louis D'Hooghe, Wilfred van Pelt
  • Publication number: 20030235786
    Abstract: Anti-reflective compositions and methods of using these compositions to form circuits are provided. The compositions comprise a polymer dissolved or dispersed in a solvent system.
    Type: Application
    Filed: June 25, 2002
    Publication date: December 25, 2003
    Applicant: BREWER SCIENCE, INC.
    Inventors: Vandana Krishnamurthy, Charles J. Neef, Juliet A.M. Snook
  • Patent number: 6649697
    Abstract: A hyperbranched polyetherketone and a heat-resistant blend of polyvinylchloride with the same. The polyethereketone is synthesized by self-polycondensation of 3,5-bis[4-[(2,3,4,5,6-pentafluorophenyl)carbonyl]phenoxy]-4-hydroxbenzophenone or 3,5-difluoro-4-hydroxybenzophenone, and then substituting 50 to 80 mole % of fluorine atoms present in the side chains and ends of the PEK molecule by polar groups. In addition, a blend of polyvinylchloride can be manufactured using the hyperbranched polyetherketone by a melt blending technique applicable for industrial purpose at a temperature of 180 to 120° C., and thus the blend of polyvinylchloride with the polyetherekentone can be applied to high temperature end-use products such as hot water pipes.
    Type: Grant
    Filed: January 9, 2002
    Date of Patent: November 18, 2003
    Assignee: Polyplus Co., Ltd.
    Inventors: Seung-yeop Kwak, Dae-up Ahn
  • Patent number: 6569953
    Abstract: Phenolic resin polyols are disclosed. The polyols, which contain aliphatic or mixed phenolic and aliphatic hydroxyl groups, are the reaction products of aralkylated phenols or phenol aralkylation polymers with an oxyalkylating agent selected from alkylene oxides and alkylene carbonates. The phenolic resin polyols are versatile intermediates for many polymer systems, including urethanes, epoxies, alkyds, acrylates, and polyesters.
    Type: Grant
    Filed: May 26, 1999
    Date of Patent: May 27, 2003
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: David C. Dehm, David A. Hutchings, Alan K. Randall, Mark A. Peters
  • Patent number: 6492482
    Abstract: A nonaqueous, heat-cured, two-component coating has a combination of good scratch resistance and resistance to etching by acid rain and comprises a solvent-containing polyol component and a cross-linking component. The cross-linking component comprises at least one aliphatic and/or cycloaliphatic polyisocyanate having 2 to 6 NCO functional groups per molecule in which 0.1 to 95 mol % of the isocyanate groups of the polyisocyanate are reacted with an N-alkyl-3-aminopropyltrialkoxysilane and/or an N-aryl-3-aminopropyltrialkoxysilane. The weight ratio of the polyol to the cross-linking component in the coating is 6:1 to 1:2.
    Type: Grant
    Filed: December 1, 2000
    Date of Patent: December 10, 2002
    Assignee: Deguss-Huels Aktiengesellschaft
    Inventors: Rainer Lomoelder, Friedrich Plogmann, Peter Speier
  • Patent number: 6252014
    Abstract: Provided are star-shaped non-vinyl polymers of a variety of compositions and a method for manufacturing such star-shaped polymers. The star-shaped polymers include a plurality of non-vinyl polymeric arms covalently linked to a crosslinked core. The core is made from crosslinkable non-vinyl reactants. The method involves reacting functionalized non-vinyl polymer pre-arms with the crosslinkable non-vinyl reactants.
    Type: Grant
    Filed: August 3, 1999
    Date of Patent: June 26, 2001
    Assignee: Colorado School of Mines
    Inventor: Daniel M. Knauss
  • Patent number: 6117943
    Abstract: A blend of a polyarylene ether and a dispersible reactive solvent such as a thermoplastic polyurethane or a cyclopentadiene can be processed at temperatures below the oxidative degradation temperature of the polyarylene ether, yet form an article upon cooling that substantially retains the properties of the polyarylene ether.
    Type: Grant
    Filed: March 1, 1999
    Date of Patent: September 12, 2000
    Assignee: The Dow Chemical Company
    Inventors: Edward Louis d'Hooghe, Jeno Kurja
  • Patent number: 6051662
    Abstract: Polyphenylene ether-thermosetting resin compositions are provided that are useful as dielectrics, particularly printed circuit boards having improved processability, good solvent and solder resistance, as well as improved morphology as compared to other polyphenylene ether-thermosetting resin compositions. More specifically, the particular polyphenylene ether resin component of this invention has a molecular weight of less than about 3,000 number average in contrast to higher molecular weight polyphenylene ethers employed in other polyphenylene ether-thermosetting resin compositions for use in preparing printed circuit boards.
    Type: Grant
    Filed: August 20, 1998
    Date of Patent: April 18, 2000
    Assignee: General Electric Co.
    Inventors: James E. Tracy, Gary William Yeager
  • Patent number: 5952417
    Abstract: The invention provides a composition for a platable resinous substrate having enhanced heat performance comprising: a thermoplastic mixture of at least one polyphenylene ether and at least one poly(alkenylaromatic) compound, at least one rubber compound, and at least one inorganic filler material.
    Type: Grant
    Filed: December 17, 1996
    Date of Patent: September 14, 1999
    Assignee: General Electric Co.
    Inventors: Herbert Shin-I Chao, Geoffrey Henry Riding, Carol Lynn Fasoldt
  • Patent number: 5902840
    Abstract: The invention relates to modified polymeric aromatic isocyanates having allophanate linkages prepared by (a) reacting a polymeric aromatic isocyanate with a monofunctional aliphatic alcohol to form an intermediate modified polymeric isocyanate; and (b) reacting the intermediate modified polymeric isocyanate at an elevated temperature in the presence of a divalent metal catalyst. The invention also relates to foundry binder systems which use these modified polyisocyanates. These modified polyisocyanates, along with a phenolic resole resin, are added to a foundry aggregate to form a foundry mix which is shaped and cured with a gaseous amine curing catalyst by the cold-box process.
    Type: Grant
    Filed: November 7, 1996
    Date of Patent: May 11, 1999
    Assignee: Ashland Inc.
    Inventors: Rina Singh, Laurence G. Dammann
  • Patent number: 5880167
    Abstract: The invention relates to polyurethane compositions with a low content of monomeric diisocyanates. Trifunctional isocyanates optionally reduced in their functionality to 3.0.+-.0.7 with a monofunctional terminator are preferably used for this purpose. In this way, the compositions contain considerably smaller quantities of readily volatile isocyanates. The compositions are suitable for use as reactive hotmelt adhesives, lamination adhesives, adhesive/sealing compounds, primers and for the production of foam plastics from non-reusable pressurized containers (aerosol cans). The low content of volatile monomeric diisocyanates enables the need for safety measures in the workplace to be significantly reduced, in addition to which the disposal of residues remaining in the containers is made considerably easier.
    Type: Grant
    Filed: March 27, 1997
    Date of Patent: March 9, 1999
    Assignee: Henkel Kommanditgesellschaft auf Aktien
    Inventors: Michael Krebs, Gerd Bolte, Christa Dernst-Mentges, Guenter Henke, Wolfgang Klauck, Hermann Kluth, Manfred Schumann
  • Patent number: 5834565
    Abstract: Polyphenylene ether-thermosetting resin compositions are provided that are useful as dielectrics, particularly printed circuit boards having improved processability, good solvent and solder resistance, as well as improved morphology as compared to other polyphenylene ether-thermosetting resin compositions. More specifically, the particular polyphenylene ether resin component of this invention has a molecular weight of less than about 3,000 number average in contrast to higher molecular weight polyphenylene ethers employed in other polyphenylene ether-thermosetting resin compositions for use in preparing printed circuit boards.
    Type: Grant
    Filed: November 12, 1996
    Date of Patent: November 10, 1998
    Assignee: General Electric Company
    Inventors: James E. Tracy, Gary William Yeager
  • Patent number: 5827907
    Abstract: A composition having enhanced fracture resistance comprising a heat curable reaction product of a fluorine-containing thermoset material and a fluorine-containing homopolymer, wherein the cured reaction product comprises the thermoset material having a plurality of discrete phases of said fluorine-containing homopolymer dispersed therein, the homopolymer phases being in the range of micron to submicron size.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: October 27, 1998
    Assignee: IBM Corporation
    Inventors: Jeffrey Thomas Gotro, Jeffrey Curtis Hedrick, Konstantinos Papathomas, Niranjan Mohanlal Patel, Alfred Viehbeck, William Joseph
  • Patent number: 5693709
    Abstract: Polyoxymethylene with improved acid stability, process for production and use thereof. By adding 0.01 to 5 parts of an alkali metal salt of a polybasic acid, for example oxalic acid, citric acid and/or 0.01 to 5 parts of a polyalkylene glycol, for example polyethylene glycol and/or 0.1 to 100 parts of a thermoplastic polyurethane, each related to 100 parts of a polyoxymethylene, this polymer is stabilized against attack by acids, wherein in particular the combination of an alkali metal salt, in particular an oxalate, with small proportions of a thermoplastic polyurethane is advantageous. The proportion of thermoplastic polyurethane may be reduced when the thermoplastic polyurethane has a Shore A hardness of 70 to 96. The weight loss of a stabilized POM under the action of acid may be less than 3% of that of an unstabilized POM. The products are useful when exposed to acidic agents such as irrigation systems, dishwashers, sanitary installations.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: December 2, 1997
    Assignee: Degussa Aktiengesellschaft
    Inventors: Edwin Nun, Stephanie Schauhoff, Detlef Arnoldi
  • Patent number: 5686539
    Abstract: The present invention relates to a resin composition comprising (A) polyphenylene ether, (B) polyarylene sulfide and (C) polyisocyanate, wherein the polyisocyanate is an organic compounds having the general formula: ##STR1## wherein n is an integer of 1 or more.
    Type: Grant
    Filed: November 15, 1991
    Date of Patent: November 11, 1997
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kenji Nagaoka, Satoru Gotoh
  • Patent number: 5681896
    Abstract: This invention is a quaternary ammonium/isocyanate compound having the formulaOCN-Z-Q.sup.+ A.sup.-,whereinZ is a divalent organic moiety;Q is a quaternary ammonium moiety; andA is a monovalent anionic counterion.Use of this quaternary ammonium/isocyanate compound or its amine/isocyanate compound enables one to convert any hydroxy containing binder into a self-wetting binder.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: October 28, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Ravindra L. Arudi
  • Patent number: 5574104
    Abstract: The present invention relates to electrostatic dissipative polymeric compositions comprising a polyether polyurethane which can be blended with one or more base polymers. In some applications, the polyurethane is useful without further blending. Further, the polyurethane blends can be blended with glass beads or glass fibers which have a synergist effect when combined with the electrostatic dissipative agent.
    Type: Grant
    Filed: September 26, 1995
    Date of Patent: November 12, 1996
    Assignee: The B. F. Goodrich Company
    Inventors: Edmond G. Kolycheck, Elaine A. Mertzel, Francis R. Sullivan, Gary F. Wilson, Timothy E. Fahey
  • Patent number: 5561199
    Abstract: A resin composition having an excellent impact property comprising a polyphenylene ether and a polyarylene sulfide is provided. The resin composition comprises (A) a polyphenylene ether and (B) a polyarylene sulfide having the terminal SM group (wherein M is hydrogen or an alkali metal) of at least 5.times.10.sup.-6 gram equivalents/g.
    Type: Grant
    Filed: November 27, 1995
    Date of Patent: October 1, 1996
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Kenji Nagaoka, Satoru Gotoh
  • Patent number: 5503938
    Abstract: This invention is a quaternary ammonium/isocyanate compound having the formulaOCN--Z--Q.sup.+ A.sup.-,whereinZ is a divalent organic moiety;Q is a quaternary ammonium moiety; andA is a monovalent anionic counterion. Use of this quaternary ammonium/isocyanate compound or its amine/isocyanate compound enables one to convert any hydroxy containing binder into a self-wetting binder.
    Type: Grant
    Filed: October 26, 1994
    Date of Patent: April 2, 1996
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Ravindra L. Arudi
  • Patent number: 5478874
    Abstract: A flame-retardant aromatic polycarbonate resin composition has excellent flame retardancy and high transparency without impairing excellent properties inherent to an aromatic polycarbonate resin, and is free from corroding a molding machine or a processing machine, the flame-retardant resin composition comprising 100 parts by weight of an aromatic polycarbonate resin, 0.01 to 1 part by weight of (a) a perfluoroalkane-sulfonic acid alkali salt and 0.02 to 2 parts by weight of (b) a halogenated triaryl phosphate of the formula [1], ##STR1## wherein each of Ar.sup.1, Ar.sup.2 and Ar.sup.3 is independently an aromatic hydrocarbon, and at least one halogen atom is substituted on ring-forming carbon of each aromatic hydrocarbon group.
    Type: Grant
    Filed: March 3, 1995
    Date of Patent: December 26, 1995
    Assignee: Teijin Chemicals Ltd.
    Inventors: Masahiro Miyouga, Shinichi Souda
  • Patent number: 5464891
    Abstract: The invention describes a thermoplastic composition made of a continuous phase made of crystalline thermoplastic resin A, a dispersed phase made of polyphenylene ether resin B, and an amide compound C represented by formula 1,R.sub.4 --CONH--R.sub.2 --HNOC--R.sub.1 --CONH--R.sub.3 --HNOC--R.sub.5( 1)wherein R.sub.1, R.sub.2, and R.sub.3 represent divalent hydrocarbon groups, which may be identical or different, and R.sub.4 and R.sub.5 represent monovalent hydrocarbon groups, which may be identical or different. The amide compound is present in an amount between about 0.1 and about 30 parts by weight per 100 parts by weight of the resins A and B mixed together.
    Type: Grant
    Filed: April 7, 1994
    Date of Patent: November 7, 1995
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Kenji Nagaoka, Kaoru Kitadono
  • Patent number: 5434224
    Abstract: A polymer composition especially suitable for producing fiber-reinforced structures having advantageous fracture toughness comprises a polyarylsulphone component and a thermoset resin component, each of which components is present at least partly as a phase continuous in at least one dimension. Preferred polyarylsulphones contain repeating units (PhSO.sub.2 Ph).sub.n and (Ph).sub.a linked through ether and/or thioether, where Ph is phenylene, n=1 to 2 and a=1 to 3; and such polyarylsulphones having amino end groups are provided as new compounds. The compositions can be made by spinodal decomposition of a mixture of the polyarylsulphone and a thermoset resin precursor.
    Type: Grant
    Filed: March 8, 1993
    Date of Patent: July 18, 1995
    Assignee: Imperial Chemical Industries PLC
    Inventors: Patrick T. McGrail, Mark S. Sefton, Judith A. Peacock, Gregory R. Almen, Steven P. Wilkinson
  • Patent number: 5405902
    Abstract: A novel thermoplastic resin composition excellent in heat resistance, mechanical properties and processability is provided which comprises a composition containing (A) a dispersing phase of polyphenylene ether obtained by oxidation polymerization of at least one phenol compound represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 each represents a hydrogen atom, a halogen atom or a substituted or unsubstituted hydrocarbon residue and at least one of them is a hydrogen atom and (B) a crystalline thermoplastic resin matrix phase and (C) a mutual compatibilizer compatible with (A) and/or (B), an average particle diameter in said dispersing phase having of 0.01-10.mu..
    Type: Grant
    Filed: December 15, 1993
    Date of Patent: April 11, 1995
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Taichi Nishio, Takashi Sanada, Satoru Hosoda, Kenji Kagaoka, Takayuki Okada
  • Patent number: 5403888
    Abstract: A novel thermoplastic resin composition excellent in heat resistance, mechanical properties and processability is provided which comprises a composition containing (A) a dispersing phase of polyphenylene ether obtained by oxidation polymerization of at least one phenol compound represented by the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 each represents a hydrogen atom, a halogen atom or a substituted or unsubstituted hydrocarbon residue and at least one of them is a hydrogen atom and (B) a crystalline thermoplastic resin matrix phase and (C) a mutual compatibilizer compatible with (A) and/or (B) , an average particle diameter in said dispersing phase having of 0.01-10 .mu..
    Type: Grant
    Filed: February 23, 1993
    Date of Patent: April 4, 1995
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Taichi Nishio, Takashi Sanada, Satoru Hosoda, Kenji Nagaoka, Takayuki Okada
  • Patent number: 5397838
    Abstract: The present inventions provides polyphenylene ether (PPE)/polyamide (PA) resin compositions having excellent dimensional stability when they absorb moisture, and good mechanical and other properties. Resin compositions of (A) 10-80 wt. parts PPE resins and (B) 90-20 wt. parts PA resins, in which the PA resins (a) are polymers formed by condensation of linear aliphatic diamines with linear aliphatic dicarboxylic acids and aromatic dicarboxylic acids, and (b) have terminal amino group contents of at least 0.4 mequiv/g.
    Type: Grant
    Filed: October 14, 1992
    Date of Patent: March 14, 1995
    Assignee: General Electric Company
    Inventors: Takashi Ohtomo, Hiromi Ishida, Hidekazu Kabaya