Mixed With Polycarboxylic Acid Or Derivative And Polyhydroxy Reactant Or Polymer Therefrom Patents (Class 525/425)
  • Patent number: 8399573
    Abstract: Thermoplastic compositions having miscible and compatible immiscible polymer blends are disclosed. The miscible polymer blends have a single glass transition temperature. The compatible polymer blends have two glass transition temperatures.
    Type: Grant
    Filed: November 22, 2006
    Date of Patent: March 19, 2013
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Robert Russell Gallucci, Tara Mullen, Roy Odle, Kapil Chandrakant Sheth, James M. White
  • Patent number: 8399557
    Abstract: Transparent blend or alloy comprising, by weight, the total being 100%: (A) 1 to 99% of at least one copolymer constituent: which is amorphous or has a crystallinity ranging up to semicrystallinity; and which comprises: (A1) amide units, among which is at least one cycloaliphatic unit; (A2) flexible ether units; (B) 99 to 1% of at least one polymer constituent selected from: (Ba) semicrystalline copolyamides comprising amide units (Ba1) and comprising ether units (Ba2), (Bb) semicrystalline polyamides or copolyamides without ether units, (Bc) transparent polyamides or copolyamides without ether units, which are amorphous or weakly crystalline, and alloys based on such polyamides or copolyamides; and (C) 0 to 50% by weight of at least one polyamide, copolyamide, copolyamide comprising ether units or alloy based on such polyamides or copolyamides other than those used in (A) and (B) above.
    Type: Grant
    Filed: June 11, 2007
    Date of Patent: March 19, 2013
    Assignee: Arkema France
    Inventors: Thibaut Montanari, Philippe Blondel
  • Publication number: 20130059968
    Abstract: The plastic composition includes PET and Nylon. The weight percentage of PET is between 20% and 90%. The weight percentage of Nylon is between 5% and 40%.
    Type: Application
    Filed: August 28, 2012
    Publication date: March 7, 2013
    Inventors: Fei-Lin YANG, Yang-Po Chiu, Ching-Feng Chen, Po-Wen Huang, Chun-Kai Chou, Wun-Sheng Wu, Win-Jon Lin, Ping-Huang Chen
  • Publication number: 20130053461
    Abstract: Biodegradable compositions containing an aliphatic-aromatic copolyester derived from aromatic polyesters. Methods of making the compositions through an in situ phosphorus containing titanium based catalyst and articles made from the compositions.
    Type: Application
    Filed: August 30, 2011
    Publication date: February 28, 2013
    Applicant: SABIC INNOVATIVE PLASTICS IP B.V.
    Inventors: Husnu Alp ALIDEDEOGLU, Hareesh Shamroa DESHPANDE, Belinda DUCKWORTH, Tukaram GUNALE, Darshan JAYANNA, Ganesh KANNAN
  • Publication number: 20130029067
    Abstract: An injection blow molding method for making a container having the steps of injecting a molten crystallizable polymer in a preform mold via a hot runner system and biaxially stretching the preform by blowing to form a container. The method further having the step to selectively modify the flow path of the molten crystallizable polymer within the hot runner system.
    Type: Application
    Filed: November 30, 2009
    Publication date: January 31, 2013
    Inventor: Steven DIRCX
  • Patent number: 8354477
    Abstract: Multi-armed, monofunctional, and hydrolytically stable polymers are described having the structure wherein Z is a moiety that can be activated for attachment to biologically active molecules such as proteins and wherein P and Q represent linkage fragments that join polymer arms polya and polyb, respectively, to central carbon atom, C, by hydrolytically stable linkages in the absence of aromatic rings in the linkage fragments. R typically is hydrogen or methyl, but can be a linkage fragment that includes another polymer arm. A specific example is an mPEG disubstituted lysine having the structure where mPEGa and mPEGb have the structure CH3O—(CH2CH2O)nCH2CH2— wherein n may be the same or different for polya- and polyb- and can be from 1 to about 1,150 to provide molecular weights of from about 100 to 100,000.
    Type: Grant
    Filed: August 3, 2010
    Date of Patent: January 15, 2013
    Assignee: Nektar Therapeutics
    Inventors: J. Milton Harris, Francesco Maria Veronese, Paolo Caliceti, Oddone Schiavon
  • Patent number: 8354491
    Abstract: Described are container(s) comprising polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; and (b) a glycol component comprising 15 to 50 mole % 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and 50 to 85 mole % 1,4-cyclohexanedimethanol residues; wherein the total mole % of said dicarboxylic acid component is 100 mole %, and the total mole % of said glycol component is 100 mole %; wherein the inherent viscosity of the polyester is from 0.50 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C.; wherein said polyester has a notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a 1/8-inch thick bar; and wherein the melt viscosity of said polyester is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C.
    Type: Grant
    Filed: January 28, 2011
    Date of Patent: January 15, 2013
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, David Scott Porter, Gary Wayne Connell, Michael James Keegan
  • Publication number: 20120329958
    Abstract: The present invention includes a polymer formed by the thermal rearrangement of an ortho-functional polyimide synthesized via chemical imidization with permeation properties for gas separation membranes higher than those synthesized via thermal imidization and a method for forming that polymer having tailored transport properties and different chemical resistance. The present invention also includes a polymer formed by the thermal rearrangement of an ortho-functional polyimide in which a portion of the ortho-position functional group is lost during thermal rearrangement to yield a thermally rearranged polymer with higher permeability than would be seen without the ortho-position group. This ortho-position group can be the result of chemical imidization, or the result of a post-imidization modification reaction.
    Type: Application
    Filed: June 1, 2012
    Publication date: December 27, 2012
    Applicants: Virginia Tech Intellectual Properties, Inc., Board of Regents, The University of Texas System
    Inventors: Benny D. Freeman, David Sanders, Claudio P. Ribeiro, JR., Zachary Smith, James E. McGrath, Ruilan Guo
  • Patent number: 8338545
    Abstract: The invention provides methods for making copolymers and multi-arm block copolymers useful as drug delivery vehicles. The multi-arm block copolymers comprise a central core molecule, such as a residue of a polyol, and at least three copolymer arms covalently attached to the central core molecule, each copolymer arm comprising an inner hydrophobic polymer segment covalently attached to the central core molecule and an outer hydrophilic polymer segment covalently attached to the hydrophobic polymer segment, wherein the central core molecule and the hydrophobic polymer segment define a hydrophobic core region. The solubility of hydrophobic biologically active agents can be improved by entrapment within the hydrophobic core region of the block copolymer. The invention further includes pharmaceutical compositions including such block copolymers, pharmaceutical compositions, and methods of using the block copolymers as drug delivery vehicles.
    Type: Grant
    Filed: November 2, 2011
    Date of Patent: December 25, 2012
    Assignee: Nektar Therapeutics
    Inventor: Xuan Zhao
  • Publication number: 20120301659
    Abstract: Polyamide terpolymer compositions, which contain biobased monomers and are suitable for making shaped articles, are disclosed. Comprised of three monomeric species polymerized randomly, including hexamethylene diamine, adipic acid and a bio-based monomer, the compositions are easier to process and have better dye uniformity than polyamides formed from melt-blended biobased components, and are comparable in dyeability, color fastnessand appearance retention performance to non-biobased polyamide copolymers.
    Type: Application
    Filed: January 31, 2011
    Publication date: November 29, 2012
    Applicant: INVISTA North America S.a r.I.
    Inventor: Sundar Mohan Rao
  • Patent number: 8304499
    Abstract: Disclosed are polymer compositions having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enable the incorporation of regrind into the polymer composition to produce transparent shaped articles. The blends of the present invention are useful in producing shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce oxygen-scavenging compositions.
    Type: Grant
    Filed: April 29, 2011
    Date of Patent: November 6, 2012
    Assignee: Eastman Chemical Company
    Inventors: Marcus David Shelby, Wesley Raymond Hale, Thomas Joseph Pecorini, Martin Emerson Rogers, Spencer Allen Gilliam, Michael Duane Cliffton, Mark Edward Stewart
  • Patent number: 8299204
    Abstract: Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbons atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: October 30, 2012
    Assignee: Eastman Chemical Company
    Inventors: Ted Calvin Germroth, Gary Wayne Connell, Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephen McWilliams, Benjamin Fredrick Barton, Damon Bryan Shackelford
  • Patent number: 8287970
    Abstract: The invention is generally directed to baby bottles and other articles produced by blow molding from polymeric materials having glass transition temperatures ranging from 100° C. to 130° C., as well as to processes for producing them. These articles can be exposed to boiling water and can be produced by using a suitable combination of a stretch ratio of less than 3 and a preform temperature at least 20° C. greater than the glass transition temperature (Tg) of the polymeric material.
    Type: Grant
    Filed: November 20, 2008
    Date of Patent: October 16, 2012
    Assignee: Eastman Chemical Company
    Inventors: Thomas Joseph Pecorini, Spencer Allen Gilliam, Alan Keith Phillips
  • Publication number: 20120244345
    Abstract: The present teachings provide a fuser member. The fuser member includes a substrate layer comprising a polymer blend polyimide polymer and amino silicone.
    Type: Application
    Filed: March 25, 2011
    Publication date: September 27, 2012
    Applicant: XEROX CORPORATION
    Inventor: Jin Wu
  • Patent number: 8273431
    Abstract: A polyamide resin composition contains a resin component containing at least a polyamide (X) and a fatty acid metallic salt having from 10 to 50 carbon atoms, and contains arbitrarily an additive (A) and/or an additive (B). The polyamide (X) is obtained through melt polycondensation of a diamine component containing 70% by mol or more of m-xylylenediamine and a dicarboxylic acid component containing 70% by mol or more of an ?,?-linear aliphatic dicarboxylic acid. The additive (A) is at least one compound selected from the group consisting of a diamide compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diamine having from 2 to 10 carbon atoms, a diester compound obtained from a fatty acid having from 8 to 30 carbon atoms and a diol having from 2 to 10 carbon atoms, and a surfactant, and the additive (B) is at least one compound selected from the group consisting of a metallic hydroxide, a metallic acetate salt, a metallic alkoxide, a metallic carbonate salt and a fatty acid.
    Type: Grant
    Filed: May 31, 2007
    Date of Patent: September 25, 2012
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Ryoji Otaki, Jun Mitadera, Tomonori Kato, Tomomichi Kanda
  • Patent number: 8268934
    Abstract: Methods of making miscible and compatible immiscible polymer blends are disclosed. The polymer blends have a polyimide as a component. The miscible polymer blends have a single glass transition temperature. The compatible polymer blends have two glass transition temperatures.
    Type: Grant
    Filed: November 22, 2006
    Date of Patent: September 18, 2012
    Assignee: Sabic Innovative Plastics IP B.V.
    Inventors: Robert Russell Gallucci, Tara Mullen, Roy Odle, Kapil Chandrakant Sheth, James M. White
  • Patent number: 8263732
    Abstract: [Object] To obtain an alignment film having excellent alignment stability of a liquid crystal and a high voltage holding ratio by application of linearly polarized light to a polyamic acid having a specific structure and then imidization under heat. [Solving Means] A photo-alignment film is obtained by: applying a polyamic acid solution on a substrate, where the polyamic acid contains, in its main chain, at least a group having unsaturated groups having 1 to 3 carbon-carbon double bonds or 1 to 4 triple bonds; vaporizing a solvent from a film formed; applying linearly polarized light to the film after the vaporization of the solvent; and then heating the film to imidize the polyamic acid.
    Type: Grant
    Filed: March 12, 2007
    Date of Patent: September 11, 2012
    Assignees: JNC Corporation, Chisso Petrochemical Corporation
    Inventor: Norio Tamura
  • Publication number: 20120220680
    Abstract: The present invention relates to biodegradable aliphatic-aromatic polyesters obtained from aliphatic dicarboxylic acids, polyfunctional aromatic acids and diols, wherein the polyfunctional aromatic acids are constituted by mixtures of acids of renewable and synthetic origin.
    Type: Application
    Filed: November 5, 2010
    Publication date: August 30, 2012
    Applicant: Novamont S.P.A.
    Inventors: Catia Bastioli, Giampietro Borsotti, Luigi Capuzzi, Gian Tomaso Masala, Tiziana Milizia, Roberto Vallero
  • Patent number: 8252868
    Abstract: A thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property containing (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer of (B1) a hard segment block with at least one of a polyamide, polyester, polyolefin or polyurethane, and (B2) a soft segment block having an ether bond.
    Type: Grant
    Filed: November 4, 2011
    Date of Patent: August 28, 2012
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Masaaki Mawatari, Tatsuya Toneri
  • Publication number: 20120183749
    Abstract: The invention relates to a polyesteramide resin containing ester groups and at least one amide group in the back-bone characterized in that it has at least one hydroxyalkylamide endgroup, and a Tg<0° C.
    Type: Application
    Filed: July 16, 2010
    Publication date: July 19, 2012
    Inventors: Franciscus Johannes Marie Derks, Jelle Bemandas Otto Van Der Werf
  • Publication number: 20120157605
    Abstract: Thermoplastic molding compositions, comprising A) from 10 to 99% by weight of at least one thermoplastic polyamide, B) from 0.01 to 50% by weight of B1) at least one highly branched or hyperbranched polycarbonate with an OH number of from 1 to 600 mg KOH/g of polycarbonate (to DIN 53240, Part 2), or B2) at least one highly branched or hyperbranched polyester of AxBy type, where x is at least 1.1 and y is at least 2.1, or a mixture of these, C) from 0 to 60% by weight of other additives, where the total of the percentages by weight of components A) to C) is 100%.
    Type: Application
    Filed: March 1, 2012
    Publication date: June 21, 2012
    Applicant: BASF SE*
    Inventors: Peter Eibeck, Bernd Bruchmann, Andreas Eipper, Jean-Francois Stumbe, Ralf Neuhaus, Michael Fischer, Jochen Engelmann, Philippe Desbois
  • Patent number: 8196627
    Abstract: A tire includes at least one outer structural element, wherein the at least one outer structural element is at least partially coated by at least one coating layer including a crosslinked composition obtained by reacting: (a) at least one polysulfide polymer; (b) at least one thermoplastic polymer having at least one hydroxyl group; with (c) at least one polyisocyanate. Preferably, the at least one structural element is at least one of the tire sidewalls.
    Type: Grant
    Filed: May 31, 2006
    Date of Patent: June 12, 2012
    Assignee: Pirelli Tyre S.p.A.
    Inventor: Fabio Negroni
  • Patent number: 8193302
    Abstract: Described as one aspect of the invention are polyester compositions containing: (I) at least one polyester which comprises: (a) a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) 1 to 99 mole % of 2,2,4,4-tetramethyl-1,3 -cyclobutanediol residues; and (ii) 1 to 99 mole % of cyclohexanedimethanol residues; and (II) at least one thermal stabilizer chosen from at least one of alkyl phosphate esters, aryl phosphate esters, mixed alkyl aryl phosphate esters, reaction products thereof, and mixtures thereof; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: June 5, 2012
    Assignee: Eastman Chemical Company
    Inventors: Ted Calvin Germroth, Gary Wayne Connell, Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, Benjamin Fredrick Barton, Damon Bryan Shackelford
  • Patent number: 8188209
    Abstract: A curable polyimide resin composition containing a polyimide resin obtainable from by a reaction of a reaction mixture containing a diisocyanate compound, a carbonate group-containing diol compound and an imide compound having two terminal hydroxyhydrocarbyl groups gives a cured insulation film having improved characteristics.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: May 29, 2012
    Assignee: Ube Industries, Ltd.
    Inventors: Masahiro Naiki, Ryoichi Takasawa, Shuichi Maeda, Tetsuji Hirano, Masayuki Kinouchi
  • Patent number: 8188185
    Abstract: A biodegradable packaging film is provided. The film is formed from a blend that contains a thermoplastic starch and polylactic acid. Starch is a relatively inexpensive natural polymer that is also renewable and biodegradable. Polylactic acid is likewise an inexpensive synthetic polymer that is biodegradable and renewable, yet also capable of providing increased tensile strength to the film. Although providing a good combination of biodegradability/renewability and increased tensile strength, the polylactic acid is also relatively rigid and can result in films having a relatively high stiffness (e.g., high modulus of elasticity) and low ductility. While more ductile than polylactic acid, the thermoplastic starch is often difficult to melt process in film forming processes and very sensitive to moisture and water vapor, reducing its ability to be used as a stand alone packaging film.
    Type: Grant
    Filed: June 30, 2008
    Date of Patent: May 29, 2012
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: James H. Wang, Sara A. Funk
  • Publication number: 20120095168
    Abstract: A method for controlling the physical state of an ultra-high molecular weight polymer to make the ultra-high molecular weight polymer suitable for further processing, and related polymers compositions methods and systems, wherein the method comprises combining a catalyst, monomers, and an additive, for a time and under condition to allow synthesis of a nascent polymer and co-crystallization of the nascent polymer with the additive.
    Type: Application
    Filed: October 18, 2011
    Publication date: April 19, 2012
    Inventors: Julia A. KORNFIELD, Artemis AILIANOU, Sara RONCA, Sanjay RASTOGI, Giuseppe FORTE
  • Publication number: 20120062228
    Abstract: This invention relates to the preparation of polyamide block copolymers by sequential monomer addition. More particularly, it relates to catalysts capable of copolymerizing not only cyclic amides, but other monomers such as cyclic esters and epoxides as well, using sequential addition so as to produce useful and novel block copolymers.
    Type: Application
    Filed: November 21, 2011
    Publication date: March 15, 2012
    Applicant: E. I. DU PONT DE NEMOURS AND COMPANY
    Inventors: David T. Williamson, Elizabeth Forrester McCord, Wilson Tam
  • Patent number: 8133417
    Abstract: Disclosed is a process for the preparation of shaped articles such as, for example, sheeting, films, tubes, bottles, preforms and profiles, having high transparency and low haze comprising immiscible blends of one or more thermoplastic polymers selected from polyesters, polycarbonates, and polyarylates, and a copolyamide or a transamidized, homogeneous blend of a least two polyamides. The components of the immiscible blend which have refractive indices which differ by about 0.006 to about ?0.0006. The small difference in the refractive indices enables the incorporation of regrind into the polymer composition to produce transparent shaped articles. These articles may have one or more layers and can exhibit improved excellent barrier properties and good melt processability while retaining excellent mechanical properties. Metal catalysts can be incorporated into the compositions to produce shaped articles having oxygen-scavenging properties.
    Type: Grant
    Filed: April 29, 2011
    Date of Patent: March 13, 2012
    Assignee: Eastman Chemical Company
    Inventors: Marcus David Shelby, Wesley Raymond Hale, Thomas Joseph Pecorini, Martin Emerson Rogers, Spencer Allen Gilliam, Michael Duane Cliffton, Mark Edward Stewart
  • Patent number: 8133967
    Abstract: Described are restaurant smallware, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.55 to 0.0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 110° C. to 160° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate.
    Type: Grant
    Filed: October 7, 2010
    Date of Patent: March 13, 2012
    Assignee: Eastman Chemical Company
    Inventors: Thomas Joseph Pecorini, Douglas Stephens McWilliams, Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
  • Publication number: 20120047634
    Abstract: Embodiments of the present disclosure include helmet liners, helmets, helmets with deflective structures, helmets with thermochromic features, and methods of making helmet liners, helmets, helmets with deflective structures, and helmets with thermochromic features.
    Type: Application
    Filed: May 14, 2010
    Publication date: March 1, 2012
    Inventor: Uday Vaidya
  • Patent number: 8119762
    Abstract: Described are film or sheet, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.55 to 0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 110° C. to 160° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate.
    Type: Grant
    Filed: November 10, 2010
    Date of Patent: February 21, 2012
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
  • Patent number: 8119761
    Abstract: Described are polyester compositions comprising at least one polyester which comprises terephthalic acid residues in the amount from 80 to 100 mole %, 2,2,4,4-tetramethyl-1,3- cyclobutanediol in the preferable amount from 30 to 40 mole % and 1,4-cyclohexanedimethanol in the preferable amount from 60 to 70 mole % , wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mote %; and the inherent viscosity of polyester is from 0.55 to 0.68 dL/g as determined in 60/40 (wt/wt) phenol/tetrachtoroethane at a concentration of 0.5 g/100 ml at 25° C., polyester has a Tg from 110 to 160° C. and polyester composition comprises no polycarbonate. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: February 21, 2012
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
  • Patent number: 8114387
    Abstract: Copolymers having linked internal polyether blocks and internal polyamide blocks have advantageous physical properties and solvent-gelling abilities. The copolymer may be prepared from a reaction mixture that contains 1,4-cyclohexane dicarboxylic acid (CHDA) and poly(alkyleneoxy) diamine (PAODA). Optionally, the reaction mixture contains no monofunctional compound reactive with either amine or carboxylic acid groups, however some of this monofunctional compound may be present. Dimer diamine and/or dimer acid may be present in the reaction mixture. A copolymer may also be prepared from a reaction mixture containing dimer acid and at least two diamine compound(s) including PAODA and short-chain aliphatic diamine having 2-6 carbons (SDA), wherein: a) the reaction mixture comprises x grams of PAODA and y grams of SDA, and x/(x+y) is 0.8-0.98; b) the reaction mixture weighs z grams, and x/z is at least 0.
    Type: Grant
    Filed: May 24, 2007
    Date of Patent: February 14, 2012
    Assignee: Arizona Chemical Company, LLC
    Inventor: Mark S. Pavlin
  • Publication number: 20120021158
    Abstract: Described are polyester compositions comprising (a) a dicarboxylicacidcomponent comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, wherein said 2,2,4,4-tetramethyl-1,3-cyclobutanediol contains certain cis to trans ratios; and 1,4-cyclohexanedimethanol residues.
    Type: Application
    Filed: June 17, 2011
    Publication date: January 26, 2012
    Applicant: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, David Scott Porter, Gary Wayne Connell
  • Patent number: 8101705
    Abstract: Described are articles, comprising polyester based composition, comprising dicarboxylic acid component as terephthalic acid residues and optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues and glycol component, comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and cyclohexanedimethanol residues. The polyester composition has the inherent viscosity from 0.60 to 0.75 dL/g as determined in 60/40 (wt/wt) phenol/tetrachloroethane at a concentration of 0.5 g/100 ml at 25° C., glass transition temperature Tg of 100° C. to 130° C., notched Izod impact strength of at least 7.5 ft-lb/inch at 23° C. according to ASTM D256 with a 10-mil notch in a ?-inch thick bar, melt viscosity is less than 10,000 poise as measured at 1 radian/second on a rotary melt rheometer at 290° C. and does not contain polycarbonate. Composition can be manufactured into articles as fibers, films, bottles or sheets.
    Type: Grant
    Filed: May 20, 2010
    Date of Patent: January 24, 2012
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephen McWilliams, David Scott Porter, Gary Wayne Connell
  • Patent number: 8097343
    Abstract: The present invention describes compositions and methods for trapping/capturing and/or destroying dangerous substances such as chemical and biological warfare agents. The present invention relates to dendritic polymers, specifically, to quaternary ammonium functionalized dendritic polymers and N-Halamine functionalized dendritic polymers. Such dendrimers are useful for the capture and neutralization of biological and chemical warfare agents.
    Type: Grant
    Filed: June 12, 2006
    Date of Patent: January 17, 2012
    Assignees: Triton Systems, Inc., DSM IP Assets B.V.
    Inventors: Khaled Mahmud, Lawino Kagumba, Franciscus Johannes Marie Derks
  • Patent number: 8097685
    Abstract: The present invention is directed to a hyperbranched-polyester comprising at least one kind of a structural unit selected from an aromatic oxycarbonyl unit (P), aromatic and/or aliphatic dioxy units (Q), and an aromatic dicarboxy unit (R), and a trifunctional or higher polyfunctional organic residue (B), wherein the content of B is within a range from 7.5 to 50 mol % based on entire monomers constituting the hyperbranched-polyester. The present invention provides a hyperbranched-polyester which can remarkably improve thin-wall flowability, stiffness and gas barrier property by blending with a thermoplastic resin, and a thermoplastic resin composition blended with the same.
    Type: Grant
    Filed: March 30, 2007
    Date of Patent: January 17, 2012
    Assignee: TORAY Industries, Inc.
    Inventors: Koji Tachikawa, Makito Yokoe, Mitsushige Hamaguchi, Makiko Saito, Hideo Matsuoka, Toru Yamanaka
  • Patent number: 8097684
    Abstract: Thermoplastic compositions containing a polyamide and/or polyester matrix and a variety of additives have high fluidity and can be shaped into plastic articles with good mechanical properties and an improved surface appearance.
    Type: Grant
    Filed: June 22, 2004
    Date of Patent: January 17, 2012
    Assignee: Rhodia Engineering Plastics S.R.L.
    Inventors: Florence Clement, Franck Touraud, Nicolangelo Peduto, Christophe Lapierre, Frédéric Tronc
  • Patent number: 8084538
    Abstract: The present invention provides a thermoplastic polymer composition capable of exhibiting excellent impact resistance, durability and destaticizing property. The present invention relates to a thermoplastic polymer composition comprising (A) 50 to 95% by mass of an aliphatic polyester-based resin and (B) 5 to 50% by mass of a block copolymer comprising (B1) a hard segment block comprising at least one polymer selected from the group consisting of a polyamide, a polyester, a polyolefin and a polyurethane, and (B2) a soft segment block having an ether bond, with the proviso that a total amount of the components (A) and (B) is 100% by mass.
    Type: Grant
    Filed: January 26, 2009
    Date of Patent: December 27, 2011
    Assignee: Techno Polymer Co., Ltd.
    Inventors: Masaaki Mawatari, Tatsuya Toneri
  • Publication number: 20110306730
    Abstract: Described are polyesters comprising (a) a dicarboxylic acid component comprising terephthalic acid residues; optionally, aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and cyclohexanedimethanol residues. The polyesters may be manufactured into articles such as fibers, films, bottles or sheets.
    Type: Application
    Filed: August 23, 2011
    Publication date: December 15, 2011
    Applicant: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
  • Publication number: 20110305883
    Abstract: Provided are an adhesive resin composition that is halogen-free, has good adhesiveness, solder heat resistance, and flame retardancy, and has good flow characteristics, and a laminate and a flexible printed wiring board using the same. The adhesive resin composition contains a phosphorus-containing epoxy resin and/or a phosphorus-containing phenoxy resin, a phosphorus-containing polyester resin having a weight-average molecular weight of more than 20,000 and 150,000 or less, another thermoplastic resin, and a curing agent. The adhesive resin composition preferably further contains a benzoxazine compound. Preferably, substantially no inorganic filler is mixed in the adhesive resin composition.
    Type: Application
    Filed: January 18, 2010
    Publication date: December 15, 2011
    Applicants: SUMITOMO ELECTRIC PRINTED CIRCUITS, INC., SUMITOMO ELECTRIC INDUSTRIES, LTD.
    Inventors: Shingo Kaimori, Jun Sugawara, Akira Mizoguchi, Syougo Asai, Takuma Yoshisaka, Naota Uenishi
  • Patent number: 8071692
    Abstract: The invention provides methods for making copolymers and multi-arm block copolymers useful as drug delivery vehicles. The multi-arm block copolymers comprise a central core molecule, such as a residue of a polyol, and at least three copolymer arms covalently attached to the central core molecule, each copolymer arm comprising an inner hydrophobic polymer segment covalently attached to the central core molecule and an outer hydrophilic polymer segment covalently attached to the hydrophobic polymer segment, wherein the central core molecule and the hydrophobic polymer segment define a hydrophobic core region. The solubility of hydrophobic biologically active agents can be improved by entrapment within the hydrophobic core region of the block copolymer. The invention further includes pharmaceutical compositions including such block copolymers, pharmaceutical compositions, and methods of using the block copolymers as drug delivery vehicles.
    Type: Grant
    Filed: August 7, 2009
    Date of Patent: December 6, 2011
    Assignee: Nektar Therapeutics
    Inventor: Xuan Zhao
  • Patent number: 8067525
    Abstract: Described are film(s) and/or sheet(s) comprising polyesters comprising (a) a dicarboxylic acid component having terephthalic acid residues; optionally, aromatic dicarboxylic acid or aliphatic dicarboxylic acid residues; 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and 1,4-cyclohexanedimethanol residues.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: November 29, 2011
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
  • Patent number: 8063173
    Abstract: Described as one aspect of the invention are polyesters containing (a) a dicarboxylic acid component having from 70 to 100 mole % of terephthalic acid residues and up to 30 mole % of aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; and (b) a glycol component having from 11 to 25 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, and 75 to 89 mole % of 1,4-cyclohexanedimethanol residues; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and the total mole % of the glycol component is 100 mole %. The polyesters may be manufactured into articles.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: November 22, 2011
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
  • Patent number: 8063172
    Abstract: Described are film(s) and/or sheet(s) made using polyester compositions comprising polyesters comprising (a) a dicarboxylic acid component comprising 70 to 100 mole % of terephthalic acid residues, and up to 30 mole % of aromatic dicarboxylic acid residues or aliphatic dicarboxylic acid residues; and (b) a glycol component comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues, and 1,4-cyclohexanedimethanol residues.
    Type: Grant
    Filed: March 28, 2006
    Date of Patent: November 22, 2011
    Assignee: Eastman Chemical Company
    Inventors: Emmett Dudley Crawford, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell
  • Publication number: 20110262672
    Abstract: There is provided a silicone-polyoxamide process additive for use in high clarity applications, articles made using the silicone-polyoxamide process additive, and methods for making these articles.
    Type: Application
    Filed: November 20, 2009
    Publication date: October 27, 2011
    Inventors: Claude Lavallee, Audrey A. Sherman
  • Publication number: 20110263791
    Abstract: A polyetherimide having an OH content that is greater than 0 and equal or less than 100 ppm; a Relative Thermal Index that is greater than or equal to 170° C.; and a chlorine content that is greater than 0 ppm is disclosed herein. A method for preparing the polyetherimide is also disclosed.
    Type: Application
    Filed: December 28, 2010
    Publication date: October 27, 2011
    Applicant: SABIC INNOVATIVE PLASTICS IP B.V.
    Inventors: Hendrich Chiong, Thomas Link Guggenheim, Farid Fouad Khouri, Matthew L. Kuhlman, Miguel Angel Navarro de Castro, Roy Ray Odle, Brennan A. Smith
  • Publication number: 20110224330
    Abstract: Fiber reinforced composites fabricated using a low-temperature, solution-based growth of nanowires such as ZnO nanowires on the surface of the reinforcing fibers such as carbon fibers and functionalized aramid fibers. The composites with nanowire interphase may have an enhanced fiber/matrix interface strength and a comparable in-plane strength, as compared to similar composites without such nanowire interphase.
    Type: Application
    Filed: June 26, 2009
    Publication date: September 15, 2011
    Inventors: Henry A. Sodano, Gregory John Ehlert
  • Patent number: 8013021
    Abstract: A composition comprising (a) a resin composition comprising a block copolymer of the formula hydrocarbon-polyether-polyamide-polyether-hydrocarbon; and (b) a polar liquid. The block copolymer may be prepared by a process comprising reacting together reactants comprising dimer acid, diamine, and a polyether having termination at one end selected from amine, hydroxyl and carboxyl, and termination at another end selected from hydrocarbons. The polar liquid may be one or more of an aromatic liquid, a polar aprotic liquid, a ketone-containing liquid, an ester-containing liquid, an ether-containing liquid, an amide-containing liquid and a sulfoxide-containing liquid. The composition may be a gel at room temperature.
    Type: Grant
    Filed: January 26, 2009
    Date of Patent: September 6, 2011
    Assignee: Arizona Chemical Company, LLC
    Inventors: Richard C MacQueen, Mark S Pavlin
  • Patent number: RE42925
    Abstract: Compositions comprising a polyester resin and a polyamide derived from a dicarboxylic acid with 6-22 carbon atoms and from m-xylylene diamine having high-level gas barrier properties, obtained by mixing in the melted state the polyester resin premixed with a dianhydride of a tetracarboxylic acid and the polyamide, operating under conditions such as to render the polymeric components theologically rheologically compatible with each other. The compositions are suitable for preparing containers and biaxially-orientated films.
    Type: Grant
    Filed: November 17, 2008
    Date of Patent: November 15, 2011
    Assignee: Cobarr S.p.A
    Inventors: Hussein Al Ghatta, Sandro Cobror, Tonino Severini