Mixed With O-c(=o)-o-, Hal-c(=o)-o-, Or Hal-c(=o)-hal Containing Reactant Or Polymer Derived Therefrom; Or Wherein Solid Polymer Is Derived From A Hal-c(=o)-hal, O-c(=o)-o-, Or Hal-c(=o)-o-, A Polycarboxylic Acid Or Derivative And A Polyhydroxy Reactant Patents (Class 525/439)
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Patent number: 11427679Abstract: A polycarbonate resin composition containing 0.1 to 10 parts by mass of a polycarbonate copolymer (B) having carbonate bonding between (B1) bisphenol A and a (B2) polyalkylene glycol and 0.005 to 0.5 parts by mass of a phosphorus-containing stabilizer (C) relative to 100 parts by mass of a polycarbonate resin (A).Type: GrantFiled: February 25, 2019Date of Patent: August 30, 2022Assignees: Mitsubishi Engineering-Plastics Corporation, MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Keisuke Tomita, Hidefumi Harada, Takehiko Isobe, Keisuke Shimokawa, Jungo Taguchi
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Patent number: 11396165Abstract: Embodiments provide a multilayer film in which: a first acrylic resin layer (?1), an aromatic polycarbonate resin layer (?), and a second acrylic resin layer (?2) are directly laminated in the stated order; the aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (?) is a product of ester exchange between a polycarbonic acid ester of an aromatic dihydroxy compound and a low-crystalline or amorphous aromatic polyester; and the relationships (T??T?1)?30 and (T??T?2)?30 (where T?1 is the glass transition temperature of the acrylic resin constituting the first acrylic resin layer (?1), T?2 is the glass transition temperature of the acrylic resin constituting the second acrylic resin layer (?2), T? is the glass transition temperature of the aromatic polycarbonate resin constituting the aromatic polycarbonate resin layer (?), and all of the temperatures are measured in degrees Celsius) are satisfied.Type: GrantFiled: May 18, 2018Date of Patent: July 26, 2022Inventors: Hideaki Yambe, Kohei Nakashima
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Patent number: 11154635Abstract: A polymeric material that includes a thermoplastic composition containing a continuous phase that includes a polyester and a copolyetherester elastomer is provided. The copolyetherester elastomer is dispersed within the continuous phase in the form of discrete domains. A porous network is defined within the thermoplastic composition that includes a plurality of nanopores.Type: GrantFiled: January 19, 2018Date of Patent: October 26, 2021Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Ryan J. McEneany, Yuewen Xu
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Patent number: 11084897Abstract: Techniques regarding chemical compounds comprising perfluoroaryl groups that can facilitate post-synthesis functionalization are provided. For example, one or more embodiments described herein can comprise a chemical compound. The chemical compound can comprise a molecular backbone. The chemical compound can also comprise a pendent functional group bonded to the molecular backbone. The pendent functional group can comprise a perfluoroaryl group and a methylene group.Type: GrantFiled: December 12, 2017Date of Patent: August 10, 2021Assignee: INTERNATIONAL BUSINESS MACHINES CORPORATIONInventors: James L. Hedrick, Nathaniel H. Park, Gavin Jones
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Patent number: 10717110Abstract: The present invention relates to an aqueous dispersion (P) of at least two polymeric resins (P1) and (P2) which are different from one another, (P1) being a copolymer obtainable by copolymerizing ethylenically unsaturated monomers in the presence of at least one polyurethane resin having polymerizable carbon double bonds, and (P2) being a polyester having functional hydroxyl groups, which has an acid number of <25 mg of KOH per g of polyester, and (P) being obtainable by a process encompassing at least four steps (1), (2), (3), and (4), to an aqueous coating composition comprising the aqueous dispersion (P), to a process for at least partly coating at least one substrate metal surface, coated with at least one primer coat, with a topcoat, using the aqueous coating composition, and to an at least partly coated substrate obtainable by such a process.Type: GrantFiled: May 13, 2015Date of Patent: July 21, 2020Assignee: BASF Coatings GmbHInventors: Frank Joege, Dominik Vollmann, Joerg Ressel, Lara Schwarzenberg
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Patent number: 10557034Abstract: A polycarbonate resin composition of the present invention comprises: a polycarbonate resin; a polyalkylene glycol; an epoxy ester compound containing an ester group and an epoxy group; and a halogenated polycarbonate oligomer. The polycarbonate resin composition has excellent discoloration resistance, color, hydrolysis resistance, flame retardancy and the like even after being irradiated with ionizing radiation.Type: GrantFiled: August 30, 2016Date of Patent: February 11, 2020Assignee: Lotte Advanced Materials Co., Ltd.Inventors: Woo Suk Chei, Hyun Hye Jang, Jung Jae Lee, Jun Ho Chi, Jong Chan Hur, O Sung Kwon
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Patent number: 10351666Abstract: A catalytic composition for preparing a polyethylene terephthalate (PET) resin is provided. The catalytic composition comprises a polycondensation catalyst and cesium tungsten oxide (CsxWO3-yCly), and 0<x?1 and 0?y?0.5. A PET resin prepared by the catalytic composition above is also provided. The PET resin comprises 2-80 ppm of cesium tungsten oxide. This catalytic composition can solve the problems of slow solid-state polymerization rate of the PET preparation and thus the long preparation time, as well as yellowing. Moreover, the PET resin can absorb infrared radiation.Type: GrantFiled: February 21, 2017Date of Patent: July 16, 2019Assignees: Almighty Green Material Inc., Chung How Paint Factory Co., Ltd.Inventors: Wen-Ting Wang, Sung-Jeng Jong, Pao-Tang Chung
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Patent number: 10240038Abstract: The present invention provides a flame resistant polycarbonate-based resin composition and molded articles thereof, and specifically, a polycarbonate-based resin composition having excellent heat resistance and impact resistance and improved flame retardancy, and molded articles formed from the polycarbonate-based resin composition.Type: GrantFiled: December 4, 2015Date of Patent: March 26, 2019Assignee: LG CHEM, LTD.Inventors: Moo Seok Lee, Ryul Lee
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Patent number: 10221279Abstract: Provided is a polycarbonate resin molding material, including an aromatic polycarbonate resin (A), in which the polycarbonate resin molding material has: a content of o-hydroxyacetophenone measured by a predetermined method (1) of 1 ppm by mass or less; and a YI value measured by a predetermined method (2) of 1.21 or less.Type: GrantFiled: July 6, 2017Date of Patent: March 5, 2019Assignee: IDEMITSU KOSAN CO., LTD.Inventors: Masami Takimoto, Takahiro Torii, Mitsugu Nakae
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Patent number: 10137679Abstract: A material deposition system for additive manufacturing including an extruder and a measuring device for measuring the viscosity and/or other rheological properties of a build material contained within the extruder. The measuring device may provide feedback to a controller for controlling one or more parameters depending on the measured viscosity and/or other rheological properties of the build material within the extruder. Two or more feed materials may be supplied to the extruder and a mixing device may be configured to mix the feed materials within the extruder to create a blended deposition material. The mixing device may be operatively coupled to the measuring device for simultaneously measuring the viscosity and/or other rheological properties of the materials during mixing. The controller may be configured to independently control one or more parameters associated with the materials depending on the viscosity and/or other rheological properties measured by the measuring device.Type: GrantFiled: October 29, 2015Date of Patent: November 27, 2018Assignee: Raytheon CompanyInventor: Michael Brennan
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Patent number: 10093797Abstract: Disclosed is a process for the manufacture of a polyalkylene terephthalate such as polybutylene terephthalate. In particular, the process comprises employing a titanium-containing catalyst formed by the reaction product of tetraalkyl titanate and a complexing agent comprising a phosphorous, nitrogen or boron atom. The process is used to prepare polyalkylene terephthalates characterized by improved hydrostability, as well as compositions derived therefrom.Type: GrantFiled: October 7, 2015Date of Patent: October 9, 2018Assignee: SABIC Global Technologies B.V.Inventors: Husnu Alp Alidedeoglu, Tianhua Ding, Ganesh Kannan
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Patent number: 10017606Abstract: A molded article comprising at least one polyester which comprises: (a) a dicarboxylic acid component comprising: i) 95 to 99.99 mole % of terephthalic acid residues; and ii) 0.01 to 5 mole % of isophthalic acid; and (b) a glycol component comprising: i) 5 to 15 mole % of 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; ii) 85 to 95 mole % of 1,4-cyclohexanedimethanol residues; and iii) 5 mole % or less of modifying glycols which are not 2,2,4,4-tetramethyl-1,3-cyclobutanediol or cyclohexanedimethanol, wherein the polyester has an inherent viscosity from 0.80 to 1.0 dL/g and a glass transition temperature (Tg) of 90 to 110° C., and wherein the molded article does not contain polycarbonate.Type: GrantFiled: March 6, 2017Date of Patent: July 10, 2018Assignee: Eastman Chemical CompanyInventors: Emmett Dudley Crawford, Thomas Joseph Pecorini, Douglas Stephens McWilliams, David Scott Porter, Gary Wayne Connell, Ted Calvin Germroth, Benjamin Fredrick Barton, Damon Bryan Shackelford
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Patent number: 10008328Abstract: A stretched film includes a dispersion of at least one polyester and/or polycarbonate in a matrix of at least one polyester and/or polycarbonate different from the first polyester and/or polycarbonate, the percentage by weight of the dispersed polyester and/or polycarbonate in the dispersion being less than 50% and the dispersed polyester and/or polycarbonate being in the form of platelets. The stretched film can be used as a dielectric in a capacitor.Type: GrantFiled: April 16, 2015Date of Patent: June 26, 2018Assignee: DUPONT TEIJIN FILMS U.S. LIMITED PARTNERSHIPInventors: Alexis Grosrenaud, Lucien Schosseler
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Patent number: 9944795Abstract: Functionalized non-halogenated flame retardants are disclosed having improved hydrolytic stability, represented by decreased conductivity measured in units of ? S/cm when immersed in distilled water and heated to 80 C. The functionalized flame retardant comprises polyphosphonate functionalized by epoxy-functional styrene-acrylic oligomer or aromatic carbodiimide, and optionally antioxidant. Also disclosed are polymer compounds, comprising the functionalized flame retardant described above and a second polymer resin; and flame retardant plastic articles made from such polymer compounds.Type: GrantFiled: September 11, 2013Date of Patent: April 17, 2018Assignee: PolyOne CorporationInventors: Chongfu Zhou, Roger W. Avakian
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Patent number: 9453128Abstract: A railway vehicle component, wherein the component is a partition or a light cover, and wherein the component is molded or formed from a thermoplastic polymer composition comprising: a siloxane-containing copolymer in an amount effective to provide a total of 0.2 to 6.5 wt % of siloxane units based on the total weight of the polymers in the thermoplastic polymer composition, a bromine-containing polymer in an amount effective to provide 9 to 13 wt % of bromine, based on the total weight of the polymers in the thermoplastic polymer composition, and optionally a third polymer, wherein the wt % of the siloxane-containing copolymer, the bromine-containing polymer, and the optional third polymer, sum to 100 wt %, and 0.05 to 10 wt % of a light diffuser additive, based on the total weight of polymers in the thermoplastic polymer composition.Type: GrantFiled: March 30, 2012Date of Patent: September 27, 2016Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Paul Dean Sybert, James Franklin Hoover, Thomas L. Evans
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Patent number: 9453127Abstract: This thermoplastic resin composition (D) contains a polycarbonate resin (A), a polyester resin (B) which comprises diol structural units and dicarboxylic acid structural units in which the ratio of diol structural units having a cyclic acetal skeleton to all diol structural units is 20 to 60 mol %, and a polyester resin (C) other than the polyester resin (B), wherein the ratio of the polycarbonate resin (A) to the total of the polycarbonate resin (A), the polyester resin (B) and the polyester resin (C) is 15 to 98 wt %, the ratio of the polyester resin (B) is 1 to 80 wt %, and the ratio of the polyester resin (C) is 1 to 60 wt %; further provided is a sheet using said thermoplastic resin.Type: GrantFiled: July 22, 2013Date of Patent: September 27, 2016Assignee: MITSUBISHI GAS CHEMICAL COMPANY, INC.Inventors: Atsuko Iwasaki, Kazunobu Sato
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Patent number: 9365719Abstract: A marine vehicle component wherein the component is a partition or a light cover, and wherein the marine vehicle component is molded or formed from a thermoplastic polymer composition comprising a siloxane-containing copolymer in an amount effective to provide a total of 0.2 to 6.5 wt % of siloxane units based on the total weight of the polymers in the thermoplastic polymer composition, a bromine-containing polymer in an amount effective to provide 9 to 13 wt % of bromine, based on the total weight of the polymers in the thermoplastic polymer composition, and optionally a third polymer, wherein the wt % of the siloxane-containing copolymer, the bromine-containing polymer, and the optional third polymer, sum to 100 wt %, and 0.05 to 10 wt % of a light diffuser additive, based on the total weight of polymers in the thermoplastic polymer composition.Type: GrantFiled: March 30, 2012Date of Patent: June 14, 2016Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Paul Dean Sybert, James Franklin Hoover, Thomas L. Evans
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Patent number: 9296898Abstract: A poly(siloxane) copolymer composition comprising: a first polymer comprising a first repeating unit, and a poly(siloxane) block unit, a second polymer different from the first polymer and comprising of bromine; and optionally, one or more third polymers different from the first polymer and second polymer; wherein siloxane units are present in the composition in an amount of at least 0.3 wt %, and bromine is present in the composition in an amount of at least 7.8 wt %, each based on the sum of the wt % of the first, second, and optional one or more third polymers; and further wherein an article molded from the composition has an OSU integrated 2 minute heat release test value of less than 65 kW-min/m2 and a peak heat release rate of less than 65 kW/m2, and an E662 smoke test Dmax value of less than 200.Type: GrantFiled: December 30, 2014Date of Patent: March 29, 2016Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Paul Dean Sybert, Laura Gayle Schultz Hume, James Franklin Hoover, Thomas L. Evans
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Patent number: 9290868Abstract: A nonwoven fabric is provided that has biodegradability and has excellent mechanical strength and excellent texture in combination, and a fiber product containing the nonwoven fabric is provided. The biodegradable nonwoven fabric contains at least two kinds of fibers including a fiber A and a fiber B, in which the fiber A contains a first component having biodegradability, and the fiber B contains a second component having biodegradability. The nonwoven fabric contains a mixed fiber web having a mixing ratio (weight ratio) of the fiber A and the fiber B in a range of from 5/95 to 95/5. The first component contains at least one member selected from the group consisting of an aliphatic polyester and an aliphatic polyester copolymer each having a melting point that is higher than a melting point of the second component. A half crystallization time at 85 degree Celsius of the second component is longer than a half crystallization time at 85 degree Celsius of the first component.Type: GrantFiled: April 23, 2010Date of Patent: March 22, 2016Assignees: JNC Corporation, CHISSO POLYPRO FIBER COMPANY LIMITEDInventors: Junji Iwata, Yasushi Matsuda, Mitsuru Kojima
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Patent number: 9266541Abstract: Seat components and claddings for railway molded or formed from a thermoplastic polymer composition comprising, based on the total weight of the composition, 50 to 93 wt. % of a specific polycarbonate; 4 to 30 wt. % of a poly(carbonate-siloxane) comprising bisphenol A carbonate units, and siloxane units; 3 to 20 wt. % of an organophosphorus compound in an amount effective to provide 0.1 to 2.0 wt. % of phosphorus, based on the total weight of the thermoplastic polymer composition; wherein an article having a thickness of 0.5 to 10 mm molded from the composition has a Ds-4 smoke density?300 measured according to ISO 5659-2, and a MAHRE?90 kW/m2 measured according to ISO 5660-1, a multiaxial impact energy ?100 J, and a ductility in multiaxial impact of 80 to 100% at +23° C. according to ISO 6603.Type: GrantFiled: May 1, 2013Date of Patent: February 23, 2016Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Mark Adrianus Johannes van der Mee, Roland Sebastian Assink, Robert Dirk van de Grampel, Paul Dean Sybert
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Patent number: 9269493Abstract: A stretched film includes a dispersion of at least one polyester and/or polycarbonate in a matrix of at least one polyester and/or polycarbonate different from the first polyester and/or polycarbonate, the percentage by weight of the dispersed polyester and/or polycarbonate in the dispersion being less than 50% and the dispersed polyester and/or polycarbonate being in the form of platelets. The stretched film can be used as a dielectric in a capacitor.Type: GrantFiled: July 7, 2014Date of Patent: February 23, 2016Assignee: DUPONT TEIJIN FILMS U.S. LIMITED PARTNERSHIPInventors: Alexis Grosrenaud, Lucien Schosseler
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Patent number: 9260561Abstract: Disclosed are polyestercarbonate copolymers comprising a carbonate unit of Formula (I), an ITR ester unit of Formula (V), and optionally a different carbonate unit of Formula (VI): wherein Ra, Rb, p, q, A, h, j, k, Rc, r, and R1 are as described herein. The polyestercarbonate copolymers have a combination of scratch resistance, good flow, and good weatherability.Type: GrantFiled: November 21, 2008Date of Patent: February 16, 2016Assignee: SABIC Global Technologies B.V.Inventors: Hans de Brouwer, Robert Dirk van Grampel, James F. Hoover, Adrianus Alphonsus Maria Kusters, Jan-Pleun Lens, Andries Jakobus Petrus van Zyl
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Patent number: 9228042Abstract: A variety of polymers and copolymers suitable for use as biologically compatible constructs and, as a non-limiting specific example, in the formation of degradable tissue scaffolds as well methods for synthesizing these polymers and copolymers are described. The polymers and copolymers have degradation rates that are substantially faster than those of previously described polymers suitable for the same uses. Copolymers having a synthesis route which enables one to fine tune the degradation rate by selecting the specific stoichiometry of the monomers in the resulting copolymer are also described. The disclosure also provides a novel synthesis route for maleoyl chloride which yields monomers suitable for use in the copolymer synthesis methods described herein.Type: GrantFiled: January 6, 2014Date of Patent: January 5, 2016Assignee: STC.UNMInventors: Elizabeth L Hedberg-Dirk, Shawn Dirk, Kirsten Cicotte
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Patent number: 9187639Abstract: Disclosed herein are blended thermoplastic compositions comprising at least one polycarbonate polymer, at least one polyester polymer, and at least one reinforcing filler. The thermal blended polycarbonate compositions can optionally further comprise at least one polycarbonate-polysiloxane copolymer, at least one impact modifier polymer, and/or at least one flame retardant. The resulting compositions can be used in the manufacture of articles requiring materials with high modulus and high flowability, while retaining good impact strength. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.Type: GrantFiled: June 4, 2014Date of Patent: November 17, 2015Assignee: SABIC Global Technologies B.V.Inventors: Yun Zheng, Shijie Song
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Patent number: 9163121Abstract: There is disclosed a polycarbonate and polysiloxane block copolymer includes 1 to 50 percent by mass of a siloxane portion derived from a polysiloxane block represented by the following formula (I) and 50 to 99 percent by mass of a carbonate portion derived from a polycarbonate block represented by the following formula (II). There can be provided a novel polycarbonate and polysiloxane block copolymer capable of readily imparting excellent flame retardance, and a flame retardant resin composition.Type: GrantFiled: March 8, 2013Date of Patent: October 20, 2015Assignee: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Masahiko Minemura, Mitsuhiro Takarada, Masaki Tanaka
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Patent number: 9102832Abstract: An aircraft component wherein the component is a partition or a light cover, and wherein the aircraft component is molded or formed from a thermoplastic polymer composition including: a siloxane-containing copolymer in an amount effective to provide a total of 0.2 to 6.5 wt % of siloxane units based on the total weight of the polymers in the thermoplastic polymer composition, a bromine-containing polymer in an amount effective to provide 9 to 13 wt % of bromine, based on the total weight of the polymers in the thermoplastic polymer composition, and optionally a third polymer, wherein the wt % of the siloxane-containing copolymer, the bromine-containing polymer, and the optional third polymer, sum to 100 wt %, and 0.05 to 10 wt % of a light diffuser additive, based on the total weight of polymers in the thermoplastic polymer composition.Type: GrantFiled: March 30, 2012Date of Patent: August 11, 2015Assignee: SABIC GLOBAL TECHNOLOGIES B.V.Inventors: Paul Dean Sybert, James Franklin Hoover, Laura G. Schultz Hume
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Patent number: 9040636Abstract: A hydroxy ester resin composition such as a vinyl ester resin including the reaction product of (a) divinylarene dioxide resin; and (b) at least one ring opening reactant such as at least one monocarboxylic acid for example (meth)acrylic acid, in the presence of (c) at least one non-gelling catalyst such as a Lewis acid catalyst; a process for making the hydroxy ester resin composition; a curable hydroxy ester resin composition such as a curable resin composition made from the hydroxy ester resin composition; a process for curing the curable hydroxy ester resin composition; and a cured product made from the curable hydroxy ester resin composition. The cured product made from the above hydroxy ester resin composition is thermally stable and offers improved properties such as a lower viscosity and a high heat resistance compared to known cured products prepared from known epoxy resins.Type: GrantFiled: November 29, 2012Date of Patent: May 26, 2015Assignee: Dow Global Technologies LLCInventor: E. J. Campbell
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Patent number: 9018291Abstract: Disclosed is a polyalkylene carbonate paint composition, which is a pre-coated metal (PCM) paint composition capable of being applied in various fields for architectural uses, domestic uses, coating a can, or the like, in which high hardness is required. The composition may provide a PCM paint capable of having a low smoke density and significantly decreasing discharge of toxic gas and smoke caused by combustion at the time of fire as compared to the existing laminate steel sheet and high gloss film. In addition, disclosed is a high hardness paint composition capable of being usefully used in a PCM print steel sheet applied to electric home appliances due to an excellent adhesion property to a metal material and excellent durability.Type: GrantFiled: February 25, 2014Date of Patent: April 28, 2015Assignee: SK Innovation Co., Ltd.Inventors: Ji Yeon Choi, Seung Gweon Hong, Yong Gu Lee, Gyu Hoe Kim
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Publication number: 20150099106Abstract: A resin composition including 40 parts by weight or more and less than 95 parts by weight of a polycarbonate resin and 5 parts by weight or more and less than 60 parts by weight of a polyester-polyether copolymer as a base resin, wherein the polyester-polyether copolymer is a copolymer which is obtained by a polymerization using a germanium compound catalyst, includes aromatic polyester units and modified polyether units represented by the following general formula 1, and has an IV value within a range of 0.30 to 1.00 can be well-balanced in moldability, heat resistance, impact resistance, and low linear expansion property, without deteriorating a surface appearance of a molding obtained therefrom.Type: ApplicationFiled: April 30, 2013Publication date: April 9, 2015Applicant: KANEKA CORPORATIONInventors: Hidekazu Kawakubo, Shuji Taketani, Tetsuro Yamamoto
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Patent number: 8962770Abstract: Disclosed herein is are thermoplastic compositions comprising a blend of a homopolycarbonate comprising units derived from an aromatic dihydroxy compound and a copolymer comprising isosorbide units and siloxane units. The copolymer comprising isosorbide units and siloxane units can further comprise non-isosorbide aliphatic units derived from a C14-44 aliphatic diacid, a C14-44 aliphatic diol or combination of these, aromatic units, aliphatic units derived from an oligomer having a weight average molecular weight of 900 to 4000 or a combination of some or all of the foregoing additional units.Type: GrantFiled: September 29, 2010Date of Patent: February 24, 2015Assignee: Sabic Global Technologies B.V.Inventors: Hans de Brouwer, Robert Dirk van de Grampel, Jan Henk Kamps, Jan Pleun Lens
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Patent number: 8952126Abstract: A method of making a pure block copolymer includes forming a crude block copolymer; heating a solution of the crude block copolymer and alcohol; and cooling the solution to promote precipitation of a purified block copolymer, wherein an amount of impurities remaining in the purified block copolymer is from about 0 to about 5 wt % based on a total weight of the purified block copolymer; a ratio of a polydispersity index of the crude block copolymer to a polydispersity index of the purified block copolymer is from about 1.02 to about 1.25; a ratio of a molecular weight of the crude block copolymer to a molecular weight of the purified block copolymer is from about 0.75 to about 1.0; and a ratio of a number average molecular weight of the crude block copolymer to a number average molecular weight of the purified block copolymer is from about 0.65 to about 1.Type: GrantFiled: July 10, 2013Date of Patent: February 10, 2015Assignees: Xerox Corporation, National Research Council of CanadaInventors: Andrew J. Myles, Karen A. Moffat, Jordan H. Wosnick, Valerie M. Farrugia
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Patent number: 8937127Abstract: A composition comprising: a first polymer comprising a poly(etherimide-siloxane) copolymer comprising (a) a repeating polyetherimide unit, and (b) a poly(siloxane) block unit, a second polymer different from the first polymer and comprising bromine; and optionally, a third polymer comprising a polycarbonate different from the first polymer and second polymer; wherein polysiloxane block units are present in the composition in an amount of at least 0.3 wt %, and bromine is present in the composition in an amount of at least 7.8 wt %, each based on the sum of the wt % of the first, second, and third polymers; and further wherein an article molded from the composition has an OSU integrated 2 minute heat release test value of less than 65 kW-min/m2 and a peak heat release rate of less than 65 kW/m2, and an E662 smoke test Dmax value of less than 200.Type: GrantFiled: September 30, 2011Date of Patent: January 20, 2015Assignee: SABIC Global Technologies B.V.Inventors: Paul D. Sybert, Thomas L. Evans
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Patent number: 8916270Abstract: Disclosed are compositions, glass filled compositions, articles made therefrom, and processes for making articles therefrom. In an embodiment, a composition can comprise: one or more polycarbonates wherein at least one of the polycarbonates is a polyester-polycarbonate having at least one unit derived from sebacic acid and has a biocontent of at least 5 weight % based upon a total weight of the polyester-polycarbonate, determined according ASTM-D6866; a glass content of 10 weight % or greater based upon a total weight of the composition; and an epoxy resin. The composition has a melt volume rate of greater than 10.5 cm3/10 minutes at 300° C./1.2 kg according to ASTM-D1238-10. A part molded having a 0.8 mm thickness molded from the composition has a gloss value of 89 or higher at 60°, according to ASTM-D523.Type: GrantFiled: August 2, 2012Date of Patent: December 23, 2014Assignee: Sabic Global Technologies B.V.Inventors: Jon Michael Malinoski, Thomas L. Evans
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Publication number: 20140357748Abstract: An object of the present invention is to provide a polycarbonate resin composition comprising a polycarbonate resin containing, as a raw material, isosorbide that is easy to produce and excellent in such as mechanical properties, etc., and a molded body, particularly a foam-molded body, composed of the resin composition. The present invention provides a foam-molded body of a resin composition containing a polycarbonate resin having at least a structural unit derived from a dihydroxy compound represented by the following formula (1): wherein the strain-hardening factor of uniaxial extensional viscosity of said resin composition is from 0.1 to 5.Type: ApplicationFiled: August 20, 2014Publication date: December 4, 2014Applicant: MITSUBISHI CHEMICAL CORPORATIONInventors: Katsushi YAMAOKA, Toru Takashima
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Publication number: 20140322513Abstract: A stretched film includes a dispersion of at least one polyester and/or polycarbonate in a matrix of at least one polyester and/or polycarbonate different from the first polyester and/or polycarbonate, the percentage by weight of the dispersed polyester and/or polycarbonate in the dispersion being less than 50% and the dispersed polyester and/or polycarbonate being in the form of platelets. The stretched film can be used as a dielectric in a capacitor.Type: ApplicationFiled: July 7, 2014Publication date: October 30, 2014Inventors: Alexis Grosrenaud, Lucien Schosseler
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Publication number: 20140322463Abstract: The invention relates to an unidirectionally-oriented film comprising a thermoplastic polyester and a polycarbonate. The unidirectionally-oriented film may further comprise an anti-blocking agent and/or a slip agent. Depending on its width, the films of the invention may be used for food packaging; it may be used for strapping cartons, boxes, pallets, textile bales; and it may be used for woven tape fabric. The fabric woven from films of the invention may be used for making sacks, flexible intermediate bulk containers, hot fill jumbo bags for materials such as bitumen, PVC coated fabrics for flex signage, carpet backing, geo textiles, geogrids, metallised fabrics, and self-reinforced composites.Type: ApplicationFiled: December 13, 2012Publication date: October 30, 2014Inventors: Zahir Bashir, Johannes Hubertus Lohmeijer, Herbert Furst, Robert Kraus
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Publication number: 20140316053Abstract: Provided is a hot-melt adhesive composition having a cold resistance, and more particularly, a hot-melt adhesive composition including an aliphatic polycarbonate resin obtained by copolymerization of carbon dioxide and polypropylene oxide, and a cold resistance improver.Type: ApplicationFiled: March 13, 2014Publication date: October 23, 2014Applicants: SK Global Chemical Co., Ltd., SK Innovation Co., Ltd.Inventors: Jae Young Park, Kwang Jin Chung, Seung Gweon Hong
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Publication number: 20140265053Abstract: Polymeric blends having improved flame retardance properties and good ductility at low temperatures are disclosed. The blend is formed from (A) a photoactive additive that is a cross-linkable polycarbonate resin containing a photoactive group derived from a dihydroxybenzophenone; and (B) a polymer resin which is different from the photoactive additive. The additive can be a compound, oligomer, or polymer. When exposed to ultraviolet light, crosslinking will occur between the photoactive additive and the polymer resin, enhancing the chemical resistance and flame retardance while maintaining ductility.Type: ApplicationFiled: March 14, 2014Publication date: September 18, 2014Applicant: SABIC Innovative Plastics IP B.V.Inventors: Jean-Francois Morizur, Paul Dean Sybert
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Patent number: 8804308Abstract: A stretched film comprising a dispersion of at least one polyester and/or polycarbonate in a matrix of at least one polyester and/or polycarbonate different from the first polyester and/or polycarbonate, the percentage by weight of the dispersed polyester and/or polycarbonate in the dispersion being less than 50% and the dispersed polyester and/or polycarbonate being in the form of platelets. The stretched film can be used as a dielectric in a capacitor.Type: GrantFiled: April 10, 2009Date of Patent: August 12, 2014Assignee: Dupont Teijin Films U.S. Limited PartnershipInventors: Alexis Grosrenaud, Luclen Schosseler
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Patent number: 8796395Abstract: Described as one aspect of the invention are polymer blends comprising at least one polyester wherein the polymer blend comprises: (A) a polyester composition comprising (I) at least one polyester (Polymer A) which comprises: (a) a dicarboxylic acid component comprising: (i) 70 to 100 mole % of terephthalic acid residues; (ii) 0 to 30 mole % of aromatic dicarboxylic acid residues having up to 20 carbon atoms; and (iii) 0 to 10 mole % of aliphatic dicarboxylic acid residues having up to 16 carbon atoms; and (b) a glycol component comprising: (i) about 10 to about 90 mole % of ethylene glycol residues; and (ii) about 90 to about 10 mole % of cyclohexanedimethanol residues; (II) residues of at least one titanium compound; and (III) at least one chelating phosphorus species, reaction products thereof, or mixtures thereof, represented by the structure: wherein: n=an integer from 1 to 4; R can be hydrogen or C1-C22-alkyl; and R1 and R2 each can be hydrogen, C1-C22-alkyl, hydroxyl, or aryl; whType: GrantFiled: December 20, 2010Date of Patent: August 5, 2014Assignee: Eastman Chemical CompanyInventors: Jason Christopher Jenkins, Dennis Edward Brickey, Michael Eugene Donelson
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Publication number: 20140179817Abstract: Disclosed herein are compositions including a cross-linked polycarbonate. The cross-linked polycarbonate may be derived from a polycarbonate having about 0.5 mol % to about 5 mol % endcap groups derived from a monohydroxybenzophenone. A plaque including the composition can achieve a UL94 5VA rating. Also disclosed herein are articles including the compositions, methods of using the compositions, and processes for preparing the compositions.Type: ApplicationFiled: December 20, 2013Publication date: June 26, 2014Applicant: SABIC Innovative Plastics IP B.V.Inventors: Jean-Francois Morizur, Paul Dean Sybert
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Patent number: 8735505Abstract: A composition comprising from 10 to 90 weight percent of a copolyetherester elastomer comprising: a modified, random polybutylene terephthalate copolymer block that is derived from a polyethylene terephthalate component selected from the group consisting of polyethylene terephthalate, polyethylene terephthalate copolymers, and combinations thereof; and that contains at least one residue derived from the polyethylene terephthalate component; and a polyalkylene oxide copolymer block that is derived from the polyethylene terephthalate component and a polyalkylene oxide glycol, and that contains polyalkylene oxide and at least one residue derived from the polyethylene terephthalate component; from 10 to 90 weight percent of a polycarbonate; and from 0 to 60 weight percent of a polyester.Type: GrantFiled: September 14, 2012Date of Patent: May 27, 2014Assignee: SABIC Innovative Plastics IP B.V.Inventors: Peter H. Vollenberg, Dhaval Shah, Kenneth F. Miller
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Patent number: 8735459Abstract: Provided are a composition for preparing expandable polypropylene carbonate and an expandable polypropylene carbonate prepared therefrom, and more particularly, to a composition for preparing expandable polypropylene carbonate capable of using supercritical carbon dioxide as a foaming agent and producing a foam having excellent moldability by using an appropriate foaming method. By using the composition according to the present invention, highly magnificated expandable polypropylene carbonate capable of having excellent thermal stability and dimensional stability can be prepared.Type: GrantFiled: October 10, 2011Date of Patent: May 27, 2014Assignee: SK Innovations Co., Ltd.Inventors: Minho Jeon, Younghyo Park, Kwangjin Chung, Myungahn Ok
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Publication number: 20140107288Abstract: Embodiments of the invention generally relate to polyols having resistance to hydrocarbons and articles made therefrom. More specifically, embodiments of the invention generally relate to hydrophilic polyester-polycarbonate polyols having resistance to hydrocarbons at high temperatures and articles made therefrom. The novel hydrophilic polyester-polycarbonate polyols described herein may be used in adhesive or elastomer applications requiring enhanced oil and/or diesel resistance. The disclosed polyols are liquid at room temperature, which facilitates processing into polyurethane products As described herein, an elastomer made from such hydrophilic polyester-polycarbonate polyols and methylene diphenyl diisocyanate (MDI) retained >90% of tensile strength after 500 hours ageing at 121 degrees Celsius. A comparative example made from a polyester polyol retained 50% of tensile strength under similar conditions.Type: ApplicationFiled: March 27, 2012Publication date: April 17, 2014Applicant: Dow Global Technologies LLCInventors: Harpreet Singh, Jorge Jimenez, William H. Heath, Woo-Sung Bae, Amarnath Singh
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Patent number: 8680211Abstract: A process for preparing a hybrid polyester-polyether polyol comprises contacting a carboxyl group-containing component and an epoxide, optionally in the presence of one or more of a double metal cyanide catalyst, a superacid catalyst, a metal salt of a superacid catalyst and/or a tertiary amine catalyst, under conditions such that a hybrid polyester-polyether polyol is formed. The hybrid polyester-polyether polyol offers the advantages of both ester and ether functionalities when used in a polyurethane formulation, thus enhancing physical properties. The process results in products having narrow polydispersity, a low acid number and unsaturation, and reduced byproduct formation, particularly when the double metal cyanide catalyst is employed.Type: GrantFiled: April 21, 2011Date of Patent: March 25, 2014Assignee: Dow Global Technologies LLCInventors: Pavel L. Shutov, Jorge Jimenez, Hanno R. Van der Wal, Francois M. Casati
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Publication number: 20140061533Abstract: Disclosed herein are indane bisphenol monomer units, and polymers derived from such monomer units. Also disclosed herein are blends including such polymers, articles made from such polymers and blends, methods of using such monomers, polymers, and blends, and processes for preparing such monomers, polymers, and blends.Type: ApplicationFiled: September 5, 2012Publication date: March 6, 2014Inventors: Laura G. Schultz Hume, S/shri. Shubashree Swaminathan, Ganapathy Bhotla Venkata Ramanarayanan
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Patent number: 8648165Abstract: The present invention seeks to provide a resin composition which contains an aromatic polycarbonate resin and a polyester resin and which has excellent mechanical strength, flowability and thermal stability and also has excellent moist heat resistance together. The present invention is a resin composition containing 50 to 99 parts by weight of an aromatic polycarbonate resin (component A) and 1 to 50 parts by weight of a polyester resin (component B), the component B being a polyester resin polymerized in the presence of a titanium-phosphorus catalyst obtained by reacting titanium tetrabutoxide, etc., with monolauryl phosphate, etc.Type: GrantFiled: January 13, 2011Date of Patent: February 11, 2014Assignee: Teijin Chemicals, Ltd.Inventors: Atsushi Sumita, Daisuke Takahashi, Fumihiro Togashi, Tomoyuki Hirano
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Publication number: 20140031456Abstract: Disclosed is a process for the manufacture of a modified polyalkylene terephthalate such as modified polybutylene terephthalate. In particular, the process comprises employing a titanium-containing catalyst formed by the reaction product of tetraalkyl titanate and a complexing agent comprising a phosphorous, nitrogen or boron atom. The process is used to prepared modified polyalkylene terephthalates characterized by improved hydrostability, as well as compositions and compositions derived therefrom.Type: ApplicationFiled: July 25, 2013Publication date: January 30, 2014Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: Husnu Alp Alidedeoglu, Tianhua Ding, Ganesh Kannan
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Publication number: 20140031457Abstract: Disclosed is a process for the manufacture of a polyalkylene terephthalate such as polybutylene terephthalate. In particular, the process comprises employing a titanium-containing catalyst formed by the reaction product of tctraalkyl titanate and a complexing agent comprising a phosphorous, nitrogen or boron atom. The process is used to prepare polyalkylene terephthalates characterized by improved hydrostability, as well as compositions derived therefrom.Type: ApplicationFiled: July 25, 2013Publication date: January 30, 2014Applicant: SABIC INNOVATIVE PLASTICS IP B.V.Inventors: HUSNU ALP ALIDEDEOGLU, Tianhua Ding, Ganesh Kannan
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Publication number: 20130338318Abstract: It is provided that a polyester composition for electrical/electronic part-sealing material having melt fluidity, initial peel strength, and initial dielectric breakdown strength that are required for electrical/electronic part-sealing material while also having excellent heat resistance, resistance to thermal aging, and durability with respect to hot-cold cycling. A polyester resin composition for electrical/electronic part-sealing material, comprising, as a main component, a copolymer polyester elastomer containing 50 weight % or more and 70 weight % or lower of an aliphatic polycarbonate segment and having 6 equivalents/106 g or more and 50 equivalents/106 g or lower of terminal vinyl groups.Type: ApplicationFiled: February 21, 2012Publication date: December 19, 2013Inventors: Junko Sakai, Kenji Shiga