Solid Polymer Derived From Polyhydroxy Reactant And Polycarboxylic Acid Or Derivative Reactant; Or Derived From Di- Or Higher Ester Of A Polycarboxylic Acid As Sole Reactant Patents (Class 525/437)
  • Patent number: 10875975
    Abstract: Methods for producing 3D printing composite polymer materials for use in additive manufacturing processes are provided. The methods result in enhancing the material properties of the printing material by providing a uniform and smooth surface finish of the printing material and the nozzle extrudate for additive manufacturing processes, such as Fused Filament Fabrication. The method includes implementing impregnation techniques for combining carbon nanotubes or other nano-fillers, a polymer resin and a fiber material to produce a polymer material that can be processed into a printing material. Further, the method may include combining the carbon nanotubes or other nano-fillers and the polymer resin to form a masterbatch that may be further combined with the fiber material through an extrusion process. The method results in a printing material with enhanced material properties and smooth surface finish for the printing material and resulting nozzle extrudate for Fused Filament Fabrication.
    Type: Grant
    Filed: July 11, 2018
    Date of Patent: December 29, 2020
    Assignee: Arevo, Inc.
    Inventors: Riley Reese, Hemant Bheda
  • Patent number: 10774189
    Abstract: Provided are a polyester film that is usable for protecting a surface of a metal plate of a construction material, a decorative material, an interior material, an electronic product, etc., and a manufacturing method therefor, and a polyester mold product using the same and a manufacturing method therefor, wherein the polyester film has low orientation and low modulus to have excellent moldability.
    Type: Grant
    Filed: April 10, 2015
    Date of Patent: September 15, 2020
    Inventors: Si Min Kim, Dong Jin Kim, Yun Jo Kim
  • Patent number: 10767005
    Abstract: Bibenzoate copolyesters are based on (4,4?-biphenyl dicarboxylic acid-co-3,4?-biphenyl dicarboxylic acid) as the diacid component, and on an alicyclic diol compound such as 1,4-cyclohexanedimethanol as a portion of the diol component. Copolyesters are based on 4,4?-biphenyl dicarboxylic acid, and/or 3,4?-biphenyl dicarboxylic acid as the diacid component and may include a multifunctional acid. Copolymers may optionally base an essentially amorphous morphology, high glass transition temperature, high elongation at break, and/or high melting temperature.
    Type: Grant
    Filed: October 7, 2016
    Date of Patent: September 8, 2020
    Assignees: ExxonMobil Chemical Patents Inc., Virginia Tech Intellectual Properties, Inc
    Inventors: Ryan J. Mondschein, Haoyu Liu, Ting Chen, Timothy E. Long, S. Richard Turner
  • Patent number: 10738149
    Abstract: Disclosed is a biodegradable compositions containing at least a polyester containing 2,5-furandicarboxylic acid and at least a polymer selected from the group consisting of polyhydroxyalkanoates and/or aliphatic and/or aliphatic-aromatic diacid diol polyesters, which is particularly suitable for use in the manufacture of mass-produced articles. The articles exhibit excellent mechanical properties, associated with a high barrier property against oxygen and carbon dioxide.
    Type: Grant
    Filed: April 20, 2017
    Date of Patent: August 11, 2020
    Assignee: NOVAMONT S.P.A.
    Inventors: Catia Bastioli, Luigi Capuzzi, Tiziana Milizia, Angelos Rallis, Roberto Vallero
  • Patent number: 10723910
    Abstract: The present invention relates to a pigmented aqueous basecoat material including a polyether-based reaction product which is preparable by reaction of (a) at least one carboxy-functional component which is preparable by esterification reaction of at least one dihydroxycarboxylic acid (a1) with at least one dicarboxylic acid (a2) and/or the anhydride of a dicarboxylic acid (a2), the components (a1) and (a2) being used in a molar ratio of 0.5/3.0 to 1.7/1.8, with (b) at least one polyether of a general structural formula (I) in which R is a C3 to C6 alkylene radical and n is selected accordingly such that the polyether (b) possesses a number-average molecular weight of 500 to 5000 g/mol, the components (a) and (b) being used in the reaction in a molar ratio of 0.7/2.3 to 1.6/1.7, and the resulting reaction product possessing an acid number of 10 to 50 mg KOH/g.
    Type: Grant
    Filed: December 7, 2016
    Date of Patent: July 28, 2020
    Inventors: Bernhard Steinmetz, Peter Hoffmann, Hardy Reuter
  • Patent number: 10676566
    Abstract: The present invention can provide a polyarylate obtained from a dihydric phenol component and an aromatic dicarboxylic acid component. The polyarylate is characterized in that the dihydric phenol component contains a compound represented by general formula (A) or (B) as a primary raw material, and the pencil hardness of the polyarylate is H or higher. (In the formula, R1 and R2 each independently denote a hydrogen atom, an alkyl group having 1-6 carbon atoms or a phenyl group. However, neither R1 nor R1 represents a methyl group.) (In the formula, R3 and R4 each independently denote a hydrogen atom or a methyl group. In addition, a is an integer between 4 and 11. However, a is not 5 if R3 and R4 are both hydrogen atoms.
    Type: Grant
    Filed: December 20, 2018
    Date of Patent: June 9, 2020
    Inventors: Noriyoshi Ogawa, Hiroo Katagiri, Genki Sugiyama
  • Patent number: 10640686
    Abstract: Crosslinkable compositions are provided that contain a) a polymeric material having at least two terminal dithiocarbamate groups or two terminal dithiocarbonate groups and b) a monomer composition that includes at least a crosslinking monomer having two or more ethylenically unsaturated groups. The polymeric materials in the crosslinkable compositions undergo chain extension and crosslinking reactions when exposed to actinic radiation in the ultraviolet region of the electromagnetic spectrum. Additionally, crosslinked compositions, articles that contain the crosslinkable compositions or the crosslinked compositions, and methods of making the articles are provided.
    Type: Grant
    Filed: December 19, 2017
    Date of Patent: May 5, 2020
    Assignee: 3M Innovative Properties Company
    Inventors: Stephen B. Roscoe, Deepti Gopalakrishnan, Stefan H. Gryska, George W. Griesgraber, Serkan Yurt, Duane D. Fansler, Kevin M. Lewandowski, Joon Chatterjee, Hae-Seung Harry Lee, Babu N. Gaddam
  • Patent number: 10442735
    Abstract: The present invention aims to provide an inorganic substance-laminated sheet that can be used suitably for applications that require high gas barrier properties. The inorganic substance-laminated sheet includes a sheet having a dispersed structure with a structural period of 0.001 ?m to 100 ?m on at least one surface and an inorganic substance layer covering the surface having the dispersed structure.
    Type: Grant
    Filed: June 20, 2014
    Date of Patent: October 15, 2019
    Assignee: Toray Industries, Inc.
    Inventors: Yoshikazu Sato, Keiichiro Nomura, Motoyuki Suzuki, Sadayuki Kobayashi, Minoru Yoshida
  • Patent number: 10385235
    Abstract: The invention relates to a method for the preparation of a polymerized CNSL composition, the method comprising subjecting a raw or technical CNSL to a heat treatment under reflux to obtain the polymerized CNSL composition, wherein the heat treatment is performed until the polymerized CNSL composition has a molecular weight Mw of about 2800 to about 3700, such as from about 2900 to about 3600, or from about 3000 to about 3500 g/mol. The invention further relates to a polymerized CNSL composition, use of a polymerized CNSL composition according to the invention in a bitumen composition, a modified bitumen composition according to the invention and an asphalt composition comprising a modified bitumen composition according to the present invention.
    Type: Grant
    Filed: November 28, 2016
    Date of Patent: August 20, 2019
    Inventor: Antonius Caspar Johannes Eijkenboom
  • Patent number: 10370581
    Abstract: The present invention relates to a non-toxic and biodegradable low dosage gas hydrate inhibitor comprising hyper-branched polyester polyols having hydroxyl end groups which are chemically modified. Further, the invention relates to a method for controlling gas hydrate formation and plugging of gas hydrate forming fluids and the use of the gas hydrate inhibitors for this purpose.
    Type: Grant
    Filed: October 28, 2013
    Date of Patent: August 6, 2019
    Assignee: SINVENT AS
    Inventors: Martin Fossen, Helene Konstantia Vralstad
  • Patent number: 10358562
    Abstract: A method of coating a carbon nanotube material with a solventless coating composition is described. The resulting coating has been shown to preserve the conductivity of the conductive layer and protect the conductive layer from the effects of subsequent coating compositions. Examples are shown in which the coating formulation comprises a polyol and an isocyanate. A layer material comprising a polyurethane coating on a carbon nanotube network layer is also described.
    Type: Grant
    Filed: July 27, 2017
    Date of Patent: July 23, 2019
    Assignee: Battelle Memorial Institute
    Inventors: Katherine M. Palmer, Amy M. Heintz, Brett R. Burton, Ioan I. Feier, Timothy J. Lastrapes
  • Patent number: 10287417
    Abstract: The present invention relates to a plasticizer composition which comprises at least one polymeric dicarboxylic ester and at least one dialkyl terephthalate, to molding compositions which comprise a thermoplastic polymer or an elastomer and such a plasticizer composition, and the use of these plasticizer compositions and molding compositions.
    Type: Grant
    Filed: January 29, 2016
    Date of Patent: May 14, 2019
    Assignee: BASF SE
    Inventors: Matthias Pfeiffer, Boris Breitscheidel, Axel Grimm, Herbert Morgenstern
  • Patent number: 10280333
    Abstract: The present disclosure provides coating compositions free of acrylates and epoxies for use in dry-erase surface preparations and protective floor coverings.
    Type: Grant
    Filed: February 1, 2016
    Date of Patent: May 7, 2019
    Assignee: Seagrave Coatings Corp.
    Inventor: Rohit Shah
  • Patent number: 10273345
    Abstract: The invention relates to a plasticizer composition containing at least one polymer dicarboxylic acid ester, to molding compounds containing a thermoplastic polymer or a elastomer and a plasticizer composition of said type, and to the use of said plasticizer compositions and molding compounds.
    Type: Grant
    Filed: September 3, 2015
    Date of Patent: April 30, 2019
    Assignee: BASF SE
    Inventors: Matthias Pfeiffer, Boris Breitscheidel, Axel Grimm, Herbert Morgenstern
  • Patent number: 10160829
    Abstract: Polyester polymers are described comprising polymerized units comprising a hydroxy functional aromatic group wherein the hydroxy group has been functionalized with an adhesion promoting group. In some embodiments, the polyester polymer comprises polymerized units have the general structure (A) wherein L1 and L2 are independently divalent linking groups comprising an ester group; and RA is an adhesion promoting group bonded to the oxygen atom by means of an ionic or covalent bond. In other embodiments, film articles, laminates are described and methods of making functionalized polyester polymers are described.
    Type: Grant
    Filed: August 16, 2016
    Date of Patent: December 25, 2018
    Assignee: 3M Innovative Properties Company
    Inventors: Yu Yang, Jiyoung Park, Suresh S. Iyer, Christopher W. A. Krohe, Kyle P. Starkey, Timothy D. Fletcher, Dong-Wei Zhu, Thomas E. S. Muehle, Jeffrey A. Peterson, Thomas J. Blong
  • Patent number: 10138345
    Abstract: A process for the production of expanded foam beads that are prepared from pellets comprising polyester mixture comprising a) from 50 to 99% by weight, based on components a and b, of a biodegradable polyester based on aliphatic, or a mixture of aliphatic and aromatic, dicarboxylic acids and an aliphatic diol, and b) from 1 to 50% by weight, based on components a and b, of polylactic acid, the process comprising the following steps: (i) providing an aqueous suspension of the polyester pellets, (ii) impregnating the pellets in the suspension of step (i) with at least one physical or chemical blowing agent to provide blowing-agent-loaded pellets in suspension, wherein the impregnation of the at least one blowing agent includes heating the mixture to a depressurization temperature IMT with stirring, and (iii) depressurizing the suspension obtained in step (ii) to provide the expanded foam beads.
    Type: Grant
    Filed: September 29, 2014
    Date of Patent: November 27, 2018
    Assignee: BASF SE
    Inventor: Uwe Keppeler
  • Patent number: 10118984
    Abstract: A silylated polyurethane obtainable by a process comprising the following steps: (a) reacting at least one polyol with at least one triisocyanate to form a hydroxyl-terminated polyurethane prepolymer, and (b) reacting said polyurethane prepolymer with at least one isocyanatosilane of the formula (1): OCN—R—Si—(X)m(R1)3?m, wherein m is 0, 1 or 2, each R1 is independently from each other a hydroxyl group, an alkoxy group having 1 to 10 carbon atoms, an acyloxy group having 1 to 10 carbon atoms, or —OCH(R2)COOR3, wherein R2 is hydrogen or an alkyl group having 1 to 4 carbon atoms and R3 is a straight-chain or branched alkyl group having 1 to 8 carbon atoms, each X is independently from each other and optionally substituted hydrocarbon group having 1 to 10 carbon atoms, which can be interrupted by at least one heteroatom, and R is a difunctional organic group, to endcap the hydroxyl groups on said prepolymer with said isocyanatosilane.
    Type: Grant
    Filed: September 7, 2017
    Date of Patent: November 6, 2018
    Assignee: Henkel AG & Co. KGaA
    Inventors: Ralf Bätzgen, Jan-Erik Damke, David Briers, Johann Klein
  • Patent number: 10087285
    Abstract: Disclosed are monomeric compounds which may be polymerized to form novel biodegradable and bioresorbable polymers and co-polymers. These polymers and co-polymers, while not limited thereto, may be adapted for radioopacity and are useful for medical device applications and controlled release therapeutic formulations.
    Type: Grant
    Filed: December 30, 2015
    Date of Patent: October 2, 2018
    Inventors: Durgadas Bolikal, Joachim B. Kohn
  • Patent number: 10087382
    Abstract: A number of variations may include a product including a fluid additive including at least one asphaltene dispersant/inhibitor including a branched dendritic core and at least one carboxylic acid moiety.
    Type: Grant
    Filed: November 11, 2013
    Date of Patent: October 2, 2018
    Assignees: Schlumberger Norge AS, M-I L.L.C.
    Inventors: Tore Nordvik, Anders Grinrod, Rachael Anne Cole, Astrid Lone, Chandrashekhar Yeshwant Khandekar
  • Patent number: 10030152
    Abstract: The present invention relates to a high elastic primer composition. The high elastic primer composition comprises: a hard urethane-modified polyester in an amount of about 10 to 20 wt %, a soft urethane-modified polyester in an amount of about 5 to 20 wt %, a polycaprolactone in an amount of about 1 to 10 wt %, a polymer resin 20 to 50 wt %, an extender pigment 0.1 to 20 wt % and a solvent 15 to 50 wt %, based on the total weight of the primer composition.
    Type: Grant
    Filed: September 29, 2015
    Date of Patent: July 24, 2018
    Assignee: Hyundai Motor Company
    Inventor: Ji Won Yang
  • Patent number: 10030097
    Abstract: A polyester-containing object, such as an injection stretch blow molded bottle, a biaxially oriented film or a drawn fiber, is made from melt-processing poly(ethylene-2,5-furandicarboxylate). The poly(ethylene-2,5-furandicarboxylate) has a number average molecular weight of at least 25,000, as determined by GPC based on polystyrene standards, and includes an antimony catalyst.
    Type: Grant
    Filed: November 16, 2016
    Date of Patent: July 24, 2018
    Assignee: Furanix Technologies B.V.
    Inventors: Laszlo Sipos, Gerardus Johannes Maria Gruter, Jeffrey John Kolstad, Matheus Adrianus Dam
  • Patent number: 9951206
    Abstract: A modified polyester resin composition comprises a combination of a PET polyester, a PCT polyester, a CHDM modified copolyester comprising PCTA, PCTG or PETG, and a modified polymer at least comprising TPU or EPDM, wherein the modified polymer accounts for 3-25 wt % and the rest accounts for 97-75 wt %, based on the total weight of the resin; and the modified polyester resin composition is suited for use in a halogen-free, heavy metal-free, and volatile organic compound-free polyester-based plastic floor tile excellent in higher resistance to wear and tear, better tensile strength, more preferable resistance to both lit cigarette e and solvents, and particularly being friendliness to environment and not hazardous to health.
    Type: Grant
    Filed: December 3, 2015
    Date of Patent: April 24, 2018
    Inventors: Dein-Run Fung, Ying-Te Huang, Chun-Lai Chen, Tzai-Shing Chen
  • Patent number: 9938389
    Abstract: A process for producing expanded foam beads from pellets comprising at least one biodegradable polyester. The process comprises (i) producing a suspension comprising pellets in an aqueous suspension medium, (ii) impregnating the pellets present in the suspension from step (i) with at least one physical blowing agent by heating the pellet suspension to a depressurization temperature IMT, with stirring, to provide pellets laden with blowing agent in the suspension medium, and (iii) depressurizing the suspension obtained in step (ii) and cooling the depressurized suspension with a liquid aqueous coolant, in order to obtain the expanded foam beads. The blowing agent can be added in step I, or in step ii during the heating phase or following the heating phase. Following the heating phase, the suspension is maintained at a temperature in the range from IMT minus 5° C. to IMT plus 2° C. for 3 to 100 minutes, and the ratio of aqueous coolant to suspension medium is at least 0.3.
    Type: Grant
    Filed: September 29, 2014
    Date of Patent: April 10, 2018
    Assignee: BASF SE
    Inventor: Uwe Keppeler
  • Patent number: 9890242
    Abstract: A polyester, including ethylene 2,5-furandicarboxylate units, has an intrinsic viscosity of at least 0.45 d L/g, and has a relative content of carboxylic acid end groups, expressed as the fraction of the molar amount of carboxylic acid end groups divided by the sum of the molar amounts of hydroxyl end groups and carboxylic acid end groups in the range of 0.10 to 0.70. The polyester can be prepared with a method wherein a starting mixture comprising 2,5-furandicarboxylic acid and ethylene glycol is subjected to esterification and subsequent polycondensation at reduced pressure when the molar ratio of 2,5-furandicarboxylic acid to ethylene glycol in the starting mixture is 1:1.01 to 1:1.15, where water, that is formed during the reaction between 2,5-furandicarboxylic acid and ethylene glycol, and some ethylene glycol are removed in a distillation system, and where ethylene glycol that is removed with water, is separated from water and at least partly recycled.
    Type: Grant
    Filed: March 11, 2015
    Date of Patent: February 13, 2018
    Assignee: Synvina C.V.
    Inventors: Jeffrey John Kolstad, Gerardus Johannes Maria Gruter, Matheus Adrianus Dam, Bing Wang, Robert Joseph Schiavone, Marion L. Andrews, Jesper Gabriël van Berkel, Edward E. Paschke
  • Patent number: 9796917
    Abstract: Disclosed herein is a fluid flow improver comprising a branched dendritic core comprising a first quaternary carbon center bonded to four second carbon atoms, wherein at least three of the four second carbon atoms are individually bonded to one or more chain extender ligands to produce the branched dendritic core, wherein the branched dendritic core has greater than or equal to about 16 terminal hydroxyl groups, and wherein at least one of the terminal hydroxyl groups is esterified with at least one carboxylic acid moiety comprising from 6 to 30 carbon atoms. Methods of inhibiting deposition of paraffin and reducing pour point temperature of a hydrocarbon fluid are also disclosed.
    Type: Grant
    Filed: July 30, 2012
    Date of Patent: October 24, 2017
    Inventors: Chandrashekhar Yeshwant Khandekar, Tore Nordvik, Anders Grinrod
  • Patent number: 9695366
    Abstract: The invention relates to novel demulsifiers for use in the demulsification of oils from water and vice versa, including the demulsification of crude oil from sea water or brine. In particular, the present invention relates to novel demulsifiers which are environmentally friendly, or ‘green’, and which can be used without restriction on-site in offshore oil drilling fields, for example in the North Sea. The novel demulsifiers are based on the reaction product of alkoxylated polyols or polyol esters with dicarboxylic acids.
    Type: Grant
    Filed: September 21, 2012
    Date of Patent: July 4, 2017
    Assignee: Croda International PLC
    Inventors: Hanamanthsa Shankarsa Bevinakatti, Neil Grainger, Tracey Joanne Wardell
  • Patent number: 9567431
    Abstract: A process for preparing a polymer having a 2,5-furandicarboxylate moiety within the polymer backbone and having a number average molecular weight of at least 10,000 (as determined by GPC based on polystyrene standards) includes a first step where a prepolymer is made having the 2,5-furandicarboxylate moiety within the polymer backbone, followed in a second step by a polycondensation reaction. Polymers so produced may have a 2,5-furandicarboxylate moiety within the polymer backbone, and having a number average molecular weight of at least 20,000 (as determined by GPC based on styrene standards), and an absorbance as a 5 mg/mL solution in a dichloromethane:hexafluoroisopropanol 8:2 at 400 nm of below 0.05.
    Type: Grant
    Filed: December 30, 2009
    Date of Patent: February 14, 2017
    Inventor: Laszlo Sipos
  • Patent number: 9533945
    Abstract: By forming a polyester film from a polyester resin composition including ketene imine compound represented by the following Formula (1) and polyester, the polyester film having excellent hydrolysis resistance in which volatilization of the ketene imine compound or the ketene compound can be suppressed. In Formula (1), R1 and R2 represent an alkyl group, an aryl group, an alkoxy group, an alkoxycarbonyl group, an aminocarbonyl group, an aryloxy group, an acyl group, or an aryloxycarbonyl group, and the R1—C(?C)—R2 substructure has a molecular weight of 320 or greater. R3 represents an alkyl group or an aryl group.
    Type: Grant
    Filed: May 5, 2015
    Date of Patent: January 3, 2017
    Inventors: Shigeki Uehira, Makoto Fukuda, Michihiro Ogawa, Masaomi Makino, Masatoshi Mizumura, Seiya Sakurai
  • Patent number: 9527978
    Abstract: The process for recycling and de-vulcanizing vulcanized rubber comprises the steps of: grinding said rubber in a mill in order to shred it into particles having a size substantially comprised between 5 and 15 mm; introducing the particles in an initial section of a two-screw co-rotating extruder having a length 64 times or more the external diameter of the screws, mixing the particles within the extruder, which is kept at a temperature comprised between 35 and 350° C., due to the screw rotation at a speed comprised between 15 and 300 rpm; and obtaining an extruded product formed by de-vulcanized rubber.
    Type: Grant
    Filed: August 5, 2011
    Date of Patent: December 27, 2016
    Assignee: F.LLI MARIS S.p.A.
    Inventor: Gianfranco Maris
  • Patent number: 9496439
    Abstract: The invention provides a polyester film including: a polyester substrate; and a layered portion that is disposed on at least one surface of the polyester substrate and has an elastic modulus of from 5 MPa to 800 MPa, a ratio of a peak intensity at 988 cm?1 that is observed by subjecting a surface of the polyester substrate to infrared spectroscopy to a peak intensity at 1410 cm?1 that is observed by subjecting a surface of the polyester substrate to infrared spectroscopy satisfying the following Inequality (I): 0.010?(peak intensity at 988 cm?1)/(peak intensity at 1410 cm?1)?0.040??(I).
    Type: Grant
    Filed: September 26, 2014
    Date of Patent: November 15, 2016
    Inventors: Shinichi Nakai, Shin Ozawa, Maki Mifune
  • Patent number: 9458287
    Abstract: A process for producing an aliphatic polyester, comprising: subjecting at least two serial stages of bulk-phase ring-opening polymerization and a solid-phase polymerization step, wherein a cyclic ester held in a dry air atmosphere is supplied to a first reactor to perform a first stage polymerization, thereby obtaining a partially polymerized molten product, and the resultant partially polymerized molten product is supplied to a second reactor held under a dry inert gas atmosphere to perform a second stage polymerization. As a result, the production efficiency can be improved, while maintaining excellent properties of the aliphatic polyester product.
    Type: Grant
    Filed: February 19, 2014
    Date of Patent: October 4, 2016
    Inventors: Yoshinori Suzuki, Fumio Maeda, Takahiro Watanabe, Hiroyuki Sato
  • Patent number: 9399700
    Abstract: An ultra-high IV polyester suitable for high melt strength end-uses, such as injection blow molding, pipe extrusion, profile extrusion, and extrusion blow molding, is provided, having IV of greater than 0.9; and a process for its production having high IV lift rate during SSP processing.
    Type: Grant
    Filed: February 6, 2013
    Date of Patent: July 26, 2016
    Assignee: DAK AMERICAS LLC.
    Inventors: Helen J. Codd, George F. Rollend, Norman W. Lisson
  • Patent number: 9396831
    Abstract: A polymer compound comprising a constituent unit represented by the formula (1), the formula (2), the formula (3) or the formula (4) can be utilized for producing an organic film solar battery showing high open end voltage: (in the formulae (1) to (4), Ar1 represents a tri-valent aromatic carbocyclic group or a tri-valent aromatic heterocyclic group. Ar2 represents a tetra-valent aromatic carbocyclic group or a tetra-valent aromatic heterocyclic group. Z represents —O—, —S—, —C(C?O)—, —S(?O)—, —SO2—, —Si(R)2—, —N(R)—, —B(R)—, —P(R)— or —P(?O)(R)—. R represents a hydrogen atom, a halogen atom or a mono-valent group.).
    Type: Grant
    Filed: June 1, 2012
    Date of Patent: July 19, 2016
    Inventors: Kenichiro Ohya, Ken Yoshimura
  • Patent number: 9334355
    Abstract: Disclosed is a hyperbranched, dendritic, hydroxyl-functional polyester comprising an OH number greater than or equal to 180 mg KOH/g as measured via DIN 53240 and to clearcoat compositions comprising said polyesters. Also disclosed are processes for preparing the disclosed polyester, methods of making coated automotive substrates by applying the disclosed clearcoat compositions to automotive substrates, and to coated substrates made therefrom.
    Type: Grant
    Filed: June 5, 2008
    Date of Patent: May 10, 2016
    Assignees: BASF Japan Ltd., BASF Coatings GmbH
    Inventors: Hitoshi Taniguchi, Eishi Tsukamoto, Hiroyuki Takagi, Andreas Poppe, Günter Klein, Veronika Lackstadter, Bianca Giesen, Petra Wagner, Björn Feldmann, Sabine Holtschulte, Julia Melzer, Tanja Bricke, Oliver Hilge, Benedikt Schnier, Silke Hottenbacher, Ulrike Clausen-Meiring
  • Patent number: 9223213
    Abstract: [Object] Provided is a method of manufacturing a polymer for lithography having reduced residual amounts of un-reacted monomers and a poor solvent used for a purification process. [Solving Means] The method of manufacturing a polymer for lithography includes a polymerization process of obtaining a polymerization reaction solution including a polymer by polymerizing monomers in the presence of a polymerization solvent, and a purification process of obtaining a wet powder of a purified polymer by purifying the polymer in the polymerization reaction solution using a re-precipitation method, in which the purification process includes a process of filtering at a filtration differential pressure of 50 kPa or more, and the solid content of the wet powder of the purified polymer exceeds 40% by mass and is less than 65% by mass.
    Type: Grant
    Filed: August 6, 2014
    Date of Patent: December 29, 2015
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Atsushi Yasuda, Kazuaki Mukai
  • Patent number: 9203130
    Abstract: Component manufactured of a polymer composition, which component has been plated with electrical conductive material to provide EMI shielding and which polymer composition contains (a) polyethylene terephthalate (b) glass fibers. The component preferably is a RF filter housing, more preferably a RF filter housing for use in base station for mobile telephone.
    Type: Grant
    Filed: November 7, 2010
    Date of Patent: December 1, 2015
    Assignee: DSM IP ASSETS B.V.
    Inventor: Abel Frans Pot
  • Patent number: 9115241
    Abstract: A crosslinkable, branched polyester prepared by free radical polymerization of unsaturated polyester prepolymers, wherein the polymerization occurs primarily by reaction of the unsaturation is disclosed. Coatings comprising the same are also disclosed, as are substrates coated at least in part with such coatings.
    Type: Grant
    Filed: April 4, 2014
    Date of Patent: August 25, 2015
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Renlong Gao, Irina G. Schwendeman, Debra L. Singer
  • Patent number: 9074052
    Abstract: A copolyester comprising repeating units derived from an aliphatic glycol, terephthalic acid, and the monomer of formula (I): wherein n=2, 3 or 4, and films, fibres, moulding compositions and moulded articles made therefrom.
    Type: Grant
    Filed: December 18, 2012
    Date of Patent: July 7, 2015
    Inventors: Stephen William Sankey, William A. MacDonald, David Turner, Howard Colquhoun, Stephen Meehan
  • Patent number: 9056947
    Abstract: Compositions of PHAs with PBS and/or PBSA are described and methods of making the same.
    Type: Grant
    Filed: January 8, 2014
    Date of Patent: June 16, 2015
    Assignee: Metabolix, Inc.
    Inventors: Rajendra K. Krishnaswamy, Xiudong Sun
  • Publication number: 20150147929
    Abstract: Compositions of biobased polymer blends of polymers of polybutylene succinate (PBS) or polybutylene-adipate-terephthalate (PBAT) and a polyhydroxyalkanoate copolymer are described. In certain embodiments, the copolymer is a multiphase copolymer blend having one phase a glass transition temperature of about ?5° C. to about ?50° C. Methods of making the compositions of the invention are also described. The invention also includes articles, films and laminates comprising the compositions.
    Type: Application
    Filed: June 5, 2013
    Publication date: May 28, 2015
    Inventors: Rajendra K. Krishnaswamy, Johan van Walsem, Oliver P. Peoples, Yossef Shabtai, Allen R. Padwa
  • Publication number: 20150148499
    Abstract: A flame retardant block copolymer is prepared from renewable content. In an exemplary synthetic method, a bio-derived flame retardant block copolymer is prepared by a ring opening polymerization of a biobased cyclic ester and a phosphorus-containing polymer. In some embodiments, the biobased cyclic ester is lactide. In some embodiments, the phosphorus-containing polymer is a hydroxyl-telechelic flame retardant biopolymer prepared by a polycondensation reaction of a biobased diol (e.g., isosorbide) and a phosphorus-containing monomer (e.g., phenylphosphonic dichloride). In other embodiments, the phosphorus-containing polymer is synthesized from a dioxaphospholane monomer.
    Type: Application
    Filed: November 26, 2013
    Publication date: May 28, 2015
    Applicant: International Business Machines Corporation
    Inventors: Dylan J. Boday, Joseph Kuczynski, Timothy C. Mauldin
  • Patent number: 9040639
    Abstract: A process for the continuous production of a biodegradable polyester, where a mixture of aliphatic dihydroxy compounds, aliphatic and aromatic dicarboxylic acids or their liquid esters, and, optionally, further comonomers is mixed, without addition of a catalyst, to give a paste, and i) this mixture with at least a portion of the catalyst, is continuously esterified or, transesterified; ii) the transesterification or, esterification product obtained in i) is continuously precondensed with any remaining amount of catalyst to an intrinsic viscosity of from 20 to 70 cm3/g; iii) the product obtainable from ii) is continuously polycondensed to an intrinsic viscosity of from 60 to 170 cm3/g, and iv) the product obtainable from iii) is reacted continuously with a chain extender in a polyaddition reaction to an intrinsic viscosity of from 150 to 320 cm3/g. The invention further relates to biodegradable polyesters obtained_by this process.
    Type: Grant
    Filed: November 18, 2013
    Date of Patent: May 26, 2015
    Assignee: BASF SE
    Inventors: Uwe Witt, Motonori Yamamoto
  • Patent number: 9034982
    Abstract: Formulations comprising an isosorbide-modified unsaturated polyester comprising maleic acid, fumaric acid, itaconic acid or maleic anhydride and isosorbide and one or more low profile additives. The formulations exhibit better shrink control in molding compound formulations with standard low profile additives than their non-isosorbide-modified analogues. These isosorbide-modified unsaturated polyester resins may be applied in molding compounds like sheet molding compounds or bulk molding compounds and may be components of fiber reinforced composites or other composite materials.
    Type: Grant
    Filed: August 12, 2009
    Date of Patent: May 19, 2015
    Inventors: Dejan D. Andjelkovic, Darcy A. Culkin, Roman Loza, Michael J. Sumner, Timothy A. Tufts, Dennis H. Fisher
  • Patent number: 9029482
    Abstract: Disclosed herein is a method for preparing a polycondensation resin. The method includes preparing a low degree condensate; and solid phase polymerizing the low degree condensate, wherein a granular molded article is introduced into the solid phase polymerization. The method enables efficient manufacture of high quality resins without problems such as agglomeration or scaling of a low degree condensate in pipes.
    Type: Grant
    Filed: December 7, 2012
    Date of Patent: May 12, 2015
    Assignee: Cheil Industries Inc.
    Inventors: Tomomich Kanda, Shimoda Tomoaki, Bok Nam Jang, Seung Hyun Jang
  • Publication number: 20150126091
    Abstract: Non-woven fabrics are made in a spun-melt process, in which a PLA resin blend is melt-spun into filaments, which are pneumatically drawn and then deposited onto a surface to produce the fabric. The PLA resin includes 1-25% of certain aliphatic or aliphatic-aromatic polyesters that have a number average molecular weight from 4,000 to 70,000 g/mol.
    Type: Application
    Filed: April 26, 2013
    Publication date: May 7, 2015
    Inventors: Chad H. Kamann, Robert A. Green, Jed Richard Randall, Donavon Kirschbaum, James R. Valentine
  • Publication number: 20150126687
    Abstract: A method for producing a trans-esterified hydroxypropyl lignin (HPL) is provided in one example embodiment and includes precipitating a lignin, dissolving the precipitated lignin in a solution, adding a reagent to the solution, adjusting the pH of the solution, allowing reactions in the solution to occur for a predetermined amount of time, precipitating the solution to produce a precipitate, and washing, filtering, and drying the precipitate to produce the trans-esterified HPL. In one example, a thermoplastic may be added to produce a trans-esterified HPL/thermoplastic blend.
    Type: Application
    Filed: January 12, 2015
    Publication date: May 7, 2015
    Applicant: Cyclewood Solutions, Inc.
    Inventors: Nhiem Cao, Kevin Oden, Wolfgang G. Glasser
  • Publication number: 20150118152
    Abstract: Compositions of P4HB (poly-4-hydroxybutyrate) and copolymers thereof, have been developed for pultrusion, as well as processes to produce profiles from these compositions by pultrusion. These pultrusion processes provide profiles without causing structural damage to the surface of the profile. The profiles may be used in medical applications. These compositions include P4HB, and copolymers thereof, having intrinsic viscosities less than 3.2 dl/g but greater than 0.8 dl/g. The profile may be formed using conditions such as: pull rate of 0.1 to 100 mm/min, die temperature of up to 95° C., rod stock temperature up to 95° C., draw ratio of up to 100×, pulling force of greater than 10 MPa, and clamping pressure at least 10% higher than the pulling force. Preferably, the profile is formed by pulling the rod stock through a series of dies placed at intervals with the hole sizes decreasing in diameter by 0.1 to 10 mm.
    Type: Application
    Filed: October 30, 2014
    Publication date: April 30, 2015
    Inventors: Amit Ganatra, Bhavin Shah, Said Rizk, David P. Martin, Simon F. Williams
  • Patent number: 9018316
    Abstract: A rapidly degradable polyester polymer and its preparation methods and applications are disclosed. The polyester polymer of the present invention is made by poly-condensation of repeat structure units, each of which consists of a non-degradable block A and degradable block B. The polyester polymer not only has good machinery processing performance, but also can be quickly degraded in appropriate of environment, thereby effectively resolve the environment pollution problems resulted in the used of polyester polymers. It satisfies the wide application demands and especially ensures such polymer can be used for beverage bottle, food package films, shopping bags and other food package containers. In addition, the method of preparation in present invention is simple, low-cost, and the raw materials are easily obtainable at low price. It is suitable for volume production and has practical value and application potentials.
    Type: Grant
    Filed: October 11, 2012
    Date of Patent: April 28, 2015
    Assignee: Molecon (Suzhou) Novel Materials Co., Ltd.
    Inventor: Bin Huang
  • Patent number: 9018315
    Abstract: The properties of a liquid crystalline polymer (LCP) containing ester linkages and made in the presence of an excess of diol are improved by treating the LCP with a dicarboxylic acid at elevated temperature. The resulting LCPs are useful as molding resins and for films.
    Type: Grant
    Filed: April 11, 2014
    Date of Patent: April 28, 2015
    Assignee: Ticona LLC
    Inventors: Marion Glen Waggoner, Richard Alan Jackson
  • Publication number: 20150105521
    Abstract: A resin composition including a polylactic acid resin, a thermoplastic resin other than a polylactic acid, and a carbodiimide compound having a specific cyclic structure. Provided is a resin composition that exhibits improved compatibility between the polylactic acid resin and the thermoplastic resin other than a polylactic acid.
    Type: Application
    Filed: June 25, 2013
    Publication date: April 16, 2015
    Applicant: TEIJIN LIMITED
    Inventors: Shinichiro Shoji, Ryuji Nonokawa