Mixed With O-c(=o)-o-, Hal-c(=o)-o-, Or Hal-c(=o)-hal Containing Reactant Or Polymer Derived Therefrom; Or Wherein Solid Polymer Is Derived From A Hal-c(=o)-hal, O-c(=o)-o-, Or Hal-c(=o)-o-, A Polycarboxylic Acid Or Derivative And A Polyhydroxy Reactant Patents (Class 525/439)
  • Patent number: 5602212
    Abstract: A linear copolyester is prepared by polycondensation of an aromatic bicarboxylic acid with an alkylene glycol and with a carboxyphosphinic acid or anhydride which produces monomeric units having the formula: ##STR1## wherein R.sub.1 is an alkylene or phenyl radical and R.sub.2 is an alkyl or phenyl radical.This copolyester can be used as a flame-retardant additive for organic polymers.
    Type: Grant
    Filed: May 28, 1996
    Date of Patent: February 11, 1997
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Neri, Gianluigi Landoni
  • Patent number: 5594059
    Abstract: The impact strength of a thermoplastic molding composition containing aromatic polycarbonate resin and thermoplastic polyester is improved upon the incorporation therewith of a particular silicone rubber powder. The silicone rubber powder, added at a level of about 3 to 25 contains a mixture of (a) a polydiorganosiloxane and (b) finely divided silica filler.
    Type: Grant
    Filed: July 6, 1995
    Date of Patent: January 14, 1997
    Assignee: Bayer Corporation
    Inventors: James P. Mason, James A. DiBernardo
  • Patent number: 5593778
    Abstract: A biodegradable copolyester having an average molecular weight of at least 50,000 produced by copolymerizing a lactic acid component as the main component with PEG, an aliphatic polyester or a sulfo group-containing ester-forming compound, a molded article produced using it, such as a conjugate fiber, and a process for producing the molded article.
    Type: Grant
    Filed: May 5, 1995
    Date of Patent: January 14, 1997
    Assignees: Kanebo, Ltd., Shimadzu Corporation
    Inventors: Yoshikazu Kondo, Masao Matsui, Hideo Yoshidome, Takuji Osaki, Hiroshi Kajiyama, Eiichi Ozeki, Yasuhiro Fujii
  • Patent number: 5578677
    Abstract: A thermosetting composition which comprises:(D) a self-crosslinking compound having in the molecule (a) one or more functional groups of the formula (2): ##STR1## wherein R.sup.5, R.sup.6 and R.sup.7 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.8 is an organic group of 1 to 18 carbons, Y.sup.2 is oxygen or sulfur, or R.sup.7 and R.sup.8 are bonded with each other to form a heterocyclic structure which comprises Y.sup.2 as the heteroatom component; and (b) one or more reactive functional groups which can form a chemical bond with carboxyl functional groups which are regenerated from (a) by heating; (C) optionally, a thermal latent acid catalyst which is activated during curing of the composition by heating; (A) optionally, a compound having in the molecule two or more functional groups of the formula (1): ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 are each hydrogen or an organic group of 1 to 18 carbons, R.sup.4 is an organic group of 1 to 18 carbons, Y.sup.1 is oxygen or sulfur, or R.
    Type: Grant
    Filed: December 27, 1995
    Date of Patent: November 26, 1996
    Assignee: Nippon Oil and Fats Company, Limited
    Inventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
  • Patent number: 5563209
    Abstract: A process for the reduction of the carboxyl end groups of linear polyester through reaction with alkylene carbonate in the melt phase in the presence of 40 to 160 ppm of allyltriphenyl phosphonium bromide, based on the weight of the polyester.
    Type: Grant
    Filed: December 7, 1995
    Date of Patent: October 8, 1996
    Assignee: Zimmer Aktiengesellschaft
    Inventors: Heinz-Dieter Schumann, Fritz Wilhelm, Rudolf Kaempf
  • Patent number: 5550207
    Abstract: A linear copolyester is prepared by polycondensation of an aromatic bicarboxylic acid with an alkylene glycol and with a carboxyphosphinic acid or anhydride which produces monomeric units having the formula: ##STR1## wherein R.sub.1 is an alkylene or phenyl radical and R.sub.2 is an alkyl or phenyl radical. This copolyester can be used as a flame-retardant additive for organic polymers.
    Type: Grant
    Filed: May 23, 1994
    Date of Patent: August 27, 1996
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Neri, Gianluigi Landoni
  • Patent number: 5548011
    Abstract: The invention relates to blends of polycarbonates, branched, phenolic hydroxy functional dimeric fatty acid polyesters and at least one component selected from polyisobutylene, silicones and mineral oils.
    Type: Grant
    Filed: August 31, 1995
    Date of Patent: August 20, 1996
    Assignee: Bayer AG
    Inventors: Burkhard Kohler, Wolfgang Ebert, Klaus Horn, Richard Weider, Thomas Scholl
  • Patent number: 5545681
    Abstract: Polymer compositions having enhanced biodegradability are disclosed. The compositions comprise a blend of:(1) a polymer containing hydrolyzable bonds; and(2) a substantially water-insoluble, pH-modifying compound capable of accelerating the hydrolysis of the hydrolyzable bonds in the polymer.The invention also relates to polymer films comprising such compositions and absorbent articles containing such polymer compositions or films. The compositions are particularly suitable for use in disposable absorbent articles such as diapers.
    Type: Grant
    Filed: April 27, 1995
    Date of Patent: August 13, 1996
    Assignee: The Procter & Gamble Company
    Inventor: Robert S. Honkonen
  • Patent number: 5545692
    Abstract: The invention relates to new polyesters of dimer fatty acid and dimer fatty diol each containing 36 or 44 carbon atoms, to their production, to their use for the production of polyester carbonates and to the new polyester carbonates.
    Type: Grant
    Filed: May 18, 1995
    Date of Patent: August 13, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Burkhard Kohler, Heinz Pudleiner, Klaus Horn
  • Patent number: 5541240
    Abstract: Blends of thermotropic liquid crystalline polymers and isotropic melt-processable polymers are made by extruding a molten stream of either a thermotropic liquid crystalline polymer or an isotropic polymer through a heated mixing zone and feeding the other of the two polymers into the stream of the first polymer in the mixing zone. The polymers are mixed under shearing conditions for a time sufficient to yield a uniform blend. Blends made according to this method exhibit improved properties in comparison with blends obtained by feeding the two polymers simultaneously into a heated mixing zone.
    Type: Grant
    Filed: March 15, 1994
    Date of Patent: July 30, 1996
    Assignee: Hoechst Celanese Corp.
    Inventors: Subhash Makhija, George L. Lundberg, James B. Stamatoff
  • Patent number: 5525670
    Abstract: The present invention provides the improvement of coating workability (e.g. pinhole resistance, sagging resistance, etc.) of an aqueous coating composition. That is, the present invention provides an aqueous coating composition which comprises: (A) an acrylic resin and/or a polyester resin having an acid value of 10 to 100, a hydroxyl value of 20 to 300 and a number average-molecular weight of 1,000 to 50,000; (B) a polycarbonate resin having a number average-molecular weight of 1,000 to 10,000 which contains a hydroxyl group at the terminal end; and (C) a curing agent.
    Type: Grant
    Filed: August 9, 1994
    Date of Patent: June 11, 1996
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Tadahiko Nishi, Hideaki Ogawa, Hisaki Tanabe, Kunihiko Takeuchi
  • Patent number: 5523361
    Abstract: Polyethylene naphthalate pellets coated with an alkylene carbonate such as ethylene carbonate or propylene carbonate crystallize more quickly and at lower temperature than uncoated pellets, reducing the tendency of the pellets to stick together during the crystallization process prior to solid-state polymerization.
    Type: Grant
    Filed: August 31, 1995
    Date of Patent: June 4, 1996
    Assignee: Shell Oil Company
    Inventors: William C. T. Tung, Samuel M. Moats, Patrick J. Pesata
  • Patent number: 5521258
    Abstract: Compositions which comprise blends of a poly(ester-carbonate) resin and a polyetherimide or a poly(ether sulfone) resin are provided. The compositions are useful for preparing articles that are resistant to autoclave sterilization conditions.
    Type: Grant
    Filed: November 14, 1994
    Date of Patent: May 28, 1996
    Assignee: General Electric Company
    Inventors: Stephen M. Cooper, Ronald A. Greenberg, Darryl Nazareth
  • Patent number: 5516846
    Abstract: Coating compositions which comprise:(i) an acid-functional compound having an average of at least two carboxylic acid groups per molecule; and(ii) an anhydride-functional compound having an average of at least two cyclic carboxylic acid anhydride groups per molecule; and(iii) an epoxy-functional compound having an average of at least one epoxy group per molecule; wherein at least one of the compounds (i), (ii), or (iii) comprises a film forming polymer.
    Type: Grant
    Filed: August 25, 1995
    Date of Patent: May 14, 1996
    Assignee: The Sherwin-Williams Company
    Inventors: Mohamad D. Shalati, James A. Marquart, John L. Petty, Rodney M. Harris
  • Patent number: 5514739
    Abstract: An improved synthetic resin composition is provided that consists essentially of 100 parts by weight of a resin component composed of 50 to 99 (preferably 50 to 90) parts by weight of a melt-processable polyester that does not form an anisotropic melt phase and 1 to 50 (preferably 10 to 50) parts by weight of a liquid crystal polyester that is capable of forming an anisotropic melt phase, to which has been added 0.01 to 0.5 part by weight of a phosphorus compound. The presence of the phosphorus compound has been found to facilitate the fibrillation of the liquid crystal polyester component during molding so as to form fibrils within the resulting molded article having an aspect ratio of 6 or more. The resulting molded article accordingly exhibits significantly enhanced mechanical properties.
    Type: Grant
    Filed: November 9, 1994
    Date of Patent: May 7, 1996
    Assignee: Polyplastics Co., Ltd.
    Inventors: Tomoyuki Aketa, Takayuki Ishikawa
  • Patent number: 5512632
    Abstract: The invention relates to mixtures of special polyesters and/or special polyester carbonates with amorphous thermoplastics and/or with partly crystalline thermoplastics and/or with rubbers and/or with graft polymers useful for molding articles.
    Type: Grant
    Filed: March 3, 1993
    Date of Patent: April 30, 1996
    Assignee: Bayer Aktiengesellschaft
    Inventors: Volker Serini, Dieter Freitag, Ulrich Grigo
  • Patent number: 5508338
    Abstract: A single phase, compatiblized blend comprising a polycarbonate resin, a polyester resin, and no more than about 5%, by weight of the combined weight of polycarbonate and polyester, of a liquid crystalline additive as a compatibilizer.
    Type: Grant
    Filed: April 11, 1995
    Date of Patent: April 16, 1996
    Assignee: Akzo Nobel NV
    Inventors: Ki-Soo Kim, Sophia Dashevsky
  • Patent number: 5508344
    Abstract: A thermoplastic molding composition comprising a resinous blend of polycarbonate, polyester and an impact modifier and an additive amount of a siloxane compound containing a pendant oxirane group is disclosed. It was surprisingly and unexpectedly discovered that unlike the corresponding compositions which contain no siloxane compound, the inventive composition is capable of being dried at low temperatures prior to molding and still maintain high impact strength.
    Type: Grant
    Filed: November 22, 1994
    Date of Patent: April 16, 1996
    Assignee: Bayer Corporation
    Inventors: James P. Mason, William B. Villee, Sivaram Krishnan
  • Patent number: 5502119
    Abstract: A polyester-polycarbonate composition comprising (A) at least one polyester prepared by the reaction of at least one alkanediol with at least one dicarboxylic acid or dialkyl ester thereof in the presence of a metallic catalyst, (B) at least one polycarbonate, (C) at least one organosilicate, the organosilicate being present in an amount effective to inhibit ester-carbonate interchange in the composition, optionally, (D) an organic or inorganic colorant, (E) an impact modifier, and (F) a stabilizer. A method for stabilizing polyester-polycarbonate compositions against ester-carbonate interchange is also provided.
    Type: Grant
    Filed: February 28, 1995
    Date of Patent: March 26, 1996
    Assignee: General Electric Company
    Inventor: Douglas G. Hamilton
  • Patent number: 5489655
    Abstract: Thermosetting resin compositions with low shrinkage are provided, which when molded show low shrinkage rates, good dimensional stability (little cracking or warping), and excellent surface smoothness, mechanical strength, and dispersion stability.The thermosetting resin compositions with low shrinkage in accordance with the present invention comprise:(a) 100 wt. parts by weight thermosetting resins, and(b) 3 to 200 parts by weight polycarbonates containing constituent units derived from aromatic dihydroxy compounds.The polycarbonates preferably have at least 5% (of all the terminal groups) terminal hydroxyl groups derived from aromatic dihydroxy compounds. The polycarbonates also preferably have an intrinsic viscosity of 0.05 to 0.65 dL/g.
    Type: Grant
    Filed: July 26, 1993
    Date of Patent: February 6, 1996
    Assignee: General Electric Company
    Inventors: Tomoaki Shimoda, Kenichi Ishiwa
  • Patent number: 5488086
    Abstract: A polycarbonate resin composition which is superior in impact resistance, fluidity, solvent resistance, wear resistance and sliding characteristics. The polycarbonate resin composition comprises (A) a mixture of polycarbonate (PC) and a polycarbonate-polydimethylsiloxane (PC-PDMS) copolymer and (B) at least one of (i) a thermoplastic resin such as a thermoplastic crystalline resin or a thermoplastic amorphous resin and (ii) a rubber elastomer.
    Type: Grant
    Filed: March 10, 1994
    Date of Patent: January 30, 1996
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Takashi Umeda, Masaya Okamoto
  • Patent number: 5478896
    Abstract: A thermoplastic molding composition comprising an aromatic carbonate polymer and a polyester derived from a cyclohexanedimethanol.
    Type: Grant
    Filed: August 12, 1993
    Date of Patent: December 26, 1995
    Assignee: General Electric Company
    Inventor: Steven W. Scott
  • Patent number: 5466754
    Abstract: A curable resin composition utilizing as the crosslinking mechanism thereof an acid catalyzed addition reaction of a cyclic alkylenecarbonate group with an alcoholic hydroxyl group is disclosed. The composition contains a compound or polymer having a plurality of 6-membered cyclic alkylenecarbonate groups and a polymer having a plurality of alcoholic hydroxyl groups. A polymer having pluralities of the cyclic alkylenecarbonate and hydroxyl groups in a single entity may also be used. The composition cures at room or elevated temperatures depending upon the acidity and amount of particular acid catalyst incorporated to the composition.
    Type: Grant
    Filed: January 27, 1995
    Date of Patent: November 14, 1995
    Assignees: Nippon Paint Co., Ltd., Daicel Chemical Industries, Ltd.
    Inventors: Takao Morimoto, Shinji Nakano
  • Patent number: 5455310
    Abstract: A thermoplastic composition which comprises a siloxane polycarbonate block copolymer wherein the polysiloxane segments of the copolymer are of the formula: ##STR1## where R.sup.1, R.sup.2, Y, D, A, X, A' and E are as defined herein, and high heat polycarbonates containing recurring or repeating polycarbonate units of the formula: ##STR2## wherein Z is --O--, --N(R.sup.3)-- or a mixture thereof and R.sup.3 is selected from hydrogen, hydrocarbyl and halogen-substituted hydrocarbyl.
    Type: Grant
    Filed: August 15, 1994
    Date of Patent: October 3, 1995
    Assignee: General Electric Company
    Inventors: James F. Hoover, Paul D. Sybert
  • Patent number: 5455311
    Abstract: The object of the present invention is the production of thermoplastically workable copolymers capable of being composted, characterized in that they consist of partially crystalline soft segments formed from aliphatic esters and also of amorphous hard segments and that the proportion of soft segments amounts to 70% to 95% by weight.
    Type: Grant
    Filed: August 8, 1994
    Date of Patent: October 3, 1995
    Assignee: Bayer AG
    Inventors: Ernst Grigat, Ralf Dujardin, Ralf Timmermann, Hans-Georg Rast
  • Patent number: 5453479
    Abstract: Novel polyesterification catalysts comprising a phosphorus component and a titanium component are disclosed which are useful in preparing improved blends of polyester and polycarbonate resins.
    Type: Grant
    Filed: July 12, 1993
    Date of Patent: September 26, 1995
    Assignee: General Electric Company
    Inventors: Willem F. H. Borman, Thomas G. Shannon
  • Patent number: 5446110
    Abstract: A hydroxy-terminated linear carbonate is produced by reacting a cyclic alkylene carbonate such as neopentyl glycol carbonate with a substance having at least one alcoholic hydroxyl group in the presence of a catalyst. Mono- or polyhydric alphatic alcohols, polycaprolactone polyols, hydroxyl group-containing acrylic monomers and polymers, and polyester polyols are modified by the reaction with the cyclic alkylene carbonate to have an enhanced reactivity and resistance to hydrolysis.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: August 29, 1995
    Assignees: Nippon Paint Co., Ltd., Diacel Chemical Industries, Ltd.
    Inventors: Shinji Nakano, Takao Morimoto, Shin-ya Yamada, Takaaki Fujiwa, Hideki Matsui, Takeharu Tabuchi
  • Patent number: 5430121
    Abstract: The invention relates to thermoplastic polyurethanes modified with segmented siloxane block copolymers which are based on relatively high molecular weight dihydroxy compounds, diisocyanates, and difunctional chain extenders. The application also relates to their use in the medical field, and particularly as a catheter material.
    Type: Grant
    Filed: December 17, 1993
    Date of Patent: July 4, 1995
    Assignee: Bayer Aktiengesellschaft
    Inventors: Heinz Pudleiner, Herbert Hugl, Rolf Dhein, Hanns-Peter Muller
  • Patent number: 5422398
    Abstract: A compatibilizer for polymer blends is presented. The compatibilizer comprises a sulfonated polystyrene and may be used to prepare miscible blends of the sulfonated polystyrene with two or more polymers having polar groups, e.g., polyamides, polyethers, polyesters, polysulfones and polyamines. The sulfonated polystyrene compatibilizer may be used in conjunction with a counterion.
    Type: Grant
    Filed: August 17, 1994
    Date of Patent: June 6, 1995
    Assignee: The University of Connecticut
    Inventor: Robert A. Weiss
  • Patent number: 5420212
    Abstract: This invention relates to a polymer blend comprising:(a) a concentrate comprising a polycarbonate resin, polycaprolactone and a copolyester having repeat units derived from terephthalic acid, ethylene glycol and 1,4-cyclohexanedimethanol; and(b) a copolyester having repeat units derived from terephthalic acid, ethylene glycol and 1,4-cyclohexanedimethanol.
    Type: Grant
    Filed: March 31, 1994
    Date of Patent: May 30, 1995
    Assignee: Eastman Chemical Company
    Inventor: Ronald R. Light
  • Patent number: 5414054
    Abstract: A thermoplastic copolycarbonate resin having improved low temperature impact strength and a process for the preparation of the resin are disclosed. Accordingly the structure of the copolycarbonate contains(i) units of the formula ##STR1## wherein D is a divalent residue of a dihydroxy compound, and (ii) units of the formula ##STR2## wherein m is 1-90, n is 5-300, R is an alkyl or a phenyl radical p is 2-12 and q is 2-20. The preparation of the copolycarbonate entails reactive blending of polycarbonate with a suitable lactone siloxane copolymer in the presence of a transesterification catalyst.
    Type: Grant
    Filed: June 1, 1994
    Date of Patent: May 9, 1995
    Assignee: Miles Inc.
    Inventors: Erik H. Jonsson, Rick L. Archey, Robert J. Kumpf, Aaron D. Meltzer, Harald Pielartzik, Raymond A. Yourd
  • Patent number: 5401813
    Abstract: Thermoplastic molding compositions containing(i) polybutylene terephthalate(ii) a first aromatic polycarbonate resin, and(iii) a second aromatic polycarbonate resinare disclosed. A high level of Total Light Transmission (herein TLT) is a key characteristic of the compositions of the invention. Preferably, the TLT values of the compositions are higher than those of compositions which contain only said (i) and either (ii) or (iii). Most preferably, the TLT values of the compositions are higher than 80%.
    Type: Grant
    Filed: November 12, 1993
    Date of Patent: March 28, 1995
    Assignee: Miles Inc.
    Inventor: James P. Mason
  • Patent number: 5393848
    Abstract: An improved liquid crystalline polymer blend is produced by mixing a preformed thermotropic liquid crystalline polymer in the melt phase with reactants needed to form a second liquid crystalline polymer under conditions sufficient to form the second liquid crystalline polymer. The resulting blends are anisotropic and have improved morphology and improved melt processability. The method is particularly useful when the second liquid crystalline polymer is biphasic or is difficult to synthesize or process in the melt.
    Type: Grant
    Filed: February 12, 1993
    Date of Patent: February 28, 1995
    Assignee: Hoechst Celanese Corp.
    Inventors: Larry F. Charbonneau, Balaram Gupta, H. Clay Linstid, Linda C. Sawyer, James P. Shepherd
  • Patent number: 5391600
    Abstract: A polycarbonate resin comprising (A) a thermoplastic resin comprising a polycarbonate resin as the main component thereof, (B) inorganic fillers and/or inorganic pigments and (C) an organopolysiloxane having an organoxysilyl group which is bonded to a silicon atom through a divalent hydrocarbon group is provided. The polycarbonate resin shows a lesser degree of molecular weight decrease, has excellent heat stability and moldability, and provides molded articles having excellent appearance, mechanical properties like impact resistance, degree of whiteness and color tone. The polycarbonate resin can be applied to production of various kinds of molded articles, such as molded articles in the field of office automation instruments, electric and electronic products, automobiles, mechanical products, building materials and the like.
    Type: Grant
    Filed: October 18, 1993
    Date of Patent: February 21, 1995
    Assignees: Idemitsu Petrochemical Co., Ltd., Dow Corning Toray Silicone Company, Ltd.
    Inventors: Takashi Umeda, Kazuto Hashimoto, Kouji Satou, Haruhiko Furukawa
  • Patent number: 5382605
    Abstract: A thermoplastic molding composition resistant to the degradation induced by ionizing-radiation is disclosed. The composition contains an aromatic polycondensate and an agent which is a compound conforming structurally to formula (I) ##STR1## or which is a member selected from the group consisting of oligocarbonate, polycarbonate, copolycarbonate, polyestercarbonate and polyesters which contain structural units conforming to formula (Ia) ##STR2## wherein R.sup.1 to R.sup.10 and X are defined. The composition is suitable for the manufacture of shaped articles, especially articles useful in medical applications.
    Type: Grant
    Filed: February 15, 1994
    Date of Patent: January 17, 1995
    Assignees: Miles Inc., Bayer Aktiengesellschaft
    Inventors: Douglas G. Powell, Charles E. Lundy, Gerhard Fennhoff, Ralf Hufen, Klaus Kircher
  • Patent number: 5376736
    Abstract: Thermoplastic molding compositions are disclosed containing (i) about 1 to 89% polyethylene terephthalate (ii) about 10 to 89% of a first aromatic polycarbonate (PC1) and (iii) about 1-89% of the second aromatic polycarbonate (PC2). PC2 is a copolycarbonate which contains about 5 to 70 mole percent of structural units derived from a dihydroxy compound the bridging unit of which corresponds to ##STR1## wherein R.sup.3 and R.sup.4 X and m are defined. A composition of the invention is characterized in a TLT value which is an improvement over that of the corresponding composition which contains the same amount of PET and only PC1. An additional embodiment of the invention concerns a method for increasing the TLT of a thermoplastic molding composition containing PET and PC1. The method comprises replacing some of said PC1 by PC2.
    Type: Grant
    Filed: April 12, 1994
    Date of Patent: December 27, 1994
    Assignee: Miles Inc.
    Inventor: James P. Mason
  • Patent number: 5374690
    Abstract: A composition of polyester resins comprising diblock copolymers formed of two different polyester blocks joined by a bifunctional radical deriving from a dianhydride of a tetracarboxylic acid. The compositions are prepared by a reaction in the solid state of two different polyesters in the presence of a dianhydride of a tetracarboxylic acid.
    Type: Grant
    Filed: December 28, 1992
    Date of Patent: December 20, 1994
    Assignee: M. & G. Ricerche S.p.A.
    Inventor: Hussain Al Ghatta
  • Patent number: 5352740
    Abstract: Thermosetting composition is excellent in storage stability, useful as one component thermosetting composition, gives cured products having excellent chemical properties, physical properties and weathering resistance and is favorably utilized in coating compositions, ink, adhesive and molded plastics.The thermosetting composition comprises a compound having in the molecule two or more carboxyl groups blocked by a vinyl ether compound, a vinyl thioether compound or a hetero compound having a vinyl type double bond and oxygen or sulfur as the hetero atom, a compound having two or more reactive functional groups which can form a chemical bond with the blocked carboxyl compound by heating and optionally a thermal latent acid catalyst. The blocked carboxyl group of the first compound and the reactive functional group of the second compound may be comprised in the same molecule.
    Type: Grant
    Filed: April 4, 1991
    Date of Patent: October 4, 1994
    Assignee: Nippon Oil and Fats Company, Limited
    Inventors: Masahiro Ishidoya, Kishio Shibato, Keiji Komoto, Kenji Shibamoto, Mitsuyuki Mashita, Osamu Ohe
  • Patent number: 5350790
    Abstract: This invention provides a polycarbonate resin composition for optical use and an optical disc substrate manufactured therefrom. Polycarbonate resin is mixed with at least one kind of carboxylic acid selected from aliphatic carboxylic acids having 1 to 10 carbon atoms in which hydrogen atoms of aliphatic group may be substituted by hydroxyl groups; or aromatic carboxylic acids in which hydrogen atoms of the aromatic ring may be substituted by low alkyl groups, hydroxyl groups, or halogen atoms.The amount of the carboxylic acids is 5 to 1000 ppm based on the polycarbonate resin.
    Type: Grant
    Filed: April 1, 1993
    Date of Patent: September 27, 1994
    Assignee: Mitsubishi Kasei Corporation
    Inventors: Yoshitomi Urabe, Hironori Hayashida, Yoshiaki Ohtani
  • Patent number: 5348999
    Abstract: The invention relates to polymer mixtures which comprise an aromatic polycarbonate, a polybutylene terephthalate and a polyalkylene glycol. Due to the presence of the polyalkylene glycol a good lacquer bonding is obtained when lacquer systems on the basis of water are used.
    Type: Grant
    Filed: April 9, 1992
    Date of Patent: September 20, 1994
    Assignee: General Electric Company
    Inventors: Robertus E. de Jong, Torben P. Kempers, Gerrit de Wit
  • Patent number: 5331066
    Abstract: The present invention provides a process for producing a polyester ether copolymer which comprises conducting polycondensation after or while melting and mixing a polyester, of 0.3 (dl/g) or more in intrinsic viscosity, and a polyether having hydroxy groups or their derivatives at its terminals and having a molecular weight of 200 or more. The present invention can dispense with the steps of esterification, transesterification, etc., because of the use of the preformed polyester. Moreover, it shortens the reaction time so that only a small quantity of polyester is produced as a by-product. In addition, since the thermal history of the polyesterh is so small, deterioration of the polymer during production is suppressed. Furthermore, this process enables continuous production of products with good quality, which serves to markedly improve productivity.
    Type: Grant
    Filed: July 9, 1992
    Date of Patent: July 19, 1994
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Yutaka Takanoo, Ikuo Okino, Yasuhiro Nakatani
  • Patent number: 5324795
    Abstract: The present invention relates to a polymer blend composition for melt molding which is a composition obtained by adding a thickener to a polymer blend comprising a liquid crystal polymer and a non-liquid crystal polymer, characterized in that the melt viscosity of the composition determined at a molding temperature at a shear rate of 1000 sec.sup.-1 is the same or higher than the melt viscosity of said non-liquid crystal polymer determined under the same conditions.According to the present invention, a polymer blend for melt molding having improved properties, whereby problems observed in prior arts upon molding a polymer blend comprising a liquid crystal polymer and a non-liquid crystal polymer (for example, insufficient alignment of the liquid crystal polymer and difficulties in extrusion, because of excessively low melt viscosity) can be solved, is obtained.
    Type: Grant
    Filed: May 12, 1993
    Date of Patent: June 28, 1994
    Assignee: Unitika Ltd.
    Inventor: Jun-ichi Suenaga
  • Patent number: 5324454
    Abstract: A thermoplastic resin composition comprising (a) 100 parts by weight of thermoplastic copolycarbonate comprising 0.1 to 50% by weight of structural unit of the following general formula (1) and 99.9 to 50% by weight of structural unit of the following general formula (2): ##STR1## and (b) 0.1 to 30 parts by weight of electroconductive carbon black can produce a molding product having good mechanical properties and surface smoothness with good moldability and (c) a polyester or styrenic resin.
    Type: Grant
    Filed: September 29, 1993
    Date of Patent: June 28, 1994
    Assignee: Mitsubishi Gas Chemical Company, Inc.
    Inventors: Toshiaki Takata, Tadami Kinugawa, Hideo Otaki
  • Patent number: 5321086
    Abstract: A polycarbonate resin composition which comprises (a) a polycarbonate containing a repeating unit (I) derived from tetrahalogenobisphenol A and a repeating unit (II) derived from bisphenol A and trihalogenophenoxy groups bonded at the terminals, and (b) at least one thermoplastic resin selected from the group consisting of (i) a polyamide resin selected from the group consisting of nylon 6 and nylon 6,6, (ii) a thermoplastic polyester selected from the group consisting of polyethylene terephthalate and polybutylene terephthalate and (iii) a polyolefin. The polycarbonate resin composition has desirable physical properties including desirable mechanical properties, moldability, heat resistance, flame retardance, thermostability, rigidity, impact resistance, solvent resistance, and fluidity, and can be used to make parts for automobiles, home electric appliances, and office automation appliances.
    Type: Grant
    Filed: December 1, 1992
    Date of Patent: June 14, 1994
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Shiro Kozakura, Takashi Komatsu
  • Patent number: 5314949
    Abstract: A polycarbonate resin composition comprising 1 to 99% by weight of a branched polycarbonate having a branched nucleus structure derived from a branching agent represented by the general formula: ##STR1## wherein R is a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and R.sup.1 to R.sup.6 are hydrogen atoms, alkyl groups having 1 to 5 carbon atoms or halogen atoms, respectively, and 99 to 1% by weight of a thermoplastic polyester resin. The polycarbonate resin composition is excellent in fluidability, solvent resistance and moldability.
    Type: Grant
    Filed: March 9, 1993
    Date of Patent: May 24, 1994
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Shiro Kozakura, Shigeki Kuze, Kenji Tanaka
  • Patent number: 5310827
    Abstract: Novel polyamide copolymers having skeletons of a specific structure are disclosed. The polyamide copolymers have excellent resistance to hydrolysis, low temperature characteristics (low temperature softness), heat aging resistance and mechanical properties as compared to conventional polyamide copolymers. The polyamide copolymers also show excellent efficiencies in fabrication properties and transparency. In particular, the polyamide copolymers having a branched structure in the molecule thereof provide good results.
    Type: Grant
    Filed: November 13, 1991
    Date of Patent: May 10, 1994
    Assignee: Kuraray Co., Ltd.
    Inventors: Yukiatsu Komiya, Masao Ishida, Koji Hirai, Setuo Yamashita, Shinji Komori, Takuji Okaya
  • Patent number: 5310793
    Abstract: The mixtures according to the present invention of polyalkylene terephthalates, certain new polycarbonates and/or polyester-carbonates and elastomers have a particularly favourable low temperature strength/heat distortion point relationship compared with conventional moulding compositions containing known polycarbonates. The mixtures are used for the production of, in particular, shaped articles.
    Type: Grant
    Filed: February 12, 1993
    Date of Patent: May 10, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Dieter Freitag, Karsten-Josef Idel, Gerd Fengler, Ulrich Grigo, Jurgen Kirsch, Uwe Westeppe
  • Patent number: 5308894
    Abstract: A polycarbonate blend of good impact and flexural strength, good weldline properties, and good solvent resistance prepared by admixing with polycarbonate an aromatic polyester, an olefinic epoxide-containing modifier, and a thermoplastic elastomer. Optionally, a graft copolymer of the core-shell type and a rubber-modified styrene/acrylonitrile copolymer may be used as an additional impact modifiers.
    Type: Grant
    Filed: January 6, 1993
    Date of Patent: May 3, 1994
    Assignee: The Dow Chemical Company
    Inventor: Michael K. Laughner
  • Patent number: 5302694
    Abstract: The present invention relates to a method of producing polyesters based on hydroxycarboxylic acids, more particularly based on .alpha.-hydroxycarboxylic acids.
    Type: Grant
    Filed: August 24, 1993
    Date of Patent: April 12, 1994
    Assignee: Boehringer Ingelheim GmbH
    Inventor: Berthold Buchholz
  • Patent number: 5300350
    Abstract: Laser-writable, black-colored blends of carbonate and polyester resins are provided by the incorporation of a black colorant formulation comprising carbon black and a fatty acid metal salt. Zinc stearate is a preferred fatty acid metal salt. The black-colored resin blends can be inscribed using standard YAG lasers and maintain an excellent balance of other properties including surface aesthetics, physical properties, heat resistance, chemical resistance and processability.
    Type: Grant
    Filed: February 22, 1993
    Date of Patent: April 5, 1994
    Assignee: The Dow Chemical Company
    Inventors: Brian K. Grosser, Thomas L. Miller