Blocked Isocyanate Reactant Or Polymer Derived Therefrom Patents (Class 525/440.02)
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Patent number: 11136444Abstract: Polyurethane foams are made by curing a reaction mixture that contains an aromatic polyisocyanate, at least one isocyanate-reactive material having an average functionality of at least 2 and an equivalent weight of at least 200 per isocyanate-reactive group, at least one blowing agent, at least one surfactant and at least one catalyst, at least one polyacetoacetate compound and least one antioxidant. Foams so produced emit low levels of both formaldehyde and acetaldehyde.Type: GrantFiled: February 20, 2017Date of Patent: October 5, 2021Assignee: Dow Global Technologies LLCInventors: Jiguang Zhang, Shaoguang Feng, Michael T. Malanga, Zhengming Tang, Wenbin Yao, Degang Zhang, Ping Zhang, Jian Zou
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Patent number: 10633519Abstract: Provided is a storage-stable polyurethane prepegs and mouldings produced therefrom composed of polyurethane compositions with liquid resin components, preferably liquid polyols. A prepeg contains(A)a fibrous support and (B)a matrix material containing a reactive polyurethane composition. The polyurethane composition contains a mixture of a liquid resin component(b)having a functional group reactive towards an isocyanate and having a glass transition temperature(Tg)or melting point below 25° C., with a hydroxyl number of 50 to 2000 mg KOH/gram, and a curing agent(a)comprising a di- or polyisocyanate internally blocked or blocked with a blocking agent. In addition, the polyurethane composition contains 0.6 to NCO equivalents or 0.3 to 1 uretdione group in (a) for each functional group of (b).Type: GrantFiled: March 21, 2012Date of Patent: April 28, 2020Assignee: Evonik Operations GmbHInventors: Emmanouil Spyrou, Friedrich Georg Schmidt, Eike Langkabel, Katharina Cielaszyk, Sandra Reemers, Holger Loesch, Elke Gollan, Marina Grammenos
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Patent number: 10233354Abstract: The invention relates to a coating material composition comprising at least one hydroxyl-containing polyester (A) having an OH number of 250 to 660 mg KOH/g, at least one polycarbonate diol (B) having an OH number of 35 to 500 mg KOH/g, in an amount of 1 to 20 wt %, based on the overall formula, and at least one polyisocyanate (C) containing biuret groups and having an isocyanate group content of 5.8 to 27 wt %, the hydroxyl-containing polyester (A) being different from the polycarbonate diol (B), and the coating material composition possessing a fraction of organic solvents of less than 420 g/l, and comprising, based on the solids content, 40 to 100 wt % of binders. The invention further relates to a method for producing a multicoat coating using a coating material composition of the invention, to the use of the coating material composition, and to substrates coated therewith.Type: GrantFiled: May 21, 2015Date of Patent: March 19, 2019Assignee: Akzo Nobel Coatings International B.V.Inventors: Dirk Seeger, Christoph Piecha, Nadine Homann
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Patent number: 9994668Abstract: The present invention relates to a biostable polyurethane or polyurea comprising: (a) a soft segment comprising a polysiloxane of the general formula (I); and (b) greater than O and less than 40 wt % of a hard segment which is a reaction product of a diisocyanate and a linear difunctional chain extender, processes for their preparation and their use in the manufacture of biomaterials, devices, articles or implants.Type: GrantFiled: December 2, 2016Date of Patent: June 12, 2018Assignee: Aortech International plcInventor: Ajay D. Padsalgikar
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Patent number: 9670305Abstract: The present invention is related to a polyurethane dispersant and a preparation method thereof. The polyurethane dispersant is terminated by a nitrogen-containing heterocyclic compound during synthesis. The nitrogen-containing heterocyclic compound is prepared by subjecting anhydride and a compound containing a primary amine and a secondary amine or a hydroxyl or mercapto group to dehydration condensation. The condensed product is the nitrogen-containing heterocyclic compound, containing a reactive hydrogen. The structural formula of the compound containing the primary amine and the secondary amine or hydroxyl or mercapto group is shown as follows: wherein n=1 to 5, and preferably 2 to 4, R1 and R2 are respectively alkyls containing 1 to 8 carbons, R1 and R2 are independent of each other or connected by a chemical bond to form one or more saturated or unsaturated 4-member to 8-member rings, and X represents N, O, or S.Type: GrantFiled: October 8, 2012Date of Patent: June 6, 2017Assignees: AFCONA CHEMICALS (HAIMEN) CO., LTD.Inventor: Zhijun Wang
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Patent number: 9512261Abstract: The present invention relates to a biostable polyurethane or polyurea comprising: (a) a soft segment comprising a polysiloxane of the general formula (I); and (b) greater than O and less than 40 wt % of a hard segment which is a reaction product of a diisocyanate and a linear difunctional chain extender, processes for their preparation and their use in the manufacture of biomaterials, devices, articles or implants.Type: GrantFiled: September 11, 2015Date of Patent: December 6, 2016Assignee: Aortech International plcInventor: Ajay D. Padsalgikar
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Patent number: 8293836Abstract: A curable coating composition includes a uretdione compound having one uretdione group and having a plurality of functional groups selected from crosslinkable groups and groups that modify a coating property. The disclosed coating compositions include those having a binder component having a plurality of active hydrogen-containing groups. When the uretdione compound has a functional group that is a crosslinkable group, the coating composition further includes a crosslinker that has a plurality of crosslinking groups reactive under curing conditions with the crosslinkable group. Also disclosed is a method of making the curable coating composition, including preparing the uretdione compound having one uretdione group and having at least one further functional group.Type: GrantFiled: May 20, 2009Date of Patent: October 23, 2012Assignee: BASF Coatings GmbHInventors: David C. Cranfill, Walter H Ohrbom, Patrick J Mormile
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Patent number: 8288486Abstract: Disclosed is an improved coating composition for food containers that is resistant to high pH processing environments. The improved coating composition is based upon an epoxy-amino resin coating composition that has been modified with other components to improve its performance in high pH environments balanced with flexibility, formability and abrasion resistance. Typically, the coating composition includes an epoxy resin, an amino resin cross-linking agent, a blocked polyisocyanate and a saturated polyester.Type: GrantFiled: October 12, 2011Date of Patent: October 16, 2012Assignee: W. R. Grace & Co.-Conn.Inventors: Armi G. Garcia, Benedick M. Francisco
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Patent number: 8106133Abstract: The invention provides a flexible tube for an endoscope, which is excellent in elasticity (impact resilience), has suitable flexibility and also has chemical resistance. Disclosed is a flexible tube for an endoscope including a flexible-tube material covered thereon with a jacket, wherein the jacket contains two or more thermoplastic polyester elastomers crosslinked therein.Type: GrantFiled: July 19, 2010Date of Patent: January 31, 2012Assignee: Olympus Medical Systems Corp.Inventors: Hitoshi Ogura, Yuuri Takeuchi
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Patent number: 8048970Abstract: Novel low viscosity oligomeric polyols and the use thereof in coating compositions are disclosed. The novel low viscosity oligomeric polyols may be prepared by reacting at least one melamine aldehyde resin and at least one of ?,?-diol, ?,?-diol, or mixture thereof. The reaction may occur in the presence of an acid catalyst. Coating compositions with a low VOC able to cure under ambient and forced dry conditions while providing good application and performance characteristics, such as an improved scratch resistance, are also disclosed.Type: GrantFiled: September 5, 2006Date of Patent: November 1, 2011Assignee: Akzo Nobel Coatings International B.V.Inventors: Alexander Leo Yahkind, Xueting Qiu, Dhruv Vrajlal Parekh
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Patent number: 7872078Abstract: The present invention is directed to curable film-forming compositions comprising: (a) a polymeric binder comprising a polyester having hydroxyl functional groups; and (b) a curing agent comprising a polyisocyanate having at least three isocyanate functional groups. In certain embodiments, after application to a substrate as a coating and after curing, the compositions demonstrate a Fisher microhardness of at least 120 at ambient temperatures of 15 to 25° C. and a softening point greater than or equal to 35° C. Additionally, in certain embodiments, after application to a substrate as a coating and after curing, the compositions demonstrate a 20° gloss recovery of at least 75% when subjected to the DRY ABRASION TEST METHOD.Type: GrantFiled: August 28, 2007Date of Patent: January 18, 2011Assignee: PPG Industries Ohio, Inc.Inventors: Lyle L. Foringer, Constantine A. Kondos, Richard J. Sadvary, Kurt G. Olson, Dennis A. Simpson
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Patent number: 7842756Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.Type: GrantFiled: March 17, 2008Date of Patent: November 30, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Jonathan T. Martz, Erick B. Iezzi
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Patent number: 7687576Abstract: A thermosetting transparent coating material, its preparation and use. The coating includes (meth)acrylate (co)polymer having a number-average molecular weight of from 1,000 to 6,000 daltons, a glass transition temperature of ?15 to +70° C., and a hydroxyl number of from 80 to 200 mg KOH/g; polyester having a number-average molecular weight of from 800 to 6,000 daltons, a hydroxyl number of from 80 to 200 mg KOH/g and an acid number of from 1 to 50 mg KOH/g, comprising, based on the polyester, from 30 to 70% by weight of cycloaliphatic structural units; a blocked polyisocyanate in which the blocked polyisocyanate groups are attached to flexibilizing structural units which, as part of a three-dimensional network, lower its glass transition temperature; and blocked polyisocyanate in which the blocked polyisocyanate groups are attached to hardening structural units which, as part of a three-dimensional network, raise its glass transition temperature.Type: GrantFiled: July 10, 2004Date of Patent: March 30, 2010Assignee: BASF Coatings AGInventors: Günter Klein, Ulrike Röckrath, Jürgen Niemann, Ulrich Poth, Andre Brosseit, Karin Wermelt, Alexandra Huber
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Patent number: 7666945Abstract: The present invention is directed to a non-gelled, curable composition including at least one compound having a plurality of imide functional groups. The compound in particular contains a reaction product of at least one secondary monoamine and at least one maleimide, and is suitable for use in coatings and castings.Type: GrantFiled: September 27, 2007Date of Patent: February 23, 2010Assignee: PPG Industries Ohio, Inc.Inventors: Kevin C. Olson, Gregory J. McCollum, Linda K. Anderson
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Patent number: 7655815Abstract: The invention relates to biuret compounds of the idealized general formula in which R1 is a (C1-C22)-alkylene, (C3-C22)-alkenylene, (C5-C15)-cycloalkylene, arylene, (C7-C12)-aralkylene, a polyoxyalkylene radical or is a polyester radical, R2 is a (C1-C22)-alkyl, hydroxy-(C1-C22)-alkyl, (C3-C18)-alkenyl, aryl, (C7-C12)-aralkyl, or (C5-C12)-cycloalkyl radical, a hydroxy-, (C1-C22)-alkoxy-, (C5-C12)-cycloalkoxy-, or (C7-C12)-aralkoxy-polyoxyalkylene radical, or a polyester radical prepared starting from a (C1-C22)-alkanol, (C5-C12)-cycloalkanol, or (C7-C12)-aralkanol or from a (C1-C22)-alkoxy-, (C6-C12)-cycloalkoxy-, or (C7-C12)-aralkoxy-polyoxyalkylene, Y stands for identical or different radicals O, NH, CO—NH—NH or NH—NH—CO, R3, R4 and R5 independently of one another are a (C2-C40)-alkylene, (C3-C40)-alkenylene, (C5-C40)-cyclo-alkylene, arylene, (C7-C40)-aralkylene or polyoxy-alkylene radical or are a polyester radical, R6 is a (C1-C30)-alkyl, (C3-C22)-alkenyl, hydroxyalkyl and hydroxyalkenyl, (C4-C13)-cyType: GrantFiled: March 6, 2007Date of Patent: February 2, 2010Assignee: BYK-Chemie GmbHInventors: Karlheinz Haubennestel, Ulrich Orth, Matthias Pickave, Stefan Moessmer, Daniela Betcke
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Patent number: 7579127Abstract: The present invention is a photoconductive element containing an electrically conductive support, an electrical barrier layer disposed over said electrically conductive support and a charge generation layer capable of generating positive charge carriers when exposed to actinic radiation disposed over the barrier layer. The barrier layer is formed from a blocked polyisocyanate containing tetracarbonylbisimide groups. The present invention also discloses a new composition of a blocked polyisocyanate containing tetracarbonylbisimide groups.Type: GrantFiled: June 15, 2006Date of Patent: August 25, 2009Assignee: Eastman Kodak CompanyInventor: Michel F. Molaire
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Publication number: 20090155462Abstract: The invention provides a powder coating composition comprising (A) at least one hydroxyl functional polyester resin binder, and (B) at least one polyurethane resin as cross-linking agent containing blocked isocyanate groups, wherein the at least one hydroxyl functional polyester resin binder (A) and the at least one polyurethane resin (B) both having a melting temperature of 60 to 180° C., in particular, 60 to 160° C. The powder coating composition according to the invention provides the desired technological properties, in particular, thin films and high flexibility in combination with excellent mechanical properties of the coatings.Type: ApplicationFiled: December 3, 2008Publication date: June 18, 2009Inventors: Carmen Flosbach, Kristina Iland, Engin Temeltas
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Patent number: 7425594Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.Type: GrantFiled: November 23, 2005Date of Patent: September 16, 2008Assignee: PPG Industries Ohio, Inc.Inventors: Jonathan T. Martz, Stephen J. Thomas
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Publication number: 20070292795Abstract: The present invention is a photoconductive element containing an electrically conductive support, an electrical barrier layer disposed over said electrically conductive support and a charge generation layer capable of generating positive charge carriers when exposed to actinic radiation disposed over the barrier layer. The barrier layer is formed from a blocked polyisocyanate containing tetracarbonylbisimide groups. The present invention also discloses a new composition of a blocked polyisocyanate containing tetracarbonylbisimide groups.Type: ApplicationFiled: June 15, 2006Publication date: December 20, 2007Inventor: Michel F. Molaire