Blocked Isocyanate Reactant Or Polymer Derived Therefrom Patents (Class 525/440.02)
  • Patent number: 11136444
    Abstract: Polyurethane foams are made by curing a reaction mixture that contains an aromatic polyisocyanate, at least one isocyanate-reactive material having an average functionality of at least 2 and an equivalent weight of at least 200 per isocyanate-reactive group, at least one blowing agent, at least one surfactant and at least one catalyst, at least one polyacetoacetate compound and least one antioxidant. Foams so produced emit low levels of both formaldehyde and acetaldehyde.
    Type: Grant
    Filed: February 20, 2017
    Date of Patent: October 5, 2021
    Assignee: Dow Global Technologies LLC
    Inventors: Jiguang Zhang, Shaoguang Feng, Michael T. Malanga, Zhengming Tang, Wenbin Yao, Degang Zhang, Ping Zhang, Jian Zou
  • Patent number: 10633519
    Abstract: Provided is a storage-stable polyurethane prepegs and mouldings produced therefrom composed of polyurethane compositions with liquid resin components, preferably liquid polyols. A prepeg contains(A)a fibrous support and (B)a matrix material containing a reactive polyurethane composition. The polyurethane composition contains a mixture of a liquid resin component(b)having a functional group reactive towards an isocyanate and having a glass transition temperature(Tg)or melting point below 25° C., with a hydroxyl number of 50 to 2000 mg KOH/gram, and a curing agent(a)comprising a di- or polyisocyanate internally blocked or blocked with a blocking agent. In addition, the polyurethane composition contains 0.6 to NCO equivalents or 0.3 to 1 uretdione group in (a) for each functional group of (b).
    Type: Grant
    Filed: March 21, 2012
    Date of Patent: April 28, 2020
    Assignee: Evonik Operations GmbH
    Inventors: Emmanouil Spyrou, Friedrich Georg Schmidt, Eike Langkabel, Katharina Cielaszyk, Sandra Reemers, Holger Loesch, Elke Gollan, Marina Grammenos
  • Patent number: 10233354
    Abstract: The invention relates to a coating material composition comprising at least one hydroxyl-containing polyester (A) having an OH number of 250 to 660 mg KOH/g, at least one polycarbonate diol (B) having an OH number of 35 to 500 mg KOH/g, in an amount of 1 to 20 wt %, based on the overall formula, and at least one polyisocyanate (C) containing biuret groups and having an isocyanate group content of 5.8 to 27 wt %, the hydroxyl-containing polyester (A) being different from the polycarbonate diol (B), and the coating material composition possessing a fraction of organic solvents of less than 420 g/l, and comprising, based on the solids content, 40 to 100 wt % of binders. The invention further relates to a method for producing a multicoat coating using a coating material composition of the invention, to the use of the coating material composition, and to substrates coated therewith.
    Type: Grant
    Filed: May 21, 2015
    Date of Patent: March 19, 2019
    Assignee: Akzo Nobel Coatings International B.V.
    Inventors: Dirk Seeger, Christoph Piecha, Nadine Homann
  • Patent number: 9994668
    Abstract: The present invention relates to a biostable polyurethane or polyurea comprising: (a) a soft segment comprising a polysiloxane of the general formula (I); and (b) greater than O and less than 40 wt % of a hard segment which is a reaction product of a diisocyanate and a linear difunctional chain extender, processes for their preparation and their use in the manufacture of biomaterials, devices, articles or implants.
    Type: Grant
    Filed: December 2, 2016
    Date of Patent: June 12, 2018
    Assignee: Aortech International plc
    Inventor: Ajay D. Padsalgikar
  • Patent number: 9670305
    Abstract: The present invention is related to a polyurethane dispersant and a preparation method thereof. The polyurethane dispersant is terminated by a nitrogen-containing heterocyclic compound during synthesis. The nitrogen-containing heterocyclic compound is prepared by subjecting anhydride and a compound containing a primary amine and a secondary amine or a hydroxyl or mercapto group to dehydration condensation. The condensed product is the nitrogen-containing heterocyclic compound, containing a reactive hydrogen. The structural formula of the compound containing the primary amine and the secondary amine or hydroxyl or mercapto group is shown as follows: wherein n=1 to 5, and preferably 2 to 4, R1 and R2 are respectively alkyls containing 1 to 8 carbons, R1 and R2 are independent of each other or connected by a chemical bond to form one or more saturated or unsaturated 4-member to 8-member rings, and X represents N, O, or S.
    Type: Grant
    Filed: October 8, 2012
    Date of Patent: June 6, 2017
    Assignees: AFCONA CHEMICALS (HAIMEN) CO., LTD.
    Inventor: Zhijun Wang
  • Patent number: 9512261
    Abstract: The present invention relates to a biostable polyurethane or polyurea comprising: (a) a soft segment comprising a polysiloxane of the general formula (I); and (b) greater than O and less than 40 wt % of a hard segment which is a reaction product of a diisocyanate and a linear difunctional chain extender, processes for their preparation and their use in the manufacture of biomaterials, devices, articles or implants.
    Type: Grant
    Filed: September 11, 2015
    Date of Patent: December 6, 2016
    Assignee: Aortech International plc
    Inventor: Ajay D. Padsalgikar
  • Patent number: 8293836
    Abstract: A curable coating composition includes a uretdione compound having one uretdione group and having a plurality of functional groups selected from crosslinkable groups and groups that modify a coating property. The disclosed coating compositions include those having a binder component having a plurality of active hydrogen-containing groups. When the uretdione compound has a functional group that is a crosslinkable group, the coating composition further includes a crosslinker that has a plurality of crosslinking groups reactive under curing conditions with the crosslinkable group. Also disclosed is a method of making the curable coating composition, including preparing the uretdione compound having one uretdione group and having at least one further functional group.
    Type: Grant
    Filed: May 20, 2009
    Date of Patent: October 23, 2012
    Assignee: BASF Coatings GmbH
    Inventors: David C. Cranfill, Walter H Ohrbom, Patrick J Mormile
  • Patent number: 8288486
    Abstract: Disclosed is an improved coating composition for food containers that is resistant to high pH processing environments. The improved coating composition is based upon an epoxy-amino resin coating composition that has been modified with other components to improve its performance in high pH environments balanced with flexibility, formability and abrasion resistance. Typically, the coating composition includes an epoxy resin, an amino resin cross-linking agent, a blocked polyisocyanate and a saturated polyester.
    Type: Grant
    Filed: October 12, 2011
    Date of Patent: October 16, 2012
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Armi G. Garcia, Benedick M. Francisco
  • Patent number: 8106133
    Abstract: The invention provides a flexible tube for an endoscope, which is excellent in elasticity (impact resilience), has suitable flexibility and also has chemical resistance. Disclosed is a flexible tube for an endoscope including a flexible-tube material covered thereon with a jacket, wherein the jacket contains two or more thermoplastic polyester elastomers crosslinked therein.
    Type: Grant
    Filed: July 19, 2010
    Date of Patent: January 31, 2012
    Assignee: Olympus Medical Systems Corp.
    Inventors: Hitoshi Ogura, Yuuri Takeuchi
  • Patent number: 8048970
    Abstract: Novel low viscosity oligomeric polyols and the use thereof in coating compositions are disclosed. The novel low viscosity oligomeric polyols may be prepared by reacting at least one melamine aldehyde resin and at least one of ?,?-diol, ?,?-diol, or mixture thereof. The reaction may occur in the presence of an acid catalyst. Coating compositions with a low VOC able to cure under ambient and forced dry conditions while providing good application and performance characteristics, such as an improved scratch resistance, are also disclosed.
    Type: Grant
    Filed: September 5, 2006
    Date of Patent: November 1, 2011
    Assignee: Akzo Nobel Coatings International B.V.
    Inventors: Alexander Leo Yahkind, Xueting Qiu, Dhruv Vrajlal Parekh
  • Patent number: 7872078
    Abstract: The present invention is directed to curable film-forming compositions comprising: (a) a polymeric binder comprising a polyester having hydroxyl functional groups; and (b) a curing agent comprising a polyisocyanate having at least three isocyanate functional groups. In certain embodiments, after application to a substrate as a coating and after curing, the compositions demonstrate a Fisher microhardness of at least 120 at ambient temperatures of 15 to 25° C. and a softening point greater than or equal to 35° C. Additionally, in certain embodiments, after application to a substrate as a coating and after curing, the compositions demonstrate a 20° gloss recovery of at least 75% when subjected to the DRY ABRASION TEST METHOD.
    Type: Grant
    Filed: August 28, 2007
    Date of Patent: January 18, 2011
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Lyle L. Foringer, Constantine A. Kondos, Richard J. Sadvary, Kurt G. Olson, Dennis A. Simpson
  • Patent number: 7842756
    Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.
    Type: Grant
    Filed: March 17, 2008
    Date of Patent: November 30, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Jonathan T. Martz, Erick B. Iezzi
  • Patent number: 7687576
    Abstract: A thermosetting transparent coating material, its preparation and use. The coating includes (meth)acrylate (co)polymer having a number-average molecular weight of from 1,000 to 6,000 daltons, a glass transition temperature of ?15 to +70° C., and a hydroxyl number of from 80 to 200 mg KOH/g; polyester having a number-average molecular weight of from 800 to 6,000 daltons, a hydroxyl number of from 80 to 200 mg KOH/g and an acid number of from 1 to 50 mg KOH/g, comprising, based on the polyester, from 30 to 70% by weight of cycloaliphatic structural units; a blocked polyisocyanate in which the blocked polyisocyanate groups are attached to flexibilizing structural units which, as part of a three-dimensional network, lower its glass transition temperature; and blocked polyisocyanate in which the blocked polyisocyanate groups are attached to hardening structural units which, as part of a three-dimensional network, raise its glass transition temperature.
    Type: Grant
    Filed: July 10, 2004
    Date of Patent: March 30, 2010
    Assignee: BASF Coatings AG
    Inventors: Günter Klein, Ulrike Röckrath, Jürgen Niemann, Ulrich Poth, Andre Brosseit, Karin Wermelt, Alexandra Huber
  • Patent number: 7666945
    Abstract: The present invention is directed to a non-gelled, curable composition including at least one compound having a plurality of imide functional groups. The compound in particular contains a reaction product of at least one secondary monoamine and at least one maleimide, and is suitable for use in coatings and castings.
    Type: Grant
    Filed: September 27, 2007
    Date of Patent: February 23, 2010
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Kevin C. Olson, Gregory J. McCollum, Linda K. Anderson
  • Patent number: 7655815
    Abstract: The invention relates to biuret compounds of the idealized general formula in which R1 is a (C1-C22)-alkylene, (C3-C22)-alkenylene, (C5-C15)-cycloalkylene, arylene, (C7-C12)-aralkylene, a polyoxyalkylene radical or is a polyester radical, R2 is a (C1-C22)-alkyl, hydroxy-(C1-C22)-alkyl, (C3-C18)-alkenyl, aryl, (C7-C12)-aralkyl, or (C5-C12)-cycloalkyl radical, a hydroxy-, (C1-C22)-alkoxy-, (C5-C12)-cycloalkoxy-, or (C7-C12)-aralkoxy-polyoxyalkylene radical, or a polyester radical prepared starting from a (C1-C22)-alkanol, (C5-C12)-cycloalkanol, or (C7-C12)-aralkanol or from a (C1-C22)-alkoxy-, (C6-C12)-cycloalkoxy-, or (C7-C12)-aralkoxy-polyoxyalkylene, Y stands for identical or different radicals O, NH, CO—NH—NH or NH—NH—CO, R3, R4 and R5 independently of one another are a (C2-C40)-alkylene, (C3-C40)-alkenylene, (C5-C40)-cyclo-alkylene, arylene, (C7-C40)-aralkylene or polyoxy-alkylene radical or are a polyester radical, R6 is a (C1-C30)-alkyl, (C3-C22)-alkenyl, hydroxyalkyl and hydroxyalkenyl, (C4-C13)-cy
    Type: Grant
    Filed: March 6, 2007
    Date of Patent: February 2, 2010
    Assignee: BYK-Chemie GmbH
    Inventors: Karlheinz Haubennestel, Ulrich Orth, Matthias Pickave, Stefan Moessmer, Daniela Betcke
  • Patent number: 7579127
    Abstract: The present invention is a photoconductive element containing an electrically conductive support, an electrical barrier layer disposed over said electrically conductive support and a charge generation layer capable of generating positive charge carriers when exposed to actinic radiation disposed over the barrier layer. The barrier layer is formed from a blocked polyisocyanate containing tetracarbonylbisimide groups. The present invention also discloses a new composition of a blocked polyisocyanate containing tetracarbonylbisimide groups.
    Type: Grant
    Filed: June 15, 2006
    Date of Patent: August 25, 2009
    Assignee: Eastman Kodak Company
    Inventor: Michel F. Molaire
  • Publication number: 20090155462
    Abstract: The invention provides a powder coating composition comprising (A) at least one hydroxyl functional polyester resin binder, and (B) at least one polyurethane resin as cross-linking agent containing blocked isocyanate groups, wherein the at least one hydroxyl functional polyester resin binder (A) and the at least one polyurethane resin (B) both having a melting temperature of 60 to 180° C., in particular, 60 to 160° C. The powder coating composition according to the invention provides the desired technological properties, in particular, thin films and high flexibility in combination with excellent mechanical properties of the coatings.
    Type: Application
    Filed: December 3, 2008
    Publication date: June 18, 2009
    Inventors: Carmen Flosbach, Kristina Iland, Engin Temeltas
  • Patent number: 7425594
    Abstract: A copolymer and a process of making the copolymer are disclosed. The copolymer is produced from reacting a glycidyl ester and/or ether with a polyol comprising a functionality of at least 2 wherein at least 50% by weight of the copolymer comprises a minimum of 3n+X repeating units, wherein n is a monomer unit and X is a monomer unit and/or other reactant. The copolymer may also include less than 50% of the polymeric units having the same molecular weight. The present invention is further directed to processes for preparing the copolymer and to coating compositions employing the copolymer.
    Type: Grant
    Filed: November 23, 2005
    Date of Patent: September 16, 2008
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Jonathan T. Martz, Stephen J. Thomas
  • Publication number: 20070292795
    Abstract: The present invention is a photoconductive element containing an electrically conductive support, an electrical barrier layer disposed over said electrically conductive support and a charge generation layer capable of generating positive charge carriers when exposed to actinic radiation disposed over the barrier layer. The barrier layer is formed from a blocked polyisocyanate containing tetracarbonylbisimide groups. The present invention also discloses a new composition of a blocked polyisocyanate containing tetracarbonylbisimide groups.
    Type: Application
    Filed: June 15, 2006
    Publication date: December 20, 2007
    Inventor: Michel F. Molaire