N=c=x Reactant Or Polymer Derived Therefrom Contains At Least One Aryl Group Patents (Class 525/440.12)
  • Patent number: 11732166
    Abstract: A moisture curable hot melt adhesive composition that includes isocyanate-terminated polyurethane prepolymer that includes the reaction product of a crystalline polyester polyol, a polyether polyol, and diisocyanate, clay, polyester/polyether elastomer, a first thermoplastic polymer selected from the group consisting of ethylene vinyl acetate copolymer, ethylene (alkyl)acrylate copolymer, and combinations thereof, a tackifying agent, and optionally a second thermoplastic polymer selected from the group consisting of thermoplastic polyurethane, thermoplastic polycaprolactone, and combinations thereof.
    Type: Grant
    Filed: August 26, 2020
    Date of Patent: August 22, 2023
    Assignee: H.B. Fuller Company
    Inventors: Kellen E. O'Brien, Marlen A. Valverde, Chao Wang, Chue Moua
  • Patent number: 11267928
    Abstract: The present invention relates to a process for producing a diblock copolymer comprising the reaction of at least one aromatic polyester having a melting point in the range from 160° C. to 350° C. and at least one polymer diol having a melting point of less than 100° C. at a temperature of greater than 200° C. to obtain a mixture (G-a); and the reaction of the mixture (G-a) with at least one diisocyanate, wherein the diisocyanate is employed in a molar amount of at least 0.9 based on the alcohol groups of the polymer diols. The present invention further relates to diblock copolymers obtained or obtainable according to such a process and to the use of such diblock copolymers for producing extruded, injection molded and pressed articles and also foams, cable sheaths, hoses, profiles, drive belts, fibers, nonwovens, films, moldings, plugs, housings, damping elements for the electricals industry, automotive industry, mechanical engineering, 3-D printing, medicine and consumer goods.
    Type: Grant
    Filed: February 22, 2017
    Date of Patent: March 8, 2022
    Assignee: BASF SE
    Inventors: Frank Prissok, Elmar Poeselt, Dirk Kempfert, Florian Puch, Martina Schoemer
  • Patent number: 10927253
    Abstract: The present invention relates to a process for producing a composition (I) at least comprising a compact thermoplastic polyurethane (P1), comprising the providing of at least one compact thermoplastic polyurethane (P1) or a reaction mixture for production of a compact thermoplastic polyurethane (R-P1), the adding of at least one compound (N) that has a conjugated, nitrogen-containing aromatic structure as nucleating agent to the at least one thermoplastic polyurethane (P1) or to the reaction mixture for production of a compact thermoplastic polyurethane (R-P1), wherein the compound (N) is a solid; and the mixing of the nucleating agent and the thermoplastic polyurethane (P1) or the reaction mixture (R-P1) to obtain a composition (I). The nucleating agent is used here in an amount in the range from 0.01% by weight to 2.0% by weight, based on the thermoplastic polyurethane (P1) or the reaction mixture (R-P1).
    Type: Grant
    Filed: February 22, 2017
    Date of Patent: February 23, 2021
    Assignee: BASF SE
    Inventors: Raphael Dabbous, Elmar Poeselt, Birte Lahrmann, Guido Bilges
  • Patent number: 10052849
    Abstract: A photochromic polyurethane laminate that is constructed to solve certain manufacturing difficulties involved in the production of plastic photochromic lenses is disclosed. The photochromic laminate includes at least two layers of a resinous material and a photochromic polyurethane layer that is interspersed between the two resinous layers and which contains photochromic compounds. The polyurethane layer is formed by curing a mixture of a solid thermoplastic polyurethane, at least one isocyanate prepolymer, at least one photochromic compound, and a stabilizing system.
    Type: Grant
    Filed: December 8, 2014
    Date of Patent: August 21, 2018
    Assignee: Vision Ease, LP
    Inventors: Xuzhi Qin, Hideyo Sugimura, Michael S. Boulineau
  • Patent number: 9382385
    Abstract: The present invention relates to a lactide copolymer exhibiting excellent flexibility and having more improved processability and productivity at the time of performing an extrusion and molding process, and a resin composition and film including the same, wherein the lactide copolymer includes a predetermined number of block copolymer repeating units in which hard segments of polylactide repeating units are bound to both ends of soft segments of polyether polyol repeating units, and has a weight-average molecular weight of 150,000 to 300,000, and a melt index y (MI; g/10 min) satisfying a specific relationship, the MI being measured under a load of 2.16 kg and at a temperature of x? between 170? and 210?.
    Type: Grant
    Filed: December 4, 2013
    Date of Patent: July 5, 2016
    Assignee: LG Chem, Ltd.
    Inventors: Jung Min Sohn, Seung Young Park, Kyung Seog Youk, Seung Ho Choi
  • Patent number: 9228111
    Abstract: Provided is a resin composition for surface treatment of a steel sheet including a binder resin, graphene and a solvent. More particularly, as only a small amount of the graphene is included in the resin composition used for surface treatment of a steel sheet, a user-required electrical conductivity can be provided to the steel sheet.
    Type: Grant
    Filed: October 29, 2009
    Date of Patent: January 5, 2016
    Assignee: POSCO
    Inventors: Jae Dong Cho, Jae Soon Lee, Jae Ryung Lee, Sang Eun Shim
  • Publication number: 20150133610
    Abstract: The invention refers to a thermoplastic polyurethane produced from at least an organic diisocyanate and a compound which is reactive toward isocyanates, wherein the polyurethane comprises the ester of a tricarboxylic acid with at least one alcohol and wherein all acid groups of the tricarboxylic acid are esterified with an alcohol. The invention further refers to a process for producing the respective polyurethane, products comprising this thermoplastic polyurethane and the use of the ester of a tricarboxylic acid as plasticizer in thermoplastic polyurethanes.
    Type: Application
    Filed: January 20, 2015
    Publication date: May 14, 2015
    Applicant: BASF SE
    Inventors: Bin-Eric CHEN, Frank Schaefer, Dirk Kempfert, Christoph Bahr, Guenter Scholz, Teruya Ohkuwa, Martin Vallo, Carsten Guenther, Harald Schulz, Yasuyuki Suzuki, Tien Kuan Lim
  • Patent number: 9012590
    Abstract: The present invention relates to an electrostatic dissipative thermoplastic polyurethane composition made by reacting (a) at least one polyester polyol intermediate with (b) at least one diisocyanate and (c) at least one chain extender. The polyester polyol intermediate, may be derived from at least one dialkylene glycol and at least one dicarboxylic acid, or an ester or anhydride thereof. The invention further provides for methods of making said thermoplastic polyurethane composition, polymer blends containing said thermoplastic and polymer articles made from said thermoplastic.
    Type: Grant
    Filed: October 1, 2010
    Date of Patent: April 21, 2015
    Assignee: Lubrizol Advanced Materials, Inc.
    Inventors: Qiwei Lu, Donald A. Meltzer, Yona Eckstein
  • Publication number: 20150087774
    Abstract: The present invention relates to a composition comprising 10 to less than 50 wt.-% of at least one oligomeric polyisocyanate a-1) based on hexamethylene diisocyanate and more than 50 to 90 wt.-% of at least one polyisocyanate a-2) based on isophorone diisocyanate, comprising monomeric isophorone diisocyanate and at least one oligomeric isophorone diisocyanate, and an isocyanate-reactive component selected from the group consisting of polyester polyol, polyether polyol and mixtures thereof. It has been shown that the above mentioned mixture of the specific isocyanate group containing components improves the thermal and mechanical properties of a cured composition. Thus prepared molded articles are particularly suitable for the preparation of spectacle lenses, inter alia due to these properties.
    Type: Application
    Filed: April 22, 2013
    Publication date: March 26, 2015
    Inventors: Dorota Greszta-Franz, Hans-Josef Laas, Hartmut Nefzger, Jens Krause
  • Publication number: 20150005450
    Abstract: An adhesive for solar battery back sheets obtainable by mixing (A) a urethane prepolymer having an isocyanate group at the end with (B) a polyol, wherein the urethane prepolymer (A) is obtainable by a reaction of a hydroxyl group-containing compound with an isocyanate compound, and the hydroxyl group-containing compound comprises a polycaprolactone polyol. Also, cured reaction products of the adhesive. Also, a solar battery back sheet and a solar cell module comprising the adhesive.
    Type: Application
    Filed: September 18, 2014
    Publication date: January 1, 2015
    Inventors: Yuichi Matsuki, Noriyoshi Kamai, Yasushi Yamada
  • Publication number: 20140301757
    Abstract: A toner including at least a crystalline resin as a binder resin, wherein a tetrahydrofuran soluble content of the toner includes 5.0% or more as a peak area of a component having a molecular weight of 100,000 or greater in a molecular weight distribution measured by gel permeation chromatography, and the tetrahydrofuran soluble content of the toner has a weight-average molecular weight of 20,000 to 60,000.
    Type: Application
    Filed: October 17, 2012
    Publication date: October 9, 2014
    Inventors: Shingo Sakashita, Shinya Nakayama, Masahide Yamada, Atsushi Yamamoto, Hideyuki Santo, Yukiko Nakajima, Suzuka Amemori
  • Publication number: 20140163178
    Abstract: The present invention relates to a lactide copolymer having good flexibility in addition to excellent properties such as mechanical properties and processability and preferably being applicable as a packaging material, a preparation method thereof, and a resin composition including the same. The lactide copolymer includes two or more specific block copolymerized repeating units that the hard segments of polylactide repeating units are connected to both ends of the soft segments of polyether polyol repeating unit, and the block copolymerized repeating units are connected to each other through the intermediation of urethane connecting groups derived from polyvalent isocyanate compound of which the average equivalent of isocyanate group per a molecule is more than 2 and less than 3.
    Type: Application
    Filed: December 3, 2013
    Publication date: June 12, 2014
    Applicant: LG Chem, Ltd.
    Inventors: Jung-Min Sohn, Seung Young Park, Sung-Cheol Yoon, Do-Yong Shim
  • Patent number: 8563654
    Abstract: An object of the present invention is to provide a golf ball comprising a core and a cover, wherein the cover is made from a cover composition containing, as a resin component, a thermoplastic polyurethane (A) and a polyisocyanate mixture (B) in which a urethane prepolymer (b-1) having at least two isocyanate groups is dispersed in a thermoplastic resin (b-2) which does not substantially react with an isocyanate group; and wherein the cover composition has a slab hardness of more than 60 and not more than 75, and the cover has a thickness of 2.5 mm or less.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: October 22, 2013
    Assignee: SRI Sports Limited
    Inventors: Tsutomu Hirau, Toshiyuki Tarao
  • Publication number: 20130269520
    Abstract: The present invention generally relates to a reactive functional group-modified molecularly self-assembling material; method of making the reactive functional group-modified molecularly self-assembling material; manufactured article comprising the reactive functional group-modified molecularly self-assembling material; and a method of shaping the reactive functional group-modified molecularly self-assembling material.
    Type: Application
    Filed: December 20, 2011
    Publication date: October 17, 2013
    Applicant: DOW GLOBAL TECHNOLOGIES INC.
    Inventors: William J. Harris, Pushkala Krishnamurthy, Scott T. Matteucci
  • Publication number: 20130095422
    Abstract: A toner, including a crystalline resin as a binder resin, wherein the toner comprises a THF-soluble component in a weight-average molecular weight not less than 20,000, and has a 50% wettability not less than 20% by volume when subjected to a methanol wettability test.
    Type: Application
    Filed: October 1, 2012
    Publication date: April 18, 2013
    Inventors: Atsushi YAMAMOTO, Shinya Nakayama, Masahide Yamada, Hideyuki Santo, Daiki Yamashita, Ryota Inoue
  • Patent number: 8389647
    Abstract: The present invention relates to a laminating adhesive composition, which contains a reaction product which contains isocyanate groups and which is obtained from the reaction of at least two specific polyester polyols, solid at room temperature, and a polyisocyanate. Particularly in the case of three-dimensionally deformed support material surfaces, the laminating adhesive compositions permit removal from the laminating mold at an elevated temperature.
    Type: Grant
    Filed: February 26, 2009
    Date of Patent: March 5, 2013
    Assignee: Sika Technology AG
    Inventor: Kai Paschkowski
  • Patent number: 8367781
    Abstract: The invention provides a golf ball having a core and one or more cover layer encasing the core, wherein at least one cover layer is formed by injection-molding a single resin composition of primarily (A) a thermoplastic polyurethane and (B) a polyisocyanate compound, and at least some polyisocyanate compound in which all the isocyanate groups on the molecule remain in an unreacted state is present in the resin composition. The golf ball has a high rebound, an excellent spin performance and an excellent scuff resistance, and the cover layer-forming resin composition has excellent flow properties and an excellent cover layer manufacturability.
    Type: Grant
    Filed: July 27, 2011
    Date of Patent: February 5, 2013
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Hiroyuki Nagasawa, Hiroshi Higuchi, Motoki Aoyagi, Daisuke Arai
  • Patent number: 8349952
    Abstract: An object of the present invention is to provide a golf ball which is excellent in abrasion-resistance and durability. The golf ball of the present invention comprises a cover using a cover composition containing thermoplastic polyurethane (A) and a polyisocyanate mixture (B) in which a urethane prepolymer (b-1a) having at least two isocyanate groups or a polyisocyanate (b-1b) having at least three isocyanate groups is dispersed in a thermoplastic resin (b-2) which does not substantially react with the isocyanate groups.
    Type: Grant
    Filed: December 28, 2007
    Date of Patent: January 8, 2013
    Assignee: Dunlop Sports Co. Ltd.
    Inventor: Toshiyuki Tarao
  • Patent number: 8318845
    Abstract: The invention provides a golf ball having a core and a cover of at least one layer that is formed over the core and is made of a resin composition. The ball has a weight change ratio, in a 72-hour accelerated moisture absorption test conducted at a temperature of 40° C. and a relative humidity of 90%, of less than 0.287%. By using in the golf ball a polyurethane having a good resistance to water vapor transmission, the weight change ratio and decrease in initial velocity with use over an extended period of time are held to a minimum, enabling the ball quality to be maintained.
    Type: Grant
    Filed: October 7, 2009
    Date of Patent: November 27, 2012
    Assignee: Bridgestone Sports Co., Ltd.
    Inventors: Satoshi Matsuda, Hiroyuki Nagasawa
  • Patent number: 8148474
    Abstract: An object of the present invention is to provide a golf ball which has excellent durability and wear-resistance and provides an excellent shot feeling. The present invention is directed to a golf ball comprising: a core; and a cover covering the core, wherein the cover is formed from a cover composition containing a thermoplastic polyurethane (A), a polyisocyanate (B) having at least two isocyanate groups, and a polyhydroxyether (C) as a resin component, and wherein the core has a surface hardness of 85 or smaller in JIS-C hardness.
    Type: Grant
    Filed: December 24, 2008
    Date of Patent: April 3, 2012
    Assignee: SRI Sports Limited
    Inventors: Keiji Ohama, Hirotaka Nakamura, Toshiyuki Tarao
  • Patent number: 8106133
    Abstract: The invention provides a flexible tube for an endoscope, which is excellent in elasticity (impact resilience), has suitable flexibility and also has chemical resistance. Disclosed is a flexible tube for an endoscope including a flexible-tube material covered thereon with a jacket, wherein the jacket contains two or more thermoplastic polyester elastomers crosslinked therein.
    Type: Grant
    Filed: July 19, 2010
    Date of Patent: January 31, 2012
    Assignee: Olympus Medical Systems Corp.
    Inventors: Hitoshi Ogura, Yuuri Takeuchi
  • Publication number: 20110306734
    Abstract: The present invention relates to a thermoplastically processable polyurethane elastomer having a hardness of 50 Shore A to 70 Shore D (ISO 868), which are obtained from reacting components comprising a) one or more linear polyester diols having a functionality from 1.8 to 2.2, wherein the one or more linear polyester diols comprise succinic acid 1,3-propionate and have an average molecular weight from 1,950 to 4,000 g/mol. b) one or more organic diisocyanates, and c) one or more diols having a molecular weight from 60 to 350 g/mol, wherein the components have a molar NCO:OH ratio of from 0.9:1 to 1.1:1.
    Type: Application
    Filed: May 26, 2011
    Publication date: December 15, 2011
    Applicant: Bayer MaterialScience AG
    Inventors: Wolfgang Bräuer, Yi Shen, Wolfgang Kaufhold, Hartmut Nefzger, Henricus Peerlings
  • Patent number: 8048958
    Abstract: An object of the present invention is to provide a golf ball comprising a core and a cover, wherein the cover is made from a cover composition containing, as a resin component, a thermoplastic polyurethane (A) and a polyisocyanate mixture (B) in which a polyisocyanate (b-1) having at least three isocyanate groups is dispersed in a thermoplastic resin (b-2) which does not substantially react with an isocyanate group; and wherein the cover composition has a slab hardness of more than 60 and not more than 75 in Shore D hardness, and the cover has the thickness of 2.5 mm or less.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: November 1, 2011
    Assignee: SRI Sports Limited
    Inventors: Tsutomu Hirau, Toshiyuki Tarao
  • Patent number: 8017690
    Abstract: An object of the present invention is to provide a golf ball comprising a core consisting of a center and at least one intermediate layer covering the center, and a cover covering the core, wherein the cover is made from a cover composition containing, as a resin component, a thermoplastic polyurethane (A) and a polyisocyanate mixture (B) in which a urethane prepolymer (b-1) having at least two isocyanate groups is dispersed in a thermoplastic resin (b-2) which does not substantially react with an isocyanate group; and wherein the cover composition has a slab hardness of more than 60 and not more than 75 in Shore D hardness, and at least one piece or one layer of the intermediate layer is formed from a low hardness intermediate layer composition which has a slab hardness of 40 or less in Shore D hardness.
    Type: Grant
    Filed: November 7, 2008
    Date of Patent: September 13, 2011
    Assignee: SRI Sports Limited
    Inventors: Tsutomu Hirau, Toshiyuki Tarao
  • Patent number: 7754828
    Abstract: A two-component bonding agent composition. The composition contains: (a) an isocyanate component comprising a difunctional isocyanate-terminated prepolymer having polymerized residues of at least one difunctional aromatic isocyanate and at least one difunctional polymer of ethylene oxide, propylene oxide or a combination thereof; (b) a polyol component comprising a triglyceride having hydroxyl functional groups; and (c) an adhesion promoter.
    Type: Grant
    Filed: December 19, 2008
    Date of Patent: July 13, 2010
    Assignee: Rohm and Haas Company
    Inventors: Pankaj V. Shah, Joseph J. Zupancic
  • Publication number: 20090214875
    Abstract: The present invention relates to a laminating adhesive composition which contains a reaction product which contains isocyanate groups and which is obtained from the reaction of at least two specific polyester polyols, solid at room temperature, and a polyisocyanate. Particularly in the case of three-dimensionally deformed support material surfaces, the laminating adhesive compositions permit removal from the laminating mould at an elevated temperature.
    Type: Application
    Filed: February 26, 2009
    Publication date: August 27, 2009
    Applicant: SIKA TECHNOLOGY AG
    Inventor: Kai Paschkowski
  • Patent number: 7569319
    Abstract: A polyester binder resin for a toner that excels in low-temperature fixing properties, offset resistance, development durability, long-term storability, electrification properties, pulverizability, etc.; and a toner containing the same. The binder resin for a toner is comprised of a polyester resin and, dispersed therein, a wax having a substituent selected from among a substituent of aromatic structure (representative example thereof is a group derived from a styrene compound), a carboxyl group and a hydroxyl group, or comprised of a polyester resin having the above wax introduced in the structure thereof. The toner containing the above binder resin for toner exhibits excellent capability in not only, as fundamental performance of toner, low-temperature fixing properties and offset resistance but also development durability, antiblocking properties and pulverizability.
    Type: Grant
    Filed: November 26, 2003
    Date of Patent: August 4, 2009
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hirotaka Uosaki, Hiroyuki Takei, Yuji Emura, Hiroshi Matsuoka