Contains Phenolic Reactant Or Polymer Thereof Patents (Class 525/442)
  • Patent number: 8859651
    Abstract: Compositions including a blend of a) a polysulfone (PSU); b) a polyphenylene sulfide (PPS); and, c) a polyetherimide and epoxy. The polyetherimide and epoxy can be present in an amount effective to act as a compatibilizer for the polysulfone (PSU) and polyphenylene sulfide (PPS). Various embodiments relate to a method of compatibilizing a blend of polysulfone (PSU) and polyphenylene sulfide (PPS). The method can include a) melt mixing a polysulfone (PSU) and a polyetherimide; and b) melt mixing a polyphenylene sulfide (PPS) and an epoxy. Step a) and b) can be carried out by one of sequential mixing and simultaneous mixing.
    Type: Grant
    Filed: March 8, 2013
    Date of Patent: October 14, 2014
    Assignee: Sabic Global Technologies B.V.
    Inventors: Hariharan Ramalingam, Kapil Sheth
  • Publication number: 20140194580
    Abstract: Compositions including a blend of a) a polysulfone (PSU); b) a polyphenylene sulfide (PPS); and, c) a polyetherimide and epoxy. The polyetherimide and epoxy can be present in an amount effective to act as a compatibilizer for the polysulfone (PSU) and polyphenylene sulfide (PPS). Various embodiments relate to a method of compatibilizing a blend of polysulfone (PSU) and polyphenylene sulfide (PPS). The method can include a) melt mixing a polysulfone (PSU) and a polyetherimide; and b) melt mixing a polyphenylene sulfide (PPS) and an epoxy. Step a) and b) can be carried out by one of sequential mixing and simultaneous mixing.
    Type: Application
    Filed: March 8, 2013
    Publication date: July 10, 2014
    Applicant: SABIC INNOVATIVE PLASTICS IP B.V.
    Inventors: Hariharan Ramalingam, Kapil Sheth
  • Publication number: 20140194556
    Abstract: Blends of a polyphenylene sulfone (PPSU); a polyphenylene sulfide (PPS); and, a polyetherimide and epoxy. The polyetherimide and epoxy are present in an amount effective to act as a compatibilizer for the polyphenylene sulfone (PPSU) and polyphenylene sulfide (PPS). Methods of compatibilizing a blend of polyphenylene sulfone (PPSU) and polyphenylene sulfide (PPS). The method can include melt mixing a polyphenylene sulfone (PPSU) and a polyetherimide; and melt mixing a polyphenylene sulfide (PPS) and an epoxy.
    Type: Application
    Filed: March 8, 2013
    Publication date: July 10, 2014
    Applicant: SABIC Innovative Plastics IP B.V.
    Inventors: Hariharan Ramalingam, Mark Sanner, Kapil Sheth
  • Publication number: 20110305883
    Abstract: Provided are an adhesive resin composition that is halogen-free, has good adhesiveness, solder heat resistance, and flame retardancy, and has good flow characteristics, and a laminate and a flexible printed wiring board using the same. The adhesive resin composition contains a phosphorus-containing epoxy resin and/or a phosphorus-containing phenoxy resin, a phosphorus-containing polyester resin having a weight-average molecular weight of more than 20,000 and 150,000 or less, another thermoplastic resin, and a curing agent. The adhesive resin composition preferably further contains a benzoxazine compound. Preferably, substantially no inorganic filler is mixed in the adhesive resin composition.
    Type: Application
    Filed: January 18, 2010
    Publication date: December 15, 2011
    Applicants: SUMITOMO ELECTRIC PRINTED CIRCUITS, INC., SUMITOMO ELECTRIC INDUSTRIES, LTD.
    Inventors: Shingo Kaimori, Jun Sugawara, Akira Mizoguchi, Syougo Asai, Takuma Yoshisaka, Naota Uenishi
  • Patent number: 8067144
    Abstract: The present invention relates to a polyester having an excellent hydrolysis resistance even when used in a process for producing a toner for electrophotography which includes a step of forming a raw material into particles in an aqueous medium, and a toner for electrophotography which contains the polyester and is excellent in storage stability and fixing property. There are provided a polyester for a toner for electrophotography which is used in a process for producing a toner including a step of forming a raw material component into particles in an aqueous medium or a solution, and produced by polycondensing an alcohol component with a carboxylic acid component containing at least one compound selected from the group consisting of an alkyl succinic acid and an alkenyl succinic acid, as well as a toner for electrophotography which contains the polyester.
    Type: Grant
    Filed: April 24, 2008
    Date of Patent: November 29, 2011
    Assignee: Kao Corporation
    Inventors: Hiroshi Mizuhata, Takashi Kubo, Takashi Mukai, Hidehito Ikebata, Katsutoshi Aoki
  • Patent number: 7927691
    Abstract: A prepreg composite material that includes a fiber layer and a resin comprising a thermoset resin component, a curing agent and a fibrous micropulp. The micropulp component is an aramid fiber having a volume average length of from 0.01 to 100 micrometers. The prepreg is useful in composite panel construction for minimizing fluid permeation into the cured structure. This prepreg is particularly suitable for making honeycomb sandwich panels. Film adhesives, liquid and paste resins containing aramid fiber micropulp are also disclosed.
    Type: Grant
    Filed: April 3, 2009
    Date of Patent: April 19, 2011
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: Subhotosh Khan, Halvar Young Loken
  • Patent number: 7452938
    Abstract: There is provided an aqueous resin composition excellent in settability, flexibility, retort resistance, hygienicity, sprayability and dispersibility in water, and used to coat an internal surface of a can.
    Type: Grant
    Filed: March 10, 2005
    Date of Patent: November 18, 2008
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Osamu Morimoto, Hideki Tanaka, Kayoko Takino, Katsuya Shimeno, Yasunari Hotta
  • Publication number: 20070208145
    Abstract: Poly(arylene ether)-polyester block copolymers and methods for their preparation are provided. The block copolymers include structural units derived from a poly(arylene ether), a hydroxy-terminated polyester, and an activated aromatic carbonate.
    Type: Application
    Filed: June 15, 2006
    Publication date: September 6, 2007
    Applicant: GENERAL ELECTRIC COMPANY
    Inventors: Rene de Kok, Erik R. Delsman, Amy R. Freshour, Farah Jean-Jacques Toublan, Edward N. Peters, Gary W. Yeager
  • Patent number: 7030197
    Abstract: There is provided an aqueous resin composition excellent in settability, flexibility, retort resistance, hygienicity, sprayability and dispersibility in water, and used to coat an internal surface of a can.
    Type: Grant
    Filed: July 3, 2002
    Date of Patent: April 18, 2006
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Osamu Morimoto, Hideki Tanaka, Kayoko Takino, Katsuya Shimeno, Yasunari Hotta
  • Patent number: 7001560
    Abstract: The present invention provides a resin composition suitable for molding a microscopic structure that has small cure shrinkage, good mold transfer properties and excellent properties for post-processing such as polishing processing and laser processing. Such a resin is a thermosetting resin composition comprising 95 to 35 wt % of a thermosetting resin and 5 to 65 wt % of organic filler having a particle size of 10 ?m or less. From such a resin, an ink ejecting apparatus having a microscopic structure, for example, a nozzle of a diameter of 30 ?m, is integrally molded.
    Type: Grant
    Filed: July 2, 2001
    Date of Patent: February 21, 2006
    Assignee: Cluster Technology Co., Ltd.
    Inventors: Minoru Adachi, Shoji Uesugi
  • Patent number: 6830804
    Abstract: Unsaturated polyetherester resins, and processes for making them, are described which are useful for making curable thermoset resin compositions, intermediates for curable thermoset resin compositions, fiber-reinforced polymer composites, intermediates for making skin laminates for gel coated fiber-reinforced composites and gel coated polymer laminates. The unsaturated polyetherester resins are obtainable by reacting at least one acid-terminated unsaturated polyetherester resin with at least one aromatic polyol having at least one non-primary hydroxy group to produce an unsaturated polyetherester resin at least partially end-capped with an aromatic polyol. The described processes, compositions, methods and uses improve the chemical and/or water resistance of resin compositions, particularly composite materials having a gel coat.
    Type: Grant
    Filed: March 28, 2001
    Date of Patent: December 14, 2004
    Assignee: Cook Composites and Polymers Co.
    Inventors: Chih-Pin Hsu, Ming Yang Zhao, Linda Bergstrom
  • Patent number: 6815495
    Abstract: A coating solution for producing a cured coating, particularly for metallic surfaces, includes (1) a binder containing organic polymers with optional organic or inorganic addictions and (2) at least one of a melamine resin, an epoxy resin, a polyurethane resin, an alkyd resin, or mixtures thereof. The coating solution, in the liquid state, contains water. The binder contains 50-100% phenolic resin, preferably based on phenol and/or resorcinol.
    Type: Grant
    Filed: May 17, 2001
    Date of Patent: November 9, 2004
    Assignee: DaimlerChrysler AG
    Inventors: Anita Marten, Daniela Maichel
  • Patent number: 6657016
    Abstract: A polyester resin composition comprising 50 equivalents/ton or more of an aromatic ring in the resin and at least one thermosetting resin selected from the group consisting of melamine resin, urea resin, benzoguanamine resin and phenol resin. The aromatic ring in the polyester resin has a phenolic hydroxyl group and at least one of ortho-position and para-position of the aromatic ring to the phenolic hydroxyl group is a hydrogen atom. The resin composition has excellent toughness at ambient temperature and heat resistance.
    Type: Grant
    Filed: March 14, 2002
    Date of Patent: December 2, 2003
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventor: Takeshi Yatsuka
  • Publication number: 20030176595
    Abstract: A polyester resin composition comprising 50 equivalents/ton or more of an aromatic ring in the resin and at least one thermosetting resin selected from the group consisting of melamine resin, urea resin. benzoguanamine resin and phenol resin. The aromatic ring in the polyester resin has a phenolic hydroxyl group and at least one of ortho-position and para-position of the aromatic ring to the phenolic hydroxyl group is a hydrogen atom. The resin composition has excellent toughness at ambient temperature and heat resistance.
    Type: Application
    Filed: March 14, 2002
    Publication date: September 18, 2003
    Inventor: Takeshi Yatsuka
  • Patent number: 6518370
    Abstract: Dispersants that adsorb to hydrophobic particle surfaces in aqueous media are described. The dispersants comprise dendritic polymers having at least one ionizable moiety and at least one peripheral hydrophobic long chain hydrocarbon moiety. Dispersions and inks wherein the dispersant operates as a solitary or co-dispersant are also described.
    Type: Grant
    Filed: May 16, 2001
    Date of Patent: February 11, 2003
    Assignee: 3M Innovative Properties Company
    Inventors: Ahmed Salih Abuelyaman, Prabhakara Satyauolu Rao, Babu N. Gaddam
  • Patent number: 6492462
    Abstract: The rheological properties of a crosslinkable resin system are modified by the presence of a side chain crystalline (SCC) polymer (or a similar crystalline polymer which melts over a narrow temperature range). The polymer dissolves in the curable system at temperatures above the melting point of the crystalline polymer (Tp), but when the system is then cooled to a temperature below Tp, at least partially forms a separate phase in the curable system. Below Tp, this separate phase substantially increases the viscosity of the curable system (i.e. makes it thicker than the same system without the crystalline polymer). This is particularly valuable for sheet molding composites (SMCs) in which the increase in viscosity makes the composites less tacky, and for dry film resists (DFRs). Above Tp, the curable system containing the dissolved crystalline polymer has a viscosity which is substantially less than its viscosity below Tp.
    Type: Grant
    Filed: December 19, 2000
    Date of Patent: December 10, 2002
    Assignee: Landec Corporation
    Inventors: Steven P. Bitler, David D. Taft, Ray F. Stewart
  • Patent number: 6458443
    Abstract: The invention concerns a stain resist composition comprising: (a) a component selected from the group consisting of (1) an anionically modified phenol formaldehyde polymer comprising a phenol moiety and a formaldehyde moiety, (2) a naphthalene condensate, (3) a lignin sulfonate, (4) a phenol sulfonate derivative, a mixture thereof and (5) a (meth)acrylic polymer comprising residues of acrylic or methacrylic acid; and (b) a polyester.
    Type: Grant
    Filed: July 24, 1998
    Date of Patent: October 1, 2002
    Assignee: Arrow Engineering, Inc.
    Inventors: Robert B. Collier, J. Todd Mull
  • Patent number: 6420491
    Abstract: A catayltic process for the hydrogenation of aromatic polymers is disclosed. The catalyst used in the process is a metal or mixture of metals of sub-group VIII of the periodic table together with a support of silicon dioxide, aluminum oxide or a mixture thereof. The catalyst, having pores is characaterized in that the pores having diameters of 100 to 1,000 Å constitute less than 15 percent of the total volume of pores. The hydrogenation, that is carried out in the presence of at least one oxygen-containing hydrocarbon is characterized in that it is essentially complete and without significant degradation of molecular weights.
    Type: Grant
    Filed: January 16, 2001
    Date of Patent: July 16, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Volker Wege, Johann Rechner, Eberhard Zirngiebl
  • Patent number: 6391967
    Abstract: This invention discloses a flame retarding thermoplastic resin composition, which is comprised of (i) a thermoplastic resin and (ii) a phenolic resin compound as a flame retardant, wherein the phenolic resin compound contains a nitrogen-containing heterocycle and phosphorus. Since the flame retarding thermoplastic resin composition of this invention does not contain halogen, and has excellent flame retardant properties and high heat resistance, it is useful in producing parts and products in the fields of electronics, electricity and automobile.
    Type: Grant
    Filed: February 11, 2000
    Date of Patent: May 21, 2002
    Assignee: Chang Chun Plastics Co., Ltd.
    Inventors: Kuen-Yuan Hwang, Hong-Hsing Chen, Ying-Ling Liu, Wen-Tsai Tsai
  • Patent number: 6392003
    Abstract: The present invention provides a flame retardant phenol resin material which includes a phenol condensate, wherein a poly-aromatic compound obtained by a reaction of phenols (A) to aromatics (B) except for phenols and a heterocyclic compound (C) including nitrogen as heteroatom are condensed via aldehydes (D), and also provides a flame retardant epoxy resin material which includes an epoxy resin obtained by glycidyl-etherification of at least a part of phenolic hydroxyl groups of a poly-aromatic compound obtained by a reaction of phenols (A) to aromatics (B) except for phenols and a heterocyclic compound (C) including nitrogen as heteroatom are condensed via aldehydes (D).
    Type: Grant
    Filed: December 15, 1999
    Date of Patent: May 21, 2002
    Assignee: NEC Corporation
    Inventors: Yukihiro Kiuchi, Masatoshi Iji, Makoto Soyama
  • Publication number: 20020055597
    Abstract: Unsaturated polyetherester resins, and processes for making them, are described which are useful for making curable thermoset resin compositions, intermediates for curable thermoset resin compositions, fiber-reinforced composites, intermediates for making skin laminates for gel coated fiber-reinforced composites and gel coated polymer laminates. The unsaturated polyetherester resins are obtainable by reacting at least one acid-terminated unsaturated polyetherester resin with at least one aromatic polyol having at least one non-primary hydroxy group to produce an unsaturated polyetherester resin at least partially end-capped with an aromatic polyol. The described processes, compositions, methods and uses improve the chemical and/or water resistance of resin compositions, particularly composite materials having a gel coat. That improvement has special significance in outdoor and marine applications, bathtubs and shower stalls, and environments exposed to chemicals such as industrial and commercial applications.
    Type: Application
    Filed: March 28, 2001
    Publication date: May 9, 2002
    Inventors: Chih-Pin Hsu, Ming Yang Zhao, Linda Bergstrom
  • Patent number: 6376624
    Abstract: Compositions based on high viscosity, high molecular weight polyesters are prepared by heating a molten mixture of: (A) a prepolymer of a polyester resin; and (B) 0.05-10 wt %, based one the weight of the polyester prepolymer, of a multifunctional polymeric chain extender having functional groups selected from the group consisting of epoxy and isocyanate.
    Type: Grant
    Filed: April 6, 2000
    Date of Patent: April 23, 2002
    Assignee: Industrial Technology Research Institute
    Inventors: Hsin-Ching Kao, Lee-Hua Chen, Chi-Lang Wu, Jinn-Jong Wong, Szu-Yuan Chan, Sheng-Te Yang
  • Patent number: 6312824
    Abstract: The invention provides a composition that exhibits good adhesion to polyamide material and other materials, comprising 60 to 99 weight percent of a copolyester elastomer, and 1 to 40 weight percent of a novolac resin, based on the total weight of the copolymer elastomer and the novolac resin only, wherein the composition comprises greater than 50 weight percent copolyester elastomer based on the total weight of the composition. The invention also concerns an article comprising at least two materials bonded together at one or more defined contact surfaces, a first one of the bonded materials comprising a copolyester elastomer and a novolac resin. Such bodies can be welded, injection molded, and extruded simultaneously or sequentially.
    Type: Grant
    Filed: August 27, 1999
    Date of Patent: November 6, 2001
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Jean-Michel Philippoz, Edmund Arthur Flexman, Jr.
  • Publication number: 20010024696
    Abstract: Transparent or pigmented powder coating materials with crosslinkers comprising hydroxyalkylamides and polyisocyanates containing uretdione groups.
    Type: Application
    Filed: February 26, 2001
    Publication date: September 27, 2001
    Applicant: Degussa-Huls Aktiengesellschaft
    Inventor: Andreas Wenning
  • Patent number: 6258896
    Abstract: Dispersants that adsorb to hydrophobic particle surfaces in aqueous media are described. The dispersants comprise dendritic polymers having at least one ionizable moiety and at least one peripheral hydrophobic long chain hydrocarbon moiety. Dispersions and inks wherein the dispersant operates as a solitary or co-dispersant are also described.
    Type: Grant
    Filed: December 18, 1998
    Date of Patent: July 10, 2001
    Assignee: 3M Innovative Properties Company
    Inventors: Ahmed Salih Abuelyaman, Prabhakara Satyauolu Rao, Babu N. Gaddam
  • Patent number: 6211305
    Abstract: Unsaturated polyetherester resins, and processes for making them, are described which are useful for making curable thermoset resin compositions, intermediates for curable thermoset resin compositions, fiber-reinforced polymer composites, intermediates for making skin laminates for gel coated fiber-reinforced composites and gel coated polymer laminates. The unsaturated polyetherester resins are obtainable by reacting at least one acid-terminated unsaturated polyetherester resin with at least one aromatic polyol having at least one non-primary hydroxy group to produce an unsaturated polyetherester resin at least partially end-capped with an aromatic polyol. The described processes, compositions, methods and uses improve the chemical and/or water resistance of resin compositions, particularly composite materials having a gel coat.
    Type: Grant
    Filed: January 19, 1999
    Date of Patent: April 3, 2001
    Assignee: Cook Composites and Polymers Co.
    Inventors: Chih-Pin Hsu, Ming Yang Zhao, Linda Bergstrom
  • Patent number: 6143219
    Abstract: The present invention discloses a generic method for producing void and gas occlusion free materials, as well as apparatuses for batch and continuous production of same. This generic method can be utilized in the production of a wide variety of polymeric compounds and composites and specifically encompasses the two ends of the polymeric composite spectrum, that is, polymer concretes on the one hand, and fiber-reinforced polymer composites on the other. The composite materials of the present invention are characterized by visual count as being void and gas occlusion free to the level of 1 micron at 1250.times. magnification. Concomitantly, the invention produces useful polymer concrete materials which exhibit substantially improved integrity for easy machining at high speeds, and high dielectric and mechanical strength, as compared with composite materials produced by conventional methods.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: November 7, 2000
    Assignee: Mardela International Inc. S.A.
    Inventors: Victor H. Vidaurre, Wilfredo G. Bendek, Jorge L. Dufeu
  • Patent number: 6093777
    Abstract: A partially or fully cured thermosetting product which includes a cured and molded product of a thermosetting composition. The composition includes 70% to 99% by weight of at least one thermosetting resin or compound and 1% to 30% by weight of at least one toughening agent. The toughening agent is at least one hyperbranched dendritic macromolecule formed of ester units, optionally in combination with ether units.
    Type: Grant
    Filed: November 3, 1997
    Date of Patent: July 25, 2000
    Assignee: Perstorp AB
    Inventors: Kent Sorensen, Bo Pettersson, Louis Boogh, Jan-Anders Edvin Manson
  • Patent number: 5990247
    Abstract: The thermosetting composition of the present invention includes an unsaturated polyester, an addition polymerizable monomer, a low shrink agent other than an aliphatic polyester, and an aliphatic polyester decomposed in a decomposing solution containing a base and at least one solvent selected from the group consisting of water, methanol, ethanol, and ethylene glycol at a temperature lower than a boiling point of the decomposing solution after being cured.
    Type: Grant
    Filed: February 26, 1998
    Date of Patent: November 23, 1999
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Takahiko Terada, Hiroshi Onishi
  • Patent number: 5976706
    Abstract: Polyesterdiols having low viscosities of less than 3500 cps, high content of non-volatile matter in excess of 96 wt %, and narrow molecular weight distribution of less than about 1.4 are prepared by esterification of one or more aliphatic dicarboxylic acids or ester derivatives thereof using at least a 1.5 molar excess of one or more aliphatic diols until an acid number of less than 20 is achieved, and stripping excess diol from the polyesterdiol reaction product. Where esterification catalyst is used, catalyst is substantially removed prior to stripping excess unreacted diol from polyesterdiol reaction product. The polyesterdiols so produced are useful as (i) curable components in thermosettable resin compositions, particularly compositions essentially free of volatile organic solvent and also containing a crosslinking agent and a reactive hardening agent: and/or (ii) useful as coatings, paints and adhesives, providing coatings with very low content of volatile organic compounds.
    Type: Grant
    Filed: July 27, 1998
    Date of Patent: November 2, 1999
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Albert Ilya Yezrielev, Konstantinos R. Rigopoulos, Richard William Ryan, Karen K. Kuo, George Andrew Knudsen
  • Patent number: 5973072
    Abstract: The present invention is directed to a polymeric vehicle, the formulated coating composition and a coating binder made from the polymeric vehicle and a method for making the polymeric vehicle where the polymeric vehicle includes a phenolic urethane reactive diluent. The phenolic urethane reactive diluent may be made from a phenolic ester alcohol having at least one aliphatic hydroxyl group.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: October 26, 1999
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: Frank N. Jones, Vijay Swarup, Ramachandran P. Subrayan, Suru Zhang
  • Patent number: 5969054
    Abstract: The present invention relates to binder compositions containingA) 40 to 95 parts by weight of OH-functional graft copolymer resins prepared by copolymerizinga) 0.1 to 10 parts by weight of polybutadienes containing at least 20% of 1,2-vinyl groups,b) 5 to 30 parts by weight of aliphatic .alpha.-olefins,c) 0.1 to 35 parts by weight of glycidyl esters of .alpha.-alkylalkane-monocarboxylic acids,d) 10 to 70 parts by weight of unsaturated, aromatic monomers,e) 5 to 60 parts by weight of hydroxyalkyl esters of acrylic and/or methacrylic acid having primary hydroxyl groups,f) 0 to 50 parts by weight of (cyclo)aliphatic esters of acrylic and/or methacrylic acid,g) 0.1 to 20 parts by weight of .alpha.,.beta.
    Type: Grant
    Filed: July 7, 1997
    Date of Patent: October 19, 1999
    Assignee: Bayer Aktiengesellschaft
    Inventors: Christian Wamprecht, Michael Sonntag, Dieter Margotte
  • Patent number: 5962600
    Abstract: The objective of the invention is to produce a thermoplastic resin capable of producing a casting with a superior granular surface appearance like marble while maintaining the impact strength and other properties of the base resin. The present invention pertains to a thermoplastic composition with a granular surface appearance like marble produced by mixing and dispersing 0.001-10 parts by weight of thermosetting resin with 100 parts by weight of thermoplastic resin.
    Type: Grant
    Filed: February 4, 1999
    Date of Patent: October 5, 1999
    Assignee: General Electric Company
    Inventors: Yoshio Ohtsuka, Katsumi Oishi
  • Patent number: 5962557
    Abstract: A colored polyester copolymer comprising the reaction product of at least one linear thermoplastic polyester precursor and at least ten parts per million by weight of a residue of at least one 1,4-bis (2,6-dialkylanilino)-9,10-anthraquinone colorant. A composition may be formed comprising the copolymer in admixture with at least one thermoplastic polymer. The copolymer may be formed by reacting at least one thermoplastic polyester precursor with a 1,4-bis (2,6-dialkylanilino)-9,10-anthraquinone colorant which has a polyester reactive group.
    Type: Grant
    Filed: August 7, 1997
    Date of Patent: October 5, 1999
    Assignee: Eastman Chemical Corporation
    Inventors: Max Allen Weaver, Brian Edison Maxwell, Gerry Foust Rhodes, James John Krutak, Sr.
  • Patent number: 5905122
    Abstract: The objective of the invention is to produce a thermoplastic resin capable of producing a casting with a superior granular surface appearance like marble while maintaining the impact strength and other properties of the base resin.The present invention pertains to a thermoplastic composition with a granular surface appearance like marble produced by mixing and dispersing 0.001-10 parts by weight of thermosetting resin with 100 parts by weight of thermoplastic resin.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: May 18, 1999
    Assignee: General Electric Company
    Inventors: Yoshio Ohtsuka, Katsumi Oishi
  • Patent number: 5888655
    Abstract: A composite coating is described. The composite comprises a substrate; one or more primer coating layers disposed on the substrate; and at least one topcoat layer disposed on the outermost primer coating layer. The outermost primer coating layer is obtained by reaction of a primer composition that includes a novolac resin having at least one carbamate group and an aminoplast resin.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: March 30, 1999
    Assignee: BASF Corporation
    Inventors: Paul J. Harris, Gregory G. Menovcik
  • Patent number: 5837799
    Abstract: A fire-retardant compound including bromine indicated by general formula (1), wherein the end group X and Y are comprised by A or B shown in formula (2), and the said fire-retardant compound is a mixture of the composition including 15 to 30% of X=Y=A, the composition including 40 to 60% of X=A and Y=B and the composition including 20 to 35% of X=Y=B, and degree of polymerization n is indicated by an integral number from 0 to 30, and a flame-retarded thermoplastic resin including said fire-retardant compound.
    Type: Grant
    Filed: August 23, 1996
    Date of Patent: November 17, 1998
    Assignee: Tohto Kasei Co., Inc.
    Inventors: Toshihiko Chen, Yoshiaki Nakamura, Tetsunori Sato, Yoshiyuki Morikawa
  • Patent number: 5817722
    Abstract: Polyesterdiols having low viscosities of less than 3500 cps, high content of non-volatile matter in excess of 96 wt %, and narrow molecular weight distribution of less than about 1.4 are prepared by esterification of one or more aliphatic dicarboxylic acids or ester derivatives thereof using at least a 1.5 molar excess of one or more aliphatic diols until an acid number of less than 20 is achieved, and stripping excess diol from the polyesterdiol reaction product. Where esterification catalyst is used, catalyst is substantially removed prior to stripping excess unreacted diol from polyesterdiol reaction product. The polyesterdiols so produced are useful as (i) curable components in thermosettable resin compositions, particularly compositions essentially free of volatile organic solvent and also containing a crosslinking agent and a reactive hardening agent: and/or (ii) useful as coatings, paints and adhesives, providing coatings with very low content of volatile organic compounds.
    Type: Grant
    Filed: April 1, 1996
    Date of Patent: October 6, 1998
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Albert Ilya Yezrielev, Konstantinos R. Rigopoulos, Richard William Ryan, Karen K. Kuo, George Andrew Knudsen
  • Patent number: 5814412
    Abstract: The thermosetting composition of the present invention includes an unsaturated polyester, an addition polymerizable monomer, a low shrink agent other than an aliphatic polyester, and an aliphatic polyester decomposed in a decomposing solution containing from about 0.1 to about 50% by weight of at least one base selected from the group consisting of alkali metal hydroxides, alkaline earth metal hydroxides, alkali metal oxides, alkaline earth metal oxides, alkali metal alkoxides and alkaline earth metal alkoxides, and at least one solvent selected from the group consisting of water, methanol, ethanol, and ethylene glycol at a temperature lower than a boiling point of the decomposing solution after being cured.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: September 29, 1998
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Takahiko Terada, Hiroshi Onishi
  • Patent number: 5739215
    Abstract: The invention relates to the use of a hydroxyl functional polyester having a glass transition temperature of at least 40.degree. C., a hydroxylnumber between 5 and 150 mg KOH/gram resin, a molecular weight (Mn) between 800 and 10.000 and a molecular weight (Mw) between 8000 and 100.000 in the preparation of coatings for the interior of can ends. The polyester has to be crosslinked with for example an amino resin or an epoxy resins.
    Type: Grant
    Filed: August 26, 1996
    Date of Patent: April 14, 1998
    Assignee: DSM N.V.
    Inventors: Wilhelmina Westerhof, Dirk J. Kolk, Wilhelmus J. P. S. M. van Riggelen
  • Patent number: 5731390
    Abstract: A thermoplastic resin composition having improved hydrolytic stability having in admixture a saturated polyester resin such as polybutylene terephthalate, an epoxy novolac, a glass fiber reinforcing filler and a catalyst such as sodium stearate.
    Type: Grant
    Filed: May 2, 1995
    Date of Patent: March 24, 1998
    Assignee: General Electric Company
    Inventor: Johannes van Helmond
  • Patent number: 5719239
    Abstract: A coated panel formed from a self-supporting cellulosic substrate and a top coating containing a thermoset resin having about 0.1-1.5 wt % free formaldehyde admixed with said resin; and (b) a thermoplastic polymer thoroughly admixed with said resin, wherein said thermoplastic polymer exhibits amine groups capable of reacting with at least some of the free formaldehyde under resin curing conditions. The coated panel can be embossed with decorative patterns such as wood grain without fracture of the coated surface or significant buildup on the press or embossing die surfaces.
    Type: Grant
    Filed: December 18, 1996
    Date of Patent: February 17, 1998
    Assignee: Georgia-Pacific Resins, Inc.
    Inventors: George E. Mirous, Bernard E. Sullivan
  • Patent number: 5707782
    Abstract: Photosensitive, dielectric insulating, crosslinkable copolyester films used as dielectric and as photoresist films for microelectronics circuits which are also suitable for use in producing MCM-L packages. In various embodiments of the invention there is provided photosensitive, dielectric insulating, crosslinkable copolyester film forming mixtures for coating onto microelectronics substrate surfaces, a photosensitive oligomer for producing the crosslinkable copolyesters and MCM-L products produced using the crosslinked copolyesters.
    Type: Grant
    Filed: March 1, 1996
    Date of Patent: January 13, 1998
    Assignee: The Board of Trustees of the University of Illinois
    Inventors: James Economy, Lizabeth A. Schneggenburger, Fang Shi
  • Patent number: 5672663
    Abstract: The objective of the invention is to produce a thermoplastic resin capable of producing a casting with a superior granular surface appearance like marble while maintaining the impact strength and other properties of the base resin.The present invention pertains to a thermoplastic composition with a granular surface appearance like marble produced by mixing and dispersing 0.001-10 parts by weight of thermosetting resin with 100 parts by weight of thermoplastic resin.
    Type: Grant
    Filed: January 30, 1996
    Date of Patent: September 30, 1997
    Assignee: General Electric Company
    Inventors: Yoshio Ohtsuka, Katsumi Oishi
  • Patent number: 5641854
    Abstract: This invention relates to a polymeric vehicle which is effective for providing a high solids formulated coating composition. The polymeric vehicle comprises a blend of at least one nonmesogenic substantially linear oligoester diol and at least one hardener which is a mesogenic polyol or crystalline polyol, which blend is effective for reaction with a crosslinker which is reactive with the nonmesogenic oligoester and hardener.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: June 24, 1997
    Assignee: Eastern Michigan University
    Inventors: Frank N. Jones, Shou-Kuan Fu, Jun Hua, Xiaoying Yuan
  • Patent number: 5610263
    Abstract: This invention provides a polymeric vehicle and formulated coating composition which are high in solids and use water to effect viscosities to permit application of such polymeric vehicles and formulated coating compositions with existing commercial application equipment. The polymeric vehicles and formulated coatings include at least one oligoester diol, a carbamate hardener, and in some instances, an additional crosslinking agent. The combination of oligoester diol with carbamate hardener provides a low viscosity coating composition with low to zero VOC content, and provides a coating binder with extremely good film properties.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: March 11, 1997
    Assignee: Eastern Michigan University
    Inventors: Frank N. Jones, Shou-Kuan Fu, Wen Jing, Suru Zhang
  • Patent number: 5536794
    Abstract: The present invention provides for amino-crosslinkable coating formulations based on a mixture of a di or polyhydroxy functional polymeric component selected from the group consisting of diesters, polyesters, alkyd polymers, acrylic polymers and polycarbonate polymers, a methylol (alkoxymethyl) amino crosslinking agent and a bis-aromatic polyhydric phenol component having the structure of formula I: ##STR1## wherein X is selected from the group consisting of carbon to carbon covalent bond, oxygen, sulfur, --S--S--, --CO--, --SO--, --SO.sub.2 -- and a divalent organic radical having a molecular weight less than about 400, and wherein Y is independently selected from the group consisting of hydrogen, halogen, C.sub.1 to C.sub.4 alkyl and C.sub.1 to C.sub.4 alkoxy.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: July 16, 1996
    Assignee: Exxon Chemical Patents Inc. (ECPI)
    Inventors: Albert I. Yezrielev, William E. Wellman
  • Patent number: 5489656
    Abstract: The objective of the invention is to produce a thermoplastic resin capable of producing a casting with a superior granular surface appearance like marble while maintaining the impact strength and other properties of the base resin.The present invention pertains to a thermoplastic composition with a granular surface appearance like marble produced by mixing and dispersing 0.001-10 parts by weight of thermosetting resin with 100 parts by weight of thermoplastic resin.
    Type: Grant
    Filed: April 8, 1994
    Date of Patent: February 6, 1996
    Assignee: General Electric Company
    Inventors: Yoshio Ohtsuka, Katsumi Oishi
  • Patent number: 5418301
    Abstract: The invention relates to a dendritic macromolecule of the polyester type comprising a central initiator molecule or initiator polymer having one or more reactive hydroxyl groups (A). The groups (A) are under formation of an initial tree structure bonded to reactive carboxyl groups (B) of a monomeric chain extender having the two reactive groups (A) and (B). The tree structure is optionally extended and further branched from the initiator molecule or initiator polymer by addition of further molecules of a monomeric chain extender by means of bonding between the reactive groups (A) and (B) thereof and is thereafter optionally further extended by reaction with a chain stopper. The invention also comprises a process for preparation of the dendritic macromolecule.
    Type: Grant
    Filed: July 13, 1994
    Date of Patent: May 23, 1995
    Assignee: Perstorp AB
    Inventors: Anders Hult, Eva Malmstrom, Mats Johansson, Kent Sorensen
  • Patent number: 5384377
    Abstract: This invention provides certain blue substituted 1,4-bis(2,6-dialkylanilino) anthraquinones in combination with selected red anthraquinone and anthrapyridone (3H-dibenz[f,ij]isoquinoline-2,7-dione) compounds which provide a toner system useful in imparting a desirable neutral to slightly blue hue to polyesters having a yellow appearance. The thermally stable colored compounds can have polyester reactive groups and are preferably incorporated into the polyester polymer structure during polymerization.
    Type: Grant
    Filed: February 16, 1994
    Date of Patent: January 24, 1995
    Assignee: Eastman Chemical Company
    Inventors: Max A. Weaver, Wayne P. Pruett, Gerry Rhodes, Samuel D. Hilbert, William W. Parham