Mixed With Ethylenically Unsaturated Reactant Or Polymer Therefrom Patents (Class 525/445)
  • Patent number: 5500212
    Abstract: New bile acid sequestrant polymer compositions and a process for preparing the polymers in particulate form, preferably in spherical form, are described. The polymer particles are prepared by crosslinking an amine-containing polymer with an amount of a polyfunctional amine-reactive compound sufficient to crosslink the polymer so that it is essentially water insoluble and has bile acid sequestering efficacy greater than that of cholestyramine, preferably greater than about three times the efficacy of cholestyramine. A preferred polymerization process revolves suspension polymerization of water-soluble amine-containing monomers, such as dialkylaminoalkyl (meth)acrylate esters and dialkylaminoalkyl (meth)acrylamides, in the presence of polyfunctional amine-reactive compounds, such as substituted dihaloalkanes. Pharmaceutical compositions containing the bile acid sequestrant polymer particles and a method for lowering blood cholesterol levels using the pharmaceutical compositions are also described.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: March 19, 1996
    Assignee: Rohm and Haas Company
    Inventors: Paul E. Bliem, Larry W. Steffier
  • Patent number: 5496889
    Abstract: Thermoplastic polyblend compositions, well suited for the production of mechanically strong and chemical-resistant shaped articles having a wide variety of chemical engineering and other applications, e.g., for the production of electrical cable for high-frequency electrical transmissions, comprise (i) a fluoropolymer, (ii) an aromatic polyester and (iii) a copolymeric compatibilizing agent therefor, the compatibilizing copolymer (iii) comprising the copolymerizate of ethylene, a glycidyl acrylate, an acrylic comonomer and, optionally, a peroxy comonomer.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: March 5, 1996
    Assignee: Elf Atochem S.A.
    Inventors: Bruno Schlund, Alain Bouilloux
  • Patent number: 5494964
    Abstract: Polyester resins suitable as binders for electrophotographic toners and for acceptor layers for the thermal diffusion printing process based on hydroxyl-containing prepolymers of olefinically unsaturated monomers obtained by(1) polymerization of a mixture of(a) from 60 to 90% by weight of styrene or of a styrene derivative,(b) from 0 to 40% by weight of one or more C.sub.1 -C.sub.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: February 27, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Georg Meichsner, Thomas Wuensch, Rainer Dyllick-Brenzinger
  • Patent number: 5491184
    Abstract: ABA block copolymers having saturated polyester midblocks "B" and unsaturated polyester condensation end blocks A of molecular weight from about 100 to 500 or 600 are described which increase the flexural strain to failure of unsaturated polyester or vinyl ester resins. These ABA block copolymers are generally compatible with unsaturated polyester resins and increase flexural strain by a different mechanism than used by incompatible rubbery polymers. These ABA block copolymers are compatible with the unsaturated polyester compositions and do not phase separate.
    Type: Grant
    Filed: October 26, 1994
    Date of Patent: February 13, 1996
    Assignee: GenCorp. Inc.
    Inventors: Douglas S. McBain, Earl G. Melby, Kevin P. LaJudice
  • Patent number: 5491201
    Abstract: Novel cyclic imino ether compositions containing one or more mesogenic moieties, when polymerized, result in products having improved properties.
    Type: Grant
    Filed: February 16, 1995
    Date of Patent: February 13, 1996
    Assignee: The Dow Chemical Company
    Inventors: Robert E. Hefner, Jr., Jimmy D. Earls
  • Patent number: 5489481
    Abstract: This development provides crystalline unsaturated polyesters having unreacted olefinically unsaturated monomer entrapped within its crystal lattice. The crystalline polyester can be used in high performance, structural SMC products or as a size or binder for glass fiber reinforcements or mats.
    Type: Grant
    Filed: December 27, 1994
    Date of Patent: February 6, 1996
    Assignee: Owens-Corning Fiberglas Technology, Inc.
    Inventors: William G. Hager, John D. Rinehart, James V. Gauchel, Edward L. Wilson
  • Patent number: 5482995
    Abstract: A grafted block copolymer having a backbone and grafts produced by monomers, the backbone consisting of sequentially distributed units wherein at least one block of the backbone is soluble in the monomer composition from which the grafts are produced and in that at-least one block of the said backbone is insoluble in the said monomer composition and the process of making such grafted block copolymer by radical grafting and radical polymerization of a monomer on the backbone are preformed.
    Type: Grant
    Filed: January 5, 1995
    Date of Patent: January 9, 1996
    Assignee: Elf Atochem S.A.
    Inventor: Nicolas Krantz
  • Patent number: 5474854
    Abstract: The invention is a polyester composition containing crosslinked polymer particles with ester bonds at the main chain. The particles are excellent in affinity to polyesters, and so the films formed from the polyester compositions do not have the particles falling off during high speed running, and do not have flaws in the film surfaces. The invention can prevent the generation of white powder and the flaws of magnetic faces caused by falling-off particles, and prevent the contamination in the production of films, even though these are problems caused when various conventional particles are added, and is especially suitable for use as products such as magnetic films.
    Type: Grant
    Filed: August 9, 1994
    Date of Patent: December 12, 1995
    Assignee: Toray Industries, Inc.
    Inventors: Nobuyuki Kagami, Masatoshi Aoyama, Masaru Suzuki, Keisuke Oshima
  • Patent number: 5472818
    Abstract: Spherical resin particles having a sharp particle size distribution and a method for producing such particles are disclosed. Resin particles according to this invention contain at least a polyester polymer and a polymer formed from a polymerizable monomer, and have an average diameter (D) of 1 to 500 .mu.m. At least 70% by weight of the particles have a diameter in the range of 0.5 D to 2.0 D. Such resin particles can be produced by swelling polyester-containing seed particles with a polymerizable monomer and then polymerizing the polymerizable monomer in swelled seed particles.
    Type: Grant
    Filed: October 6, 1994
    Date of Patent: December 5, 1995
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Yasunari Hotta, Satoshi Maeda, Yozo Yamada, Shinichiro Mori, Toshio Tanaka, Koji Tanaka, Hiroshi Ono
  • Patent number: 5464919
    Abstract: The invention relates to polyester-polyurethane hybrid resins containing halogenated aromatic polycarboxylate moieties to obtain flame retardance without significantly affect the preparation, processing and physical properties of the hybrid resins.
    Type: Grant
    Filed: May 11, 1994
    Date of Patent: November 7, 1995
    Assignee: Cook Composites and Polymers Co.
    Inventor: David P. Sinclair
  • Patent number: 5462996
    Abstract: A thermosettable resin composition is prepared by admixing a liquid mixture of thermosettable resins such as a polyepoxide and amorphous thermoplastic polymer particles such as a polyetherimide to form a homogeneous cured resin composition. The particles have an average diameter of from 0.5-50 micrometers, a surface area of at least 1.0 m.sup.2 /g, a dissolution temperature of at least 50.degree. C., and are essentially insoluble in the thermosettable resin at temperatures of up to 15.degree. C. below the dissolution temperature but are completely dissolved at a temperature of at least 20.degree. C. below the cure temperature of the resin.
    Type: Grant
    Filed: February 6, 1995
    Date of Patent: October 31, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Gene B. Portelli, William J. Schultz, John T. Boden, Daniel M. Kaufer
  • Patent number: 5460892
    Abstract: A coating material is described which exhibits high resistance to chemicals and is emulsifier-free. The coating material is useful as a lacquer layer coating on metallic substates such as automobiles. The coating material is based upon a polyester oligomer/polyacrylate wherein the polyacrylate contains hydrophilic and hydrophobic portions and the polyester contains hydroxyl functions. Capped polyisocyanates are also included in the coating material.
    Type: Grant
    Filed: January 7, 1994
    Date of Patent: October 24, 1995
    Assignee: Herberts Gessellschaft mit beschrankter Haftung
    Inventors: Klaus Bederke, Volker Duecoffre, Carmen Flosbach, Wolfgang Goldner, Walter Schubert
  • Patent number: 5456947
    Abstract: A determined amount of at least C.sub.8 dicarboxylic functional unsaturated anhydride or acid, excluding polymeric anhydrides and acids, is incorporated in an unsaturated polyester resin which comprises (1) a condensation polymer which is the reaction product of: (a) dicarboxylic acid, at least a portion of which contains ethylenic unsaturation, with (b) dihydric alcohols; and (2) an alpha-beta-ethylenically unsaturated copolymerizable monomer, to provide modified polyester resins for curable polyester resin systems having improved cohesive and adhesive strengths of the cured resin and improvement in adhesion of such systems to a wide range of substrates, especially substrates considered extremely difficult to bond to, viz., hot dipped galvanized steel, stainless steel, copper, bronze, tin, aluminum, solder, brass and glass (silicon oxide), while also reducing or effectively eliminating retardation of cure by the presence of galvanized (zinc) coated steel or the like.
    Type: Grant
    Filed: February 19, 1991
    Date of Patent: October 10, 1995
    Assignee: Fibre Glass-Evercoat Company, Inc.
    Inventors: David M. Parish, John A. Hatton, Jr.
  • Patent number: 5449719
    Abstract: A process for the preparation of an unsaturated polyester which comprises the first reaction of a phthalate and a glycol to provide a transesterified product, and subsequently a second reaction comprising reacting said product with an unsaturated dicarboxylate monomer.
    Type: Grant
    Filed: July 5, 1994
    Date of Patent: September 12, 1995
    Assignee: Xerox Corporation
    Inventors: Guerino G. Sacripante, Enno E. Agur, Michael S. Hawkins
  • Patent number: 5445877
    Abstract: An unsaturated polyester resin composition capable of affording a molded product having a small cured volume shrinkage, a superior dimensional stability, a surface quality and a high hardness, a sheet-form molding material using the composition and a process for producing a fiber-reinforced plastic molded product are provided, which composition comprises a saturated polyester obtained by reacting a saturated dibasic acid component containing 20% by mol or more of adipic acid with a saturated glycol component and having a number average molecular weight of 4,000 or higher and an acid value of 2 to 8 KOH mg/g, an unsaturated polyester and an ethylenic unsaturated monomer; which sheet-form molding material has the unsaturated resin composition together with a fiber reinforcing material placed between two films.
    Type: Grant
    Filed: October 3, 1994
    Date of Patent: August 29, 1995
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Hiroyuki Kawakami, Masaaki Yasuda, Shoichi Sasaki
  • Patent number: 5444124
    Abstract: Thermoplastic polyblend compositions, well suited for the production of mechanically strong and chemical-resistant shaped articles having a wide variety of chemical engineering and other applications, e.g., for the production of electrical cable for high-frequency electrical transmissions, comprise (i) a fluoropolymer, (ii) an aromatic polyester and (iii) a copolymeric compatibilizing agent therefor, the compatibilizing copolymer (iii) comprising the copolymerizate of ethylene, a glycidyl acrylate, an acrylic comonomer and, optionally, a peroxy comonomer.
    Type: Grant
    Filed: June 17, 1994
    Date of Patent: August 22, 1995
    Assignee: Elf Atochem S.A.
    Inventors: Bruno Schlund, Alain Bouilloux
  • Patent number: 5420205
    Abstract: A binder composition suitable for coating agents is described, that contains one or more unsaturated polyesters with an acid number of 5-60 mg KOH/g, a hydroxyl number of 50-200 mg KOH/g and a weight-average molecular weight (Mw) of 500-3000 g/mol, that are obtainable by reaction ofA) one or more alpha,beta-ethylenically unsaturated dicarboxylic acids or their anhydrides,B) one or more hydroxy-functional allyl ethers andC) one or more ethylenically unsaturated compounds with an oxirane group in the molecule,in the molar ratio of A):B):C)=(2 to 4):(2 to 4):(0.5 to 1.8). The composition is suitable in particular for filling putties and filling compounds that dry rapidly, even at low temperatures.
    Type: Grant
    Filed: June 20, 1994
    Date of Patent: May 30, 1995
    Assignee: Herberts Gesellschaft mis beschrankter Haftung
    Inventors: Heinz D. Becker, Klaus Bederke, Gerhard Bremer, Herrmann Kerber, Birgit Precht, Fritz Sadowski, Werner Stephan
  • Patent number: 5420166
    Abstract: The present invention is directed to a method for treating cross-linked (cured) filled or untilled unsaturated polyester for deriving an alcohol recycle reactant useful in the synthesis of alcohol-formed derivative products. The first step of the method is the attrition of the cured unsaturated polyester to form particulates thereof. In the next step of the process, at least a fraction of any filler or fiberglass in the cured unsaturated polyester is separated to form a cured unsaturated polyester regrind. The next step is the subjecting of the cured unsaturated polyester regrind to agitated, uncatalyzed or catalyzed glycolysis in the presence of excess glycol and, optionally, a transesterification catalyst under agitation at elevated transesterification temperature. The final step of the process is the recovery of the recycle alcohol reactant for use in the synthesis of alcohol-formed derivative products.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: May 30, 1995
    Assignee: Ashland Oil, Inc.
    Inventors: Timothy A. Tufts, Chung-Chieh Tsai, Stephen S. Hupp
  • Patent number: 5418301
    Abstract: The invention relates to a dendritic macromolecule of the polyester type comprising a central initiator molecule or initiator polymer having one or more reactive hydroxyl groups (A). The groups (A) are under formation of an initial tree structure bonded to reactive carboxyl groups (B) of a monomeric chain extender having the two reactive groups (A) and (B). The tree structure is optionally extended and further branched from the initiator molecule or initiator polymer by addition of further molecules of a monomeric chain extender by means of bonding between the reactive groups (A) and (B) thereof and is thereafter optionally further extended by reaction with a chain stopper. The invention also comprises a process for preparation of the dendritic macromolecule.
    Type: Grant
    Filed: July 13, 1994
    Date of Patent: May 23, 1995
    Assignee: Perstorp AB
    Inventors: Anders Hult, Eva Malmstrom, Mats Johansson, Kent Sorensen
  • Patent number: 5414068
    Abstract: New bile acid sequestrant polymer compositions and a process for preparing the polymers in particulate form, preferably in spherical form, are described. The polymer particles are prepared by crosslinking an amine-containing polymer with an amount of a polyfunctional amine-reactive compound sufficient to crosslink the polymer so that it is essentially water insoluble and has bile acid sequestering efficacy greater than that of cholestyramine, preferably greater than about three times the efficacy of cholestyramine. A preferred polymerization process involves suspension polymerization of water-soluble amine-containing monomers, such as dialkylaminoalkyl (meth)acrylate esters and dialkylaminoalkyl (meth)acrylamides, in the presence of polyfunctional amine-reactive compounds, such as substituted dihaloalkanes. Pharmaceutical compositions containing the bile acid sequestrant polymer particles and a method for lowering blood cholesterol levels using the pharmaceutical compositions are also discribed.
    Type: Grant
    Filed: January 24, 1994
    Date of Patent: May 9, 1995
    Assignee: Rohm and Haas Company
    Inventors: Paul E. Bliem, Larry W. Steffier
  • Patent number: 5412038
    Abstract: A process for crosslinking a polymer containing hydroxyl groups which process comprises:(a) forming a mixture of said polymer and crosslinking amount of a poly(alpha, beta-alkenylcarboxylate), and(b) maintaining the mixture at conditions under which the polymer cures by reaction of the hydroxyl groups of the polymer with the poly(alpha, beta-alkenylcarboxylate) to produce a crosslinked polymer.
    Type: Grant
    Filed: June 28, 1993
    Date of Patent: May 2, 1995
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Rex E. Murray, Robert F. Eaton, Thomas A. Upshaw, James W. Taylor, David R. Bassett, David M. Lincoln
  • Patent number: 5409764
    Abstract: A curable adhesive composition comprising an unsaturated polyester oligomer (A) of any of the following formulae (I) to (IV), obtained by reacting a compound (a) having a hydroxyl group and/or an amino group, a cyclic acid anhydride (b) and an epoxide (c) having an ethylenically unsaturated group, and an adhesive polymer (B), ##STR1## wherein: R.sub.1 is a divalent organic moiety having 1 to 40 carbon atoms,R.sub.2 is a divalent organic moiety having 1 to 10 carbon atoms,R.sub.3 is hydrogen or methyl,R.sub.4 is a monovalent organic moiety having 1 to 40 carbon atoms,R.sub.5 is a monovalent organic moiety having 1 to 40 carbon atoms,R.sub.6 is hydrogen or a monovalent organic moiety having 1 to 10 carbon atoms, andn is an integer of 2 or greater.
    Type: Grant
    Filed: September 23, 1994
    Date of Patent: April 25, 1995
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Tsukasa Otsuki, Masato Yanagi, Toshikazu Onikubo, Kouichi Iibuchi
  • Patent number: 5410000
    Abstract: Copolyester compositions are provided which comprise the reaction product of at least one straight chain, branched, or cycloaliphatic C.sub.2 -C.sub.10 alkane diol or a chemical equivalent thereof, a mixture of at least two cycloaliphatic diacids or chemical equivalents thereof, the mixture comprising predominantly a trans-enantiomer, and at least one aromatic diacid or a chemical equivalent thereof. These copolyesters have superior ductility to the homopolymers of the diol component and either of the diacid components.
    Type: Grant
    Filed: August 18, 1994
    Date of Patent: April 25, 1995
    Assignee: General Electric Company
    Inventor: Willem F. H. Borman
  • Patent number: 5409989
    Abstract: A resin composition for toners, composed essentially of a suspension polymerizate of:(a) 5 to 40% by weight per total polymer of a polyester comprising at least one aromatic diol component an at least one aliphatic diol component, and having a weight average molecular weight of 3,000 to 30,000, an acid value of 0.5 to 10 mgKOH/g, and an OH value of 10 to 60 mgKOH/g;(b) 60 to 95% by weight per total polymer of a vinyl monomer; and(c) 0.1 to 1.0% by weight per total polymer of a divinyl monomer,wherein said suspension polymerizate hasa glass transition temperature of 40.degree. to 70.degree. C.,an acid value of 0.1 to 10 mgKOH/g, anda softening temperature of 100.degree. to 160.degree. C.
    Type: Grant
    Filed: December 27, 1993
    Date of Patent: April 25, 1995
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Hirokazu Ito, Masahiro Ito, Keiji Yoshida, Syuji Takahiro, Motoshi Inagaki
  • Patent number: 5408013
    Abstract: An unsaturated polyester resin composition capable of affording a molded product having a small cured volume shrinkage, a superior dimensional stability, a surface quality and a high hardness, a sheet-form molding material using the composition and a process for producing a fiber-reinforced plastic molded product are provided, which composition comprises a saturated polyester obtained by reacting a saturated dibasic acid component containing 20% by mol or more of adipic acid with a saturated glycol component and having a number average molecular weight of 4,000 or higher and an acid value of 2 to 8 KOH mg/g, an unsaturated polyester and an ethylenic unsaturated monomer; which sheet-form molding material has the unsaturated resin composition together with a fiber reinforcing material placed between two films.
    Type: Grant
    Filed: December 1, 1993
    Date of Patent: April 18, 1995
    Assignee: Hitachi Chemical Co., Ltd.
    Inventors: Hiroyuki Kawakami, Masaaki Yasuda, Shoichi Sasaki
  • Patent number: 5408002
    Abstract: An azlactone-functional thermoplastic composition is disclosed. The composition is a blend of an azlactone-functional composition and a thermoplastic polymer. A method of making azlactone-functional homopolymers by bulk homopolymerization is disclosed, optionally also concurrent or sequential blending of a thermoplastic polymer. A method of blending azlactone-functional compositions and thermoplastic polymers is disclosed. Molded articles and adduct molded articles formed from the thermoplastic composition are disclosed.
    Type: Grant
    Filed: September 9, 1993
    Date of Patent: April 18, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Patrick L. Coleman, Steven M. Heilmann, Steven L. Kangas, Robert H. Menzies, Jerald K. Rasmussen, Richard J. Rolando, Jennifer J. Sahlin, Julie B. Stahl
  • Patent number: 5405657
    Abstract: A process for the production of flexible impregnated protective, auxiliary and insulating materials on a fibre basis for electrical purposes by the application of an impregnating agent to the material to be impregnated, followed by curing, characterised in that a solvent-free impregnating mass containing one or more olefinically unsaturated, radically polymerisable polyesters, which contain one or more radically polymerisable monomers as reactive diluents, one or more plasticizing agents and optionally one or more peroxide-free radical initiators is applied to the material to be impregnated and curing is then carried out with high energy radiation and optionally by further heating.
    Type: Grant
    Filed: November 2, 1993
    Date of Patent: April 11, 1995
    Assignee: Herberts G.m.b.H.
    Inventors: Udo Bastian, Rainer Krause, Gerhard Kiessling
  • Patent number: 5399616
    Abstract: Lubricant-containing aqueous preparations of copolymers are obtainable by polymerisation of(A) 70 to 95% by weight of a monomer mixture of(a) 20 to 90% by weight of an ethylenically unsaturated carboxylic acid, in particular of a monocarboxylic acid, or of a corresponding amide,(b) 10 to 80% by weight of a sulfonated, aliphatic or aromatic monovinyl compound, and(c) 0 to 25% by weight of N-vinylpyrrolidone or of an N-vinyl-substituted amide of a saturated aliphatic monocarboxylic acid in the presence of(B) 5 to 30% by weight of a polyol whose hydroxyl groups have been esterified with a fatty acid of 8 to 26 carbon atoms, the sum totals of (A) and (B) on the one hand and (a), (b) and (c) on the other each adding up to 100%.
    Type: Grant
    Filed: April 8, 1993
    Date of Patent: March 21, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Martin Kuhn, Philippe Ouziel, Hans-Ulrich Berendt, deceased
  • Patent number: 5397671
    Abstract: A reactive melt mixing process for preparing toner resin, comprising: melting a reactive base resin, thereby forming a polymer melt; adding to said polymer melt a free radical initiator compound and optionally a vinyl monomer compound to form a second melt; and heating and mixing under high shear said second melt with optional addition of a vinyl monomer compound to form a partially crosslinked and partially gelled toner resin.
    Type: Grant
    Filed: February 10, 1994
    Date of Patent: March 14, 1995
    Assignee: Xerox Corporation
    Inventors: Robert D. Bayley, Carol A. Fox, Thomas R. Hoffend
  • Patent number: 5395866
    Abstract: A resin composition including a modified acrylic unsaturated polyester resin composition comprising a maleic dicyclopentadienyl glycol polyester which is dissolved in a mixture of styrene monomer and methylmethacrylate monomer. The maleic dicyclopentadienyl glycol polyester is the reaction product of a glycol or mixture of glycols, an ethylenically unsaturated polycarboxylic acid moiety and dicyclopentadiene. The glycol utilized as a reactant preferably has a structure defined by: H--(OCHR--CH.sub.2).sub.n --OH wherein R is H or CH.sub.3 and n is 1-10. The concentration of unsaturated polyester is preferably about 40 weight percent to about 75 weight percent in the resin composition. The concentration of styrene monomer ranges from about 5 weight percent to about 40 weight percent, while the concentration of methylmethacrylate monomer ranges from about 5 weight percent to about 45 weight percent.
    Type: Grant
    Filed: June 18, 1993
    Date of Patent: March 7, 1995
    Assignee: Interplastic Corporation
    Inventors: Louis R. Ross, Matthew C. Kastl
  • Patent number: 5391643
    Abstract: The invention consists of a new method of curing a polyester powder coating composition. The resin is cured by the use of an organotitanium or organozirconium derivative of an alkanolamine having the formula M.sub.3 [(OR).sub.3 N].sub.4 or O[M(OR).sub.3 N].sub.2 or R.sup.1 [OM(OR).sub.3 N].sub.x where M represents Ti or Zr, R represents a divalent aliphatic radical, x is 1 to 4 and R .sup.1 is a saturated hydrocarbyl group or a group containing one or more ether linkages. The method is suitable for use with both hydroxyl-rich and carboxyl-rich polyester resins and the cured coatings have desirable physical properties.
    Type: Grant
    Filed: May 11, 1994
    Date of Patent: February 21, 1995
    Assignee: Tioxide Specialties Limited
    Inventors: John Ridland, Brian S. Jolly
  • Patent number: 5385987
    Abstract: Disclosed is a resin composition comprising 20 to 90 parts by weight of an ethylene/(meth)acrylic ester/carbon monoxide terpolymer having been graft modified with an unsaturated carboxylic acid or its anhydride and 80 to 10 parts by weight of a polyester elastomer having been graft modified with the above modifier, the total amount of said graft modified ethylene/(meth)acrylate/carbon monoxide terpolymer and polyester elastomer being 100 parts by weight. Also disclosed is an adhesive comprising the above-mentioned resin composition. The resin composition and the adhesive according to the invention are excellent in adhesion properties, heat resistant adhesive properties, hue and heat stability.
    Type: Grant
    Filed: March 8, 1994
    Date of Patent: January 31, 1995
    Assignee: Du Pont-Mitsui Polychemical, Co., Ltd.
    Inventors: Hirohide Hamazaki, Akira Fujiwara
  • Patent number: 5382624
    Abstract: Spherical resin particles having a sharp particle size distribution and a method for producing such particles are disclosed. Resin particles according to this invention contain at least a polyester polymer and a polymer formed from a polymerizable monomer, and have an average diameter (D) of 1 to 500 .mu.m. At least 70% by weight of the particles have a diameter in the range of 0.5 D to 2.0 D. Such resin particles can be produced by swelling polyester-containing seed particles with a polymerizable monomer and then polymerizing the polymerizable monomer in swelled seed particles.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: January 17, 1995
    Assignee: Toyo Boseki Kabushiki Kaisha
    Inventors: Yasunari Hotta, Satoshi Maeda, Yozo Yamada, Shinichiro Mori, Toshio Tanaka, Koji Tanaka, Hiroshi Ono
  • Patent number: 5382633
    Abstract: A modified polymer is described comprising a thermoplastic polymer composition comprising a graft copolymer between (1) a preformed thermoplastic polymer and (2) a monomer composition comprising (a) at least one polymerisable monomer containing a polymerisable group and at least one functional polymer-modifying group and (b) at least one comonomer containing at least two polymerisable groups, said copolymer being substantially free of unbound monomer. Such polymers can be produced by reacting together, in a melt and in the presence of free radicals whilst applying shear to the melt, the preformed thermoplastic polymer to be modified, the polymerisable monomer, and the comonomer, thereby to graft said monomer to said preformed polymer leaving substantially no unbound monomer, the reaction being continued for a period of time sufficient to produce a graft copolymer that is thermoplastic and can be blended with an unmodified polymer. A free radical generator can be added, if desired.
    Type: Grant
    Filed: April 8, 1991
    Date of Patent: January 17, 1995
    Assignee: 3i Research Exploitation Limited
    Inventors: Gerald Scott, Sahar Al-Malaika
  • Patent number: 5380793
    Abstract: This invention is a low cost styrene-soluble unsaturated polyester resin made using recycled or virgin polyethylene terephthalate. The PET is first glycolyzed using inexpensive glycols and then reacted with maleic anhydride and dicyclopentadiene, forming polyesters containing cyclopentadiene added by Diels-Alder reaction and/or norbornyl-terminated polyesters.
    Type: Grant
    Filed: July 13, 1993
    Date of Patent: January 10, 1995
    Assignee: Ashland Oil, Inc.
    Inventor: Timothy P. Pepper
  • Patent number: 5378537
    Abstract: The polyester monofilament of this invention has a terminal carboxyl group concentration of not more than 10 equivalent weights/10.sup.6 g and contains an unaltered carbodiimide compound in an amount in the range of from 0.005 to 1.5% by weight and a fluorine type polymer in an amount in the range of from 0.01 to 30% by weight. The polyester monofilament of this invention has an excellent resistance to hydrolysis and proof against staining. When used under high temperature and high humidity conditions susceptible to hydrolysis and the collection of stains, as when used in a papermaking drier canvas, it brings about a notable effect of prolonging the service life of the canvas and lengthening the cycle of cleaning.
    Type: Grant
    Filed: June 17, 1992
    Date of Patent: January 3, 1995
    Assignee: Toray Industries, Inc.
    Inventors: Toyohiko Masuda, Takehiko Miyoshi, Yoshinori Horii
  • Patent number: 5376500
    Abstract: A polyester resin for a dye receptive layer of a recording medium for sublimation type heat-sensitive transfer recording process, and a recording medium using thereof, which has superior resistance to light exposure and dark fade out. A polyester resin for a dye receptive layer of a recording medium for sublimation type heat-sensitive transfer recording process, wherein said polyester resin is formed by using a diol component containing a diol compound shown in Formula (1) in a range of 5-80 molar % with respect to the total diol component, and a receiving medium using thereof. ##STR1## (In Formula (1), each of R.sub.1 and R.sub.2 represents an alkylene group having a number of carbon atoms within a range of 1-12.
    Type: Grant
    Filed: December 1, 1993
    Date of Patent: December 27, 1994
    Assignee: Mitsubishi Rayon Co., Ltd.
    Inventors: Kenji Kushi, Takayuki Iseki, Tadayuki Fujiwara, Kazuhiko Jufuku, Akifumi Ueda, Hitoshi Iwasaki, Youichi Nagai
  • Patent number: 5374669
    Abstract: A sprayable, high solids, low-volatiles filler composition is provided which may be used as a coating on a variety of substrates. The sprayable filler composition comprises a first filler/glazing component formed from a mixture of a resin, a filler, a mixture of thixotropic clays, activated fumed silica, hollow glass microspheres, and a ketone solvent. The sprayable filler composition has a second catalyst component. The glazing/filler component is blended with the catalyst component, preferably either internally or externally of the spray nozzle, and the resultant sprayable filler composition is sprayed onto a substrate. The resulting cured coating provides a sandable surface which is corrosion resistant.
    Type: Grant
    Filed: May 26, 1993
    Date of Patent: December 20, 1994
    Assignee: Fibre Glass-Evercoat Company, Inc.
    Inventors: David M. Parish, Kenneth E. Lewis
  • Patent number: 5373058
    Abstract: This development provides glycidyl-acrylates that, when copolymerized with unsaturated polyesters, provide high performance, structural SMC products. The acrylates increase the reactivity of the polyesters. One result has been "zero shrinkage" parts with good heat distortion, pigmentability and excellent mechanical and physical properties.
    Type: Grant
    Filed: February 18, 1993
    Date of Patent: December 13, 1994
    Assignee: Owens-Corning Fiberglas Technology Inc.
    Inventors: William G. Hager, Timothy W. Ramey, Paul R. Krumlauf, Jay J. Beckman
  • Patent number: 5373036
    Abstract: A sprayable, high solids, low-volatiles filler composition is provided which may be used as a coating on a variety of substrates. The sprayable filler composition comprises a first filler/glazing component formed from a mixture of a resin, a filler, a mixture of thixotropic clays, activated fumed silica, hollow glass microspheres, and a ketone solvent. The sprayable filler composition has a second catalyst component. The glazing/filler component is blended with the catalyst component, preferably either internally or externally of the spray nozzle, and the resultant sprayable filler composition is sprayed onto a substrate. The resulting cured coating provides a sandable surface which is corrosion resistant.
    Type: Grant
    Filed: January 18, 1994
    Date of Patent: December 13, 1994
    Assignee: Fibre Glass-Evercoat Company, Inc.
    Inventors: David M. Parish, Kenneth E. Lewis
  • Patent number: 5371112
    Abstract: Coating compositions derived from the acidolysis of polyethylene terephthalate.
    Type: Grant
    Filed: January 23, 1992
    Date of Patent: December 6, 1994
    Assignee: The Sherwin-Williams Company
    Inventors: Daniel R. Sayre, William B. Lesney, Madhukar Rao, Richard F. Tomko
  • Patent number: 5368968
    Abstract: Modified polyester resins contain polyester blocks which have been obtained from dicarboxylic acids and dialcohols, groupings of the formulae ##STR1## where X=Z=a hydrocarbon radical having 1 to 20 C atoms and Y=a hydrocarbon radical having 2 to 25 C atoms, and if appropriate groupings originating from crosslinking agents. They can be used as base polymers for toners.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: November 29, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Rolf Wehrmann, Matthias Kocher, Harald Pielartzik, Gunter Klug
  • Patent number: 5362819
    Abstract: A block copolymer of generally an AB, ABA, or A(BA).sub.n structure, or mixtures thereof where the A block is an unsaturated polyester, the B block is a flexible polymer having a Tg of 0.degree. C. or lower, and n is 2 to 5. The various block components are generally first separately prepared as polymers with the flexible polymer generally having 1 or 2 functional end groups such as an amine group, a carboxyl group, or a hydroxyl group with the later being preferred. Alternatively, for low molecular weight unsaturated polyester blocks, the block can be made in situ. The preferred reaction route is to react a mono or dihydroxy terminated flexible polymer with a diisocyanate which subsequently can be readily reacted with the polyester. The block copolymers can be utilized as toughening agents.
    Type: Grant
    Filed: January 30, 1992
    Date of Patent: November 8, 1994
    Assignee: GenCorp Inc.
    Inventors: Douglas S. McBain, Andrew L. Ratermann, I. Glen Hargis, Earl G. Melby, Kevin P. LaJudice
  • Patent number: 5352742
    Abstract: Fluorinated styrenes of the formula I: ##STR1## where R.sub.1 is a C.sub.1 -C.sub.6 alkyl and R.sub.2 is the repeating unit ##STR2## where x is zero or any positive integer, which are useful as compatibilizing and toughening agents for various polymers such as styrene, dienes (butadiene, isoprene, etc.) acrylates, polymethacrylates, polycarbonates, polyesters, polyamides, etc. Particularly preferred are p-(1,1,1,3,3,3-hexafluoro-2-hydroxy isopropyl)-.alpha.-methylstyrene, polymers thereof, block and random copolymers thereof and polymer blends incorporating the same.
    Type: Grant
    Filed: December 7, 1993
    Date of Patent: October 4, 1994
    Assignee: The United States of America as represented by the Secretary of Commerce
    Inventors: Charles C. Han, Manjun He, Yongming Liu, Yi Feng, Ming Jiang
  • Patent number: 5350810
    Abstract: A thermosetting powder paint coating containing a polymeric binder comprising a polyester graft acrylic copolymer and a low molecular weight crystalline polyester. The coatings can be pigmented or non-pigmented. The polyester-graft-acrylic copolymer can be self-crosslinking by the inclusion of beta-hydroxy ester groups or crosslinked by an external crosslinker.
    Type: Grant
    Filed: November 12, 1993
    Date of Patent: September 27, 1994
    Assignee: Ferro Corporation
    Inventors: Henry J. DeGraaf, Susan M. Sobek
  • Patent number: 5342860
    Abstract: This invention relates to alk-1-enyl ether-polyester block prepolymers which are curable by cationically initiated radiation and which are defined by the formula ##STR1## wherein m has a value of from 1 to 25;A is C.sub.2 to C.sub.12 alkylene, C.sub.6 to C.sub.14 aryl, both groups optionally substituted with lower alkyl, halo lower alkyl, alkyleneoxy, halogen or aryl;R.sub.1 is alkylene containing from 1 to 6 carbon atoms;R.sub.2 is a saturated or unsaturated divalent radical containing from 1 to 14 carbon atoms and is selected from the group of alkylene, alkenylene and arylene, each group optionally substituted with oxygen, halogen, lower alkyl and/or hydroxy;R.sub.3 is hydrogen or C.sub.1 to C.sub.6 alkyl;R.sub.4 is C.sub.1 to C.sub.6 alkylene, C.sub.6 to C.sub.14 arylene, lower alkyl substituted phenylene or xylylene andR.sub.5 and R.sub.6 are independently hydrogen or C.sub.1 to C.sub.4 alkyl.
    Type: Grant
    Filed: August 18, 1993
    Date of Patent: August 30, 1994
    Assignee: ISP Investments Inc.
    Inventors: Jeffrey S. Plotkin, Mark M. Miller
  • Patent number: 5342724
    Abstract: Polymeric electrophotographic toner and developer compositions are produced by methods including conventional as well as limited coalescence manufacturing techniques. The compositions are prepared by heating a diacid and a diol under conditions effective to form a chain transfer polyester, wherein either the diacid or the diol contain a disulfide moiety. The polyester is reacted with one or more vinyl monomers to form a block copolymer having polyester blocks linked to polyvinyl blocks by sulfide groups previously constituting the disulfide moiety. The block copolymer is reduced to a particulate form to a size suitable for use as an electrophotographic toner by conventional methods, evaporation limited coalescence, and suspension limited coalescence.
    Type: Grant
    Filed: April 10, 1992
    Date of Patent: August 30, 1994
    Assignee: Eastman Kodak Company
    Inventor: John C. Wilson
  • Patent number: 5340873
    Abstract: A cyanoacrylate adhesive composition having improved toughness comprising a cyanoacrylate monomer and an effective toughening amount of a polyester polymer derived from a dibasic aliphatic or aromatic carboxylic acid and a glycol and having repeating units of the structure: ##STR1## where R is the organic residue of the dibasic carboxylic acid and R.sup.1 is the organic residue of the glycol, the polyester having a weight average molecular weight of greater than 10,000 and a Tg of from about -40.degree. to 30.degree. C.
    Type: Grant
    Filed: June 30, 1993
    Date of Patent: August 23, 1994
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventor: Mark Mitry
  • Patent number: 5334656
    Abstract: A polyester resin composition obtained by melt-mixing a mixture comprising resin components comprising as main resins(A) a thermoplastic polyester resin and(B) a polyorganosiloxane graft copolymer obtained by graft-polymerizing one or more kinds of vinyl monomer containing at least an epoxy group-containing vinyl monomer onto a compound rubber in which a polyorgano-siloxane rubber and a polyalkyl (meth)acrylate rubber have been inseparably united with each other. According to the present invention is provided a polyester resin composition in which the impact resistance of a thermoplastic polyester resin, a main constituent, has been improved over a wide temperature range including low temperatures below 0.degree. C., and which provides molded products having good appearance.
    Type: Grant
    Filed: January 25, 1993
    Date of Patent: August 2, 1994
    Assignee: Matsubishi Rayon Co., Ltd.
    Inventors: Naoki Yamamoto, Akira Yanagase, Akira Nakata, Atsunori Koshirai, Toshimi Yanai
  • Patent number: 5328770
    Abstract: According to the present invention there is provided a polyester composition comprising an aromatic polyester having copolymerized therein a compound containing at least one sulfonic acid group or sulfonic acid metal salt group, and crosslinked polymer particles, preferably crosslinked polymer particles coated with a water-soluble polymer. The particles are incorporated in a slurried state into the polymer. There is also provided a laminate film containing the polymer with the particles thus incorporated therein.The polyester composition is superior in uniform dispersibility of the particles, re-agglomeratin does not occur in melt-storage for a long time, and films formed using the polyester composition are superior in traveling performance and abrasion resistance.
    Type: Grant
    Filed: May 5, 1993
    Date of Patent: July 12, 1994
    Assignee: Toray Industries, Inc.
    Inventors: Minoru Yoshida, Masaru Suzuki, Masahiro Kimura, Toshihiro Sasaki