Abstract: The present invention relates to aromatic aldimines, which are based on primary aromatic polyamines, which are solid at room temperature and liquid at room temperature and which have the lowest possible viscosity, hydrolyze with little odor, and can be used as blocked amines in curable compositions, in particular in compositions having one-component and two-component isocyanate groups. Said compositions have a relatively long open time, but cure surprisingly rapidly, said curing occurring without strong odor formation and without bubbling. In addition, the compositions have outstanding mechanical properties after curing, in particular high strength with high ductility, and good resistance to heat and moisture.

Abstract: The present invention relates to a pultrusion resin system, comprising (a) di- or polyisocyanates, (b) compounds having at least two groups reactive toward isocyanates, (c) catalyst, (d) polybasic acid with functionality greater than or equal to 2 and, optionally, (e) further auxiliaries and additives, where the boiling point of the polybasic acid is at least 200° C. at standard pressure and it is soluble in the compound having at least two groups reactive toward isocyanates. The invention further relates to a process for producing a pultrudate, and also to this pultrudate.

Abstract: A method of forming ionically-charged, colorant nanoparticles involves forming in-situ ionically-charged polyurethane monomers, and forming an emulsion including the ionically-charged polyurethane monomers and a colorant nanoparticle. The method further involves polymerizing or crosslinking the ionically-charged polyurethane monomers in the emulsion, where the polymerizing or crosslinking chemically attaches the ionically-charged polyurethane monomers to a surface of the colorant nanoparticle to form an ionically-charged encapsulation layer on the surface.

Abstract: The biocompatible, biodegradable materials in the solid and/or liquid form are based on segmented linear polyurethanes and/or segmented crosslinked polyurethanes based on A) one or more biocompatible polyols susceptible to hydrolytic and/or enzymatic degradation having a molecular weight of 100 to 20,000 dalton and a number of active hydroxyl groups per molecule (functionality) of at least two or higher; B) one or more diisocyanates and/or triisocyanates; and C) one or more low molecular weight chain extenders having a molecular weight of 18 to 1000 dalton and the functionality of at least two or higher.

Abstract: Blends made of thermoplastic polyurethanes (TPUs) and of polylactides (PLAs) are produced via A) reaction of at least one thermoplastic polyurethane with at least one diisocyanate or one diisocyanate prepolymer which has at least two isocyanate groups, or a mixture thereof, in the melt, with reduction of the molar mass of the thermoplastic polyurethane and with formation of a thermoplastic polyurethane having an excess of isocyanate end groups, B) introduction of at least one polylactide into the melt of the stage A) product, and reaction of the stage A) product with the polylactide at a temperature below 190° C., C) cooling of the resultant blend, where no polyols are used in stages A) to C).

Abstract: A surface-modified polymer is described, comprising a polymeric material and a self-assembling monolayer covalently bound thereto. The monolayer comprises monoethylene glycolated-OH (MEG-OH); 2-(3-trichlorosilyl-propyloxy)-ethyl-trifluoroacetate (7-OEG or MEG-TFA); 2,2,2-trifluoroethyl-13-trichlorosilyl-tridecanoate (TTTA); OEGylated TTTA (OEG-TTTA); S-(2-(2-(2-(3-trichlorosilyl-propyloxy)-ethoxy)-ethoxy)-ethyl)-benzenethiosulfonate (OEG-TUBTS); or a combination thereof. Methods are described for forming a surface-modified polymer by surface activation, such as with plasma. By utilizing the surface-modified polymer to make medical equipment or devices for contacting biological fluids, a reduction in surface fouling and thrombus formation can result. Advantageously, polymeric equipment or components so modified may have a reduction in unwanted chemical interactions leading to fouling or clotting.

Abstract: In various embodiments a urethane/molecular rebar formulation comprising a specific composition is disclosed. The composition comprises a urethane polymer or prepolymer/discrete carbon nanotube formulation. Utility of the urethane/molecular rebar composition includes improved foams and adhesives.

Abstract: The present invention relates to a polylactic acid resin and a packaging film comprising the same, wherein the polylactic acid resin is useful as a packaging material due to excellent properties including heat resistance as well as optimized flexibility. The polylactic acid resin comprises: a hard segment including a predetermined polylactic acid repeating unit; and a soft segment including a polyurethane polyol repeating unit in which certain polyether-based polyol repeating units are linearly connected in a medium of a urethane bond. In addition, the polylactic acid resin has a glass transition temperature (Tg) of 25-55° C.

Abstract: The invention provides an adhesive sheet which can be stuck to a wafer at low temperatures of 100° C. or below, which is soft to the extent that it can be handled at room temperature, and which can be cut simultaneously with a wafer under usual cutting conditions; a dicing tape integrated type adhesive sheet formed by lamination of the adhesive sheet and a dicing tape; and a method of producing a semiconductor device using them. In order to achieve this object, the invention is characterized by specifying the breaking strength, breaking elongation, and elastic modulus of the adhesive sheet in particular numerical ranges.

Abstract: A photocurable material for sealing including (A) an oligomer having a weight average molecular weight of 10,000 to 30,000 and having (meth)acryloyl group(s), (B) a (meth)acrylate monomer, (C) a polythiol compound, and optionally (D) a carbodiimide compound enables the provision of a sealing material that has high compression recovery performance, high tensile strength and excellent flexibility, can have low hardness if required, and therefore has excellent sealing properties including air-tightness performance and water-proof performance and undergoes the formation of little surface tacks and the like.

Abstract: An aqueous crosslinkable coating composition that includes a PU polymer and a vinyl polymer bearing carbonyl groups (i.e., a carbonyl-functional vinyl polymer) and/or latex polymer. The composition also preferably includes carbonyl-reactive amine and/or hydrazine functional groups.

Abstract: Disclosed is a thermosetting resin composition including; (A) a carboxyl group-containing polyurethane prepared by using (a) a polyisocyanate compound (b) polyol compounds (c) a carboxyl group-containing dihydroxy compound as raw materials, (B) a curing agent, wherein the polyol compounds (b) are one or more kinds of polyol compound(s) selected from Group (I) and one or more kinds of polyol compound(s) selected from Group (II); Group I: polycarbonate polyol, polyether polyol, polyester polyol, and polylactone polyol, Group II: polybutadiene polyol, polysilicone having terminal hydroxyl groups, and such a polyol that has 18 to 72 carbon atoms and oxygen atoms present only in hydroxyl groups. The thermosetting resin composition can give a protection film for flexible printed circuits that has excellent long-term reliability of electric insulation, flexibility, and low warpage from curing shrinkage, and particularly low tackiness.

Abstract: A pharmaceutically-active polymeric compound of the general formula (I), Y-[Yn-LINK B-X]m-LINK B??(I) wherein (i) X is a coupled biological coupling agent of the general formula (II) Bio-LINK A-Bio??(II) wherein Bio is a biologically active agent fragment or precursor thereof linked to LINK A through a hydrolysable covalent bond; and LINK A is a coupled central flexible linear first segment of <2000 theoretical molecular weight linked to each of said Bio fragments; (ii) Y is LINK B-OLIGO; wherein (a) LINK B is a coupled second segment linking one OLIGO to another OLIGO and an OLIGO to X or precursor thereof; and (b) OLIGO is a short length of polymer segment having a molecular weight of less than 5,000 and comprising less than 100 monomeric repeating units; (iii) m is 1-40; and (iv) n is selected from 2-50. The compounds are useful as biomaterials, particularly, providing antibacterial activity in vivo.

Abstract: A primer-less coating composition for facestock comprises: a binder being a water-dispersible polymer; an ethylenically unsaturated compound which is aqueous-dispersible and miscible with or bonded to said water-dispersible polymer, wherein said ethylenically unsaturated compound is able to form a covalent bond with an ink; and a crosslinker, wherein said crosslinker is suitable for binding the coating to the facestock. The coating composition may be applied to a substrate to form a printable film. A printed film in accordance with the invention may be used in a label, for example for use on a container such as a bottle.

Abstract: A primer-less coating composition for facestock comprises: a binder being a water-dispersible polymer; an ethylenically unsaturated compound which is aqueous-dispersible and miscible with or bonded to said water-dispersible polymer, wherein said ethylenically unsaturated compound is able to form a covalent bond with an ink; and a crosslinker, wherein said crosslinker is suitable for binding the coating to the facestock. The coating composition may be applied to a substrate to form a printable film. A printed film in accordance with the invention may be used in a label, for example for use on a container such as a bottle.

Abstract: A primer-less coating composition for facestock comprises: a binder being a water-dispersible polymer; an ethylenically unsaturated compound which is aqueous-dispersible and miscible with or bonded to said water-dispersible polymer, wherein said ethylenically unsaturated compound is able to form a covalent bond with an ink; and a crosslinker, wherein said crosslinker is suitable for binding the coating to the facestock. The coating composition may be applied to a substrate to form a printable film. A printed film in accordance with the invention may be used in a label, for example for use on a container such as a bottle.

Abstract: A primer-less coating composition for facestock comprises: a binder being a water-dispersible polymer; an ethylenically unsaturated compound which is aqueous-dispersible and miscible with or bonded to said water-dispersible polymer, wherein said ethylenically unsaturated compound is able to form a covalent bond with an ink; and a crosslinker, wherein said crosslinker is suitable for binding the coating to the facestock. The coating composition may be applied to a substrate to form a printable film. A printed film in accordance with the invention may be used in a label, for example for use on a container such as a bottle.

Abstract: A primer-less coating composition for facestock comprises: a binder being a water-dispersible polymer; an ethylenically unsaturated compound which is aqueous-dispersible and miscible with or bonded to said water-dispersible polymer, wherein said ethylenically unsaturated compound is able to form a covalent bond with an ink; and a crosslinker, wherein said crosslinker is suitable for binding the coating to the facestock. The coating composition may be applied to a substrate to form a printable film. A printed film in accordance with the invention may be used in a label, for example for use on a container such as a bottle.

Abstract: The invention provides a heat-curable resin composition comprising (A) a polyurethane having two or more carboxyl groups in one molecule, in particular a polyurethane having one or more carboxyl groups at a molecular terminal and (B) a heat-curable component, a cured product thereof, a solder resist and a protective film consisting of the cured product and a printed wiring board coated with the cured product. The polyurethane (A), preferably has a number average molecular weight of 500 to 100,000 and an acid value of 5 to 150 mgKOH/g. The heat-curable component (B) is preferably an epoxy resin. The heat-curable resin composition of the invention is excellent in adhesion with a substrate, low-warpage property, flexibility, resistance to moisture and heat, soldering heat resistance and resistance to tin plating.

Abstract: A curing agent for epoxy resins that is comprised of the reaction product of an amine, an epoxy resin, and an elastomer-epoxy adduct; compositions containing the curing agent and an epoxy resin; the compositions are useful in electronic displays, circuit boards, semi conductor devices, flip chips and other applications.

Abstract: The present invention is a method for forming a golf ball, the method comprising mixing an aqueous polyurethane dispersion with an azridine to form an aqueous polyurethane dispersion/aziridine mixture. Then, adding the aqueous polyurethane dispersion/aziridine mixture to a water tank, to form a PUD/aziridine solution and dipping a polybutadiene core in the PUD/aziridine solution. The PUD/aziridine solution comprises 0.4 percent aziridine, 4 percent aqueous polyurethane dispersion, and 95.6 percent de-ionized water, which forms a dipped polybutadiene core. The dipped polybutadiene core is then dried at room temperature.

Abstract: Biocidal compositions containing organoselenium compounds are disclosed, as well as methods of producing and using same.

Abstract: Disclosed is a resin composition for laser engraving, comprising (Component A) an oligomer or polymer having a (meth)acryloyloxy group in the molecule, (Component B) an ethylenically unsaturated compound, (Component C) a compound having in the molecule at least one type selected from the group consisting of a mercapto group, a primary amino group, and a secondary amino group and at least one type of hydrolyzable silyl group and/or silanol group, and (Component D) a thermopolymerization initiator.

Abstract: The present invention relates to biocompatible, biodegradable polyurethane/urea polymeric compositions that are capable of in-vivo curing with low heat generation to form materials suitable for use in scaffolds in tissue engineering applications such as bone and cartilage repair. The polymers are desirably flowable and injectable and can support living biological components to aid in the healing process. They may be cured ex-vivo for invasive surgical repair methods, or alternatively utilized for relatively non-invasive surgical repair methods such as by arthroscope. The invention also relates to prepolymers useful in the preparation of the polymeric compositions, and to methods of treatment of damaged tissue using the polymers of the invention.

Abstract: Compounds having the formula (I) wherein L is a linking group, at least one of R1 to R10 comprises the group C?N, at least one of R1 to R5 and at least one of R6 to R10 comprise the group NH2 for use as curing agents in an epoxy resin, together with a process for their synthesis and composites comprising the curing agents.

Abstract: There is provided a polymeric film comprising one or more thermoplastic polyurethane and one or more acrylic polymer comprising, as polymerized units, one or more hydrogen-bondable monomer.

Abstract: Provided are a resin composition for the manufacture of marble chips including a halogenated epoxy resin binder and showing high heat resistance, high chemical resistance, high impact resistance, high specific gravity and high transparency, a marble chip manufacturing method using the resin composition and an artificial marble made from marble chips.

Abstract: The present invention provides a polyurethane elastomer composition for electrophotographic printing, including: a polyester polyol (A) obtained by polycondensing a polyvalent carboxylic acid (A-1) containing sebacic acid as a main component and a polyhydric alcohol (A-2) selected from (I) a linear glycol having 2 to 4 carbon atoms, (II) a linear glycol having 2 to 4 carbon atoms and a glycol having 2 to 4 carbon atoms with an alkyl side chain and (III) a linear glycol having 2 to 4 carbon atoms and 1,6-hexaneglycol; a polyisocyanate compound (B); and a mixture (C) of a short-chain diol and a short-chain triol. The polyurethane elastomer composition for electrophotographic printing has reduced temperature dependency, improved long-term durability and satisfactory mechanical strength. An electrophotographic printing member is also provided.

Abstract: The invention provides a cross-linkable mixture of thermoplastic polyurethanes and ethylenic unsaturated compounds and thermoset materials that can obtained therefrom. The invention also provides application of the cross-linkable mixtures and processes in a solvent-less coating process.

Abstract: To provide a modified polymer substrate that has both excellent releasability from an accretion adhering to a surface of the substrate and functions for intended use other than releasability, and to provide a method for producing the modified polymer substrate. A modified polymer substrate (1) includes a polymer substrate (2) containing an organic component having unsaturated carbon-to-carbon double bonds, and an organic group having a functional group (R1) arranged to provide functions to a surface of the polymer substrate, wherein the organic group is bonded to the surface of the polymer substrate via an isocyanuraic acid backbone by bringing a treatment solvent (3) that contains (a) a trichloroisocyanuric acid and (b) a compound having an unsaturated carbon-to-carbon double bond and an organic group having a functional group (R1) arranged to provide functions to the surface of the polymer substrate into contact with the surface of the polymer substrate.

Abstract: The invention is an epoxy resin based adhesive composition comprising an epoxy resin and a compound comprising an elastomeric prepolymer residue selected from the group of a polyurethane, a polyurea and a polyurea polyurethane having isocyanate end groups, the isocyanate end groups of said prepolymer residue being capped by a capping compound selected from the group consisting of a primary aliphatic, cycloaliphatic, heteroaromatic and araliphatic amine, a secondary aliphatic, cycloaliphatic, aromatic, heteroaromatic and araliphatic amine, a thiol and an alkyl amide, said capping compound being bound to the end of the polymer chain of the elastomeric prepolymer in a manner such that the end to which it is bonded no longer has a reactive group. In addition to the capping compound defined above above, a capping compound selected from the group consisting of a phenol and a polyphenol can be used for capping the isocyanate end groups of the prepolymer residue.

Abstract: A single-component, moisture-curing composition, including at least one polyisocyanate, a polyaldimine, an organomethoxysilane, an acid as well as a tin catalyst in special proportions that can be matched to one another. An exemplary composition cures by moisture as much as possible without forming bubbles. In the curing of the composition by atmospheric humidity, an anisotropic material is produced with a predominantly elastic sheath that is virtually tack-free on the surface and a predominantly plastic core. An exemplary composition can be especially well suited as a flexible sealant.

Abstract: The current invention relates to a moisture-hardening composition that contains, in addition to a silane-functional polymer with end groups of formula (I), a reaction product that can be manufactured from an amino silane with primary amino groups and an alkene that is free of silane groups. The compositions are characterized by improved expandability with concurrent high reactivity, good adhesion characteristics, and high tear strength and are suited especially for use as elastic bonding substance or sealant.

Abstract: Elastomer composites are prepared by wetting particles of a natural or synthetic rubber with a liquid one-component moisture-curable resin composition and then exposing the wetted particles to moisture to cure the resin composition. The moisture-curable resin composition comprises (a) an isocyanate-terminated polyurethane prepolymer having an isocyanate content of from 0.5 to 12% by weight and (b) from 1 to 30%, based on the combined weight of components (a) and (b), of an epoxide or lactone compound having a molecular weight of from about 70 to about 1000 and which is miscible in the prepolymer at the relative proportions thereof that are present. In addition, the composition contains no more than 0.1% by weight of compounds having a primary or secondary amino group.

Abstract: Urethane modified water-reducible alkyd resins ABCD, comprising moieties derived from polyhydric alcohols A, modified fatty acids B made h? grafting olefinically unsaturated carboxylic acids B2 onto fatty acids B1, ungrafted fatty acids C and polyfunctional isocyanates D, a process for their production, and a method of use thereof in coating binders

Abstract: Golf ball components, such as cores, intermediate layers, and covers, formed with compositions including precursors with acrylate functionality crosslinked with a curing agent.

Abstract: The invention provides adhesive and sealant compositions prepared from urethane prepolymers. The urethane prepolymers are obtained by reacting the novel urethane diols, polyester polyols and polyether polyols with an excess of diisocyanate. The urethane diols are prepared by reacting excess low molecular weight diols and diisocyanates. The invention is particularly useful in end use applications such as panel lamination.

Abstract: The disclosure relates to biocompatible components useful for forming compositions for use as medical/surgical synthetic adhesives and sealants. Biocompatible components of the present disclosure may include a polymeric polyol core, which may be treated with a nitroaryl compound to form a nitro ester. The resulting nitro ester groups may be reduced to form amino groups which, in turn, may be treated to form isocyanate groups. The resulting isocyanate may then be reacted with a second component to form adhesive and/or sealant compositions.

Abstract: A single-component, moisture-curing composition, including at least one polyisocyanate, a polyaldimine, an ?-functional organoalkoxysilane, and an acid in special proportions that can be matched to one another. An exemplary composition cures by moisture as much as possible without forming bubbles. In the curing of the composition by atmospheric humidity, an anisotropic material is produced with a predominantly elastic sheath that is virtually tack-free on the surface and a predominantly plastic core. An exemplary composition can be especially well suited as a flexible sealant.

Abstract: A composite material comprises aggregate and an elastomeric composition. The elastomeric composition comprises the reaction product of an isocyanate component and an isocyanate-reactive component. The isocyanate component comprises a polymeric isocyanate, and optionally, an isocyanate-prepolymer. The isocyanate-reactive component comprises a hydrophobic polyol and a chain extender having at least two hydroxyl groups and a molecular weight of from about 62 to about 220. The chain extender is present in the isocyanate-reactive component in an amount of from about 1 to about 20 parts by weight based on 100 parts by weight of the isocyanate-reactive component. The aggregate may be rock, crumb rubber, and/or glass. The composite material has excellent physical properties and may be formed underwater, used in various locations, and used in various applications, such as for pavement, revetments, etc.

Abstract: A crosslinked resin composition includes a resin composition including not less than 0.01 parts by mass and not more than 20 parts by mass of a vinyl monomer relative to 100 parts by mass of a thermoplastic polyurethane, the vinyl monomer having a molecular structure including at least one functional group of acid anhydride, silane, amine and epoxy. The resin composition is crosslinked by an electron beam irradiation.

Abstract: The present invention relates to a polyurethane prepared from a mixture comprising: (a) at least one polyethylene glycol; (b) at least one di-isocyanate; (c) at least one polydialkyl siloxane diol; and (d) at least one diol of formula (I) wherein n is an integer from 1 to 25; wherein the polyethylene glycol, di-isocyanate, polydialkyl siloxane diol and diol are reacted under substantially anhydrous conditions. Further aspects of the invention relate to a process for preparing a polyurethane.

Abstract: The disclosure relates to a composition having at least one radically polymerisable monomer M; at least one radical former, at least one epoxide resin A including an average of more than one epoxide group per molecule, and at least one compound of formula (I). Such compositions are suitable as adhesives, sealants or coatings. Shortly after the application thereof, they have a high initial strength and, after further hardening at room temperature, they reach a high level of final strength.

Abstract: Adhesion promoter compositions which include at least one binder having isocyanate groups. This specific binder is prepared from a mixture of a polyester resin A, at least one monomeric diphenylmethane diisocyanate, and at least one polyisocyanate B, where the proportion of monomeric diphenylmethane diisocyanate (MDI) is ?2% by weight of the overall composition. Such adhesion promoter compositions are particularly suitable for new generation automotive paint systems and are very desirable from an ecological and toxicological point of view owing to their low content of MDI.

Abstract: A multi-component curable composition which is reactive upon admixing of the components and wherein the composition comprises: A. a first component which comprises: (i) a first amine functional adduct which comprises the reaction product of a stoichiometric excess of a diamine and a compound having an epoxide group and an alpha, beta unsaturated carbonyl group; B. a second component which comprises: (i) at least one compound having an average of more than 2.0 groups per molecule which are reactive with amines.

Abstract: A multi-component curable composition which is reactive upon admixing of the components and wherein the composition comprises a first component which comprises a first amine functional adduct and a second amine functional adduct; and a second component which comprises at least one compound having an average of more than 2.0 groups per molecule which are reactive with amines.

Abstract: A pressure-sensitive adhesive composition for optical use is disclosed. The adhesive composition includes 40 to 80 wt. % of a mono-functional urethane acrylate oligomer; 5 to 55 wt. % of isobornyl (meth)acrylate as a first mono-functional diluted monomer; 5 to 55 wt. % of a second mono-functional diluted monomer having a glass transition temperature of not less than 1° C. and an unsaturated ethylene group; and 0.1 to 5 wt. % of a free radical photo-initiator, so as to attain excellent adhesiveness to inorganic materials as well as plastic materials, durability such as heat resistance and moist heat resistance, and shear strain, wherein it does not contain any alternative solvent, to thereby render a thick film type adhesive film to be fabricated.

Abstract: Disclosed are anhydrous transparent dispersions of polyurethane(meth)acrylate particles in a reactive diluent, which can be obtained by reacting a polyisocyanate with at least one polyol and a nucleophilically functionalized (meth)acrylic acid ester in the reactive diluent. The inventive dispersions are characterized in that the polyurethane(meth)acrylate particles have an average diamert of less than 40 nm. The invention further relates to a method for producing such dispersions, the use thereof as an adhesive, cut glass, or impact resistance modifier, and a molded article made from said dispersion.

Abstract: Solvent free, moisture curable reactive hot melt adhesives are prepared using an oxazolidine functional prepolymer and a polyfunctional isocyanate.

Abstract: Multi-modal vinyl ester resins having one or more of good fracture toughness, good processing viscosity, and low volatile organic compound emissions are provided. The multi-modal vinyl ester resins are the reaction product of a liquid or crystalline epoxy and an amorphous, solid epoxy, as determined at 25° C., with a vinyl carboxylic acid. The multi-modal vinyl ester resins may contain a reactive diluent, though generally, lower reactive diluent contents are required for such resins than for similar, commercially available vinyl ester resins.