Solid Polymer Derived From Alkali Metal Sulfide And Halogenated Aromatic Reactant, E.g., Polyarylene Sulfide, Etc. Patents (Class 525/537)
  • Patent number: 6818706
    Abstract: A polymer mixture of a thermoplastically processable fluoropolymer and a sulfur polymer, wherein the sulfur polymer component in the polymer mixture is 0.1 to 20% by weight.
    Type: Grant
    Filed: February 7, 2002
    Date of Patent: November 16, 2004
    Assignee: Nexans
    Inventor: Uwe Marx
  • Patent number: 6780911
    Abstract: Molding compositions including low molecular weight polyhydroxyalkanoates are provided. The use of the low molecular weight polyhydroxyalkanoates as a binder in molding compositions provides improved binder removal in the finished molded product, and offers a wide range of physical properties suitable for use in a variety of processing conditions. The composition preferably includes a powdered material, such as a metal powder, ceramic powder, or blend, admixed with a low molecular weight polyhydroxyalkanoate binder. The compositions are useful in powder processing techniques, such as injection molding, slip casting, tape casting, or extrusion. Methods of forming low molecular weight polyhydroxyalkanoates are also described.
    Type: Grant
    Filed: August 21, 2001
    Date of Patent: August 24, 2004
    Assignee: Metabolix, Inc.
    Inventors: Luhua Zhong, Robert S. Whitehouse
  • Patent number: 6780944
    Abstract: A resin composition which comprises from 50 to 99.5 parts by weight of a polyphenylene sulfide and from 0.5 to 50 parts by weight of a fluorinated resin having a solidification temperature of at least 237° C. when cooled at a cooling rate of 10° C./min after melting in a nitrogen atmosphere at 330° C., and from 0 to 250 parts by weight of a filler, etc. per 100 parts by weight of the two components.
    Type: Grant
    Filed: September 15, 2000
    Date of Patent: August 24, 2004
    Assignee: Asahi Glass Company, Limited
    Inventors: Yasuki Miura, Fukuo Kanno, Masataka Yokota
  • Patent number: 6770224
    Abstract: A process for forming a polyphenylene sulfide (PPS) component is disclosed. The PPS is molded at a temperature of about 110° C. to about 150° C. After molding, the PPS has a morphology that is at least fifty percent polycrystalline. The component is then annealed to further increase the polycrystalline portion of the PPS morphology. To effect this increase, the component is annealed at a temperature that is at least above the glass transition temperature of the molded PPS component but below its melting temperature. The component is used in optical applications and other applications in which alignment tolerances are small.
    Type: Grant
    Filed: March 22, 2001
    Date of Patent: August 3, 2004
    Assignee: TriQuint Technology Holding Co.
    Inventors: Harvey Edward Bair, John William Osenbach
  • Patent number: 6699946
    Abstract: Polyphenylene sulphide-based compositions essentially containing 60 to 99.5% by weight of polyphenylene sulphide and 0.5 to 40% by weight of a combination (C) containing a compound (C1) chosen from olefinic elastomers containing epoxy groups and a compound (C2) chosen from crosslinking agents containing functional groups which are reactive towards the epoxy groups of the compound (C1) and are chosen from amino, hydroxyl, carboxyl and carboxylic acid anhydride groups. They are obtained by melt-blending polyphenylene sulphide with each of the compounds (C1) and (C2) of the combination (C) successively and in any order.
    Type: Grant
    Filed: October 24, 1994
    Date of Patent: March 2, 2004
    Assignee: Solvay (Societe Anonyme)
    Inventors: Morand Lambla, Raphaƫl Mestanza, Dar-Jong Lin, Eric Vandevijver, Marie-Paule Collard
  • Publication number: 20040030061
    Abstract: A resin binder composition for the production of a fibre preform comprising an amount of at least one polyarylether thermoplast resin component and an amount of at least one thermoset resin component in weight ratio 80/20-10/90, in substantial absence of a catalyst which is active at the prevailing preform production temperature, wherein the polyarylether thermoplast has number average molecular weight (Mn) in the range 2,000-20,000, and comprises ether linked phenyl units and ether linked arylsulphone units and reactive end groups, method for producing a fibre preform using the thermally stable binder resin composition, a perform obtained with use of the method and composition, a method for injecting or infusing the preform with curable matrix resin, the curable injected or infused preform resin, a method for curing thereof and a cured composite obtained with the method.
    Type: Application
    Filed: May 21, 2003
    Publication date: February 12, 2004
    Inventors: Patrick Terence McGrail, Jeffrey Thomas Carter, Carmelo Lo Faro
  • Patent number: 6682812
    Abstract: Powders of oxidized polyarylene sulfide and powders comprising from 1 to 99% by weight of oxidized polyarylene sulfide and from 1 to 99% by weight of a metal, carbide, ceramic or high temperature polyimide, polyamide imide, polyester imide and aromatic polyester plastic, or a mixture thereof are very suitable for use in thermal spraying and thereby form coatings having a strong chemical and mechanical resistance and high dimensional stability when exposed to high and low temperatures. Such coatings are advantageous for use as abradable seal clearance control coating in the compressor section of gas turbine engines, motor vehicle turbochargers and superchargers, and for use as a coating of reaction vessels, kitchen ware, sealings or bearings.
    Type: Grant
    Filed: January 2, 2002
    Date of Patent: January 27, 2004
    Assignee: Ticona GmbH
    Inventors: Dl. Helmut Scheckenbach, Christophr William Smith
  • Patent number: 6677406
    Abstract: A resin composition is provided containing a polyarylene sulfide, and an aromatic polyester with a higher glass transition temperature than the polyarylene sulfide and represented by a general formula (1) shown below: wherein, Ar represents either an aromatic ring or a heterocyclic ring; R1 to R4 each represent a hydrogen atom or an alkyl group of 1 to 8 carbon atoms, which may be the same or different, provided that at least one of these groups is an alkyl group of 1 to 8 carbon atoms; Y represents a single bond, a bivalent hydrocarbon group of 1 to 12 carbon atoms which may incorporate a hetero atom, an oxygen atom, a sulfur atom, etc.; and n is an integer representing the number of repeating units), as well as a molded product produced using such a composition.
    Type: Grant
    Filed: June 10, 2002
    Date of Patent: January 13, 2004
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Ikuko Ogawa, Takashi Furusawa, Kiyotaka Kawashima, Yoshiyuki Ono, Yoshinari Santo, Katsuji Takahashi
  • Patent number: 6653437
    Abstract: A process for producing oxidative cross-linked polyarylene sulfide using a reaction apparatus including a reaction vessel provided with a resin inlet, a gas inlet, a resin outlet, and a gas outlet, and a transverse type heating member having a helical structure which is rotatable around a central shaft disposed in the reaction vessel. The process includes the step of supplying heated oxygen containing gas to the polyarylene sulfide from the downward direction of the transverse type heating member while the polyarylene sulfide is heated and agitated by the rotation of the transverse type heating member to carry out an oxidative cross-linking reaction of the polyarylene sulfide. According to the process, it becomes possible to increase the productivity and the gas components present in polyarylene sulfide can be effectively removed when the melt viscosity of polyarylene sulfide is increased to a desired degree after polymerizing the polyarylene sulfide.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: November 25, 2003
    Assignee: Dainippon Ink and Chemicals, Inc.
    Inventors: Toshio Hinokimori, Nobuhiko Yamauchi, Takayuki Mine
  • Patent number: 6646066
    Abstract: This invention relates to rubber composition which contains a thermoplastic polymer and use thereof as a tire sidewall component and/or tread supporting ring for use in a tire/rim assembly. Such tire sidewall component may be a sidewall insert and/or apex of a rubber composition which contains a thermoplastic polymer.
    Type: Grant
    Filed: March 14, 2002
    Date of Patent: November 11, 2003
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Bruce Raymond Hahn, Ivan Glen Hargis, David Andrew Benko
  • Patent number: 6627278
    Abstract: An injection blow-molded disposable tumbler is formed from a polymeric material and includes a fortified upper rim having a thickness greater than the adjacent sidewall. The tumbler may be formed of a variety of resinous materials and exhibits improved toughness and crush resistance as well as aesthetic qualities particularly desired by consumers. In a particularly preferred embodiment, thick-walled polycarbonate tumblers are prepared from hydrolysis-stabilized polycarbonate compositions while minimizing molded-in stress. In still further embodiments, nanocomposites compositions are used to form the containers of the invention.
    Type: Grant
    Filed: May 26, 2000
    Date of Patent: September 30, 2003
    Assignee: Fort James Corporation
    Inventors: Erland R. Sandstrom, Brigitte K. Weigert, Donald C. McCarthy, Michael G. Thomas, Michael A. Freek
  • Publication number: 20030166797
    Abstract: Polyphenylene sulphide-based compositions with improved impact strength and process for preparing them Polyphenylene sulphide-based compositions essentially containing 60 to 99.5% by weight of polyphenylene sulphide and 0.5 to 40% by weight of a combination (C) containing a compound (C1) chosen from olefinic elastomers containing epoxy groups and a compound (C2) chosen from crosslinking agents containing functional groups which are reactive towards the epoxy groups of the compound (C1) and are chosen from amino, hydroxyl, carboxyl and carboxylic acid anhydride groups. They are obtained by melt-blending polyphenylene sulphide with each of the compounds (C1) and (C2) of the combination (C) successively and in any order.
    Type: Application
    Filed: March 11, 2003
    Publication date: September 4, 2003
    Inventors: Morand Lambla, Raphael Mestanza, Dar-Jong Lin, Eric Vandevijver, Marie-Paule Collard
  • Patent number: 6562238
    Abstract: In a multistage counter current wash operation wherein an original solvent contained in a cake of polymeric material is displaced with a wash solvent which enters the final stage and progresses forwardly a mathematical model of the counter current wash operation is developed for providing a feedforward control system. In use, the feedforward control system maintains a desired weight fraction of the original solvent that remains in the cake exiting the final wash stage at a desired low level by manipulating the wash solvent flow rate as a function of the flow rate of the feed material. Additionally a feedback control is used in conjunction with the feedforward control.
    Type: Grant
    Filed: December 29, 1998
    Date of Patent: May 13, 2003
    Assignee: Phillips Petroleum Company
    Inventors: Jeffrey S. Fodor, Fernando C. Vidaurri, Jr.
  • Patent number: 6548608
    Abstract: A polymer composition comprises at least one thermoplastic polymer selected from the group formed by polyetherimides and polysulphones, at least one epoxy resin modified by at least one aromatic polyamine, and at least one other thermoplastic selected from the group consisting of a polyphenylene ether, a polyphenylene sulfide and an aromatic polyether. The epoxy resin is formed from at least one polyepoxide containing at least 2 epoxy groups in its molecule and the aromatic polyamine contains at least two primary amine groups in its molecule and preferably at least one alkyl substituent containing 1 to 12 carbon atoms located alpha to one of the amino groups. The molar ratio of the polyamine to the epoxy is such that, each amino group corresponds to 1.6 to 2.6 epoxy groups.
    Type: Grant
    Filed: April 20, 2001
    Date of Patent: April 15, 2003
    Assignee: Institut Francais du Petrole
    Inventors: Yves Camberlin, Jacky Grenier, Jacques Vallet, Anthony Bonnet, Jean-Pierre Pascault, Mohamed Taha
  • Patent number: 6441104
    Abstract: The present invention provides: a process for producing a high molecular weight thermoplastic resin composition, which can give the high molecular weight thermoplastic resin composition with good reproducibility and stably; and uses of the resultant resin composition. The process for producing a high molecular weight thermoplastic resin composition comprises the step of mixing a thermoplastic resin with pyromellitic dianhydride to carry out a reaction therebetween to convert the thermoplastic resin into a high molecular weight one, and this process is characterized in that the pyromellitic dianhydride has at least one of the following properties in particle form: (1) intrinsically linear or needle-like particle forms; (2) a bulk density of 0.4˜0.9 g/ml; and (3) a rest angle of 50˜70 degrees.
    Type: Grant
    Filed: June 14, 2000
    Date of Patent: August 27, 2002
    Assignee: Nippon Shokubai Co., Ltd.
    Inventor: Hiroyuki Ishida
  • Patent number: 6420491
    Abstract: A catayltic process for the hydrogenation of aromatic polymers is disclosed. The catalyst used in the process is a metal or mixture of metals of sub-group VIII of the periodic table together with a support of silicon dioxide, aluminum oxide or a mixture thereof. The catalyst, having pores is characaterized in that the pores having diameters of 100 to 1,000 Å constitute less than 15 percent of the total volume of pores. The hydrogenation, that is carried out in the presence of at least one oxygen-containing hydrocarbon is characterized in that it is essentially complete and without significant degradation of molecular weights.
    Type: Grant
    Filed: January 16, 2001
    Date of Patent: July 16, 2002
    Assignee: Bayer Aktiengesellschaft
    Inventors: Volker Wege, Johann Rechner, Eberhard Zirngiebl
  • Patent number: 6388003
    Abstract: Provided are a polyarylene sulfide having a chloroform soluble content of at most 0.5% by weight and having an inherent viscosity &eegr;inh of from 0.05 to 0.4; a polyarylene sulfide resin composition comprising a polyarylene sulfide and an inorganic filler, of which the chloroform soluble content is at most 0.5% by weight relative to the polyarylene sulfide in the composition; car parts produced through injection molding of the composition; and a method for producing a polyarylene sulfide. The polyarylene sulfide has a reduced content of low-molecular components, and has well balanced properties of fluidity, flexural strength and impact resistance.
    Type: Grant
    Filed: September 15, 1999
    Date of Patent: May 14, 2002
    Assignees: Idemitsu Kosan Co., Ltd., Idemitsu Petrochemical Co., Ltd., Petroleum Energy Center (PEC)
    Inventors: Masaya Okamoto, Toru Bando
  • Patent number: 6369172
    Abstract: The invention relates to a process for using nitric acid to oxidize polyarylene sulfide to polyarylene sulfoxide, oxidizing at least 98% of the sulfide groups of the polyarylene sulfide to sulfoxide groups. According to the invention polyarylene sulfide is treated with nitric acid at a concentration of from 60 to 80% with heating. The polyarylene sulfoxide prepared by the novel process can be used as an excellent chemical blowing agent for foaming thermoplastics.
    Type: Grant
    Filed: April 12, 2000
    Date of Patent: April 9, 2002
    Assignee: Ticona GmbH
    Inventors: Dirk Zierer, Helmut Scheckenbach, Michael Dierolf
  • Patent number: 6365274
    Abstract: Powders of oxidized polyarylene sulfide and powders comprising from 1 to 99% by weight of oxidized polyarylene sulfide and from 1 to 99% by weight of a metal, carbide, ceramic or high temperature polyimide, polyamide imide, polyester imide and aromatic polyester plastic, or a mixture thereof are very suitable for use in thermal spraying and thereby form coatings having a strong chemical and mechanical resistance and high dimensional stability when exposed to high and low temperatures. Such coatings are advantageous for use as abradable seal clearance control coating in the compressor section of gas turbine engines, motor vehicle turbochargers and superchargers, and for use as a coating of reaction vessels, kitchen ware, sealings or bearings.
    Type: Grant
    Filed: February 25, 1999
    Date of Patent: April 2, 2002
    Assignee: Ticona GmbH
    Inventors: DI. Helmut Scheckenbach, Christopher William Smith
  • Patent number: 6350852
    Abstract: The process for preparing sulfur-containing polymers, in particular polyarylene sulfides, from at least one sulfide and at least one aromatic dihalogen compound, in a solvent, is carried out in the steps: a) a mixture of aromatic dihalogen compound and sulfide is polymerized, b) aromatic dihalogen compound and sulfide are added to the polymerized mixture and c) the reaction mixture is polymerized further. The sulfur-containing polymers prepared by the process are distinguished by high purity and good mechanical properties.
    Type: Grant
    Filed: February 10, 1999
    Date of Patent: February 26, 2002
    Assignee: Ticona GmbH
    Inventors: Michael Haubs, Reinhard Wagener
  • Patent number: 6329493
    Abstract: Plumbing articles made from a thermoplastic resin comprising a poly(biphenyl ether sulfone) and a poly(aryl ether sulfone) comprising bisphenol A residues.
    Type: Grant
    Filed: October 4, 1999
    Date of Patent: December 11, 2001
    Assignee: BP Corporation North America Inc.
    Inventors: Mohammad J. El-Hibri, Barry L. Dickinson
  • Patent number: 6306935
    Abstract: Provided is a thermosetting resin composition for build-up method comprising (A) an epoxy resin having two or more glycidyl groups, (B) a curing agent for epoxy resin, (C) a poly(ether sulfone) and (D) an inorganic filler. The thermosetting resin composition does not deteriorate the processability such as that found in the conventional one and gives a cured product excellent in low-thermal expansion and low-water absorption.
    Type: Grant
    Filed: October 6, 1999
    Date of Patent: October 23, 2001
    Assignee: Sumitomo Chemical Co., Ltd.
    Inventors: Toshiaki Hayashi, Nobuyuki Nakajima, Noriaki Saito
  • Patent number: 6303708
    Abstract: A composition is provided which comprises a functionalized poly(phenylene ether) resin, poly(arylene sulfide) resin, epoxy functional alpha-olefin elastomer, elastomeric block copolymer, and a metal salt. The composition is preferably prepared by premixing a poly(phenylene ether) resin with an organic acid and a vinyl aromatic-diene block copolymer to form a premix, and then compounding the premix with an epoxy functional alpha-olefin elastomer, a poly(arylene sulfide) resin and a metal salt of an organic acid. The composition has enhanced levels of mechanical properties such as impact strength, and is suitable for making molded articles such as vertical automotive body panels.
    Type: Grant
    Filed: March 17, 1995
    Date of Patent: October 16, 2001
    Assignee: General Electric Company
    Inventors: Sterling Bruce Brown, Chorng-Fure Robin Hwang, Hiromi Ishida, James Joseph Scobbo, Jr., John Bennie Yates, III
  • Patent number: 6281326
    Abstract: A process is provided for producing a poly(arylene sulfide) polymer which employs waste material comprising poly(arylene sulfide) polymer that is normally discarded or otherwise disposed of, wherein the waste stream is contacted with a polymerization reaction mixture under polymerization conditions. The waste material can optionally contain other components such as cyclic and linear oligomers, inorganic salts, polar organic compounds and water.
    Type: Grant
    Filed: September 13, 1993
    Date of Patent: August 28, 2001
    Assignee: Phillips Petroleum Company
    Inventors: Carlton E. Ash, Jon F. Geibel
  • Patent number: 6265491
    Abstract: A curable composition including a thermoset resin a curing agent component, an amount of a thermoplast component having reactive pendant and/or end groups, an organometallic curing catalyst component. The organometallic curing catalyst component is capable of forming cross-links with reactive pendant and/or end groups of the thermoset and thermoplast resins and comprises an organometallic complex compound of the formula I=M(R)n, where M is selected from titanium, zirconium, hafnium, cerium, vanadium, niobium, R is selected from mono-, bi- and tri and/or tetra dentate organic ligands and n is four or six.
    Type: Grant
    Filed: June 14, 1999
    Date of Patent: July 24, 2001
    Assignee: Cytec Technology Corp.
    Inventors: Jeffrey T. Carter, Patrick Terence McGrail
  • Patent number: 6136929
    Abstract: Polyarylene ether for optical communications, expressed by the formula 1: ##STR1## The polyarylene ether has excellent resistance to heat and film processing properties and the light absorption loss in the wavelength range for optical communications is low. Also, by controlling the copolymerization ratio of a monomer whose hydrogen of C--H bond is substituted by F and a monomer whose hydrogen of C--H bond is substituted by Cl, the refractive index of the polymer can be adjusted to a level suitable for an optical material used for optical communications.
    Type: Grant
    Filed: September 4, 1998
    Date of Patent: October 24, 2000
    Assignee: SamSung Electronics Co., Ltd.
    Inventors: Kwan-soo Han, Woo-hyuk Jang, Eun-ji Kim, Tae-hyung Rhee
  • Patent number: 6130292
    Abstract: The present invention provides a method of preparing polyarylene sulfide fibers, particularly polyphenylene sulfide fibers, comprising melt blowing a blend of polyarylene sulfide and a polyolefin, wherein the polyolefin is present in the blend in an amount of up to about 40% by weight of the total blend. The present invention also provides fibers, webs, and other products prepared in accordance with the present inventive method.
    Type: Grant
    Filed: December 9, 1999
    Date of Patent: October 10, 2000
    Assignee: Pall Corporation
    Inventors: Colin F. Harwood, Isaak Vasserman, Thomas C. Gsell
  • Patent number: 6127466
    Abstract: To obtain an injection-molded article of a resin composition blended with a thermoplastic resin and a liquid-crystal polymer, which is excellent in mechanical strengths, etc., by forming the liquid-crystal polymer into fibers during molding. The molded article, wherein the liquid-crystal polymer (B) capable of forming an anisotropic molten phase is present in the form of fiber having an average aspect ratio of 6 or higher in a matrix of the thermoplastic resin (A) not forming an anisotropic molten phase, is produced by injection-molding a thermoplastic resin composition obtained by blending 100 parts by weight of a resin component consisting of 99 to 50 parts by weight of the thermoplastic resin (A) not forming an anisotropic molten phase and 1 to 50 parts by weight of the liquid-crystal polymer (B) capable of forming an anisotropic molten phase with 0.01 to 1.0 part by weight of at least one compound (C) selected from the group consisting of phosphoric acid, phosphorous acid and metal salts thereof.
    Type: Grant
    Filed: April 21, 1999
    Date of Patent: October 3, 2000
    Assignee: Polyplastics Co., Ltd.
    Inventors: Haruji Murakami, Takayuki Ishikawa, Kazuhito Kobayashi
  • Patent number: 6121353
    Abstract: A polymer alloy comprising ETFE having a melting point of at most 250.degree. C. and a melt flow rate of at least 20 at 297.degree. C., PPS and a compatibilizer (such as 3-aminopropyltriethoxysilane).
    Type: Grant
    Filed: July 14, 1998
    Date of Patent: September 19, 2000
    Assignee: Asahi Glass Company Ltd.
    Inventors: Masao Umino, Yasuki Miura, Masataka Yokota
  • Patent number: 6111030
    Abstract: The present invention relates to cured compositions useful as adhesives and sealants formed by dispersing an amine-terminated polyamide curative into a base to form a composite and activating the composite forming the cured composition. Bases described include epoxies, polysulfides and cyanoacrylates. Curing mechanisms include heat and pressure activation. The amine-terminated polyamide curative has a ratio of equivalents of amine to acid groups of from about 1.05:1.00 equivalents NH.sub.X :COOH to no greater than about 1.95:1.00 when x is 1 or 2.
    Type: Grant
    Filed: January 21, 1994
    Date of Patent: August 29, 2000
    Assignee: Rheox, Inc.
    Inventors: Terrence L. Hartman, Charles A. Cody
  • Patent number: 6093319
    Abstract: A process is provided for making a composition said process comprising mixing about 60% by weight to about 90% by weight of a first P(AS) having a melt flow index of about 120 grams/10 minutes or more and about 10% by weight to about 40% by weight of a second P(AS) having a melt flow index of about 110 grams/10 minutes or less. In another embodiment of this invention, said composition and manufactures produced from said composition are provided.
    Type: Grant
    Filed: December 18, 1998
    Date of Patent: July 25, 2000
    Assignee: Phillips Petroleum Company
    Inventors: David A. Soules, Jon F. Geibel, Aubrey South, Jr.
  • Patent number: 6077918
    Abstract: Phosphonium ionomers which, as random copolymers, are composed of the units (1) and (2) ##STR1## in which Ar-- is a phenylene radical or a biphenylene, naphthylene or anthrylene radical or another divalent aromatic radical and may be different units within the polymer chain;--X-- is an --S--, --SO-- and/or --SO.sub.2 -- unit,where --X-- within the polymer chain may be up to 3 different units;Z is a monovalent or polyvalent opposite ion;Ph is a phenyl radical;m is the charge of the opposite ionand the average degree of polymerization is in the range from 3 to 2000.The polymers can be used for the production of membranes, in particular for electrochemical cells.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: June 20, 2000
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Helmut Witteler
  • Patent number: 6060170
    Abstract: This invention is a novel combination of crosslinking groups, which grafted to the backbone of thermally stable polymers, can be thermally induced to crosslink the polymers, affording a thermoset polymer system. This invention is particularly suited for high Tg polymers where the desired temperature for crosslinking reaction (cure) is in the range of 200-450.degree. C. This invention utilizes a graft technique to attach various diarylhydroxymethyl and 9-(9-hydroxyfluorenyl) groups to poly(arylene ether) polymer backbone. Upon thermal treatment of the modified (grafted) polymer at temperatures of 200-450.degree. C., crosslinking reactions take place, resulting in a thermoset polymer with increased Tg and elastic modulus above the Tg.
    Type: Grant
    Filed: February 25, 1998
    Date of Patent: May 9, 2000
    Assignee: Air Products and Chemicals, Inc.
    Inventor: William Franklin Burgoyne, Jr.
  • Patent number: 6048948
    Abstract: There is a provided a method to produce a polymer composite material in which the rigid polymer (R.sub.m).sup.n is dispersed uniformly at the molecular level in the flexible polymer (M), preferably by both polymerization with no solvent in the molten and mixed state and subsequent polymerization in the solid state. According to the preferred embodiment of the present invention, the polymer composite material is produced by polymerization with no solvent in the molten and mixed state. In the case that the rigid polymer is polymerized from the monomer having a slow polymerization rate, in order to prevent roughness of the rigid polymer during polymerization, the polymerization in the molten state is stopped at the polymerization degree equal to that of an oligomer and the resulting composite is subsequently polymerized in the solid state to increase the polymerization degree of the rigid polymer.
    Type: Grant
    Filed: September 19, 1997
    Date of Patent: April 11, 2000
    Assignee: Mazda Motor Corporation
    Inventor: Takahiro Tochioka
  • Patent number: 6046285
    Abstract: Polymer blends obtainable by thermal treatment, at not less than 150.degree. C., of a mixture containing at least one high-performance polymer and from 15 to 99 parts by weight or preferably from 40 to 90 parts by weight and particularly preferably from 55 to 75 parts by weight, of a polymer containing sulfoxide groups, and crosslinked or partly crosslinked polymer blend obtainable by thermal treatment, at not less than 150.degree. C., of a mixture containing at least one of the high-performance polymers polyesters, partly fluorinated polymers, polyethersulfones, polysulfones, polyetherimides, polyamidoimides or polyacetals and at least one polymer containing sulfoxide groups, are distinguished by high thermal and chemical stability. Polymers containing sulfoxide groups are polyarylene sulfoxides, in particular polyphenylene sulfoxide. The polymer blends are used for the production of fibers, films or shaped articles.
    Type: Grant
    Filed: September 3, 1997
    Date of Patent: April 4, 2000
    Assignee: Hoechst Aktiengesellschaft
    Inventor: Helmut Scheckenbach
  • Patent number: 6042910
    Abstract: A polyarylene sulfide resin composition comprising (A) a polyarylene sulfide resin, (B) an aliphatic or saturated cyclic polycarbodiimide resin or a precursor thereof, and preferably (C) reactive silicone compound grains, and (D) a polyethylene naphthalate resin or (E) a filler, which improves excellent properties exhibited by polyarylene sulfide resins, and which is also endowed with an excellent adhesion characteristics to adhesives such as epoxy resins. In addition, a molded article obtained by molding a polyarylene sulfide resin composition endowed with such excellent properties is useful as a container for accommodating an electric component material. Such a molded article may also be used as an electronic component having conductive portions which are totally or partially accommodated in the container, wherein the conductive portions are seled by a sealant encapsulated in the container.
    Type: Grant
    Filed: January 29, 1998
    Date of Patent: March 28, 2000
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Satoru Kinouchi, Tomoyoshi Murakami, Shigemasa Suzuki
  • Patent number: 6037422
    Abstract: A polyarylene sulfide resin composition contains a polyarylene sulfide containing at least one group selected from a group consisting of an amino group and an amide group, a polyamide resin, an epoxy resin and, as needed, a filler. A further composition contains 100 parts by weight of the polyarylene sulfide, 0.05 to 5 parts of the epoxy resin, and 5 to 400 parts of the filler. Another type of the resin composition contains the polyarylene sulfide, the polyamide, a compound selected from an acid, an acid anhydride and an acid halide, each having in its molecule not less than two functional groups reactive with the amino group or the amide group, and, as needed, the filler. A further type of the resin composition contains the polyarylene sulfide, the compound and, as needed, an inorganic filler subjected to surface treatment with a silane type coupling agent. A still further type of the resin composition contains the polyarylene sulfide and the compound.
    Type: Grant
    Filed: August 30, 1993
    Date of Patent: March 14, 2000
    Assignee: Idemitsu Petrochemical Company Limited
    Inventors: Shinobu Yamao, Wataru Kosaka
  • Patent number: 6025440
    Abstract: A blend of at least one fluorine polymer, at least one oxidized polyarylene sulfide, at least one polyarylene sulfide and, if required, conventional additives results in a reduction in the expulsion of the oxidized polyarylene sulfides in gaseous form in the production of shaped articles from this blend, so that no cracks occur in the shaped article and problem-free processing by a cutting method is permitted.
    Type: Grant
    Filed: December 18, 1997
    Date of Patent: February 15, 2000
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Helmut Scheckenbach, Gregor Buche
  • Patent number: 6020442
    Abstract: Oxidation product of polyarylene sulfides comprising recurring units of the formula.brket open-st.C.sub.6 H.sub.4 --S.brket close-st. (I)in the form of a compound comprising recurring units of the formula.brket open-st..paren open-st.C.sub.6 H.sub.4 --S.paren close-st..sub.a .paren open-st.C.sub.6 H.sub.4 --SO.paren close-st..sub.b .brket close-st.(II)in which the sulfur/oxygen ratio is from 1:0.1 to 1:1, the sum of a and b always being 1 and a and b each being greater than zero or with the proviso that a is zero if b is 1.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: February 1, 2000
    Assignee: Ticona GmbH
    Inventors: Dietrich Fleischer, Heinz Strutz, Jurgen Kulpe, Andreas Schleicher
  • Patent number: 6013761
    Abstract: A process for the preparation of polyarylene sulfoxides, in which polyarylene sulfide, suspends in a concentrated acid of formula R--SO.sub.3 H, in which R is a halogen atom Ian OH group, an aliphatic radical having 1 to 6 C atoms or an aromatic radcal having 6 to 18 C atoms, or of the formula R.sup.1 --CR.sup.2 R.sup.3 --COOH, in which R.sup.1 is a halogen atom and R.sup.2 and R.sup.3, independently of one another are each a halogen atom, an aliphatic radical having 1 to 50 atoms or a halogenated aliphatic radical having 1 to 5 C atoms, is oxidized by metering in a 30 to 85% strength hydrogen peroxide solution with thorough mixing and at a temperature of from -20 to +45.degree. C. According to this process, the sulfide units of the polyarylene sulfide are converted virtually selectively and completely into sulfoxide units.
    Type: Grant
    Filed: November 19, 1998
    Date of Patent: January 11, 2000
    Assignee: Ticona GmbH
    Inventors: Dirk Zierer, Helmut Scheckenbach
  • Patent number: 6001957
    Abstract: A thermoplastic resin composition that includes a polyetherimide resin and a phosphorus-containing stabilizer that exhibits a low volatility. The thermoplastic resin composition exhibits improved melt stability and improved resistance to thermal degradation.
    Type: Grant
    Filed: December 23, 1997
    Date of Patent: December 14, 1999
    Assignee: General Electric Company
    Inventors: Robert Puyenbroek, Darryl Nazareth, Robert Hayes, Yimin Jin
  • Patent number: 5998029
    Abstract: A nonaqueous sizing for glass fibers useful for reinforcement of polymers. The sizing composition comprises one or more film formers miscible with the polymer to be reinforced and one or more coupling agents. The sizing composition of the invention provides a glass fiber which may be wirecoated with the polymer to be reinforced, eliminating the need for extrusion or pultrusion processing to make glass/polymer composite fibers, compound or pellets.
    Type: Grant
    Filed: June 30, 1997
    Date of Patent: December 7, 1999
    Assignee: Owens Corning Fiberglas Technology, Inc.
    Inventors: Leonard Joseph Adzima, David Lee Shipp, Andrew Bencich Woodside, David George Miller, Catherine Ashley Barron
  • Patent number: 5965663
    Abstract: A resin composition comprising (a) polyarylene polyether represented by the general formula of Z.sub.1 -(polyarylene polyether) chain-Z.sub.1 ' (wherein Z.sub.1 and Z.sub.1 ' denote individually a monovalent organic group containing a cross-linkable unsaturated carbon-carbon linkage), and (b) an inorganic filler.
    Type: Grant
    Filed: May 24, 1996
    Date of Patent: October 12, 1999
    Assignee: Kabushiki Kaisha Toshiba
    Inventor: Rumiko Hayase
  • Patent number: 5955566
    Abstract: Thermosetting polymers with high temperature capability for composite and adhesive applications are disclosed. Inhibitors for improving pot life, gel time and storage stability are disclosed. These polymers are ideally suited for adhesives and RTM, resin film infusion, and prepreg methods to make polymer matrix, fiber reinforced composite parts.
    Type: Grant
    Filed: November 13, 1996
    Date of Patent: September 21, 1999
    Assignee: Cytec Technology Corporation
    Inventors: Jean Lee, Jack Douglas Boyd, Albert Kuo
  • Patent number: 5945490
    Abstract: Polyarylene sulfide (PAS) is disclosed, of which extract with methylene chloride is in an amount of not more than 0.7% by weight, a melt viscosity V.sub.6 is 20 to 15,000 poises and a content of --SX groups is at least 15 micro moles/g, wherein X represents an alkali metal or a hydrogen atom. The PAS is prepared as follows: an alkali metal sulfide is reacted with a dihaloaromatic compound in an organic amide solvent, while a part of a gaseous phase in a reactor is condensed by cooling a gaseous phase part of the reactor to return the condensed liquid to a liquid phase; and the polyarylene sulfide thus prepared is washed with an organic solvent and then with water. The present invention also provides a composition comprising 100 parts by weight of (A) the aforesaid PAS and 0.01 to 5.0 parts by weight of (B) at least a silane compound selected from the group consisting of methacryloxysilane compounds, ureidosilane compounds and epoxy silane compounds.
    Type: Grant
    Filed: November 10, 1997
    Date of Patent: August 31, 1999
    Assignee: Tonen Chemical Corporation
    Inventors: Takashi Tsuda, Osamu Komiyama
  • Patent number: 5886134
    Abstract: The invention relates to a Bismaleimide-Triazine resin (BT resin ) and production method thereof and in particular, a series of novel BT resin prepared by reacting a novel bismaleimide with various aromatic cyanate esters. By combining said novel bismaleimide monomer with various proportions of cyanate esters having different structures, BT resins having various processing temperature conditions can be formulated, which, after polymerizing and crosslinking, can provide materials with various thermal stability, dielectric constants, and mechanical properties for various applications.
    Type: Grant
    Filed: October 6, 1997
    Date of Patent: March 23, 1999
    Assignee: National Science Council of Republic of China
    Inventors: Chun-Shan Wang, Haan-Jang Hwang
  • Patent number: 5883150
    Abstract: A polysulfone composition is formed from a solution of a polysulfone and a free radical polymerizable monomer exposed to ultraviolet light to form a blend of the polysulfone and copolymers of activated polysulfone and polymerized monomer having polymer segments covalently bonded to each other. The blend is separated from solvent of the solution to form a solid comprising the blend throughout its bulk matrix.
    Type: Grant
    Filed: August 9, 1996
    Date of Patent: March 16, 1999
    Assignee: Millipore Corporation
    Inventor: John Charkoudian
  • Patent number: 5856403
    Abstract: A process for efficiently manufacturing polyarylene sulfide copolymer in which polymers are well dispersed and which copolymer exhibiting superior mechanical properties. The process comprises reacting a polyarylene sulfide resin (A) and an amination agent (B) in a non-protonic organic solvent (C), and copolymerizing the resulting amino polyarylene sulfide resin (A') and a reactive elastomer (D) in a non-protonic organic solvent (C'), thereby obtaining a polyarylene sulfide resin (A") with the elastomer dispersed in the resin matrix.
    Type: Grant
    Filed: May 30, 1996
    Date of Patent: January 5, 1999
    Assignee: Idemitsu Petrochemical Co., Ltd.
    Inventors: Minoru Senga, Koji Namiki
  • Patent number: 5852139
    Abstract: Polymer mixtures which comprise at least one thermoplastic and at least one oxidized polyarylene sulfide show particularly good tribological behaviour. The thermoplastics of the mixture are, for example, polyacetal, polyester, liquid-crystalline polymer, polyaryl ether ketone, polysulfone, polyether sulfone, polyphenylene sulfide or polyether imide. The oxidized polyarylene sulfide is preferably polyphenylene sulfone. The polymer mixtures are used for producing gear wheels, gear racks, bearings, chains, pulleys, rollers, wheels or gasket materials.
    Type: Grant
    Filed: April 8, 1997
    Date of Patent: December 22, 1998
    Assignee: Ticona GmbH
    Inventor: Di Helmut Scheckenbach
  • Patent number: 5852134
    Abstract: A process for the preparation of polymeric alloys from polyester resins and polymers containing groups capable of giving addition reaction with functional compounds containing at least two reactive groups comprising the melt state mixture stage of polyester resin, reactive polymer and functional compound of mixture pelletizing and following polyaddition reaction in the solid state at temperatures between 150.degree. and 220.degree. C. to obtain an increase of the polymer intrinsic viscosity of 0.1 dl/g in comparison with the starting polyester resin.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: December 22, 1998
    Assignee: Sinco Engineering S.p.A.
    Inventor: Hussain Ali Kashif Al Ghatta