Utilizing An Apparatus With Two Or More Physically Distinct Zones Patents (Class 525/53)
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Publication number: 20140155547Abstract: Unoriented film comprising at least 70 wt.-% of an heterophasic propylene copolymer, said heterophasic propylene copolymer comprises a matrix being a random propylene copolymer and an elastomeric propylene copolymer dispersed in said matrix, wherein the heterophasic propylene copolymer has (a) a melt flow rate MFR2 (230° C.) in the range of 3.0 to 10.0 g/10 min, (b) a melting temperature in the range of 130 to 150° C., (c) a xylene cold soluble content in the range of 25 to 50 wt.-%, (d) comonomer content in the range of 10.0 to 15.0 wt.-%, wherein further the xylene cold soluble content of the heterophasic propylene copolymer has (e) a comonomer content in the range of 20 to 30 wt.-% and (f) an intrinsic viscosity in the range of 0.8 to below 2.0 dl/g.Type: ApplicationFiled: July 10, 2012Publication date: June 5, 2014Applicant: Borealis AGInventors: Markus Gahleitner, Martina Sandholzer, Klaus Bernreitner, Pauli Leskinen
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Patent number: 8703879Abstract: A continuous process for the multistage drying and postcondensation of polyamide pellets in the solid phase comprises 1) carrying out the predrying process in a continuous drying apparatus which is operated in countercurrent mode or in crossflow mode with inert gas or steam, or with a mixture of inert gas and steam, using a pellet temperature in the range from 70 to 200° C., and 2) Carrying out the subsequent continuous postcondensation process in a separate vertical duct with moving bed at a pellet temperature in the range from 120 to 210° C., where the duct is operated in countercurrent mode with inert gas or steam, or with a mixture of inert gas and steam, the inert gas is introduced at least two sites along the duct, and from 15 to 90% of the inert gas is introduced at the base of the vertical duct and from 10 to 85% of the inert gas is introduced in the upper half below the surface of the pellets.Type: GrantFiled: June 19, 2009Date of Patent: April 22, 2014Assignee: BASF SEInventors: Wolfgang Loth, Faissal-Ali El-Toufaili, Achim Stammer, Gad Kory, Achim Gerstlauer, Jens Becker
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Publication number: 20140107274Abstract: The present disclosure relates to a class of impact copolymer polypropylene (ICP) compositions exhibiting the advantageous combination of excellent tiger (flow) marking performance in large/long molded parts, very low gels count and exceptional mold flowability (high MFR) despite the high viscosity ratio (e.g., >4) between rubber and propylene based matrix phases. Furthermore, it has been surprisingly found that the inventive compositions are associated with a low gels count even when using a quite coarse mesh wire screen, e.g., 60 mesh wire screen, independent of screw type e.g., twin or single screw. Finally, the inventive compositions exhibit significantly reduced the levels of volatiles, and excellent stiffness-impact balance used as standalone materials or in filled compounds. The significantly reduced number of large gels leads to excellent surface appearance and paintability of the molded parts. The composition of the present disclosure is made with a bulk/gas reactor process (i.e.Type: ApplicationFiled: December 23, 2013Publication date: April 17, 2014Applicant: Braskem America, Inc.Inventors: Jeffrey S. Salek, Rita A. Majewski
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Patent number: 8697808Abstract: A high-temperature solution process for making an ethylene polymer blend having a controlled degree of long-chain branching is disclosed. Ethylene is polymerized in the presence of a first Ziegler-Natta catalyst comprising titanium, magnesium, and aluminum in the absence of hydrogen to produce a first ethylene polymer component having substantial long-chain branching. A second ethylene polymer component having little or no long-chain branching is also prepared. Both polymerizations are performed at a temperature from 140° C. to 250° C. The first and second ethylene polymer components are combined to give a polymer blend. The degree of long-chain branching in the blend is controlled by adjusting the relative amounts of the first and second ethylene polymer components. The invention enables the preparation of valuable products having a pre-determined degree of long-chain branching using readily available Zeigler-Natta catalysts, commercially practiced techniques, and conventional equipment.Type: GrantFiled: November 8, 2010Date of Patent: April 15, 2014Assignee: Equistar Chemicals, LPInventors: Michael W. Lynch, Kenneth J. Klug
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Patent number: 8691912Abstract: A process for producing an aliphatic polyester, comprising: subjecting at least two serial stages of bulk-phase ring-opening polymerization and a solid-phase polymerization step, wherein a cyclic ester held in a dry air atmosphere is supplied to a first reactor to perform a first stage polymerization, thereby obtaining a partially polymerized molten product, and the resultant partially polymerized molten product is supplied to a second reactor held under a dry inert gas atmosphere to perform a second stage polymerization. As a result, the production efficiency can be improved, while maintaining excellent properties of the aliphatic polyester product.Type: GrantFiled: February 17, 2010Date of Patent: April 8, 2014Assignee: Kureha CorporationInventors: Yoshinori Suzuki, Fumio Maeda, Takahiro Watanabe, Hiroyuki Sato
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Patent number: 8680201Abstract: The present invention relates to a compounding method for producing impact-modified thermoplastic compositions with a low content of volatile organic compounds (hereinafter VOCs), wherein relatively inexpensive polymer raw materials with a comparatively elevated initial VOC content may be used, resulting in lowered production costs for producing such VOC-reduced polymer compositions.Type: GrantFiled: February 18, 2010Date of Patent: March 25, 2014Assignee: Bayer Materialscience AGInventors: Andreas Seidel, Hans-Jürgen Thiem
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Publication number: 20140080974Abstract: Disclosed herein is an in-reactor produced multi-component copolymer comprises a semi-crystalline component having a crystallinity of 20% or more, and an amorphous component having a crystallinity of 5% or less. The copolymer comprises at least 80 wt % of units derived from propylene and from about 1 to about 20 wt % of units derived from at least one C6 to C12 alpha-olefin. The copolymer has a viscosity at 190° C. of at least 530 mPa sec and a heat of fusion between about 10 and about 70 J/g. An adhesive containing the copolymer exhibits a good balance of adhesive properties and mechanical strength.Type: ApplicationFiled: November 21, 2013Publication date: March 20, 2014Inventors: Peijun Jiang, Patrick Brant, David Aaron Henning, David Raymond Johnsrud, Charles Lewis Sims
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Publication number: 20140039124Abstract: Polypropylene composition comprising propylene homopolymer (H-PP) and a propylene copolymer (C-PP), said copolmyer comprises (a) a propylene copolymer fraction (A) having a comonomer content of equal or above 1.0 wt.-%, the comomers are C5 to C12 ?-olefins, and (b) a propylene copolymer action (B) having a comonomer content of 4.0 to 20.0 wt-%, the comomers are C5 to C12 ?-olefins, wherein further (i) the comonomer content in propylene copolymer fraction (A) is lower compared to the comonomer content in the propylene copolymer fraction (B), (ii) the propylene copolymer (C-PP) has a comonomer content of at least 2.0 wt.-%, the comomers are C5 to C12 ?-olefins, (iii) the weight ratio [(A)/(B)] of the propylene copolymer fraction (A) to the propylene copolymer fraction (B) is in the range of 20/80 to 80/20, and (iv) the weight ratio [(C-PP)/(H-PP)] of the propylene copolymer (C-PP) to the propylene homopolymer (H-PP) is in the range of 95/5 to 75/25.Type: ApplicationFiled: January 2, 2012Publication date: February 6, 2014Applicant: Borealis AGInventors: Kristin Reichelt, Wolfgang Stockreiter, Pablo Ivan Aguayo Arellano
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Publication number: 20140031492Abstract: Polypropylene composition comprising a propylene homopolymer having a melt flow rate MFR2 (230° C.) in the range of 1.0 to 20.0 g/10 min and a propylene copolymer, said copolmyer comprisesa polypropylene fraction having a comonomer content of not more than 1.0 wt.-%, the comomers are C5 to C12 ?-olefins, anda propylene copolymer fraction having a comonomer content 4.0 to 20.0 wt.-%, the comomers are C5 to C12 ?-olefins, wherein furtherthe propylene copolymer has a comonomer content of at least 2.5 wt.-%, the comomers are C5 to C12 ?-olefins, the melt flow rate MFR2 (230° C.) of the propylene homopolymer is higher than the melt flow rate MFR2 (230° C.) of the polypropylene fraction, the weight ratio of the polypropylene fraction to the propylene copolymer fraction is in the range of 30/70 to 70/30, andthe weight ratio of the propylene copolymer to the propylene homopolymer is in the range of 95/5 to 75/25.Type: ApplicationFiled: January 2, 2012Publication date: January 30, 2014Applicant: Borealis AGInventors: Kristin Reichelt, Wolfgang Stockreiter, Pablo Ivan Aguayo Arellano
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Publication number: 20140024775Abstract: An ethylenic polymer comprising amyl groups from about 0.1 to about 2.0 units per 1000 carbon atoms as determined by Nuclear Magnetic Resonance and both a peak melting temperature, Tm, in ° C., and a heat of fusion, Hf, in J/g, as determined by DSC Crystallinity, where the numerical values of Tm and Hf correspond to the relationship Tm?(0.2143*Hf)+79.643. An ethylenic polymer comprising at least one preparative TREF fraction that elutes at 95° C. or greater using a Preparative Temperature Rising Elution Fractionation method, where at least one preparative TREF fraction that elutes at 95° C. or greater has a gpcBR value greater than 0.05 and less than 5 as determined by gpcBR Branching Index by 3D-GPC, and where at least 5% of the ethylenic polymer elutes at a temperature of 95° C. or greater based upon the total weight of the ethylenic polymer.Type: ApplicationFiled: September 23, 2013Publication date: January 23, 2014Applicant: Dow Global Technologies LLCInventors: Mehmet Demirors, Teresa P. Karjala, Christopher R. Eddy, Lonnie G. Hazlitt, Pak-Meng Cham, Sarat Munjal, Wallace W. Yau
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Patent number: 8633279Abstract: A method for continuously producing a thermoplastic resin from a conjugated diene includes: primarily polymerizing a conjugated diene monomer with an aromatic vinyl monomer in a first solvent in a first reactor, and feeding a hydroxyl group-containing polymerization inhibitor and a polar hydrocarbon to the first reactor to prepare a rubber solution; and adding an aromatic vinyl monomer and a monomer copolymerizable with the aromatic vinyl monomer to the rubber solution, and subjecting the mixture to secondary polymerization in a second solvent of the same kind as the first solvent in a second reactor. The method can provide a thermoplastic resin that can have excellent color and low gloss characteristics.Type: GrantFiled: December 12, 2012Date of Patent: January 21, 2014Assignee: Cheil Industries Inc.Inventors: Jae Keun Hong, Sung Hun Kim, Dong Keun Yoo, Young Kyu Chang
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Publication number: 20130345361Abstract: A process for preparing a polyolefin product can include providing a first high molecular weight (HMW) polyolefin resin having an HLMI of between 0.01 and 5 g/10 min, and separately providing a second low molecular weight (LMW) polyolefin resin having an MI2 of between 1 and 150 g/10 min. A device can be used to continuously physically melt and blend the first HMW polyolefin resin and the second LMW polyolefin resin to produce the polyolefin product. The device can include at least two feeding zones spatially separated and operably connected to each other. At least a art of the first HMW polyolefin resin is introduced in a first feeding zone, and at least a part of the second LMW polyolefin is introduced in a second feeding zone different from the first zone.Type: ApplicationFiled: March 2, 2012Publication date: December 26, 2013Applicant: TOTAL RESEARCH & TECHNOLOGY FELUYInventors: Daan Dewachter, Eric Damme
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Patent number: 8614277Abstract: Isotactic polypropylene ethylene-propylene copolymer blends and in-line processes for producing. The blends may have between 1 and 50 wt % of isotactic polypropylene with a melt flow rate of between 0.5 and 20,000 g/10 min and a melting peak temperature of 145° C. or higher, and wherein the difference between the DSC peak melting and the peak crystallization temperatures is less than or equal to 0.5333 times the melting peak temperature minus 41.333° C., and between 50 and 99 wt % of ethylene-propylene copolymer including between 10 wt % and 20 wt % randomly distributed ethylene with a melt flow rate of between 0.5 and 20,000 g/10 min, wherein the copolymer is polymerized by a bulk homogeneous polymerization process, and wherein the total regio defects in the continuous propylene segments of the copolymer is between 40 and 150% greater than a copolymer of equivalent melt flow rate and wt % ethylene polymerized by a solution polymerization process.Type: GrantFiled: February 13, 2012Date of Patent: December 24, 2013Assignee: ExxonMobil Research and Engineering CompanyInventors: Gabor Kiss, Patrick Brant, Robert Patrick Reynolds, Jr., Aspy K. Mehta, Manika Varma-Nair, John W. Chu, Steven P. Rucker
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Patent number: 8580890Abstract: The present invention concerns a heterophasic propylene copolymer of high melt flow for injection molding, which comprise a propylene polymer matrix and a rubber. The heterophasic propylene copolymers of the present invention are characterized by a high viscosity of the rubber phase and a well-defined ratio of the intrinsic viscosities of the rubber phase and the propylene polymer matrix, thus resulting in improved mechanical properties. The present invention further relates to a process for the production of such heterophasic propylene copolymers, their use and articles produced with them.Type: GrantFiled: July 2, 2009Date of Patent: November 12, 2013Assignee: Total Petrochemicals Research FeluyInventors: Rita De Luca, Philippe Hoslet
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Patent number: 8557917Abstract: The present invention relates to a process for the preparation of a propylene homo- or copolymer, comprising the following steps: (i) feeding propylene and hydrogen, and optionally one or more comonomers, to a reactor R1, wherein the hydrogen is fed to the reactor R1 in a periodically varying amount, (ii) preparing a first fraction of the propylene homo- or copolymer in the reactor R1 in the presence of a catalyst, (iii) transferring the first fraction to a reactor R2, and (iv) preparing a second fraction of the propylene homo- or copolymer in the reactor R2, wherein the melt flow rate MFR (2.16 kg, 230° C.) of the propylene homo- or copolymer is higher than the melt flow rate MFR (2.16 kg, 230° C.) of the first fraction.Type: GrantFiled: October 6, 2009Date of Patent: October 15, 2013Assignee: Borealis AGInventors: Pauli Leskinen, Michiel Bergstra
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Patent number: 8557923Abstract: Disclosed herein is a thermoplastic resin composition having excellent scratch resistance and a method for preparing the same. The thermoplastic resin composition comprises (A) about 80 to about 95% by weight of a terpolymer of (meth)acrylic acid alkyl ester-aromatic vinyl-cyanide vinyl compound; and (B) about 5 to about 20% by weight of a butadiene rubber.Type: GrantFiled: December 29, 2008Date of Patent: October 15, 2013Assignee: Cheil Industries Inc.Inventors: Young Sub Jin, Hwan Seok Park, Jae Keun Hong, Sung Kwan Kim, Ho Ryong Sun, Byeong Do Lee, Kyung Jong Lee
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Patent number: 8552112Abstract: The present invention provides a weather resistant thermoplastic resin with low gloss and a method of preparing the same. The thermoplastic resin of the present invention comprises a (meth)acrylic acid alkyl ester-based polymer (A) and a (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B), and an aromatic vinyl-cyanide vinyl based copolymer (C), wherein the (meth)acrylic acid alkyl ester-based polymer (A) and the (meth)acrylic acid alkyl ester-based oligomeric prepolymer (B) form a network-shaped disperse phase and the aromatic vinyl-cyanide vinyl based copolymer (C) forms a continuous phase.Type: GrantFiled: December 29, 2010Date of Patent: October 8, 2013Assignee: Cheil Industries Inc.Inventors: So Young Kwon, Young Sub Jin, Sung Kwan Kim, Byeong Do Lee
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Publication number: 20130253124Abstract: Heterophasic polypropylene copolymers having an MFR (2.16 kg, 230° C.) of 15 to 200 g/10 min, determined according to ISO 1133 comprising a propylene homo- or copolymer matrix with an MFR (2.16 kg, 230° C.) of 80 to 500 g/10 min, determined according to ISO 1133 (A) and an ethylene or C4-C10-alpha-olefin propylene rubber phase (B) dispersed within the matrix, wherein the heterophasic polypropylene resin has a fraction soluble in p-xylene at 25° C. (XCS), having an intrinsic viscosity of 2.85 to 4.00 dl/g, determined according to DIN EN ISO 1628-1 and -3 and being composed of propylene monomer units in an amount of 70 wt % to 90 wt %, with optimum balance of impact resistance and low amount of hexane extractables; a process for their preparation and their use.Type: ApplicationFiled: June 15, 2011Publication date: September 26, 2013Applicant: BOREALIS AGInventors: Klaus Bernreiter, Petar Doshev, Gregory Potter, Martina Sandholzer
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Patent number: 8507609Abstract: The present invention provides a thermoplastic resin composition which comprises (A) a (meth)acrylic acid alkyl ester-based polymer forming a network-shaped disperse phase; and (B) an aromatic vinyl-cyanide vinyl based copolymer forming a continuous phase. The thermoplastic resin composition of the present invention can have an excellent low gloss characteristics while maintaining basic physical properties of a weather resistance, impact strength, thermal resistance, and delamination characteristics.Type: GrantFiled: December 28, 2010Date of Patent: August 13, 2013Assignee: Cheil Industries Inc.Inventors: Young Sub Jin, So Young Kwon, Sung Kwan Kim, Hwan Seok Park, Jae Keun Hong, Byeong Do Lee, Chul In Lim
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Patent number: 8507619Abstract: The invention relates to a process for the polymerization of vinyl-containing monomers such as, for example, monomeric vinyl halides, in a reaction mixture, in which process less waste is generated.Type: GrantFiled: January 26, 2006Date of Patent: August 13, 2013Assignee: Vinnolit Technologie GmbH & Co. KGInventors: Ulrich Woike, Heinz Klippert, Jürgen Kirschner, Peter Kammerhofer
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Publication number: 20130178586Abstract: Heterophasic propylene copolymer comprising a matrix (M) being a polypropylene, said polypropylene comprises at least three polypropylene fractions, the three polypropylene fractions differ from each other by the melt flow rate MFR2 (230° C.) and at least one of the three polypropylene fractions has a melt flow rate MFR2 (230° C.) in the range of 1.0 to 15.0 g/10 min, and an elastomeric propylene copolymer dispersed in said matrix, wherein the heterophasic propylene copolymer has a melt flow rate MFR2 (230° C.) of equal or more than 20.0 g/10 min, and the amorphous phase of the xylene cold soluble fraction of the heterophasic propylene copolymer has an intrinsic viscosity of equal or higher than 2.0 dl/g.Type: ApplicationFiled: August 1, 2011Publication date: July 11, 2013Applicant: Borealis AGInventors: Cornelia Kock, Petar Doshev, Elisabeth Potter, Guenter Gsellmann, Pauli Leskinen
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Publication number: 20130144009Abstract: A process for making a block copolymer compatibilizer, comprising reacting an acrylic monomer that has functional groups with one or more vinyl monomers in the presence of a free radical initiator and a stable free radical to form a reaction product that includes residual unreacted acrylic monomer, and reacting one or more vinyl monomers with the reaction product to form a second block that incorporates the residual unreacted acrylic monomer. A blend composition comprising a first thermoplastic polymer, which has functional groups, a reactive block copolymer that has functional groups in two or more blocks, and a second thermoplastic polymer that is compatible with one block of the block copolymer, where the functional groups in the first thermoplastic react with the functional groups in the block copolymer.Type: ApplicationFiled: January 13, 2013Publication date: June 6, 2013Applicant: CID Centro de Investigacion y Desarrollo Tecnológico S.A. de C.V.Inventor: CID Centro de Investigacion y Desarrollo Tecnologico S.A. de C.V.
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Patent number: 8450428Abstract: The present invention relates to a process for producing water-absorbent polymer particles by polymerizing droplets of a monomer solution in a surrounding heated gas phase and flowing the gas cocurrent through the polymerization chamber, which comprises thermal postcrosslinking in the presence of steam.Type: GrantFiled: March 23, 2011Date of Patent: May 28, 2013Assignee: BASF SEInventors: Thomas Daniel, Marco Krüger, Karin Flore, Stefan Blei, Uwe Stueven, Norbert Herfert, Michael A. Mitchell
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Publication number: 20130075409Abstract: Fuel containers made from polyethylene compositions exhibiting improved creep resistance are provided. The polyethylene compositions include two components, a first component ethylene-based interpolymer, and a second component ethylene-based polymer. A process for producing a fuel container from the polyethylene compositions by blow molding is also provided. The fuel containers may include vehicle fuel tanks.Type: ApplicationFiled: April 13, 2011Publication date: March 28, 2013Inventors: Mridula Kapur, Stephanie M. Whited, Josef J. Van Dun
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Publication number: 20130072632Abstract: A dual reactor solution process gives high density polyethylene compositions containing a first ethylene copolymer and a second ethylene copolymer and which have good processability, toughness, and environmental stress crack resistance combined with good organoleptic properties. The polyethylene compositions are suitable for compression molding or injection molding applications and are particularly useful in the manufacture of caps and closures for bottles.Type: ApplicationFiled: August 31, 2012Publication date: March 21, 2013Applicant: NOVA CHEMICALS (INTERNATIONAL) S.A.Inventors: XiaoChuan Wang, Yves Lacombe, Mark Edmund Weber
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Patent number: 8378032Abstract: Elastoplastic polyolefin composition comprising, in percent by weight: A) 10-50% of a copolymer of propylene with one or more comonomer(s) selected from ethylene and CH2?CHR alpha-olefins where R is a 2-8 carbon alkyl, which copolymer contains from 1 to 8% of comonomer(s); B) 50-90% of a copolymer of ethylene and (i) propylene or (ii) CH2?CHR alpha-olefins, where R is a 2-8 carbon alkyl radical, or (iii) a combination thereof, optionally with minor amounts of a diene, containing from 57 to 80% of ethylene; wherein the weight ratio B/XS of the content B of copolymer component (B) to the fraction XS soluble in xylene at room temperature, both referred to the total weight of (A)+(B), is of 1.5 or less, and the intrinsic viscosity [?] of the said XS fraction is of 3 dl/g or more.Type: GrantFiled: March 26, 2012Date of Patent: February 19, 2013Assignee: Basell Poliolefine Italia s.r.l.Inventors: Giampaolo Pellegatti, Paolo Goberti, Michael Balow, Robert Butala
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Publication number: 20130035442Abstract: Provided are elastic propylene-alpha olefin blocky copolymers. In one form, the elastic propylene-alpha olefin blocky copolymer includes an ?-olefin content from 12 to 25 wt % and having a propylene crystallinity less than 30 J/g, a Tm <100° C. and a Tg >?45° C., wherein said copolymer has blocky propylene segments with r1r2 greater than 1.5, and a process for producing such copolymer.Type: ApplicationFiled: August 4, 2011Publication date: February 7, 2013Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Andy Haishung Tsou, Gabor Kiss, Robert Patrick Reynolds, JR., John W. Chu, Alan Anthony Galuska, Patrick Brant, Donald Andrew Winesett
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Patent number: 8362143Abstract: Disclosed herein is a non-glossy rubber modified aromatic vinyl-vinyl cyanide copolymer and a method for continuously preparing the same. The copolymer comprises about 80 to about 93% by weight of an aromatic vinyl-vinyl cyanide copolymer grafted onto about 7 to about 20% by weight of a diene-based rubber, and a dispersed phase of the copolymer has an average rubber particle diameter of about 6 to about 20 ?m and a span of about 1.2 to about 2.8.Type: GrantFiled: December 29, 2008Date of Patent: January 29, 2013Assignee: Cheil Industries Inc.Inventors: Hwan Seok Park, Young Sub Jin, Jae Keun Hong, Sung Kwan Kim, Byeong Do Lee, Ho Ryong Sun, Seung Dae Lee
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Publication number: 20130005902Abstract: The present invention relates to a heterophasic polypropylene composition with rather high melt flow rate, high stiffness, acceptable impact properties and an advantageous balance between stiffness and transparency. Still further, the present invention is also directed to a process for producing the inventive polypropylene composition, to an article made of the inventive polypropylene composition and to the use of the inventive polypropylene composition for the production of films and moulded articles, such as thin-walled plastic containers for packaging. The inventive heterophasic polypropylene composition comprises at least a propylene homopolymer fraction, a propylene random copolymer fraction, two different ethylene-propylene rubber fractions and an ethylene homo- or copolymer fraction.Type: ApplicationFiled: December 14, 2010Publication date: January 3, 2013Inventors: Petar Doshev, Rao Kona Balakantha, Pirjo Jaaskelainen, Bo Malm
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Patent number: 8324328Abstract: An apparatus defined as a set of loop reactors suitable for the polymerization process of a monomer, preferably ethylene and optionally an olefin co-monomer, comprising for each of said reactors: a plurality of interconnected pipes P defining a flow path for a polymer slurry, said slurry consisting essentially of ethylene, optionally a co-monomer, a polymerization catalyst, liquid diluent and solid olefin polymer particles, means for feeding monomer, optionally a co-monomer, diluent and optionally hydrogen in the reactor, means for feeding a polymerization catalyst in the reactor, a pump suitable for maintaining the polymer slurry in circulation in such reactor, one or more settling legs connected to the pipes P of such reactor for settling of polymer slurry, one or more control valves connected to the outlet of such settling legs, and one or more flash lines for discharging settled polymer slurry out of the reactor characterized in that each of said loop reactors comprises a three-or-more-way valve definiType: GrantFiled: August 22, 2011Date of Patent: December 4, 2012Assignee: Total Petrochemicals Research FeluyInventors: Louis Fouarge, Carl Van Camp
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Publication number: 20120296039Abstract: A polypropylene composition for injection-moulded drainage systems comprising 78-84 wt % of a crystalline propylene polymer, 8 to less than 13 wt % of an elastomeric copolymer and 8 to less than 13 wt % of polyethylene. The said composition exhibits a flexural modulus value higher than 1400 MPa, a melt flow rate (MFR), determined according to ISO method 1133 (230° C. and 2.16 kg), of from 1.5 to 5.0 g/10 min, and a value of Izod impact resistance at 0° C. of more than 6 kJ/m2 according to ISO method 180/1 A.Type: ApplicationFiled: December 14, 2010Publication date: November 22, 2012Applicant: BASELL POLIOLEFINE ITALIA, S.R.L.Inventors: Claudio Cavalieri, Moníca Galvan, Roberto Pantaleoni, Enrico Beccarini, Francesca Tisi, Werner Rothhöft
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Patent number: 8314180Abstract: The present invention concerns heterophasic propylene copolymers, comprising a propylene homopolymer (PPH) and an ethylene-propylene rubber (EPR), having a broad molecular weight distribution and a well-defined total ethylene content and a specific ratio of the intrinsic viscosities of the ethylene-propylene rubber (EPR) and the propylene homopolymer (PPH), ?EPR/?PPH. The invention further concerns the process to produce such heterophasic propylene copolymers. The heterophasic propylene copolymers of the present invention are particularly suited for corrugated sheet and cast film applications.Type: GrantFiled: November 25, 2008Date of Patent: November 20, 2012Assignee: Total Petrochemicals Research FeluyInventors: Isabelle Ydens, Alain Standaert, Olivier Lhost, Jérôme Gromada, Katty Den Dauw
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Publication number: 20120288656Abstract: The present disclosure describes a polypropylene resin composition useful for the preparation of buried structures such as corrugated, non-pressure pipe.Type: ApplicationFiled: June 29, 2012Publication date: November 15, 2012Applicant: Braskem America, Inc.Inventor: Antonios Doufas
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Publication number: 20120277375Abstract: A process for producing rubber modified polymers having an increased rubber phase volume, including feeding a vinyl aromatic monomer and an elastomer to a polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a copolymer to the polymerized reaction mixture to form a combined mixture, subjecting the combined mixture to further polymerization, and obtaining a rubber modified polymer product from the further polymerization.Type: ApplicationFiled: April 28, 2011Publication date: November 1, 2012Applicant: Fina Technology, Inc.Inventors: Carlos DeAnda, Graciela Morales, Jose M. Sosa, David Knoeppel
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Publication number: 20120247274Abstract: Methods of making metal-terephthalate polymers from a polyester ethylene terephthalate or terephthalic acid produces high yield and high purity reaction products for a range of metals. Among the preferred metal compounds employed in the processes are metal oxides and metal hydroxides. The methods are preferably carried out at a low pressure and can produce metal-terephthalate polymer powders containing small crystals which can be employed to enhance properties of polymers or disperse metals in specific applications by thermal decomposition of metal-terephthalate polymers.Type: ApplicationFiled: March 29, 2011Publication date: October 4, 2012Inventors: DANIEL ERIC STEINMEYER, Jonathan Lyle Winstrom
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Publication number: 20120252975Abstract: A process for producing a high impact polystyrene having a high swell index including feeding at least one vinyl aromatic monomer and at least one elastomer to at least one polymerization reactor to form a reaction mixture, polymerizing the reaction mixture, combining a chain transfer agent to the reaction mixture leaving the at least one polymerization reactor to form a combined mixture, sending the combined mixture to a devolatilization zone and obtaining a HIPS product having a high swell index.Type: ApplicationFiled: March 30, 2011Publication date: October 4, 2012Applicant: Fina Technology, Inc.Inventors: John Tomlinson, Jose M. Sosa
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Publication number: 20120245287Abstract: An ethylenic polymer comprising amyl groups from about 0.1 to about 2.0 units per 1000 carbon atoms as determined by Nuclear Magnetic Resonance and both a peak melting temperature, Tm, in ° C., and a heat of fusion, Hf, in J/g, as determined by DSC Crystallinity, where the numerical values of Tm and Hf correspond to the relationship Tm?(0.2143*Hf)+79.643. An ethylenic polymer comprising at least one preparative TREF fraction that elutes at 95° C. or greater using a Preparative Temperature Rising Elution Fractionation method, where at least one preparative TREF fraction that elutes at 95° C. or greater has a gpcBR value greater than 0.05 and less than 5 as determined by gpcBR Branching Index by 3D-GPC, and where at least 5% of the ethylenic polymer elutes at a temperature of 95° C. or greater based upon the total weight of the ethylenic polymer.Type: ApplicationFiled: May 16, 2012Publication date: September 27, 2012Applicant: Dow Global Technologies LLCInventors: Mehmet Demirors, Teresa P. Karjala, Christopher R. Eddy, Lonnie G. Hazlitt, Pak-Meng Cham, Sarat Munjal, Wallace W. Yau
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Patent number: 8268425Abstract: The invention relates to a polyethylene molding composition which has a multimodal molar mass distribution and is particularly suitable for producing external sheathing of electric or information transmission cables. The molding composition has a density at a temperature of 23° C. in the range from 0.94 to 0.95 g/cm3 and an MFI190/5 in the range from 1.2 to 2.1 dg/min. It comprises from 45 to 55% by weight of a low molecular weight ethylene homopolymer A, from 30 to 40% by weight of a high molecular weight copolymer B of ethylene and another olefin having from 4 to 8 carbon atoms and from 10 to 20% by weight of an ultra high molecular weight ethylene copolymer C. The invention also relates to an electric or information transmission cable having an external sheath of the polyethylene molding composition which has a thickness in the range from 0.2 to 3 cm.Type: GrantFiled: November 17, 2005Date of Patent: September 18, 2012Assignee: Basell Polyolefine GmbHInventors: Heinz Vogt, Joachim Berthold
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Publication number: 20120225998Abstract: Isotactic polypropylene ethylene-propylene copolymer blends and in-line processes for producing. The blends may have between 1 and 50 wt % of isotactic polypropylene with a melt flow rate of between 0.5 and 20,000 g/10 min and a melting peak temperature of 145° C. or higher, and wherein the difference between the DSC peak melting and the peak crystallization temperatures is less than or equal to 0.5333 times the melting peak temperature minus 41.333° C., and between 50 and 99 wt % of ethylene-propylene copolymer including between 10 wt % and 20 wt % randomly distributed ethylene with a melt flow rate of between 0.5 and 20,000 g/10 min, wherein the copolymer is polymerized by a bulk homogeneous polymerization process, and wherein the total regio defects in the continuous propylene segments of the copolymer is between 40 and 150% greater than a copolymer of equivalent melt flow rate and wt % ethylene polymerized by a solution polymerization process.Type: ApplicationFiled: February 13, 2012Publication date: September 6, 2012Applicant: EXXONMOBIL RESEARCH AND ENGINEERING COMPANYInventors: Gabor Kiss, Patrick Brant, Robert Patrick Reynolds, JR., Aspy K. Mehta, Manika Varma-Nair, John W. Chu, Steven P. Rucker
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Publication number: 20120202947Abstract: The copolymer rubber composition comprises 60 to 75% by weight of a copolymer rubber (1) and 40 to 25% by weight of a copolymer rubber (2), and exhibits a difference in iodine value of 5 to 30 between the copolymer rubber (1) and the copolymer rubber (2). The copolymer rubber (1) is an ethylene-?-olefin-nonconjugated polyene copolymer rubber having an ethylene unit of 50 mol % to 70 mol %, an ?-olefin unit of 50 mol % to 30 mol %, and an iodine value of 10 to 30, and the copolymer rubber (2) is an ethylene-?-olefinic copolymer rubber having an ethylene unit of more than 70 mol % and 95 mol % or less, an ?-olefin unit of less than 30 mol % and 5 mol % or more, and an iodine value of 0 to 8.Type: ApplicationFiled: April 20, 2012Publication date: August 9, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Sadayuki NAKANO
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Publication number: 20120184675Abstract: Elastoplastic polyolefin composition comprising, in percent by weight: A) 10-50% of a copolymer of propylene with one or more comonomer(s) selected from ethylene and CH2?CHR alpha-olefins where R is a 2-8 carbon alkyl, which copolymer contains from 1 to 8% of comonomer(s); B) 50-90% of a copolymer of ethylene and (i) propylene or (ii) CH2?CHR alpha-olefins, where R is a 2-8 carbon alkyl radical, or (iii) a combination thereof, optionally with minor amounts of a diene, containing from 57 to 80% of ethylene; wherein the weight ratio B/XS of the content B of copolymer component (B) to the fraction XS soluble in xylene at room temperature, both referred to the total weight of (A)+(B), is of 1.5 or less, and the intrinsic viscosity [?] of the said XS fraction is of 3 dl/g or more.Type: ApplicationFiled: March 26, 2012Publication date: July 19, 2012Applicant: BASELL POLIOLEFINE ITALIA S.R.L.Inventors: Giampaolo Pellegatti, Paolo Goberti, Michael Balow, Robert Butala
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Publication number: 20120157625Abstract: Disclosed is a method for producing a water absorbent resin, by which a surface-crosslinked water absorbent resin having excellent physical properties can be efficiently obtained at low cost, while assuring high productivity. When the production scale is increased to a continuous production at 1 t/hr or more, the physical properties are improved and stabilized (for example, standard deviation of the physical properties is reduced) by a surface-crosslinking treatment, and the absorption against pressure (AAP) and liquid permeability (SFC) are further improved.Type: ApplicationFiled: August 27, 2010Publication date: June 21, 2012Applicant: NIPPON SHOKUBAI CO., LTD.Inventors: Takahiro Kitano, Kozo Nogi, Kunihiko Ishizaki
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Patent number: 8202936Abstract: The present invention relates to a process of producing an ethylene polymer composition in multiple stages of which the first stage is a slurry polymerization stage, in the presence of a catalyst system comprising a) a solid catalyst precursor comprising a transition metal selected from titanium and vanadium; magnesium, a halide, optionally an electron donor, and a solid particulate material comprising an inorganic oxide, wherein the median particle diameter of the solid catalyst precursor based upon the total volume of solid catalyst precursor, D50, is from 1 to 13 micrometers; and b) an organoaluminium compound.Type: GrantFiled: July 6, 2005Date of Patent: June 19, 2012Assignee: Dow Global Technologies LLCInventors: Patrick J. C. Schouterden, Ruddy Nicasy, Sarat Munjal, Burkhard E. Wagner, Robert J. Jorgensen
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Publication number: 20120148775Abstract: A polyethylene composition is disclosed having an unpigmented density of at least 946 kg/m3 and a melt index MI5 of 0.05 to 2 g/10 min, and comprising from 48 to 49.5% by weight based on the total weight of the composition of an ethylene polymer fraction (A) having a density of at least 969 kg/m3, and from 50.5 to 52% by weight with based on the total weight of the composition of a copolymer fraction (B) of ethylene and 1-hexene having a melt index MI5 of 0.001 to 0.5 g/10 min and a density of no more than 930 kg/m3.Type: ApplicationFiled: February 21, 2012Publication date: June 14, 2012Applicant: Ineos manufacturing Belgium NVInventors: Pascale Godon, Daniel Libert
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Publication number: 20120108747Abstract: A process for producing high impact polystyrene including feeding at least one vinyl aromatic monomer, an elastomer, and a free radical initiator to a first linear flow reactor to form a reaction mixture. Polymerizing the reaction mixture in the first linear flow reactor to a point below the point at which phase inversion occurs to produce a first polymerization mixture and feeding the first polymerization mixture from the first linear flow reactor to a second linear flow reactor. Polymerizing the reaction mixture in the second linear flow reactor to at least a phase inversion point of the mixture to produce a second polymerization mixture and feeding the second polymerization mixture from the second linear flow reactor to at least a third linear flow reactor for post-inversion polymerization of the second polymerization mixture. The product stream can have an ESCR value of at least 10% toughness retained with less than 10 wt % rubber content.Type: ApplicationFiled: September 30, 2011Publication date: May 3, 2012Applicant: FINA TECHNOLOGY, INC.Inventors: Likuo Sun, Jose M. Sosa, Serge Eon, Carlos Corleto, Scott Cooper
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Patent number: 8143352Abstract: A process for fluid phase in-line blending of polymers.Type: GrantFiled: December 17, 2007Date of Patent: March 27, 2012Assignee: ExxonMobil Research and Engineering CompanyInventors: Gabor Kiss, Patrick Brant, Robert Patrick Reynolds, Jr., Robert Charles Portnoy, David B. Dunaway
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Patent number: 8138269Abstract: Isotactic polypropylene ethylene-propylene copolymer blends and in-line processes for producing them. The blends may have between 1 and 50 wt % of isotactic polypropylene with a melt flow rate of between 0.5 and 20,000 g/10 min and a melting peak temperature of 145° C. or higher, and wherein the difference between the DSC peak melting and the peak crystallization temperatures is less than or equal to 0.5333 times the melting peak temperature minus 41.333° C., and between 50 and 99 wt % of ethylene-propylene copolymer including between 10 wt % and 20 wt % randomly distributed ethylene with a melt flow rate of between 0.5 and 20,000 g/10 min, wherein the copolymer is polymerized by a bulk homogeneous polymerization process, and wherein the total regio defects in the continuous propylene segments of the copolymer is between 40 and 150% greater than a copolymer of equivalent melt flow rate and wt % ethylene polymerized by a solution polymerization process.Type: GrantFiled: December 18, 2008Date of Patent: March 20, 2012Assignee: ExxonMobil Research and Engineering CompanyInventors: Gabor Kiss, Patrick Brant, Robert Patrick Reynolds, Jr., Aspy K. Mehta, Manika Varma-Nair, John W. Chu, Steven P. Rucker
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Patent number: 8138264Abstract: A bimodal polyethylene having a high density ranging from about 0.955 to about 0.959 g/cc, an improved environmental stress cracking resistance (ESCR) of from about 400 to about 2500 hours, and an improved 0.4% flexural modulus of from about 180,000 to about 260,000 psi (1,200 MPa to about 1,800 MPa) may be formed using a Ziegler-Natta polymerization catalyst using two reactors in series. The bimodal polyethylene may have a high load melt index (HLMI) of from about 2 and about 30 dg/min and may be optionally made with a small amount of alpha-olefinic comonomer in the second reactor. It is emphasized that this abstract is provided to comply with the rules requiring an abstract which will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.Type: GrantFiled: May 4, 2007Date of Patent: March 20, 2012Assignee: Fina Technology, Inc.Inventors: Tim J. Coffy, Gerhard Guenther, Steven D. Gray
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Publication number: 20120059123Abstract: The copolymer rubber composition comprises 60 to 75% by weight of a copolymer rubber (1) and 40 to 25% by weight of a copolymer rubber (2), and [iodine value of the copolymer rubber (1)?iodine value of the copolymer rubber (2)] is 5 to 30. The copolymer rubber (1) is an ethylene-?-olefin-nonconjugated polyene copolymer rubber having an ethylene unit of 50 mol % to 70 mol %, an ?-olefin unit of 50 mol % to 30 mol %, and an iodine value of 15 to 45, and the copolymer rubber (2) is an ethylene-?-olefinic copolymer rubber having an ethylene unit of more than 70 mol % and 95 mol % or less, an ?-olefin unit of less than 30 mol % and 5 mol % or more, and an iodine value of 10 to 30.Type: ApplicationFiled: November 10, 2011Publication date: March 8, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventor: Sadayuki NAKANO
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Patent number: 8124709Abstract: Embodiments of the invention provide a class of mesophase separated ethylene/?-olefin block interpolymers with controlled block sequences. The ethylene/?-olefin interpolymers are characterized by an average block index, ABI, which is greater than zero and up to about 1.0 and a molecular weight distribution, Mw/Mn, greater than about 1.4. Preferably, the block index is from about 0.2 to about 1. In addition or alternatively, the block ethylene/?-olefin interpolymer is characterized by having at least one fraction obtained by Temperature Rising Elution Fractionation (‘TREF’), wherein the fraction has a block index greater than about 0.3 and up to about 1.0 and the ethylene/?-olefin interpolymer has a molecular weight distribution, Mw/Mn, greater than about 1.4.Type: GrantFiled: January 30, 2009Date of Patent: February 28, 2012Assignee: Dow Global Technologies LLCInventors: Gary R. Marchand, Yunwa W. Cheung, Benjamin C. Poon, Jeffrey D. Weinhold, Kim L. Walton, Pankaj Gupta, Colin Lipishan, Phillip D. Hustad, Roger L. Kuhlman, Edmund M. Carnahan, Eddy I. Garcia-Meitin, Patricia L. Roberts