Previously Formed Solid Polymer Is Derived From Ethylenically Unsaturated Reactants Only Patents (Class 525/54.23)
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Patent number: 12116462Abstract: Methods of forming cross-linked polysaccharides are disclosed in which one or more polysaccharides are dissolved in solution, gelled, modified to have a desired concentration, and subsequently irradiated. The irradiation of the gel crosslinks the polysaccharide(s) present. The disclosed techniques may be applied to various polysaccharides, including but not limited to agarose and/or hyaluronic acid.Type: GrantFiled: June 8, 2023Date of Patent: October 15, 2024Assignee: Advanced Aesthetic Technologies, Inc.Inventors: Richard Provonchee, Valentino Gitto, Leonard Miller
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Patent number: 11667763Abstract: A cellulose fiber dispersion polyethylene resin composite material formed by dispersing a cellulose fiber into a polyethylene resin, in which a proportion of the above-described cellulose fiber is 1 part by mass or more and 70 parts by mass or less in a total content of 100 parts by mass of the polyethylene resin and the cellulose fiber, and the polyethylene resin satisfies a relationship: 1.7>half-width (Log(MH/ML))>1.0 in a molecular weight pattern obtained by gel permeation chromatography measurement, and a formed body and a pellet using the same, a production method therefor, and a recycling method for the cellulose fiber adhesion polyethylene thin film piece.Type: GrantFiled: August 23, 2017Date of Patent: June 6, 2023Assignee: FURUKAWA ELECTRIC CO., LTD.Inventors: Jirou Hiroishi, Hidekazu Hara, Yuka Sawada, Masami Tazuke, Toshihiro Suzuki, Shingo Mitsugi
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Patent number: 11603612Abstract: A binder composition for use in the manufacture of a nonwoven mat including a low-density fiber, and nonwoven mats made with the binder, are disclosed. The low-density fiber is able to reduce the acoustic openness of the nonwoven mats made therefrom while also capable of being delivered with existing binder technology and equipment.Type: GrantFiled: May 29, 2019Date of Patent: March 14, 2023Assignee: Owens Corning Intellectual Capital, LLCInventors: Jianhui Wu, David Hartman, William Sorsby, Jeff Pessell
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Patent number: 10543455Abstract: A gas separation membrane has a gas separation layer containing a crosslinked cellulose resin. The crosslinked cellulose resin has a particular linking structure in a crosslinked structure. The gas separation layer contains an organic solvent in a particular amount.Type: GrantFiled: August 7, 2017Date of Patent: January 28, 2020Assignee: FUJIFILM CorporationInventors: Satoshi Sano, Koji Hironaka, Keisuke Kodama
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Publication number: 20150119503Abstract: The present disclosure relates to a plastic article for automotive interior parts using a biomass pellet and to a method for manufacturing the plastic article, which is characterized by injection molding a pellet containing paper powder and plastic resin. The present disclosure provides a plastic article for automotive interior parts using a biomass pellet, which meets the physical property requirements for automotive interior parts.Type: ApplicationFiled: March 18, 2013Publication date: April 30, 2015Inventors: Seung Hoon Ryu, Jun Hong Park, Seung Yeon Ryu
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Publication number: 20150072581Abstract: Methods of forming a nanocellulose composite are provided. The methods can include blending a copolymer with a nanocellulose to form the nanocellulose composite. The copolymer can be a reaction product of a first monomer, a second monomer, and a third monomer. The first monomer is a hydrophilic monomer, the second monomer is a cellulose-reactive monomer and the third monomer is an amphiphobic monomer.Type: ApplicationFiled: September 9, 2014Publication date: March 12, 2015Applicant: Empire Technology Development LLCInventor: Sivaraman Raghu
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Patent number: 8927098Abstract: The present invention relates to a hard coating film including a hard coating layer comprising: a crosslinked product of (a) a polyrotaxane compound including a macrocycle to which a lactone-based compound is bonded, wherein a (meth)acrylate-based compound is introduced at the end of the lactone-based compound at a ratio of 40 mol % to 70 mol %, a linear molecule penetrating the macrocycle, and blocking groups arranged at both ends of the linear molecule and preventing the macrocycle from escaping; and (b) a binder resin.Type: GrantFiled: September 6, 2013Date of Patent: January 6, 2015Assignee: LG Chem, Ltd.Inventors: Soon-Hwa Jung, Heon Kim, Yeong-Rae Chang, Hye-Min Kim
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Patent number: 8703847Abstract: The present invention is directed to a method for preparing a cellulose reactive adduct of polyvinylamide and a composition resulting from the method. The preparation of the cellulose reactive adduct is carried out close to a Critical Concentration defined herein. When the reaction is run close to this Critical Concentration, the risk of gelation is minimized, consumed glyoxal is maximized, and shelf live is enhanced. Additionally, the glyoxalated vinylamides of the present invention impart improved wet and dry strengthening efficiency to paper and paperboard when compared to adducts disclosed in previously described art.Type: GrantFiled: June 15, 2012Date of Patent: April 22, 2014Assignee: BASF SEInventor: Matthew D. Wright
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Patent number: 8703293Abstract: Provided herein re a composition and a coating or a device (e.g., absorbable stent) that includes a PEGylated hyaluronic acid and a PEGylated non-hyaluronic acid biocompatible polymer and the methods of use thereof.Type: GrantFiled: April 1, 2010Date of Patent: April 22, 2014Assignee: Advanced Cardiovascular Systems, Inc.Inventors: Lothar W. Kleiner, Connie S. Kwok
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Publication number: 20140100332Abstract: The present invention is directed to plant fiber-reinforced thermoplastic compositions and a method for reinforcing thermoplastic resins. The present invention provides a use for the cellulose portion of a plant material, which is the portion left over after processing the selected plant materials to separate the hemi-cellulose and lignin from the cellulose.Type: ApplicationFiled: October 10, 2012Publication date: April 10, 2014Applicant: CNH Canada, Ltd.Inventors: James Henry, Satyanarayan Panigrahi, Radhey Lal Kushwaha
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Publication number: 20140088252Abstract: A method for preparing a specific product from a polysaccharide in which at least one hydroxyl of a saccharide unit is substituted with an ether or ester moiety. The ether or ester moiety is provided with ethenyl and/or epoxy functionality for preparing an activatable polysaccharide polymer and the activatable polysaccharide polymer with ethenyl and/or epoxy functionality is optionally reacted with an additional coupling reagent, having at least two coupling functionality for preparing polysaccharide polymer with additional activatable crosslinker.Type: ApplicationFiled: March 22, 2012Publication date: March 27, 2014Applicant: Teknologian Tutkimuskeskus VttInventors: Ali Harlin, Harri Setälä, Helinä Talja
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Publication number: 20130310519Abstract: A cellulose resin produced by binding cardanol or a derivative thereof, and a flexible component to cellulose or a derivative thereof.Type: ApplicationFiled: July 6, 2011Publication date: November 21, 2013Applicant: NEC CORPORATIONInventors: Shukichi Tanaka, Masatoshi Iji, Sungil Moon
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Patent number: 8420735Abstract: A modified microfibrillated cellulose, a resin composition and a resin composite material that contain the modified microfibrillated cellulose are provided. In a modified microfibrillated cellulose according to the present invention, a hydrolyzable-silyl-group-containing resin (A) bonds to or adheres to a cellulose surface and a silicon atom content is 0.01 to 0.5 atomic percent. A resin composition containing 0.1% to 10% by weight of the modified microfibrillated cellulose is also provided.Type: GrantFiled: December 21, 2010Date of Patent: April 16, 2013Assignee: DIC CorporationInventors: Kenichi Hamada, Tetsuya Harada
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Publication number: 20130053475Abstract: An additive composition for mortars, exterior insulation finish systems, self-leveling compounds and joint compounds is disclosed. The additive composition contains a nitrogen-containing polymer and a reactive agent capable of forming a crosslinking reaction with the nitrogen-containing polymer. Small amounts of the additive composition contained in a product not only can increase one or more properties of the product but can also minimize the use of redispersible polymers in the product.Type: ApplicationFiled: October 26, 2012Publication date: February 28, 2013Applicant: CELANESE INTERNATIONAL CORPORATIONInventor: Celanese International Corporation
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Publication number: 20120309898Abstract: A modified microfibrillated cellulose, a resin composition and a resin composite material that contain the modified microfibrillated cellulose are provided. In a modified microfibrillated cellulose according to the present invention, a hydrolyzable-silyl-group-containing resin (A) bonds to or adheres to a cellulose surface and a silicon atom content is 0.01 to 0.5 atomic percent. A resin composition containing 0.1% to 10% by weight of the modified microfibrillated cellulose is also provided.Type: ApplicationFiled: December 21, 2010Publication date: December 6, 2012Applicant: DIC CORPORATIONInventors: Kenichi Hamada, Tetsuya Harada
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Publication number: 20120183494Abstract: Novel acrylamide and methacrylamide hydantoin monomers which can be reacted with other acrylamide, methacrylamide, acrylate, and methacrylate monomers to form copolymers, which upon halogenation, provide oxidative coatings which are biocidal for use with various materials including, but not limited to, textiles, filters, and latex paints.Type: ApplicationFiled: October 11, 2011Publication date: July 19, 2012Applicant: AUBURN UNIVERSITYInventors: Shelby D. Worley, Royall M. Broughton, Hasan B. Kocer, Idris Cerkez
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Patent number: 8221574Abstract: A composition for a removable top coating for protecting the exposed face of a temporary removable graphic is provided. A remover for the transferred graphic image is provided that completely dissolves the temporary removable graphic, but does not affect the commonly encountered substrates such as concrete, brick, wooden floors, asphalt surfaces, terrazzo and motor vehicle body surfaces, marine and aeronautical craft surfaces. A method for making, applying and removing the temporary removable graphic is provided.Type: GrantFiled: August 2, 2007Date of Patent: July 17, 2012Assignee: CSD, LLCInventors: Parvez Akhtar, John Fitzwater, Norman J. Greenberg
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Patent number: 8222343Abstract: The present invention is directed to a method for preparing a cellulose reactive adduct of polyvinylamide and a composition resulting from the method. The preparation of the cellulose reactive adduct is carried out close to a Critical Concentration defined herein. When the reaction is run close to this Critical Concentration, the risk of gelation is minimized, consumed glyoxal is maximized, and shelf live is enhanced. Additionally, the glyoxalated vinylamides of the present invention impart improved wet and dry strengthening efficiency to paper and paperboard when compared to adducts disclosed in previously described art.Type: GrantFiled: December 16, 2010Date of Patent: July 17, 2012Assignee: BASF SEInventor: Matthew D. Wright
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Publication number: 20120100097Abstract: Cellulose support containing mannose derivatives able to fix type 1 piliated bacteria, application to disinfecting wipes especially. Support intended to bind type 1 piliated bacteria comprising cellulose fibers and/or regenerated cellulose fibers onto which mannose derivative is fixed characterized in that the mannose derivative is present in the form of copolymer obtained by copolymerization of: —a monomer derivative of alkenyl ?-D-mannopyranoside modified with a function capable of reacting with an acrylamid monomer, —a cationic monomer —an acrylamid monomer.Type: ApplicationFiled: April 23, 2010Publication date: April 26, 2012Inventors: Menno Dufour, Lynda Ferez
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Publication number: 20120058536Abstract: The present invention relates to a polymer made of a primary amine functionalized polymer and a hemicellulose e.g. chitosan and xyloglucan, wherein the primary amine functionalized polymer is covalently bound to the hemicellulose, and to a cross-linking agent composition comprising the polymer. A method wherein manufacturing a cellulose containing product comprises the steps of; providing a cellulose containing product; treating said cellulose product with a cellulose adsorbing agent comprising a polymer made of a primary amine functionalized polymer and a hemicellulose e.g. chitosan and xyloglucan, and optionally other additives is also provided.Type: ApplicationFiled: May 27, 2010Publication date: March 8, 2012Applicant: SweTree Technologies ABInventors: Marcus Ruda, Rikard Slättegård
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Patent number: 8129450Abstract: Durable and disposable articles are provided which include a thermoplastic polymer composition, which includes a blend of a polymer and a modified polymer. The modified polymer has covalently bonded pendant substituents derived from cyclodextrin. The articles can be a films, coatings, nonwoven webs, or monolithic articles. An article can have the polymer composition as one part of the article, such as in one distinct area of the article, or on the surface of the article, for example as a coating or surface film. The article can be, for example, a multilayer barrier film, a nonwoven sheet or pad, an absorbent article, or a storage container.Type: GrantFiled: June 11, 2007Date of Patent: March 6, 2012Assignee: Cellresin Technologies, LLCInventors: Willard E. Wood, Timothy H. Bohrer, Stanley R. Kellenberger, Neil J. Beaverson
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Patent number: 8105391Abstract: Provided herein are a method, which comprises implanting in a patient an implantable device comprising a coating that includes a PEGylated hyaluronic acid and a PEGylated non-hyaluronic acid biocompatible polymer and the methods of use thereof.Type: GrantFiled: April 1, 2010Date of Patent: January 31, 2012Assignee: Advanced Cardiovascular Systems, Inc.Inventors: Lothar W. Kleiner, Connie S. Kwok
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Publication number: 20110282048Abstract: The present invention relates to a method of cross-linking a polymeric carbohydrate material with a second material by means of a soluble carbohydrate polymer and a crosslinking agent. The present invention furthermore relates to the resulting cross-linked material, to uses of the cross-linked material, as well as to a kit comprising the soluble carbohydrate polymer and the cross-linking agent.Type: ApplicationFiled: January 25, 2006Publication date: November 17, 2011Applicant: Swe Tree Technologies ABInventors: Harry Brumer, Mark William Rutland, Michael L. Sinnott, Tuula Telervo Teeri, Qi Zhou
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Patent number: 7910654Abstract: A polymer blend film contains a film forming material containing at least a polymer having an absolute value of an intrinsic birefringence of 0.02 or less, and a cyclic olefin resin, wherein the film has a haze of 5% or less.Type: GrantFiled: January 27, 2009Date of Patent: March 22, 2011Assignee: Fujifilm CorporationInventor: Jun Takeda
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Publication number: 20110028371Abstract: Hybrid copolymers include a synthetic polymer which is derived from at least one anionic or non-anionic ethylenically unsaturated monomer and a naturally derived hydroxyl containing chain transfer agent as an end group. The hybrid copolymer may be prepared as a blend with a builder or a chelating agent. Hybrid copolymers also include a synthetic portion derived from at least one ester monomer and a naturally derived hydroxyl containing chain transfer agent as an end group. Ester graft copolymers include a naturally derived hydroxyl moiety backbone and side chains derived from at least one ester monomer. Further, a method of determining the concentration of a hybrid copolymer in an aqueous system and methods of preparing a hybrid copolymer are also included.Type: ApplicationFiled: July 31, 2009Publication date: February 3, 2011Applicant: AKZO NOBEL N.V.Inventors: Klin A. RODRIGUES, Allen M. Carrier, Jannifer Sanders
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Publication number: 20110021701Abstract: The invention relates to a material comprising cellulose in association with a support selected from a polymer and/or a fibre, wherein said cellulose is produced by a micro-organism. The cellulose-reinforced material is provided for incorporation into a composite.Type: ApplicationFiled: August 14, 2007Publication date: January 27, 2011Applicant: IMPERIAL INNOVATIONS LIMITEDInventors: Alexander Bismarck, Julasak Juntaro, Athanasios Mantalaris, Marion Pommet, Milo S.P. Shaffer
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Patent number: 7875676Abstract: The present invention is directed to a method for preparing a cellulose reactive adduct of polyvinylamide and a composition resulting from the method. The preparation of the cellulose reactive adduct is carried out close to a Critical Concentration defined herein. When the reaction is run close to this Critical Concentration, the risk of gelation is minimized, consumed glyoxal is maximized, and shelf live is enhanced. Additionally, the glyoxalated vinylamides of the present invention impart improved wet and dry strengthening efficiency to paper and paperboard when compared to adducts disclosed in previously described art.Type: GrantFiled: August 28, 2007Date of Patent: January 25, 2011Assignee: Ciba Specialty Chemicals CorporationInventor: Matthew D. Wright
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Publication number: 20100264353Abstract: In accordance with one aspect, a thermally regulating construction material comprises a base material and a polymeric phase change material bound to the base material, wherein the base material provides reversible temperature regulation properties to the building construction material. In accordance with another aspect, an insulation material for use in building construction comprises a base material and a polymeric phase change material bound to the base material, wherein the base material provides reversible temperature regulation properties to the insulation material. The base material may be selected from the group consisting of foam insulation, loose fill insulation, and batted insulation.Type: ApplicationFiled: April 16, 2010Publication date: October 21, 2010Applicant: OUTLAST TECHNOLOGIES, INC.Inventors: Mark Hartmann, Greg Roda, Aharon Eyal
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Patent number: 7713637Abstract: Provided herein are a coating or a device (e.g., absorbable stent) that includes a PEGylated hyaluronic acid and a PEGylated non-hyaluronic acid biocompatible polymer and the methods of use thereof.Type: GrantFiled: March 3, 2006Date of Patent: May 11, 2010Assignee: Advanced Cardiovascular Systems, Inc.Inventors: Lothar W. Kleiner, Connie S. Kwok
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Publication number: 20100065499Abstract: The invention describes a composite microfibre, which is comprising a polysaccharide polymer selected from the group consisting of cellulose, hydroxyethyl cellulose, hydroxypropyl cellulose, methyl cellulose, ethyl cellulose, n-propyl cellulose, isopropyl cellulose, cellulose acetate and combinations of two or more of these substances, and combinations of two or more of these substances, thereby the polysaccharide polymer further comprising substituents comprising a given formula, wherein k is 1 or greater, and wherein each moiety R1 is independently selected from H and methyl, and wherein each moiety R2 is independently selected from —H, —OH, —NH2, —SH, —OR3, —NHR3 and —NR3R4, —SR3, and wherein each moiety R3 and R4 are chemical groups independently selected from C1-C4 alkyl, C1-C4 alkoxy, C1-C4 alkoxy halide and C1-C4 heteroalkyl substituents, and is preferably selected from —CH3, —CH2—CH3, —CH2—OH, —CH2—CH2—OH, —CH2—CH2—NH2, —CH—CH(OH)—CH2—OH, —CH—CH(OH)—CH3, glycidyl, anhydride, sulfonic acid and hydroxysType: ApplicationFiled: March 7, 2008Publication date: March 18, 2010Inventors: Marcello Fernandez-Lahore, Mariano Grasselli
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Patent number: 7605199Abstract: Thermoplastic polymer compositions, films, continues, closures, laminates can comprise a modified vinyl polymer said modified polymer having a moiety comprising a cyclodextrin compound. The cyclodextrin compound, locked into the polymer structure, can absorb impurities, permeants, or other undesirable volatile materials. The cooperation between the cyclodextrin grafted onto the thermoplastic polymer and the polymer structure can provide barrier properties to a film, web or other polymer structure. A permeant or a contaminant can be complexed or trapped within the polymer and held within the film or Web preventing the permeant or contaminant from passing into the interior of a container or enclosure.Type: GrantFiled: May 5, 2006Date of Patent: October 20, 2009Assignee: Cellresin Technologies, LLCInventors: Willard E. Wood, Neil J. Beaverson, Kasyap V. Seethamraju
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Publication number: 20090220386Abstract: A porous article of manufacture (a sealing material) which comprises sintered hydroxyalkylcellulose, for example, sintered hydroxypropylcellulose, or a sealing material which is capable of being formed into a porous article in the form of a filter and which is made by heating at least one gelling agent that has carboxyl functionality and at least one gelling agent that has hydroxyl functionality, preferably carboxylmethylcellulose (CMC) and hydroxypropylcellulose (HPC) respectively, and a method for preparing the same from a powdery admixture thereof, and a pipette which includes the sealing material in the form of a filter, and also including embodiments of a bilayer filter and of a trilayer filter, each of which comprises a composite of a filter of the present invention and a filter comprising porous sintered polyethylene, preferably ultra high-molecular weight polyethylene.Type: ApplicationFiled: March 2, 2009Publication date: September 3, 2009Inventors: Joseph E. Ferri, Kenneth P. Kreska
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Publication number: 20090192256Abstract: A polymer blend film contains a film forming material includes at least a polymer having an absolute value of an intrinsic birefringence of 0.02 or less, and a cyclic olefin resin, wherein the film has a haze of 5% or less.Type: ApplicationFiled: January 27, 2009Publication date: July 30, 2009Applicant: FUJIFILM CorporationInventor: Jun TAKEDA
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Publication number: 20080268140Abstract: This invention is for a composition of clear or pigmented coating that is temporary and removable. It is especially designed to protect the surface of an automobile from the damaging effects of the environment and also from damage caused by normal daily use. The coating is a composition of 40 to 80% of cellulose acetate butyrate ester, 15 to 60% of an acrylic polymer and 2 to 10% of a sucrose acetate isobutyrate. The remover is a combination of tetrahydrofurfuryl alcohol, dibasic ester, diacetone alcohol, ethyl 3 ethoxypropionate; 2,2,4 trimethyl-1,3 pentanoldiol monoisobutyrate, and white mineral oil.Type: ApplicationFiled: August 21, 2007Publication date: October 30, 2008Applicant: CSD, INC.Inventors: Parvez Akhtar, John Fitzwater, Norman J. Greenberg
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Publication number: 20080264559Abstract: A composition for a removable top coating for protecting the exposed face of a temporary removable graphic is provided. A remover for the transferred graphic image is provided that completely dissolves the temporary removable graphic, but does not affect the commonly encountered substrates such as concrete, brick, wooden floors, asphalt surfaces, terrazzo and motor vehicle body surfaces, marine and aeronautical craft surfaces. A method for making, applying and removing the temporary removable graphic is provided.Type: ApplicationFiled: August 2, 2007Publication date: October 30, 2008Applicant: CSD, INC.Inventors: Parvez Akhtar, John Fitzwater, Norman J. Greenberg
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Publication number: 20080108750Abstract: An object of the present invention is to propose a novel thermoplastic resin composition having high impact resistance without degrading weather resistance even when the content of an impact modifier is small. A thermoplastic resin composition includes 100 parts by weight of a thermoplastic resin (a) and 0.5 to 20 parts by weight of an impact modifier (b) containing a graft copolymer (b-1) containing at least one (meth)acrylate flexible polymer phase and a rigid polymer phase serving as the outermost part of the graft copolymer, a water-soluble polymer compound (b-2) having a physical gel-forming property, and a gelling agent (b-3). In the thermoplastic resin composition, the content of the water-soluble polymer compound (b-2) having the physical gel-forming property is 0.01 to 3.0 parts by weight relative to 100 parts by weight of the graft copolymer (b-1) and the content of the rigid polymer phase serving as the outermost part in the graft copolymer (b-1) is 0.5 to 10 percent by weight.Type: ApplicationFiled: December 13, 2005Publication date: May 8, 2008Inventors: Toru Terada, Shinya Hongo, Hirotsugu Yamada, Takashi Ueda
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Patent number: 7335699Abstract: A description is given of water-soluble aminoplast ether copolymers of the following structural type: wherein Z is a glycoluril central unit, B is a radical of an essentially water-insoluble polymer and R1 is a radical of a hydrophilic organic compound. The ratio R1:B is selected within a range of about 1.5 to 4:1 and the overall mass of the water-soluble aminoplast ether copolymer is from about 2000 to 50 000 g/mol such that the copolymer is soluble in water and may be used as a dispersant for e.g. pigments in polar solvents, e.g. water.Type: GrantFiled: December 17, 2002Date of Patent: February 26, 2008Assignee: Sud-Chemie AGInventors: Klaus Dziwok, Inge Krämer, Norbert Schall, Helmut Coutelle, Sabine Huth, Alan Steinmetz, Thadeus Schauer, Heinz Greisiger, Mark Entenmann
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Patent number: 7153904Abstract: This invention relates to an inhibited non-solubilized granular starch modified by less than 5% of a carboxylated polymer. In addition, a process is provided wherein a non-solubilized, substantially granular starch is mixed with a carboxylated polymer, dried to form a starch/carboxylated polymer blend and then physically treated to form a starch/carboxylated polymer composite. Further, this invention relates to the improved industrial and food products prepared from these starch/carboxylated polymer composites.Type: GrantFiled: May 13, 2002Date of Patent: December 26, 2006Assignee: National Starch and Chemical Investment Holding CorporationInventors: Paul H. Richardson, Robert A. Skorge, Maximilian M. R. Koxholt
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Patent number: 7144852Abstract: The present invention is directed to a process for the preparation of polysaccharide-grafted polymer particles wherein the polysaccharide is preferably a ?-1,4 linked polysaccharide, comprising miniemulsion polymerisation.Type: GrantFiled: June 6, 2005Date of Patent: December 5, 2006Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.Inventors: Paul Ferguson, Christopher Clarkson Jones, Paul Simon Stevenson
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Patent number: 7132479Abstract: The present invention relates to polymer mixtures including hydrogel-forming polymers capable of absorbing aqueous fluids and prepared by polymerization of olefinically unsaturated carboxylic acids or derivatives thereof together with copolymers of C2–C8 olefins or styrenes with anhydrides and also their preparation, use and hygiene articles which include same.Type: GrantFiled: March 4, 2003Date of Patent: November 7, 2006Assignee: BASF AktiengesellschaftInventors: Friedrich Engelhardt, Rüdiger Funk, Mariola Wanior
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Patent number: 7030187Abstract: Cellulosic polymers, copolymers and grafts, are disclosed that adhere to fibers and surfaces during an aqueous treatment process. The cellulosic polymers having grafts and/or co-blocks are prepared using living-type free radical polymerization techniques, which provides control over the degree of substitution and graft/co-block composition and structure. These cellulosic polymers allow for the modification of fibers and surfaces to provide a desired effect.Type: GrantFiled: September 28, 2004Date of Patent: April 18, 2006Assignee: Symyx Technologies, Inc.Inventors: Dominique Charmot, Manikandan Jayaraman, Han Ting Chang, Paul Mansky, Wilfried Blokzijl
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Patent number: 7026277Abstract: The present invention is directed to a process for the preparation of polysaccharide grafted latex particles wherein the polysaccharide has ?-1,4 linkages, wherein the process comprises core/shell emulsion polymerisation. Preferably, the process comprises a single step of preparing the latex particles by emulsion polymerisation of latex monomers with the simultaneous grafting of the polysaccharide.Type: GrantFiled: December 17, 2003Date of Patent: April 11, 2006Assignee: Unilever Home & Personal Care USA Division of Conopco, Inc.Inventors: Paul Ferguson, Christopher Clarkson Jones, David Richard Arthur Mealing
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Patent number: 6958429Abstract: The invention relates to absorbent polymers based on optionally partially neutralised, monoethylenically unsaturated, acid group-carrying monomers. The surfaces of said polymers are re-cross-linked. The inventive polymers also have cyclodextrines and/or cyclodextrine derivatives which are covalently and/or ionically bonded and/or included therein.Type: GrantFiled: February 11, 2004Date of Patent: October 25, 2005Assignee: Stockhausen GmbH & Co. KGInventors: Christoph Bruhn, Edgar Herrmann, Jörg Issberner, Dagmar Kersten, Richard Mertens, Georg Werner
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Patent number: 6911572Abstract: The invention relates to absorbent polymers based on optionally partially neutralised, monoethylenically unsaturated, acid group-carrying monomers. The surfaces of said polymers are re-cross-linked. The inventive polymers also have cyclodextrines and/or cyclodextrine derivatives which are covalently and/or ionically bonded and/or included therein.Type: GrantFiled: May 28, 1999Date of Patent: June 28, 2005Assignee: Stockhausen GmbH & Co. KGInventors: Christoph Bruhn, Edgar Herrmann, Jörg Issberner, Dagmar Kersten, Richard Mertens, Georg Werner
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Patent number: 6906133Abstract: The present invention relates to a process for making polyalkyldiallylamine-epihalohydrin resins, the resultant resins and their uses as wet strength additives for papermaking. These resins are obtained by a two step process, wherein the first step comprises the free radical polymerization or copolymerization of an alkyldiallylamine monomer in its protonated form; and the second step comprises reacting an ADAA polymer or copolymer with epihalohydrin under carefully controlled reaction conditions.Type: GrantFiled: January 3, 2003Date of Patent: June 14, 2005Assignee: Hercules IncorporatedInventors: Fang Deng, Daniel Yaodong Gan
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Patent number: 6884842Abstract: Synthetic polymer complements (SPCs) are provided, as well as methods for their synthesis and use. The SPCs may have surfaces that include functional groups that are complementary to surface sites of targets such as nanostructures or macromolecular targets, and may be capable of specifically interacting with such targets. The positions of the functional groups in one embodiment are stabilized by a polymer network. The SPCs are formed by contacting the target with a set of monomers which self-assemble on the target, and then are polymerized into a network to form the synthetic polymer complement. At least a portion of the surface of the resulting SPC thus may include an imprint of the target. The complex of the SPC and the target may be the desired product. Alternatively, the target is released, for example, by controllably expanding and contracting the crosslinked network. The SPC is isolated and used in many applications.Type: GrantFiled: October 26, 2001Date of Patent: April 26, 2005Assignee: Alnis BioSciences, Inc.Inventors: David S. Soane, Stephen E. Barry, Andrew Goodwin, David A. Offord, Michael G. Perrott
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Patent number: 6803410Abstract: Cellulosic polymers, copolymers and grafts, are disclosed that adhere to fibers and surfaces during an aqueous treatment process. The cellulosic polymers having grafts and/or co-blocks are prepared using living-type free radical polymerization techniques, which provides control over the degree of substitution and graft/co-block composition and structure. These cellulosic polymers allow for the modification of fibers and surfaces to provide a desired effect.Type: GrantFiled: March 19, 2003Date of Patent: October 12, 2004Assignee: Symyx Technologies, Inc.Inventors: Dominique Charmot, Manikandan Jayaraman, Han Ting Chang, Paul Mansky, Wilfried Blokzijl
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Patent number: 6730722Abstract: The invention provides cross-linkable polymer powder compositions containing a) at least one water-soluble polyhydroxy compound; b) at least one boric acid complex compound which is of limited solubility in water that is, it has a water solubility of less than 10 g per liter at normal conditions; and optionally c) a water-soluble film-forming polymer consisting of one or more free-radical polymerizable, ethylenically unsaturated monomers. The compositions are useful as a constituent in adhesives, plaster, jointing mortars, paints and binders for coating compositions, textiles, paper and the like.Type: GrantFiled: February 2, 2001Date of Patent: May 4, 2004Assignee: Wacker-Chemie GmbHInventors: Herbert Eck, Hans Donislreiter
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Patent number: 6660804Abstract: The present invention concerns a process for preparing copolymers of cyclodextrin(s) and/or cyclodextrin derivative(s), characterized by the following operations: (a) preparing a solid state mixture of cyclodextrin(s) and/or cyclodextrin derivative(s) and/or inclusion complex(es) of cyclodextrin(s) and/or cyclodextrin derivative(s) and a poly(carboxylic) acid and/or a poly(carboxylic) acid anhydride or a mixture of poly(carboxylic) acid(s) and/or poly(carboxylic) acid anhydride(s), and optionally, a catalyst; and (b) heating the solid mixture to a temperature in the range 100° C. to 200° C. for a period in the range 1 min to 60 min, preferably 30 min or substantially 30 min. The present invention also concerns soluble and insoluble compounds of cyclodextrin(s) and/or cyclodextrin derivative(s) or their inclusion complexes with at least one poly(carboxylic) acid.Type: GrantFiled: August 15, 2001Date of Patent: December 9, 2003Assignee: Universite des Sciences et Technologies de LilleInventors: Marek Weltrowski, Michel Morcellet, Bernard Martel
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Patent number: 6653399Abstract: A water absorbent material, comprising, as a main component, a water absorbent resin which has a structure in which a anhydropolyamino acid having an ethylenically unsaturated double bond is grafted with polysaccharides, wherein at least a portion of the anhydropolyamino acid is hydrolyzed and crosslinked, has high water absorbency and high biodegradability even if the anhydropolyamino acid has a low molecular weight.Type: GrantFiled: February 26, 2002Date of Patent: November 25, 2003Assignee: Dainippon Ink and Chemicals, Inc.Inventors: Hisakazu Tanaka, Shigeki Ideguchi, Yoshiki Hasegawa