With Solid Polymer Derived From Ethylenic Reactants Only Patents (Class 525/57)
-
Publication number: 20140094542Abstract: The invention relates to processes for producing protective colloid-stabilized polymers based on (meth)acrylate esters in the form of their aqueous dispersions and water-redispersible polymer powders by means of free-radically initiated emulsion polymerization of one or more monomers from the group consisting of the esters of acrylic acid or methacrylic acid and optionally one or more further monomers which are copolymerizable therewith, in the presence of one or more protective colloids, and optionally drying of the resulting aqueous dispersion, characterized in that the emulsion polymerization is carried out in the presence of one or more fully hydrolysed 1-alkylvinyl ester-vinyl ester copolymers as protective colloid.Type: ApplicationFiled: April 27, 2012Publication date: April 3, 2014Applicant: WACKER CHEMIE AGInventors: Michael Faatz, Reinhard Haerzschel
-
Publication number: 20140076928Abstract: The present disclosure relates to a material composition comprising: a High Density Polyethylene; Ethylene Vinyl Alcohol; and at least one compatibilizer; wherein the material composition comprises flake-shaped particles. The present disclosure further relates to a laminate tube comprising: a body portion; a neck portion; and a tube shoulder; wherein the tube shoulder is made up of a material composition comprising: a High Density Polyethylene; Ethylene Vinyl Alcohol; and at least one compatibilizer; wherein the material composition comprises flake-shaped particles. The present disclosure also relates to a tube shoulder made up of a material composition comprising: a High Density Polyethylene; Ethylene Vinyl Alcohol; and at least one compatibilizer; wherein the material composition comprises flake-shaped particles.Type: ApplicationFiled: June 4, 2012Publication date: March 20, 2014Applicant: ESSEL PROPACK LTD.Inventor: Mrinal Kanti Banerjee
-
Publication number: 20140058009Abstract: The invention provides fabricated PVA-hydrogels, PVA-hydrogel-containing compositions, and methods of making the same. The invention also provides methods of implanting or administering the PVA-hydrogels, or the PVA-hydrogel-containing compositions to treat a subject in need. Methods of cross-linking pre-solidified or pre-gelled hydrogel particles and making cross-linked PVA-hydrogels, and cross-linked PVA-hydrogel-containing compositions also are disclosed herein.Type: ApplicationFiled: August 22, 2013Publication date: February 27, 2014Inventors: Jeeyoung Choi, Orhun K. Muratoglu
-
Patent number: 8658278Abstract: Provided is a film which can be industrially coated easily and exhibits excellent gas barrier performance without being subjected to a high-temperature heat treatment. The film exhibits good gas barrier performance immediately after the production, and maintains the excellent gas barrier performance while exhibiting excellent hot water resistance and printing resistance.Type: GrantFiled: August 30, 2006Date of Patent: February 25, 2014Assignee: Mitsubishi Plastics, Inc.Inventors: Chiharu Okawara, Shigenobu Yoshida, Tooru Hachisuka, Motoyoshi Takemura
-
Patent number: 8658738Abstract: A curable resin composition, comprising 100 parts by mass of a (meth)acrylic polymer (A) having, at a terminal thereof, at least one crosslinkable silyl group; 0.1 to 100 parts by mass of a diamine compound (B) having a monovalent or bivalent aliphatic or alicyclic hydrocarbon group that has 8 or more carbon atoms and may be branched and having at least one primary amino group; and 0.1 to 100 parts by mass of a diamine compound (C) having a monovalent aliphatic or alicyclic hydrocarbon group that has 8 or more carbon atoms and may be branched, and having a crosslinkable silyl group and/or a (meth)acryloyl group.Type: GrantFiled: June 24, 2009Date of Patent: February 25, 2014Assignee: Kaneka CorporationInventors: Jun Kotani, Nobuyuki Kobayashi, Hiroyuki Hosoda, Kazunori Ishikawa
-
Publication number: 20140004301Abstract: Embodiments herein relate to a polyolefin-containing film comprising a solidified form of a melt, the melt comprising at least 1 weight percent shredded recycled crosslinked vinyl-alcohol polymer coated polyolefin material and an amount of a compatibilizing agent and/or an un-crosslinking agent configured to un-crosslink the crosslinked vinyl-alcohol in the melt, the polyolefin-containing film having an average dimple count of less than about 50 dimples/4 in2, and method of manufacturing the same.Type: ApplicationFiled: June 29, 2012Publication date: January 2, 2014Applicant: Toray Plastics (America), Inc.Inventors: JOSHUA R. CLOUTIER, Shichen Dou, Claudio Paulino, Chang Yeol Jung
-
Patent number: 8569414Abstract: Disclosed is a polyvinyl alcohol resin composition capable of providing a melt-molded article with superior gas barrier properties and flex crack resistance. The resin composition comprises (A) a PVA resin having 1,2-diol unit in side chain thereof; and (B) a mixture of block copolymers each having an aromatic vinyl polymer block, and a conjugated diene polymer block and/or hydrogenated thereof, wherein the (B) mixture of block copolymers includes (B1) a block copolymer having no carboxyl group and (B2) a block copolymer modified with a carboxyl group-containing compound.Type: GrantFiled: February 28, 2012Date of Patent: October 29, 2013Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.Inventors: Mitsuo Shibutani, Kazutoshi Tsuji, Kaoru Inoue, Norihito Sakai
-
Patent number: 8536271Abstract: An object of the present invention is, in a thermoplastic elastomer composition in which a modified rubber is dispersed and filled in an ethylene-vinyl alcohol copolymer matrix in order to improve the low-temperature durability of the ethylene-vinyl alcohol copolymer, to reduce the extrusion load during extrusion molding thereof into a film without deteriorating the low-temperature durability. The present invention is a thermoplastic elastomer composition comprising an ethylene-vinyl alcohol copolymer (A) and a modified rubber (B) dispersed in the ethylene-vinyl alcohol copolymer (A), wherein the modified rubber (B) has an acid anhydride group or epoxy group and is dynamically cross-linked by a compound (C) having at least two amino groups. This thermoplastic elastomer composition can be suitably used in the production of an inner liner of a pneumatic tire.Type: GrantFiled: August 2, 2010Date of Patent: September 17, 2013Assignee: The Yokohama Rubber Co., Ltd.Inventors: Koichi Kawaguchi, Naoyuki Morooka
-
Publication number: 20130225749Abstract: Disclosed is a composition comprising (a) a poly(vinyl alcohol) characterized by (i) a hydrolysis level of from about 85 to about 93 mole % and a 4 weight % aqueous viscosity at 20° C. of 15 centipoise or less; or (ii) a hydrolysis level of about 95 mole % or greater; and (b) an ionomer comprising a parent acid copolymer comprising copolymerized units of ethylene and acrylic acid or methacrylic acid with melt flow rate from about 200 to about 1000 g/10 min., wherein about 50% to about 70% of the carboxylic acid groups of the copolymer are neutralized to carboxylic acid salts.Type: ApplicationFiled: February 29, 2012Publication date: August 29, 2013Applicant: E.I. DU PONT DE NEMOURS AND COMPANYInventors: Elliott Echt, Richard Allen Hayes
-
Patent number: 8470922Abstract: Ethylene-vinyl alcohol (EVOH) based thermoplastic elastomers (TPE) and thermoplastic vulcanizates (TPV) including a cured rubber dispersed therein and an EVOH-rubber compatibilizer.Type: GrantFiled: March 3, 2011Date of Patent: June 25, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventor: Sunny Jacob
-
Publication number: 20130156982Abstract: A method for producing a thermoplastic resin composition, comprising the steps of: (I) melt-kneading (A) acid anhydride-modified or epoxy-modified rubber with (B) ethylene-vinylalcohol copolymer resin to prepare a first resin composition in which (A) acid anhydride-modified or epoxy-modified rubber is dispersed in (B) ethylene-vinylalcohol copolymer resin, (II) crosslinking (C) crosslinkable elastomer while melt-kneading the crosslinkable elastomer with (D) polyamide resin to prepare a second resin composition in which crosslinked elastomer particles are dispersed in (D) polyamide resin, and (III) melt-mixing together the first resin composition with the second resin composition. The thermoplastic resin composition has excellent gas barrier properties, low-temperature durability, and fatigue resistance.Type: ApplicationFiled: May 18, 2011Publication date: June 20, 2013Applicant: The Yokohama Rubber Co., Ltd.Inventors: Koichi Kawaguchi, Yuichi Hara
-
Publication number: 20130156983Abstract: Various barrier films are described that include barrier layers that contain ethylene vinyl alcohol copolymers and elastomers. Polyolefin elastomers can be used such as ethylene octene copolymers. The barrier films can also include secondary barrier layers that contain one or more norbornene copolymers.Type: ApplicationFiled: June 21, 2012Publication date: June 20, 2013Applicant: AVERY DENNISON CORPORATIONInventors: Hoang T. PHAM, Thomas LANEY, Farid F. GHIAM, Kevin O. HENDERSON
-
Publication number: 20130123427Abstract: The invention relates to a process for the preparation of polymers and to an apparatus for performing this process. The apparatus comprises devices and reactors that are combined in the sequence of first a mixing device, second a flow microwave and optionally third one or more additional reactors.Type: ApplicationFiled: April 1, 2011Publication date: May 16, 2013Applicants: DSM FINE CHEMICALS AUSTRIA NFG GMBH & CO KG, DSM IP ASSETS B.V.Inventor: Karsten Luettgen
-
Publication number: 20130074718Abstract: A laser-engraveable flexographic printing precursor or patternable element comprises a laser-engraveable layer having two orthogonal dimensions. This laser-engraveable layer comprises one or more elastomeric resins and non-metallic fibers that are oriented in the laser-engraveable layer predominantly in one of its two orthogonal dimensions. The non-metallic fibers have an average length of at least 0.1 mm and an average diameter of at least 1 ?m. The oriented non-metallic fibers reduce curl and shrinkage in the precursor and improve print quality and press life.Type: ApplicationFiled: September 27, 2011Publication date: March 28, 2013Inventors: Ido Gal, Ophira Melamed
-
Publication number: 20130053475Abstract: An additive composition for mortars, exterior insulation finish systems, self-leveling compounds and joint compounds is disclosed. The additive composition contains a nitrogen-containing polymer and a reactive agent capable of forming a crosslinking reaction with the nitrogen-containing polymer. Small amounts of the additive composition contained in a product not only can increase one or more properties of the product but can also minimize the use of redispersible polymers in the product.Type: ApplicationFiled: October 26, 2012Publication date: February 28, 2013Applicant: CELANESE INTERNATIONAL CORPORATIONInventor: Celanese International Corporation
-
Patent number: 8372517Abstract: An acrylic thermoplastic resin composition is obtained by melt-kneading a methacrylic resin (A) and a polyvinyl acetal resin (B) at a resin temperature of not less than 140° C. while applying shear at a shear rate of 100 sec?1 or more, and then cooling the kneaded product to not more than 120° C. In the acrylic thermoplastic resin composition, at least the methacrylic resin (A) forms a continuous phase, and among glass transition temperatures of the acrylic thermoplastic resin composition, a glass transition temperature TgA P ascribed to the methacrylic resin (A) indicates a value between a glass transition temperature (TgA) of the methacrylic resin (A) alone and a glass transition temperature (TgB) of the polyvinyl acetal resin (B) alone. A film- or sheet-like molded article is obtained by molding the resin composition. An acrylic resin composite is obtained by laying a layer of metal and/or metal oxide on at least one side of the acrylic resin molded article.Type: GrantFiled: October 23, 2007Date of Patent: February 12, 2013Assignee: Kuraray Co., Ltd.Inventors: Kazuki Tokuchi, Nobuhiro Moriguchi, Yohei Kamata, Yukiatsu Komiya
-
Publication number: 20130025757Abstract: Provided is a thermoplastic elastomer composition that can be suitably used for the inner liners of pneumatic tires and exhibits high air barrier properties and high fatigue durability. The present invention is a thermoplastic elastomer composition comprising a thermoplastic resin composition and a rubber composition dispersed in the thermoplastic resin composition, wherein the thermoplastic resin composition comprises a polyamide and an ethylene-vinyl alcohol copolymer or a poly(vinyl alcohol), the rubber composition comprises a halogenated isoolefin-p-alkylstyrene copolymer and is cross inked. The thermoplastic resin composition preferably comprises 1 to 25% by weight of the ethylene-vinyl alcohol copolymer or the poly(vinyl alcohol). The thermoplastic elastomer composition preferably comprises 100 parts by weight of the thermoplastic resin composition and 80 to 200 parts by weight of the halogenated isoolefin-p-alkylstyrene copolymer.Type: ApplicationFiled: May 17, 2011Publication date: January 31, 2013Applicant: The Yokohama Rubber Co., Ltd.Inventors: Shusaku Tomoi, Koichi Kawaguchi
-
Publication number: 20130030086Abstract: The present invention provides compositions comprising redispersible polymer powders of polyolefins with carboxyl group containing dispersant polymers and vinyl ester copolymers which may further comprise hydraulic or water curable inorganic cements for various construction applications, such as cement tile adhesives. Methods of making redispersible polymer powders of polyolefins are also provided, including forming an aqueous polyolefin dispersion, such as, for example, by mechanical dispersion, followed by drying to form the redispersible polymer powders.Type: ApplicationFiled: July 23, 2012Publication date: January 31, 2013Inventors: Robert BAUMANN, Sandra D. HOFMANN, Hartmut KUEHN, Margarita PERELLO
-
Patent number: 8349932Abstract: Disclosed is a polyamide composition including at least one semi-aromatic copolyamide, said semi-aromatic copolyamide consisting essentially of about 25 to about 55 mole percent repeat units of the formula —C(O)(CH2)mC(O)NHCH2ArCH2NH—??(I) and about 45 to about 75 mole percent repeat units of the formula —C(O)(CH2)mC(O)NH(CH2)nNH—??(II) wherein m is 8, 10, and/or 12, n is 6, 10 and/or 12 and Ar is a meta-substituted benzene ring; and said polyamide has a melting point equal to or less than 225° C.; and 0.25 to 20 weight percent of one or more polyhydroxy polymer(s) having a number average molecular weight of at least 2000 and selected from the group consisting of ethylene/vinyl alcohol copolymer and poly(vinyl alcohol). Also disclosed are molded or extruded articles including the polyamide composition.Type: GrantFiled: January 28, 2011Date of Patent: January 8, 2013Assignee: E I du Pont de Nemours and CompanyInventors: Shailesh Ratilal Doshi, Annakutty Mathew, Marvin M. Martens
-
Patent number: 8344064Abstract: There is provided a thermoplastic resin composition which comprises a modified rubber having excellent low-temperature durability dispersed in a polyamide resin matrix in order to improve the low-temperature durability or repeated fatigue resistance of the polyamide resin and which maintains its flowability and can be formed into a film even at a high content of the modified rubber, and has excellent low-temperature durability. The thermoplastic resin composition comprises a modified polyamide resin (A) obtained by melt blending 100 parts by weight of a polyamide resin (A1) and 0.05 to 5 parts by weight of a compound (A2) capable of binding to a terminal amino group of the polyamide resin, at a temperature equal to or higher than the melting point of the polyamide resin (A1), and a modified rubber (B) having an acid anhydride group, an epoxy group, or a carboxyl group or a derivative thereof. The compound (A2) is preferably a monofunctional epoxy compound.Type: GrantFiled: November 2, 2009Date of Patent: January 1, 2013Assignee: The Yokohama Rubber Co., Ltd.Inventor: Naoyuki Morooka
-
Publication number: 20120329909Abstract: A polymer composition comprising at least one epoxy resin; at least one vinyl ester polymer; and at least one nonionic surfactant having a molecular weight within the range of from 1,000 to 7,000 Daltons which is different from an alkyl polyglycol ether or alkylaryl polyglycol ether having 8 to 40 ethylene oxide units. A redispersible powder comprising the polymer composition can be used in a construction chemistry product containing a hydraulic binding agent.Type: ApplicationFiled: June 15, 2012Publication date: December 27, 2012Inventors: Hartmut KUEHN, Margarita PERELLO, Eva-Marie MICHALSKI
-
Publication number: 20120329939Abstract: A poly(arylene ether)-poly(hydroxy ether) block copolymer includes at least one poly(hydroxy ether) block and at least one poly(arylene ether) block, and the mole ratio of poly(hydroxy ether) blocks to poly(arylene ether) blocks is 0.95:1 to about 1.00:1. The poly(arylene ether)-poly(hydroxy ether) block copolymer can be prepared by reacting a telechelic poly(arylene ether) having terminal hydroxyl groups with a telechelic poly(hydroxy ether) epoxy resin having terminal epoxy groups, wherein the mole ratio of the telechelic poly(hydroxy ether) to the telechelic poly(arylene ether) is 0.95:1 to 1.00:1. The poly(arylene ether)-poly(hydroxy ether) block copolymer can be shaped into an article by extrusion, thermoforming, or molding, and is a compatibilizing agent for non-polar and polar polymers.Type: ApplicationFiled: June 27, 2011Publication date: December 27, 2012Inventor: Edward Norman Peters
-
Publication number: 20120301652Abstract: Provided is a thermoplastic elastomer composition comprising a polyamide resin and a modified rubber, in which low temperature resistance is improved. The thermoplastic elastomer composition comprising the polyamide resin and the modified rubber having an acid anhydride group or an epoxy group is characterized in that the modified rubber having an acid anhydride group or an epoxy group is modified with a secondary amine. The secondary amine is preferably a compound having a structural formula: R1—NH—R2, in which R1 is a linear alkyl group having 1 to 30 carbon atoms and R2 is a hydrocarbon group having 1 to 30 carbon atoms or a hydrocarbon group having 1 to 30 carbon atoms and having a hydroxyl group, a sulfonyl group, a carbonyl group or an ether bond.Type: ApplicationFiled: May 20, 2011Publication date: November 29, 2012Applicant: THE YOKOHAMA RUBBER CO.,LTD.Inventors: Koichi Kawaguchi, Yuichi Hara
-
Publication number: 20120302489Abstract: A film-forming composition includes a blend of polyvinyl alcohol and hydrophobically modified solution polymer or a water soluble polymer including an anionic ethylenically unsaturated monomer wherein the composition has a pH of about 5 or less. Further included are self-supporting materials, such as films, derived from the compositions and formulations including at least one volume-filling formulation surrounded by the self-supporting material.Type: ApplicationFiled: December 23, 2010Publication date: November 29, 2012Applicant: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.Inventors: Klin Aloysius Rodrigues, Matthew Michael Vanderhoof
-
Publication number: 20120289654Abstract: A process for preparing mechanically stabilized polyazoles, comprising the following steps: I) treating at least one polyazole having at least one amino group in a repeat unit with a solution comprising (i) at least one strong acid and (ii) at least one stabilizing reagent, the total content of stabilizing reagents in the solution being in the range from 0.01 to 30% by weight, II) performing the stabilization reaction directly and/or in a subsequent processing step by heating to a temperature greater than 25° C., the stabilizing reagent used being at least one polyvinyl alcohol. The polyazoles thus obtainable are notable especially for a high conductivity and a very good mechanical stability. They are therefore especially suitable for applications in fuel cells.Type: ApplicationFiled: May 9, 2012Publication date: November 15, 2012Applicant: BASF SEInventors: Friederike Fleischhaker, Jörg Belack, Oliver Gronwald
-
Publication number: 20120279176Abstract: An object of the present invention is to provide a packaging material for heat sterilization treatment, in which a decrease in the oxygen absorption capacity until the time of a heat sterilization treatment is prevented, a sufficient oxygen absorption capacity is exhibited at the time of a heat sterilization treatment, and odor that is generated along with oxygen absorption is suppressed. To attain the object, the present invention provides a resin composition for a package to be subjected to heat sterilization, comprising an oxygen absorptive resin composition dispersed in an oxygen barriering matrix resin, wherein the oxygen absorptive resin composition comprises a conjugated diene polymer cyclized product, the oxygen absorptive resin composition has a glass transition temperature of 31° C. to 55° C., and the oxygen barriering matrix resin is at least one resin selected from an ethylene-vinyl alcohol copolymer resin and a polyamide resin.Type: ApplicationFiled: December 27, 2010Publication date: November 8, 2012Inventors: Shizuo Kitahara, Kensaku Fujii
-
Patent number: 8298636Abstract: Provided is an EVOH resin composition suitable for use as a multilayer structure serving as a material for molded articles, in particular, liquid container such as bags for bag-in-boxes. The EVOH resin composition has such flexibility that even when used in applications where the resin composition is repeatedly folded or deformed over a long period, the resin composition does not develop pinholes or the like, and further has excellent gas barrier properties and melt molding stability.Type: GrantFiled: November 4, 2011Date of Patent: October 30, 2012Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.Inventors: Shouichi Kani, Noriaki Kurokawa
-
Patent number: 8293346Abstract: The objective of the invention is to provide a gas barrier resin composition that is excellent in oxygen absorbability and further excellent in adhesiveness to olefin resins, a structure comprising the same, and a multi-layer structure comprising the same. The oxygen-absorbing gas barrier resin composition disclosed comprises a cyclized product of a conjugated diene polymer and an ethylene/vinyl alcohol copolymer having a specified oxygen permeation rate. The oxygen-absorbing gas barrier resin composition further comprises an ?-olefin resin. The oxygen-absorbing gas barrier structure is obtained by molding the subject oxygen-absorbing gas barrier resin composition. The oxygen-absorbing gas barrier multi-layer structure comprises a layer of the subject oxygen-absorbing gas barrier structure and a sealing material layer.Type: GrantFiled: March 17, 2006Date of Patent: October 23, 2012Assignee: Zeon CorporationInventors: Shizuo Kitahara, Yasushi Tanaka
-
Publication number: 20120240798Abstract: Disclosed are a resin composition, a flexo printing plate precursor, a process for producing a flexo printing plate precursor, a process for making a flexo printing plate, and a flexo printing plate having a relief layer produced by the process for making a flexo printing plate. The resin composition comprises 1 to 25 wt % of colorless resin particles having a volume-average particle diameter of 0.2 to 30 ?m, 1 to 15 wt % of a photothermal conversion agent capable of absorbing light having a wavelength of 700 to 1,300 nm, and 2 to 95 wt % of a binder polymer, in which the 20% weight-reduction temperature of the colorless resin particles in thermogravimetric analysis under an inert gas atmosphere is from 200 to 600° C.Type: ApplicationFiled: March 22, 2012Publication date: September 27, 2012Applicant: FUJIFILM CORPORATIONInventor: Yuusuke KOZAWA
-
Publication number: 20120245238Abstract: The invention relates to a composition that has been obtained by the melt-process recycling of one or more multi-layer articles, where the multi-layer articles are composed of at least one melt-processible fluoropolymer layer. The composition of the invention is a compatible blend of the different layers from the multi-layer articles. The other layers of the multi-layer articles are also melt-processible, and include one or more layers chosen from: a) a melt-processible fluoropolymer of a different composition, b) a non-fluoropolymer, and c) a barrier layer. The composition is useful for forming an article in a melt-process operation. The composition may be used by itself, may be blended with other virgin or recycled materials, or may be used at low levels with melt-processible polymers as a process aid.Type: ApplicationFiled: September 23, 2010Publication date: September 27, 2012Applicant: Arkema Inc.Inventors: Saeid Zerafati, Sean M. Stabler, William J. Hartzel
-
Publication number: 20120237742Abstract: Disclosed is an inner liner for a pneumatic tire, the inner liner including no less than 8 resin-layers, the resin-layer having a layer A constituted with a resin composition containing a gas barrier resin, and a layer B constituted with a resin composition containing an elastomer, at least one of the resin compositions included in the layer A and the layer B that are adjacent with each other containing a metal salt, the content of the metal salt being no less than 1 ppm and no greater than 10,000 ppm in terms of metal element equivalent, and an interlayer adhesive force between the layer A and the layer B being no less than 500 g/15 mm. The layer A and the layer B are preferably alternately laminated.Type: ApplicationFiled: November 30, 2010Publication date: September 20, 2012Applicants: BRIDGESTONE CORPORATION, KURARAY CO., LTD.Inventors: Shinji Tai, Hiroshi Kawai, Satoshi Yamakoshi, Kouta Isoyama, Masao Hikasa, Yuwa Takahashi, Hideki Kitano, Tetsuo Amamoto, Takatsugu Tanaka
-
Publication number: 20120225990Abstract: Ethylene-vinyl alcohol (EVOH) based thermoplastic elastomers (TPE) and thermoplastic vulcanizates (TPV) including a cured rubber dispersed therein and an EVOH-rubber compatibilizer.Type: ApplicationFiled: March 3, 2011Publication date: September 6, 2012Inventor: Sunny JACOB
-
Publication number: 20120214943Abstract: Disclosed is a process for producing a thermoplastic elastomer composition having a matrix phase comprising a polyamide and an ethylene/vinyl alcohol copolymer and a disperse phase comprising a rubber composition, by which gelation by a reaction between a polyamide and an ethylene/vinyl alcohol copolymer can be inhibited and the dispersion of the rubber composition can be good. In the process, the polyamide resin and the rubber composition are melt-blended to the extent necessary for the rubber composition to form a disperse phase, and then the ethylene/vinyl alcohol copolymer is added and further melt-blended together.Type: ApplicationFiled: May 23, 2011Publication date: August 23, 2012Applicant: The Yokohama Rubber Co., Ltd.Inventors: Shun Sato, Koichi Kawaguchi
-
Patent number: 8236342Abstract: The invention provides a multi-polymer hydrogel article having a first polymeric, water-swellable material and a second polymeric material, organized such that a first region substantially comprises the first polymeric, water-swellable material, a second region adjacent the first region comprises a mixture of the first polymeric, water-swellable material and the second polymeric material, and a third region adjacent the second region substantially comprises the second polymeric material. The article exhibits an increasing concentration gradient of the second polymeric material moving from the first region, through the second region, to the third region.Type: GrantFiled: April 26, 2010Date of Patent: August 7, 2012Assignee: Zimmer, Inc.Inventors: Brian Thomas, Kai Zhang
-
Patent number: 8227543Abstract: The invention relates to a flexible thermoplastic composition resistant to the ageing effects of oil, said composition comprising a grafted copolymer containing polyamide blocks and consisting of a polyolefin backbone and at least one polyamide graft. According to the invention, the grafts are attached to the core by the residues of an unsaturated monomer (X) having a function that can react with a polyamide comprising an amine end or a carboxylic acid end; the residues of the unsaturated monomer (X) are attached to the backbone by grafting or copolymerization from the double bond thereof; and the composition comprises between 40 to 90 wt % of the polyolefin core comprising the unsaturated monomer (X); between 5 to 40 wt % of polyamide grafts; and between 5 to 40% of at least one polymer selected from a saponified ethylene/vinyl acetate copolymer and a polyamide.Type: GrantFiled: February 6, 2008Date of Patent: July 24, 2012Assignee: Arkema FranceInventors: Stephane Bizet, Jean-Jacques Flat
-
Patent number: 8211974Abstract: A curable formaldehyde-free binding composition for use with fiberglass is provided. Such curable composition comprises an acid-catalyzed reaction product of an aldehyde or ketone with a multihydric alcohol. When heated, the composition forms polyacetal or polyketal that undergoes curing to form a water-insoluble resin binder which exhibits good adhesion to glass. In a preferred embodiment, maleic anhydride initially serves as a catalyst and subsequently enters into a cross-linking reaction during curing to form a poly(ester-acetal). Also, in a preferred embodiment, the fiberglass is in the form of building insulation. In other embodiments the product can be a microglass-based substrate for use in a printed circuit board, battery separator, filter stock, or reinforcement scrim.Type: GrantFiled: October 7, 2005Date of Patent: July 3, 2012Assignee: Johns ManvilleInventors: Kiarash Alavi Shooshtari, Jawed Asrar
-
Publication number: 20120153544Abstract: Technologies and implementations for providing melt processable poly(vinyl alcohol) blends and poly(vinyl alcohol) based membranes are generally disclosed.Type: ApplicationFiled: December 16, 2010Publication date: June 21, 2012Applicant: EMPIRE TECHNOLOGY DEVELOPMENT LLCInventor: Carlos A. Cruz
-
Publication number: 20120157627Abstract: Disclosed is a polyvinyl alcohol resin composition capable of providing a melt-molded article with superior gas barrier properties and flex crack resistance. The resin composition comprises (A) a PVA resin having 1,2-diol unit in side chain thereof; and (B) a mixture of block copolymers each having an aromatic vinyl polymer block, and a conjugated diene polymer block and/or hydrogenated thereof, wherein the (B) mixture of block copolymers includes (B1) a block copolymer having no carboxyl group and (B2) a block copolymer modified with a carboxyl group-containing compound.Type: ApplicationFiled: February 28, 2012Publication date: June 21, 2012Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.Inventors: Mitsuo SHIBUTANI, Kazutoshi TSUJI, Kaoru INOUE, Norihito SAKAI
-
Patent number: 8188184Abstract: An environmentally safe additive and vehicle system are provided for water-based and oil-based printing inks, paints, coatings and adhesives which can be rapidly transferred, dispersed, dispensed, spread, dried and cured. The low cost, stable additive and vehicle system enhance multiple color, high speed printing with sharp, highly defined images and superior quality, and can be used on many different types of substrates, such as paper, paperboard, cardboard, clay coated board, foil, plastic, glass, metal, wood and composites. The additive may be formed by the reaction product of a photoinitiator, such as an UV-activated polyelectrolyte, and a monomer, such as an acrylate or a methacrylate in an aqueous solution. In other embodiments, the additive is formed from a carboxylic acid or anhydride and alkylalkanolamine monomer or a dialkylaminoalkyl acrylate or methacrylate monomer in an aqueous solution.Type: GrantFiled: November 30, 2010Date of Patent: May 29, 2012Assignee: Omnitech Environmental, LLCInventors: Leroy John Cook, Richard T. Skov
-
Patent number: 8163832Abstract: The invention is to provide: an aqueous emulsion which is excellent in emulsion polymerization stability when produced, and is excellent in mechanical stability, freezing stability, stability to long-term standing at high temperatures, water resistance adhesive property, and redispersibility; and a redispersible resin and adhesive where the aqueous emulsion is used. The invention relates to an aqueous emulsion comprising a polyvinyl alcohol-based resin (A) comprising a 1,2-diol component in a side chain and having an average degree of polymerization of 50 to 2,500 and a polymer (B) comprising at least one unsaturated monomer selected from an ethylenically unsaturated monomer and a diene-based monomer.Type: GrantFiled: April 25, 2006Date of Patent: April 24, 2012Assignee: The Nippon Synthetic Chemical Industry Co., Ltd.Inventors: Mitsuo Shibutani, Masahiro Saito
-
STYRENE-BUTADIENE BASED REDISPERSIBLE POLYMER POWDERS WITH IMPROVED STABILITY IN CEMENT APPLICATIONS
Publication number: 20120077907Abstract: A water redispersible polymer powder is produced by drying an aqueous mixture of a carboxylated styrene butadiene polymer and a colloidal stabilizer which includes a polyvinyl alcohol modified with an alkyl end chain. The alkyl modified polyvinyl alcohol provides excellent redispersibility of the redispersible polymer powder without adversely affecting spray drying. Cement compositions such as mortars, which contain the redispersible polymer powder with the alkyl modified polyvinyl alcohol exhibit unexpectedly superior stability and an unexpectedly lower rate of mortar viscosity buildup which is advantageous for workability or troweling.Type: ApplicationFiled: September 21, 2011Publication date: March 29, 2012Inventors: Etienne Lazarus, Gerold Lohmüller, Juergen Dombrowski, Hartmut Kuehn, Margarita Perello, Sonja Scharlemann -
Publication number: 20120070737Abstract: Disclosed are a binder composition for a rechargeable lithium battery including a cross-linked compound of polyacrylic acid substituted with an alkali cation and polyvinyl alcohol and an electrode and rechargeable lithium battery including the same. The cross-linked compound of polyacrylic acid and polyvinyl alcohol is obtained by heating polyacrylic acid and polyvinyl alcohol to effect a cross-linking reaction via esterification. The cross-linked compound of polyvinyl alcohol and polyacrylic acid substituted with an alkali cation may improve phase stability of a binder, and has high cross-linking ratio, thereby providing for excellent performance of a rechargeable lithium battery.Type: ApplicationFiled: March 3, 2011Publication date: March 22, 2012Applicant: SAMSUNG SDI., LTD.Inventors: Dong-Ho SON, Ki-Jun KIM, Ihn KIM, Chae-Woong CHO, Myoung-Sun KIM
-
Publication number: 20120052225Abstract: Provided is an EVOH resin composition suitable for use as a multilayer structure serving as a material for molded articles, in particular, liquid container such as bags for bag-in-boxes. The EVOH resin composition has such flexibility that even when used in applications where the resin composition is repeatedly folded or deformed over a long period, the resin composition does not develop pinholes or the like, and further has excellent gas barrier properties and melt molding stability.Type: ApplicationFiled: November 4, 2011Publication date: March 1, 2012Applicant: THE NIPPON SYNTHETIC CHEMICAL INDUSTRY CO., LTD.Inventors: Shouichi KANI, Noriaki KUROKAWA
-
Publication number: 20120052042Abstract: The present disclosure relates to amphiphilic compounds, self assembling compositions formed from the amphiphilic compounds and methods of making such compositions.Type: ApplicationFiled: February 22, 2010Publication date: March 1, 2012Inventors: Sébastien Ladet, Philippe Gravagna
-
Patent number: 8124681Abstract: Golf balls including at least one layer formed from high moisture barrier nanocomposite compositions that have increased moisture resistance and generally include a nanocomposite including an intercalated clay and at least one resin having a barrier property, a polyolefin resin, and a compatilizer.Type: GrantFiled: December 12, 2008Date of Patent: February 28, 2012Assignee: Acushnet CompanyInventors: Michael J. Sullivan, Murali Rajagopalan
-
Publication number: 20120035321Abstract: The present disclosure relates to compounds and medical devices activated with a solvophobic material functionalized with a first reactive member and methods of making such compounds and devices.Type: ApplicationFiled: February 22, 2010Publication date: February 9, 2012Inventors: Sébastien Ladet, Philippe Gravagna
-
Publication number: 20120029150Abstract: The present disclosure relates to a method of forming fibers. First and second precursors, each possessing a core and at least one functional group known to have click reactivity, are mixed. The mixed precursors are then extruded under heat to cross-link during fiber production.Type: ApplicationFiled: February 22, 2010Publication date: February 2, 2012Inventors: Ahmad Robert Hadba, Sébastien Ladet
-
Publication number: 20120028064Abstract: Polymer powders comprising in copolymerized form a) one or more vinyl aromatic comonomers, b) one or more 1,3-diene comonomers, c) from 0.1 to 15 percent, based on the total comonomer weight, of one or more comonomers selected from the group consisting of ethylenically unsaturated mono- and dicarboxylic acids and their salts, wherein at least 75 percent of the total number of carboxylic groups present in the polymer are located at the surface of the polymer particles in the powder and at least 75 percent of the carboxylic groups located at the surface of the polymer particles in powder are present in their salt form, and d) from 0 to 40 percent, based on the total comonomer weight, of one or more additional comonomers have an excellent redispersibility in water.Type: ApplicationFiled: July 29, 2010Publication date: February 2, 2012Inventors: Margarita Perello, Harmut Kühn, Jürgen Dombrowski, Francois M. Casati, Etienne Lazarus, Gerold Lohmüller
-
Publication number: 20120010364Abstract: Encapsulated cure systems are provided wherein a curative is incorporated into a solid or semi-solid carrier material whereby mere fracturing or failure of the capsule wall encapsulating such cure systems will not provide for or allow sufficient release of the curative. Also provided are adhesive systems incorporating said encapsulated cure systems.Type: ApplicationFiled: September 17, 2011Publication date: January 12, 2012Applicant: APPLETON PAPERS INC.Inventors: Todd Arlin Schwantes, Michael Curley Krzoska, Gregory Stephen Kulibert, Adam Gregg Malofsky, Bernard Miles Malofsky, Nagib Maurice Ward
-
Patent number: 8084536Abstract: A resin composition is provided which comprises from 50 to 95% by weight of a modified ethylene-vinyl alcohol copolymer (C) obtained by reacting an ethylene-vinyl alcohol copolymer (A) with a monovalent epoxy compound (B) having a molecular weight of 500 or less, and from 5 to 50% by weight of a soft resin (F) that has at least one functional group able to react with a hydroxyl group and has a Young's modulus at 23° C., 50% RH of 500 MPa or less, wherein the soft resin (F) is dispersed with an average particle diameter of 0.1 ?m or less in a matrix of the modified ethylene-vinyl alcohol copolymer (C). This resin composition is excellent in barrier properties and also in flex resistance and impact resistance at low temperature.Type: GrantFiled: January 11, 2006Date of Patent: December 27, 2011Assignee: Kuraray Co., Ltd.Inventors: Kouta Isoyama, Hiroyuki Shindome, Naoki Kataoka, Tomoyuki Watanabe